April 20, 2017 Cardno

Cardno 031093CXJS.L35
801 Second Avenue
Suite 700
Seattle, WA 98104
LUST Coordinator USA
Washington State Department of Ecology
Northwest Regional Office Phone: +1 206 269 0104
3190 160th Avenue Southeast Fax: +1 206 269 0098
Bellevue, Washington 98008-5452
www.cardno.com
SUBJECT In-Situ Chemical Oxidation Report
Former Exxon Station 72427
2137 N Northgate Way
Seattle, Washington

LUST Coordinator:

At the request of ExxonMobil Environmental Services Company (EMES), on behalf of ExxonMobil Oil Corporation,
Cardno has prepared the enclosed In-Situ Chemical Oxidation Event Report presenting results of the in-situ
chemical oxidation injection performed on March 29, 2017 at the subject site.

Please contact Mr. Bobby Thompson, Cardno Project Manager for this site at 206 510 5855, or Ms. Jennifer
Sedlachek, EMES Project Manager for this site at 510 547 4718 with any questions.

Sincerely,

Cristina Tillberry Bobby Thompson

Staff Scientist Assistant Project Manager
Cardno Cardno
Direct Line +1 206 832 4618 Direct Line +1 206 510 5855
Email: [email protected] Email [email protected]

ENCLOSURE
In-Situ Chemical Oxidation Report, dated April 20, 2017

cc: w/ enclosure
Ms. Mary Shaleen-Hansen (Paper copy via USPS)
Mr. Ed Ralston, Phillips 66 (Electronic copy via email)
Ms. Michelle Bien-Curtin, BP (Electronic copy via email)
Mr. Jasbir Singh, Site Owner (Electronic Copy via USPS)
Mr. Jennifer Sedlachek, ExxonMobil Environmental Services Company (Filed in official project folder)

Australia Belgium Canada Colombia Ecuador Germany Indonesia

Kenya New Zealand Nigeria Papua New Guinea Peru Philippines Singapore
United Arab Emirates United Kingdom United States Operations in over 100 countries
April 20, 2017 Cardno
Cardno 031093CXJS.L35 801 Second Avenue
Suite 700
Ms. Jennifer Sedlachek Seattle, WA 98104
ExxonMobil Environmental Services Company USA
4096 Piedmont Avenue #194
Phone: +1 206 269 0104
Oakland, California 94611 Toll-free +1 877 470 4334
Fax: +1 206 269 0098
SUBJECT In-Situ Chemical Oxidation Injection Report
Former Exxon Station 72427 www.cardno.com
2137 North Northgate Way
Seattle, Washington

Ms. Sedlachek:

INTRODUCTION

At the request of ExxonMobil Environmental Services Company (EMES), on behalf of Exxon Mobil Corporation,
Cardno has prepared this report presenting the results of the targeted injection of an in-situ chemical oxidation
(ISCO) solution and post-injection groundwater monitoring and sampling at the subject site. The purpose of the
work is to remediate the central portion of the subject site, where historical analytical results indicated hydrocarbon
concentrations exceeding the MTCA Method A Cleanup Levels.

SITE DESCRIPTION

The site is currently occupied by an active gas station, service station building, and Starbucks with drive-thru. The
site location is shown on Plate 1. Locations of USTs, dispenser islands, groundwater monitoring wells, and other
select site features are shown on Plate 2.

TARGET INJECTION

The ISCO solution injected consisted of a PersulfOx solution. The ISCO solution was injected into wells MW10
and IJ1. Well construction details are shown on Table 1 and injection locations are shown on Plate 2. A diagram
depicting the layout of the injection trailer and the injection process is shown on Plate 3. The PersulfOx safety
data sheet is enclosed as Appendix A.

Pre-Field Activities

Prior to field activities, Cardno obtained an underground injection control (UIC) permit in order to perform the ISCO
injection in compliance with the Washington State Department of Ecology (Appendix B).

Chemical-Oxidation Injection

On March 29, 2017, Cardno personnel visited the subject site to perform ISCO injection activities. Water for the
injection event was transported to the site using Cardnos portable injection trailer. A total of twelve 55-pound bags
(660 pounds) of PersulfOx was injected into wells MW10 and IJ1. The trailer was connected to the wells via the
trailer manifold. The 660-pound solution was injected at a flow rate of approximately 4.8 gpm with a recorded
pressure of 4 psi at the wellhead for MW10 and a flow rate of approximately 6.0 gpm with a recorded pressure of
15 psi at the wellhead for IJ1.

