Engineering Design Handbook - Hydraulic Fluids
Engineering Design Handbook - Hydraulic Fluids
Engineering Design Handbook - Hydraulic Fluids
MP 7061123
PROPERTY OF
&MC TECHNICAL LlBRARfo
ENGINEERING DESIGN
HANDBOOK
HYDRAULIC FLUIDS
~~ ~ ~
USTOF ILLUSTRATIONS
Fig.No . Title
.
Page
.
1-1 Graphic Symbol for a Three.position. Four-port Hydraulic Valve ...................... 1-3
1-2 Graphic Symbols for (A) a Hydraulic Pump With Variable Displacement and Pressure
Compensation; and (B) a HydraulicTMotor With Variable Displacement .................-1-3
1-4 Graphic Symbol for a Variable-flow Hydraulic Volume Control. Such as a Needle Valve..... 1-3
1-5 Graphic Symbol for a Pressure Relief Valve ....................................... 1-3
2-1 Rotary Motor Circuit Which Produces Constant Torque ............................. 2.2
2-3 Typical Operating Characteristic Curves for a Spur Gear Rotary Hydraulic Pump:..........2.4
2-4 Crescent Seal Internal Gear Hydraulic Pump ...................................... 2.4
2-5 Gerotor Internal Gear Hydraulic Pump .......................................... 2.4
2-11 Redial-piston Hydraulic Pump With Rotating Piston Housing ......................... 2-7
2-12 Radial-piston Hydraulic Pump With Spherical Pistons ............................... 2.7
X
AMCP 706-123
Fig.No. Title
.
Page
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2-26 Typical Operating Characteristic Curves for a Spur Gear Hydraulic Motor . . . . . . . . . . . . . . .2-14
2-21 Typical Operating Characteristic Curves for a Crescent Seal Hydraulic Motor ..............2.14
2-28 Typical Operating Characteristic Curves for a Gerotor Hydraulic Motor ..................2.15
2-29 Typical Operating Characteristic Curves for a Vane Hydraulic Motor ...................-2-15
2-30 Typical Single-vane Actuator .................................................. 2.16
2-36 Hydraulic Fluid Filter With Disk-type Filter Elements ............................... 2.20
xi
AMCP 706-123
Fig. No . Title
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Page
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3-1 Velocity Distribution in a Liquid Between Two Parallel Plates With the Top Plate Moving
With Respect to the Stationary Bottom Plate ..................................... 3.2
3-2 Viscosity and Shear Stress Curves for a Newtonian Fluid ............................. 3.4
3-3 Viscosity and Shear Stress Curves for a Plastic Material .............................. 3-4
34 Viscosity and Shear Stress Curves for a Pseudoplastic Material ........................ 3.5
3-5 Viscosity and Shear Stress Curves for a Dilatant Material ............................. 3.5
3-6 Viscosity and Shear Stress Curves for a Thixotropic Material .......................... 3.5
Xiii
AMCP 706-1 23
.
Fig No. Title
. page
3-7 Viscosity and Shear Stress Curves for a Rheopectic Material ......................... 3.5
3-8 Viscosity Curves for a Newtonian Fluid and a Non-Newtonian Fluid .................... 3.6
3-13 Viscosity-temperature Graphs of Four Military Specification Hydraulic Fluids ........... :3-10
3-14 Method of Calculating the ASTM Slope of a Hydraulic Fluid ......................... 3.12
3-17 Viscosity vs Pressure at Several Temperatures for a Typical Petroleum Fluid .............. 3-16
3-18 Viscosity vs Temperature at Various Pressures for MLO-60.50 Fluid .................... 3-17
3-19 Schematic Diagram of Pump Test Apparatus for Determining Shear Stability of Hydraulic
Fluids ................................................................... 3-19
3-20 Effect of Shear Upon Viscosity of a MIL-H-5606B Hydraulic Fluid in a Pump Test ........ 3-20
3-21 Effect of Sonic Irradiation on the Viscosity of a MJLH-5606B Hydraulic Fluid ...........3.20
3-22 Cleveland Open Cup Flash and Fire Point Test Apparatus ............................ 3.23
3-26 Test Apparatus for the Pipe Cleaner Evaporation Test ............................... 3.27
XiV
AMCP 706-123
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Fig No Title
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Page
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3-27 Autoignition Temperature Test Apparatus ........................................ 3-28
3-28 Spontaneous Ignition Temperature of a MILO-5606 Fluid in Air in Contact With Various
Surfaces As a Function of Test Chamber Pressure ................................... 3-29
3-32 Vapor Pressure vs Temperature of Several Types of Hydraulic Fluids .................... 3.34
3-33 Cut-away Sketch of the Evaporation Loss Apparatus Used in ASTM D972 Test Method ....3.35
3-35 Density vs Temperature of Several Types of Hydraulic Fluids at Atmospheric Pressure ..... 3.37
3-37 Density vs Pressure at Several Temperatures for MLO-60-50 Fluid (an ester of
trimethylolpropane) ........................................................ 3-39
3-38 Coefficient of Cubical Expansion vs Temperature of Several Types of Hydraulic Fluids ..... 3-40
3-39 Lipkin Bicapillary Pycnometer for Determining Density and Specific Gravity of Liquids .... 3-41
3-40 Singham Pycnometer for Determining Density and Specific Gravity of Liquids ............ 3-41
3-41 Specific Heat vs Temperature of Several Types of Hydraulic Fluids .................... 3-43
3-42 Thermal Conductivity vs Temperature of Several Types of Hydraulic Fluids .............. 3-44
AMCP 706-123
Fig.No . .
Title page
3-43 Fluid Percent Volume Compression vs Pressure of Typical Fluids .................... -3-45
3-44 Bulk
. Modulus vs Pressure-A Generalized
. ~-Relationship for a Variety of Fluids Over
~
3-45 Example Representation of Secant and Tangent Bulk Moduli ......................... 3-48
3 4 ................3.49
Apparatus for Measurement of Adiabatic Bulk Modulus by Sonic Speed
3-53 Coefficient of Friction in the Transition from Hydrodynamic to Boundary Lubrication .....3.58
.
Fig No . Title
xvii
AMCP 706-123
LIST OF TABLES
2-2 ........................
Dimensions and Characteristics of Pipe for Hydraulic Systems 2.40
3-3 Pour Point Requirements of Four Military Specification Fluids ....................... 3.21
3-4 Flash Point Requirement of Five Military Specification Fluids ........................ 3.23
3-18 Common Trade Names and Recommended Uses of Basic Types of Elastomers ...........3.86
AMCP 706-123
3-21 Rubber Swell Requirements of Military Specification Hydraulic Fluids .................. 3.92
6.3 AIA Particle Contamination Limits for Hydraulic Fluids ............................. 6.7
6-4 Particle Contamination Limits for Hydraulic Systems at Martin Aircraft Company .........6.7
6-5 Effects of Various Contaminants on Hydraulic System Components .................... 6.9
6-6 Solid Particle Contamination Limits in Hydraulic Fluid Corresponding to MILH-5606B ....6.11
AMCP 706-123
PREFACE
comments were supplied by 3. Messina of Frankford Arsenal and other members of the
Ad Hoc Working Group of which Mr. Messina was chairman.
The Handbooks are readily available to all elements of AMC including personnel and
contractors having a need and/or requirement. The Army Materiel Command policy
is to release these Engineering Design Handbooks to other DOD activities and their
contractors and other Government agencies in accordance with current Army Regula-
tion 70-31, dated 9 September 1966. Procedures for acquiring these Handbooks follow:
a. Activities within AMC and other DOD agencies should direct their request
on an official form to:
Commanding Officer
Letterkenny Army Depot
ATTN: AMXLE-ATD
Chambersburg, Pennsylvania 17201
TABLE OF CONTENTS
Paragraph Page
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PREFACE ................................................................ xx
CHAPTER 1
INTRODUCTION
i
AMCP 706-1 23
Paragraph Page
.
CHAPTER 2
POWER TRANSMISSION EQUrPMENT
Paragraph Page
.
CHAPTER 3
FLUID PROPERTIES. SIGNIFICANCE. AND TEST METHODS
Paragraph
Paragraph Page
.
CHAPTER 4
TYPES OF HYDRAULIC FLUIDS
Paragraph Page
.
5-2.3.1 Esters .................................................................... 5.2
5-2.3.2 Highly Refined Mineral Oils ..................................................... 5.3
5-2.3.3 Silicon-containingFluids ..................................................... 5.3
5-2.3.4 Ethers .................................................................... 5-3
5-3 CORROSIONINHIBITORS ................................................... 5-4
5-3.1 Definitions ................................................................ 5-4
5-3.2 Mode of Action of Rust Inhibitors .............................................. 5.4
5-3.3 Limitations in the Use of Rust Inhibitors ......................................... 5.4
5-3.4 Examples of Rust and Corrosion Inhibitors ....................................... 5.5
5-3.5 Volatile Corrosion Inhibitors .................................................. 5.5
5-4 VISCOSITY INDEX IMPROVERS ............................................. 5.6
5-4.1 ModeofAction ............................................................ 5-6
5-4.2 Limitations ................................................................ 5-6
5-4.3 Examples of Effective Polymers ................................................ 5.6
5-5 FOAM INHIBITORS, EMULSIFIERS, AND DEMULSIFIERS ........................ 5.7
5-5.1 Characteristics of Foams and the Mode of Foam Inhibition ........................... 5.7
5-5.2 Examples of Foam Inhibitors .................................................. 5.7
5-5.3 Emulsifiers and Demulsifiers .................................................. 5.8
5.6 . LUBRICITY ............................................................... 5-8
5-6.1 Hydrodynamic vs Boundary Lubrication ......................................... 5.8
5-6.2 Oiliness, Antiwear, and Extreme-pressure Additives ................................. 5.8
5-6.2.1 Oiliness Additives ........................................................... 5.8
5-6.2.2 Antiwear Additives .......................................................... 5-9
5-6.2.3 Extreme-pressure Additives ................................................... 5.9
5-6.3 Classes of Lubricity Additives ................................................. 5.9
5-6.3.1 Additives for Mineral Oils and Esters ............................................ 5.9
5-6.3.2 Additives for Silicon-containingFluids ........................................... 5.9
5-6.3.3 Additives for Aryl Ether Fluids ................................................ 5.10
5-7 POUR POINT DEPRESSANTS ................................................ 5.10
5-8 SEAL DEGRADATION RETARDANTS ......................................... 5.10
5-9 HYDROLYTIC INHIBITORS ................................................. 5.10
5-10 CAVITATION INHIBITORS .................................................. 5.11
5-11 BIOCIDES ................................................................ 5-11
REFERENCES ............................................................. 5-11
CHAPTER 6
STORAGEAND HANDLING
6- 1 CONTAINERS ............................................................. 6-1
6-1.1 General ................................................................... 6-1
6- 1.2 ContainerMaterials ......................................................... 6-1
6-1.3 Container Sizes, Storage, and Marking ........................................... 6.1
6-2 CONTAMINANTS .......................................................... 6-3
6-2.1 Sources of Contamination .................................................... 6.3
6-2.1.1 Contamination from Lint and Dust ............................................. 6.3
6-2.1.2 Moisture Contamination During Storage ......................................... 6.3
6-2.1.3 Contamination Accompanying Additives ......................................... 6.3
6t2.2 Types of Contaminants ...................................................... 6.5
6-2.2.1 Water As a Contaminant ...................................................... 6.5
viii
AMCP 706-123
CHAPTER 2
The pressure regulator (d) and the relief valve (g) pro-
vide pressure control. A fluid reservoir (b) serves both
for storage and as a system vent location. Less obvious
is the hydraulic fluid without which the system could
not perform a single useful function.
The design of a hydraulic system encompasses many
factors. Given a particular power transmission or con-
trol problem, the designer must first determine what
type of components will accomplish the desired objec-
tive. A conceptual layout of the system is then followed
by engineering analysis to determine the necessary size,
configuration, and details of the hardware. Suitable
materials must be selected for component construction,
and engineering drawings must be prepared. Underly-
ing each of these steps is the nebulous factor commonly
referred to as good engineering practice. This entails a
knowledge, usually acquired through experience, of the
features which constitute good design practice, i.e.,
those factors which cannot be readily subjected to pre-
cise mathematical and engineering analysis.
The equations with which the designer constructs a
r-1 mathematical model of a hydraulic system are, in gen-
d ' I eral, nonlinear differential equations, frequently of sec-
dl
ond or higher order. Such equations usually require
c numerical solutions and, hence, digital and analog
f computers have become valuable aids in the design of
LLI hydraulic systems. A thorough engineering analysis be-
C I gins with the specification of certain parameters which
the system must satisfy-such as force or load require-
ments, stability, speed of response, accuracy, and reso-
a lution. The mathematical model is then manipulated
until the desired specifications are met on paper. The
resulting information can be used in system specifica-
tion and fabrication.
However, a detailed computer solution of the equa-
tions which describe the system does not always result
b in a design which performs as predicted by the analysis.
Fig. 21. Rotary Motor Circuit Which Produces Constant
It is frequently possible, using the appropriate approxi-
Torque [Shown are: (a) hydraulic pump and
mations and sound engineering practice, to design a
drive motor, (b) reservoir and strainer,
system based upon hand computations which will per-
(c) manually operated control valve, (d) pres-
form as well as, or better than, one based upon a de-
sure regulator valve, (e) check valve, (f) hy-
tailed computer analysis. Usually, it is desirable to use
draulic motor, and (g) pressure relief valve]-
a preliminary hand-calculated analysis to optimize a
The circuit of Fig. 2-1 contains all six of the basic subsequent, more detailed computer analysis. Math-
components mentioned in Chapter 1. The pump (a), ematical techniques in the form of computer programs
driven by an electric motor, serves as the source of fluid are now available, which facilitate detailed analysis by
energy. The fixed-displacement hydraulic motor ( f ) relieving the designer of the necessity of developing
converts hydraulic energy into mechanical energy. Hy- routines for the solution of complex nonlinear equa-
draulic piping is provided between the system compo- tions.
nents. Directional controls are provided by the manu- Merritt (Ref. 4) distinguishes between two types of
ally actuated control valve (c) and the check valve (e). parameters involved in hydraulic system design. A
2-2
AMCP 706-123
hard parameter is defined as a physical quantity which 2-2.1.1 External Gear Pumps
can be measured with good precision and which re-
mains essentially constant. A soft parameter, on the In external gear pumps, two or more gears mesh with
other hand, is a quantity which is difficult to measure minimum clearance. The gear motion generates a suc-
or compute and, for a given system, can be determined tion at the inlet, which causes fluid to be drawn into the
only within a range of values. The most important pump housing. The liquid is drawn through the pump
design features of a system should be based upon hard and is displaced as the teeth mesh on the outlet side.
parameters, if possible. Merritt points out that an im- (I) Spur gear pumps: A spur gear rotary hydraulic
portant part of sound engineering design practice is the pump is illustrated in Fig. 2-2. The two gears rotate in
ability to distinguish between hard and soft parameters. opposite directions and transfer liquid from the inlet to
the outlet through the volume between the teeth and
the housing. The output depends on tooth width and
2-2 PUMPS depth, and is largest for a minimum number of teeth.
Involute teeth with a pressure angle of 20-30 deg are
A hydraulic pump is a device used to impart motion common in spur gear pumps. However, progressive-
to a liquid and thereby convert mechanical energy to contact and edge-contact gears are sometimes used to
hydraulic energy. It provides the force required to avoid the severe loads generated by liquid trapped be-
transmit power. Pumps are rated in terms of flow and tween the contact points of the meshed involute teeth.
pressure. The flow rating (volumetric output) is the
amount of liquid which can be delivered by the pump
per unit time at a specified speed. A pump does not
produce pressure. The pressure developed at the outlet
depends on the resistance to flow in the circuit.
Pumps are classified according to configuration or
operating characteristics. One obvious classification is
that of rotary or reciprocating pumps. Rotary pumps
utilize a rotating assembly to transfer the fluid from the
inlet to the outlet andtoimpart motion. Rotary pumps
can be further classified as gear, vane, or rotating piston
pumps. Reciprocating pumps employ a plunger or pis-
ton to impart motion to the fluid.
Pumps can also be classified as positive- or non-
positive-displacement devices. Positive-displacement
pumps move a definite amount of fluid during each
stroke or revolution. They are most frequently used in
hydraulic systems. Nonpositive-displacement, or hy-
drodynamic, pumps provide continuous flow. They are
primarily low-pressure devices with high volumetric
output.
Positive-displacement pumps can be of either fixed Fig. 2-2. Spur Gear Rotary Hydraulic Pump
or variable displacement. The output of a fixed-dis-
placement pump is constant at a given pump speed. [From: H. E. Merrit, Hydraulic Control System:*
The output of a variable-displacement pump can be Used by permission of John Wiley and Sons]
changed by adjusting the geometry of the displacement
chamber. The spur gear pump is a fixed-displacement pump.
Output at a given speed decreases slightly with pres-
sure. Typical operating characteristics are shown in
2-2.1 GEAR PUMPS Fig. 2-3. These curves are for a spur gear pump operat-
ing with a liquid of constant viscosity. This viscosity
Gear pumps are the most widely used pumps for effect illustrates one of the ways in which the liquid
hydraulic systems. They are available in a wide range influences the specification of system components.
of flow and pressure ratings. The drive and gears are
*Superscript numbers refer to References at the end of each
the only moving parts. chapter.
2-3
AMCP 706-123 LIVE GRAPH
Click here to view
of both gears. The contact point of the gear teeth forms
100 50 a seal, as does the small tip clearance at the crescent.
This pump is generally used for low output applications
at pressures below 1,OOO psi.
a0 40
U
W
rn ZZ
>= 60 30 0
a
I- W
V
'
v)
n
8 ::
40 20
20 10
-CRESCENT
0
0 60 120 180 240 300
DISCHARGE PRESSURE, psi
Fig. 2-4. Crescent Seal Internal Gear Hydraulic
Fig. 2-3. Typical Operating Characteristic Curves Pump [Shown are: crescent C, gear teeth
for a Spur Gear Rotary Hydraulic Pump T, and drive gear G I
2
[From: Pippenger and Hicks, Industrial Hydraulics . [Erom: Pippenger and Hicks, Industrial Hydraulics?
Used by permission of McGraw-Hill, Inc.] Used by permission of McGraw-Hill, Inc.]
( 2 ) Helical gear pumps: A variation of the external ( 2 ) Gerotor pumps: The gerotor pump consists of a
gear spur gear pump is the helical gear pump. The fact pair of gears which are always in sliding contact (Fig.
that several teeth are engaged simultaneously allows 2-5). The larger internal gear has one more tooth than
the helical gear pump to carry larger loads at high the external gear. Both gears rotate in the same direc-
speeds than can the spur gear pump. Operation is simi- tion. Liquid is drawn into the chamber where the teeth
lar to that of the spur gear pump, but with less noise are separating, and is ejected when the teeth again start
and usually smaller flow pulsations. Because of the to mesh. The seal is provided by the sliding contact.
helical gear configuration, end thrusts are developed by Gerotor pumps are restricted to low-pressure opera-
helical gears. These forces act in opposite directions on tion because of the loads generated by the hydraulic
the drive and driven gears. unbalance.
( 3 ) Herringbone gear pumps: Another variation of OUTER
the external gear pump incorporates herringbone gears.
Like all gear pumps, the herringbone device is a con-
stant displacement pump. It is generally available for
pressures up to about 2,000 psi but some models are
rated at over 3,000 psi.
Vane pumps consist of a rotor mounted in a cam- In the unbalanced vane pump, the rotor and cam
shaped housing. The rotor is provided with radial slots housing are eccentric (Fig. 2-7). The pump suction is
which accommodate vanes. As the internal assembly generated in the region where the vanes begin to move
rotates, the vanes are forced radially outward against outward. The liquid is carried around the rotor by the
the housing by centrifugal force sometimes assisted by vanes, which form a seal with the housing and the end
springs. Vane pumps can operate at speeds up to 2,000 plates, and it is discharged as the vanes are forced back
rpm and are available in pressure ratings to 2,500 psi. into the rotor slots by the eccentric housing.
Their simple construction results in a high degree of
re!iability and easy maintenance. They are relatively
low in cost and exhibit long operating life partially due
to the fact that vane wear is accommodated by the
-Vanes
radial motion of the vanes. They have comparatively
high volumetric and overall efficiencies, and are availa-
ble in a wide range of output ratings. Typical operating
characteristic curves of a vane pump are shown in
Fig. 2-6. LIVE GRAPH
Click here to view
THRUST CAM
WIPER SEAL
HAFT BEARING
\
INLET OR OUTLET POkT BARREL BEARING
2-2.3.2 Radial-piston Pumps Pumps of this type operate at high speeds, ranging from
about 7,000 rpm for a 35-gpm unit to nearly 20,000
In a radial-piston pump, the pistons move perpen- rpm for pumps with 2- to 8-gpm output ratings (Ref.
dicularly to the shaft centerline. Two basic types of 1). One advantage of the spherical-piston pump is a
radial-piston pumps are available. One uses cylindrical- relatively high power-to-weight ratio.
shaped pistons and the other uses spherical-shaped pis-
-1. Pintle
tons. In the pump shown in Fig. 2-1 1, the pistons move Cylinder block
in a rotating cylinder block and are forced outward by Stroking ring
centrifugal force. In Fig. 2-1 1, only one piston is
shown (in four positions); however, most pumps are I -XI
multi-piston.
Cylinder
CYLINDER BLOCK Boil
Fig. 2-13. Rotating Piston Hydraulic Pump [Shown are two rotating pistons F!, and &., and rotating abutment V.]
[From: H. E. Merrit, Hydraulic Control Sy.stem?. Used by permission of John Wiley and Sons]
2-7
AMCP 706-123
2-2.4 SCREW PUMPS materials. Bellows pumps also are very effective pumps
for liquids that are contaminated with solid particle
A screw pump is an axial-flow gear pump. Fig. 2-14 material, and for abrasive slurries. There are no small
shows a two-rotor screw pump with helical gears. Liq- clearance areas for the particles to damage or close.
uid is introduced at the two ends and discharged at the
center. The seal is formed by the contact of the two
gears at the intersection of their addenda and by the
small clearance between the gears and the pump hous-
ing. In pumps employing double helical gears, as shown I-
in Fig. 2-14, the thrust loads are balanced. This design
is frequently employed in large pumps. Screw pumps ds
1 - 1
l I
TOP VIEW
- DISCHARGE - 2-2.6 DIAPHRAGM PUMPS
Fig. 2-16. Typical Diaphragm Pump (1) Rotating or nonrorating: In a rotating actuator
the cylinder, rod, and piston can rotate. In many ap-
plications, such as on rotary machine tools, this
feature is necessary to allow unrestricted motion of
2-2.7 CONNECTION BETWEEN PUMP AND the piston rod. Such an actuator is illustrated in Fig.
DRIVE MOTOR 2-17. In order to permit stationary mounting of the
fluid connections, a rotating seal is required.
The physical connection between the hydraulic
The nonrotating linear actuator, in which the cylin-
pump and its drive motor is not technically a hydraulic
der is not free to rotate, is the most widely used fluid
component. However, it is an important part of the
motor.
hydraulic system, and in many cases, may be the weak-
est link in the power train. There are a number of
methods for coupling the drive motor output shaft to
the hydraulic pump input shaft. Some of the more com-
mon methods are keys and pins, flexible couplings,
universal joints, clutches, and splines. The most fre-
quently used connector in hydraulic systems is the
spline. Fig. 2-17. Rotating Linear Actuator
Splines offer the advantage of being able to transmit [From: E. C. Fitch, Fluid Power and Control Systems?
the maximum load with the smallest coupling diame-
Used by permission of McGraw-Hill, Inc.]
ter. In addition, they are self-centering, tend to equally
distribute the load, and are simple to manufacture with
standard gear-cutting equipment. Their major disad- (2) Piston or plunger: The piston and rod assembly
vantage is the problem of wear. Even the best designed in a piston-type linear actuator serves to divide the
splines are subject to relative motion of the parts and cylinder volume into two separate chambers. The pis-
are difficult to lubricate. ton and attached sealing devices provide the seal be-
tween the two chambers. The rotating actuator shown
in Fig. 2-17 is a piston actuator.
In a plunger-type there is no piston. The end of the
2-3 ACTUATORS reciprocating rod serves as the working face (see Fig.
2-18). The only seal provided is at the point where the
An actuator is a device for converting hydraulic en- plunger passes through the end of the cylinder. An
ergy to mechanical energy, and thus has a function external force is required to move the plunger into
opposite that of a pump. An actuator, or fluid motor, the cylinder.
can be used to produce linear, rotary, or oscillatory Both types provide a longer stroke and permit the
motion. use of the highest pressure.
2-9
AMCP 706-123
(6) Cushioned or noncushioned type: In noncush- The nature of the force provided by a linear actuator
ioned actuators, no provision is made for controlled depends on the kinematic linkage between the straight-
acceleration or deceleration of the piston assembly. line output of the cylinder and the point at which the
Therefore, such units have speed and inertia limitations force and motion are utilized. Because of the many
imposed at both ends of the stroke. Cushioned actua- alternatives in the design of the linkage, the linear ac-
tors are designed to enable the kinetic energy of the tuator can be used to produce rotary or oscillatory
moving piston to be absorbed at the ends of the stroke motion as well as linear motion. The resultant ver-
and thereby reduce peak pressures and forces. Cushion- satility of linear actuators is partially illustrated by the
ing can be accomplished by blocking the discharge applications shown in Fig. 2-25.
CUSHION
FLUID
INLET AND
OUTLET
\ \
ROD
\
SEAL
\ FLUID
INLET AND
OUTL\ET
ROD
SCRAPER
SECONDARY I I ROO I
POCKET CAPTIVE CYLINDER PACKING
AREA BARREL
TIE RODS EXTENDED REAR END ONLY TIE RODS EXTENDED FRONT END ONLY
Motion
S t r a i g h t line m o t i o n S t r o i g ht push Horizontal transferred t o
in t w o d i r e c t i o n s parallel motion a distant point
LIVE GRAPH
Click here to view I
600 24
500 20
-& 400 16
.-
I
-
-0
2)
0
300 12
U
200 8
I-
100 4
0
'
0 200 400 600 800 1000 1200 1400 1600
Speed (rpm)
Fig. 2-29. Typical Operating Characteristic Curves
for a Vane Hydraulic Motor
Fig. 2-28. Typical Operating Characteristic Curves [From: Fluid Power Issue; Machine Design. Used by
for a Gerotor Hydraulic Motor permission of Penton Publishing Co.]
[From: Fluid Power Issue; Machine Design. Used by
permission of Penton Publishing Co.]
2-3.2.3 Limited-rotation Motors
'GUIDE ROD
/ h.-FILLED CHAMBER
motor inlet forces the piston assembly against the (2) Fixed-displacementpump and variable-displace-
thrust cam or wobble plate. The angular application of ment motor: The pump operates as described in par.
this force causes the plate to rotate and this rotation is 2-3.3(1). The torque of the motor varies inversely with
transmitted by the shaft. The displacement can be var- speed. Motor flow rate is a function of both displace-
ied by changing the angle of the thrust cam. Leakage ment and relief-valve flow. The transmission produces
is low under both running and stalled conditions. constant horsepower and a torque which varies
(2) Radial-piston type: The radial-piston motor is with speed.
also essentially its pump counterpart operating in re- (3) Variable-displacementpump andfixed-displace-
verse (Fig. 2-11). Liquid enters the piston chamber ment motor: The pump pressure and speed are con-
through a central pintle. The piston is forced radially stant, but the torque and horsepower vary. The motor
outward against the thrust ring, thereby producing a pressure and torque are constant while the speed and
force tangent to the piston chamber. The resulting horsepower vary. The resulting transmission has con-
torque causes the shaft to rotate. This motor type ex- stant torque. The horsepower varies with speed.
hibits very high volumetric efficiencies and high (4) Variable-displacement pump and motor: The
torque, and is well-suited for low-speed application be- pump operates as in the preceding case. The motor
cause of the small mass of the rotating parts. torque and speed are inverse functions of the displace-
(3) Rotary-piston type: The rotary-piston motor is ment. The torque and horsepower transmitted by the
the same as the rotary-piston pump except for the flow system can be constant or variable.
direction. The pump was described in par. 2-2.3.3.
