Analizer H2S Manual PDF

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By Kristie Seagroves at 11:21 am, Dec 15, 2011

SUBMITTAL PACKAGE 3K401-22742

FOR

SOLAR TURBINES, INC.


PURCHASE ORDER NO. ECP005904

TECO-3K401E-1600-H2S

IN-STREAM H2S ANALYZER

Sierra Monitor Corporation


Milpitas, California

Q012194

SMC Sales Order No. 113442-00 November 17, 2011


TABLE OF CONTENTS

REFERENCE: Solar Turbines, Inc. Page 1 of 1


Purchase Order No. ECP005904
Teco- 3K401E-1600-H2S
In-stream H2S Analyzer

1. Equipment List & Recommended Spare Parts


2. Drawings
KANA0006-A 4400 Outline Dimensions
CCF09-822-B-1 5100-99-IT Outline Dimensions
KANA0003-B 4400 Installation Instructions
A14039-2 4400 Mechanical Assembly
A27062-3 4400 Flow Assembly
A2706311 A27063-1 Flow Harness
3. Brochures and Data Sheets
Model 4400 In-Stream Analyzer
Model 5100-99-IT Transmitter
4. Instruction Manuals
T14004 Model 4400 In-Stream H2S Analyzer
T12005 Model 5100-99 IT Transmitter, 4-20mA
T15006 Model 1250-XX Calibrator

SMC Sales Order No. 113442-00 November 17, 2011


Section 1 Equipment List
Solar Turbines, Inc
Purchase Order No. ECP005904
Teco- 3K401E-1600-H2S
In-Stream H2S Analyzer

SMC Sales Order No. 113442-00 November 17, 2011


EQUIPMENT LIST

REFERENCE: Solar Turbines, Inc. Page 1 of 1


Purchase Order No. ECP005904
Teco- 3K401E-1600-H2S
In-stream H2S Analyzer

Item Model Description Quantity

1 4400-10 In-Stream H2S Analyzer 1


2 5100-99-IT-AL-02 Display/Transmitter for 4400-10 with Relay 1

Recommended Spare Parts


(Not Scope of PO Supply)
3 SPMN26105 Sensor Assembly, H2S for 4400-10 1
4 SPM22063 Flow Harness 1
Maintenance Kit (Consist of 1 Spare Sensor and 2
5 SPM27064 Flow Harness 1
6 SPM64017 Filter Element 1
Calibrator/Calibration Accessories
(Not Scope of PO Supply)
7 1250-01 Gas Sensor Calibrator Kit, Type A 1
8 1260-05 Gas Cylinder, H2S-N2, 25ppm (Type A) 1

SMC Sales Order No. 113442-00 November 17, 2011


Section 2 Drawings
Solar Turbines, Inc
Purchase Order No. ECP005904
Teco- 3K401E-1600-H2S
In-Stream H2S Analyzer

SMC Sales Order No. 113442-00 November 17, 2011


G
S
P
G
S
P
CAUTION:
THIS ASSY CONTAINS SEVERAL
VERY FRAGILE PARTS.
ASSEMBLE WITH CARE
DO NOT STRESS PARTS.
Section 3 Brochures Data Sheets
Solar Turbines, Inc
Purchase Order No. ECP005904
Teco- 3K401E-1600-H2S
In-Stream H2S Analyzer

SMC Sales Order No. 113442-00 November 17, 2011


Model 4400
In-Stream Hydrogen Sulfide Analyzer

The Model 4400 In-Stream Hydrogen Sulfide Analyzer


is used to continuously verify the H2S content of a natu-
ral gas sample for the presence of 0-100 ppm levels of
Hydrogen Sulfide. This system is used to insure that
H2S levels in natural gas collection lines remains at ac-
ceptable levels to help guard against the corrosive ef-
fects of H2S on compressors, pipelines and process
equipment. It is intended for continuous monitoring prior
to the addition of odorants to the gas.

The Sierra Monitor Model 4400 provides the user with a


low-cost, easy-to-use solution to effective monitoring of
natural gas streams. This system accurately measures
H2S concentration in the 0-100 ppm range. Fast re-
sponse of 90% of step change within 30 seconds en- A 4-20 mA linear signal proportional to sample concen-
ables the user to respond quickly to changes in natural tration is provided from the sensor assembly. This sig-
gas supply conditions to prevent product contamination. nal can interface with a Sierra Monitor Model 4107-99
Transmitter/Display, a single channel controller, the Sen-
There is minimal maintenance with the Model 4400 with try multi-channel controller or most industry standard
no tapes to replace, no conditioning solutions, no me- controllers or PLCs.
chanical stream blenders to calibrate. Calibration is easy
with external application of span gas and simple one The Model 5100-99-IT-AL Transmitter/Display option can
person adjustments. Calibration and swapping of the accept the 4-20 mA signal from the Model 4400-10 and
gas sensor is a quick and simple operation performed provide digital display of the H2S concentration, dual
every two weeks. concentration alarm contacts, 4-20 mA output and se-
rial MODBUS communication. The Model 5100-99-IT-
The 4400-10 receives a low pressure natural gas slip- AL can be mounted directly to the Model 4400 H2S Ana-
stream sample. A flow controller in the system delivers lyzer or at a remote location. The Model 5100-99-IT-AL
a constant flow to the gas sensor and allows for easy is mounted in an explosion proof enclosure available in
calibration and maintenance. An in-line coalescing filter aluminum or stainless steel enclosures.
protects the system from sample contaminants.

Features Benefits

No tapes to replace or conditioning solutions Minimal maintenance, no hazardous material to


dispose

Fast response Prevention of product contamination

Simple one-person adjustments Easy calibration, minimal service time

Sierra Monitor Corporation 1991 Tarob Court Milpitas, CA 95035 USA (408) 262-6611 (800) 727-4377 Fax: (408) 262-9042
Model 4400
In-Stream Hydrogen Sulfide Analyzer
Specifications:
4400 In-Stream Analyzer 5100-99-IT Transmitter/Display
Power: 24VDC Power: 24VDC

Output: 4-20 mA = 0-100 ppm H2S Operating


Temperature Range: -40 to 50oC (-40 to 122oF)
Environmental:
Temperature Range Display: Fixed and Scrolling LED
Operating:: -20 to 50oC (-4 to 122oF)
Storage: -40 to 50oC (-40 to 122oF) Optional Alarms: Dual level alarms (8A) plus
Humidity: 0-95% RH (non-condensing) fault alarm (4A)

Sensor: Serial Output: Bi-directional RS-485


Range: 0-100 ppm Hydrogen Sulfide MODBUS protocol
Type: Electrochemical Mechanical:
Life: Approximately 1 year in cycled Housing: Aluminum: Epoxy-coated, die-cast,
service copper-fire aluminum
Response: <30 seconds to 90% FS Stainless Steel: 316 Stainless Steel
Dimensions( WxHxD):
Mechanical: Aluminum: 6.0 x 4.4 x 4.9 in.
Area Classification: Div 1, Class 1, Groups B,C,D 316 Stainless Steel: 5.9 x 4.8 x 4.9 in.
Enclosure: NEMA-1 with removable cover panel Weight:
Mounting: installs on 9 x 7 H Frame Aluminum: 2.7 lbs (1.3 Kg)
Connections: 3 position terminal strip with 316 Stainless Steel: 5.4 lbs (2.6 Kg)
separate conduit
Dimensions (WxHxD): 9.0 x 11.0 x 4.0 inches
(22.9 x 27.9 x 10.2 cm)
Weight: 5 lbs (2.2 Kg)

