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Heavy Metals Analysis in Drinking Water of Lakki

Marwat District, KPK, Pakistan

Article in World Applied Sciences Journal · January 2016

DOI: 10.5829/idosi.wasj.2016.34.1.10252

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World Applied Sciences Journal 34 (1): 15-19, 2016
ISSN 1818-4952
© IDOSI Publications, 2016
DOI: 10.5829/idosi.wasj.2016.34.1.10252

Heavy Metals Analysis in Drinking Water of Lakki Marwat District, KPK, Pakistan
1
Shagufta Bibi, 2Rizwan Ullah Khan, 2Ruqia Nazir, 1Pirzada Khan, 2Hameed Ur Rehman,
1
Shakirullah Khan Shakir, 1Sonia Naz, 1M.A. Waheed and 1Rahmatullah Jan

1
Department of Botany, Kohat University of Science and Technology-26000, KPK, Pakistan
2
Department of Chemistry, Kohat University of Science and Technology-26000, KPK, Pakistan

Abstract: The present study was designed to investigate presence of different elements in drinking water of
district Lakki Marwat. Concentration of iron, zinc, lead, cadmium and chromium were studied in water samples
collected from seventeen different areas of Lakki Marwat district. It was observed that concentration of iron
was above the standard values in all samples and was found maximum in Wanda and Machen Khel areas
of Lakki Marwat. On the other hand, zinc was found to be well below the standard limits in all areas.
The concentration of lead varied in different areas with the highest concentration in Kaka Khel while the lowest
was found in Bego Khel and Mir Janan areas. Cadmium was found above the standard value of WHO in eight
places while remaining places had lower values of cadmium. Chromium was found at lower concentration in
thirteen areas while the remaining areas had chromium concentration above the standard limits of WHO. It can
be concluded from the present study that iron is commonly exceeding the standard limits in drinking water of
district Lakki Marwat, while the remaining element are variable in quantity in different areas.

Key words: Water Heavy Metals Atomic Absorption Spectrophotometer

INTRODUCTION and aesthetically pleasing. Ideally, it should be clear,

colorless and well aerated, with no unpalatable taste or
Water is one of the most important natural resources, odor and it should be free from pathogenic organisms.
useful for developmental purposes in both urban and rural Thus water for different purposes has its own
areas [1]. Clean and safe drinking water is not only the requirements for the composition and purity and each
basic need of human beings but it also has a great body of water has to be analyzed on a regular basis to
influence on the all aspects of life [2]. Water is the most confirm to suitability. The types of analysis could vary
drinking fluid by living things and is the universal from simple field testing for a single analyze to laboratory
solvent, therefore often a potential source of causing based multi component instrumental analysis. The
infections. The primary concern of the people living in analytical process involves sampling and sample storage
most of the developing countries, throughout the world since changes in composition of water do not stop once
is that of obtaining clean and safe drinking water. It is the sampling has been taken. Precautions have to be
needless to emphasize the importance of water in our life. taken to make sure that the water reaching the laboratory
We need water for different purposes; we need water for has the same composition as it did when the sampling was
drinking, for industries, for irrigation, for swimming, for done [3].
fishing etc. drinking water is defined as water intended Heavy metals present in water, soil and air are one of
primarily for human consumption but which has other the most serious ecological problems for human and
domestic uses. It may be consumed directly as it comes animal health. Lead, toxic at very low doses, is particularly
from the tap, or indirectly in beverages or foods prepared dangerous to people. It is the only heavy metal with no
with water and among its other uses are bathing and known beneficial effect in the human body. No case of
showering. (The guidelines do not cover bottled or lead deficiency has ever been noted in the medical
packaged water [3]. Drinking water should be safe to use literature. Many other elements, such as Cr, Mn, Mo, Ni