Australia Belgium Canada Colombia Ecuador Germany Indonesia

Kenya New Zealand Nigeria Papua New Guinea Peru Philippines Singapore
United Arab Emirates United Kingdom United States Operations in over 100 countries
 2
April 20, 2017
Cardno 031093CXJS.L35 Former Exxon Station 72427, Seattle, Washington

RECOMMENDATIONS

Cardno recommends submitting a copy of this report to the Washington State Department of Ecology and that
groundwater at the subject site be monitored on a periodic basis to evaluate concentrations of hydrocarbon.

LIMITATIONS

For documents cited that were not generated by Cardno, the data taken from those documents is used as is and
is assumed to be accurate. Cardno does not guarantee the accuracy of this data and makes no warranties for the
referenced work performed nor the inferences or conclusions stated in these documents.

This report and the work performed have been undertaken in good faith, with due diligence and with the expertise,
experience, capability and specialized knowledge necessary to perform the work in a good and workmanlike
manner and within all accepted standards pertaining to providers of environmental services in Washington at the
time of investigation. No soil engineering or geotechnical references are implied or should be inferred. The
evaluation of the geologic conditions at the Site for this investigation is made from a limited number of data points.
Subsurface conditions may vary away from these data points.

Please contact Mr. Bobby Thompson, Cardno Project Manager for this site, at 206 510 5855, with any questions.

Sincerely,

Cristina Tillberry Bobby Thompson

Staff Scientist Assistant Project Manager
Cardno Cardno
Direct Line +1 206 832 4618 Direct Line +1 206 510 5855
Email: [email protected] Email [email protected]

ENCLOSURES

Acronym List
References

Plate 1 Site Location Map

Plate 2 Generalized Site Plan
Plate 3 Process and Instrumentation Diagram

Table 1 Groundwater Monitoring and Sampling Schedule and Well Construction Details

Appendix A PersulfoxTM Safety Data Sheet

Appendix B Underground Injection Control Permit
 3
April 20, 2017
Cardno 031093CXJS.L35 Former Exxon Station 72427, Seattle, Washington

ACRONYM LIST

g/L Micrograms per liter NEPA National Environmental Policy Act

s Microsiemens NGVD National Geodetic Vertical Datum
1,2-DCA 1,2-dichloroethane NPDES National Pollutant Discharge Elimination System
acfm Actual cubic feet per minute O&M Operations and Maintenance
AS Air sparge ORP Oxidation-reduction potential
bgs Below ground surface OSHA Occupational Safety and Health Administration
BTEX Benzene, toluene, ethylbenzene, and total xylenes OVA Organic vapor analyzer
CEQA California Environmental Quality Act P&ID Process & Instrumentation Diagram
cfm Cubic feet per minute PAH Polycyclic aromatic hydrocarbon
COC Chain of Custody PCB Polychlorinated biphenyl
CPT Cone Penetration (Penetrometer) Test PCE Tetrachloroethene or perchloroethylene
DIPE Di-isopropyl ether PID Photo-ionization detector
DO Dissolved oxygen PLC Programmable logic control
DOT Department of Transportation POTW Publicly owned treatment works
DPE Dual-phase extraction ppmv Parts per million by volume
DTW Depth to water PQL Practical quantitation limit
EDB 1,2-dibromoethane psi Pounds per square inch
EPA Environmental Protection Agency PVC Polyvinyl chloride
ESL Environmental screening level QA/QC Quality assurance/quality control
ETBE Ethyl tertiary butyl ether RBSL Risk-based screening levels
FID Flame-ionization detector RCRA Resource Conservation and Recovery Act
fpm Feet per minute RL Reporting limit
GAC Granular activated carbon scfm Standard cubic feet per minute
gpd Gallons per day SSTL Site-specific target level
gpm Gallons per minute STLC Soluble threshold limit concentration
GWPTS Groundwater pump and treat system SVE Soil vapor extraction
HVOC Halogenated volatile organic compound SVOC Semivolatile organic compound
J Estimated value between MDL and PQL (RL) TAME Tertiary amyl methyl ether
LEL Lower explosive limit TBA Tertiary butyl alcohol
LPC Liquid-phase carbon TCE Trichloroethene
LRP Liquid-ring pump TOC Top of well casing elevation; datum is msl
LUFT Leaking underground fuel tank TOG Total oil and grease
LUST Leaking underground storage tank TPHd Total petroleum hydrocarbons as diesel
MCL Maximum contaminant level TPHg Total petroleum hydrocarbons as gasoline
MDL Method detection limit TPHmo Total petroleum hydrocarbons as motor oil
mg/kg Milligrams per kilogram TPHs Total petroleum hydrocarbons as stoddard solvent
mg/L Milligrams per liter TRPH Total recoverable petroleum hydrocarbons
mg/m3 Milligrams per cubic meter UCL Upper confidence level
MPE Multi-phase extraction USCS Unified Soil Classification System
MRL Method reporting limit USGS United States Geologic Survey
msl Mean sea level UST Underground storage tank
MTBE Methyl tertiary butyl ether VCP Voluntary Cleanup Program
MTCA Model Toxics Control Act VOC Volatile organic compound
NAI Natural attenuation indicators VPC Vapor-phase carbon
NAPL Non-aqueous phase liquid
 Only One Batch Tank Outlet Will be Connected to the Injection Manifold at Any Point