Units are available with a rating of up to 300 hp at
2,800 rpm with a maximum torque of over 20,000 in.- 2-4 INTENSIFIERS
lb. Weight and space-to-power ratios are high, and cost
per horsepower is usually high. A liquid intensifier-used only in single cylinder ap-
plications-is a device used to compress the liquid by a
pressure greater than the system pressure generated by
2-3.3 FLUID TRANSMISSIONS the primary pump. This is accomplished by using dif-
ferent piston working areas to boost the pressure. The
A fluid transmission is a device which converts me- increase in pressure obtained in the simple intensifier
chanical power into fluid power, transports this power, shown in Fig. 2-34 is directly related to the area ratio
and then converts it back into mechanical power. of the pistons. The high-pressure piston is attached to
Therefore, the circuit consists of some suitable combi- the same rod as the larger low-pressure piston. When
nation of pump and motor with the necessary piping. the control valve is in the neutral position, the liquid,
The transmission characteristics depend on the pump which is at system pressure, is directed to a reservoir.
and motor combination. The various possible combina- If the left solenoid is actuated, fluid is introduced to the
tions are outlined in the paragraphs which follow. As- rod side of the low-pressure piston and into the cham-
sumptions made are that the pump outlet and motor ber on the downstream side of the high-pressure piston.
inlet pressure are the same; a constant output pressure The piston assembly moves to the right, returning the
is maintained on variable-displacement pumps; and the fluid in the low-pressure chamber to a reservoir. The
pump speed is constant. Fixed-displacement pumps are intensifier is then ready for a working stroke. When the
assumed to have relief valves. right solenoid is energized, fluid is introduced into the
(1) Fixed-displacement pump and motor: The tor- low-pressure chamber. The piston assembly is driven to
que and horsepower of the pump are functions of the the left, compressing the fluid in the high-pressure
pressure but the speed and flow rate are usually con- chamber. Because of the reciprocating pumping action,
stant. Below the relief-valve setting, the motor torque the intensifier produces a pulsating high-pressure flow.
and horsepower vary with pressure while the speed and The high-pressure flow rate is less than the system flow
flow rate are constant. At or above the relief-valve rate by the same ratio as that of system pressure to
pressure, the motor torque is constant, but motor speed boosted pressure.
and flow rate are functions of the volume flow rate In circuits which require high-volume, low-pressure
through the relief valve. The resulting transmission ex- flows-as well as smaller high-pressure flow over short
hibits constant speed with variable torque and horse- periods-the fluid intensifier offers an economic alterna-
power below the relief valve pressure, and constant tive to the necessity of providing two primary power
torque with variable speed and horsepower at sources.The intensifier has several additional advan-
higher pressures. tages. A low power input can be used to maintain a
2-1 7
AMC? 706-1 23
CYLINDER
HIGH
,CYLINDER
LIMIT SWITCH G
%=
L LOW-PRESSURE
PISTON
'(AREA= 10x
THAT OF THE
PRESSURE C I - ~
A
HIGH-PRESSURE
B
PISTON)
5,000
psi
(AREA=O.l THAT
I I
LIMIT SWITCH H
--D
'I
OF LOW PRESSURE
DIRECTIONAL'
CONTROL
VALVE
t
Fig. 2-34. Diagram of a Hydraulic Intensifier Circuit
2
[From: Pippenger and Hicks, Industrial HydrauIics . Used by permission of McGraw-Hill, Inc.]
high pressure for a period of time. The high-pressure must be determined. The size and configuration depend
regions of the circuit can be localized, thereby reducing on many factors. The minimum required capacity can
the amount of high-pressure piping and the number of vary from one to three times the volumetric rating of
high-pressure seals required. Because of the seal be- the pump in gallons per minute. The reservoir should
tween the high- and low-pressure chambers, the inten- be sufficiently large to accommodate the liquid neces-
sifier can be operated with a liquid different from that sary to fill all system components if the liquid drains
used in the high-pressure part of the circuit. Since no back to the reservoir. It should have sufficient capacity
heat is generated while static pressure is maintained to maintain a liquid supply at the pump suction at all
and little heat is generated during rapid cycling, only times. Sufficient liquid should be in the system to pre-
small reserves of oil are required. vent the formation of vortices at the pump suction.
Reservoir volume should be provided to allow time for
solid contaminants and gases to separate from the liq-
uid. This factor also depends on both the charac-
2-5 RESERVOIRS teristics of the liquid and filtering system design. Ade-
quate space above the liquid level should be provided
to accommodate thermal expansion of the liquid. If the
2-5.1 FUNCTION reservoir serves as the primary means of dissipating
heat from the liquid, it should be large enough to ac-
Reservoirs not only provide a storage facility for the commodate the required cooling. In some applications,
liquid but can also serve to separate entrained air, the liquid in the reservoir is intermittently used as a
remove contaminants, and dissipate heat from the heat sink. It is then necessary to provide storage for
liquid. Thus, along with heat exchangers and fil- enough liquid to give the desired heat capacity. For
ters, the reservoir is an important liquid-condition- operation in cold environments excessive cooling can
ing component. also be avoided by proper reservoir capacities.
Even before the conditioning functions of the reser- There are three basic reservoir arrangements-sepa-
voir are considered in design, the necessary capacity rate, integral, and dual-purpose. Separate reservoirs are
2-1 8
AMCP 706-123
commonly used in large stationary systems where space Filters are rated in terms of the degree of filtration.
and weight are not important considerations. Integral The ratings are usually expressed in microns (1 micron
reservoirs are spaces provided within the hydraulic sys- = 3.937 x losin.). If a filter can remove 98 percent of
tem-such as piping, tubular structural members, or the particles of a certain size or larger, then this particle
machine bases. Such a design minimizes space and size, expressed in microns, is termed the nominalfiltra-
weight requirements. However, the storage of a hot tion value. The absolutefiltration value is the size of the
liquid within the system can sometimes cause thermal smallest particle which the filter can completely
distortion of precision components. If the liquid can remove from the flow. Filters are usually rated in terms
serve as both a lubricant and a hydraulic fluid, in- of both nominal and absolute values. It is common
dividual reservoirs are not required. The reservoir in practice to specify filters with an absolute filtration
which such a liquid is stored is termed a dual-purpose value equal to one-half of the smallest clearance
reservoir. For example, the case which houses the or tolerance in the components which the filter
transmission in some vehicles, and which thus contains must protect.
the transmission lubricant, also serves as the hydraulic
fluid reservoir. In such applications it is, of course,
necessary that the liquid function satisfactorily both as 2-6.1 CLASSIFICATION OF FILTERS
a lubricant and as a hydraulic fluid. Also, since the
liquid absorbs heat from two sources, it may be difficult Filters are classified according to the filter media, the
to provide adequate cooling. configuration, or the filtering method. The filter media
Many of the guidelines which assist in the design of can be either the surface-type or the depth-type. The
reservoirs are the same regardless of the reservoir type. surface-type filtering media contain numerous orifices
Baffles should be provided between the suction line and of relatively uniform size. Particles larger than the ori-
the fluid-return lines to prevent continual use of the fice size are trapped on the surface of the media. Depth-
same liquid. Baffles also reduce the liquid velocity and type media have long tortuous paths through which the
thereby facilitate the settling of solid contaminants and liquid must flow. Particles larger than the cross section
deaeration of the liquid. of these flow paths are retained except perhaps for
Lines which return liquid to the reservoir should be some particles which are larger in only one dimension.
well below the liquid level to minimize aeration. Suc- Wire mesh is an example of a surface filter medium.
tion lines should also terminate below the minimum Depth media include sintered metal powders and fi-
liquid level, but the inlet should be at least 1-1/2 pipe brous materials such as paper, felt, glass, and cellulose.
diameters above the tank floor. If the suction line Classification by filter media is closely related to clas-
strainer is not sufficiently beneath the liquid level at all sification by filtering method, which is discussed in
times, a vortex could form and permit air to enter the par. 2-6.2.
suction line. Gravity drains from seal cavities should be There are five basic filter configurations (see Fig.
separate from the liquid return lines and should enter 2-35). The T-type filter is the most widely used unit
the reservoir above the liquid level. because it is compact and easy to clean or replace.
Ample provision must be made for draining and By-pass reliefs and pressure-difference indicators are
cleaning. Liquid-level indicators should be provided to frequently incorporated to determine when a filter
indicate the maximum and minimum allowable liquid is clogged.
levels. An air breather and filter allow air to enter or
leave the reservoir as the liquid level fluctuates. Some
reservoirs are pressurized to assist pump suction. 2-6.2 FILTERING METHODS
2-19
AMCP 706-123
Y-type
In-line type
30 gpm
2 Wash type
through the multitude of small holes or orifices in the between the disks. The filter can be cleaned while in
filter. Metal or fabric screens are commonly used as the service by revolving the central shaft to which alternate
filter media. The disk-type filter shown in Fig. 2-36 is disks are keyed. The stationary elements then act as
also a mechanical filter. The size of particles which can wipers. Wire-screen mechanical filters can also be
be removed by this filter depends on the spacing cleaned if care is taken not to force contaminant parti-
cles inside or through the elements.
hydraulic fluid passes through the filter medium, con- 2-6.5 REPLACEMENT OR CLEANING
taminants are trapped by absorption. Water and water- INTERVALS
soluble contaminants can be removed by some absorb-
ent filters. The size of solid contaminant which can be Two approaches can be made to establish a mainte-
filtered depends upon the permeability and porosity of nance program for hydraulic fluid filters. If instru-
the filter element. ments are provided to monitor filter operation, replace-
ment or cleaning can be based upon the data obtained
from these measurements. If no such data are available,
2-6.3 HYDRAULIC FLUID-FILTER it is necessary to establish a systematic maintenance
COMPATIBILITY program which specifies the operating intervals for
each filter.
The hydraulic fluid filter must not be affected by the Pippenger and Hicks (Ref. 2) present the following
hydraulic fluid at any operating condition. Also, the guidelines on which to base a filter maintenance
filter must not have any effect on the hydraulic fluid- schedule:
such as removing additives in the liquid. Filter compat- (1) Providi instruments to monitor filter saturation
ibility is not often a problem with pure mechanical-type and indicate cleaning or replacement requirements
filters. In this case it is only necessary to use a filter (2) Stress the importance of the filters in the system
element made of materials (usually metal) that are operating procedure by instructing a11 operating and
compatible with the particular hydraulic fluid. This is maintenance personnel in the filter locations, functions,
not the case, however, when absorbent- or adsorbent- and service schedules
type filters are used. In addition to their mechanical (3) Establish service procedures which minimize
filtering action, these filters also have a chemical filter- downtime and fluid loss
ing action. The chemical action may result in the re- (4) Maintain records of filter performance and use
moval of additives as well as impurities and contami- these to establish satisfactory filter service times
nants. Because additives are usually included to ( 5 ) Evaluate filter performance to determine if dif-
improve properties of the liquid, their removal is not ferent filters might improve the system operation.
desirable. Special consideration must be given to the
use of these filters when the hydraulic fluid is not a
straight unmodified base stock.
2-7 ACCUMULATORS
2-6.4 FILTER PRESSURE DROP
An accumulator is a device which can store hydrau-
The influence of pressure drop on filter selection lic energy. It is useful in intermittent operation of hy-
involves a compromise between two conflicting factors. draulic machines when the accumulator can be charged
In order to filter small particles from a hydraulic fluid, at a low flow rate during the idle portion of the cycle
the size of the filter passages must be small, and this of the driven machine. Accumulators can be used for
results in high pressure drop. However, if the pressure pressure compensation, pulse damping, leakage com-
drop is too high, contaminant particles can penetrate pensation, emergency power, auxiliary pressure, and
into or through the filter element. A pressure drop several other applications. They can also be used to
greater than 12 or 15 psi is usually sufficient to force apply pressure across a physical boundary between two
the contaminants commonly found in hydraulic sys- liquids without contact or mixing of the liquids. This
tems through a typical filter. feature permits the pressurization of hazardous fluids,
The pressure drop is a function of contaminant parti- e.g., a volatile liquid, by means of a second liquid which
cle size, the fineness of the filter medium, the ability of can be safely pumped.
the particle to resist the drag forces created by the flow,
the rate at which particles accumulate in the filter, and
the mechanical strength of the filter element. The pres- 2-7.1 ACCUMULATOR LOADING
sure differential which can be tolerated across a filter
also depends upon the location of the filter in the sys- Accumulators are classified in terms of the manner
tem. Allowable pressure drop is also an important fac- in which the load is applied. This is the major factor
tor in establishing the cleaning and service schedule of which influences design. Accumulators can be weight-
a filter. loaded, spring-loaded, or pneumatic-loaded.
2-2 1
AMCP 706-123
OF FLUID -
FROM SOURCE
UNDER PRESSUR
*TO WORK LOAD
Accumulator
Shop air
Relief valve
High level
switch
6
2
[From: Pippenger and Hicks, Industrial Hydraulics .
Used by permission of McGraw-Hill, Inc.]
Low level
switch
AMCP 706-123
fluid. Diaphragms, bladders, or pistons are used as A free-floating piston can also serve as a barrier
barriers. A diaphragm-type accumulator is shown in between the gas and hydraulic fluid (Fig. 2-42). This
Fig. 2-40. The spherical vessel is separated into two type is less effective as a pulsation damper than is the
compartments by a flexible diaphragm. One compart- bladder-t ype.
ment is connected to the hydraulic system and the Fluid port-
other to the high-pressure gas system. In most designs
a spring-loaded, normally-open check valve or a screen
is provided at the liquid connection to prevent extru-
sion of the diaphragm into the liquid line when the fluid
is discharged. Accumulator charged with oir and f l u i d pressure
Piston shown in "balonced" position
To pressure
manifold
Hydraulic f l u i d dischorged
Piston"bot1omed"ogainst f l u i d port head
Eza 0
Fluid Air
Fig. 2-42 . Free-floating Piston, Pneumatic-loaded
Hydraulic Accumulator
[From: E. Lewis, Design of Hydraulic Control Systems.
Fig. 2-40 . Diaphragm-type Pneumatic-loaded Hydrau- Used by permission of McGraw-Hill, Inc.]
lic Accumulator
The separated, pneumatic-loaded accumulators are
[From: E. Lewis, Design of Hydraulic Control Systems. the most commonly used. They are small, lightweight,
Used by permission of McGraw-Hill, Inc.] and can be mounted in any position.
CHAPTER 3
will depend upon the hydraulic system, its use, and Viscosity is defined by Newton's Law-at a given
its environment. point in a liquid, the shearing stress Sis directly propor-
The various properties which are important in the tional to the rate of shear R, i.e.,
selection and use of hydraulic fluids are presented in S =r)R (3-1)
this chapter. Some properties may be important in all
liquids, while others have significance only in limited The proportionality constant q is known as the coeffi-
applications. Properties are discussed in relation to cient of viscosity or simply the viscosity. Since for the
their function in a hydraulic system. The importance of relative motion of two parallel layers of liquid the
these properties is assessed, and methods for measuring shearing stress is equal to F/A, where Fis the force and
them are given. A is the area, and since the rate of shear is equal to V/d
where Vis the velocity and d is the distance between
the layers (see Fig. 3-1), Eq. 3-1 may be written as
3-2 PHYSICAL PROPERTIES
3-2.1 VISCOSITY
or
Viscosity is one of the most important properties of
a liquid from the standpoint of its performance in hy- (3-3)
draulic systems. It is the resistance offered by a liquid
to relative motion of its molecules or the resistance a
liquid offers to flow. Temperature is the most impor- 3-2.1.1 Absolute Viscosity
tant variable affecting viscosity and must be stated in
all viscosity data. The viscosity q defined by Eq. 3-3 is the absolute or
Fig. 3-1. Velocity Distribution in a Liquid Between Two Parallel Plates With the
Top Plate Moving With Respect to the Stationary Bottom Plate
3-2
AMCP 706-123
dynamic viscosity. If the metric system of units (centi- The Saybolt Universal and Saybolt Furol viscosity
meter, gram, second) is used, the unit of absolute vis- scales, used extensively in the United States, give vis-
cosity is the dyne-second per square centimeter or the cosity in terms of seconds-Saybolt Universal Seconds
poise. Because the poise is a rather large unit, the cen- (SUS) or Saybolt Furol Seconds (SFS). A Furol vis-
tipoise (one hundredth of a poise) is customarily used. cosity is approximately one-tenth of the Universal vis-
Pure water at a temperature of 20.2"C (68.4"F) has an cosity for the same liquid at the same temperature. The
absolute viscosity of one centipoise. If the English sys- Furol scale is used chiefly for petroleum products hav-
tem of units (foot, pound, second) is used, the unit of ing viscosities greater than 1,OOO SUS, such as heavy
absolute viscosity is the pound-second per square inch fuel and road oils.
or the reyn. Since the reyn is an extremely large unit,
the newton (one millionth of a reyn) is more conven-
ient. Conversion between metric and English system 3-2.1.4 Viscosity Unit Conversions
units of absolute viscosity can be made on the basis that
one reyn (or one million newtons) is equal to 68,950 A viscosity determined in a particular instrument at
poises (or 6,895,000 centipoises). a specific temperature can be converted to the equiva-
lent viscosity in some other instrument at the same
temperature. A wide variety of equations, tables,
3-2.1.2 Kinematic Viscosity charts, and nomographs have been developed to facili-
tate such conversions. Currently, the trend is toward
The ratio of the absolute viscosity of a liquid to its expressing viscosity in the metric units of centipoises
density frequently occurs in the study of viscosity and (cp) and centistokes (cSt). Data in convenient tabular
hydraulics and the term "kinematic viscosity" with the form for the conversion of kinematic viscosity to Say-
symbol V has been assigned to it bolt Universal and Saybolt Furol viscosity are provided
in American Society for Testing Materials (ASTM)
(3-4) Method D-2161-66 (Ref. 2). Procedures for converting
the five more common viscosity scales to the metric
where p is the density. In the metric system, the unit scale in centistokes are described.
of kinematic viscosity is the square centimeter per sec- (1) Saybolt Universal seconds to centistokes:
ond or the stoke. The centistoke (one hundredth of a
stoke) is more generally used. The kinematic viscosity 195
of a liquid can be looked upon as the liquid's resistance v = 0.226 T - -, 32 4 T 4 100 sec (3-5)
T
to flow under its own gravity head.
(T = efflux time in seconds)
V = 2.46 T - - 32
loo,
T
< T < 9Osec (3- 1 1) t t
v = 2.45 T , T > 9Osec (3-12)
v = 8.0 E - *,
E
1.35 < E G 3.2 (3-13) Rate of Shear k i t e of Shear
Fig. 3-2. Viscosity and Shear Stress Curves for a
v = 7.6E- 2,
40
E > 3.2 (3-14) Newtonian Fluid
Fig. 3-5). However, when the applied force is removed, THIXO TROPIC
the material reverts to its original state, i.e., liquid.
Examples of dilatant materials are pigment-vehicle
suspensions-such as paints and printing ink-and some
starches.
PSEUDOPLAST I C
f
U
.3
rn
0
Rate of Shear Shear Stress 0
rn
3-5
AMCP 706-123
Newtonian Fluid
Non- Newtonian
STREAMLINE FLOW
V Fig. 3-9. Streamline Flow and Turbulent Flow in a Pipe
Rate of Shear
Fig. 3-8. Viscosity Curves for a Newtonian Fluid and 3-2.1.9 Measurement of Viscosity
a Non-Newtonian Fluid
Liquid viscosity is measured by an instrument called
a viscometer. A large number of viscometers have been
3-2.1.8 Turbulent Flow and Reynolds Number developed. Eight of the most common measurements
upon which viscometers are based are (Ref. 4)
If the flow velocity of a Newtonian fluid is increased (1) The time of flow of a quantity of liquid through
beyond some critical value, the flow characteristics be- a capillary or a short tube, using gravity as themoving
gin to change. The critical velocity marks the transition force.
between viscous flow, where the liquid follows New- (2) The torque required to rotate a cylinder, disk, or
ton's Law, and turbulent flow, where the liquid does paddle in a liquid at constant speed
not behave in a Newtonian fashion. Viscous flow is an (3) The torque exerted on a disk suspended in a
orderly motion of the liquid in the direction of flow. rotating cup of the liquid
Turbulent flow, however, is an erratic flow with eddy (4) The rotational speed of a cylinder or disk driven
currents (see Fig. 3-9). Reynolds has shown that the in the liquid by a constant torque
critical velocity depends upon the dimensionless ( 5 ) The time of fall through the liquid of a ball or
parameter known as the Reynolds number (Ref. 3). For cylindrical object
flow in pipes, Reynolds number R n is given by:
(6) The time of rise of an air bubble through the
liquid
(7) The rate of damping of ultrasonic waves in-
- DVP duced in the liquid
R , -- (3-15)
V (8) The pressure drop through a capillary.
The most widely used viscometers in the petroleum
where industry are the capillary and the short tube viscome-
D = pipe diameter ters. ASTM D-445-65 (Ref. 5) prescribes the standard
V = fluid velocity procedure for measuring kinematic viscosity and de-
p = fluid density scribes the capillary viscometers that are to be used.
v = kinematic viscosity Briefly, the method calls for measuring the time of flow
of a known quantity of liquid at a constant temperature
When the Reynolds number is sufficiently low, the flow through a capillary with gravity as the only moving
is viscous and the liquid behaves in a Newtonian man- force, and multiplying the time by a calibration con-
ner. The transition to turbulent flows usually occurs stant. The calibration constant is determined by using
between Reynolds number values of 2,100-4,00& a master viscometer (Bureau of Standards) and stand-
depending upon the geometry of the conduit and the ard oils. Absolute viscosity is given by the equation
liquid properties. rl = VP (3-16)
3-6
AMCP 706-123
T
and component response. Thus, a compromise in vis-
cosity requirements must be made. The viscosity of the
hydraulic fluid affects the response of system compo-
nents, and because its sensitivity to temperature usually
imposes limitations on the upper or lower operating
temperature of any hydraulic system, viscoshy must
always be considered in design calculations.
230 .o
.
I P
(dimensions i n m i l l i m e t e r s )
Fig. 3-10 Cannon-Fenske Capillary Tube Viscometer
3-2.1.1 1 Test Methods for Viscosity
T
4.92
Repeatability- 0.35 percent of mean
Reproducibility- 0.7 percent of mean
(2) Saybolt Viscosity
1
Test Methods: Federal Test Method 304.8 (Ref. 7)
ASTM D-88-56 (Ref. 8)
These methods describe the procedure for determin-
ing the Saybolt viscosity of petroleum products in the
temperature range of 70" to 210F.The emux time in
seconds of 60 ml of the sample flowing under gravity
head through a calibrated orifice is measured under
carefully controlled temperature conditions. A Univer-
sal orifice is used for Saybolt Universal viscosity and a
the nearest 0.1 sec. Values above 200 sec are reported
-
to the nearest whole second.
(3) Conversion of Kinematic Viscosity to Saybolt
Universal Viscosity or to Saybolt Furol Viscosity
Test Methods: Federal Test Method 9101.3 (Ref. 9)
ASTM D-2161-66 (Ref. 10)
These methods provide conversion tables and equa-
tions for converting viscosity in centistokes at any tem-
perature to Saybolt Universal Seconds at the same tem-
perature; and also for converting viscosity in
centistokes at 122"and 210F to Saybolt Furol Seconds
at the same temperature.
(4) Calibration of Master Viscometers and Viscosity
Oil Standards
Test Method: ASTM D-2162-64 (Ref. 11)
This method covers procedures for calibrating mas-
ter viscometers and viscosity oil standards, both of
which may be used to calibrate routine viscometers
used in the determination of kinematic viscosity (Ref.
5). Master viscometers are calibrated with water at
620-640
I1
445 -455
TABLE 3-1.
lines of constant viscosity (see Fig. 3-14). The slope Subsequently, however, solvent refining, the use of ad-
values are unitless and negative, but by convention the ditives, and synthetics have produced materials that are
minus sign is omitted. The greater the slope, the greater outside the KZ. scale in both directions.
the change in viscosity for a given change in tempera- The KZ. of a liquid with a given viscosity at 210F
ture. If the slope is determined at a temperature where is calculated by relating its viscosity at 100F to the
the graph is not a straight line, the slope of the tangent viscosity at 100F for each of the standard fractions
to the curve at the temperature in question is used. having a viscosity at 210F equal to that of the un-
The ASTM slope is easily determined and values known at 210F. The K I. is calculated by the follow-
accurate to within k0.01 slope units can be obtained ing equation:
by use of the chart and a simple ruler. However, the
slope has little physical meaning and has not been
(3-19)
adopted for general use.
3-11
AMCP 706-123
KINEMATIC VISCOSITY, cSt
3-12
AMCP 706-123
lOO'F 210'F
In spite of its shortcomings, the KZ. remains the (a) Chart A. Saybolt Universal Viscosity:-30" to
most popular system for expressing viscosity-tempera- +450"F, 33 to 100,000,000 Saybolt Universal
ture characteristics of fluids. Numerous suggestions Seconds
have been proposed to eliminate the shortcomings of (b) Chart B. Saybolt Universal Viscosity,
the system or to find a more fundamental means of Abridged:-30" to +350"F, 33 to 100,OOO Say-
expressing viscosity-temperature characteristics. Most bolt Universal Seconds
of the suggestedsystems were too complex for general (c) Chart C. Kinematic Viscosity, High Range:
use or had faults of their own, so a method (Refs. 16, -30" to +450"F, 2 to 20,000,000 centistokes
17) was developed to correct the deficiencies in the (d) Chart D. Kinematic Viscosity, Low Range:
ASTM E l ' s above 100 without shifting the values -30" to +450"F, 0.40 to 100 centistokes
between 0 and 100. Values above 100 are designated (e) Chart E. Kinematic Viscosity, Low Tempera-
Viscosity Index Extended ( V.Z.E) (Ref. 19) to dis- ture Range:-100" to +450"F, 2.0 to 20,000,000
tinguish them from values obtained by the previ- centistokes
ous method. (f) Chart F. Kinematic Viscosity, Extended
Range:-100'' to +700"F, 0.40 to 20,000,000
centistokes
3-22.? Test Methods for Viscosity-temperature ( 2 ) Culcuiution of Viscosity Index
Properties Test Methods: Federal Test Method 91 11.2 (Ref. 17)
ASTM D-2270-64 (Ref. 16)
(1) Viscosiry-temperuture Charts These methods provide tables and equations for cal-
culating the V.I. of petroleum products from their vis-
Test Methods: ASTM D-341-43 (Ref. 13) cosities at loo" and 210F. Tables are provided for liq-
FederalTest Method 9121.1 (Ref. 14) uids with viscosities at 210F between the values of 210
These methods provide specifications for standard and 75.0 cSt.
viscosity-temperature charts (e.g., Fig. 3-13) for pe- Tedious calculation of V.Z. can be eliminated by the
troleum fluids for both kinematic and Saybolt viscosi- use of data in ASTM Data Series 39a, ASTM Viscosiry
ties and for a range of temperatures. Charts available Index Tables Culculutedfrom Kinematic Viscosity,Sep-
from ASTM Headquarters are: tember 1965. This reference gives V.I. in the following
3-1 3
AMCP 706-123
ranges: from 0 to 200 U. for all liquids from 2 to 75 per square inch, the increase in viscosity can cause
cSt at 210F;up to 300 K L for liquids from 2.00 to 9.99 considerable differences in the results obtained by a
cSt at 210F; and up to 250 KZ. for liquids from 10.00 lubrication theory calculation (Ref. 4).
to 19.98 cSt at 210F. A number of empirical equations have been sug-
gested for relating viscosity to pressure. The following
one, although valid only over a moderate pressure
3-2.3 VISCOSITY OF BLENDS OF TWO range, is the one most commonly used (Ref. 20):
LIQUIDS
q p = rl e b (3-20)
The ASTM viscosity-temperature charts can be used
to predict the composition of a new blend of two liquids
to give a required viscosity, or to estimate the composi-
tion of an existing blend when the viscosities of the two where
components are known. In this procedure, the vertical r) p = absolute viscosity at pressure p,
scale of any ASTM chart is used without change. The cst
horizontal scale between 0"-1WF is relabeled 0-100 77 = absolute viscosity at
percent and used to represent the percent by volume of atmospheric pressure, cSt
the higher viscosity component. The viscosity at a given e= 2.71828 (base of natural
temperature of the lower viscosity component is logarithms)
marked on the zero percent line and the viscosity at the k= a constant for a given oil and
same temperature of the higher viscosity component on temperature, (psi)-'
the 100 percent line. The two points are connected by p= pressure, psi
a straight line, and the required volumetric composi-
tion of any blend of intermediate viscosity may be read Several general statements about the viscosi -
on the abscissa (see Fig. 3-16). Conversely, the compo- ty-pressure properties of petroleum products can be
sition of a blend can be estimated when the viscosities made, namely:
of the two components are known and plotted in this (1) A pressure increase of about 500 psi has the
manner (Ref. 4). equivalent but opposite effect on viscosity as a tempera-
ture increase of 2F.
(2) The same increase in pressure will show a
3-2.4 VISCOSITY-PRESSURE PROPERTIES greater effect on viscosity at high pressures than at
low pressures.