Warranty: 2 years as non non-consumable items

Ordering Information:

4400-10 In-Stream Hydrogen Sulfide Monitor


Single Point Explosion Proof Transmitter/Display
Model Enclosure Relay/Connection
5100-99-IT -XX -XX -00 -0 -0 -0
- A1 = AL 3/4 NPT - 01 = No Relays
- A2 = AL M20 x 1.5 - 02 = Relays/Aux. Conn.
- S1 = SS 3/4 NPT
- S2 = SS M20 x 1.5

Model 5100-99-IT-AL Transmitter/Display

Sierra Monitor Corporation 1991 Tarob Ct. Milpitas, CA 95035 (408) 262-6611 800-727-4377 FAX: (408) 262-9042
Visit our Web site at: www.sierramonitor.com E-Mail: [email protected]
2011 by Sierra Monitor Corporation
Sentry IT Series
5100-99-IT 4-20mA Transmitter

Easily interface sensor device to 4-20mA,


Modbus, relays or Sentry bus

The IT Toxic Series 4-20mA Transmitter requires


minimal maintenance and has continuous self-
diagnostics that will automatically detect and
indicate any fault condition. This transmitter
interfaces sensor devices to other devices using
RS-485 Modbus RTU communications, a three or
four wire 4-20 mA analog output signal, or directly
to Sentry Controllers via Sentrybus. By integration
of IT modules into a Sentry system the user gains
the capability of system Modbus serial
communications, extensive diagnostic features,
WebServer interface, multiplexed sensor wiring and
field-proven reliability.

Sentry IT technology has the benefits of: Non-intrusive calibration and set-up
Non-intrusive, one-person calibration and best Extensive diagnostics for reliability
in industry calibration frequencies for reduced Choice or combination of outputs:
maintenance costs (depending upon
9 4-20 mA output (3 or 4 wire)
sensor/device)
9 Serial RS-485 Modbus RTU interface
User-friendly, 8-character, fixed and scrolling
LED display for ease of set-up and calibration 9 SMC Sentry digital bus Interface
Cast aluminum or 316 Stainless Steel 9 Standard 2 Amp Trouble relay
enclosures for Class I, Div. 1, Groups B, C, D 9 Optional 8 Amp Integral High/Low relays
areas
Comprehensive user-friendly menus

Specifications:
Output: Enclosure:
Display: Fixed and Scrolling LED Material Standard:
Relays: 2 Amp Trouble all SPDT Polyester powder-coated, sand-cast,
8 Amp, High Alarm, Low Alarm (optional) copper-free aluminum
Analog Output: ISA Standard Type 3 or Type 4(see Fig. 1.1) Material Stainless Steel Option:
Analog 4-20 mA (Trouble 2.5 mA, 316 Stainless Steel
Calibration 1.5 mA) Enclosure Hazardous Location Approvals:
Signal Outputs: Sentry bus FM, ATEX, CSA
Serial RS-485 Modbus RTU Dimensions: 7.5 x 5.0 x 4.8 in. AL, 7.5 x 5.0 x 4.4 in. SS

Input: (H x W x D) (21.6 x 12.7 x 12.2 cm.)


Digital Input: Normally open digital Weight: 2.7 lb. (1.3 Kg) standard Aluminum enclosure
Analog Input (supervised or non-supervised) 5.4 lb. (2.6 Kg) 316 Stainless Steel
4-20 mA Housing: NEMA 4X
Electrical Classification:
Electrical Data: FM Approved: Explosion proof, Class 1, Div. I, Groups B, C, D
Power consumption: 2 watts maximum Class I, Zone 1, Groups IIB + H2 IP66
Connection type: 3 wire
Input voltage: 24 VDC nominal: 10-30VDC Modbus:
Baud: 38400 (Adjustable 2400 38400 Baud)
Operating Range: Parity: None
o
Ambient Temp ( F):
o
5 to 122 F Stop bit: 1
o o Data bits: 8
Ambient Temp ( C): -15 to 30 C
Flow Control: None
Relative Humidity: 15 90%
Memory map available from Sierra Monitor

Warranty: Limited Warranty 2 years


Specifications subject to change without notice

Sierra Monitor Corporation 1991 Tarob Ct. Milpitas, CA 95035 (408) 262-6611 (800) 727-4377 Fax: (408) 262-9042
Web site: www.sierramonitor.com E-Mail: [email protected]
07/09 Rev. A1
5100-99-IT 4-20mA Transmitter

Ordering Information:
Relay/ Remote
Model Enclosure Connection Output Protection Option
5100 - XX - IT - XX - XX - XX - X - X
5100 Series - 99 = 4-20mA - IT Series - AL = AL - 01 = No Relays - 00 = Standard - 0 = Standard - 0 = None
Transmitter - SS = SS - 02 = Relays - 1 = Marine
- 2 = Conformal

Figure 1.1
3-wire and 4-wire
4-20mA output

Sierra Monitor Corporation 1991 Tarob Ct. Milpitas, CA 95035 (408) 262-6611 (800) 727-4377 Fax: (408) 262-9042
Web site: www.sierramonitor.com E-Mail: [email protected]
07/09 Rev. A1
Gas Sensor Accessories
Sierra Monitor offers a variety of accesso-
ries for gas sensor modules to aid the user
in calibration, placement and use of gas
sensor modules to ensure accurate and
reliable monitoring of hazardous gases.

CALIBRATORS
1200-26 Calibration Gas Delivery System
The Model 1200-26 Calibration Gas Delivery System provides
calibration gas for Combustible Gas, Carbon Monoxide, or Oxy-
gen Deficiency gas detection monitors. This system consists of
disposable pressure vessels (2 cylinders supplied with each sys-
tem) containing calibration gas and a non-disposable pressure
and flow regulation system. Gas flow is controlled in two steps
with a regulator and flow meter to conserve gas and to accu-
rately regulate flow.
Model 1200-26