Corresponding Author: Hameed Ur Rehman, Department of Chemistry, Kohat University of Science and Technology-26000,
KPK, Pakistan. E-mail: [email protected].
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 World Appl. Sci. J., 34 (1): 15-19, 2016

and Se, although toxic at high concentration, are actually Table 1: Showing Heavy metals Concentrations in water of Laki marwat

required at lower levels. The exposure to lead can affect Iron Zinc Lead Cobalt Cadmium
every organ and, on a molecular level, it interferes with Location (Ppm) (Ppm) (PPm) (PPm) (mg/L)
fundamental biochemical processes. Lead has the ability 1 Lakkitown 0.378 0.021 0.009 0.032 0.002
to mimic or inhibit calcium action and to interact with 2 Begu khel 0.482 0.012 0 0.021 0.001
proteins. The most sensitive is the nervous system, 3 Ghazni khel 0.39 0.158 0.004 0.009 0.002
especially of children. Neuropsychological defects and IQ 4 Nawar khel 0.391 0.044 0.01 0.009 0.001
lowering [4] as well as encephalopathy and sensory 5 Mir janan 0.392 0.028 0.02 0.003 0.004
deficits have been proved after exposure to lead [5,6]. 6 Dalo khel 0.383 0.033 0.006 0.007 0.001
Biosorption is a process that utilizes low-cost biosorbents 7 Doda lakki 0.384 0.012 0.009 0.012 0.004
to remove toxic heavy metals [7]. 8 Masti khel 0.387 0.09 0.04 0.05 0.004
Atomic absorption spectrophotometry is commonly 9 Isak khel 0.42 0.002 0.004 0.006 0.003
used in many analytical laboratories for determination of 10 Wanda 1.97 0.012 0.15 0.21 0.005
trace elements in water samples and in acid digests of 11 Zahrhan 0.422 0.09 0.07 0.08 0.001
sediment or biological tissues. For determination of 12 Machan khel 1.223 0.09 0.021 0.012 0.002
selected trace elements such as iron (Fe), Cobalt (Co) 13 Ahmad khel 0.394 0.003 0.034 0.023 0.005
Cadmium (Cd), zinc (Zn) and Lead (Pb), the method of 14 Aba khel 0.416 1.101 0.18 0.015 0.006
World Commission on Water [8] modified for macro levels 15 kaka khel 0.41 0.366 0.91 0.023 0
was employed. The ground state atom absorbs light 16 dalat khel 0.617 0.016 0.034 0.25 0.006
energy of a specific wavelength as it enters the excited 17 Wanda fateh 0.406 0.005 0.063 0 0.007
state. As the number of atoms in the light path increases,
the amount of light absorbs also increases. By measuring Zinc (Zn) in Water Samples: Zinc (Zn) is one of the most
the amount of light absorbed a quantitative determination abundant trace elements and has been proved as an
of the amount of analysis can be made. The use of special essential nutrient for human, animal, plant and bacterial
light source and selection of wavelength allow the growth.The availability of zinc is greater in the food of
specific determination of individual element. The aim of animal origin than that of vegetable sources. Absorbed
the research work was to find out the awareness among zinc accumulates rapidly in liver, pancreas, spleen,
the public from heavy metals in drinking water. kidneys, hair and nails. The etiology of zinc deficiency
has been mainly attributed to reduced intake or
MATERIALS AND METHODS malabsorption of zinc from Gastro international tract
and its regular elimination in feces, urine and sweat [9].
Collection of Water Samples: All the samples 17 were Zinc deficiency manifests the following diseases
collected in the month of November 2012. The locations Acrodermatitis Entespathica (Danbolt), Hypogonadal
selected for the investigation were from Tehsil and Dwarfism and impaired Wound Healing. Zinc has been
District Lakki Marwat at sampling points of area names as long recognized as playing a critical physiological role in
shown in Fig. 1. Before the collection of samples, each structure and function of biomembrane. Zinc (Zn) is a
bottle was first rinsed with sample for pre -concentration. necessary element for human health. But the excess
Heavy metals in water samples were extracted with conc. amount of zinc can lead to adverse health effect on
HNO3 and preserved in a refrigerator till analysis for Fe, human. According to WHO [10] the standard acceptable
Zn, Cd, Co and Pb.The samples were analyzed for these value for zinc is 3 mg/L. The standard values are same for
selected heavy metals through atomic absorption ground and surface water. But the present data (Fig. 1)
spectrophotometer. shows that all the areas had values lower than the
standard values. The concentration of Zinc (Zn) in all
RESULTS AND DISCUSSION water samples varied in the range of 0.002 to 1.101 mg/L,
the lowest being observed in Isak khel water while the
The results of analysis of the drinking water samples highest in Aba khel.
collected from district Lakki Marwat showed that most the
water samples were unfit for human consumption Iron (Fe) in Water Samples: Iron (Fe) is the most
according to the WHO standards. The results of water important element of the human body, as it plays a pivotal
samples are given in table and graph. role in the erythropoietin as well as much intra- cellular