(3) Lower viscosity fluids are less affected by pres-
The viscosity of a liquid varies with pressure as well sure than higher viscosity fluids.
as temperature. For many years pressure effects in hy- (4) An increase in pressure will increase the El.
draulic systems were neglected since the pressures en- The study of the effects of pressure on viscosity is an
countered were moderate and the viscosity was not area of research that has received considerable interest
greatly affected. Viscosity increases with increases in in recent years. The viscosity of liquids at pressures up
pressure, and the rate of increase is greater at lower to 150,OOO psi and temperatures up to 425F has been
temperatures and pressures. The rate of increase is also reported by the ASME (Ref. 21) and, more recently, by
influenced by the structural and chemical composition Wilson (Ref. 22). Klaus et al. (Refs. 23-25) have con-
of the fluid. Graphs of viscosity vs pressure at several ducted viscosity-pressurestudies on numerous liquids,
temperatures for a typical petroleum fluid are shown in at pressures up to 10,OOO psi, which are likely to be
Fig. 3- 17. Graphs of viscosity vs temperature at several encountered in typical hydraulic systems. As more data
pressures for a typical synthetic fluid are shown in are accumulated on viscosity-pressure effects, more in-
Fig. 3-18. telligent choices of lubricants and hydraulic fluids will
Most of the work on viscosity-pressure effects has be possible. The inclusion of viscosity-pressure data in
been done in studies concerned with lubrication theory. design studies could result in the use of liquids of lower
Lubricating fluids for ball bearings and gears are often viscosity than the classical lubrication equations would
subjected to extremely high pressures at contact sur- indicate. Using a liquid of lower viscosity has the ad-
faces under which their viscosities are increased appre- vantage of permitting lower operating temperatures,
ciably. At pressures as low as a few thousand pounds less liquid friction, and smaller power losses.
3-14
AMCP 706-1 23
~ ~ ~ ~ ~ ~~ ~ ~ ~ ~~
o
/' LOWER VISCOSITY COMPONENT- VOLUME
EXAMPLE: MIXTURE O F A
COMPONENT O F 150 cSt
I.000
1
3 WITH A COMPONENT OF
40 cSt
+(I000
COMPONENT AND 82%
LOW VISCOSITY
COMPONENT IS 50 .O cSt
4.0. 4.0
3.0. 3.0
2.0 2.0
3-15
AMCP 706-123
LIVE GRAPH
Click here to view
1,000, OGO where speeds are high and clearances small. Some typi-
cal shear rates are shown in Table 3-2 (Ref. 26). Circu-
100,000 lation of a hydraulic fluid through a system subjects the
fluid to rapid shear rates and sudden pressure changes
10,000
as it passes through orifices and close tolerance areas
1, 000 (Ref. 27). The resultant loss in viscosity may be either
a permanent loss, or a temporary loss, or a combination
100 of the two.
10 3-2.5.1 Temporary Viscosity Loss Due to
1 Shear
Temporary viscosity loss is due to orientation or
0.1 lining-up of the long chain polymer molecules in the
0 50 100 1
direction of flow. The polymer molecules thicken a
PRESSURE, PSIG x liquid more when they are oriented in a random man-
ner, than when they are oriented in the direction of
Fig. 3-17. Viscosity vs Pressure at Several Temperatures
flow. The orientation of the molecules can actually be
for a Typical Petroleum Fluid seen when the flow in transparent tubes is observed
under polarized light (Ref. 28). When the shear-
[From: ASME Pressure- Viscosity Report, Vol. 221 Used ing stress is removed, the liquids regain their origi-
by permission of ASME] nal viscosity.
Temporary loss of viscosity has two important ef-
fects on the performance of hydraulic fluids-an in-
3-2.5 VISCOSITY-SHEAR CHARACTERISTICS crease in leakage and a reduction of fluid friction. Leak-
age around close fitting parts increases as the viscosity
Some aircraft and many industrial hydraulic fluids decreases and can result in reduced system efficiency if
currently in use contain polymeric thickeners called the rate becomes too great. However, the reduction in
Viscosity Index improvers, or K I. improvers, to fluid friction that accompanies reduced viscosity in-
reduce viscosity change due to temperature. When liq- creases system efficiency and performance. Several
uids containing these K I . improvers are subjected to methods for measuring the temporary viscosity de-
high rates of shear, they often suffer a loss in viscosity crease have been developed. One method uses a bank
and KI. because of degradation of the polymers. The of capillary tubes; another uses a rotating tapered plug
unit of shear rate is the reciprocal second (sec-). A viscometer. The concentric cylinder is another com-
shear rate of one reciprocal second occurs when paral- mon apparatus. Any one of these methods is sufficient
lel planes 1 cm apart move in opposite directions at a for determining the relationship between viscosity and
relative speed of 1 cm/sec. High shear rates will occur shear rate (Ref. 28).
TABLE 3-2.
ESTIMATED SHEAR RATES OF LUBRICANTS
I I ~adialclemce I Relative Shear Rate ,
Application Velocity
of Parts sec -1
Parts, in.
Piston-cylinderclearance in automotive engine 0.001 200400 200,000 to
in./sec 400,000
Plain journal bearing (2-in. diameter) 0.001 to 1800 rpm 188,000 to
0.0001 1,820,000
Ball-typehydraulic pump 0.0003 3500 rpm 3,000,000
Bosch piston-type Diesel fuel pump 0.00004 36 in./sec 900,000
[From: Klaus and Fenske, Some Viscosity shear Characteristics of Lubricants, Lubrication Engineering26.
Used by permission of ASLE.]
3-16
AMCP 706-123
KINEMATIC VISCOSITY, cSt
3-17
AMCP 706-1 23
3-2.5.2 Permanent Viscosity Loss Due to molecules in extremely short periods of time as com-
Shear pared to the pump tests. The sonic energy is supplied
from magnetostrictive oscillators. One such device gen-
Permanent viscosity loss is the result of chemical erates 10 kilocycles per second at 200 watts (Ref. 27).
breakdown or mechanical rupturing of the large The sonic method has the advantages of using only a
polymer molecules into smaller molecules. Rupture of small sample (50 ml or less) of the liquid and requiring
the polymer molecules may occur in both laminar and one hour or less to perform. Fig. 3-21 (Ref. 31) shows
turbulent flow; however, polymer degradation is gener- the effect of sonic irradiation on the viscosity of a typi-
ally greater under turbulent conditions. Cavitation, cal MIL-H-5606B fluid.
where large shearing forces are developed by the rapid The correlation between sonic results and pump test
formation and collapse of cavities in the liquid, can results has been poor in many cases. Recent investiga-
cause extensive scission of the polymer chain. Polymer tions have shown that the poor correlation might be
degradation by chemical reactions (oxidation, hydrol- attributed to at least two factors (Ref. 32): (1) the sonic
ysis, radiation; etc.) does occur, but mechanical scission procedure is performed at atmospheric pressure
of the polymer chain resulting from the large shearing whereas the pump test uses a reservoir under pressure,
forces on the molecule is the principal cause of viscosity and (2) both methods vary in their effect on different
loss in hydraulic fluids. Viscosity losses due to reduc- polymers. The problem of dissolving gases in the liquid
tion in the chain length (molecular weight) of the from the pressurized reservoir can be reduced by using
polymer thickener are permanent and the liquids do an interface such as a diaphragm between the liquid
not regain their viscosity when the shearing forces and the pressurizing gas. When the effect of dissolved
are removed. gases and the selective nature of the sonic irradiations
are considered, there is closer correlation to data from
pump tests. Considerable effort has been expended in
3-2.5.3 Test Methods for Viscosity-shear
developing a set of conditions to be used in the sonic
Characteristics
method and much of the work has been summarized in
ASTM Special Technical Publication No.182 (Ref. 29).
There are several methods of measuring permanent
shear viscosity loss. Most of them are summarized in (3) Diesel Injector Method: The diesel injector
ASTM Special Technical Publication No. 182 (Ref. method is similar to the pump-orifice method in that
29). The three most commonly used methods are the the liquid is pressurized and forced through a small
pump-orifice test, the sonic method, and the diesel in- orifice. In the injector method, the diesel injector serves
jector method. as both the pressurizing pump and the orifice. Excellent
(1) Pump-orifice Test: The liquid is pressurized agreement between pump tests and results obtained by
with a pump and the pressure is released by passing the multiple passes through the diesel injector have been
liquid through a small orifice to a low pressure area. obtained (Ref. 4).
After a given number of cycles the amount of perma-
nent shear viscosity loss is expressed as the percent
change in the viscosity at a given temperature. This test 3-2.6 LOW-TEMPERATURE PROPERTIES
simulates actual service conditions and employs hy-
draulic system components. As hydraulic fluids are cooled, they become more
Federal Test Method 3471.2 (Ref. 30) describes a viscous and flow becomes slower. If cooling is carried
procedure and apparatus (see Fig. 3-19) used to deter- to sufficiently low temperatures, the fluids approach
mine shear stability of hydraulic fluids with a pump plastic solids. Many liquids, if cooled under prescribed
test. The method consists of pumping one pint of liquid conditions, will begin to precipitate wax or separate
through a simulated hydraulic system and reporting components at a specific temperature. This tempera-
changes in visual appearance, viscosity, and neutraliza- ture is called the cloud point. If cooling under pre-
tion number. Graphs of viscosity loss of MIL-H-5606B scribed conditions is continued, a temperature will be
fluid during a pump loop test similar to that described reached at which the oil will not pour or flow. This
above are shown in Fig. 3-20 (Ref. 31). temperature is defined as the solid point. By definition,
the pour point is 5F above the solid point. The pour
(2) Sonic Method: The sonic method consists of point approximates the lowest temperature at which a
subjecting the liquid to high-frequency vibrations that liquid will flow in a container of a given size. To be
produce permanent shear breakdown of the polymer useful, a hydraulic fluid must have a pour point below
3-18
AMCP 706-123
r - - --
5
- - -.- -- 1
0
1 I-
s
I -J
4
I-
I z
W
x
z
0
l
z
I H
>
z
w
,I I---I---- t \--J
3-19
AMCP 706-1 23
LIVE GRAPH
Click here to view
components removed. The latter are referred to as deep
dewaxed fluids.
J 30
*?a
v)
1 ent upon such factors as the rate of cooling and degree
of agitation (Ref. 4). Table 3-3 lists the minimum pour
point required by four common Military Specifications
for hydraulic fluids.
TABLE 3-3.
POUR POINT REQUIREMENTS OF FOUR MILITARY SPECIFICATION FLUIDS
These methods describe the procedures for determin- A sample of the oil is placed in a glass jar in a bath
ing the cloud point for liquids which are transparent in and subjected to a schedule of temperature variations
layers 1-1/2 in. in thickness and for determining pour for a period of up to 6 days. The lowest temperature at
point for any petroleum fluid. which no surface movement will occur when the sam-
(a) Cloud point: (ASTM D-2500-66, Federal Test ple is turned horizontally for 3 sec (the solid point) is
Method 201.8) A sample of the fluid is placed then determined. The stable pour point is recorded as
in a test jar, heated at least 25F above the the temperature 5F above the solid point. This method
approximate cloud point, and then chilled in differs from the method of par. 3-2.6.4(1) in that the
successively cooler baths. At intervals of 2F sample first undergoes a period of heating and cooling
the sample is inspected for clouding. When a over a period of several days.
distinct cloudiness or haze appears at the bot- Precision:
tom of the test jar, the temperature reading is (a) Repeatability. Results may vary in one labora-
recorded as the cloud point. tory by 5F for oils with pour stability charac-
teristics. For blends with solid points below
Precision: Duplicate results from one laboratory 0F results may vary 10F.
may differ by 4F and the results of two different labs (b) Reproducibility. Results may vary in different
may differ by 8F for gas oils. For all other oils, re- laboratories by 10F. The averages of three or
sults of duplicate tests should not differ by more more results per laboratory in different
than 10F. laboratories should not differ more than 5F.
(b) Pour point: (ASTM D-97-66, Federal Test (3) Diluted Pour Point
Method 201.8) A sample of the fluid is placed Test Method: Federal Test Method 204 (Ref. 37)
in a test jar of 1-1/4 in. diameter and heated to This method is used for indicating the flow charac-
15F above the expected pour point, but not teristics of engine oils that have been diluted with avia-
hotter than 115F. The sample is then chilled tion gasoline.
in successively cooler baths. At intervals of A sample of the oil is diluted to a mixture of 70
5"F, the jar is tilted and the fluid surface is percent oil and 30 percent diluent. The diluent is a
inspected for movement. When the fluid re- mixture of 80 percent naphtha and 20 percent xylene.
aches a temperature where the jar can be tilted The pour point is determined as outlined in ASTM
horizontally for 5 sec with no movement, the D-97-66 (Ref. 34) or Federal Test Method 201.8 (Ref.
temperature is recorded as the solid point. The 33) for cloud and pour point (par. 3-2.6.4(1)).
pour point is taken as the temperature 5F Precision: The same limits as set forth in ASTM or
above the solid point temperature. Federal Test Method for cloud and pour point (par.
3-2.6.4(1)) apply to this method.
Precision: Results of the pour point from one labora- (4) Cloud Intensity at Low Temperature
tory may vary by 5F and from different laboratories Test Method: Federal Test Method 202 (Ref. 38)
by 10F. This method describes the procedure for determining
(2) Pour Stability Characteristics the ability of hydraulic fluids or highly refined
Test Method: Federal Test Method 203 (Ref. 36) light lubricating oils to remain free of turbidity at
This method is used for determining the stable pour low temperatures.
point of blends of winter grade motor oil and of certain A sample of the fluid and a standard are stored at
types of hydraulic fluids. -65F (or lower as specified by the purchaser) for a
3-21
AMCP 706-1 23
specified period. It is then agitated and its turbidity is an instantaneous flash. The fire point, however, is the
compared to the standard. The standard is a mixture of minimum temperature at which sufficient vapor is
barium chloride, sulfuric acid, and sodium hydroxide. continuously generated to sustain combustion. Since
The turbidity of the sample is reported as less than, differences between flash and fire points are not great,
more than, or equal to the standard. and since fire point data cannot be obtained in a closed
tester, the fire point is often omitted in commercial data
on hydraulic fluids. Table 3-4 lists the flash point
3-2.6.5 Significance of Cloud and Pour Points requirements of five common Military Specifications for
hydraulic fluids.
THERMOMETER
TEST FLAME
APP LICA T 0 R
TEST CUP
HEATER (FLAME-TYPE
OR ELECTRIC
RESISTANCE-TYPE)
Fig. 3-22. Cleveland Open Cup Flash and Fire Point Test Apparatus
Precision: Results should not be considered suspect mechanism on the cover that opens a shutter, lowers
unless they differ by more than the following amounts: the test flame through the opening into the vapor space
(a) Repeatability. 2F of the cup in 0.5 sec, leaves the flame in place for 1 sec,
(b) Reproducibility. Below 55"F-GF and quickly retracts the flame and closes the shutter.
55F or above-4"F The flash point is recorded as the temperature of the
(3) Pensky-Martens Closed Cup Tester Method sample at the time the test flame application causes a
Test Methods: Federal Test Method 1102 (Ref. 43) distinct flash in the interior of the cup.
ASTM D-93-66 (Ref. 44) Precision: Results should not be considered suspect
These methods describe procedures for the determi- unless they differ by more than the following amounts:
nation of the flash point of fuel oils, lubricating oils,
suspensions of solids, liquids that tend to form a surface Materia Flash Point Repeatability Reproducibility
film under test conditions, and other liquids, with the Range
Pensky-Martens Closed Cup Tester. Suspen.
The sample is placed in the cup of the tester; the lid sion of 95" to 110F 4F 6F
closed; and the sample heated at a slow, constant rate Solids
with continual stirring. A small flame is directed into
All Below 220F 4F 6F
the cup at 5F intervals with simultaneous interruption
of stirring. The test flame is applied by operating the Others Above 220F 10F 15F
AMCP 706-123
3-2.7.1.2 Significance of Flash and Fire Points the general types of tests and procedures and the efforts
towards standardization is given in Ref. 46.
Petroleum liquids do not burn as such, but in gen- ( 1) Spray Ignition Tests
eral, must first be vaporized. The flash and fire points There are two versions of this test-the high-pressure
are measures of the minimum temperature at which spray ignition test and the low-pressure spray igni-
sufficient vapor will be given off from the liquid so that tion test.
a combustible mixture of air and vapor is obtained. In High-pressure Spray Test (MIL-F-7100( Ref.
this manner, the relative fire and explosion hazard can 45)): The liquid is pressurized to 1,000 psi with
be estimated from the flash and fire points. nitrogen and forced through an orifice 0.0145
Flash and fire points are also useful for evaluation of in. in diameter. Attempts are made to obtain
used liquids. If a liquid undergoes a rise in flash or fire ignition by application of an oxy-acetylene
point while in service, loss of the lighter fractions by torch flame at various standard distances from
evaporation is indicated. A lower flash or fire point is the nozzle. At each position, a report is made
an indication that the liquid has become contaminated as to whether or not the fluid will ignite, will
with a more volatile product (such as a fuel) or that flash with diffculty, or flashes readily. If flash-
some of the heavier fractions have broken down. The ing occurs, the distance from the orifice at
flash and fire points are also aids in establishing the which the ignition or flashing is carried down-
identity of unknown petroleum products. stream from the test flame area, and whether
the flashing is self-extinguishingor results in a
3-2.7.2 Flammability Tests Under Simulated sustained fire, are also reported. A pictorial
Service Conditions sketch of the high-pressure spray ignition test
apparatus is shown in Fig. 3-23.
There are many complex factors involved in assess- Low-pressure Spray Test (Ref. 4): A fire is
ing the flammability of hydraulic fluids, and no one started in a metal pan filled with oil-soaked
single test can be used to evaluate all of the types of rags and is allowed to burn. The liquid to be
liquids under all of the expected conditions of use. The tested is sprayed towards the fire from the
flash and fire points are laboratory tests that bear little reservoir of an ordinary paint spray machine
resemblance to actual operating conditions. As a result, several feet from the fire. The increased inten-
several different methods for testing the flammability sity of the fire is then used as a measure of the
of liquids were developed. Most of these tests were flammability of the liquid. A pictorial sketch
designed to simulate conditions in aircraft resulting of the low-pressure spray ignition test ap-
from a broken hydraulic line spraying liquid onto vari- paratus is shown in Fig. 3-24.
ous sources of ignition. Although the tests were deve- An alternative low-pressure spray ignition test has
loped primarily for the aircraft industry, they are useful been developed by Rowand and Sargent (Ref. 46). This
in any industry where hydraulic liquids are exposed to method uses an airless paint spray gun. The gun gener-
ignition sources. Three of the more common of these ates a flat, well-defined atomized spray by pumping the
tests-the spray ignition, the hot manifold or hot surface liquid onto a high-speed rotating disk which propels
ignition, and the incendiary gun fire test-are described the liquid in the form of small droplets through a slot
in MIL-F-7100, Fluid, Hydraulic, Nonflammable, Air- in the side of the gun. A glass blowers torch 4 in. from
craft(Ref. 4 9 , an early specification for a fire-resistant the nozzle is the ignition source. The amount of flame
hydraulic fluid. It was issued December 1950 and can- produced in the spray is used as a measure of the flam-
celled February 1958. No products were ever produced mability of the liquid. This method has the advantages
that conformed to the specification. The fire-resistance of requiring only electricity, a source of ignition, and
tests in the specification (described briefly here) are still can be performed in a laboratory hood.
used by many companies involved in hydraulic fluid
(2) Hot Manifod Ignition Test (MIL-F-7100(Ref.
work, although they vary from company to company.
Other tests are described in the literature, in various 45))
Military Specifications, and in ASTM special publica- The liquid is allowed to drop at a specified rate on
tions. Many of these tests are similar in nature but a simulated aircraft manifold heated to approximately
differ in their apparatus and procedures. A major prob- 1300F. The ignition of the liquid and the carrying of
lem confronting industry today is the lack of test stand- the flame to the pan below the manifold are used as
ardization and interpretation of test results to ade- measures of the flammability of the liquid. Variations
quately measure fire resistance of fluids. A review of of the test involve raising or lowering the manifold
3-24
AMCP 706-123
r F L U I D RESERVOIR
'LENE
PRESSURE SOURCE
N O F BURNING RAGS
FLUID SPRAY
temperature until ignition occurs or until the limits of and/or explosion, depending on the rate of pressure
the apparatus have been exceeded. This variation pro- release, volume of air, and quantity of organic material.
vides an indication of the spontaneous ignition temper- The phenomenon of compression ignition can be im-
ature of liquids contacting heated steel surfaces in the portant in generating fires in hydraulic systems. Ac-
presence of large amounts of air. A pictorial sketch of cumulators, pressure gages, and other closed-end
the hot manifold spray ignition test apparatus is shown equipment are especially susceptible to this phenome-
in Fig. 3-25. non. Two basic tests have been developed to determine
( 3 ) Incendiary Gun Fire Tests (MIL-F-7100 (Ref. the compression ignition characteristics of hydraulic
45)) fluids-the diesel engine test and the shock tube or pip-
The liquid is placed in a 3 ft long, 5 / 8 in. OD alumi- ing system test.
num alloy tube and pressurized to 1,OOO psi with nitro- (a) Diesel Engine Compression Ignition: This test
gen. A cal.30 incendiary bullet is fired from a range of is described in MIL-H-19475 (Ref. 47), a Mili-
50 yd into the tube. Observations for burning or explo- tary Specification for hydraulic fluids for Na-
sion of the liquid are made and are reported as a meas- val aircraft catapult launching systems. The
ure of the flammability of the liquid. test is a modification of the ASTM CFR Ce-
(4) Compression Ignition tane rating engine test described in ASTM
It has been found that high-pressure air suddenly Manual of Engine Test Methods for Rating
expanding into a confined space containing organic Fuels. A sample of the liquid is injected into
matter such as a hydraulic fluid can cause ignition a variable compression diesel engine, and the
HEAT TUBE
(INSIDE TUBE) \L/ /
LDRIP PAN
engineisthenturnedover at variouscompression
ratios. The lowest compression ratio for com-
bustion of the liquid is reported as a measure
of the fluids flammability. The higher the
compression ratio, the more resistant the liq-
uid is to compression ignition.
(b) Shock Tube or Piping System Test: This test is
described in MIL-H-22072 (Ref. 48) for a tire-
resistant hydraulic fluid. A small amount of
steel wool soaked with the liquid is placed at
the closed end of a pipe. By use of high-pres-
sure air and a fast opening valve, a shock wave
is introduced and directed down the pipe.
Combustion of the liquid on the steel wool can DIMENSIONS IN INCHES
be determined by a rapid rise in temperature of
the steel wool or by examination at the end of
Fig. 3-26. Test Apparatus for the Pipe Cleaner Evap-
the test. Several repeat tests are conducted, oration Test
and the results are reported as the ratio of the
number of times that fire occurred to the num-
ber of tests tried at a given temperature. The
ASTM D-2155-66 (Ref. 50). A small sample of the
fewer times the liquid burns, the more resistant
liquid to be tested is injected, with a hypodermic sy-
it is to compression ignition. Reproducible re-
ringe, into a heated glass flask containing air. The con-
sults have been difficult to obtain in this test.
tents of the flask are observed in a darkened room for
5 min following injection of the sample or until ignition
3-2.7.3 Effects of Evaporation on occurs. Ignition is evidenced by the sudden appearance
Flammability (Pipe Cleaner Test) of a flame inside the flask. The lowest temperature at
which autoignition occurs is taken as the autoignition
Test Method: Federal Test Method 352 (Ref. 49) temperature of the product in air at 1 atmosphere pres-
sure. The time lag between injection and ignition is also
-
This method is used for determining the effect of
reported. A cross-sectional sketch of the AIT ap-
evaporation on the flammability of a liquid petroleum
product. A pipe cleaner, soaked with the fluid, is passed paratus is shown in Fig 3-27.
repeatedly through a flame at a rate of 25 cycles per A new test procedure is expected to be included in
minute and the number of passes required for ignition the revised edition of Federal Test Method Standard
is noted. The fluid is then stored in an oven for the time 791a. The new procedure will be designated Method
and at the temperature required by the fluid specifica- 5050 and entitled Autogenous Ignition at Reduced or
tion, and its flammability is rechecked. Four repeats of Elevated Pressure. The temperature determined with
the test are made before and after heating in the oven. this test procedure is sometimes referred to as the reac-
The results are reported as the average number of cy- tion threshold temperature.
cles necessary for a self-sustaining flame to be achieved The autoignition temperature is a laboratory meas-
on the pipe cleaner both before and after partial evapo- urement and is very sensitive to the procedure used in
ration in the oven. A sketch of the test apparatus is its determination. It has been shown that in practice
shown in Fig. 3-26. autoignition depends on many factors, such as the na-
ture of the surface contacting the liquids, the composi-
tion of the combustible air mixture, and the pressure at
3-2.7.4 Autoignition Temperature the area of contact. Researchers at the U. S. Bureau of
Mines (Ref. 51) have found that the AIT of a MIL-O-
The autoignition temperature (A1T)-often called the 5606 liquid increases appreciably with a decrease in
spontaneous ignition temperature (SIT)-is that tem- environmentai pressure below one atmosphere but
perature at which a flame can be obtained without an changes little with increasing environmental pressures
external source of ignition. It should not be confused above one atmosphere (Fig. 3-28). Not all liquids will
with flash or fire points which rely upon ignition have the marked change in slope of the AIT/pressure
source. Autoignition temperature is determined by curve near atmospheric pressure shown on Fig. 3-28.
3-27
AMCP 706-1 23
ERLENMEYER FLASK -\
200cc
HEATERS
8 INSULATION
THERMOCOUPLE Sd
Fig. 3-27. Autoignition Temperature Test Apparatus
Some liquids will have a gradual decrease in minimum and emulsion-type. A complete discussion of the vari-
spontaneous ignition temperature with pressure in- ous types is beyond the scope of this text and the discus-
crease and may or may not exhibit a slope change near sion here will be limited.
one atmosphere. For example, Fig. 3-29shows that the (1) Synthetics: A wide variety of synthetic liquids
AIT of a chlorinated phenyl methyl silicone liquid is have been investigated as candidate hydraulic fluids,
essentially a linear function of pressure. Figs. 3-28 and and certain types have been adopted and specifications
3-29 also show that the nature and type of surface in written (see Chapter 4). Some of the typical classes of
contact with these liquids have little or no effect on the fluids under investigation are phosphate esters, haloge-
change in AIT with pressure. It has also been found nated hydrocarbons, silicones, and silicates. A detailed
(Ref. 52) that the AIT generally decreases with increas- discussion of synthetic fluids can be found in Refs. 53,
ing environmental oxygen content (see Fig. 3-30). 54, and 55.
3-2.7.5 Fire-resistant Liquids (2) Water-glycol: Water-glycol base fire-resistant
The development of liquids that are inflammable or liquids are solutions of from 35 to 50 percent water in
highly fire-resistant is the area of hydraulic fluid re- ethylene or propylene glycol, which are thickened, if
search that is receiving the greatest attention. As late necessary, to a higher viscosity by adding a water-solu-
as 1950 fire-resistant hydraulic fluids were uncommon. ble polyglycol. The fire resistance of these liquids is due
For reasons of safety, insurance companies and Gov- entirely to the presence of water. They were originally
ernment and industrial safety agencies have en- developed for use in military equipment but have been
couraged the use of fire-resistant fluids in Government, used extensively in industrial equipment.
industrial, and agricultural equipment. Fire-resistant
liquids should not be confused with high-temperature (3) Emulsions: Emulsion-type hydraulic fluids are
liquids. A fire-resistant liquid will not burn easily. A multiphase systems containing two liquids, such as oil
high-temperature liquid will not significantly change and water, which are not usually mutually soluble.
its properties at high temperatures. Water is a fire- Water-in-oil emulsions have found wide acceptance as
resistant liquid but it is not a high-temperature liquid. industrial hydraulic fluids. The emulsions contain up to
40 percent water which acts as a snuffer to render the
One of the fundamental properties of petroleum liq- liquid fire-resistant.
uids is their flammability. Although the flammability
characteristics of petroleum liquids can be modified by
the use of special refining procedures (Ref. 50) and/or 3-2.8 VOLATILITY
the use of additives, fluids of this type have shown
considerable improvement in fire resistance over MIL- All liquids tend to vaporize when they are heated.
H-5606B type hydraulic fluids (Ref. 55). Other catego- The volatility of a liquid describes the degree and rate
ries of fire-resistant liquids are synthetic, water base, at which it will vaporize under given conditions of
3-28
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MLO 53-446
MLO 54-581
MLO 54-856
MLO 54-645
MLO 8200
MLO 54-540
MIL-H-5606B
-4
0
LIVE GRAPH P
d
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w
AMCP 706-123
temperature and pressure. It is desirable that a hydrau- An apparatus has been developed for determining
lic fluid have low volatility. Vaporization of a liquid in the vapor pressure of low-volatility solids and liquids.
service can result in pump damage through cavitation The apparatus can determine absolute vapor pressures
and a reduction in efficiency.There are three character- at temperatures up to l W F , in a very short period of
istics generally used to indicate the volatility character- time, and with relatively simple equipment. The
istics of a liquid-vapor pressure, boiling point, and method is based on the kinetic theory of gases, which
evaporation loss. All three are different aspects of the states that the weight loss of a material per unit time
volatility of a liquid. is proportional to the vapor pressure of the material
(Ref. 4).