The 1200-26 and the Methane calibration gas cylinders are ap-
proved for calibration of FM Approved Sierra Monitor Combus- Specificationsfor
Specifications for1260
1260Series
SeriesGas
GasCylinders:
Cylinders:
tible Gas Sensors.
TypeAAGas
Type GasCylinders
Cylinders(Combustible
(CombustibleGas Gas- -LEL,
LEL,CO,CO,HH2 , 2Air)
, Air)
Specificationsfor
Specifications for1200-26
1200-26 Dimensions(cylinder):13.75
Dimensions (cylinder):13.75xx3.253.25in.
in.(34.9
(34.9xx8.28.2cm)
cm)
Dimensions:
Dimensions: 4.0xx7.0
4.0 7.0xx3.0
3.0in.
in.(10.2
(10.2xx17.8
17.8xx7.6
7.6cm)
cm) Weight(Cylinder):
Weight (Cylinder): 2.3 2.3lb.
lb.(1.05
(1.05Kg) Kg)
Weight:
Weight: 2.75lblb(1.24
2.75 (1.24kg.)
kg.)(including
(includingcylinder)
cylinder) Cylinderpressure:
Cylinder pressure: Max Max1000
1000psig psig
FlowRate:
Flow Rate: 50-500cc/min
50-500 cc/min Cylindervolume:
Cylinder volume: 3.6cu.
3.6 cu.ft.ft.(105
(105liters)
liters)atatSTP
STP
CylinderPressure:
Cylinder Pressure: Max180
Max 180psi psi
CylinderVolume:
Cylinder Volume: 0.27
0.27cu.
cu.ft.
ft.(7.7
(7.7liters)
liters)at
atSTP
STP
TypeAAGas
Type GasCylinders
Cylinders(H (H 2S for 4101/5100-05)
1250-XX Calibrator Kit Dimensions(cylinder):13.5
Dimensions (cylinder):13.5xx3.5
3.5in. in.(34.3
(34.3xx8.98.9cm)
cm)
Weight(Cylinder):
Weight (Cylinder): 1.8 1.8lb.
lb.(0.8
(0.8Kg) Kg)
The 1250-XX Calibrator Kit is used to deliver calibration gas for Cylinderpressure:
Cylinder pressure: Max Max500500psigpsig
combustible gases and a wide variety of toxic gas detection Cylindervolume:
Cylinder volume: 2.0cu.
2.0 cu.ft.ft.(57
(57liters)
liters)atatSTP
STP
modules including Carbon Monoxide, Hydrogen, Combustible
Gas, Hydrogen Sulfide, Chlorine, Sulfur Dioxide, Nitric Oxide, TypeBBGas
Type GasCylinders
Cylinders(SO(SO22,,NO
NO2 ,2 ,NO)
NO)
Nitrogen Dioxide and Zero Dimensions(cylinder):16.25
Dimensions (cylinder):16.25xx4.0 4.0in.
in.(41.3
(41.3xx10.2
10.2cm)
cm)
Weight(Cylinder):
Weight (Cylinder): 1.751.75lb.
lb.(0.8
(0.8Kg)
Kg)
Grade Air. Other gases are
Cylinderpressure:
Cylinder pressure: Max Max480
480psig psig
available, contact Sierra Cylindervolume:
Cylinder volume: 2.6cu.
2.6 cu.ft.ft.(74
(74liters)
liters)atatSTP
STP
Monitor for the latest infor-
mation. There are three TypeCCGas
Type GasCylinders
Cylinders(CI(CI22))
versions of the calibration Dimensions(cylinder):12.25
Dimensions (cylinder):12.25xx3.25 3.25in.
in.(31.1
(31.1xx8.28.2cm)
cm)
kit available depending Weight(Cylinder):
Weight (Cylinder): 2.2 2.2lb.
lb.(1.0
(1.0Kg) Kg)
upon the specific calibra- Cylinderpressure:
Cylinder pressure: Max Max18001800psig psig
tion gas required. Each kit Cylindervolume:
Cylinder volume: 3.7cu.
3.7 cu.ft.ft.(104
(104liters)
liters)atatSTP
STP
contains a regulator, cali-
bration adapter and carry- 9210-00 Permeation Type Calibrator
ing case. The individual
calibration gas cylinders The 9210-00 Permeation Type Calibrator with the individual per-
(Series 1260) are sold meation tube for the specific gas required offers a unique means
separately. of generating a desired gas. This device has the advantages of
a wide selection of gas types, long life, and is an economical
solution for the regular calibration of a large number of toxic
Model 1250-01 Calibration Kit
sensors. Most popular applications are ammonia and hydrogen
Type A (with cylinder) sulfide.
Sierra Monitor Corporation 1991 Tarob Ct. Milpitas, CA 95035 (408) 262-6611 800-727-4377 FAX: (408) 262-9042
Visit our Web site at: www.sierramonitor.com E-Mail: [email protected]
ACCESSORIES Gas Sensor Accessories
SAMPLE DRAW PRODUCTS 5311-00 Rainshield
Sample draw products are used in applications in which the sensor The Rainshield is mounted over the sensor head to protect the sen-
cannot be installed directly at the gas sensing location due to poor sor from direct exposure to rain, hosedown and other splashing liq-
accessibility or the harshness of the environment. Sample is con- uids.
tinuously drawn from the sensing location to the sensor at a more
suitable location.

The primary component of the sample draw product is a venturi


manifold that uses a continuous flow of driver air to pull a slight vacuum
through the sample supply line drawing the sample into the manifold
cavity connected to the sensor.

5311-00

5394-00 Duct Mount Fitting


The Duct Mount Fitting facilitates installation of the gas sensor mod-
ule onto an air duct. The fitting also includes the 5360-00 calibration
5398-01 gas delivery fitting so that calibration gas can be delivered to the
5398-02 sensor with out removing the module from the duct.
5399-01

5399-01 Sample Draw Fitting


The sample manifold assembly is the 5399-01 Sample Draw Fitting.
Sample stream draw and flow control is provided by the user.

5398-01 Sample Draw Assembly


The 5398-01 Sample Draw Assembly is a complete sample draw 5360-00 5394-00
assembly including the sample draw fitting, flow metering assembly,
plus the driver air, sample and exhaust fittings. This allows accurate
adjustment of sample flow using the signal flow meter located on the CALIBRATION ADAPTERS
flow metering assembly.
The Sierra Monitor Gas sensor modules are designed for easy cali-
bration. The standard calibration adapter screws over the head of
5398-02 Sample Draw/Dilution Assembly sensor. Then calibration gas is fed through a tube connected onto
For applications where the expected gas concentration is either higher the adapter.
than maximum range of the sensor or sufficiently high to significantly Most Sierra Monitor gas sensor modules are equipped with a mag-
reduce sensor life with extended exposure, the 5398-02 Sample Draw/ netic switch to signal the sensor module that calibration is being per-
Dilution Assembly is recommended. This assembly adds a second formed. The magnetic calibration adapter is used to control this
flow meter for control of dilution air. Adjustment of sample and dilu- switch. When the adapter is attached to the sensor the switch closes
tion air flow meters achieves the dilution ratio required. Concentra- to indicate the tart of calibration. The sensor module will then hold
tions displayed on the sensor controller must then be multiplied by the present output until the magnetic calibration adapter is removed
the dilution factor to arrive at actual consecrations. signaling completion of calibration.

There are two calibration adapters available, the 5358-00 Magnetic


SENSOR MOUNTING PRODUCTS Calibration Adapter and the 5358-01 Standard (non-magnetic) Cali-
5360-00 Calibration Gas Delivery Fitting bration Adapter. The magnetic adapters are needed when the user
needs to hold the current value during calibration to avoid nuisance
The Calibration Gas Delivery Fitting provides the ability to deliver the alarms and the standard (non-magnetic) adapter if necessary dur-
gas to the sensor module in a remote location. A tube fitting enables ing global calibration.
the operator to direct calibrations gas flow to the sensor at any time
desired.

