CHAPTER 1:

Blackbody Radiation
(3 Hours)
Dr. Ahmad Taufek Abdul Rahman
(DR ATAR)

School of Physics & Material Studies

Faculty of Applied Sciences
Universiti Teknologi MARA Malaysia
Campus of Negeri Sembilan
72000 Kuala Pilah
Negeri Sembilan
064832154 / 0123407500 / [email protected]
 Learning Outcome:
Plancks quantum theory
At the end of this chapter, students should be able to:
Explain briefly Plancks quantum theory and
classical theory of energy.
Write and use Einsteins formulae for photon energy,

hc
E hf

DR.ATAR @ UiTM.NS PHY310 - Modern Physics 2
 Need for Quantum Physics
Problems remained from classical mechanics that the special theory of
relativity didnt explain.
Attempts to apply the laws of classical physics to explain the behavior of
matter on the atomic scale were consistently unsuccessful.
Problems included:
Blackbody radiation
The electromagnetic radiation emitted by a heated object
Photoelectric effect
Emission of electrons by an illuminated metal

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 Quantum Mechanics Revolution
Between 1900 and 1930, another revolution took place in physics.
A new theory called quantum mechanics was successful in explaining
the behavior of particles of microscopic size.
The first explanation using quantum theory was introduced by Max
Planck.
Many other physicists were involved in other subsequent
developments

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 Blackbody Radiation
An object at any temperature is known to emit thermal radiation.
Characteristics depend on the temperature and surface properties.
The thermal radiation consists of a continuous distribution of
wavelengths from all portions of the em spectrum.
At room temperature, the wavelengths of the thermal radiation are mainly
in the infrared region.
As the surface temperature increases, the wavelength changes.
It will glow red and eventually white.

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 Blackbody Radiation, cont.
The basic problem was in understanding the observed distribution in the
radiation emitted by a black body.

Classical physics didnt adequately describe the observed

distribution.

A black body is an ideal system that absorbs all radiation incident on it.

The electromagnetic radiation emitted by a black body is called

blackbody radiation.

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 Blackbody Approximation
A good approximation of a black
body is a small hole leading to the
inside of a hollow object.
The hole acts as a perfect
absorber.
The nature of the radiation leaving
the cavity through the hole depends
only on the temperature of the
cavity.

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 Blackbody Experiment Results
The total power of the emitted radiation increases with temperature.

Stefans law:

P = s A e T4

The emissivity, e, of a black body is 1, exactly

The peak of the wavelength distribution shifts to shorter wavelengths as

the temperature increases.

Wiens displacement law

maxT = 2.898 x 10-3 m . K

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 Intensity of Blackbody
Radiation, Summary
The intensity increases with
increasing temperature.
The amount of radiation emitted
increases with increasing
temperature.
The area under the curve
The peak wavelength decreases
with increasing temperature.

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 Rayleigh-Jeans Law
An early classical attempt to explain blackbody radiation was the

Rayleigh-Jeans law.

2 c kBT
I ,T
4

At long wavelengths, the law matched experimental results fairly well.

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 Rayleigh-Jeans Law, cont.
At short wavelengths, there
was a major disagreement
between the Rayleigh-Jeans
law and experiment.
This mismatch became
known as the ultraviolet
catastrophe.
You would have infinite
energy as the wavelength
approaches zero.

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 Max Planck
1858 1847
German physicist
Introduced the concept of quantum
of action
In 1918 he was awarded the Nobel
Prize for the discovery of the
quantized nature of energy.

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 Plancks Theory of Blackbody
Radiation

In 1900 Planck developed a theory of blackbody radiation that leads to

an equation for the intensity of the radiation.
This equation is in complete agreement with experimental observations.
He assumed the cavity radiation came from atomic oscillations in the
cavity walls.
Planck made two assumptions about the nature of the oscillators in the
cavity walls.

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 Plancks Assumption, 1
The energy of an oscillator can have only certain discrete
values En.
En = n h
n is a positive integer called the quantum number
is the frequency of oscillation
h is Plancks constant
This says the energy is quantized.
Each discrete energy value corresponds to a different
quantum state.
Each quantum state is represented by the quantum
number, n.
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 Plancks Assumption, 2

The oscillators emit or absorb energy when making a transition from one
quantum state to another.
The entire energy difference between the initial and final states in the
transition is emitted or absorbed as a single quantum of radiation.
An oscillator emits or absorbs energy only when it changes quantum
states.
The energy carried by the quantum of radiation is E = h .

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 Energy-Level Diagram
An energy-level diagram
shows the quantized energy
levels and allowed
transitions.
Energy is on the vertical axis.
Horizontal lines represent the
allowed energy levels.
The double-headed arrows
indicate allowed transitions.

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 More About Plancks Model

The average energy of a wave is the average energy difference between

levels of the oscillator, weighted according to the probability of the wave
being emitted.

This weighting is described by the Boltzmann distribution law and gives

the probability of a state being occupied as being proportional to e E k T
B

where E is the energy of the state.