A tentative standard test method (Ref. 59) has been
3-2.8.1 Vapor Pressure adopted by ASTM for determining the vapor pressure
of petroleum products that are nonviscous. The
The pressure exerted by a vapor which is in equilib- method involves injecting a sample of the liquid into a
rium with the liquid is known as vapor pressure. For glass bulb that has been evacuated. The rise in pressure
a given liquid, this pressure is a function only of tem- in the bulb, resulting from the sample introduction, is
perature. The more volatile the liquid, the higher the the sum of the vapor pressure of the sample and the
vapor pressure at a specified temperature and the faster partial pressure of dissolved air, practically all of which
the vaporization. comes out of solution.
The vapor pressure for a pure liquid is a physical The vapor pressure of hydraulic fluids and other
property of the liquid for a given temperature. How- low-volatility liquids is usually expressed in millimeters
ever, most hydraulic fluids are mixtures of several com- of mercury. The vapor pressure of more volatile pro-
ponents. The vapor pressure of the mixture is a com- ducts such as gasoline and solvents is often expressed
posite value that reflects the combined effects of the as the Reid vapor pressure. The Reid vapor pressure is
individual components. Theoretically, the vapor pres- approximately the vapor pressure in pounds per square
sure of the mixture can be calculated from knowledge inch absolute. The method of measuring the Reid vapor
of the vapor pressures of the individual components pressure of a liquid is described by ASTM D-323-58
and their mole fractions. (Ref. 60) and Federal Test Method 1201.6 (Ref. 61). It
Numerous methods have been developed for deter- is determined by placing a sample of the fuel (chilled
mining the vapor pressure of pure fluids. Several of the to 32 to 40F) in a sealed bomb with air at ambient
more common test methods are the isoteniscope, gas pressure and 100F and measuring the change of pres-
saturation methods, and effusion methods. The use of sure in the bomb. The Reid vapor pressure is a standard
these methods to determine the vapor pressure of mix- measure of volatility in the fuels and solvents industry.
tures, such as hydraulic fluids, can introduce errors,
and it is difficult to obtain accurate vapor pressure
data. Of the above methods, the isoteniscope is proba-
3-2.8.2 Boiling Point
bly the most commonly used. Descriptions of the
isoteniscope technique and apparatus can be found in
Refs. 56 and 57. However, a standardized test proce- The boiling point becomes important only for rela-
dure has not been adopted, and the apparatus and test tively pure compounds and is not generally used to
procedure vary slightly in different laboratories. When describe liquids which are mixtures. It is determined by
the vapor pressure is presented, it is frequently the extrapolation of vapor pressure data or by simply heat-
vapor pressure of the base liquid. A graph of vapor ing a liquid until it refluxes or distills. For liquids that
pressure vs temperature for some of the more common are mixtures, a range of boiling points is obtained
types of hydraulic fluids is shown in Fig. 3-31 (Ref. 58). rather than a single boiling point. The boiling point
The vapor pressures of specific hydraulic fluids may temperature range of petroleum products is normally
differ from those of the examples shown in Fig. 3-31. determined by ASTM D-86-66, Distillation of Pe-
In an homologous series of liquids, the vapor pressures troleum Products. A 100-ml sample of the product is
of the individual liquids vary inversely with their distilled in a prescribed manner, depending upon its
molecular weights. Fig. 3-32 is a graph of vapor pres- nature. Temperature readings taken are the initial boil-
sure vs temperature for several types of liquids and ing temperature of the sample, the maximum boiling
exemplifiesthe differences in the vapor pressures of two temperature, and other temperatures as prescribed per-
petroleum base hydraulic fluids (MIL-H-5606B and centages of the distilled product are recovered in a
MIL-H-27601A). condensing unit.
3-32
AMCP 706-123
1000
100
E
E
0.01
0.001
40 ti0 120 160 200 2% 360
TEMPERATURE,
Fig. 3-31. Vapor Pressure vs Temperature of Typical Fluids (Approximate)
[From: F. D. Yeaple, Hydraulic and Pneumatic Power and Conrrolm.Used by permission of McGraw-Hill, Inc.]
Boiling of a hydraulic fluid in a system can result in hydraulic fluids, lubricants, and greases. The actual
failure or component damage. Formation of vapor in evaporation rate is not an overly important factor in
control lines, actuators, servomotors, and other compo- closed-loop hydraulic systems which are not exposed to
nents will adversely affect the operation of those com- the atmosphere, but can be important in systems with
ponents. Boiling on the suction side of the pump will reservoirs vented to the atmosphere. Several tests for
reduce the pump delivery and cause cavitation in determining evaporation loss have been developed and
the pump. adopted as ASTM or Federal Test Methods. Most of
these tests are essentially the same in that they consist
3-2.8.3 Evaporation of heating a sample of the liquid in the presence of air
Evaporation loss is widely used in the United States and observing the results. They differ in their proce-
to describe the volatility of liquid products such as dure, apparatus, and method of reporting results.
3-33
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AMCP 706-12?
~-
i 000
LIVE GRAPH
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100
2 10
E
E
1
d
0
a
s
0.1
0.01
200 300 400 5 00
TEMPERATURE, OF
(1) Evaporation (Tackiness Test): oven is heated to the temperature for the period of time
Test Method: Federal Test Method 353 (Ref. 62) called for in the fluid specification. The c d t i o n of the
This test method is intended for hydraulic fluids fluid on the slide is reported. A fluid k considered to
which contain viscosity improvers (such as acryloid have passed the test if it is still oily and not hardlor
polymers). It serves as a means of determining the tacky.
tackiness of the viscosity improver after the base liquid
(2) Evaporation Loss:
has been evaporated.
A glass slide is dipped in a sample of the fluid at Test Methods: Federal Test h4ethod 351.2 (Ref. 63)
room temperature and then suspended in an oven. The ASTM D-972-56(Ref. 64)
3-34
AMCP 706-123
CHAPTER 4
as hydraulic fluids, the physical properties are depend- Classification of hydraulic fluids and systems based
ent upon the compound structure and, accordingly, the on operational temperature ranges is not satisfactory in
physical properties of two chemically similar fluids many cases, such as in industrial systems, since there
may not be the same. Within a given class of hydraulic is no need for a-65F operational temperature require-
fluids where the chemical properties are similar, the ment. However, it is important that every hydraulic
physical properties of these fluids may vary greatly. fluid have a definite operational temperature range es-
tablished. Knowledge of these temperature limits is
4-2.3 CLASSIFICATION BY OPERATING necessary in selecting a hydraulic fluid for a specific
CHARACTERISTICS application.
4-2.6 CLASSIFICATION USED IN THIS oxidation, corrosion, sludge, and foam formation. Of
HANDBOOK course, not all fluids in this class will have all of these
characteristics but, through selection of the proper
The classification system used in this handbook com- grade of petroleum base fluid and additives, the desired
bines the two classification systems described in pars. properties may usually be obtained. These fluids gener-
4-2.2and 4-2.5. The major division in this classification ally have a high viscosity index (approximately 100)so
is petroleum base and nonpetroleum and/or synthetic that they may be used over a wide temperature range.
base. However, the latter category is subdivided into They have pour points as low as-90F and flash points
chemical classes to aid in identifying the wide range of as high as 400F. Fire point of these fluids generally
properties of these hydraulic fluids. ranges from 400"to 550F.Viscosity and viscosity-tem-
Comparative or relative ratings of some of the gen- perature characteristics vary over a wide range.
eral characteristics of the different classes of hydraulic Most petroleum and many chemical manufacturing
fluids are shown in Table 4-1.It must be remembered companies market a large number of petroleum base
that these ratings are only a general overall rating of hydraulic fluids, and these companies can provide in-
the hydraulic fluid base stock in each class and that formation on specific properties or applications of their
wide variation may be found in specific liquids products. There are numerous Military or Government
particularly when additives are used. Specifications covering different types of petroleum
A description of general properties and characteris- base hydraulic fluids. Some of the more widely used
tics of the different classes of hydraulic fluids is given liquids are described in the specification summaries
in subsequent paragraphs. Included at the end of the and specification data sheets in par. 4-6.
chapter are summaries and specification data of Mili-
tary or Government Specificationsfor typical liquids in
the respective classes (see par. 4-6).Requirements such
as composition, usable temperature range, and typical 4-4 NONPETROLEUM BASE
usage are listed. There are specifications for hydraulic HYDRAULIC FLUIDS
fluids other than those listed. No attempt was made to
list specifications for all liquids or oils which could be
used as hydraulic fluids. The hydraulic fluids and lubri- 4-4.1 PHOSPHATE ESTERS
cants selected are those which are most widely used or
those which represent the range of properties in specific This class of hydraulic fluids results from the incor-
classes of hydraulic fluids. It should be remembered poration of phosphorus into organic molecules. The
that the specification values are only limiting values resulting compounds have properties making them use-
and that specific hydraulic fluids may differ considera- ful as hydraulic fluids. They can also be used as a base
bly from these values. Also, it should be noted that stock fluid, as a part of the base stock, or as an additive.
there are many nonspecification hydraulic fluids, in all The principal advantage of this class of hydraulic fluids
classes, which may have properties equal or superior to over petroleum base hydraulic fluids is that many of the
the specification values. compounds are not only excellent lubricants but also
have excellent fire-resistant properties. They have good
oxidation stability and their thermal stability is consid-
4-3 PETROLEUM BASE HYDRAULIC ered good at medium-high temperatures, but they begin
FLUIDS to deteriorate rapidly above 300F. Hydrolytic stability
ranges from poor to very good depending upon in-
Petroleum base hydraulic fluids were among the first dividual compounds. Viscosity-temperature character-
liquids employed as hydraulic or power transmission istics of most phosphate esters are considered medium-
fluids. The use of petroleum base hydraulic fluids far to-good. In this respect they are equivalent to the better
surpasses that of all other ciasses including the synthet- petroleum base hydraulic fluids but are not as good as
ics and nonpetroleum classes. However, the wide var- the best petroleum products. Viscosity of the phosphate
iety of materials produced from different grades of ester hydraulic fluids is generally low and, on an
crude oils and additives makes a summary of their equivalent volatility basis, their viscosity characteris-
properties difficult. In general, these fluids are consid- tics are superior to petroleum base products. Some
ered to give outstanding performance, long life, good phosphate esters can be used as a mild extreme pres-
lubricating characteristics, and protection against rust, sure lubricant.
e
P
I. Petroleum Base G P G F E P F E
The MIL-SPEC requirements for a typical phos- lubricating properties. However, they allow fairly high
phate ester base hydraulic fluid are shown in the sum- wear because of low shear strength, high volatility, and
mary and specification data sheets in par. 4-6. susceptibility to oxidative breakdown. For these rea-
sons, the monoesters have little or no applications as
hydraulic fluids. On the other hand, the diesters
4-4.2 SILICATE ESTERS have excellent viscosity-temperature properties, low
volatility, good lubricating characteristics, high chemi-
This class of hydraulic fluids has many properties cal solvency, good additive response, and good hy-
similar to the phosphate esters since both are esters of drolytic stability. The diester lubricating film charac-
organic acids. The principal differences in the two teristics and oxidation stability are generally equal to or
classes are in hydrolytic stability, lubricating character- better than equivalent petroleum hydrocarbon fluids.
istics, flammability, and viscosity-temperature rela- The principal restriction or limitation of organic ester
tionships. In general, silicate esters have low volatility liquids is thermal stability since they tend to break
and excellent viscosity-temperature characteristics, but down at temperatures above 500F.
relatively poor hydrolytic stability. One of the out- The MIL-SPEC requirements for typical organic
standing characteristics of this class of hydraulic fluids acid esters are given in the summary and data sheets in
is good thermal stability combined with excellent re- par. 4-6.
sponse to antioxidant additives. Silicate esters possess
only fair oxidation stability and are similar to hydro-
carbon hydraulic fluids in their susceptibility to attack 4-4.4 POLYSI LOXANES
by oxygen; however, it is relatively easy to improve this
property with proper additives. The lubricating proper- The silicone liquids, as a class, possess very good
ties of silicate esters are only fair but with care in viscosity-temperature and mechanical properties, mak-
selection of materials and operating conditions, these ing them attractive as base stocks for synthetic lubri-
hydraulic fluids will provide some degree of lubrica- cants or as hydraulic fluids. These liquids have been
tion. Silicate esters are generally fairly good solvents used as hydraulic fluids, either alone or as compounded
and, although they do not dissolve many plastics or hydraulic fluids. Other characteristics which make the
synthetic elastomers, they tend to harden most elas- silicone liquids ideal for hydraulic fluids under severe
tomers after prolonged exposure at elevated tempera- operating conditions are: (1) their properties do not
tures. With proper additives and the right operating change appreciably under a wide range of temperature
conditions, some silicate ester hydraulic fluids operate and atmospheric conditions, (2) they have very low
satisfactorily for extended periods at temperatures up volatility, (3) they are compatible with many construc-
to 425F. tion materials, (4) they resist permanent viscosity
In addition to their use as hydraulic fluids, silicate change under severe mechanical stresses, (5) they are
esters are used as heat-transfer fluids, electronic equip- available in a wide range of viscosities, (6) they have
ment coolants, weapon lubricants, etc. because of their very good dielectric properties, (7) they have good oxi-
outstanding thermal stability and excellent response to dation resistance, and (8) they have low chemical sol-
antioxidants. A typical MIL-SPEC for a silicate ester vency properties. These liquids are also less flammable
aircraft hydraulic fluid is given in the summary and the than petroleum oils of similar viscosities but do not
specification data sheets in par. 4-6. resist ignition in many flammability tests. Significant
limitations of silicone liquids are their marginal lu-
4-4.3 ORGANIC ACID ESTERS bricity for ferrous materials in sliding contact and their
high compressibility. In general, the serviceable tem-
This class of liquids is employed principally as lubri- perature of most silicone fluids ranges from well below
cants for gas turbine engines, instrument lubricants, -65" to above 400F.
base stock for synthetic greases, and, to a limited ex- Summaries of Federal and MIL-SPEC requirements
tent, as a base stock for hydraulic fluids. Use as a for typical silicone fluids and data sheets for these
hydraulic fluid is generally in applications where en- specifications are in par. 4-6.
gine lubricating oil is used to actuate hydraulic units
such as accessories attached to jet engines.
Organic esters are produced in both monoester (sin- 4-4.5 GLYCOLS
gle ester group) and diester (two ester groups per mole- This class of hydraulic fluids is frequently referred to
cule) compounds. The monoesters have relatively good by several names including polyglycols, polyalkylene
4-5
AMCP 706-123
glycols, and polyethers. These glycol or polyglycol liq- polyoxypropylene base and are characterized by high
uids are used extensively as base stocks and as compo- viscosity indexes, low pour points, good thermal stabil-
nents for synthetic lubricants and hydraulic fluids such ity, fair-to-good oxidation stability, good water toler-
as air conditioner lubricants, heavy duty brake fluids, ance, good corrosion resistance, and compatibility with
and components of fire-resistant water-base hydraulic rubber and other materials in brake systems. These
fluids. These liquids are characterized by good lubricity liquids are considered particularly useful as hydraulic
and antiwear properties, high flash point, high viscosity fluids for automotive brake systems.
indices (up to 150), wide range of viscosities, low A summary of MIL-SPEC requirements for a brake
volatility and pour point, poor-to-fair high temperature fluid containing this class of liquid and a data sheet of
oxidation properties, little effect on rubber and metals, specification properties are in par. 4-6.
and very good solubility characteristics and additive
response. They have good resistance to sludge and var-
nish formation, and excellent resistance to mechanical
shear. The viscosity-temperature properties are equal
to or better than similar petroleum products. In gen- 4-4.8 WATER GLYCOLS
eral, the serviceable temperature range of these fluids
is from near 0" to above 500F.
MIL-SPEC requirements for a typical glycol type
This class of hydraulic fluids is generally considered
hydraulic fluid are given in the summary and specifica-
fire-resistant. It usually contains 35-60 percent water,
tion data sheets in par. 4-6.
a glycol, and a water-soluble thickener to improve vis-
cosity.Additives are also incorporated to improve anti-
4-4.6 CASTOR OILS corrosion, antiwear, and lubricity properties. Since
the fire-resistance properties of these liquids are de-
This class of hydraulic fluids is based on organic pendent upon the water content, extended use at tem-
fatty oils similar to animal oils, fish oils, and mineral peratures above 150F is not recommended. The vis-
oils. Because of their properties, they are seldom used cosity of these liquids is fairly low, but with proper
alone as a lubricating oil or hydraulic fluid. The organic additives they may be used satisfactorily at fairly low
oils oxidize, causing gumming, and they spoil or operating temperatures in systems such as aircraft hy-
become rancid, thus releasing free fatty acids. At high draulic systems. Typical viscosity indices for these liq-
temperature, these oils tend to decompose to corrosive uids are in the range of 140 to 160. Because of the
acids. These oils also will support bacteria and care corrosive nature of the water component of these liq-
should be taken to keep them sterile. The addition of uids, proper additives must be used to make them com-
castor oil or other fatty oils to petroleum mineral oils patible with most common construction materials such
will increase the load-carrying ability. Some of the liq- as steel, aluminum, brass, and copper. It is generally
uids incorporating these oils are steam-cylinder oils, not good practice to use these liquids in contact with
marine-engine oils, cutting oils, automatic-transmis- soft or sacrificial plated materials such as galvanizing
sion fluids, hydraulic fluids, and industrial gear oils. In or cadmium plating. Antiwear and lubricity additives
general, castor oils are moderately high viscosity liq- can make these liquids suitable for use in hydraulic
uids with a flash point above 500F and a pour point systems and machines at moderate pressures. However,
above 0F. at high pressures or loads, service and maintenance
Summary and data sheets of several typical MIL- problems increase. The additive-containing water-
SPEC requirements for compounded liquids containing glycol liquids generally are compatible with the various
castor oil are in par. 4-6. seal and packing materials used in systems designed for
petroleum type fluids, but these aqueous-base liquids
tend to soften or lift many conventional paints or coat-
4-4.7 POLYOXYALKYLENE GLYCOLS ings. In general usage, it is a good practice to conduct
periodic checks of water content of these liquids since
The polyoxyalkylene glycol class of hydraulic fluids the viscosity and other properties vary appreciably with
have many of the same properties as the polyalkylene the water content.
In some cases, the
glycol liquids discussed in par. 4-4.5. MIL-SPEC requirements for a typical water-glycol
polyoxyalkylene liquids have somewhat superior prop- type hydraulic fluid are given in the summary and
erties. Most of these fluids have a polyoxyethylene- specification data sheets in par. 4-6.
4-6
AMCP 706-123
4- 7
AMCP 706-123
measure of the flammability of phosphate esters, is the that "Houghto-Safe" is also the name of a glycol
spontaneous or autogenous ignition temperature which water fluid.)
ranges from 800F to more than 1,100"F. 5. Other Phosphate Ester Base Hydraulic Fluids
The third group, the triaryl phosphates, are the most and Lubricants
viscous of the tertiary phosphate compounds, have a In addition to these typical commercial products,
short liquid range, and are essentially water insoluble. phosphate ester liquids are compounded with many
This type of phosphate has a maximum recommended different materials to produce new liquids for different
bulk operating temperature range between 150" and applications. Some of these liquids are compounds of
200F which is somewhat lower than the aryl phos- several types of phosphate esters and additives; others
phates. Their applications are mostly as compounding are compounds of phosphate esters and other liquids
ingredients for synthetic hydraulic fluids. such as chlorinated silicone liquids. In general, the pur-
The major advantage of the phosphate esters as a pose of these developmental oils is to improve or extend
class of hydraulic fluids is their fire resistant properties the operating temperature limits and the range of cer-
combined with their ability to lubricate moving parts, tain characteristics such as lubricity, antiseize, and vis-
especially steel on steel. cosity index.
Some of the names of commercial liquids of the phos-
phate ester-type widely used by industry are:
1. Skydrol 7000 and 500A (Monsanto Chemi-
cal Company) 4-5.2.2 Halogenated Compounds
Both of these hydraulic fluids are fire-resistant phos-
phate esters containing small amounts of several addi-
tives (the 7000 and 500 designations refer to the fluid 4-5.2.2.1 Polysiloxanes (Manes)
viscosity in centistokes at -40F). These fluids were
developed for use in transport aircraft hydraulic sys- These compounds are silicone-containing materials
tems. Skydrol 500A has been adopted as the standard being investigated for applications as hydraulic fluids.
hydraulic fluid by most of the world's airlines. These liquids have molecular structures which contain
only silicon-to-carbon bonds and no silicon-oxygen
2. Pydraul (Monsanto Chemical Company) bonds as do other silicones and silicate esters. The
These liquids are a series of fire-resistant phosphate molecular organic radical of these fluids may be paraf-
esters and additive-containing hydraulic fluids deve- finic or aromatic hydrocarbons with mixtures of alkyl,
loped for industrial machinery. Pydraul hydraulic aryl, alkaryl, or arylalkyl groups present.
fluids are less expensive than Skydrol and are available In general, these liquids have poor lubricity and 'i
in a range of viscosities to fit numerous industrial ap- narrow viscosity range. Some additives have shown
plications. Pydraul AC, although produced primarily promise of improving selected characteristics; some
as a fire-resistant lubricant for air compressor systems, polymers are effective in increasing the viscosity; tricre-
may also be used in certain hydraulic systems. syl phosphate and sodium petroleum sulfonate both act
3. FR YQUEL (Cellulube) (Stauffer Chemical as antiwear additives, and sodium and potassium
Company) amides are effective as antioxidants. Because of su-
These liquids are a group of fire-resistant triaryl perior thermal stability and chemical inertness, the si-
phosphate ester hydraulic fluids and/or lubricants lanes appear to be a promising base stock for hydraulic
available in controlled viscosity ranges. The product or fluids for use in the temperature range of 0" to more
fluid numbers represent the fluid viscosity at 100F in than 700F. Typical properties of silane fluids are pour
Saybolt Universal Seconds (SUS). Products available point,-25"F; flash point, above 500F; bulk density, 7.4
include FRYQUEL 90, 150,220,300, 550, and 1,OOO. Ib/gal; and viscosity, 37 cSt at 100F.
Although these liquids function primarily as fire-resist-
ant hydraulic fluids, they also find applications as lu- 4-5.2.2.2 Hydrocarbons
bricants where fire resistance is not a requirement.
The halogenated hydrocarbon liquids possess several
4. Houghto-Safe (E. F. Houghton and Company) properties that make them attractive for use as hydrau-
These products are also a series of phosphate ester lic fluids. They have outstanding fire resistance, good
fire-resistant hydraulic fluids and lubricants which thermal stability and heat-transfer characteristics,
have properties and recommended usage similar to the good oxidative stability, and boundary-lubrication ac-
Cellulube and Pydraul fluids. (The reader is reminded tivity. However, they do have some deficiencies, i.e.,
ea
AMCP 706-123
poor viscosity-temperature properties and high freez- and are marginal lubricants. Their operating tempera-
ing point. ture range is room temperature to near 1 , W F . How-
Some of the commercial hydrocarbon liquids usable ever, their main deterrent is their deficiency in low-
as hydraulic fluids and/or lubricating fluids are: temperature characteristics.
(1) Aroclor (Monsanto Chemical Company)
Aroclor fluids are a series of hydrocarbon liquids 4-5.2.4 Heterocyclic Compounds
containing chlorinated biphenyls and cover a wide
range of viscosities. These fluids have excellent shear Several heterocyclic compounds have been investi-
resistance, are thermally and chemically stable, non- gated for applications as synthetic hydraulic fluids and
corrosive, and provide a high degree of extreme pres- lubricants. The most promising are those compounds
sure lubricity. containing nitrogen, which show thermal stability
(2) Kel-F Fluids (Halocarbon Corporation) above 800F to around 1,200"F. Other heterocyclic
The Kel-F fluids are a series of wide range hydrocar- compounds are less stable. At the present time, no
bon hydraulic fluids and oils containing halofluorocar- commercial fluids of this class are available.
bon oils. These fluids are fire-resistant, chemically and
thermally stable, and may be used in mechanisms as-
sociated with reactive chemicals. The Kel-F fluids have 4-5.2.5 Phosphonitrilates
extreme resistance to breakdown, and excellent flow
and load-bearing characteristics. In addition to hydrau- These liquids are being investigated as intermediate
lic fluid applications, they are also employed as com- temperature range hydraulic fluids and also as lubri-
pressor lubricants. cants. Generally, they are stable to hydrolysis and resist
thermal polymerization up to 750F. These liquids are
(3) Fluorolube (Hooker Chemical Company)
still classed as research items and no commerical fluids
The Fluorolube fluids are a series of hydrocarbon are available.
compounded liquids of similar composition, properties,
and usage as the Kel-F fluids.
4-5.2.6 Liquid Metals
4-9
AMCP 706-123
4-6 HYDRAULIC FLUID AND Navy-WP: Naval Air Systems Command (AS)
LUBRICANT SPECIFICATIONS Washington, D.C. 20360
Navy-SA: Naval Supply Systems
The following pages contain information on the Command Headquarters
specifications for hydraulic fluids and lubricants men- Washington, D.C. 20360
tioned in preceding paragraphs. For each liquid, data Navy-YD: Naval Facilities Engineering
presented are: (a) a Specification Summary Sheet; and Headquarters Command
(b) Specification Property Requirements Sheet. The Washington, D.C. 20360
specifications are presented in the following order: Air Force-1 1: Systems Engineering Group
(AFSC, SEP)
1. Petroleum Base Liquids: Wright-Patterson AFB, Ohio 45433
VV-L-800 Air Force-67: Middletown Air Material Area
MIL-L-2104B (MAAMA, MANSS)
MIL-H-5606B Olmsted AFB, Pennsylvania 17057
MIL-H-6083C
MIS-I01 37 VV-LdOO: L UBRICA TING OIL,GENERAL PUR -
MIS- 10150 POSE, PR ESER VATI YE (WATER-
MIL-L-10295A DISPLACING, LOW TEMPERATURE)
MIL-H-l3866B(MR)
MIL-H-13919B (NATO Symbol: 0-190)
MIL-F-1711l(N0RD)
MIL-L-1733lF(SHIPS), Amendment 1 a. General characteristics: This specification cov-
MIL-L-17672B ers a general purpose, water-displacing, lubricating oil
MIL-L-21260A for low-temperature applications. It has a pour point of
MIL-F-25598(USAF) -70"For lower and a viscosity of 7,000 cSt at -40F.
MIL-H-27601A(USAF) b. Usable temperatures: The operating tempera-
MIL-L-45199A ture range is not specified.
MIL-H-46001A c. Chemical composition: This liquid is a pe-
MIL-L-46002(ORD) troleum base oil containing additives necessary to meet
MI L-L-46oO4(ORD) specification requirements. Principal requirements are
MIL-H-8 1019(WEP) for corrosion, oxidation and water displacing proper-
ties.
2. Phosphate Ester Liquids: MIL-H- 19457B
d. Uses: This liquid is a lubricating oil for protec-
(SHIPS) tion against corrosion of small arms, automatic weap-
3. Silicate Ester Liquids: MIL-H-8446B
ons, fuze mechanisms, general squirt-can applications
4. Organic Acid Ester Liquids: MIL-6085A; MIL-
and whenever a general purpose, water-displacing, low
L-7808G; MIL-L-23699A
temperature, lubricating oil is required.
5 . Polysiloxane Liquids: MIL-S-81087A(ASG);
e. Limitations: This liquid loses its Newtonian
VV-D-001078 (GSA-FSS)
properties at temperatures below -WF,snould not be
6. Glycol Liquids: MIL-H-5559A(WEPS) used on aircraft equipment such as guns when opera-
7. Castor Oils Liquids: MIL-P-46046A(MR); tion at -65F is required.Very low-temperature applica-
JAN-F-461 tions should be established by tests.
8. Poboxyalkylene Glycol Liquids: MIL-H- f. Custodian: Army-MR
13910B; VV-B-680a
9. Water Glycol Liquids: MIL-H-22072A(WP)
MIL-L-2104B: LUBRICATING OIL, INTERNAL
The code assigned to the abbreviations for military
COMBUSTION ENGINE (HEA VY
activities listed as the custodians of a specification is:
DUTY)
Army-MR: U.S. Army Materials Research Agency
Watertown, Massachusetts 02 172 (NATO Symbol: None)
Army-GL: U.S. Army Natick Laboratories a. General characteristirs: This specification cov-
Natick, Massachusetts 07 162 ers a multi-grade, detergent-type, petroleum base oil
Navy-SH: Naval Ship Engineering Center which may contain additives to meet specifica-
Washington, D.C. 20360 tion requirements.