Sierra Monitor Corporation 1991 Tarob Ct. Milpitas, CA 95035 (408) 262-6611 800-727-4377 FAX: (408) 262-9042
Visit our Web site at: www.sierramonitor.com E-Mail: [email protected]
2006 by Sierra Monitor Corporation Printed in U.S.A. Rev. A 5/23/06
Section 4 Instruction Manuals
Solar Turbines, Inc
Purchase Order No. ECP005904
Teco- 3K401E-1600-H2S
In-Stream H2S Analyzer

SMC Sales Order No. 113442-00 November 17, 2011


Model 4400
IN STREAM HYDROGEN
SULFIDE MONITOR
Instruction Manual
TABLE OF CONTENTS

PAGE
1. PRODUCT DESCRIPTION
1.1. General 1
1.2. Description 1
1.2.1. Sample Flow Controller 1
1.2.2. Sensor & Transmitter 1
2. CAUTIONS WARNINGS AND RECOMMENDATIONS
2.1. Introduction 2
2.2. Cautions 2
2.2.1. Wiring 2
2.2.2. Natural Gas Hazards 2
2.2.3. Hydrogen Sulfide Hazards 2
2.2.4. Input Pressure Regulation 2
2.3. Preventative Maintenance 2
3. INSTALLATION
3.1. Site Selection 3
3.2. Monitor Installation 3
3.3. Controller Installation 3
3.4. Interface wiring 3
3.5. Sample Line Connection 3
4. OPERATION AND CALIBRATION
4.1. Operation 4
4.1.1. Power-up 4
4.1.2. Flow Control 4
4.2. Calibration 4
4.2.1. Preparation 4
4.2.2. Sensor Cycle 4
4.2.3. Calibration Procedure (Model 4001 Controller) 5
4.2.4. Calibration Procedure (Model 5100-99-IT) 6
4.3. Maintenance 7
4.3.1. Coalescing Filter 7
4.3.2. Sample Harness 7
4.3.3. Sensor Replacement 7
5. SPECIFICATIONS 8

6. LIMITED WARRANTY 8

Model 4400 In-Stream Hydrogen Sulfide Monitor (03/09)


Model 4400
In Stream Hydrogen Sulfide Monitor

APPLICABILITY & EFFECTIVITY

Effective for all Model 4400 systems manufactured after May 1, 1997.

Instruction Manual Part Number T14004


Rev A1
Instruction Manual
1. Product Description

1.1 General
The Model 4400 In-Stream Hydrogen Sulfide Ana-
lyzer (Figure 1.1) is a fixed installation system de-
signed for continuous analysis of a natural gas
sample for the presence of 0-100 ppm levels of
Hydrogen Sulfide. The system is used to insure
that Hydrogen Sulfide levels in natural gas collec-
tion lines remain below acceptable levels. It is in-
tended for continuous monitoring prior to the addi-
tion of odorants to the gas.

1.2 Definition
The Model 4400-10 is a monitor which is used in
conjunction with a controller. The following are
the components of the monitor.
1.2.1 Sample Flow Control (Figure 1.2) Figure 1.2
Sample System Flow Diagram
The Model 4400 receives a low pressure natural
gas sample, analyzes the sample for the presence
of Hydrogen Sulfide and vents the sample. A flow Calibration Gas Input port
controller delivers a constant flow to the sensor and Sample Flow Control rotameter
allows for easy calibration and maintenance.
System Flow Harness
The sample flow portion of the Model 4400 includes: Sample Flow Regulation
Sample line input Sensor Manifold
Sample Control Valve 1.2.2 Sensor & Transmitter
Coalescing Filter
The sensor and transmitter includes:
Transmitter mounting base
Fully encapsulated transmitter electron-
ics
Sensor assembly
The sensor electronics provides a 4-20 mA current
loop which is proportional to the full scale sensitivity
of the sensor (0-100 ppm). This signal can interface
to any standard industrial controller, including the
5100-99-IT Display/Tranmitter Modules, Models
4001 or 4011 Single Channel Controllers or Sentry
Controller available from Sierra Monitor
Corporation. Integral features of the sensor
electronics are:
Electrical fault indication (0 mA) to
controller.
Sensor protective circuitry to maintain
operational readiness of sensor during
Figure 1.1 power off periods.
Model 4400 In-Stream H2S Analyzer

Model 4400 In-Stream Hydrogen Sulfide Monitor (03/09) Page: 1


Instruction Manual
2. Cautions Warnings and Recommendations stream and to monitor for the presence of low con-
centrations of Hydrogen Sulfide. Standard safety
2.1 Introduction
practices applicable to Hydrogen Sulfide hazards
Although the system is designed and constructed should be observed due to the possibility of the pres-
for installation and operation in industrial applica- ence of high levels of toxic gas in the stream or in
tions including hostile environments, caution the work vicinity.
should be taken to insure that the installation is made 2.2.4 Input Pressure Regulation
in compliance with this instruction manual and that
certain procedures and conditions are avoided. The system is designed to accept low sample stream
pressures only and reliable pressure regulation must
This chapter discusses the necessary cautions. be provided in-line prior to the delivery of the sample
Read the entire chapter prior to installation of the to the analyzer flow regulator.
equipment.
NOTE: The regulated sample pressure delivered
2.2 Cautions to the sampling system must be maintained between
15 and 100 psi to insure proper functioning of the
2.2.1 Wiring
filter and flow control systems. The sampling sys-
All wiring must be installed in compliance with NEC tem must be installed vertically and insulated against
practices for working in a Class I, Division 2 envi- continuous vibration to insure proper operation.
ronment. Proper grounding of supply wiring, ap- 2.3 Preventative Maintenance (See Section 4.2)
propriate conduit and fittings and explosion proof
sealing must be used. In addition to calibration periodic preventative main-
tenance is required as follows:
Avoid installing the system where it will be unnec-
essarily exposed to wind, dust, water (esp. direct 1. The collection bulb on the coalescing filter
hose down), shock, or vibration. Observe tempera- must be bled at any time liquid builds to the
ture range limitations. bottom of the filter element.
The sample flow controller should not be painted. 2. The coalescing filter element must be re-
Paint may contain compounds which will contami- placed when it is discolored.
nate the sensor. Paint will also cause clogging of 3. The replaceable flow system harness must
the breathing surface of the sensor. The flow con- be replaced when it is sufficiently dirty to
troller should be tagged DO NOT PAINT. restrict sample flow. This will occur when
2.2.2 Natural Gas Hazards the clear tubing in the harness has discol-
ored so that it is no longer transparent.
Natural gas is VERY COMBUSTIBLE! The lower
explosive limit is 5.0% by volume and the gas in the 4. Inspect the sample flow monitor visually
sample stream is 100% by volume. Natural gas is to determine if dust or dirt build up needs
lighter than air, the specific gravity is 0.665 (air to be removed. This cleaning should be
specifc gravuty is 1.0). Extreme caution should be done with dry instruments such as com-
taken to avoid accumulation of natural gas in any pressed air, cloth wipes or whisk broom.
containment where an explosive mixing with air can 5. Insure that threads are kept clean and prop-
occur, also to avoid generating any ignition source. erly lubricated.
Area classification and declassification regulations
should be strictly enforced including the use of por-
table combustible gas detection instruments prior
to opening the explosion proof enclosures.
2.2.3 Hydrogen Sulfide Hazards
This system is designed to operate in a natural gas

Page: 2 Model 4400 In-Stream Hydrogen Sulfide Monitor (03/09)


3. Installation Instruction Manual
3.1 Site Selection
Select a location for the monitor which is remote
from the controller to insure that leaked natural gas
is fully ventilated and is not accumulated in explo-
sive concentrations. Other considerations include:
Keep sample exhaust away from
structures which may cause gas accu-
mulation.
Wiring must be installed between the
monitor and the controller following site
classification regulations.
Tubing must be installed between the Figure 3.1
Mounting Post
monitor and the sample location follow-
ing site classification and safety regula- 3.5 Sample Line Connection
tions.
To provide for correct sample handing:
3.2 Monitor Installation 1. At the sample source, provide pressure
Install a mounting post following the dimensional regulation such that the sample line can
instructions in figure 3-1. never exceed 100 psi.
Install the monitor by passing the four mounting 2. From the sample source provide a 1/4 OD
studs through the holes on the H bracket and se- stainless steel tube for connection to the
cure with the supplied washers and nuts. sample input port on the right hand side of
the monitor. See Figure 3-2.
3.3 Controller Installation
3. Open the monitor by lifting and removing
The controller is supplied in an enclosure appropri- the louvered cover. Locate the exhaust
ate to the application based on location classifica- tubing which is coiled inside the monitor.
tion. The mounting location should be selected to Uncoil the tube and route it to a conve-
provide maximum protection from weather and di- nient free air exhaust location. Cut the tube
rect sunlight. Preferably the controller will be in- to the shortest functional length.
side a secured structure.
4. Remove the black protective cap from the
Mount the controller on a vertical surface at eye bottom of the coalescing filter.
level insuring sufficient clear space to install con-
duit into the downward facing conduit hubs. Also
allow for clear space to open the door.