CE3
SECONDARY CONTAINMENT WALL P3

P2 PI
INJECTION
MANIFOLD
GV2-4 GV1-4
Recirculation Line 2
Recirculation Line 1 GROUND SURFACE

D2 D1

T2 T1
2", 2", 4"
WELL CASING
BATCH TANK 1 BATCH TANK 2
275 gal 275 gal

GV2-3

GV2-2

GV1-1 GV2-1 PUMP 2 GV1-2

WELL SCREENING

GV1-2

PUMP1

CE1 CE2

ELECTRICAL CONTROL PANEL

WITH EMERGENCY SHUTOFF

EXPLANATION
GATE VALVE BURB VALVE

CRITICAL EQUIPMENT 1. Water From Office Pumped into Batch Tanks Prior to Adding Chemicals
DIAPHRAGM VALVE FLOW DIRECTION
CE1: EMERGENCY STOP BUTTON 2. Re-Circulation Loop Opened - Pump Primed, Energized to Mix Chemicals
CE2: SYSTEM GROUND 3. Batch Tanks Connected to Injection Manifold via Spiralite Hose
PRIMER VALVE FLOW TOTALIZER
CE3: SECONDARY CONTAINMENT WALL
CHEMOX Trailer

Project Drawing
Drawn/Approved

Diagram
AutoCad File
Plot Scale
Last Rev. Date
Creation Date
Sheet No.

Project No.

NO SCALE
031093

RRT/ASG
08/29/12
08/29/12
3

FORMER EXXON STATION 72427

2137 N Northgate Way
Seattle, Washington
 TABLE 1
GROUNDWATER MONITORING AND SAMPLING SCHEDULE AND WELL CONSTRUCTION DETAILS
Former Exxon Station 72427
2137 North Northgate Way
Seattle, Washington
Page 1 of 1
Well ID Well Activity Frequency of Frequency of Date of Wellhead Screened Interval Total Well Depth Casing/Borehole Diameter Slot Size
Gauging Sampling Installation Elevation (feet) (feet bgs) (feet bgs) (inches) (inches)
MW4 LF Periodically Periodically October 7, 1991 313.45 25-40 40 2/8 0.020

MW10 LF Periodically Periodically May 24, 2005 312.38 5-30 30 2/8 0.010

MW10D LF Periodically Periodically April 28, 2009 312.47 35-55 55 2/8 0.010

MW11 LF Periodically Periodically May 24, 2005 309.23 5-30 30 2/8 0.010

MW12 LF Periodically Periodically February 28, 2006 313.49 30-50 50 2/8 0.010

MW13 LF Periodically Periodically February 28, 2006 311.19 5-30 30 2/8 0.010

MW14 LF Periodically Periodically March 1, 2006 312.11 27-47 47 2/8 0.010

MW15 LF Periodically Periodically March 1, 2006 311.59 31-46 46 2/8 0.010

MW16 LF Periodically Periodically March 1, 2006 311.60 31-46 46 2/8 0.010

MW17 LF Periodically Periodically April 29, 2009 310.30 5-20 20 2/8 0.010

MW18 LF Periodically Periodically April 29, 2009 310.06 5-25 25 2/8 0.010

MW18D LF Periodically Periodically March 27, 2017 310.02 30-40 40 2/8.5 0.010

MW19 LF Periodically Periodically March 3, 2011 310.16 37-57 57 2/8 0.010

AS1 NS NM NS October 14, 2002 311.43 22-25 25 2/8 0.010

IJ1 NS NM NS March 27, 2017 NE 5-10 10 2/8.5 0.020

EXPLANATION:
feet bgs = Feet below ground surface
LF = Low-flow
NS = Not Sampled
NM = Not Measured
NE = Not Established
Wellhead elevations were resurveyed on 03/18/11 by Cardno using NAVD 88
MW10 and MW10D wellhead elevations were increased by 1.188" following retrofits for chem-ox injection on 09/16/14

031093.GW
Table 1
 APPENDIX A

PERSULFOXTM SAFETY DATA SHEET

 APPENDIX B

UNDERGROUND INJECTION CONTROL PERMIT

Bobby Thompson

From: Shaleen-Hansen, Mary (ECY) <[email protected]>

Sent: Thursday, March 23, 2017 12:57 PM
To: Bobby Thompson
Cc: Shaleen-Hansen, Mary (ECY)
Subject: RE: Cardno - Former Exxon Station 72427, UIC site 32616

Great.ThanksBobby.