4-10
AMCP 706-123
PROPEIirIEs VALUES
4-1 1
AMCP 706-123
PROPERTIES VALUES
Color : NR
S p e c i f i c Gravity: NR
Pour Point, OF (Max): Grade 10 -20
Grade 30 0
Grade 50 +15
Stable Pour Point, OF (Max): Grade 10 ( c n l y ) -20
Flash Point, OF (Min): Grade 10 360
Grade 30 390
Grade 50 400
Viscosity, c S t : 0F; Grade 10 (Max) 2,614
OOF; Grade 30 ( M a x ) 43,570
OOF; Grade 50 (Max) NR
210F; Grade 10 5.44- 7.29
210'F; Grade 30 9.65-12.98
210F; Grade 50 16 -83-22.7
Additives: Allowed (No r e r e f i n e d )
Oxid. C h a r a c t e r i s t i c s : ( f e r r o u s and nonferrous engine
parts) No Corrosion
Low Temperature Deposit: 180 h r low temp cycle S l i g h t Corrosion
Ring Stick: 120 h r engine t e s t Nonstick, Kin wear
Light-load deposit accumulation: 120 h r engine t e s t Minimize Deposit
Foaming: 75'F, a f t e r 5 . 0 min blowing, m l ( M a x ) No l i m i t
75'F, a f t e r 10.0 min s e t t l i n g , m l (Nm) 300
200'F a f t e r 5 . 0 min blowing, m l (Max) No l i m i t
200'F a f t e r 10.0 min s e t t l i n g , m l (Max) 25
Repeat 75F Test Same as i n i t . 75'F Test
O i l Additive S t a b i l i t y : No a d d i t i v e i n s t a b i l i t y
Storage S t a b i l i t y : Remain Homogeneous
Compatibilj t y : A l l o i l s t o Spec
Recommended Temperature Rsnge, OF: Above -10
NATO Symbol: None
Water Content :
4-1 2
AMCP 706-123
~~
b. Usable temperatures: The operating tempera- open hydraulic system unless the reservoir is filled
ture range is not specified, but use above -10F frequently. It is most effective in closed-system hy-
is recommended. draulic units. It is not interchangeable with any other
c. Chemical composition: This liquid is a pe- types of hydraulic fluid.
troleum base oil which may contain antifoam and pour f. Custodians: Army-MR
point depressant additives, as well as corrosion and Navy-WP
oxidation inhibitors to meet specification requirements. Air Force-1 1
It shall not contain any re-refined components.
d. Uses: This liquid is for crankcase lubrication of MIL-H-6083C: HYDRA ULIC FL UIDS,PETROLEUM
reciprocating internal combustion engines of both BASE, FOR PR ESER VATION AND
spark-ignition and combustion-ignition types when TESTING
ambient temperatures are above -10F. (NATO Symbol: C-635)
e. Limitations: This liquid is not recommended for a. General characteristics: This liquid is a pe-
gear box applications without prior performance troleum base corrosion preservative for hydraulic
evaluation. For highly supercharged compression-igni- equipment. The finished product shall have no deleteri-
tion engines operating at output levels of 150 psi brake ous effect on pressure-seal packing used on aircraft
mean effective pressure or above, it may be necessary hydraulic systems and shock struts.
to decrease oil drain periods or change to oils supplied b. Usable temperatures: The operating tempera-
under MIL-L-45 199A and specifically intended for this ture range is -65 to +160F.
service. This liquid shall be compatible with other oils c. Chemical composition: The finished liquid shall
qualified to this specification and shall have good stor- be a petroleum base oil with additives to provide corro-
age life when stored in closed containers at nor- sion protection and to improve the viscosity/tempera-
mal temperatures. ture characteristics and resistance to oxidation. No
f. Custodians: Army-MR pour point depressant additive is allowed.
Navy-SH d. Uses: This fluid is intended as a preservative oil
Air Force-1 1 in aircraft and ordnance hydraulic systems during ship-
ment and storage, and also as a testing and flushing
MIL-H-5606B: HYDRAULIC FL UID, PETROLEUM liquid for hydraulic system components. It is not in-
BASE: AIRCRAFT, MISSILE, AND tended as an operational hydraulic fluid, but may be
ORDNA NCE used for limited operational use.
e. Limitations: Not recommended for high tem-
(NATO Symbol: H-5 15) perature use or for heavy duty requirements. This liq-
a. General characteristics: This specification cov- uid is not interchangeable with Hydraulic Fluid, Castor
ers a petroleum base hydraulic fluid for low tem - Oil Base, Specification MIL-H-7644(USAF) or Hy-
pera ture applications. It is dyed red for Identifica- draulic Fluid, Nonpetroleum Base, Automotive,
tion purposes.
Specification VV-B-680a.
b. Usable temperatures:The recommended operat-
f. Custodians: Army-MR
ing temperature ranges are -65 to 160F in open sys-
tems and -65 to 275F in closed systems. Navy-SA
c. Chemical composition: This liquid is a pe- Air Force-1 1
troleum base oil with the following additives: viscosity
index improver, oxidation inhibitor, and TCP antiwear MIS-10137: HYDRAULIC FLUID, PETROLEUM
agent. The finished liquid must not contain any pour BASE, INTERMEDIA TE VISCOSITY
point depressants. (NATO Symbol: None)
d. Uses: The primary uses for this liquid include a. General characteristics:This hydraulic fluid is a
aircraft hydraulic system, automatic pilots, shock petroleum base liquid containing additives for moder-
struts, brakes and flap control mechanisms. It is also ate temperature ranges. It is dyed dark green or dark
used in missile hydraulic servo-controlled systems and blue for identification purposes.
ordnance hydraulic systems using synthetic seal - b. Usable temperatures: The operating tempera-
.jng materials. ture range is not specified.
e. Limitations: Since this material has a rather c. Chemical composition: This liquid is a refined
high rate of evaporation, it should not be used as a petroleum base liquid with additive materials to im-
general purpose high temperature lubricant or in prove oxidation resistance and viscosity-temperature
4-13
AMCP 706-1 23
I PROPERTIES VALUES
Co'or: Red
P o u r P o i n t , "F (Max): -75
F l a s h P o i n t , "F (Min): 200
Vi-cosity, cSt: -65F ( M a x ) 3,000
-40F (Max) 500
130F (Min) 10
Additives: Antiwear; % > I t 0.50
Oxidation I n h i b i t o r s , % w t f 2.00
Corrosion I n h i b i t o r s , $ w t NR
v i s c o s i t y Improvers, % w t 20.00
f
4-14
AMCP 706-123
~~ ~~ ~_____ ~ ~
PROPERTIES VALUES
4-15
AMCP 706-123
PROPERTIES VALUES
Color: Blue/Green
S p e c i f i c Gravity: NR
Pour P o i n t , OF (Max): -75
Flash Point, OF (Min): 200
v i s c o s i t y , c s t : @OF 50 f 5.0
lOO'F 7.5 f 0.5
Neutralization No. : mg KOH/g (Max) 0.20
Additives: $ w t ; Antiwear ( t r i c r e s y l phosphate) 0.5 f 0.1
Oxidation I n h i b i t o r < 2.0
Viscosity Improvers 5 10.0
Pour Point Depressant None
Others Approval Req'd
Corr. and Oxid. S t a b i l i t y : S t e e l 53.20
168 h r a t 250F Aluminum Alloy 39.20
M a x w t Chg, Magnesium Alloy fo.20
mg/m2 Cad.-Plate fo.20
Copper fo.60
P i t t i n g , Etch o r Corr. a t 2 0 X None
$ Visc Chg a t 130F -5 t o +20
Increase i n n e u t r a l N O . ( M ~ x ) 0.20
Insoluble M a t ' l or Grmnn-ing None
Low Temperature S t a b i l i t y : 72 h r at -65F No S o l i d , nongel
Rubber Swell: Type "L", $ Vol Chg 19-20
Evaporation: 4 h r a t 150'F Oily, nontacky
Copper S t r i p Corr.: 72 h r a t 250'F (Max) No. 2 (ASTM)
S o l i d P a r t i c l e Content: 5-15 Microns 2,500
(Max P a r t s / 1 0 0 ml) 16-25 Microns 1,000
15 min Max f i l t e r
time 26-50 Microns 250
51-100 Microns 25
Over 100 Microns None
Weight of Residue: mg (Max) 0.30
Fonming: (75'F) a f t e r 5.0 min blowing, m l (Max) 65
a f t e r 10.0 min s e t t l i n g m l (MG) None
Water Content: $ ( M W ) 0.015
Storage S t a b i l i t y : ( 70"-120F) month (Min) 12
NATO Symbol: None
Recommended Temperature Range, F : Intermediate
Compatibility: None Recommended
4-1 6
AMCP 706-123
characteristics, and tricresyl phosphate for antiwear a. General characteristics: This specification cov-
properties. The liquid may also be prepared by blending ers a light duty, low viscosity oil with suitable additives
equal quantities of fluids on the qualified products list to meet specification requirements for low ambient
of MIL-H-5606 and MIL-H-46004. temperatures.
d. Uses: This hydraulic fluid is for guided missile b. Usable temperatures: This liquid is intended for
hydraulic systems such as the NIKE HERCULES use at ambient temperatures from -65" to 0F.
Missile System at intermediate temperatures. c. Chemical composition: This liquid is a pe-
e. Limitations: This liquid shall contain no pour troleum base oil, or a synthetically prepared product,
point depressants, admixtures of resins, rubber, soaps, or combination thereof, with suitable additives to meet
gums, fatty oils, oxidized hydrocarbons or other addi- the requirements of this specification including foam-
tives unless specifically approved. It has a storage life ing, oxidation, ring stick and wear tests, as well as
of 12 months under normal conditions (-70"to viscosity range, flash, pour point, etc.
+ 120F). d. Uses: This liquid is used for crankcase lubrica-
f. Custodian: U.S. Army Missile Command tion of reciprocating internal combustion engines at
Redstone Arsenal, Alabama 35809 very low ambient temperatures, and other applications
where a light duty nonoxidizing and nondeposit-form-
MIS-101.50: HYDRAULIC FLUID, PETROLEUM ing oil is required.
BASE, LOW TEMPERATURE, COR- e. Limitations:This liquid is not for high tempera-
R OSION PREVENTING ture or heavy duty applications. This liquid is to be
compatible with all engine oils previously qualified to
(NATO Symbol: None) this specification. It has good storage life when stored
a. General characteristics: This liquid is a pe- in closed containers at normal temperatures.
troleum base hydraulic fluid containing additives for f. Custodians: Army-MR
use in aircraft, missile, and ordnance hydraulic systems Navy-SH
in the low temperature range. It has a pour point of Air Force-1 1
-9O"Fand a viscosity of 800 cSt at -65F.
MIL-H-l3866B(MR): HYDRAULIC FL UID, PETRO-
b. Usable temperatures: The operating tempera-
LEUM BASE, ARTILLERY
ture range is not specified, but the liquid is generally for
very low temperature applications (to -9O"F)and mod- RECOIL, SPECIAL
erate high temperatures (less than + 200F). (NATO Symbol: None)
c. Chemical composition: The finished liquid is a a General characteristics: This hydraulic fluid is
clear and transparent petroleumbase fluid with polyme- one grade of special recoil hydraulic fluid for shock
ric additives to improve viscosity-temperature charac- load mechanisms. The liquid is clear and transparent
teristics, and other additives to inhibit oxidation and and is dyed green for identification purposes.
corrosion and to improve antiwear properties. b. Usable temperatures: The usable temperature
d. Uses: This hydraulic fluid is intended for use in range is not specified, but is generally limited to be-
automatic pilots, shock absorbers, brakes, flap-control tween -30" and +200"F.
mechanisms, missile hydraulic servo-controlled sys- c. Chemical composition: The finished liquid base
tems, and other hydraulic systems using synthetic seal- is a refined mineral oil-free from resin, soap, unrefined
ing materials. oils, and injurious ingredients which may affect the
e. Limitations: This hydraulic fluid is not for high proper function of the fluid. Viscosity index improvers,
temperature applications, and is not interchangeable oxidation inhibitors, and other additives-within de-
with any other hydraulic fluid except as specified in fined limits-may be added if needed to meet specifica-
equipment Technical Manuals. It has a normal storage tion requirements.
life of 12 months. d. Uses: This hydraulic fluid is primarily for ord-
f. Custodian: U.S. Army Missile Command nance equipment such as hydrosprings and hydro -
Redstone Arsenal, Alabama 35809 pneumatic artillery recoil mechanisms. It may also
(ERR MI-56001) be used in other fluid or force damping mechanisms.
e. Limitations: This hydraulic fluid is not suitable
MIL-L-10295A :LUBRICATING OIL, INTERNAL for extreme temperatures; the fluid, and any of its com-
COMBUSTION ENGINE, SUBZERO ponents, must not be subjected to temperatures above
300F during blending or subsequent operation.
(NATO Symbol: None; Product Symbol: OES) f. Custodian: Army-MR
4-1 7
AMCP 706-123
PROPERTIES VAUJES
4-18
AMCP 706-123
I PROPERTIES VALUES
Color : NR
Spec i f i c G r a v i t y : NR - Report
Pour P o i n t , OF (Max): - 65
S t a b l e Pour P o i n t , "F (Max) : -65
F l a s h P g i n t , O F (Min) : 290
V i s c o s i t y , c S t : -40'F (Min) 5.75
-210'F (Max) 8,500
Addi ti v e s : Allowed
E f f e c t o f A d d i t i v e s : I n c r e a s e i n foam None
Homogeneity Range, O F -65 t o +250
Storage S t a b i l i t y No S e p a r a t i o n
Oxid. C h a r a c t e r i s t i c s : ( f e r r o u s and n o n f e r r o u s
engine p a r t s ) No Corrosion
Ring S t i c k : 120 h r Engine T e s t Nonstick, Report mm Wear
Foaming: 75'F, a f t e r 5 . 0 min blowing, ml (Max) No l i m i t
75'F, a f t e r 10.0 min s e t t l i n g , m l (Max) 300
200F,a f t e r 5 . 0 inin blowing, m l (Max) No l i m i t
~OO'F, a f t e r 10.0 min s e t t l i n g , m l ax) 25
Repeat 75F t e s t Same a s i n i t . 75'F Test
Compatibility: A l l o i l s t o Spec.
Water Content, $, : None
Suspended Matter, $ : None
S t o r a g e Sl a b i l i t y : NR
NAlO Symbol: None
Hecoinmended Ambient Temperature Range, "F : -65 to 0
1.
Noics: NK, no r c q u i r cl iinns n l s .
Uie: L o w i r m p e r a i u r e lub for c r a n k c a s e o f i n t e r n a l combustion e n g i n e s . May be s y n t h e t i c
4-19
AMCP 706-123
Color: Green ( C l e a r )
S p c c i f i c G r a v i t y , 6 0 / 6 0 , OF: 15
Bur/Cloud P o i n t s , O F ax) : -50/-40
Flash/Fire h i c t s , OF ( M i n ) : 210/220
V i s c o s i t y , cSt: -40'F (Nax) --
-30'F (Max) 4 400
~
100F (Mix) 55
210'F (Min) 15
Additives: Oxidation I n h i b i t o r s , $ w t Approval Req'd
Corrosion I n h i b i t o r s , $ w t Approval Req'd
V i s c o s i t y Improvers, $ c 17.5
Others None
:!cu',ralization No. : mg KOH/g (Max) 3.30
P r e c i p i t a t i o n No. : (Max) 0.05
Corr. and Oxid. S t a b i l i t y : S t e e l -0.20
168 h r a t 212'F Copper -0.20
M a x w t Chg, P i t t i n g , Etch or Corr. a t 2OX None
3g/m2 V i s c o s i t y Chg a t 100F, $ -5 t o +20
N e u t r a l i z a t i o n No. i 0.50
P r e c i p i t a t i o n No. < 0.05
I m o h k l e K a t ' l o r >.x=.<cg ?;me
Copper S t r i p Corr.: 3 h r a t 212'F NR
Law Temperature S:abili:y: 72 h r a t -30'F Nongel, N 3 . Sep.
Rubber Swell: Typr "L", 168 h r a t 70"F, $ Vol Chg g 25.0
D i e l e c t r i c Strength: k V / m (Min) 15.0
Shear Stab.: (Pump); 100F, Cycles t o reduce Visc. 25% > Ref. Fluid*
Corr. R o t . ; ( b a r e s t e e l ) : 200 h r a t 77"F, lO@ R.H. NR
S a l t Water Corr. ; ( b a r e s t e e l ) : 20 h r a t 77$ NR
D i s t i l l a t i o n : lO$ Evaporation; OF (Min) ?rR
5 6 Pva.poration; OF (Min) NR
Foaming: 7 5 ' F , a f t e r 5.0 min blowing; ml (Max) NR
75'F, a f t e r 10.0 min s e t t l i n g ; ml (Max) NR
200F, a l ' t e r 5.0 min blowing, m l (Max) m
200F, af't-er 1 0 . 0 min s e t t l i n g , m l (Max) NR
Reconmended Temperature Range, O F : --
S e r v i c e P e r f . : ( O i l Gear M3), Oil Temperature O F (Max) NR
Water Coctent: --
4-20
AMCP 706-123
4-2 1
AMCP 706-123
PROPEKCIES VALUES
4-22
AMCP 706-123
I PROPEFiTIES VALUES
Color: N o . 2 (ASTM)
S p e c i f i c Gravity: NR
pour F o i n t , O F , (MU): -40
Flash/Fire Points, OF (Min): 220/235
Viscosity, cSt: -25'F (Max) 600
O O F (Max) 215
100F (Min) 27
210'F (Min) 10
Additives: Antiwear; $ w t Approval Req'd
Oxidation I n h i b i t o r , $ wt Approval Req'd
Corrosion I n h i b i t o r , % wt P-pproval Req'd
Viscosity Improver, $ wt Approval Req'd
T r i c r e s y l Phosphate, $,wt 1.0 f 0.1
N e u t r a l i z a t i o n No. : mg KOH/g (Max) 0.3
P r e c i p i t a t i o n No.: 0.05
Water Content: 46 i ax) None
Low Temperature S t a b i l i t y : 72 hr a t -35'F No S o l i d s , nongel
Rust Prevention: ( b a r e s t e e l ) , 24 h r a t 140'F No Visual Evidence
Corr. and Oxid. S t a b i l i t y : copper w t l o s s ; rng/cm2 < 0.20
336 h r a t 220'F $ Vise Chg; 210'F 0 t o +25
Fluid and water $ Visc Chg; 0F 0 t o +25
N e u t r a l i z a t i o n No. (Max) 0.50
Oil-Insoluble Residue; $, w t
(Max) 0.50
Color; (ASTM) (M=) No. 5
Copper Wire Oxid.: $ Vise Chg; 210'F 0 t o +15
72 h r a t 200'F $ Vise Chg; OF 0 t o +15
F l u i d and Water N e u t r a l i z a t i o n No. (Max) s 0.50
Shear S t a b i l i t y : $ Visc Chg a t 210'F (Max) -25
5,000 cycle pump F l u i d Condition No Separation o r Sludge
100'F and 1,000 p s i N e u t r a l i z a t i o n No. (Max) 0.50
WearGear Pump: W t Loss/pUmp Gear, g 0.20 (Max)
(100 hr, 100F, 1,000 p s i ) W t Lss/Bronze Bushing, g 0.04 (Max)
W t Loss/4 Bronze Bushings, g 0.08 (Max)
Evaporation: 72 h r a t 190'F; Visc.; 210F, cSt 3,000 (Max)
Water Sludging: 24 h r a t 100'F; 46 Vise Chg a t lOO'F -2 t o +10
NATO Symbol: H-575
Recommended Temperature Range , " F : NR
Foaming : NR
Storage S t a b i l i t y : NR
4-23
AMCP 706-123
PROPERTIES VALUES
Color : NR - Record
Specific Gravity: NR - Record
Pour Point, OF (Max): 20
Flash Point, OF (Max): 350
Viscosity, c S t : l O O O F 82-110
210F (Min) 8.2
N e u t r a l i z a t i o n No. : mg KOH/g (Max) 0.20
Mineral Acidity: Neutral
Additives: Allowed (nonchlorine )
Corr. Prot.: ( b a r e s t e e l ) s a l t spray ( f o g ) ; 48 h r a t 95'F No Corrosion
Copper s t r i p c o r r : 3 hr a t 212'F S l i g h t Tarnish
Oxid. Test: (1,000 hr a t 95'F): N e u t r a l i z a t i o n No. (Min) 2 .o
Iron-Copper Cat., Insoluble Sludge, mg (Max) 100
a i r and water Copper or. i r o n i n o i l ; mg (Max) 100
Work Factor: (Min) 0.9 (No d e p o s i t )
Water Content: None
Ash (sulphated residue) : NR - Record
Carbon Residue: NR - Record
Compatibility : Ref. O i l s
H o m o g e n e i t y T e m p e r a t u r e R a n g e , OF: 30 t o 250
Foaming: 75'F, a f t e r 5 . 0 min blowing, m l (Max) No l i m i t
7SoF, a f t e r 10.0 min s e t t l i n g , m l (Max) 300
200F, a f t e r 5.0 rnin blowing, m l (Max) No l i m i t
200F, a f t e r 10.0 min s e t t l i n g , m l (Max) 25
Repeat 75F Test Same as i n i t . 75F Test
Emulsion: 130F, s e t t l i n g time; min (Max) 30
Load Carrying Ability: (Ryder Gear Machine); P.P.I. (Min) 2,200
Wear: ( 2 h r 175'F, 600 rpm, 15 kg); Scar. Dia mm (Max) 0.45
Contamination: (325 Mesh); mg/gal; (Max) 10 .o
6.0 n i l f i b e r / g a l (Max) 1.0
NATO Symbol: 0-250
Military Symbol: 2190-TEP
Storage S t a b i l i t y : --
Recommended Temperature Range, OF : --
4-24
AMCP 706-123
PROPERTIES VALUES
I
Color: NR
Specific Gravity: NR -
Report
Bur Bint, OF (Max): MIL-Symbol 2075 T-H -20
MILSymbOl 2110 T-H -10
MIL-Symbol 2135 T-H 0
Flash Point, OF (Min): MILSymbol 2075 T-H 315
MILSymbOl 2110 T-H 325
MIL-Symbol 2135 T-H 340
Viscosity, cSt: OOF, MILSymbOl 2075 T-H 1,200(Max)
OOF, MIL-Symbol 2110 T-i 2,400 (Max)
10*F, MIL-Symbol 2135 T-H 2,800 (Max)
210F, MIL-SymbOl 2075 T-H 4.3-5.3
210F, MIL-Symbol 2110 T-H 5.3-6.7
210q MIL-Symbol 2135 T-H 6.7-7.7
Neutralization No. : mg KOH/g (Max) 0.20
Neutrality, Qualitative: Neutral
Copper Strip: 3 hr at 212'F (Max) No. 1 (ASTM)
Rust Preventative: 24 hr at 140'F No Corrosion
Water Content: $ (MW) None
Ash, Sulfated Residue :$ (Max) -
NR Report
Additives: Allowed
Homogeneity Temperature Range, OF: MIL-Symbol 2075 T-H -20 to 250
MIL-Symbol 2110 T-H -10 to 250
MIL-Symbol 2135 T-H 0 to 250
Emulsion: 130"F, 30 min settling, Max Cuff, ml 3.00
Foaming: 75'F, after 5.0 min blowing, ml (Max) No limit
75'F, after 10.0 min settling, ml (Max) 300
200F, after 5.0 rnin blowing, ml (Max) No limit
200 OF, after 10.0 min settling, ml ( M a ) 25
Repeat 75'F Test Same as init. 75'F Tes
Oxid. Test: Time to reach Neut. No. 2.0 mg KOH; hr (Max) 1,000
Contamination: (325 Mesh); -/gal (Max) 10.0
6.0 ml fibers/gal (Max) 1.0
NATO Symbol: 11-573
Storage Stability: --
Recommended Temperature Range, OF: --
Compatibility: Ref. and Spec. oils
4-25
AMCP 706-123
stored in closed containers at normal temperatures. It d. Uses: This liquid is used for low temperature
shall be compatible with other reference oils furnished hydraulic systems such as missile hydraulic systems,
by the Government. Compatibility is determined by automatic pilots, shock struts and other hydraulic sys-
mixing equal portions of specification oil and reference tems using synthetic sealing material.
oil, and passing requirements of this specification. e. Limitations:This liquid is not for high tempera-
f. Custodians: Army-GL ture conditions. It is not interchangeable with Hydrau-
Navy-SH lic Fluid, Castor Oil Base, Specification MIL-H-7644
Air Force-1 1 (blue color) nor Hydraulic Fluid, Petroleum Base,
Specification MIL-H-5606B.
MIL-L-2126OA: LUBRICATING OIL, INTERNAL f. Custodian: Air Force - WADC, WCRTR-1
COMB USTION ENGINE, PR E - (Preliminary Spec.: Non-release)
SER VATI VE Wright-Patterson Air Force Base,
Ohio 45433
(NATO Symbol: None)
a. General characteristics: This specification cov-
ers three viscosity grade preservative lubricating oils MIL-H-27601A(USAF): HYDRA ULIC FLUID, PE-
used as lubricants in spark-ignition and compression- TROLEUM BASE, HIGH
ignition types of reciprocating internal combus- TEMPERATURE, FLIGHT
tion engines. VEHICLE
b. Usable temperatures: The operating tempera-
ture ranges are not specified.
(NATO Symbol: None)
c. Chemical composition: The finished oil may be
a. General characteristics:This hydraulic fluid is a
a petroleum base of a synthetically prepared product,
petroleum or synthetic hydrocarbon base fluid contain-
or a combination thereof, with or without additives.
ing specified additives. The finished fluid has good
However, no re-refined components are permitted.
thermal and electrical properties and a viscosity index
d. Uses: The oil is a crankcase oil for diesel or
of 89 (min).
spark-ignition type internal combustion engines. Al-
b. Usable temperatures: The operating tempera-
though intended principally as a static preservative,
ture range is-40" to 550F.
this oil may be used as an operating lubricant for short
c. Chemical composition: This liquid is a pe-
periods, and for some hydraulic equipment. It is com-
troleum or synthetic hydrocarbon base fluid with speci-
patible with other fluids to this specification and MIL-
fied amounts of hindered bisphenol oxidation inhibitor
L-2 104.
and tricresyl phosphate antiwear additives.
e. Limitations: This oil is not for low temperature
d. Uses:This fluid can be used in high temperature
usage and not generally for gear box applications.
hydraulic systems, principally for flight vehicles.
f. Custodians: Army-MR
e. Limitations: The fluid is not suitable or recom-
Navy-SH
mended for extreme low temperature operation. Also,
Air Force-1 1
this fluid is not compatible with any other hydraulic
MIL-F-25598(USAF): OIL, HYDRA ULIC, MISSILE, fluids except those meeting this specification.
PETROLEUM BASE f. Custodian: Air Force- 1 1
(NATO Symbol: None)
a. General characteristics: This specification cov- MIL-L-45199A: L UBRICA TING OIL, INTERNAL
ers a low viscosity hydraulic oil for light or medium
COMBUSTION ENGINE, HIGH
duty applications at low temperatures. It has a pour
OUTPUT DIESEL
point of -90F and a viscosity of 600 cSt at -65F. It is
dyed purple for identification purposes. (NATO Symbol: None)
b. Usable temperatures: No specified requirement a. General characteristics: This specification cov-
but intended for temperatures -65F to +20O0F. ers a multi-grade heavy duty crankcase engine oil with
c. Chemical composition: This liquid is a pe- a pour point as low as-20F.
troleum base oil containing approved additives to meet b. Usable temperatures: The operating tempera-
specification requirements for oxidation, corrosion and ture range is not specified.
wear (tricresyl phosphate, 0.5 percent by weight, an- c. Chemical composition: This liquid is a pe-
tiwear agent). No pour point depressant shall be used. troleum base oil or synthetically prepared product, or
4-26
AMCP 706-123
PROPERTIES VALUES
Color : NR
Speci f i c Gravity : NR
Pour Point, OF ( M a x ) : Grade 1 -20
Grade 2 0
Grade 3 c15
Stable Pour Point, OF (Max): Grade 1 only -20
Flash Point, OF (Min): Grade 1 360
Grade 2 390
Grade 3 400
Viscosity, cSt: Grade 1 2,61415.44-7.29
(Visc, OOF ( M ~ x ) / Grade 2 43,570/9.65-12.98
Visc, 210'F) Grade 3 NR/16.83-22.75
Viscosity Index: Grade 3 only 75
V o l a t i l e Matter: (4 h r steam bath); $ w t 2.0
Additives : Allowed
Corr. R o t . : 200 h r , high-humidity; Corr. Trace Only
(Bare S t e e l , 77OF) s a l t water dip, 20 h r dry; $ Corr. Trace Only
Acid Neut.: 7iF, acid s o l . dip, 4 h r i n o i l ; $ Corr. No Corrosion
Oxid. C h a r a c t e r i s t i c s : ( f e r r o u s and nonferrous engine
Parts 1 Noncorrosive
Compatibility: M I L L-2104
Foaming: 75'F, a f t e r 5.0 min blowing, ml ( M a x ) NO l i m i t
75"F, a f t e r 10.0 min s e t t l i n g , m l (Max) 300
200F, a f t e r 5.0 min blowing, ml ( M a x ) No l i m i t
200F, a f t e r 10.0 min s e t t l i n g , m l ( M a x ) 25
?5'F, Repeat 75'F ,Test Same 85 i n i t . 75" Test
Water Content: $ -c
Notes: M, no requirements.
--,no information.
Use: Light, medium, and heavy p r e s e r v a t i v e lub and p r e s e r v a t i v e o i l for r e c i p r o c a t i n g
i n t e r n a l combustion engines.