3.4 Interface wiring


Install a two conductor shielded cable (18 AWG)
between the controller and the monitor. At the
monitor condulet connect the two conductors to P
power and S signal. Connect the drain wire to
terminal G ground.
At the controller connect the P conductor to chan-
nel power, S conductor to channel signal and the
shield to chassis ground.
Follow controller instruction manual for power and
alarm connections. Figure 3.2
Component Locators

Model 4400 In-Stream Hydrogen Sulfide Monitor (03/09) Page: 3


Instruction Manual
4. Operation and Calibration 4.2 Calibration
4.1 Operation The Model 4400 requires calibration using Hydro-
4.1.1 Power-up gen Sulfide span gas, via a permeation tube, every
2 weeks. The span gas should be approximately
After installation has been completed in compliance 15 ppm using the stream as the balance and should
with section 3, provide primary power to the con- be delivered at a flow rate of 0.5 SCFH
troller. Allow time for the sensor in the monitor to
stabilize until a zero reading is established. 4.2.1 Preparation

4.1.2 Flow Control 1. Remove the monitor cover.


2. Clear any liquid accumulation in the coa-
Begin sample flow to the monitor by:
lescing filter by pressing the actuator at the
1. Open the monitor cover and place the bottom of the bulb. Visually inspect the
sample flow control valve (Figure 4-1) in filter element and replace if necessary. (To
the off (vertical) position. replace the element the sample control
2. Turn the rotameter to full off by closing the valve must be shut off).
knob finger tight clockwise. 3. Turn off the gas flow at sample control
3. At the sample location confirm that pres- valve.
sure is regulated to less than 100 psi and 4. Inspect the clear tubing lines on the flow
open the valve to the sample line. system harness to determine is there is any
4. Open the sample control valve. oiling or other contamination in the line. If
the line is contaminated an orifice in the
5. Open the sample flow control (rotameter) harness may be blocked and the harness
slowly until the indicator is at 0.5 SCFH. must be replaced.
The system is now in run mode. Allow one hour 5. To remove the harness (see Figure 3-2)
for stabilization before logging data or activating twist the white leur fitting located immedi-
alarms. ately behind the sample flow control
counter-clockwise 1/2 turn and unseat it
from the connecting port. Remove the other
end of the harness from the sensor mani-
fold. To disconnect from the manifold, push
the black ring upward and simultaneously
pull the tubing downward.
6. To install the replacement harness slide the
open end into the fitting on the bottom of
the manifold and connect the white leur fit-
ting to the back of the rotameter.
4.2.2 Sensor Cycle
The Model 4400 monitor is supplied with one sen-
sor installed and one spare. At each calibration the
sensors should be cycled to allow one sensor to
refresh while the other is in service. To cycle the
sensors:
1. Disable alarm and shut down devices at
Figure 4.1 the controller
Flow Control Components 2. Shut off sample flow using the sample con-
trol valve.

Page: 4 Model 4400 In-Stream Hydrogen Sulfide Monitor (03/09)


Instruction Manual

3. Unscrew the wiring connector on the top 1. The sample flow which was turned off for
of the sensor assembly. (Figure 4.2) sensor cycling should remain off while the
zero is adjusted.
4. Remove the sensor and sensor transmitter
head from its base, but turning the knurled 2. Refer to figure 2 of the Model 4001 con-
head counter-clockwise. troller manual and find the location of the
zero display adjust potentiometer. Adjust
5. Unplug the sensor from the transmitter
the zero potentiometer on the sensor elec-
head.
tronics (round enclosure) until the display
6. Move the shorting spring from the refreshed on the controller reads zero (00.2).
sensor to the one which has been removed
3. Span gas is to be supplied via a permeation
from service (connect the spring to termi-
tube. Calculate the concentration for the
nals R and S).
tube using current temperature and a flow
7. Plug the refreshed sensor into the trans- rate of 0.5 SCFH.
mitter head and return it to the base. In-
4. Remove the cap on the Calibration Gas In-
sure that the transmitter is screwed al the
put (Figure 3-2).
way down onto the base.
5. Connect the permeation tube to the Cali-
8. Re-attach the wiring connector.
bration Gas Input.
4.2.3 Calibration Procedure (Model 4001
6. Turn the flow sample control valve on.
Controller)
7. Allow the span gas to run until the control-
The following instructions assume that the control-
ler reading is stable (approximately 5 min-
ler is a Sierra Monitor Model 4001. If a different
utes).
controller is used, modify this procedure to con-
form to the controller instructions.

Figure 4.2
Model 4400 Sensor

Model 4400 In-Stream Hydrogen Sulfide Monitor (03/09) Page: 5


Instruction Manual

8. Adjust the controller gain potentiometer


until the display on the controller indicates
the concentration of the span gas.
9. Turn off the flow at the sample control
valve.
10. Remove the calibration gas and recap the
calibration gas input.
11. Turn on the flow at the sample control
valve.

4.2.4 Calibration Procedure - Model 5100-


99-IT

The following instructions are applicable when


using the Model 5100-99-IT Display/Transmitter Figure 4.3
with the Model 4400. Refer to the Model 5100- Flow Harness
99-IT Instruction Manual for further details.

The procedures requires that the menu "keys" be


activated using the magnet stick. Each key
pressed steps through the process of setting the
zero value for clean air and then setting the span
value.
At each of these steps, apply calibration gas of
the value corresponding to the setting accepted
on the sensor module display.

Page: 6 Model 4400 In-Stream Hydrogen Sulfide Monitor (03/09)


Instruction Manual

Sensor Exposure to Gas


Calibration gas must be delivered to the sensor using the flow rate and duration listed in below:

Model Gas Flow Period


5100-99-IT Hydrogen Sulfide 300 cc/min Until Stable (minimum 2 minutes)

Ke y Function Displa y De scription Reference


XXXPPM Default Display
M E
Mode ALMRSET: Mode Func tion - Alarm Res et

M E
Mode CALIB:-- Mode Func tion - Calibrate

M E
Enter CAL-0PP M-- Banner: A pply z ero gas, enter <E> w hen done

Operation: Confirm area cl ear of gas , or appl y z ero ai r to
s ensor.
M E
Enter ACK Zero gas setting acknowledged

10PPM-SP Banner: Select s pan, enter <E> to c alibrate s ens or Sub A
M E Banner: A pply s pan gas, then enter <E> to c alibrate gas
Enter C 4 PPM Sub B
s ensor
C 4 PPM Operation: Apply c al b ration gas .
Operation: As gas is applied the reading wi ll increas e -
CXXXPPM
wai t 3 mi nutes
M E
Enter CAL-OK Calibration Passed - now remove gas

Operation: F ive mi nute time out b efore s ens or is returned
W AIT-300
to s ervi ce.
Sub-Routine s
10PPM-SP Banner: Select s pan, enter <E> w hen done Sub A
M E
Up 25PPM-SP Operation: Change Span Gas Value to 25PPM

