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    B.SC 1st Year Syll

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    JayArora
    This document provides an overview of topics in organic chemistry including: 1) Classification and nomenclature of organic compounds, hybridization and molecular shapes, and induction, resonance, and hyperconjugation effects. 2) Stereochemistry including Fischer projections, cis-trans and syn-anti isomerism, chirality, and R/S nomenclature. 3) Reactions of aliphatic hydrocarbons including formation of alkanes, alkenes, and alkynes, and reactions such as halogenation, hydration, oxidation, and Diels-Alder reactions. Conformational analysis of cycloalkanes is also discussed.

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    B.SC 1st Year Syll

    Uploaded by

    JayArora
    611 views1 page
    This document provides an overview of topics in organic chemistry including: 1) Classification and nomenclature of organic compounds, hybridization and molecular shapes, and induction, resonance, and hyperconjugation effects. 2) Stereochemistry including Fischer projections, cis-trans and syn-anti isomerism, chirality, and R/S nomenclature. 3) Reactions of aliphatic hydrocarbons including formation of alkanes, alkenes, and alkynes, and reactions such as halogenation, hydration, oxidation, and Diels-Alder reactions. Conformational analysis of cycloalkanes is also discussed.

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    b.sc 1st year syll

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    This document provides an overview of topics in organic chemistry including: 1) Classification and nomenclature of organic compounds, hybridization and molecular shapes, and induction, resonance, and hyperconjugation effects. 2) Stereochemistry including Fischer projections, cis-trans and syn-anti isomerism, chirality, and R/S nomenclature. 3) Reactions of aliphatic hydrocarbons including formation of alkanes, alkenes, and alkynes, and reactions such as halogenation, hydration, oxidation, and Diels-Alder reactions. Conformational analysis of cycloalkanes is also discussed.

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    Download as docx, pdf, or txt
    611 views1 page

    B.SC 1st Year Syll

    Uploaded by

    JayArora
    This document provides an overview of topics in organic chemistry including: 1) Classification and nomenclature of organic compounds, hybridization and molecular shapes, and induction, resonance, and hyperconjugation effects. 2) Stereochemistry including Fischer projections, cis-trans and syn-anti isomerism, chirality, and R/S nomenclature. 3) Reactions of aliphatic hydrocarbons including formation of alkanes, alkenes, and alkynes, and reactions such as halogenation, hydration, oxidation, and Diels-Alder reactions. Conformational analysis of cycloalkanes is also discussed.

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    of 1

    Basics of Organic Chemistry Organic Compounds: Classification, and

    Nomenclature, Hybridization, Shapes of molecules, Influence of hybridization on


    bond properties. Electronic Displacements: Inductive, electromeric, resonance
    and mesomeric effects, hyperconjugation and their applications; Dipole moment;
    Organic acids and bases; their relative strength. Homolytic and Heterolytic fission
    with suitable examples. Curly arrow rules, formal charges; Electrophiles and
    Nucleophiles; Nucleophlicity and basicity; Types, shape and their relative stability
    of Carbocations, Carbanions, Free radicals and Carbenes. Introduction to types of
    organic reactions and their mechanism: Addition, Elimination and Substitution
    reactions. (6 Lectures) Stereochemistry: Fischer Projection, Newmann and
    Sawhorse Projection formulae and their interconversions; Geometrical isomerism:
    cistrans and, syn-anti isomerism E/Z notations with C.I.P rules. Optical
    Isomerism: Optical Activity, Specific Rotation, Chirality/Asymmetry, Enantiomers,
    Molecules with two or more chiral-centres, Distereoisomers, meso structures,
    Racemic mixture and resolution. Relative and absolute configuration: D/L and R/S
    designations. (18 Lectures) Chemistry of Aliphatic Hydrocarbons A. Carbon-
    Carbon sigma bonds Chemistry of alkanes: Formation of alkanes, Wurtz Reaction,
    Wurtz-Fittig Reactions, Free radical substitutions: Halogenation -relative reactivity
    and selectivity.

    B. Carbon-Carbon pi bonds: Formation of alkenes and alkynes by elimination


    reactions, Mechanism of E1, E2, E1cb reactions. Saytzeff and Hofmann
    eliminations. Reactions of alkenes: Electrophilic additions their mechanisms
    (Markownikoff/ Anti Markownikoff addition), mechanism of oxymercuration-
    demercuration, hydroborationoxidation, ozonolysis, reduction (catalytic and
    chemical), syn and anti-hydroxylation (oxidation). 1,2-and 1,4-addition reactions
    in conjugated dienes and, Diels-Alder reaction; Allylic and benzylic bromination
    and mechanism, e.g. propene, 1-butene, toluene, ethyl benzene. 15 Reactions of
    alkynes: Acidity, Electrophilic and Nucleophilic additions. Hydration to form
    carbonyl compounds, Alkylation of terminal alkynes. C. Cycloalkanes and
    Conformational Analysis Types of cycloalkanes and their relative stability, Baeyer
    strain theory, Conformation analysis of alkanes: Relative stability: Energy
    diagrams of cyclohexane: Chair, Boat and Twist boat forms; Relative stability with
    energy diagrams. (24 Lectures)

    Aromatic Hydrocarbons

    Aromaticity: Hckels rule, aromatic character of arenes, cyclic


    carbocations/carbanions and heterocyclic compounds with suitable examples.
    Electrophilic aromatic substitution: halogenation, nitration, sulphonation and
    Friedel-Crafts alkylation/acylation with their mechanism. Directing effects of the
    groups.

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