4-27
AMCP 706-1 23
PROPERTIES VALUES
Color: NR
S p e c i f i c Gravity: NR - Report
Pour Point, OF (Max) : -65
Flash Point, OF (Min) : 360
Viscosity, cSt: -65'F Report
-40'F (Max) 4,000
OF (Max) 385
210'F (Min) 3.2
550'F (Min) Report
Viscosity Index: (Min) 89
Neutralization No. : mg KOH/g (Max) 0.20
Additives, $ w t : Antiwear ( t r i c r e s y l phosphate) (Max) 1.0
Oxidation I n h i b i t o r s (bis-phenol) 0.45 -
1.0
Others Approval Re q 'd
Corr. and Oxid. S t a b i l i t y : Copper 0.60
40 h r a t 347'F Type 350 S t . S t e e l 0.20
Max w t Chg, Type 355 S t . S t e e l 0.20
w/m2 Type 440 S t . S t e e l 0.20
Silver 0.20
$ Visc. Chg. a t lOO'F -5 t o +20
Neutralization No. (Max) 2.0
Insoluble M a t ' l $ w t (Max) 0.1
Thermal S t a b i l i t y : M-10 Tool S t e e l 0.10
6 hr a t 700F, 52100 S t e e l 0.10
20 p s i g Nitrogen Naval Bronze 0.10
atmosphere, $ Visc Chg a t lOO'F (Max) 25
Neutral. No. ( M a x ) 0.40
Rubber Swell ( S y n ) : Viton A o r B; 72 h r a t 400F, $ Vol. +10.0 (Max)
Lubricity; ( S h e l l 4-Ball T e s t e r ) : 1 kg load 0.21
1.0 h r a t 600 rpm, 167OF, 10 kg load 0.30
52100 S t e e l Max Scar Dia mm 40 kg load 0.65
S o l i d P a r t i c l e s : Time t o f i l t e r 100 ml, min (Max) 10.0
( 0 . 4 5 Micron f i l t e r ) Max P a r t i c l e on f i l t e r (Micron) 100.0
Compatibility: All f l u i d s t o t h i s Spec.
Foaming: 75'F, a f t e r 5.0 min blowing, ml (Max) 75
75'F, a f t e r 3 . 0 min s e t t l i n g , ml (Max) None
200F a f t e r 5.0 min blowing, ml (Max) 75
200'F a f t e r 3.0 min s e t t l i n g , ml (Max) None
Repeat 75.F Test Same a s i n i t . 75' Test
Water Content: $ ( M W ) 0.10
Trace Sediment: $ Vol (Max) 0.025
D i e l e c t r i c Strength: ( v o l t / m i l ) , 68'F; (Min) 3 00
S p e c i f i c Heat: (Btu/lb OF) a t 200'F (Min) 0.484
Thermal Cond.: (Btu/( f t 2 ) ( h r ) ( ' F ) / f t a t 400F (Min) 0.063
Thermal Expansion/"F: a t 400'F (Max) 0.00060
Bulk Mod. : (isothermal secant, 0-104 p s i , 100F), p s i > 200,000
Recommended Temperature Range, O F : -40 t o 6 5 0
Storage S t a b i l i t y : NR
4-29
AMCP 706-123
P3.OPER'?IJ?S VALLT S
olor: NR
p e c i f i c Gravity: NR - Report
our Point, OF ( M a x ) : Grade 10 -20
Grade 30 0
Grade 50 NF
t a b l e Pour Point, OF (Max) : Grade 10 (only) -20
l a s h Point, OF (Min) : Grade 10 360
Grade 30 390
Grade 50 NP
i s c o s i t y , c s t : O'F; Grade 10 (MKK) 2,614
0F; Grade 30 (Max) 43,570
O'F; Grade 50 (Max) NP
210'F; Grade 10 5.44-7.29
210F; Grade 30 9.65-12.98
210F; Grade 50 NF
dditives: Allowed (No r e r e f i n e d )
xid. C h a r a c t e r i s t i c s : ( f e r r o u s end nonferrous engine
parts) No Corrosion
ow Temperature Deposit: 180 h r low temp Cycle NR
i n g Stick: 120 hr engine t e s t No S t i c k , Min. Wear
ight-load deposit accumulation: 120 hr engine t e s t NR
owning: 75'F, a f t e r 5.0 min blowing, m l (Max) No L i m i t
75'F, after 10.0 min s e t t l i n g , m l (Max) 300
200'F a f t e r 5.0 min blowing, m l (Max) No L i m i t
200'F a f t e r 10.0 min s e t t l i n g , ml (Max) 25
Repeat 75'F Test Same as i n i t . 75'F Test
il Additive S t a b i l i t y : No Additive I n s t a b i l i t y
torage Stability: --
ompat i b i l i t y : A l l O i l s t o Spec.
ecormuended Temperature Range, OF: Above -20
AT0 symbol: None
4-30
AMCP 706-123
combination thereof, with additive materials (deter- b. Usable temperatures: The operating tempera-
gents, dispersants, oxidation inhibitors, etc.) necessary ture range is not specified, but the oiI or oil-water va-
to meet the requirements of this specification. No re- pors shall be capable of protecting parts from corrosion
refined components are allowed. throughout a temperature range of +W to +130"F.
d. Uses: This liquid is for crankcase lubrication of c. Chemical composition:This oil is a volatile cor-
high output supercharged and unsupercharged diesel rosion inhibited, petroleum base oil containing addi-
engines under all conditions of service at ambient tem- tives necessary to meet specification requirements. The
peratures above-20F. oil shall contain no ingredients injurious to personnel
e. Limitations: This liquid is not for use at low using reasonable safety precautions and must be free
temperature conditions. It is compatible with all oils from disagreeable or offensive odors.
qualified to this specification. d. Uses:This oil is intended for use in the preserva-
f. Custodians: Army-MR tion of enclosed systems where the volatile components
Nav y-SH will provide protection above the oil level. It is also
Air Force-67 effective as a contact preservative.
e. Limitations:The oil is not intended for use as an
MIL-H-46001A: HYDRAULICFLUID,PETROLEUM operational preservative oil and should not be used in
BASE FOR MACHINE TOOLS, applications where magnesium, cadmium-plated or
TYPES I, II, III, AND IV rubber components are' present. Generally, it should
(NATO Symbol: None) not be mixed with other oils to same specification due
a. General characteristics: This liquid is a multi- to wide product tolerances.
grade refined petroleum hydrocarbon hydraulic fluid f. Custodian: Army-MR
containing additives. It has a viscosity range of 30 to
121 cSt at l W F , and a minimum viscosity index of 80.
b. Usable temperatures: The operating tempera- MIL-H-46004(0RD):HYDRA ULIC FLUID, PETRO-
ture range is not_specified, but ambient temperatures LEUM BASE, MISSILE
should be above +20"F.
(NATO Symbol: None)
c. Chemical composition:The finished liquid shall
a. General characteristics: This specification cov-
be a petroleum base fluid containing additives neces-
ers a low viscosity liquid containing approved additives
sary to meet the requirements of this specification-i.e.,
for low temperature missile applications. It has a vis-
oxidation, corrosion, foam, flash, etc.
cosity of 300 cSt at-65"F and a pour point of-75F. The
d. Uses:This liquid is primarily for use in hydrau-
liquid is dyed yellow for identification purposes.
lic systems of metalworking machine tools. The selec-
b. Usable temperatures: The operating tempera-
tion of the particular type of liquid is based on fluid
ture range is not specified.
viscosity recommendations of machine tool manufac-
c. Chemical composition: This liquid is a refined
turers. The finished liquid shall be compatible with
petroleum base liquid with additives to improve oxida-
other liquids meeting this specification.
tion resistance and wear (tricresyl phosphate, 0.5 5 0.1
e. Limitations: This liquid is not suitable for low percent by weight as the antiwear agent). The finished
temperatures, and ambient temperatures should be product shall contain no pour point depressants, vis-
above +20"F. cosity index improvers, admixtures of resins, rubber,
f. Custodians: Army-MR
soaps, gums, fatty oils, oxidized hydrocarbons, nor
Navy-SA
other additives not specifically approved.
Air Force-11
d. Uses: This liquid is designed for use in missile
MIL-L-46002(0RD): LUBRICATING OIL, CON- hydraulic systems applications at ambient tempera-
tures below 20F.
TACTAND VOLATILE, COR -
e. Limitations: This liquid is not for high tempera-
R OSION INHIBITED
ture or high load applications. It is not interchangeable
(NATO Symbol: None) with Hydraulic Fluid, Castor Oil Base (blue color),
a. General characteristics: This oil is a dual grade Specification MIL-H-7844. This liquid shall not be
volatile corrosion inhibited lubricating oil for preserva- mixed with, but may be substituted for, Hydraulic
tion of material in enclosed systems. Light and medium Fluid, Petroleum Base, Specification MIL-H-5606B,
viscosity oils are available with pour points of -50F for low temperature operation.
and -10F. f. Custodian: Army-MR
4-3 1
AMCP 706-123
~~ ~~
MIL-H-4600lA: HYDRAULIC F L U I D , PEl!RoLEXM BASE, FOR MACHINE TOOLS, TYPES I, 11, 111, AND I V
PROPEHPIES VALUES
Color: NR
S p e c i f i c Gravity: NR
Pour m i n t , OF (Max) : Type I +10
Type I1 +10
Type I11 +10
Type I V +2 0
Flash Foint , OF (Min) : Type I ,325
Type I1 325
Type 111 350
Type I V 375
Viscosity, cSt: lOOOF Type I 30-37
Type I1 42 -52
Type I11 62-70
Type I V 106-l21
Viscosity Index: (Min) 80
Neutralization No.: mg KOH/g (Max) 0.20
Additives: Approval Req'd
Oxidation S t a b i l i t y : Bare S t e e l S t r i p 0.20
168 h r a t 212'F Copper S t r i p 0.20
Max w t Chg, P i t t i n g , Etch and Corr. a t 20X None
w/m2 $ Visc. Chg a t LOOOF (Max) 25.0
Neutral. No. Chg (Max) +O .15
P r e c i p i t a t i o n N O . ax) 0.05
Insoluble Mat'l o r Gumming None
Compatibility : All Fluids t o This Spec,
Water Content: None
Foaming: 75'F, a f t e r 5.0 min blowing, m l ( M a x ) No l i m i t
75'F, a f t e r 10.0 min s e t t l i n g , m l (Max) 100
200F,after 5.0 min blowing, m l (Max) No l i m i t
200 OF, a f t e r 10.0 min s e t t l i n g , m l (Max) 25
Repeat 75'F t e s t Same as i n i t . 75'F Test
Emulsion: After 30 min s e t t l i n g ; foam o r cuff (Max) 3.0 m l
( O i l and Water, 130F, 5 . 0 min s t i r , 30 min s e t t l i n g ) Trace
Copper Corr. : 168 h r a t 212'F No P i t o r Etch
Rust Prevention: ( b a r e s t e e l ) , 24 h r a t 130'F None
Recommended Temperature Range , F : NR
NATO Symbol: None
Storage S t a b i l i t y : NR
4-32
AMCP 706-123
PROPEIPCIES VALUES
Color: NR
Specific Gravity: m
our Point, "F (MU): Grade 1 -5 0
Grade 2 -10
Flash FQint, OF (Min): Grade 1 240
Grade 2 250
Viscosity, cSt: -40'F ( M a x ) Grade 1 10,000
-40'F (Max) Grade 2 NR
lOO'F (Min) Grade 1 12
100F (Min) Grade 2 95 t o 125
210F Grede 1 NR
210F Grade 2 9.65 t o 12.98
Precipitation N O . : m1/10 m l ax) 0.05
Hydrocarbon Solubility: 24 hr a t 77'F No Separation
Corrosive Protection: Humidity Cabinet, 300 h r a t 120'F No Corrosion
Vapor Phase; 6 hr a t 40'F
and 18 hr a t 130F No Corrosion
Vapor Phase Prot. a f t e r exhaustion;
6 hr a t 210F No Corrosion
Acid Neut.: 7 7 O ~ , acid sol. dip, 4 hr i n o i l ; $J C O r r . No Corrosion
Water Displacement/Stability: 1.0 hr a t 77OF No Corrosion
Corrosion Inrmersion: Aluminum 0.20
7 days a t 130'F Steel 0.50
MS w t mg; %/em2 Copper 1.50
Evaporation: $ w t Volatile matter (Max), Grade 1 15.0
(210'F) $ w t Volatile matter (Max), Grade 2 5.0
$ Vise, Chg a t 100F, Grade 1 -5 t o +20
$J Vise, Chg a t 100F, Grade 2 -5 t o +20
NATO Symbol: None
Storage S t a b i l i t y : --
Recommended Temperature Range , OF : up t o I30
Compatibility: Not Interchangeable
4-33
Next Page
AMCP 706-1 23
~~
PRODERTIES VALUES
4-34
AMCP 706-123
CHAPTER 5
ADDITIVES
ROOH
2ROOH
-
additional radicals:
- RO- + HO.
RO- + R O O + H20
thylamine-are very effective.
5-2.2.2 Free Radical Acceptors Ester fluids can be inhibited against oxidation to at
least 212F (100C) with 0.1 to 0.2 percent of the usual
Amines and phenols are most commonly used as free phenolic and aromatic amine antioxidants (Ref. 4)
radical acceptors and are effective in many base stocks. which are also commonly used in petroleum oils.
5-2
AMCP 706-123
A number of inhibitors have been examined for use 5-2.3.3 Silicon-containing Fluids
with esters at higher temperatures. Phenothiazine and
its derivatives are usually effective to 350F (175C) but Diarylamines are effective antioxidants in siloxanes
lacquer formation has been observed at 325F(163C). at 400F (205C) but cause sludging. At that tempera-
Phenyl- 1-naphthylamine is the most effective of the ture, phenolic antioxidants are ineffective and selenides
aromatic amines and has an upper temperature limit cause severe copper corrosion. When a sufficiently high
of 325F (16$C). n-alkyl selenides are effective at degree of nuclear alkylation is introduced into the
325F (163"C), but the analogous sulfur compounds structure of the diarylamines, sludge formation can be
have an upper temperature limit of 257F (125C). avoided (Ref. 9).
Phosphites, which are effective -to 212"-257"F(100"- Chlorophenylsilicones have been reported to be ade-
125"C), are limited by their hydrolytic susceptibility quately stabilized at 500F (2WC) against oxidation
and volatility. Except for serious copper corrosion at with iron octoate (Ref. 10). Aromatic compounds con-
325F (163"C), 4-[err-butylphenyl-2-mercaptothiazole taining three or more ring systems, for example 1,2-
provides adequate inhibition. The zinc complex of di- benzanthracene and pyrene, are also effective in retard-
butyldithiocarbamate and dibutylamine functions satis- ing the oxidation of a chlorophenylsilicone (Ref. 11).
factorily at 302 "F (150C) (Ref. 5). Silane fluids have been found to be not susceptible to
improvement with oxidation inhibitors (Ref. 11).
Phenothiazine substantially extends the induction The presence of trace metals can have a profound
period at 350"-400"F (175"-205"C)and reduces the rate effect on the oxidative stability of polydimethylsilox-
of oxidation at 500F (375C). However, at the higher anes and polymethylphenylsiloxanes (Refs. 12, 13). At
temperature, phenothiazine, as well as other amine in- 392F (200C) lead selenium and tellurium accelerate
hibitors, causes darkening and the formation of trace oxidation. Organic selenides, aromatic amines, and
dirtiness in the liquids (Ref. 1). phenothiazine prolong the life of silicone oils two to
five times, but the life of the oils can be extended to
At 425" and 500F (218" and 260"C), the most effec- eight times with the use of iron or copper chelates of
tive selenides for inhibiting oxidation are pamino- disalicylalethylenediamine or disalicylalpropylenedia-
phenyl phenyl selenide, 5-dimethylaminobenz0(2,1,3) mine, the solubilized metal acting as an inhibitor. The
selenadiazole, and diphenyl diselenide. The selenides use of this inhibitor in poorly ventilated systems under
have been found to be corrosive to copper, silver, oxygen-deficient conditions, however, leads to the
magnesium, and aluminum at selenium concentrations precipitation of the metal as the reduced metal oxide.
of 0.5 percent (Ref. 6). Cerium complexes have been found not to be subject to
5-ethyl- 10,lO- diphenylphenazasiline (5- 10- 10) is this limitation (Ref. 14). New processes have been
useful in inhibiting ester base stocks at 400"-500"F developed for modifying silicone oils with cerium com-
(205"-260C). Since a certain thermal level is required plexes that raise the stabilization temperature from 617"
to activate 5-10-10 as an antioxidant, it is best used in to 752F (325" to 400C) (Ref. 15).
combination with a low temperature antioxidant. Mix-
tures of 5-10-10 and phenyl-1-naphthylamine are effec-
tive (Ref. 7). 5-2.3.4 Ethers
(260C) in fluorocarbon polyether liquids but lead to compounds are less soluble in oils but have a greater
corrosion of ferrous and titanium alloys. Solubility and tendency to adsorb on a metal surface and are, there-
volatility remain problems in the use of these additives fore, more effective as rust inhibitors. These closely
(Refs. 19-21). packed films prevent the penetration of water.
Salts or soaps of high molecular weight carboxylic
acids-such as naphthenates or sulfonic acids, particu-
5-3 CORROSION INHIBITORS larly the petroleum mahogany sulfonic acids-are useful
and inexpensive additives for lubricant compositions.
These soaps, dispersed in nonpolar solvents, form col-
5-3.1 DEFINITIONS loidal systems. The soaps are adsorbed on the metal
surfaces and are in equilibrium with low concentrations
Corrosion is the deterioration through chemical of soaps in solution, which, in turn are in equilibrium
change of a metal into one or more of its oxides, hy- with the soaps in the colloidal micelle. Although the
drated oxides, carboxylates, fluorides, carbonates, or complex equilibria are not fully understood, considera-
other compounds. The special case of the deterioration tion of the system as one in equilibrium allows the
of iron or steel by moist air (oxygen) is called rusting. explanation of some of the phenomena associated with
Rusting cannot occur in systems from which oxygen is the use of these rust inhibitors. These effects include
rigorously excluded. Corrosion of metal components in temperature range limitations in the use of the inhibi-
contact with a hydraulic fluid may occur through the tors, mechanical removal and rehealing of coated sur-
action of water and air present in the system, through faces, leaching of the inhibitor from solution with wa-
the action of lubricant decomposition products, or by ter, and depletion of the adsorbed layers by dilution
direct chemical action of the fluid on the metal surface. with hydraulic fluids not containing the inhibitor.
A corrosion inhibitor is an additive that prevents or The colloid soap micelle also serves as a sink for
decreases corrosive attack on metals. Although its corrosive acids that are formed as products of oxida-
function may be one of directly protecting the metal tion. Sequestration of corrosive acids by the soap mi-
surface, an additive may function as a corrosion inhibi- celles offers an explanation why the soaps are better
tor if it interferes with any of the processes that ulti- inhibitors than the corresponding acids. The combina-
mately culminate in corrosion. For this reason, the tion of the soap micelle with the corrosive acids may
processes of inhibiting corrosion and oxidation are inti- occur through cooperative micelle formation or
mately related. through hydrogen bonding.
Not only do oxidation products cause corrosion, but
corrosion products may promote oxidation. The inter-
dependence of oxidation and corrosion inhibitors can 5-3.3 LIMITATIONS IN THE USE OF RUST
be illustrated as follows. An antioxidant that retards INHIBITORS
the auto-oxidation of a fluid will prevent the formation Since the most effective rust inhibitors have low
of corrosive acids. Amine antioxidants can react with solubilities in the base oils, precipitation during storage
and neutralize certain acidic materials, but aromatic may occur when inhibitor concentrations exceed 0.5 to
amines do not effectively neutralize carboxylic acid, a 1.0 percent. Precipitation will be accelerated at low
common corrosive oxidation product. In many screen- temperatures because inhibitor solubility decreases
ing tests for hydraulic fluids and lubricants, oxidation with decreasing temperature. Compounded lubricants
and corrosion are considered concurrently. may suffer significant losses in their ability to inhibit
rusting after six months storage because of the precipi-
tation of the inhibitor. Inhibitor insolubility is fre-
5-3.2 MODE OF ACTION OF RUST quently evident by the development of a haze in
INHIBITORS the oils.
The varying solubility of an inhibitor in different
Rust inhibitors are effective through the formation of base fluids results in corresponding differences in in-
closely packed hydrophobic monomolecular layers on hibitor effectiveness. For example, the minimum con-
the surface of the ferrous metal to be protected (Refs. centration of undecyclic acid required for inhibiting a
22-27). Most organic molecules with an adsorbable po- petroleum fluid is 0.20 percent, while 0.75 percent of
lar group attached to a hydrophobic chain are effective the same acid is required for di-2-ethylhexyl sebacate,
rust inhibitors. The higher molecular weight polar 1.00 percent for a polyalkylene glycol, and 0.20 and
5-4
AMCP 706-1 23
0.50 percent for two silicone fluids (Ref. 22). When with maleic anhydride-are also effective rust preven-
large concentrations of an additive are required, less tive additives (Ref. 30).
soluble inhibitors should be sought in order to reduce Impurities present in an additive may have an ad-
the concentration required for minimum protection. verse effect on a hydraulic system. When concentra-
Because molecular agitation in a liquid increases as tions of inorganic salts such as calcium chloride or
temperature increases, the solubility of the additive calcium sulfate are present in concentrations as great as
and, therefore, its tendency for desorption from the 0.12 percent in a mahogany sulfonate, corrosion due to
metal surface will be increased with temperature. galvanic action may occur (Ref. 31).
Stated differently, raising the temperature of the oil When inhibitors are selected to prevent corrosion,
increases the minimum concentration of the additive the identity of the specific metal-liquid system must be
necessary to achieve adequate protection. Usually, a considered since an additive that protects iron may
temperature is reached above which a rust inhibiting itself corrode copper or silver. An example of the need
additive is not effective at any concentration. The max- for a specific inhibitor for a particular system is evident
imum temperature for the complete inhibition of rust- in recent work with fluorocarbon polyether fluids
ing for several acids in a petroleum oil increases in the which have proved corrosive to ferrous and titanium
following order: linoleic, 115'F; undecylic, 140F; my- alloys in oxidizing atmospheres at 500F. Per-
ristic, 165F;and stearic, 190F (Ref. 22). The solubili- fluoroarylphosphines and phosphine oxides used as ad-
ties of the additives in the oil decrease in the ditives prevent degradation of the fluorocarbon fluids
same order. and the consequent metal corrosion under these condi-
The adsorbed monolayers can be ruptured by abra- tions up to 650F (Refs. 20, 21).
sion or wear and leave areas vulnerable to corrosion. If Different classes of inhibitors must be used in polar
sufficient inhibitor is present in the hydraulic fluid, it fluids in which water is either a part of the composition
will be readsorbed in the scuffed location. The rate of or soluble to some extent in the fluid. For example, 0.2
repair will be greater the less viscous the oil. percent of sodium nitrite and 0.8 percent of disodium
The presence of water as a contaminant in a hydrau- phosphate dodecahydrate function as corrosion inhibi-
lic system may result in the leaching of the tors in glycerol-water hydraulic fluids containing 40
monomolecular layer from the surface of the metal or percent glycerol (Ref. 32).
the inhibitor from the hydraulic fluid. The polar nature For inhibiting corrosion of tin, steel, aluminum, cast
of most inhibitors allows some solubility in water, iron, brass, and cppper-in contact with ethylene glycol
which results in the leaching, even though the solubility and 1,Zpropylene glycol-the following combinations
may be small. have proved satisfactory: 0.5 percent borax and 0.5
Since the adsorbed monolayer is in equilibrium with percent hydroquinone; 0.5 percent triethanolamine and
the inhibitor in solution, addition of make-up fluid con- 0.5 percent potassium hydroxide; and 0.5 percent 1,5-
taining no inhibitor to a hydraulic fluid system may dihydroxynapththalene and 0.5 percent potassium hy-
ultimately result in the desorption of the monolayer droxide. The most satisfactory inhibitors for systems
and loss of rust inhibiting properties. Monolayers of containing n-butanol are 0.5 percent hydroquinone
compounds, having rust inhibiting properties, on met- with 0.5 percent potassium mercaptobenzothiazole
als can usually be removed by exhaustively washing the (Ref. 33).
surfaces with solvents.
5-3.5 VOLATILE CORROSION INHIBITORS
5-3.4 EXAMPLES OF RUST AND
CORROSION INHIBITORS The polar rust inhibiting compounds described in
par. 5-3.4 are effective only on ferrous surfaces con-
Many classes of compounds are effective as rust in- tacted by the hydraulic fluid. Corrosion and rust in
hibitors, namely: sodium and barium mahogany sul- other parts of the system can be inhibited through the
fonates; carboxylates, including sorbitan mono-oleate; use of volatile corrosion inhibitors which readily sub-
and a variety of other compounds (Ref. 22). Hydrox- lime at ordinary temperatures and deposit a monolayer
yarylstearic acids have been found to function both as on exposed metal surfaces. These inhibitors are often
oxidation and rust inhibitors (Refs. 28, 29). Nitrogen water soluble and can be washed from the surface with
compounds-such as amines or amides, certain phos- water. Although this technique of corrosion inhibition
phorus compounds (especially esters of phosphorus is most frequently used in connection with packaging
acids) and dicarboxylic acids made by reacting olefins (Ref. 34), aqueous hydraulic fluids can be inhibited in
5-5
AMCP 706-123
both the liquid and vapor phase with diisopropylam- loss, has been offered in order to differentiate the
monium nitrite (Ref. 35). effect from the same effect which may result from
thixotropic viscosity loss of mineral oils below their
cloud point (Ref. 37). Also, under high shear stress the
5-4 VISCOSITY INDEX IMPROVERS polymer chains may be ruptured with a consequent
permanent loss in viscosity of polymer-thickened oils.
This change, which is not a depolymerization, is more
5-4.1 MODE OF ACTION pronounced in blends that contain high molecular
weight, or more viscous polymers. Lower molecular
The addition of certain polymers to a hydraulic oil weight polymers are less susceptible to permanent vis-
will increase the viscosity of the oil throughout its use- cosity loss.
ful temperature range and improve its viscosity-tem- The term shear stability, encompassesboth effects,
perature relationship. The contribution of a polymer to temporary and permanent viscosity loss. Laboratory
the viscosity of a polymer-oil blend is related directly methods for producing accelerated shearing of polymer-
to the effective hydrodynamic volume of the polymer. thickened oils have included a mechanical pump
The hydrodynamic volume of the polymer, in turn, is loop in which a pump recycles the fluid through an
related to the degree of solvation of the polymer by the orifice, and a sonic oscillator test method. Since the
base oil (Ref. 36). Higher temperatures favor better latter technique offers some advantages over pump
solubility of the polymer in the oil hence better solva- loop tests, an ASTM Sonic Shear Method has been
tion and an expanded macromolecule. Lower tem- proposed (Ref. 39). In studies of the sonic shear test, it
peratures favor contraction of the macromolecule, or has been found that shear breakdown of the polyisobu-
stated differently, the formation of a convoluted spe- tylenes could be blocked by water contamination, but
cies. In this way, the effective contribution of the that the shear stability of polymethacrylates was not
polymer to the viscosity of the polymer-oil blend is significantly affected under similar conditions (Ref.
greater at higher temperatures. Not all polymers differ 40). The shear stability of polymethacrylates and
in their contribution to viscosity at different tempera- polyisobutylenes varies inversely with their ability to
tures, but nonetheless they may be referred to as V.I. improve the viscosity index (Ref. 41). The ability of an
improvers owing to the inconsistenciesof the Dean and additive to improve the viscosity index decreases with
Davis viscosity-index system (Ref. 37). applied shear stress (Ref. 42).
The thickening power of a polymer increases as the
molecular weight increases and, consequently, as its Sources of high energy other than shear can also
effective hydrodynamic volume increases. The thicken- induce degradation of polymer thickeners. These
ing power is usually proportional to the molecular sources include high temperatures, ultrasonic degrada-
weight to the 0.5 to 0.8 power (Ref. 38). tion, and gamma irradiation (Ref. 43).
A final limitation in the use of polymeric materials
is their solubility in the base fluid and the compatibility
5-4.2 LIMITATIONS of compounded fluids with possible contaminants.
Thus, the polymethacrylates have an advantage
In order to maintain a specified viscosity in a hydrau- as V. I. improvers in diester fluids in that the
lic fluid at a given temperature, a lower viscosity and additives are not precipitated when the hydraulic fluid
therefore more volatile base fluid must be compounded is accidentally contaminated by petroleum oils or the
with a polymer thickener because the effect of the addi- common volatile solvents used to clean hydraulic sys-
tive is to increase the viscosity at all temperatures. In tems (Ref. 4).
applications where low volatility and low viscosity are
required, the use of polymer thickeners will be limited.
