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    Welcome: Siddiky Md. Mahfuzur Rahman ID No: 12990214 Bachelor of Engineering, Chemical Engineering

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    Mahfuzur Rahman Siddiky
    This document discusses the preparation and application of a catalyst for the one-step oxidation synthesis of acrylic acid from propylene. It describes the experimental method for preparing the Mo1V0.17Te0.11Nb1.3B0.11 catalyst and testing it in the catalytic oxidation of propylene to acrylic acid. The optimal reaction conditions were found to be a temperature of 420°C, a propylene space velocity of 3.8mL/(g·min), a propylene to oxygen ratio of 1.9:1, and a water to propylene ratio of 0.8-6:1. Under these conditions, the conversion of propylene was 58.51

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    Welcome: Siddiky Md. Mahfuzur Rahman ID No: 12990214 Bachelor of Engineering, Chemical Engineering

    Uploaded by

    Mahfuzur Rahman Siddiky
    48 views21 pages
    This document discusses the preparation and application of a catalyst for the one-step oxidation synthesis of acrylic acid from propylene. It describes the experimental method for preparing the Mo1V0.17Te0.11Nb1.3B0.11 catalyst and testing it in the catalytic oxidation of propylene to acrylic acid. The optimal reaction conditions were found to be a temperature of 420°C, a propylene space velocity of 3.8mL/(g·min), a propylene to oxygen ratio of 1.9:1, and a water to propylene ratio of 0.8-6:1. Under these conditions, the conversion of propylene was 58.51

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    This document discusses the preparation and application of a catalyst for the one-step oxidation synthesis of acrylic acid from propylene. It describes the experimental method for preparing the Mo1V0.17Te0.11Nb1.3B0.11 catalyst and testing it in the catalytic oxidation of propylene to acrylic acid. The optimal reaction conditions were found to be a temperature of 420°C, a propylene space velocity of 3.8mL/(g·min), a propylene to oxygen ratio of 1.9:1, and a water to propylene ratio of 0.8-6:1. Under these conditions, the conversion of propylene was 58.51

    Copyright:

    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd
    Download as pdf or txt
    48 views21 pages

    Welcome: Siddiky Md. Mahfuzur Rahman ID No: 12990214 Bachelor of Engineering, Chemical Engineering

    Uploaded by

    Mahfuzur Rahman Siddiky
    This document discusses the preparation and application of a catalyst for the one-step oxidation synthesis of acrylic acid from propylene. It describes the experimental method for preparing the Mo1V0.17Te0.11Nb1.3B0.11 catalyst and testing it in the catalytic oxidation of propylene to acrylic acid. The optimal reaction conditions were found to be a temperature of 420°C, a propylene space velocity of 3.8mL/(g·min), a propylene to oxygen ratio of 1.9:1, and a water to propylene ratio of 0.8-6:1. Under these conditions, the conversion of propylene was 58.51

    Copyright:

    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd
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    of 21

    WELCOME

    SIDDIKY MD. MAHFUZUR RAHMAN


    ID No: 12990214
    Bachelor of Engineering, Chemical
    Engineering
    Preparation and Application of Catalyst for One Step Oxidation Synthesis

    of Acrylic Acid from Propylene

    Contents

    Introduction to acrylic acid

    Method for producing acrylic acid

    Experimental method for preparation of catalyst

    Craft research of propylene to acrylic acid

    Conclusion
    Catalyst

    Catalyst is a substance, usually used in small amounts relative to the reactants, that modifies and
    increase the rate of the reaction without being consumed in the process.

    Its participation is a process or event especially without being involved in or changed by consequence .
    Reaction
    Keywords

    Acrylic acid

    Propylene

    Conversion

    Selectivity

    Yield
    Acrylic acid

    AcrylicacidisanorganiccompoundwiththeformulaCH 2CHCO2H.

    It is the simplest unsaturated carboxylic acid consisting of a vinyl group connected directly to a carboxylic
    acid terminus.

    Acrylic acid is a useful compound because polymers and copolymers that are used for high water-
    absorbing materials, paints, adhesives, fibers, and so on.
    Method for producing Acrylic acid

    Cyanide Ethanol Method

    Propylene Method

    Acrylonitrile Method

    High Reppe Method


    Uses of Acrylic Acid

    Paint and Varnish

    Chemical Fiber and Textile Processing

    Leather Processing

    Paper Processing

    Plastic
    Experimental method for preparation of catalyst
    Reagent

    Ammonium meta vanadate(NH 4)6Mo7O24.4H2O)

    Ammonium paramolybdate(NH 4VO3)

    Hydrogen peroxide(H2O2)

    deionized water(H2O)

    telluric acid(TeO2)

    Niobium hydroxide(Nb(OH)O 7)

    Oxalic acid(C2H2O4.2H2O)

    Nitric acid (NNO3) (1:1)


    Rotary evaporation

    Box type resistance furance


    Fixed bed reactor

    Tubular resistance furnace


    Preparation of catalyst
    Catalytic Oxidation Method

    The amount of 2g catalyst packed in the middle of the reactor thermocouple


    placedinthecenterofthecatalystbed.

    Propylene, air, water vapor in proportion to the feed gas into the reaction
    tube, the reaction occurred at a suitable temperature.

    Reaction from the exhaust gas chromatograph online testing the liquid
    product obtained by the reaction is condensed by the injector into the
    quantitative gas chromatography.
    p py y
    Process variable

    Catalyst

    Temperature

    space velocity

    the ratio of oxygen and propylene

    the ratio of the water and propylene


    Optimum Catalyst Selection

    Theselectivityofacrylicacidversus The yield of acrylic acid versus


    ConversionofPropyleneversus
    temperature temperature
    temperature
    The Optimum Choice of Reaction Condition

    From the above analysis of the catalytic performance


    of the best catalyst, here we use the following four
    aspects.

    Mo1V0.17Te0.11Nb1.3B0.11 oxidation catalyst propylene


    acrylic step reaction process were studied.
    Effect of Temperature

    Conversion of propylene, selectivity and yield of Selectivity and yield of acetic acid versus
    acrylic acid versus temperature temperature
    The Impact of Airspeed/ Propylene

    17

    Conversion, selectivity and yield of acrylic acid Selectivity and yield of acetic acid versus space
    versus space velocity velocity
    Ratio of Oxygen/Propylene

    Conversion of propylene, selectivity and yield Selectivity and yield of acetic acid versus
    acrylic acid versus oxygen propylene ratio oxygen propylene ratio
    Ratio of Water/Propylene

    Conversion, selectivity and yield of acrylic acid Selectivity and yield of acetic acid
    versus water propylene ratio versus water propylene ratio
    Conclusions

    The process for the catalysts in this study, the optimal catalyst is Mo 1V0.17Te0.11Nb1.3B0.11.

    Used the optimum temperature of the catalyst is about 420.

    If best when using the catalyst space velocity of propylene is 3.8mL / (g min) or so.

    If best when using the catalyst propylene with oxygen ratio is about 1.9:1.

    If best when using the catalyst of water-propylene ratio is about 0.8 ~ 6:1.

    In this condition, conversion of propylene was 58.51%, selectivity of acrylic acid is about
    67.14% that acrylic acid in a yield of 39.48%.

    Selectivity and yield of acetic acid were 7.44% and 4.37% respectively.

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