M E
Up Adj-SPAN Operation: User adjustab l e value

M E Enter 25PPM-SP Operation: Ready for user adjustment

M E Banner: A pply 25PPM gas , then enter <E> to calibrate gas
Enter C 25PP M Sub B
s ensor
C 25PP M Operation: Apply c al b ration gas .
M E Operation: No c alib rati on gas applied, or s ens or did not
Enter CAL-FAIL
res pond correc tl y.
Operation: F ive mi nute time out b efore s ens or is returned
W AIT-300
to s ervi ce.
M E Operation: Hold magnet over Mode Swi tc h for ten
Mode (Any) Sub C
s enconds to ab ort cali b ration
Banner: Calibration A borted

XXXPPM Default Display


Ta ble 5-1
Calibration

Model 4400 In-Stream Hydrogen Sulfide Monitor (03/09) Page: 7


Instruction Manual

4.3 Maintenance
4.3.1 Coalescing Filter
To replace the filter element:
Remove the monitor cover.
1. Clear any liquid accumulation in the coa-
lescing filter by pressing the actuator at the
bottom of the bulb. Visually inspect the
filter element and replace if necessary. (To
replace the element the sample control
valve must be shut off.)
2. Turn off the gas flow at sample control
valve.
3. Unthread the transparent bulb and lift out
the old filter.
4. Place a new filter in the bulb and return it
to the filter assembly.
5. Turn on the gas flow at the sample control
valve.
4.3.2 Flow Harness (Figure 4.3)
The flow harness must be inspected at every main-
tenance or calibration interval and should be re-
placed following the instructions in 4.2.1.
4.3.3 Sensor Replacement
The sensor is to be replaced when it is no longer
possible to adjust the display readings correctly dur-
ing calibration or when the electrical output becomes
noisy causing erroneous or fluctuating readings
which are observed either on the display or the chart
recorder.
The Hydrogen Sulfide sensor life will vary depend-
ing upon average H2S concentration, but in typical
applications the sensor life should be approximately
one year.
To replace the sensor follow the steps in section
4.2.2\

Page: 8 Model 4400 In-Stream Hydrogen Sulfide Monitor (03/09)


Instruction Manual
5. Specifications
Power: 24 VDC
Output: 4-20 mA = 0 - 100 ppm H2S
Environmental:
Temperature: Operating Range
4o to 122oF (-20o to 50oC)
Storage Range
-40o to 122oF (-40o to 50oC)
Humidity: 0 - 95% RH

Sensor: Hydrogen Sulfide


Range: 100 ppm
Sensor type: Electrochemical
Sensor life: Approximately 1 year in cycled service
Response: < 30 seconds to 90% FS

Mechanical:
Area classification: Class 1, Div I, Groups C, D
Enclosure: NEMA-1 with removable cover panel
Mounting: Installs on 9 X 7: H frame.
Connections: 3 position terminal strip in separate condulet
Dimensions: 9.0 x 11.0 x 4.0 inches (WxHxD) (22.9 x 27.9 x 10.2 cm)
Weight: 5 lbs (2.2 Kg)

Spare and Replacement Parts:


SPMN26105 Sensor Assembly
SPM22063 Flow Harness
SPM27064 Maintenance Kit (consists of 1 spare sensor assembly,
and 2 flow harnesses)
SPM64017 Filter element
6. Limited Warranty

SIERRA MONITOR CORPORATION warrants its In all cases SMCs responsibility and liability under
products to be free from defects in workmanship or this warranty shall be limited to the cost of the equip-
material under normal use and service for two years ment. The purchaser must obtain shipping instructions
after date of shipment. SMC will repair or replace for the prepaid return of any item under this warranty
without charge any equipment found to be defective provision and compliance with such instruction shall
during the warranty period. Final determination of the be a condition of this warranty.
nature and responsibility for defective or damaged
equipment will be made by SMC personnel. Except for the express warranty stated above, SMC
disclaims all warranties with regard to the products sold
All warranties hereunder are contingent upon proper hereunder including all implied warranties of merchant-
use in the application for which the product was in- ability and fitness and the express warranties stated
tended and do not cover products which have been herein are in lieu of all obligations or liabilities on the
modified or repaired without SMC approval or which part of SMC for damages including, but not limited to,
have been subjected to accident, improper maintenance, consequential damages arising out of/or in connection
installation or application, or on which original iden- with the use or performance of the product.
tification marks have been removed or altered. This
Limited Warranty also will not apply to interconnect-
ing cables or wires, consumables (ie. calibration gases,
flos harness, filter elememts, batteries, sensors), nor to
any damage resulting from battery leakage.

Model 4400 In-Stream Hydrogen Sulfide Monitor (03/09) Page: 9


MODEL 5100-99-IT

IT Series
4-20 mA Transmitter

Version 2.0

APPLICABILITY & EFFECTIVITY

Effective for all Model 5100-99-IT-AL and 5100-99-IT-SS Transmitters manufactured after March 1, 2008

Instruction Manual Part Number T12005


Rev A
Model 5100-99-IT 4-20 mA Transmitter

THIS PAGE IS INTENTIONALLY LEFT BLANK

Contents
Model 5100-99-IT 4-20 mA Transmitter

TABLE OF CONTENTS

1. PRODUCT DESCRIPTION .............................................................................................................................1


1.1 GENERAL........................................................................................................................................................1
1.2 PRODUCT CONFIGURATION........................................................................................................................1
1.3 MODES OF OPERATION................................................................................................................................1
1.3.1 SENTRY INTERFACE..............................................................................................................................1
1.3.2 MODBUS OPERATION............................................................................................................................2
1.3.3 ANALOG OPERATION ............................................................................................................................2
1.3.4 REMOTE ALARM RESET (DIGITAL INPUT) (Figure 3-7) ......................................................................2
1.3.5 OPTIONAL INTEGRAL RELAYS .............................................................................................................2
1.3.6 MECHANICAL ..........................................................................................................................................2
1.3.7 ENCLOSURE ...........................................................................................................................................2
1.3.8 TRANSMITTER ELECTRONICS .............................................................................................................4
1.4 INTERCONNECT WIRING ..............................................................................................................................4
1.5 POWER REQUIREMENTS .............................................................................................................................4
2. CAUTIONS & WARNINGS .............................................................................................................................5
2.1 INTRODUCTION .............................................................................................................................................5
2.2 IT TRANSMITTERS - GENERAL.....................................................................................................................5
2.3 WIRING............................................................................................................................................................5
3. INSTALLATION ..............................................................................................................................................7
3.1 TRANSMITTER LOCATIONS .........................................................................................................................7
3.2 WIRING............................................................................................................................................................7
3.2.1 ANALOG 4-20 mA OPERATION..............................................................................................................7
3.2.2 MODBUS OPERATION USING RS-485 CONNECTION ........................................................................7
3.2.3 SENTRY OPERATION USING SMC SENTRY CONNECTION ..............................................................7
3.2.4 GENERAL ................................................................................................................................................7
3.3 ENCLOSURE INSTALLATION........................................................................................................................7
3.4 TRANSMITTER AND SENSOR INSTALLATION ............................................................................................9
3.5 TRANSMITTER ADDRESS SWITCH............................................................................................................14
4. OPERATION .................................................................................................................................................15
4.1 INTRODUCTION HUMAN-MACHINE INTERFACE SYSTEM ...................................................................15
4.2 HUMAN-MACHINE INTERFACE ..................................................................................................................15
4.3 MAIN MENU...................................................................................................................................................16
4.4 CONFIGURE SET-POINTS...........................................................................................................................17
4.5 MAINTENANCE FUNCTIONS.......................................................................................................................20
5. CALIBRATION ..............................................................................................................................................21
5.1 CALIBRATION FREQUENCY .......................................................................................................................21
5.2 CALIBRATION PREPARATION ....................................................................................................................21
5.2.1 CALIBRATION GAS DELIVERY METHODS .........................................................................................21
5.3 CALIBRATION PROCEDURE.......................................................................................................................21
5.3.1 SENSOR EXPOSURE TO GAS.............................................................................................................22
6. SERVICE .......................................................................................................................................................23
6.1 TRANSMITTER CONFIGURATION ..............................................................................................................23
6.2 ENCLOSURE REPLACEMENT ....................................................................................................................23
6.3 TRANSMITTER REPLACEMENT .................................................................................................................24
6.4 SENSOR REPLACEMENT............................................................................................................................24
6.5 INSTALLATION INSPECTION ......................................................................................................................24
6.5.2 INSPECTION AND TROUBLESHOOTING GUIDE ...............................................................................24
6.5.3 IF MODULE DOES NOT RESPOND TO GAS ......................................................................................24