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 World Appl. Sci. J., 34 (1): 15-19, 2016

Fig. 1: Concentration of Zinc (Zn) in water samples with range of 0.002 to 1.101 (mg/L).

Fig. 2: Concentration of Iron (Fe) in water samples with range of 0.378 to 1.97 (mg/L)

reaction in all tissues and also in oxygen transport. Iron wide range of physiological, biochemical and behavioral
forms active compounds of heme- containing enzymes dysfunction in laboratory animals and humans. Lead (Pb)
such as cytochrome, catalase, peroxide and used to be common in the environment due to its
metalloproteinase such as transferrin, xanthene oxidase widespread historic use in petrol, paint and water pipes,
and hemoglobin. Iron deficiency is quite rampant in as well as its natural occurrence in soils as a consequence
human race and 20-40% of people, particularly infants of local geological conditions. From the 1970s onwards
and pregnant women, suffer from iron deficiency. In these uses of lead have been prohibited across Europe
drinking water WHO proposed the standard value is and the human health risks have studied extensively and
0.3 mg/L for Iron (Fe) [10]. The following results (Fig. 2) are generally well understood. Lead is considered very
indicate that all the areas of Lakki Marwat had toxic for plants and especially for microorganisms. WHO
higher values from the standard values. The Iron (Fe) set the desirable concentration of Lead for drinking water
content values of seventeen samples were found high 0.01 mg/L[11]. The concentration of Lead in all water
than the WHO (0.3 mg/L) standard. The concentration of samples (Fig. 3) indicates varied in the range of 0.00 to
Iron (Fe) in all water samples varied in the range of 0.378 0.19 mg/L. Among total Seventeen samples, 6 were having
to 1.97 mg/L, the lowest being observed in Lakki town Lead concentration below the Standard value and are
water while the highest in Wanda water samples. The therefore very safe. One sample i.e Nawar khel had a
polluted samples are not recommended for drinking standard value. While the ten samples result showed high
purposes. concentration of Lead (Pb) than the WHO (0.01 mg/L)
standard for drinking water. These include Mir janan (0.02
Lead (Pb) in Water Samples: Lead (Pb) pollution occurs mg/L) Machan khel (0.021 mg/L), Dalat Khel and ahmad
due to the lead mines, fuel combustion, sewage sludge khel (0.034 mg/L), Masti khel (0.04 mg/L),Wanda fateh
application and farmyard manure. This element has no (0.063 mg/L), Zahran (0.07 mg/L), Wanda (0.15 mg/L), Aba
beneficial effect in human. Lead is known to produce a khel (0.18 mg/L) and Kaka khel (0.19 mg/L).

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 World Appl. Sci. J., 34 (1): 15-19, 2016

Fig. 3: Concentration of Lead (Pb) in water samples with range of 0.00 to 0.19 (mg/L).

