Adsorption Review Questions and Problems
Adsorption Review Questions and Problems
Adsorption Review Questions and Problems
1. A unit operation wherein specific components of a fluid phase (gas or liquid) are
preferentially adhered to the surfaces of the solid
a. adsorption c. chemisorption
b. absorption d. leaching
5. Fifty parts of copperas and lime per million parts of dye house effluent removes
50% of the color. How much will be required to reduce the color to 5% if n= 8.5 ?
a.124.5 ppm c. 120.5 ppm
b. 130 ppm d. 126.5 ppm
6. Water contains organic color which is to be extracted with alum and lime. Five
parts of alum and lime per million parts of water will reduce the color to 25% of the
original color and 10 parts will reduce the color to 3.5%. Estimate how much alum and
lime as parts per million are required to reduce the color to 0.5% of the original color.
a. 16.4 c. 18.5
b. 14.8 d. 15.8
Economic adsorption factor refers to the amount of adsorbate per amount of adsorbent
used.
10. Two identical aqueous solutions containing valuable solute are colored by small
amounts of an impurity, to a different, extent. The dark solution has a color intensity of
50 units and the light solution has 20 color units, measured on the same arbitrary scale.
It is desired to treat an equal amount of light and dark solutions to a color unit of 0.5.
The equilibrium adsorption isotherm on activated carbon is given by Freundlich
Equation Y = mXn where n = 1 and m = 0.005 with Y = color units/kg solution and X =
color units adsorbed/kg carbon. The color scale is such that colors are additive, i.e.,
equal weights of solution of color 20 and 50 will give a solution of color (20+50)/2 = 35.
In a single stage process, will it be more economical of carbon to first blend the original
solutions and to treat the blend, or treat each separately to color 0.5 and to blend the
finished products ?
a. blend first, treat later c. both a and b
b. treat first, blend later d. none of these
11. The following data are for the adsorption of CO on wood charcoal at 0C. The
partial pressure P of CO is in mmHg while V is the volume of gas in cc, measured at
standard conditions, adsorbed by 2.964 g of charcoal.
P 73 180 309 .540 882
V 7.5 16.5 25.1 38.1 52.3
Determine the constants m and n of the Freundlich Equation. Use units of mmHg,
cc, and gram.
a. 17,2.0 c. 30, 1.7
b. 17, 1.37 d. 30,2.0
18. In case of physical adsorption, the difference between heat of adsorption and heat
of normal condensation is
a. equal to the heat of formation of surface compound
b. equal to the heat of wetting
c. zero
d. called integral heat of adsorption
19. Pick out the wrong statement Generally for physical adsorption, a gas of
a. higher molecular weight is adsorbed in preference to a gas of low molecular
weight , b. high critical temperature is adsorbed in preference to a gas of law
critical temperature
c. low volatility is adsorbed in preference to a gas of high volatility
d. both b and c
20. The change in enthalpy per unit weight of adsorbed gas when adsorbed on a gas-
free or "outgassed" adsorbent to form a definite concentration of adsorbate is called its
a. integral heat of adsorption c. differential heat of adsorption
b. heat of wetting d. heat of normal condensation
21. With an increase in concentration of the adsorbate the integral heat of adsorption
a. increases
b. decreases
c. remains unchanged
d. may increase or decrease; depends on type of adsorbate