A second limitation in the use of V.1. improvers is 5-4.3 EXAMPLES OF EFFECTIVE POLYMERS
their susceptibility to shear. In a hydraulic fluid-
polymer blend, the extended polymer coil may become The two classes of polymeric thickeners that have
oriented under high shear stress with a consequent loss achieved the greatest commercial importance are the
in viscosity. Since the original polymer configuration polyisobutylenes and the polymethacrylate esters (Ref.
reforms when the shear force is removed, the term 30). The effectiveness of each depends both on the na-
temporary viscosity loss has been applied to this phe- ture of the base fluid, and the particular composition
nomenon. An alternate term, orientation viscosity and molecular weight of the polymer. Another class of
5-6
AMCP 706-123
useful polymers is that of various paraffinic resins (Ref. Synthetic fluids that are a single chemical compound
44). Many classes of polymers-including cellulose es- cannot foatn because no impurities are present; how-
ters and ethers, polyvinyl alcohols, polyvinyl acetate, ever, even highly refined petroleum fluids have the in-
polyvinyl acetal, coumarone-indene resins, polysty- herent capability of foaming because they are mixtures.
renes, polybutenes, and polyacrylic esters-have been Problems with foam are more likely to arise when polar
examined as potential V.I. improvers and have been impurities are present. In addition to direct contamina-
found effective. tion, these polar impurities can come from any of sev-
In synthetic base stocks, a particular thickener must eral sources. Accumulated acidic oxidation products or
be sought which is effective with the system. The the addition of additives may cause foaming. For exam-
polymethacrylate esters are most effective with diester ple, rust inhibitors frequently contain polar groups and
fluids (Ref. 4); various polydimethylsiloxanes and are potential foam stabilizers. A secondary effect is that
polymethylphenylsiloxanes have been examined for use the possibility of inhibiting foaming may be diminished
with silicate and disiloxane fluids (Refs. 9, 45, 46); and by the presence of other additives. Thus, an antifoam
polyaryl ethers have been considered as V.I. improvers additive is less effective in a polymer-containing liquid
for aryl ether fluids, but they increase the already mar- than in one that does not contain a polymeric additive
ginally acceptable pour points (Ref. 47). (Ref. 51).
The amount of a polymer required to blend fluids of The foaming characteristics of a liquid can depend
a required viscosity, viscosity index, and mechanical on a number of operating characteristics, as well as the
stability from a particular base stock is related to the system design. Temperature, primarily because of its
polymer molecular weight (Ref. 48). Blending charts effect on viscosity, is also an important factor in foam
have been developed that allow the prediction of the stability. Since the collapse of the entrained air can
viscosity of an oil-polymer blend from the polymer depend in part on the ability of the liquid to flow into
molecular weight, polymer concentration, and the vis- the void, a lower viscosity would favor control of foam.
cosity of the base oil (Ref. 49). Although liquids decrease in viscosity with increases in
temperature, foaming at higher temperature can be a
serious problem because of the large coefficient of ther-
5-5 FOAM INHIBITORS, mal expansion of vapors relative to liquids. Thus, it is
EMULSIFIERS, AND reported that, at higher temperatures, foams are more
difficult to control in lower-viscosity mineral oils and
DEMULSIFIERS synthetic hydrocarbons than in high-viscosity materi-
als (Ref. 1).
Additives useful as foam inhibitors, emulsifiers, and Several side effects can be observed in connection
demulsifiers have in common their ability to modify with foaming. Foaming of an oxidation-susceptible
(increase or decrease) the stability of an interface be- material at a high temperature increases the gas-liquid
tween two phases in a fluid system. Foaming results contact area and time, and consequently the rate at
from the formation of stable gas bubbles in the liquid which oxidation occurs. Although foaming is usually
phase; emulsion occurs with the formation of two sta- associated with air, it may also occur when impurities
ble liquid phases, one dispersed in the other. Foams and are present and the gas phase is the vapor of the fluid,
emulsions are stabilized by the presence of an adsorbed and particularly in regions of a system where the local
film at the interface between the two phases. pressure drops to the vapor pressure of the lubricant.
Since these are the same conditions that lead to cavita-
tion, the two phenomena are related, and a foam inhibi-
tor may well serve as a cavitation inhibitor.
5-5.1 CHARACTERISTICS OF FOAMS AND
THE MODE OF FOAM INHIBITION
5-5.2 EXAMPLES OF FOAM INHIBITORS
The mechanism of foam inhibition is frequently
thought to involve changes in the interfacial tension
between the liquid and vapor through changing the Methyl silicone oils, for example those with viscosi-
concentration of polar impurities in the region of the ties in the range of 50,000 cSt at 100F (37C), are
vapor bubble. A number of other theories on the stabil- effective foam inhibitors at the remarkably low concen-
ity of foams and the inhibition of foams have been trations of 10 ppm. They are generally considered as
reviewed by Zuidema (Ref. 50). insoluble inhibitors since they must be present in an
5-7
AMCP 706-123
5-8
AMCP 706-123
and the metal by adsorption of the acid portion of the materials. Phosphates and phosphites, particularly
molecule on the metal surface. tricresyl phosphate, have received considerable atten-
tion as additives (Ref. 1). Acid phosphates and even
phosphoric acid show antiwear properties in the proper
5-6.2.2 Antiwear Additives concentration, but too large a concentration of phos-
phoric acid can lead to chemical erosion (Ref. 1). Phos-
Phosphorus-containing additives are usually classed phates and phosphonates containing long alkyl chains
as antiwear additives. Under higher pressures and tem- provide good lubricity and, in addition, function as
peratures, these additives are thought to be effective in antioxidants (Ref. 58). The effectiveness of tricresyl
reducing wear through their ability to form iron (11) phosphate is reduced in the presence of polar com-
phosphate and its hydrate on the metal surface (Ref. pounds such as petroleum sulfonates, which have a
54). The formation of the iron (11) phosphates has been greater affinity for metal surfaces than does tricresyl
attributed to the presence of polar impurities, perhaps phosphate (Ref. 1). Metal dithiocarbamates function as
acidic hydrolysis products, of the phosphate (Refs. 55- antiwear additives in ester fluids, but not in mineral
57). The most common example of this type of additive oils. Fluorinated esters have been found to be as suscep-
is tricresyl phosphate which is frequently used in con- tible to antiwear additives as nonfluorinated esters
junction with an oiliness agent. (Ref. 59), but many additives are not sufficiently solu-
ble to be used in the fluorinated esters.
5-6.2.3 Extreme-pressure Additives
Extreme-pressure additives are used under the most 5-6.3.2 Additives for Silicon-containing Fluids
severe conditions and are usually sulfurized or chlori-
nated organic materials. Compounds containing benzy- A great many additives that are effective in mineral
lic sulfur are particularly effective. Under conditions of oil and ester fluids are ineffective in silicones, silicates,
extreme pressure or temperature, welding of the two and siloxanes. Silicones show especially poor additive
mating surfaces can occur with consequent seizure, susceptibility for lubricating steel-on-steel. The wear
galling, or scuffing. In a lubricant containing an ex- properties can be improved in ester-siliconeblends, but
treme pressure additive, when high temperatures that such a high proportion of ester is required that the good
can produce welding are approached, the additive pre- high-temperature properties of the silicones are lost
sumably undergoes a chemical reaction with the metal (Ref. 1).
surface to form a metal chloride or sulfide film that Silicon-containing liquids are usually not susceptible
protects the surface. The sulfur-containing additives to modification by antiwear additives. There is evi-
may be used with lead naphthenate to obtain a protec- dence that the silicon reacts preferentially with the
tive lead-sulfide coating. metal to be lubricated, forming a coating on the metal
that is no longer reactive with the antiwear additive.
Silicones and silicates themselves can be used as addi-
5-6.3 CLASSES OF LUBRICITY ADDITIVES
tives in esters and mineral oils to obtain antiwear prop-
Lubricity additives function through their action at erties, a fact which suggests that a soft, inert silicon-
the surface of the metal to be lubricated; therefore, iron alloy is formed (Ref. 1). Some attempts have been
lubrication of different metal combinations may re- made to modify the chemical structures of silicones to
quire the use of different additives. All base stocks are improve their wear properties. Friction and wear
not equally susceptible to additive modification, and studies of chlorinated methylphenyl silicones show an
the effectiveness of antiwear additives can be modified improvement over nonhalogenated methylphenylsili-
by the presence of other additives. For these reasons, cones, but high friction and wear are still observed with
a very large number of compounds and materials have hard steel on soft steel and soft steel on soft steel (Ref.
been investigated as potential boundary lubricants in 60). In addition, the chlorine-modified silicones suffer
hydraulic fluids. a second limitation in being poorer lubricants for steel
on copper above 400F than are unmodified silicones
(Ref. 60). A great improvement in the lubricity of chlo-
5-6.3.1 Additives for Mineral Oils and Esters rinated phenylmethylsilicone was found when the liq-
Ester-based fluids and mineral oils are readily sus- uid was cooked with tin tetrachloride (Ref. 10).
ceptible to additive modification with a variety of. Fluorosilicone fluids are reported to have at least
5-9
AMCP 706-123
equivalent wear performance on the Shell 4-Ball a hydraulic fluid in order to more effectively seal the
Extreme Pressure Tester to di-2-ethylhexyl sebacate system. Certain fluids, however, notably the silicates
(Ref. 61). and siloxanes, are poor rubber solvents but good sol-
A final class of silicon-containingfluids, the tetraalk- vents for rubber plasticizer. The result is that the plasti-
ylsilanes, have better additive susceptibility than the cizer can be extracted from the rubber with consequent
silicones, silicates, or siloxanes. Although tetraalkylsi- shrinking and hardening.
lane base fluids exceed target wear limits, their wear The approach to solving this problem is the addition
properties can be improved with phosphates, phosph- of 5 to 15 percent of compounds to the fluids that can
ites, phosphonates, phosphorothioates, and sulfonated act as rubber plasticizers (Refs. 9, 46, 67). Esters such
petroleum derivatives (Ref. 62). as butyl oleate, di-2-ethylhexyl sebacate, and dibutyl
phthalate, and certain aromatic compounds have been
5-6.3.3 Additives for Aryl Ether Fluids most commonly used in this application. With such
large quantities, the function of the added material is
A variety of additives have proved effective in im- not so much an additive as a modification of the base
parting improved wear properties to poly(pheny1 liquid through blending. In so modifying a liquid, spe-
ethers) (Ref. 16). These additives include bis(cyc1open- cial attention must be given to changes in the physi-
tadieny1)titanium bis(trich1oroacetate)and its polysul- cal properties.
fide derivative, diphenyltin bis(trichloroacetate), bis(-
triphenylphosphine) nickel dichloride, and particularly,
trichloroacetic acid. Tricresyl phosphate at the 5 per-
cent level is also effectivein aryl ethers (Ref. 63). 5-9 HYDROLYTIC INHIBITORS
5-1 1
AMCP 706-123
6. Dueltgen, Lugasch, and Cosgrove, Or- 20. R. E. Dolle, High Temperature Corrosion Pre-
ganosilenium Compounds as High-Tempera- ventive Additives for Fluorocarbon Polyether
ture Antioxidants, Lubrication Engr. 18, 2 18 Fluids, AFML-TR-67-210 (1967).
(1962). 21. R. L. Adamczak, R. J. Benzing, and H.
7. H. W. Adams, Additive Studies in Research Schwenker, Proceedings of the AFML Hydraulic
on High-Temperature Gas-Turbine Lubri- Fluids Conference, AFML-TR-67-369, Decem-
cants, Sci. Lubrication (London) 12, No. 8, 16 ber 1967.
(1960). 22. H. R. Baker and W. A. Zisman, Polar-Type
8. Klaus, Tewksbury, and Fenske, Preparation, Rust Inhibitor - Part I, Ind. Eng. Chem.
Properties, and Some Applications of Super- 40,2338 (1948).
Refined Mineral Oils, ASLE Trans. 5, 115 23. Baker, Jones, and Zisman, Polar-Type Rust
(1962). Inhibitors - Part 11, Ind. Eng. Chem. 41, 137
9. N. W. Furby et al., The Development of High (1949).
Temperature Aircraft Hydraulic Fluids, 24. H. R. Baker and W. A. Zisman, Liquid and
WADC-TR-54-191 (1954). Vapor Corrosion Inhibitors, Lub. Eng. 7, 117
10. Brown, Holdslock, and McGuire, Silicone Fluid (1951).
Researchfor the Development of High-Tempera- 25. C. R. Singleterry and E. M. Solomon, Neutral
ture Hydraulic Fluids and Engine Oils, WADC- and Basic Sulfonates, Ind. Eng. Chem. 46,
TR-56-25, Parts I, 11, and I11 (1956). 1035 (1954).
26. S. Kaufman and C. R. Singleterry, Micelle
11. R. M. Silverstein, Synthesis and Evaluation of
Formation by Sulfonates in a Nonpolar Sol-
High-Temperature Antioxidants for Synthetic
vent, J. Colloid Chem. 10, 139 (1955).
Hydraulic Fluids and Lubricants, WADC-TR-
27. W. D. Bascom, S. Kaufman, and C. R. Single-
58-335, Parts I and I1 (1958).
terry, Colloid Aspects of the Performance of Oil-
12. Murphy, Saunders, and Smith, Thermal and Soluble Soaps as Lubricant Additives, 1959,
Oxidation Stability of Polymethylphenylsilox- Fifth World Petroleum Congress, Section VI,
anes, Ind. Eng. Chem. 42, 2462 (1950). Paper 18, New York (1959).
13. Atkins, Murphy, and Saunders, Polymethyl- 28. Gisser, Messina, and Snead, Hydroxyaryl-
siloxanes-Thermal and Oxidation Stabilities, stearic Acids as Oxidation and Rust Inhibitors
Ind. Eng. Chem. 39, 1395 (1947). in Lubricants, Ind. Eng. Chem. 48, 2001
14. H. R. Baker and C. R. Singleterry, Stabiliza- (1956).
tion of Silicon Lubricating Fluids above 200C 29. Snead, Messina, and Gisser, Structural Effects
by Iron, Copper, Cerium, and Other Metal of Arylstearic Acids as Combination Oxidation
Compounds, J. Eng. Chem. Data 6, 146 and Rust Inhibitors, Ind. Eng. Chem., Prod.
(1961). Res. Dev. 5, 222 (1966).
15. Baker, Kagarise, ORear, and Sniegoski, Sta- 30. R. Hatton, Introduction to Hydraulic Fluids,
bilization of Silicone Lubricating Fluids at 300 Reinhold Publishing Corp., N.Y., 1962.
to 400C by Soluble Cerium Complexes , J. 31. J. Messina and A. Mertwoy, Inorganic Salts in
Chem. Eng. Data 11, 110 (1965). Mahogony Sulfates and Their Effect on Pe-
troleum Hydraulic Fluids, Lub. Eng. 23, 46
16. Brown et al., Research and Development on
(1967).
High-Temperature Additives for Lubricants and
32. D. Wyllie and A. W. Morgan, Prevention of
Hydraulic Fluids, WADC-TR-59-19 1, Parts
Corrosion in Glycerol-Water Hydraulic
I-IV (1959).
Fluids, J. Appl. Chem. (London) 15, 289
17. Smith et al., Research on High- Temperature Ad- (1965); C. A. 63, 9552 (1965).
ditivesfor Lubricants, Office Tech. Serv. Report 33. C. B. Jordan, Study of Corrosion Znhibitors and
AD281, U. S. Dept. Com., 831 (1962). Antioxidants for Alcohols Found in Hydraulic
18. J. R. Stemniski et al., Antioxidants for High- Brake Fluids, Ordnance Project TB5-5010F, D.
Temperature Lubricants, ASLE Trans. 7, 43 A. Project No. 593-21-054, Engineering
(1964). Laboratories Report No. 28, Aberdeen Proving
19. R. E. Dolle and F. J. Harsacky, New High Tem- Ground, Maryland (1955).
perature Additive Systems for PR-143 Fluids, 34. H. R. Baker, Volatile Rust Inhibitors, Ind.
AFML-TR-65-349, January 1966. Eng. Chem. 46,2592 (1954).
5-12
AMCP 706-123
35. J. E. Brophy et al., Aqueous Nonflammable Chem. SOC.,Div. Petroleum Chem. Preprints 7,
Hydraulic Fluids, Ind. Eng. Chem. 43, 884 B-103 (1962).
(1961). 49. W. A. Wright and W. W. Crouse, General
36. T. W. Selby, Non-Newtonian Characteristics Relationships for Polymer-Petroleum Oil
of Lubricating Oils, ASLE Trans. 1,68 (1958). Blends, Ind. Eng. Chem. Prod. Res. and Dev.
37. T. W. Selby, The Low Temperature Viscometry 3, 153 (1964).
of Oils Containing Polyisobutylene and Poly(a1- 50. H. H. Zuidema, The Performance of Lubricat-
kyl methacry late) as Viscosity Index Improvers, ing Oil, Reinhold Publishing Corp., N.Y., 1959.
Am. Chem. SOC.,Div. Petrol. Chem., Preprints 51. Foaming characteristics of Hydraulic Fluids
2, 89 (1957); C. A. 55, 8834 (1961). and Special Lubricants, Petroleum Refining
38. W. T. Stewart and F. A. Stuart, Lubricating Laboratory Report PRL-3.48, Pennsylvania
Oil Additives, in: Kobe and Smith, Eds., Ad- State College, December 1949.
vances in Petroleum Chemistry and Refining, 52. L. T. Shearer and W. W. Akers, Foaming in
Vol. VIZ,Interscience, N.Y.,1963. Lube Oils, J. Phys. Chem. 62, 1269 (1958).
39. Proposed Method of Test for Shear Stability of 53. Fire Resistant Hydraulic Fluids, Lubrication
Polymer-Containing Oils, Committee D-2 on 48, 161 (1962).
Petroleum Products and Lubricants, 1961, Am. 54. D. Godfrey, The Lubrication Mechanism of
SOC. Testing Materials, Supplementary Preprint Tricreqyl Phosphate on Steel, ASLE Trans. 8,l
to the 1961 Report of Committee D-2 on Pe- (1965).
troleum Products and Lubricants, Appendix 55. E. E. Klaus and H. E. Bieber, Effects of
XIII, pp. 61-66. P32 Impurities on the Behavior of Tricresyl
40. C. M. Murphy and H. Raoner, Oxidation Phosphate-32 as an Antiwear Additive, ASLE
Characteristics of Some Diester Fluids, Ind. Trans. 8, 12 (1965).
Eng. Chem. 44, 1607 (1952). 56. E. E. Klaus et al., A Study of Tricresyl Phos-
41. T. W. Selby, Consideration of the Degradation of phate as an Additive for Boundary Lubrica-
Polymer Systems on the Basis of Reduced. Vis- tion, ASLE Trans. 11, 155 (1968).
cosity Loss, ASTM Special Publication 382, p. 57. F. T. Barcroft and S. G. Daniel, The Action of
58, 1964. Neutral Organic Phosphates as EP Additives,
42. R. LeMar, Factors Affecting Sonic Degrada- ASME Trans. J. Basic Eng. 87, 761 (1965).
tion of Polymer Solutions, Ind. Eng. Chem., 58. J. Messina et al., Evaluation of Long Chain
Prod. Res. Dev. 6, 19-23 (1967). Phosphorus Compounds as Lubricity Addi-
43. Klaus, Tewksbury, Jolie, Lloyd, and Manning, tives, ASLE Trans. 3, 48 (1960).
Effect of Some High Energy Sources on Polymer 59. R. C. Bowers et al., Boundary Lubrication
Thickened Lubricants, ASTM Special Publica- Studies of Typical Fluoroesters, Lubrication
tion 382, p. 54, 1964. Eng. 12, 245 (1956).
44. E. E. Klaus, R. E. Hersh, and J. M. Perez, 60. R. C. Bowers et al., Friction and Wear Studies
Paraffinic Resins Have Dual Role as High of Chlorinated Methylphenyl Silicones, Ind.
Temperature Lubricants and Viscosity Index Eng. Chem. 48, 943 (1956).
Improvers, SAE Journal 74, 76 (1966); C. A. 61. H. M. Schiefer and J. V. Dyke, Boundary Lu-
65, 19898 (1966). bricating Properties of Fluoroalkyl Silicones in
45. N. W. Furby, Development of Non-Flammable Bench and Pump Tests, ASLE Trans. 7, 32
Aircraft Hydraulic Fluids, AF-TR 6685(Suppl. I). (1 964).
62. A. W. Sawyer and T. M. Medved, Formulation
46. R. L. Peeler and S. A. Kovacich, Development
of Silane Base High- Temperature Hydraulic
of a Hydrolytically Stable High Temperature
Fluid, WADC-TR-58-407, Parts I and I1
Hydraulic Fluid, WADC -TR-57-119, Parts
(1958).
I and 11.
63. W. A. Marshal, Energy Transfer Fluid Studies,
47. Research and Development on High Tempera- ML-TDR-64-154 (1954).
ture Additives for Lubricants and Hydraulic 64. L. E. Lorensen, Pour Point Depression I;
Fluids, WADC -TR-59 -191, Parts 11, 111, Mechanism Studies, Am. Chem. SOC.,Div. of
and IV. Petroleum Chem. Preprints 7, B-61 (1962).
48. Prizer, Radtke, and White, Mechanical Break- 65. G. A. Holder and J. Winkler, Wax Crystalliza-
down of 0.1-Soluble Polymethacrylates, Am. tion From Distillate Fuels; Part I. Cloud and
5-13
AMCP 706-123
Pour Phenomena Exhibited by Solution of Bi- 70. W. Hampton, The Problem of Cavitation Ero-
nary n-parafin mixtures; Part 11, Mechanism of sion in Aircraft Hydraulic Systems, Aircraft
Pour Depression; Part 111. Effect of Wax Com- Engineering 38, 8 (1966).
position on Response to Pour Depressant and
7 1. J. Sharpley, Elementary Petroleum Microbi-
Further Development of the Mechanism of
ology, Gulf Publishing Company, Houston,
Pour Depression, J. Inst. of Petroleum 51,228,
1966.
235, and 243 (1965).
66. L. E. Lorensen and W. A. Hewett, Pour Point 72. J. Davis, Petroleum Microbiology, Elsevier Pub-
Depression 11; Structure vs. Activity, Am. lishing Company, N.Y., 1967.
Chem. SOC.,Div. of Petroleum Chem. Preprints
7, B-71, 1962. 73. D. 0. Hetzman, The Control of Bacterial and
67. R. LeMar, Development of a Wide-Temperature Fungal Growth in Jet Fuels by Use of a Fuel
Range Hydraulic Fluid, RIA Report No. 67- Additive, Developments in Industrial Mi-
2254, Rock Island Arsenal, Rock Island, 11- crobiology 6, 105 (1964).
linois (1967). 74. A. U. Churchill and W. W. Leathern, Develop-
68. N. W. Furby, Development of Non-Flammable ment of Microbiological Sludge Inhibitors,ASD-
Aircraft Hydraulic Fluids, AF-TR-6685 (ATI- TR-61-193, 1st Reprint, September 1962.
188471).
69. D. Godfrey and N. W. Furby, Cavitation of 75. G. C. Blanchard and C. R. Goucher, Mech-
Oils and Hydraulic Fluids, in: R. L. Adamc- anism of Microbiological Contamination of Jet
zak, R. J. Benzing, and H. Schwenker, Proceed- Fuel and Development of Techniquesfor Detec-
ings of the AFML Hydraulic Fluids Conference, tion of Microbiological Contamination, APL-
AFML-TR-67-369, December 1967. TDR-64-70, Part 11, February 1966.
5-14
AMCP 706-123
CHAPTER 6
6- 1
AMCP 706-123
TABLE 6-1.
HYDRAULIC FLUID CONTAINER SIZES5
Eontainer Container Capacity ClaSS Cap Design Shape
Can 1-pint Screw cap, spout, or special closure Oblong
Figs. 6-4 and 6-5. The numbers in parentheses on Fig. 6-2.1 SOURCES OF CONTAMINATION
6-5 refer to the letter size to be used. The abbreviations
listed in Table 6-2 are frequently used for hydraulic There are many sources of hydraulic fluid contami-
fluid container marking. nation. Some of the more common are: (1) lint and
dust, (2) moisture, and (3) additive problems.
TABLE 6-2.
RECOMMENDED ABBREVIATIONS
FQuantitative Units - 1 6-2.1.1 Contamination from Lint and Dust
Dozen . . . . . . . . . . . . . . . . . . . . . . DZ Lint, dust, and other foreign matter should be the
Each . . . . . . . . . . . . . . . . . . . . . . . EA least common type of fluid contaminant. Their source
Gross . . . . . . . . . . . . . . . . . . . . . . . GR can usually be traced to carelessness on the part of
Hundred . . . . . . . . . . . . . . . . . . . . . HD personnel who handle the fluid. Airborne dust can en-
Thousand . . . . . . . . . . . . . . . . . . . .MX ter the container when it is left uncapped or improperly
Weight . . . . . . . . . . . . . . . . . . . . . .WT sealed. Lint and other foreign matter can be traced to
Cube (cubic foot) . . . . . . . . . . . . . . . . CU careless procedures in wiping lids, funnels, and other
Gallon . . . . . . . . . . . . . . . . . . . . . .GA items which come into contact with the fluid.
Quart.......................Q T
Pint . . . . . . . . . . . . . . . . . . . . . . . PT
Ounce . . . . . . . . . . . . . . . . . . . . . . OZ 6-2.1.2 Moisture Contamination During
Cubic Centimeter . . . . . . . . . . . . . . . . CC Storage
b. Procurement Marking Abbreviations
Aircraft . . . . . . . . . . . . . . . . . . . ACFT Moisture is one of the greatest enemies of hydraulic
Automotive . . . . . . . . . . . . . . . . . AUTO fluids and systems, except for aqueous type hydraulic
Engine . . . . . . . . . . . . . . . . . . . . . ENG fluids and the systems designed to use them. In general,
Lubricating . . . . . . . . . . . . . . . . . . LUBE special care should be taken to make containers water-
Petroleum . . . . . . . . . . . . . . . . . .PETRO proof-especially when they are stored without protec-
Preservative . . . . . . . . . . . . . . . PRESERV tion from the weather. Introduction of moisture into
Temperature . . . . . . . . . . . . . . . . . TEMP waterproof containers by breathing and condensa-
Turbine . . . . . . . . . . . . . . . . . . . TURB tion is a problem whenever containers are exposed to
Reciprocating . . . . . . . . . . . . . . . . RECIP frequently and widely varying temperatures. For this
Gyroscope . . . . . . . . . . . . . . . . . . GYRO reason, storage conditions where such problems can
~~~~
occur should be avoided. Containers stored out-of-
6-3
r SPACE ALLOWANCE FOR CLOSURES TOP HEAD
Contractor's Name
DOMESTIC ADDRESS
CAUTION AND
USE MARKINGS
NETCONTENT
GROSS WEIGHT CUBE
4
(A) Top Markings (B) Side Markings
1
~~
Mahogany sulfonate rust inhibitors widely used in immiscible. Solid particle contaminants are self-
finished hydraulic fluids can also be a source of con- defined. They are impurities which may either be
tamination, i.e., rusting and staining of steel in a hy- chemically reactive with hydraulic fluids or which may
draulic system. It has been found that some mahogany foul hydraulic systems.
sulfonates contain inorganic water soluble salts (such
as calcium chloride and calcium sulfate) ranging from
0.02 to 0.19 percent. Data show that the concentration 6-2.2.1 Water As a Contaminant
of inorganic salts do not appear to affect the rust pre-
vention properties of the mahogany sulfonates, but Although water was tke first liquid to be used in a
their presence does produce corrosion due to galvanic hydraulic system, it is generally a harmful contaminant
action. It was found that use of petroleum hydraulic (Ref. 14) in current sophisticated hydraulic systems.
fluids containing sulfonates with a relatively high chlo- Depending on the properties of the liquid under consid-
ride content of 0.12 percent produced system malfunc- eration, water will either form an emulsion in the hy-
tions while use of petroleum hydraulic fluids contain- draulic fluid (up to a certain percentage) or be partially
ing sulfonates with less than 0.03 percent of the salt immiscible with the hydraulic fluid with some water
permitted satisfactory operation (Ref. 13). floating on the surface of the hydraulic fluid or settling
to the bottom of the container. Immiscible or free quan-
tities of water in a hydraulic fluid are usually the result
6-2.2 TYPES OF CONTAMINANTS of careless handling and cause damage to both the
hydraulic fluid and the system. Unwanted water in a
The many impurities that can affect hydraulic fluids hydraulic fluid leads to a multitude of problems in
adversely can be classified as either solid particle or terms of hydraulic system damage and failure. The
liquid contaminants. The most common and most trou- worst threats of water contamination are the corrosive
blesome liquid contaminant is water, but liquid con- effects of water and the subsequent fluid and/or system
taminants include all foreign liquids, both miscible and contamination with corrosion particles.