IamgoingtoupdatetheUICsiteinformationandextendtheUICProgramconditionalruleauthorizationthrough2017
tousethe3UICwells,MW10,MW10D,andIJ1,toinjectproductsintothesubsurfaceattheformerExxon72427,at
2137NNorthgateWay,Seattle.

Ifadditionalinjectionsareneededpleaseforwardtomethepostinjectiongroundwatersamplingsulfateresultsfrom
thedowngradientwellspriortothenextinjection.

MaryShaleenHansen
DeptofEcologyWaterQualityProgram
(360)[email protected]

From:BobbyThompson[mailto:[email protected]]
Sent:Thursday,March23,201711:07AM
To:ShaleenHansen,Mary(ECY)<[email protected]>
Subject:RE:CardnoFormerExxonStation72427,afewquestions

HelloMary,

SulfateresultswerecollectedfromMW4on06/03/15:

1

WecantestMW12priortoinjectionifyouwish.

Atthistimeweonlyanticipate1injectionintoeachwell.

Ihaveattachedanupdatedmapshowingthenewinjectionwellmoreclearly.

Thanks,

Bobby

Robert Thompson
ASSISTANT PROJECT MANAGER
ENGINEERING & ENVIRONMENTAL SERVICES DIVISION
CARDNO

Direct +1 208 272 9180 Mobile +1 206 510 5855 Fax +1 206 575 9504
Address 250 Bobwhite Court, Suite 250, Boise, Idaho 83706
Email [email protected] Web www.cardno.com

This email and its attachments may contain confidential and/or privileged information for the sole use of the intended recipient(s). All electronically supplied data
must be checked against an applicable hardcopy version which shall be the only document which Cardno warrants accuracy. If you are not the intended recipient,
any use, distribution or copying of the information contained in this email and its attachments is strictly prohibited. If you have received this email in error, please
email the sender by replying to this message and immediately delete and destroy any copies of this email and any attachments. The views or opinions expressed
are the author's own and may not reflect the views or opinions of Cardno.

From:ShaleenHansen,Mary(ECY)[mailto:[email protected]]
Sent:Thursday,March23,201711:26AM
To:BobbyThompson<[email protected]>
Subject:RE:CardnoFormerExxonStation72427,afewquestions

Bobby,

Theshallowaquiferhasbeensampledforsulfatedowngradientbutnotthedeep.HastheNWcornerwells,MW4of
MW12,beensampled?

Doyouplanononlyoneinjectioneventat3wells?

IcouldnotfindIJ1onthesitemap.

MaryShaleenHansen
DeptofEcologyWaterQualityProgram
(360)[email protected]

From:BobbyThompson[mailto:[email protected]]
Sent:Thursday,March23,20178:31AM
To:ShaleenHansen,Mary(ECY)<[email protected]>
Cc:AndrewYonkofski<[email protected]>
Subject:CardnoFormerExxonStation72427
2

HelloMary,

CardnowouldliketoconductanadditionalroundofinjectionsatformerExxonStation72427nextweekaspartofsome
confirmationdrillingactivities.IhavetheoriginalUICpermitattached.Wewouldliketoinject330poundsofPersulfox
with240gallonsofpotablewaterintoMW10,MW10D,andawellthatwewillinstallnextweekIJ1.IJ1willbea4
groundwatermonitoringwelladvanced15feetbelowgroundsurface.Thewellwillbescreenedfrom10to15feet
belowgroundsurface.IhaveattachedamapshowingtheproposedlocationofthenewInjectionWell.

ThelastinjectioneventatthesiteoccurredonSeptember16,2014.Sulfateresultsforinjectionwells(MW10and
MW10D)anddowngradientwell(MW18)fromthemostrecentgroundwatersamplingeventbelow:

Pleaseletmeknowifyouhaveanquestionsorconcernswiththisplan.

Thanks,

Bobby

Robert Thompson
ASSISTANT PROJECT MANAGER
ENGINEERING & ENVIRONMENTAL SERVICES DIVISION
CARDNO

Direct +1 208 272 9180 Mobile +1 206 510 5855 Fax +1 206 575 9504
Address 250 Bobwhite Court, Suite 250, Boise, Idaho 83706
Email [email protected] Web www.cardno.com

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This email and its attachments may contain confidential and/or privileged information for the sole use of the intended recipient(s). All electronically supplied data
must be checked against an applicable hardcopy version which shall be the only document which Cardno warrants accuracy. If you are not the intended recipient,
any use, distribution or copying of the information contained in this email and its attachments is strictly prohibited. If you have received this email in error, please
email the sender by replying to this message and immediately delete and destroy any copies of this email and any attachments. The views or opinions expressed
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