Assoc Dissoc
Assoc Dissoc
Assoc Dissoc
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PHYSICS OF FLUIDS 19, 057102 共2007兲
electrodes or induction from electric fields, but by dissocia- trodes. The ion density distributions in the dielectric liquid
tion of neutral electrolytic species within the dielectric liq- bulk can be determined on the basis of the conservation law
uid. The EHD conduction pumping can be applied to drive of neutral species and ions. Under a steady-state condition,
both isothermal liquid and two-phase fluids without the deg- the governing equations of ion distribution have the follow-
radation of the working fluid electric properties. ing expressions:
At the current stage, experimental studies have shown
៝ · 共K E៝ p + u៝ p − Dⵜ
ⵜ ៝ p兲 = k c − k pn, 共3兲
that the EHD conduction pumping successfully generated + D R
pressure up to several kPa, drove dielectric liquid, and con-
trolled two-phase refrigerant flow distribution.5–9 The associ- ៝ · 共− K E៝ n + u៝ n − Dⵜ
ⵜ ៝ n兲 = k c − k pn, 共4兲
− D R
ated electrical current was on the order of microamperes.
and
Such a nonmechanical and low-power-consumption pumping
mechanism can be utilized for flow generation and active ៝ · E៝ = 共p − n兲/,
ⵜ 共5兲
control in either ground or microgravity environment. Nev-
ertheless, most studies conducted have focused on the real- where c, n, p, and D denote the concentration of neutral
ization of the pumping phenomenon. More fundamental/ species, the charge density of negative ions, the charge den-
analytical studies, such as unified nondimensional modeling, sity of positive ions, and the charge diffusion coefficient,
theoretical analysis with convection effects considered, and respectively. K, kR, and kD denote the ion mobility, the re-
pumping efficiency prediction, are required for a thorough combination rate, and the dissociation rate, respectively. At a
understanding of this new EHD pumping phenomenon. In thermodynamic equilibrium, the ion conservation allows
the following text, an asymptotic nondimensional EHD con- kDc = kR p0n0 = kR p20 = kRn20 , 共6兲
duction pumping model with the convection term incorpo-
rated will be developed and discussed in details. The theo- where p0 and n0, respectively, represent the positive and
retical analysis will reveal the effects of flow convection on negative ion densities at an equilibrium state and n0 = p0. As-
the EHD conduction pumping and the energy conversion suming the positive and negative ions have identical mobili-
during the pumping process. Based on the nondimensional ties, i.e., K+ = K− = K, the recombination rate constant
model, the pumping efficiency of the EHD conduction becomes10
pumping will also be analytically derived and compared with kR = 2K/. 共7兲
the experimental data.
The electrical current density in the dielectric liquid has the
following expression of
II. MODELING OF EHD CONDUCTION PUMPING
WITH FLUID MOTION ៝j = 共K+ p + K−n兲E៝ + 共p − n兲u៝ − Dⵜ
៝ 共p − n兲, 共8兲
The EHD conduction pumping phenomenon stems from where the three terms on the right side are named as the
the dynamic dissociation/recombination process of ions in a mobility term, the convection term, and the diffusion term,
dielectric liquid. At a thermodynamic equilibrium state, a respectively. Since the electrical conductivity of a static di-
neutral electrolyte, denoted as AB, dissociates into counter- electric liquid can be expressed as
ions, denoted as A+ and B−, while these ions can recombine
back into AB. The corresponding dynamic process can be e = 2n0K = 2p0K, 共9兲
expressed in the following form: Eq. 共8兲 becomes
Dissociation
Recombination ៝j = 1 e共p/p0 + n/n0兲E៝ + eu៝ − Dⵜ
៝ ,
e 共10兲
AB ↔ + −
A +B . 共2兲 2
With an external electric field applied to a dielectric liquid, where e = p − n denotes the local net charge density. The dot
existing ions due to the dissociation of neutral species expe- product of the electrical field intensity and the electrical cur-
rience the electrical Coulomb force, which concentrates the rent density represents the localized electrical power
positive and negative ions around counter-polarized elec- consumption
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057102-3 Electrical charge transport and energy conversion Phys. Fluids 19, 057102 共2007兲
៝ · 共KE៝ p + u៝ p兲 = k c − k pn
ⵜ 共12兲
D R
and
៝ · 共KE៝ n − u៝ n兲 = − 共k c − k pn兲.