Fig. 4: Concentration of Cadmium (Cd) in water samples with range of 0.00 to 0.007 (mg/L).

Fig. 5: Concentration of Chromium in water samples varied in range of 0.00 to 0.25( mg/L).

Cadmium (Cd) in Water Samples: Cadmium (Cd) is a seventeen samples eight samples had lower values than
toxic metal causing both acute and chronic toxicity in WHO (0.003 mg/L) standard. One sample i.e. Isak khel had
humans. Intake of cadmium may cause acute a standard value and therefore very safe for drinking
gastrointestinal problems, such as vomiting and diarrhea purposes. While the other eight samples of drinking water
while chronic exposure to cadmium for a long time may of district Lakki Marwat showed relatively high
cause kidney damage [12]. Cadmium (Cd) is an element of contamination of Cd. Concentration of Cadmium in all
great concern from a toxicity point of view. The safe water samples (Fig. 4) indicates varied in the range of 0.00
standard for Cd concentrations in drinking water set by to 0.007 (mg/L). The polluted samples are not
WHO is 0.003 mg/L[13]. In Pakistan Cd concentrations in recommended for drinking purposes. Cadmium (Cd) is
ground and surface water, the standard value are same. poisonous and therefore water from the polluted sources
The data of the study (Fig. 4) revealed that out of is very harmful.

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 World Appl. Sci. J., 34 (1): 15-19, 2016

Chromium (Cr) in Water Samples: Chromium (Cr) itself 4. Bukhari, A.O., S. Ahmad and M. Mirza, 1987. The
is not toxic and plays an important role in the Role of Trace Elements in Health and Diseases.
carbohydrate metabolism in the body. But some of its Elements in Health and Diseases. In: The
compounds especially in its hexavalent status cause skin Proceedings of the 2nd international conference
diseases, cancers, irritants and diseases related to the held in Karachi, Pakistan.
digestive, excretory, respiratory and reproductive system 5. Bettger, W.J. and O.B.L. Dell, 1981. A Critical Role of
[14]. Chromium is one of the most common elements in the Zinc in the Structure and Function of Biomembranes.
earth crust and water. For drinking water WHO described Life Sci., 28: 1425-1438.
its maximum allowable concentration at 0. 05 mg/L[13]. In 6. Patrick, L., 2006. Lead toxicity, a review of the
water sources of Pakistan it has been documented in a literature. Part I. Exposure, evaluation and treatment.
wide concentration range by different studies. The Altern. Med. Rev., 11(1): 2-22.
concentration of Chromium in all water samples (Fig. 5) 7. Kratochvil, D. and B. Volesky, 1998. Advances in the
showed varied in the range of 0.00 to 0.25 mg/L. Among biosorption of heavy metals. Trends Biotechnol.,
total seventeen samples, thirteen were having Chromium 16(7): 291-300.
concentration below the WHO standard limit and are 8. Abid, M.A. and A. Jamil, 2005. The Assessment of
therefore very safe for drinking purposes. The sample of Drinking Water Quality and Availability in NWFP,
Masti khel had a standard value while the three samples NWFP, RWSSP, Peshawar.
showed high concentration of Chromium than the WHO 9. Barbier, O., G. Jacquillet, M. Tauc, M. Cougnon and
(0.05 mg/L) standard for drinking water. These included P. Poujeol, 2005. Effect of heavy metals on and
Zahran (0.08 mg/L) Wanda (0.21 mg/L) and Dalat handling by, the kidney. Nephron Physiol,
khel.(0.25 mg/L). 99: 105-10.
10. WHO, 1999. Overview of Environment and Health in
CONCLUSIONS Europe in the 1990s. Report prepared for the 3rd
European Conference on Environment and Health.
From the obtained studies it may be concluded that Geneva, World Health Organization.
the water of Lukki Marwat were suitable for drinking. 11. WHO (1999).Overview of Environment and Health in
Europe in the 1990s. Report prepared for the 3rd
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