6-5
AMCP 706-123
One clarification concerning water and hydraulic considered as a standard for all hydraulic fluids. In-
fluids must be made, however. In certain fire-resistant deed, if contamination levels are to be established for
hydraulic fluids, water is a welcome ingredient, making a hydraulic fluid, it is best to refer to the manufac-
up from 20-70 percent of the liquid. Such fire-resistant turers data for the most reliable indication of the con-
hydraulic fluids are formed by an emulsion of water tamination limits and to take into account the design
dispersed in a second liquid, such as oil or a glycol. In of the system(s) in which the liquid will be used.
these liquids the distinction between water as a needed Table 6-4 is an example of contamination limits for
ingredient and water as a contaminant is clear. hydraulic fluids established by one aircraft company
A distinction must be made between oil-in-water (Ref. 15). Not only is the maximum number of particles
emulsions and water-in-oil emulsions. Although a sta- specified, but the maximum weight of the contaminant
ble solution can be made by dispersing oil in water, per 100 ml of liquid is also specified. The differences in
problems with corrosion and wear are more apt to contamination limits between Tables 6-3 and 6-4 serve
occur with this type of emulsion. Inverse or water-in- to illustrate the relative nature of fluid cleanliness.
oil emulsions, on the other hand, offer the fire-resistant What may be a clean fluid in one application may not
quality of water while retaining the lubricating and be clean enough for another. The specific application
anticorrosion qualities of the oil. In inverse emul- of the fluid is always the ultimate factor in determining
sions, water is the dispersed phase while oil is the con- contamination limits.
tinuous phase. In oil-in-water emulsions, the situation
is reversed-the oil is the dispersed phase and the water
is the continuous phase.
6-2.2.3 Liquid Contaminants Other Than
Water
6-2.2.2 Solid Contaminant Particles
In addition to solid particle and water contamina-
Of all contaminants, solid particles are of most fre- tion, contamination from other liquids, both miscible
quent concern. Their measurement is usually deter- and immiscible, can occur.
mined according to size and number. The cleanliness of Liquid contaminants in hydraulic fluids often enter
a hydraulic fluid is normally reported as the relative a system as a result of mixing (accidental or inten-
solid particle cleanliness. tional) two or more hydraulic fluids. Accidental mixing
Solid particle contaminants are either of the fibrous often occurs when replacing the hydraulic fluid in a
or nonfibrous variety. Fibrous particles have a large system with another hydraulic fluid without a
length-to-diameter ratio. A fibrous particle has been thorough cleaning of the system. Liquid contamination
defined by Aircraft Industries Association as one hav- of a hydraulic fluid can also occur when transferring
ing a length-to-diameter ratio greater than 10 to 1. the liquid into unclean containers. In general, such
Nonfibrous solid particle contaminants include all par- transfers should be avoided. In some cases, however,
ticles not in the fibrous class. Their irregular shapes Military Specifications indicate that two different liq-
make it necessary to define their size by their larg- uids are compatible and may be mixed. Such a mixture
est dimension. may be considered usable in that it does not form resin-
The unit of measurement for solid particle contami- ous gums, sludges, or insoluble solid materials; how-
nation is the micron (about 39 millionths of an inch). ever, the liquids in the mixture are contaminated in the
The normal human eye can detect particles as small as sense that the liquids may no longer retain their origi-
40microns. However, contaminant particles as small as nal characteristics. Such characteristics may be critical
1/2 micron may be of concern. in certain applications that require a clean fluid.
Because of the wide variety of hydraulic fluids and Contamination of a hydraulic fluid by oils or sol-
their equally wide variety of applications, there are vents used in or on the hydraulic system is a frequent
many standards of fluid cleanliness. MIL-H-5606B re- form of contamination. This type of contamination
quires that (1) there be no particles over 100 microns reduces the effectiveness of the hydraulic fluid by
in size, and (2) the total contamination in a 100-ml changing characteristics such as viscosity, density, and
sample retained on a 0.45-micron cellulose filter be no lubricating ability or by attacking system components
more than 0.3 mg. such as seals. However, the oil or solvent may have no
Table 6-3 presents data on generalized contamina- chemical effect on the hydraulic fluid itself, particu-
tion limits for hydraulic fluids as proposed by the Air- larly in the case of petroleum base hydraulic fluids and
craft Industries Association (Ref. 15). It is not to be petroleum fraction oils or solvents (Ref. 12).
6-6
AMCP 706-123
TABLE 6-3.
AIA PARTICLE CONTAMINATION LIMlTS FOR HYDRAULIC FLUIDS
Number of Particles
Particle Size, p particle Size > 100rd
Class 11-25 26-50 51-100 F1kISb Particlesb
220 20 5 2 0
530 60 10 3 1
1,530 150 15 4 1
5,530 420 40 7 3
1,650 320 25 1 OC
Notes:
a. Value to be controlled for each application.
b. Particles with length-to-width ratio greater than 10 are termed fibers; with length-to-width ratio less than
10, they are termed particles.
c. Zero particles are defined as none if one sample is taken; if an average of several samples is taken, total
particles in all samples must be less than number of samples to meet zero requirement.
d. p = 1 micron = 10-4cm
6-7
AMCP 706-123
contamination can occur in hydraulic fluids. If suffi- Solid particles on the order of 100 microns can be
cient quantities of the organisms are allowed to grow formed from smaller ones. This effect has been espe-
unchecked, they can clog filters, restrict small orifices, cially noted in noncorrosion-preventing petroleum base
and cause poor operation of close tolerance parts. hydraulic fluids (Ref. 12). These fluids are highly die-
The growth of micro-organisms can be increased by lectric and contaminant particles retain a static charge.
the presence of other contaminants in the hydraulic The result is that when the fluid is exposed to long
fluid. Water contamination, for example, provides an periods of agitation, such as in shipping, the probability
environment, and is necessary, for the growth of living of particles colliding with one another increases and
organisms. In most cases, elimination of microbial con- particle agglomerations form. Fluids with submicronic
taminants with biocides does not solve the underlying particles have been known to form 25- to 200-micron
contaminant problems that originally contributed to particles under these conditions (Ref. 12).
growth of the micro-organisms (Ref. 16). Moisture is a contaminant which causes a slime in
some hydraulic fluids. The necessary ingredients for
6-2.3 EFFECTS OF CONTAMINATION the formation of this slime that can clog filters are
Contamination in a hydraulic system is damaging to tricresyl phosphate (an antiwear additive used in sev-
the hydraulic fluid and to the system in which it is used. eral hydraulic fluids), an alkali, and moisture (Ref. 12).
The degree of contamination usually begins at a low In a hydraulic fluid of the corrosion-preventive type,
level and increases because of the formation of con- moisture can also cause the formation of a slime resem-
taminants in the system itself (especially solid particle bling egg white. When sufficient moisture is present,
contaminants caused by system wear, oxidation, the corrosion-preventing additives can exhaust them-
and corrosion). selves by wrapping up the moisture in additive and
water dispersions (Ref. 12).
which is indicative of the effects of at least solid particle in general use. They are: Federal Test Method 3009
contaminants, is that normal contamination can be (Ref. 19), ASTM D -2390 -65T (Ref. 20), andAero-
controlled to the point where the life of a servo-valve nautical Recommended Practice ARP-598 (Ref. 21).
assembly can be increased by as much as 277 percent The three methods are very similar in the proce-
(Ref. 17). Table 6-5 presents data on some of the many dure and the reporting of results. In each method a
types of contaminants and their general effects on the sample of the specimen is filtered through a 0.45-
most common components in a hydraulic system. micron cellulose membrane filter. The filter is exam-
(Ref. 18). ined under a microscope and the number of solid parti-
cles in a given area of the filter is counted. The particle
counts are grouped in the following size ranges (in
6-2.4 METHODS OF DETERMINING
microns): 5 to 15, 15 to 25, 25 to 50, 50 to 100, over
CONTAMINATION
100 (length-width ratio under lO:l), over 100 (length-
width ratio over 1O:l). The total number of particles
The required cleanliness of a hydraulic system is
present is calculated by statistical methods.
relative and is dependent on the design of a particular
system. Although the criteria for cleanliness may vary (2) Automatic Counting Methods:
for different systems, the methods of contaminant The tedious nature of most particle-contaminant
measurement are basically alike. Methods of solid par- counting and weighing methods can be avoided
ticle contaminant measurement involve counting, siz- through the use of automatic particle counters. Two
ing, and/or weighing of the particles in a given volume types of automatic counters exist. Sample counters
of fluid. Methods of determining the amount of liquid measure the number of particles in a sample of hydrau-
contaminants present in hydraulic fluids usually in- lic fluid. On-stream counters record the number of con-
volve chemical or physical procedures-distillation, taminant particles in a system while it is in operation.
separation with a solvent, or isolation of the contami-
(a) Sample-type Automatic Counters:
nant by chemical reaction.
One sample-type counter* is capable of counting
solid particle contaminants and indicating their size.
6-2.4.1 Solid Particle Contamination Electrodes on each side of a small channel detect a
Measurement by Counting change in resistance whenever a contaminated sample
of hydraulic fluid passes. The fluid sample must be
(1) Microscope Methods:
Three test procedures for determining the solid parti-
cle contamination in hydraulic fluids by counting are Made by Coulter Electronics, Inc., Chicago.
TABLE 6-5.
EFFECTS OF VARIOUS CONT, IINANTS ON HYD QULICSYSTEM COMPO ENTS' *
6-9
AMCP 706-123
made conductive before testing by mixing it with a The insoluble contamination is determined by draw-
suitable solvent. Passing contaminants cause a voltage ing a 100-ml sample of hydraulic fluid through a mem-
pulse in proportion to the size of the particle so that the brane filter disk and measuring the resultant increase
number of particles within a certain size range can be in the weight of the filter. In addition, the filter disk is
determined. Measurement may be made down to about microscopically scanned for excessively large particles,
5 microns. fibers, or other unusual conditions.
Another sample-type counter" works on an electro- Precision: Results should not be considered suspect
optical system capable of measuring and counting con- unless they differ by more than the following amount:
taminant particles on test slides. Measurement may be (a) Repeatability. 0.2 mg/100 ml
made down to 1.0 micron. Also operating as an electro- (b) Reproducibility. 0.05 mg/100 ml
optical device is a sample-type counter, which allows
a sample of the fluid on a slide to oscillate past a photo-
cell which counts and sizes the contaminant particles. 6-2.4.3 Solid Particle Contamination
(b) On-stream Automatic Counters: Measurement by Combined Counting
A second category of particle counters provides for and Weighing Methods
automatic sampling of the hydraulic fluid. On-stream
counters connect directly into an operating hydraulic Many users of hydraulic fluids prefer to rely on more
system and tap fluid from a point in the flow believed than one technique for determining contamination.
to yield samples representative of the entire flow. The testing procedure required for MIL-H-5606B fluid
One commercially available on-stream device * * is a good example. This particular fluid is considered
counts and sizes particles in the 5-250 micron range. below specification if it fails either a weight analysis or
The counter automatically draws a fluid sample from particle count test. According to weight, there must not
a hydraulic system through a narrow passage fitted be more than 0.3 mg of solid particle contaminants per
with a photoelectric detection system. The system 100 ml when the test is conducted under the provisions
makes contamination data available in terms of number of Federal Test Method Standard No. 791a, Test
of particles in various size ranges per unit volume Method 3009 (Ref. 19). According to the particle
of sample. count', the number of contaminant particles must not
Another on-stream automatic counter designtt al- exceed the values given in Table 6-6.
lows for the automatic sampling, sizing, and counting
of particles greater in size than 10 microns. Measure-
ments are accomplished by reflecting ultrasonic waves
off contaminant particles. 6-2.4.4 Liquid Contaminant Measurement
6-10
AMCP 706-123
TABLE 6-6.
SOLID PARTICLE CONTAMINATION LIMITS IN HYDRAULIC
FLUID CORRESPONDING TO MILH-56MB
~~ ~
*p = 1 micron = 1 0 - ~cm
(1) Test for Water in Petroleum and Other Bitumi- 6-3 PRECAUTIONS
nous Materials:
Test Methods: Federal Test Method 3001.8 (Ref. 23) The exercise of certain precautions in the storage and
ASTM D-95-62 (Ref. 24) handling of hydraulic fluids is vital for the safety of
These methods are used to determine the water con- personnel and for the protection of the fluid. The intro-
tent of bituminous materials by distillation with a water duction of contaminants into the hydraulic fluid and
immiscible, volatile solvent. contact with incompatible materials are both to be
The sample is heated under reflux with a water- avoided. Personal hazards from explosion,fire,skin poi-
immiscible solvent which co-distills with the water in soning, ingestive poisoning, and vapor inhalation are of
the sample. Condensed solvent and water are continu- even more concern. Anyone who stores and handles
ously separated in a trap, the water settling in the gra- hydraulic fluids should know well the hazards they face
duated section of the trap and the solvent returning to and follow all recommended safety precautions.
the still.
( 2 ) Test for Water With Karl Fischer Reagent:
Test Methods: Federal Test Method 3253 (Ref. 25) 6-3.1 HEALTH HAZARD
ASTM D-1744-64 (Ref. 26)
These methods cover the procedures for determining Skin poisoning, ingestive poisoning, and exposure to
water in the concentration of 50 to 1,OOO ppm in liquid vapors and sprays of hydraulic fluids are common
petroleum products. The procedure, referred to as the threats to hydraulic fluid handlers. Other darlgers are
Karl Fischer Method, or some variation of it, is due to the explosive or highly flammable nature of
widely used for the determination of moisture content some liquids. Most hydraulic fluids, however, do not
of many materials. Although the test standards list the pose a serious health hazard. For specific information
procedure for petroleum products only, it can be used on the hazardous nature of a particular fluid, the fluid
on most materials where the reagents will not produce manufacturer should be consulted.
reactions that give false readings.
Sufficient Karl Fischer reagent is diluted with pyri-
dine to adjust its strength to a water equivalence of 2 6-3.1.1 Precautions Against Poisoning
to 3 rng %O per ml of solution. Fifty ml of the sample
is diluted with 50 ml of methanol-chloroform (1 part to Skin poisoning or irritation caused by repeated han-
3 parts by volume). The sample is then added to the dling of a hydraulic fluid, and ingestive poisoning
adjusted solution. If water is present, the solution will caused by accidental swallowing are two hazards that
no longer be dry. A second adjustment with Karl can be easily guarded against. The swallowing of a
Fischer reagent is made until the water equivalence of hydraulic fluid is very rare. Nonetheless, poisonous
2 to 3 rng H P per rnl of solution is again reached. The hydraulic fluids should be clearly marked as such and
amount of moisture present is then determined by the an antidote or other first aid procedure should be
amount of reagent used to reach the second end point. known from the manufacturers data or fromcautionary
6-1 1
AMCP 706-123
information on the fluid container. For all hydrau - coupling)-can spray system components and surround-
lic fluids, the avoidance of extended contact with the ings that may be hot enough to cause ignition. If the
skin is recommended. Although most hydraulic fluids, liquid is conducting, the spray can also cause short
including synthetics, are not harmful to bare skin, pro- circuits in electrical systems which, in turn, can cause
longed contact should be avoided because many of the ignition. Precautions against this sort of fire hazard are
ingredients and additives may tend to dry out the skin. the responsibility of the system designer. If possible, the
However, the effect is usually not long lasting if the probable points of system failure should be situated so
exposure is not prolonged. that, should a leak occur, the hydraulic spray will not
be exposed to potential ignition sources.
REFERENCES
6-3.2 DANGER OF EXPLOSION AND FIRE
11. MIL-H-27601, Petroleum Base, High Tempera- November 1961, Institution of Mechanical
ture, Flight Vehicle, 23 January 1964. Engineers, London (1962).
12. T. N. Deane, The Effect of Contamination on 19. Federal Test Method Standard No. 791a, Test
Fluids and the Effect of the Ingredients of the Method 3009.
Fluids on Contamination, Proceedings of 20. ASTM Standards 1967, Designation D-2390-
Aerospace Fluid Power Systems and Equipment 65T, Part 18, p. 533, Philadelphia, American
Conference-May 1965, Society of Automotive Society for Testing Materials, 1967.
Engineers, New York, 1965. 21. Procedure for the Determination of Particulate
13. J. Messina and A. Mertwoy, Inorganic Salts Contamination of Hydraulic Fluids by the Parti-
in Mahogany Sulfonates and Their Effect on cle Count Method, Aeronautical Recommended
Petroleum Hydraulic Fluids, Lub. Eng., Practice 598, Society of Automotive Engineers,
Feb. 1967. Inc., New York, N.Y. pp. 1-6 (1960).
14. R. E. Hatton, Introduction to Hydraulic Fluids, 22. ASTM Standards 1967, Designation D-2387-
Reinhold Publishing Corp., N.Y., 1962. 65T, Part 18, pp. 5 10-513, Philadelphia, Ameri-
15. M. Piccone, Control of Contamination in can Society for Testing Materials, 1967.
Rocket Booster Hydraulic Systems, Proceed- 23. Federal Test Method Standard No. 791a, Test
ings of Aerospace Fluid Power Systems and Method 3001.8.
Equipment Conference-May 1965, Society of 24. ASTM Standards 1967, Designation D-95-62,
Automotive Engineers, New York (1965). Part 17, p. 55, Philadelphia, American Society
16. S. A. London, Microbial Activity in Air Force for Testing Materials 1967.
Jet Fuel Systems, Developments in Industrial 25. Federal Test Method Standard No. 791a, Test
Microbiology 6, 62 (1964). Method 3253.
17. H. L. Huggett, Servo Valve Internal Leakage 26. ASTMStandards 1967, Designation D- 1744-64,
as Affected by Contamination, Proceedings of Part 17, p. 667, Philadelphia, American Society
Aerospace Fluid Power Systems and Equipment for Testing Materials, 1967.
Conference-May 1965, Society of Automotive 27. Accident Prevention Handbook, AFM 32-3, De-
Engineers, New York (1965). partment of the Air Force, 1 August 1964.
18. D. F. Denny, Cleanliness in Hydraulic Sys- 28. H. M. Shiefer, For Hydraulic Systems, Drives,
tems, Proceedings of the C mference on Oil Hy- Dashpots: Whats Hot in Fluids? Product En-
draulic Power Transmission and Control- gineer, 107, August 1964.
6-13
AMCP 706-123
GLOSSARY
G- 1
AMCP 706-123
flow, steady A flow situation wherein conditions synthetic A material which, by definition, is
state such as pressure, temperature, and nonpetroleum, but which may
velocity at every point in the fluid contain nonfunctional amounts of
do not change. petroleum. Specifically, this per-
flow, streamline A flow situation in which motion mits petroleum to be used as a car-
occurs as a movement of one layer rier for a constituent, i.e., for an
of fluid upon another. This is syn- additive, etc., but excludes pe-
onymous with laminar flow. troleum used for any benefit of its
flow, turbulent A flow situation in which the liquid properties per se.
particles move in a random man- water-glycol- A fluid whose major constituents
ner. type are water and one or more glycols
flow rate The unit volume of a fluid flowing or polyglycols and which may con-
per unit of time. tain additional amounts of other
constituents.
flow velocity The rate of speed at which a volume
of fluid passes a particular point in water-oil A stabilized emulsion of water
a passage. emulsion -oil, and which may contain ad-
type ditional amounts of other constitu-
fluid A substance which yields to any ents. There are two types: (1)
pressure tending to alter its shape. oil-in-water, a conventional solu-
Fluid, by strict definition, includes ble oil in which oil is dispersed in
both liquid and gas. a continuous phase of water; and
halogenated- A fluid composed of halogenated (2) water-in-oil, a dispersion of wa-
type organic materials and which may ter in a continuous phase of oil.
contain additional amounts of fluid power Power transmitted and controlled
other constituents. through use of a pressurized fluid.
hydraulic A fluid suitable for use in hydraulic fluid power A system that transmits and con-
systems. system trols power through use of a press-
organic ester- A fluid composed of esters of car- urized fluid within an enclosed cir-
type bon, hydrogen, and oxygen, and cuit.
which may contain additional foam An intimate mixture of gas and liq-
amounts of other constituents.
uid occupying much more volume
petroleum- A fluid composed of petroleum hy- than the liquid alone.
type drocarbons and which may con- freezing point The temperature at which a fluid
tain additional amounts of other changes from liquid phase to solid
constituents. phase.
phosphate A fluid composed of phosphate es- friction Resistance to motion. Fluid friction
ester -type ters and which may contain addi- is that friction due to the viscosity
tional amounts of other constitu- of the fluid.
ents.
polyalky lene A fluid composed of polyalky- heat exhanger A device for transferring heat from
glycol- lene glycols or derivatives and a hot fluid to a cold one, without
type which may contain additional a- the two coming in contact with
mounts of other constituents. each other. When used as a fluid
silicate ester- A fluid composed of organic sili- cooler in a hydraulic system, it
cates and which may contain addi- may take the form of either a nest
type
tional amounts of other constitu- of pipes in a suitable container,
ents. through which coolant flows, or a
radiator.
silicone-type A fluid composed of silicones and
which may contain additional hose A flexible conduit for conveying
amounts of other constituents. fluid.
6-3
AMCP 706-123
stoke The standard unit of kinematic vis- gate A valve with a gate which is raised
cosity in the centimeter-gram- or lowered by the action of a screw
second system. It is expressed in or other means to close or open the
square centimeters per second. flow passage.
strainer A filter made from wire mesh and globe A valve with a plug, ball, or disc,
capable of removing the larger par- which by action of a screw or other
ticles of solids from a fluid. means, is pulled away from or low-
switch, pressure A switch operated by pressure and ered into a corresponding seat to
used for (a) controlling pressure open or close the flow passage.
between predetermined limits, (b) needle A valve with a tapered needle which
starting or stopping a sequence is pulled away from or forced into
when a certain pressure is reached, a corresponding seat. The tapered
and (c) as a safety device. needle permits gradual opening or
thermostat A device for controlling tempera- closing of the passage.
ture either by switching on and off open center A valve which in the center position
an electric current or by opening connects all ports.
and closing a valve in a liquid line. pilot A valve applied to operate another
torque Force applied through a rotary path valve or control.
of motion. pilot-operated A valve in which operating parts
vacuum A pressure which is less than the are actuated by pilot fluid.
prevailing atmospheric pressure. poppet-type A valve construction which closes
valve A device for controlling flow rate, off flow by a poppet seating against
direction of flow, or pressure of a a suitable seating material. Nor-
liquid. mally considered a dead-tight seal.
cam-operated A valve in which the spool is posi- The poppet may be a ball, a cone,
tioned mechanically by a cam. or a flat disk.
check A valve which permits flow of fluid pressure A valve which maintains a reduced
in one direction only and self reducing pressure at its outlet regardless of
closes to prevent any flow in the the higher inlet pressure.
opposite direction. relief A valve which opens when a set
pressure is reached to prevent fur-
closed center A valve which in the center position
ther rise of pressure in a system or
has all ports closed.
to keep the pressure constant. The
directional A valve whose primary function is relief valve limits pressure which
to direct or prevent flow through can be applied to that portion of
selected passages. the circuit to which it is attached.
flow control A valve whose primary function is sequence A valve which directs flow to a sec-
to control flow rate. ondary portion of a fluid circuit in
flow dividing A valve which divides the flow from sequence. Flow is directed only to
a single source into two or more that part of the circuit which is
branches. connected to the primary or inlet
port of the valve until the pressure
flow dividing, A valve which divides the flow setting of the valve is reached. At
pressure from a single source into two or this time, the valve opens and pres-
compensating more branches at constant ratio, sure in the secondary port may
type regardless of the difference in the vary from zero to near the setting
resistances of the branches. of the primary side with no varia-
four-way A valve having four controlled tion in the primary pressure.
working passages, usually ending shuttle A connective valve which selects
in four external ports. one of two or more circuits because
G-6
AMCP 706-123
6-7
INDEX
additives (Cont.)
for silicone fluids 5-9
hydrolytic inhibitors 5-10
pour point depressants 5-10
seal degradation retardants 5-10
AIT 3-27
alkalinity 3-70
alky aIyl phosphate ester 4-7
Almen tester 3-61
antioxidants 5-1
classes of 5-2
for esters 5-2
for ethers 5-3
for highly refined mineral oils 5-3
for silicon containing fluids 5-3
mode of action 5-1
synergistic effect 5-2
antiwear additives 3-60 5-8 5-9
API Gravity 3-40
Aroclor 4-9
ASTM Color 3-70
ASTM slope 3-9
autoignition temperature 3-27
availability 1-6
axial-piston motors 2-16
axial-piston pumps 2-6
classification (Cont.)
fire resistance 4-2
operating characteristics 4-2
physical properties 4-1
'I'ypes I-VI 4-2
viscosity 4-1
Cleveland open cup 3-22
cloud point 3-20
significance 3-22
test for 3-21
coatings, containers 6-1
coefficient of friction 3-57 3-61
coefficient of cubical expansion 3-40
coefficient, viscosity-temperature 3-11
coke 3-72
color 3-70
color-indicator titration 3-71
compatibility 1-4 2-21 3-79
test for 3-94
with additives 3-96
with metals 3-80
with other lubricants 3-93 5-1
with paints 3-93
with solid film lubricants 3-95
compressibility 1-5 3-44
compression ignition tests 3-26
conduction 2-35
Conradson test 3-72
containers 6-1
coating 6-1
liners 6-1
marking 6-1
materials 6-1
sizes 6-1
storage 6-1
contaminants 6-3
dust 6-3
lint 6-3
liquids 6-6
microbiological 6-7
contaminants (Cont.)
particles 6-6
sources 6-3
types 6-5
water 6-5
contamination 1-7
automatic counting 6-9
effect on oxidation 3-66
effects 6-8
hydraulic fluids 1-7 6-8
liquid 6-10
measurement 6-9 6-10
microbiological 6-7
sedimentation 3-56
weighing of 6-10
controls, directional 2-2
pressure 2-2
convection 2-35
conversion units, viscosity 3-3 3-8
cooling systems 2-36
air-cooled 2-37
water-cooled 2-37
corrosion 3-67 3-75 3-81
cause of metal fatigue 3-81
chemical 3-75
copper strip test 3-76
corrosion-fog cabinet test 3-76
electrochemical 3-75
metal-liquid test 3-76
oxidation-corrosion 3-72 3-74 5-1
protection-salt spray test 3-76
corrosion inhibitors 5-4
limitations of 5-4
mode of action 5-4
volatile corrosion inhibitors 5-5
couplings 2-9 2-39
crescent seal motors 2-14
crescent, seal pumps 2-4
crystdization 3-56
cushioned actuators 2-11
elastomers 3-83
compatibility with seals 3-79 3-83
materials 3-84
test for compatibility 3-92
electrochemical corrosion 3-75
electronic equipment coolant 4-5
emulsifiers 5-7 5-8
emulsions 1-7 3-51 3-52 4-2
4-7
energy 1-1
Engler 3-3 3-4
esters 5-2
organic acid 4-5 4-10
phosphate 4-2 4-3 47 4-10
silicate 4-2 4-5 4-10
ethers 5-9
polyphenyl 3-66 3-69 4-2 4-9
4-10
ethylene propylene rubber 3-85
evaporation 3-33 3-34 3-35 3-73
evaporation-oxidation tests 3-73
explosions 6-12
extreme pressure 3-59
additives 5-8 5-9
Kel-F 4-8
kinematic viscosity 3-3 3-6 3-7
oiliness 3-59
organic acid esters 4-5 4-10
organic oils 4-6
orientation viscosity loss 5-6
orifice 3-7
Ostwald viscometer 3-8
oxidation-corrosion test 3-72 3-76
oxidation inhibitors 5-1
oxidation stability 3-65 3-68 3-72 3-73
properties
low-temperature 3-18
lubrication 3-57
physical 3-2
viscosity-pressure 3-14
viscosity-temperature 3-8
pseudoplastic fluid 3-4
pumps 2-3
axial-piston 2-6
balancedvane 2-12
bellows 2-8
crescent seal 2-4
diaphragm 2-8
external gear 2-3
gerotor 2-4
helical gear 2-4
herringbone gear 2-4
internal gear 2-4
piston 2-6
radial-piston 2-7
reciprocating 2-3
rotary 2-3
rotating piston 2-7
screw 2-8
spur gear 2-3
unbalanced vane 2-5
vane 2-5 2-15
pump tests 3-63
Pydraul 4-8
valves (Cont.)
flow-dividing 2-24
pressure-control 2-26
back-pressure 2-27
hydraulic fuze 2-28
load-dividing 2-27
pressure switch 2-28
regulator 2-28
relief 2-26
sequence 2-27
unloading 2-26
seating 2-24
sliding-spool 2-24
symbols for 1-6
volume control 2-30
vapor pressure 3-32
viscometers 3-6
calibration 3-8
Cannon-Fenske 3-7 3-8
Cannon-Master 3-8
capillary 3-6
glass 3-8
kinematic 3-8
Ostwald 3-8
reverse-flow 3-8
Saybolt 3-7
suspended-level 3-8
viscosity 1-4 3-2
absolute 3-2
blends 3-14
definition 3-2
Engler 3-3
kinematic 3-3 3-6 3-7
non-Newtonian materials 3-5
Redwood 3-3
Saybolt Furol 3-3
Saybolt Universal 3-3 3-7 3-9
significance 1-4
Viscosity Index (V.I.) 3-11 3-13