ⵜ 共13兲 共16兲
D R
Equations 共5兲, 共12兲, and 共13兲 constitute the theoretical where U is the average flow velocity. The above equation
model for the EHD conduction pumping process in the ab- implies that at a given external voltage potential, the result-
sence of charge diffusion. Along with proper boundary con- ant dielectric flow velocity affects the EHD conduction
ditions and given velocity profile, these governing equations pumping efficiency in both direct and indirect manners, as
are sufficient to determine the charge and electric field dis- the flow convection transports ions in the dielectric liquid
tributions. With the solved charge and electrical field distri- and influences the local net charge distribution. Solving Eqs.
butions, the total consumed electric current associated with 共5兲, 共12兲, and 共13兲 with convection terms becomes the key
the EHD conduction pumping phenomenon can be obtained step to get the distribution profiles of ion and electrical field
by integrating Eq. 共10兲 along the cathode or anode boundary for quantitative analyses of the EHD conduction pump
performance.
The theoretical analyses in this paper are presented in a
共14兲 nondimensional form to unify the EHD conduction pumping
phenomenon under various conditions. Due to the complex-
where the ion diffusion term is neglected. The EHD conduc- ity of theoretical analysis, the theoretical analyses are carried
tion pumping pressure generation can also be expressed as out mainly within a one-dimensional spatial domain. Similar
to the theoretical model in the absence of fluid flow previ-
共15兲 ously applied by Feng and Seyed-Yagoobi,7 the perforated
disk-ring electrodes as shown in Fig. 2 are treated as the left
where A denotes the cross-sectional area of liquid flow path half of a parallel permeable 共or perforated兲 plate electrode
and E⬜ denotes the electric field perpendicular to the cross- pair, in order to one-dimensionally formulate the electric
sectional surface. field and the flow field. Initially, the electrode gap distance is
Hydrodynamic pumping efficiency is a key parameter to utilized to normalize the one-dimensional theoretical model
evaluate the performance of an EHD conduction pump. Gen- with convection term included. Later, the heterocharge layer
erally, the pumping efficiency is defined as the ratio of work thickness, instead of the electrode gap, will be utilized as the
output to power input. For an EHD conduction pump, its length scale to obtain the asymptotic solutions. Such
work output is the product of pressure generation and volu- asymptotic theoretical model will also be extended to two-
metric flow rate, while the corresponding electric power con- dimensional flow field with the electric field treated one-
sumption represents its power input. With the flow treated as dimensionally. MATLAB Version 7.0 has been utilized to nu-
homogeneous, the EHD conduction pumping efficiency can merically calculate the ion and electrical field distribution
be simplified as profiles, if the analytical solutions are unavailable.
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057102-4 Y. Feng and J. Seyed-Yagoobi Phys. Fluids 19, 057102 共2007兲
n* = 0 at x* = 1, 共22兲
⌽* = 1 at x* = 0, 共23兲
and
⌽* = 0 at x* = 1. 共24兲
While x* = x / d is applied, the resultant parameter Co
= n0d2 / V is a function of n0, , V / d, and d. Thus, Co cor-
responds inversely to the intensity of applied electric field.
When the nominal applied electric field V / d becomes stron-
ger, the value of Co decreases. The variation of Co along with
the applied electric field makes it difficult to unify the non-
dimensional solutions of the EHD conduction pumping
model. Figure 4 shows the rather different nondimensional
ion and electric field profiles at various Co ranging from 1.0 FIG. 5. Profiles of n*E* at various u* and Co = 8.0.
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057102-5 Electrical charge transport and energy conversion Phys. Fluids 19, 057102 共2007兲
at Co Ⰷ 1.0, the nondimensional governing equations and its dE*/dx* = C共p* − n*兲. 共27兲
solutions become independent of the nominal applied electric If Co Ⰷ 1.0, the applied electric field generates a rather thin
field V / d. heterocharge layer compared to the electrode gap distance,
and 0 Ⰶ d. Consequently, the boundary conditions can be
A. Asymptotic theoretical model using heterocharge
further simplified as
layer thickness as length scale
p* = 0 at x* = 0, 共28兲
As presented above, at Co Ⰷ 1.0, the normalized curves
共such as p*E*, n*E*, and E*兲 between two parallel electrodes
p* = n* = 1 at x* → ⬁, 共29兲
become flat and reach 1.0 at the middle. For simplicity, the
following analyses are focused on the left half of the parallel
electrode pair with the constant boundary conditions set at E* = 1 at x* → ⬁. 共30兲
the middle, as shown in Fig. 8. The governing equations will 7
Feng and Seyed-Yagoobi obtained the following analytical
be normalized as those in the above section, except that x* solutions of Eqs. 共25兲–共30兲 in the absence of flow motion
= x / d will be replaced by x* = x / 0 and C = n0d0 / V will be 共u* = 0兲:
used instead of Co. 0 denotes the characteristic thickness of
the heterocharge layer in a static dielectric liquid 共u* = 0兲.