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 Plancks Model, Graph

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Plancks Wavelength Distribution
Function
Planck generated a theoretical expression for the wavelength
distribution.
2hc 2
I ,T 5 hc k T
e B
1
h = 6.626 x 10-34 J.s
h is a fundamental constant of nature.
At long wavelengths, Plancks equation reduces to the Rayleigh-Jeans
expression.
At short wavelengths, it predicts an exponential decrease in intensity with
decreasing wavelength.
This is in agreement with experimental results.
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 Einstein and Plancks Results

Einstein re-derived Plancks results by assuming the oscillations of the

electromagnetic field were themselves quantized.
In other words, Einstein proposed that quantization is a fundamental
property of light and other electromagnetic radiation.
This led to the concept of photons.

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 Plancks quantum theory
Classical theory of black body radiation
Black body is defined as an ideal system that absorbs all the
radiation incident on it. The electromagnetic (EM) radiation
emitted by the black body is called black body radiation.
From the black body experiment, the distribution of energy in
black body, E depends only on the temperature, T.

E k BT (1.1)

where k B : Boltzmann's constant

T : temperature in kelvin
If the temperature increases thus the energy of the black body
increases and vice versa.

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 The spectrum of EM radiation emitted by the black body
(experimental result) is shown in Figure.

Experimental
result

Rayleigh -Jeans
theory Classical
physics
Wiens theory

From the curve, Wiens theory was accurate at short

wavelengths but deviated at longer wavelengths whereas the
reverse was true for the Rayleigh-Jeans theory.
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 The Rayleigh-Jeans and Wiens theories failed to fit
the experimental curve because this two theories
based on classical ideas which are
Energy of the EM radiation is not depend on its
frequency or wavelength.
Energy of the EM radiation is continuously.

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 In 1900, Max Planck proposed his theory that is fit
with the experimental curve in Figure at all
wavelengths known as Plancks quantum theory.
The assumptions made by Planck in his theory are :
The EM radiation emitted by the black body is in
discrete (separate) packets of energy. Each
packet is called a quantum of energy. This
means the energy of EM radiation is quantised.
The energy size of the radiation depends on its
frequency.

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 According to this assumptions, the quantum of the
energy E for radiation of frequency f is given by

E hf (1.2)

where h : Planck' s constant 6.63 10 34 J s

Since the speed of EM radiation in a vacuum is

c f
then eq. (1.2) can be written as
hc
E (1.3)

From eq. (1.3), the quantum of the energy E for
radiation
DR.ATAR @ UiTM.NS is inversely proportional
PHY310 - Modern Physics to its wavelength. 25
 It is convenient to express many quantum energies in
electron-volts.
The electron-volt (eV) is a unit of energy that can be
defined as the kinetic energy gained by an electron
in being accelerated by a potential difference
(voltage) of 1 volt.
19
Unit conversion: 1 eV 1.60 10 J
In 1905, Albert Einstein extended Plancks idea by
proposing that electromagnetic radiation is also
quantised. It consists of particle like packets (bundles)
of energy called photons of electromagnetic radiation.
Note:
For EM radiation of n packets, the energy En is given
by
En nhf (1.4)

DR.ATAR @ UiTM.NS
where n : real number 1,2,3,...
PHY310 - Modern Physics 26
 Photon
Photon is defined as a particle with zero mass
consisting of a quantum of electromagnetic
radiation where its energy is concentrated.
A photon may also be regarded as a unit of energy
equal to hf.
Photons travel at the speed of light in a vacuum. They
are required to explain the photoelectric effect and
other phenomena that require light to have particle
property.
Table shows the differences between the photon and
electromagnetic wave.
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 EM Wave Photon
Energy of the EM wave Energy of a photon is
depends on the intensity of proportional to the
the wave. Intensity of the frequency of the EM wave
wave I is proportional to the where
squared of its amplitude A2
where
E f
IA 2

Its energy is continuously Its energy is discrete as

and spread out through the shown in Figure 9.2b.
medium as shown in Figure
9.2a.

Photon

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 Example 1 :

A photon of the green light has a wavelength of 740 nm.

Calculate
a. the photons frequency,
b. the photons energy in joule and electron-volt.
(Given the speed of light in the vacuum,
c =3.00108 m s1 and Plancks constant,
h =6.631034 J s)

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 Solution :

740 10 9 m
a. The frequency of the photon is given by

c f
3.00 108 740 10 9 f
f 4.05 1014 Hz
b. By applying the Plancks quantum theory, thus the photons
energy in joule is
E hf
E 6.63 10 34 4.05 1014
E 2.69 10 19 J
and its energy in electron-volt is
2.69 10 19
E 19 E 1.66 eV
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1.60PHY310 30
 Example 2 :
For a gamma radiation of wavelength 4.621012 m
propagates in the air, calculate the energy of a photon
for gamma radiation in electron-volt.
(Given the speed of light in the vacuum, c =3.00108 m s1 and
Plancks constant, h =6.631034 J s)

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 Solution :
12
4.62 10 m
By applying the Plancks quantum theory, thus the energy
of a photon in electron-volt is

E
hc
E
6.63 10 3.00 10
34 8

4.62 10 12
E 4.31 10 14 J
4.31 10 14

1.60 10 19
E 2.69 10 5 eV

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 Thank You

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