Contents
Model 5100-99-IT 4-20 mA Transmitter

6.5.4 IF THE TRANSMITTER DISPLAYS STARTING FOR MORE THAN 1 HOUR...................................24


7. APPENDICES ...............................................................................................................................................25
APPENDIX A: SPECIFICATIONS ............................................................................................................................25
APPENDIX B: MODEL NUMBERS & PARTS LIST ..................................................................................................26
APPENDIX C: LIMITED WARRANTY ......................................................................................................................27
APPENDIX D: MODBUS MEMORY MAP.................................................................................................................28

Contents
Model 5100-99-IT 4-20 mA Transmitter

1. PRODUCT DESCRIPTION

1.1 GENERAL
The Model 5100-99-IT Transmitter is a member of the Information Technology IT family of gas sensor
transmitters.

IT transmitters offer a broad array of features, including:


Integral alphanumeric LED display
4-20 mA output
Modbus RTU interface
SMC Sentry interface
316 Stainless steel enclosure option
Auxiliary integral relay option
Remote display option
Low maintenance and operation costs

The 5100-99-IT is designed and approved for installation and operation in hazardous locations.
1.2 PRODUCT CONFIGURATION
Various transmitter configuration options are available. Where applicable, these options are factory
configured prior to shipment. Options which can be re-configured by the installer or field technician are fully
described in this manual.
1.3 MODES OF OPERATION
1.3.1 SENTRY INTERFACE
IT gas sensor transmitter can be connected to on Sierra Monitor Sentry Model 5000 controllers. When it is
connected to a Sentry system the IT transmitter must have a unique address which can be established by
setting an address between 1 and 8 on the Transmitter Address Switch accessible from the cover plate as
illustrated in Figure 3-1. Figure 3-6 in this manual provides the wiring terminations for connections to the
Sentry controller.

When the transmitter is operated in conjunction with a Sentry controller, the alarms outputs in the
transmitter can both be set to Sentry, allowing the Sentry controller to manage alarm acknowledge and
reset rather than the transmitter. The alarm relay outputs are triggered by the alarm values established in
the transmitter and can be independent of the settings in the Sentry controller.

The Sentry configuration allows daisy chain installation using the Sentry multiplex capability, thus reducing
costs by avoiding the requirement for wiring junction boxes. The connector card has two sets of
connections, allowing for a continuous run to the next transmitter.

Registered trademark of Schneider Electric


Page: 1
Model 5100-99-IT 4-20 mA Transmitter

1.3.2 MODBUS OPERATION


An RS-485 Modbus RTU serial interface allows direct connection to standard PLCs and DCSs. The
Transmitter Address Switch (section 3.5) allows the user to select up to 16 different Modbus addresses.
Also, an additional 238 Modbus addresses (for a total of 254 different Modbus Addresses) are available
via menu selection. Figure 3-6 in this manual provides the wiring terminations for Modbus connections. The
5100-XX-IT provides the additional terminal connectors to enable the user to connect In/Out terminations of
a RS-485 connection.
1.3.3 ANALOG OPERATION
The 4-20 mA interface allows direct connection to standard analog controllers or PLCs. The 5100-XX-IT 4-
20 mA connection can be wired as a Type 3 (3-wire) or Type 4 (4-wire) circuit as described by ANSI/ISA-
50.00.01-1975 Standard (see figure 3-5).
1.3.4 REMOTE ALARM RESET (DIGITAL INPUT) (Figure 3-7)
An input is available for connection of remote alarm reset/acknowledge. Figure 3-7 provides the wiring
termination for connecting the remote alarm reset. This only resets local alarms, not Sentry alarms. This
input can be wired as supervised or non-supervised.
Note that when the Remote Alarm Reset is operated in a supervised mode that both the switch and resistor
must be present as outlined in Figure 3-7.
1.3.5 OPTIONAL INTEGRAL RELAYS
The optional relays are integral to the transmitter and are rated as SPDT, 250VAC, 8 Amps for the High
Alarm and Low Alarm relays and SPDT, 250 VAC, 2 Amp for the Trouble relay.
If the transmitter is provided with the optional relays, it will include Terminal P4 on the interface board
(Figure 3-2). Relay output connections are on P4.
1.3.6 MECHANICAL
The transmitter of comprised of the following three primary components:
1.3.7 ENCLOSURE
Standard on the 5100-99-IT-AL is an explosion-proof, rain-tight cast aluminum electrical housing (Figure 1-
1) with three FNPT conduit hubs. The 5100-99-IT-SS (Figure 1-2) has a 316 Stainless Steel enclosure.
Both enclosure covers have a viewing window. The design of the enclosures allows 3-way mounting
choices as shown in figure 1-3.

Page: 2
Model 5100-99-IT 4-20 mA Transmitter

Figure 1-1
Model 5100-99-IT-AL & SS Transmitter
Aluminum & Stainless Steel Enclosure, Dimensions

Page: 3
Model 5100-99-IT 4-20 mA Transmitter

Figure 1-3
Model 5100-99-IT Transmitter Mounting Options

1.3.8 TRANSMITTER ELECTRONICS


Electronic Assembly consist of one top transmitter board (connected to the cover plate) and a lower
interface board. Connectors for wiring for power, signal interface and alarm relays are located on the
interface board assembly

1.4 INTERCONNECT WIRING


Not supplied with the transmitter, but necessary to the installation and operation is the multi conductor
wiring which connects the transmitter to its power source and controller. Before this wiring is installed it is
important to read and understand the control system installation instructions to determine wiring
requirements and alternatives.

1.5 POWER REQUIREMENTS


5100-99-IT operates on DC power between 10 VDC and 30 VDC. Regulated DC power must be supplied
from a separate source, or from an approved Sentry or IT controller.