The corresponding nondimensional governing equations
冕 0
共p*E*兲 dz
2C共1 + g兵e 关z共z − 2.0兲兴其兲
−1 = x* , 共31兲
become
d共p*E* + p*u*兲/dx* = 2C共1 − p*n*兲, 共25兲 共n*E*兲 = − 共p*E*兲 + 2.0, 共32兲
d共n*E* − n*u*兲/dx* = − 2C共1 − p*n*兲, 共26兲 共E*2兲 = p*E*共p*E* − 2.0兲/g兵e−1关p*E*共p*E* − 2.0兲兴其, 共33兲
and where the function g兵 其, is defined as g兵yey其 = y. At x* = 1.0,
Eq. 共31兲 gives that the parameter C has a constant value of
1.8 when u* = 0. Since the definition of C excludes the in-
fluence of the flow motion, the value of C remains the same
even when u* ⫽ 0. With x* = x / 0 and C = n0d0 / V = 1.8 in-
troduced, the asymptotic theoretical model becomes solely
dependent on the flow velocity of the dielectric liquid as long
as Co Ⰷ 1.0.
In the presence of flow motion 共u* ⫽ 0兲, the convection
tends to alter the heterocharge layer thickness. Figures 9 and
10 show the normalized profiles 共i.e., p*E*, n*E*, E*兲, around
a fully permeable anode at u* = −0.4 −0.2, 0, 0.2, and 0.4. For
the electrode configuration of Fig. 8, the heterocharge layer
becomes thinner around the anode electrode when the dielec-
tric fluid flow is opposite to the x direction and vice versa.
This is due to the fact that the convective flow in the positive
x direction carries the charges away from the anode elec-
trode, resulting in a thicker heterocharge layer. Such a
FIG. 7. Profiles of n*E* at various u* and Co = 8.0. change in the heterocharge layer further affects the pressure
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057102-6 Y. Feng and J. Seyed-Yagoobi Phys. Fluids 19, 057102 共2007兲
FIG. 9. Profiles of n*E* and p*E* around a permeable electrode at various FIG. 11. Prediction of EHD conduction pumping pressure generation versus
u *. velocity for a permeable electrode.
冏冕 冏
electrodes was assumed to be uniform, since the electrodes
+⬁
were considered as porous and permeable. However, this as-
共n*E* − p*E*兲dx* sumption does not properly correspond to the imposed ve-
⌬P 0
冏冕 冏
u*⫽0
⌬P =*
= . 共34兲 locity distribution between the perforated disk-ring electrode
⌬P0 +⬁
pair studied here. As illustrated in Fig. 2, the velocity profile
共n E − p E 兲dx
* * * * *
0
varies along x direction and consequently affects the ion den-
u*=0
sity and electric field distributions accordingly.
The predicted curve of normalized velocity u* versus To predict the velocity variation of dielectric liquid
normalized pressure head ⌬P* has been provided in Fig. 11 along the x direction, the solid portions of the perforated disk
for fully permeable electrodes. The results show that when electrode will be treated as flat plates with a length of 2c
the pumping velocity reaches its mobility limit 共i.e., = 0.8 mm. The flow motion in the dielectric liquid is consid-
u* = −1.0兲, the EHD conduction pumping pressure generation ered as ideal flow with viscosity effects neglected. According
decreases to zero as the convective flow blows off the het- to Milne-Thomson,12 the complex potential flow around a
erocharge layer from the permeable electrode. However, the vertical plate with a width of 2c is given as follows:
blow-off phenomenon of the heterocharge layer at high ve-
locities is not true for the perforated electrode design, since w = U共z2 + c2兲1/2 , 共35兲
the liquid flow stagnates on the solid electrode surface. In the
next section, a nonviscous two-dimensional flow assumption where w = + i and z = x + iy. The streamline equation has
will be used to predict the convective flow around the perfo- the following form:
rated electrode.
关共x/c兲2 + 1 + 共/Uc兲2兴/关1 + 共xUc/兲2兴 = 共y/c兲2 . 共36兲
The streamlines around the flat plate are depicted in Fig. 12.
The local velocity at y = 0 can be expressed as
d 冋冕−c
c
共KEp + ux p兲dy 册 = 冕 c
共kDc − kR pn兲dy, 共38兲
FIG. 10. Profiles of E* around a permeable electrode at various u*. dx + 2uy p −c
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057102-7 Electrical charge transport and energy conversion Phys. Fluids 19, 057102 共2007兲
FIG. 13. Profiles of n*E* and p*E* for ideal flow at various u* and c*
= 0.43.
FIG. 12. Streamlines of flow around a vertical plate.
冋冉 u *x *
冊册
冋冕 册
d p* E* +
c 共c*2 + x*2兲1/2 u*c*2
+ p*
共− KEn + uxn兲dy
冕
d c dx* 共c*2 + x*2兲3/2
−c
= 共kDc − kR pn兲dy, 共39兲 = 2C共1 − p*n*兲, 共45兲
dx + 2uyn −c
and
and
冋冉
d n* E* −
u *x *
冊册
冉冕 冊 冕 共c + x*2兲1/2
*2
c c u*c*2
d Exdy 共p − n兲dy − n*
dx* 共c + x*2兲3/2
*2
−c −c
= 共40兲 = − 2C共1 − p*n*兲. 共46兲
dx
With the effects of nonuniform flow field taken into account
with the same boundary conditions indicated by Eqs. and the boundary conditions remaining the same, the ion
共28兲–共30兲. Assuming n, p, E, and ux do not vary along the y density and electric field distributions become different from
direction and ux ⬅ 兩ux兩y=0, the mass conservation law requires those discussed in Sec. III A. The profiles with u* = −0.4,
that −0.2, 0, 0.2, and 0.4 for c* = 0.43 and c* = 0.645 are depicted
in Figs. 13 and 14. c* = 0.43 and c* = 0.645 correspond to the
uy = Uc3/共c2 + x2兲3/2, at y = ± c, 共41兲 applied voltages of 15 and 10 kV, respectively, with c
= 0.4 mm and R-123 as the working fluid. Figure 15 shows
and Eqs. 共38兲–共40兲 can be expressed as the pressure generation versus velocity at the applied volt-
冉 冊
ages of 15 kV and 10 kV with the fluid motion treated as
Ux ideal flow. On the basis of the ideal flow assumption, the
d KEp + p
共c + x2兲1/2
2
Uc2
+ 2 2 3/2 p = kDc − kR pn,
dx 共c + x 兲
共42兲
冉
d − KEn +
Ux
共c + x2兲1/2
2 n
Uc2
冊
+ 2 2 3/2 n = kDc − kR pn,
dx 共c + x 兲
共43兲
and
FIG. 17. Theoretical predictions versus experimental data 共pressure losses FIG. 19. Comparison of experimental current consumption data with theo-
within pumping section are not included兲. retical results for EHD conduction pumping.
冏 冏
integral portion only varies with the flow motion. The model I* = =
reveals that the pressure generation during EHD conduction 兩I兩u*=0 1 V
pumping depends only on the applied electrical field, the m共1 − r兲Ae 共n*E* − n*u*兲
2 d x*=0,u*=0
flow velocity, and the electrical permittivity of the working
fluid. The variation in the electrical conductivity of the work- 兩共n*E* − n*u*兲兩x*=0
= . 共48兲
ing fluid will not affect the pressure generation as long as 兩共n*E* − n*u*兲兩x*=0,u*=0
Co Ⰷ 1.0 and the other factors remain unchanged, though
higher electrical conductivity may make it difficult to estab- Figure 19 shows the comparison of theoretical and experi-
lish intense electric field in the dielectric fluid. mental normalized electric current levels.
For the perforated electrode design in this paper, the con- When investigated one-dimensionally, the EHD conduc-
sumed electric current associated with the EHD conduction tion pumping efficiency can be simplified as
pumping phenomenon can be simplified from Eq. 共14兲 as Au⌬P
冏冋 冉 冊 册冏 EHD pump =
1 p n ៝ VI
I = m共1 − r兲A e + E + eu៝
1 V
2 p0 n0 x*=0
Aum共1 − r兲 冕0
⬁
共n − p兲Edx
= m共1 − r兲Ae 兩共n*E* − n*u*兲兩x*=0 , 共47兲 =
2 d 1 V
Vm共1 − r兲A e 兩共n*E* − n*u*兲兩x*=0
where the ion diffusion term is neglected, and 兩p兩x*=0 = 0. 2 d
Normalization of the current level leads to VK V V *
d
n0 C
d n 0d
u 冕 ⬁
共n* − p*兲E*dx*
冏 冏
0
=
1 V
eV 共n*E* − n*u*兲
2 d x*=0
VK
u*
0
冕 ⬁
共n* − p*兲E*dx*
= 3.6 . 共49兲
e d d 兩共n*E* − n*u*兲兩x*=0
Since 兩u*兰⬁0 共n* − p*兲E*dx* / 共n*E* − n*u*兲兩x*=0 is only related
to u* in the asymptotic model when Co Ⰷ 1.0, it can be des-
ignated by f共u*兲. Equation 共49兲 will be further expressed as
VK *
EHD pump = 3.6 f共u 兲. 共50兲
e d d
FIG. 18. Theoretical predictions versus experimental data 共pressure losses The above equation indicates that the efficiency of EHD con-
within pumping section are included兲. duction pumping depends on flow motion, working fluid
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057102-10 Y. Feng and J. Seyed-Yagoobi Phys. Fluids 19, 057102 共2007兲
共d兲 The pumping efficiency can be evaluated with trohydrodynamically induced dielectric liquid flow through pure conduc-
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9
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Ⰷ 1.0 was invalid. 82, 262 共1942兲.
11
I. Adamczewski, Ionization, Conductivity and Breakdown in Dielectric
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