Page: 4
Model 5100-99-IT 4-20 mA Transmitter

2. CAUTIONS & WARNINGS

2.1 INTRODUCTION
Although IT Transmitter is designed and constructed for installation and operation in industrial applications
including "hostile" environments, caution should be taken to insure that the installation is made in
compliance with this instruction manual and that certain procedures and conditions are avoided. This
chapter discusses the necessary cautions. Read the entire chapter prior to installation of the
equipment.
2.2 IT TRANSMITTERS - GENERAL
Avoid installing Transmitter where they will be unnecessarily exposed to wind, dust, water (esp. direct hose
down), shock, or vibration. Observe temperature range limitations.
2.3 WIRING
The manufacturer recommends that extra caution be taken where the installation is near any sources of
electromagnetic or radio frequency interference. Precautions include:
Avoid running transmitter cable close to high power cables, radio transmission lines, or cables subject
to pulses of high current.
Avoid running cables near large electric motors or generators.
When the transmitter is to be operated in analog (4-20mA output) mode shielded cable is required.
All splices must be via either a termination hardware system or soldered. Improperly spliced cable can
result in corrosion, resistance changes and system errors.
Use low capacitance cable for RS-485 Modbus RTU Operation.

NOTE
Installation and wiring must be in accordance with the National Electrical Code. AC Voltage
conductors are not to be run in the same conduit as DC voltage conductors.

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Model 5100-99-IT 4-20 mA Transmitter

THIS PAGE INTENTIONALLY LEFT BLANK

Page: 6
Model 5100-99-IT 4-20 mA Transmitter

3. INSTALLATION

NOTE
All transmitters are factory are pre-configured and calibrated.
Identify all components during unpacking and install using the factory configuration.

3.1 TRANSMITTER LOCATIONS


Select locations for each transmitter so that they are placed in areas accessible for calibration.
3.2 WIRING
3.2.1 ANALOG 4-20 mA OPERATION
The 4-20 mA output for the 5100-99-IT can be either 3-wire or 4-wire operation. If using 3-wire operation,
use a minimum of 18 AWG, shielded, 3-conductor cable up to 2000. For 4-wire operation, use a minimum
of 2 each, 18 AWG, twisted, shielded, pair up to 2000.
3.2.2 MODBUS OPERATION USING RS-485 CONNECTION
Use a minimum of 18 AWG, 2 conductor for DC power connection. No shield required. In addition use a
minimum of 24 AWG, low capacitance, shielded data cable for RS-485 half duplex communication. The
installation may be planned in a manner which provides up to 32 sensor modules on a single home run.

Refer to Figure 3-3. Units ship with BIAS jumpers connected. For all installations, except very long cable
runs, leave these jumpers connected. The TERM jumpers should be installed in the last (furthest) module
of every loop.
3.2.3 SENTRY OPERATION USING SMC SENTRY CONNECTION
Wire shall be rated as 600 volt tray cable, such as Belden (or equivalent) 27331 or 27331 AS (shielded). If
high RFI or EMI levels exist wiring should be protected by conduit or shield. The installation may be
planned in a manner which provides up to 4 sensor modules on a single home run to a Sentry controller.

NOTE
Be sure to follow all local electric code and safety requirements when installing the 5100-99-IT
Transmitter

3.2.4 GENERAL
Install conduit as required by local code or construction specifications. When transmitters are to be
multiplexed for Sentry or RS-485 communication, two alternatives may be planned:
Use multi-position positive contact terminals to connect daisy chain wiring and provide a pigtail to
connect to the transmitter board.
NOTES
The drain wire of shielded cable must NOT be used as one of the conductors.
Installation and wiring must be in accordance with the National Electrical Code. Temperature
o
rating of cable wire must be at least 75 C. If cable runs through higher temperature
environments, it must be specified for that environment.

3.3 ENCLOSURE INSTALLATION


To protect the transmitter they should be removed from the enclosure and preserved until final installation and
wiring termination.
Prior to installation and wiring:
1. Remove the transmitter from the module housing by:
Unscrew the two captive panel screws in the face plate.
Lift the transmitter out of the housing.
2. Install the module housing onto the end of the supply conduit and/or bolt into position as required.
NOTES
When housing earth grounding is required for the installation a grounding lug is located in the
base of the enclosure. Install the earth ground wire under the green lug.

Page: 7
Model 5100-99-IT 4-20 mA Transmitter

P1 PCB Label Function


1 Switch IN + Digital Input SW +
2 IN - Digital Input SW -
3 4-20 IN + 4-20 mA Input +
4 IN - 4-20 mA Input -
5 GND Ground
6 4-20 OUT + 4-20 mA Output +
7 OUT - 4-20 mA Output -

P2 PCB Label Function


1 + RS 485 (+) (A)
2 RS 485 - RS 485 (-) (B)
3 S RS 485 shield (Isolated GND)
4 + RS 485 (+) (A)
5 RS 485 - RS 485 (-) (B)
6 S RS 485 shield (Isolated GND)

P3B PCB Label Function


1 P VDC Power
2 S Sentry Signal or Communication
3 G VDC Ground
P3A
4 P VDC Power
5 S Sentry Signal or Communication
6 G VDC Ground

P4 Connections are only available when the optional Relays are included
P4 PCB Label Function
1 N/C Low Alarm Relay NC
2 LO ALM COM Low Alarm Relay COM
3 N/O Low Alarm Relay NO
4 N/C High Alarm Relay NC
5 HI ALM COM High Alarm Relay COM
6 N/O High Alarm Relay NO
7 N/C Trouble Alarm Relay NC *
8 TRBL COM Trouble Alarm Relay COM*
9 ALM N/O Trouble Alarm Relay NO*
* Trouble relay is fail safe so it is energized for normal operation,
functions are labeled for normal operation.
Table 3-1
Transmitter External Interfaces (See Figure 3-2)

1. Establish the module address according to section 3.5.

NOTES
The starting delay period normally takes approximately 3 minutes but it depends on the sensor
connected.

Page: 8
Model 5100-99-IT 4-20 mA Transmitter

3.4 TRANSMITTER ADDRESS SWITCH


For digital interface applications the module address switch (or Modbus node) Figure 3-1 must be set per
Table 3-2:

POSITION ADDRESS POSITION ADDRESS


1 Sensor 1 9 Sensor 09
2 Sensor 2 A Sensor 10
3 Sensor 3 B Sensor 11
4 Sensor 4 C Sensor 12
5 Sensor 5 D Sensor 13
6 Sensor 6 E Sensor 14
7 Sensor 7 F Sensor 15
8 Sensor 8 0 Software
Menu
Table 3-2
Transmitter Address Switch Positions

NOTES
For Sentry applications only sensor addresses 1-8 are allowed. If using Modbus output sensor
addresses 1-15 are available. Position 0 allows the Modbus Address to be set by software
menu, in the range 16-254.

Figure 3-1
Transmitter Face Plate

Page: 9
Model 5100-99-IT 4-20 mA Transmitter

Figure 3-2
Interface Board Connectors

Figure 3-3
RS-485: Termination, BIAS Jumper

Page: 10
Model 5100-99-IT 4-20 mA Transmitter

Figure 3-4
4-20mA Circuit Types

Page: 11
Model 5100-99-IT 4-20 mA Transmitter

Figure 3-5
4-20mA Circuit Type Connections for 5100-99-IT

Page: 12
Model 5100-99-IT 4-20 mA Transmitter

5100-99-IT TO SENTRY

5100-99-IT TO MODBUS DEVICE

Figure 3-6
Wiring Connections for Modbus and Sentry Interface

Page: 13
Model 5100-99-IT 4-20 mA Transmitter

5100-99-IT Remote Alarm Reset (Unsupervised)


(Dry contact only unpowered)

P1
OUT
-
4-20

+
GND
-
4-20

IN

+
SWITCH

- IN

4.7K OHM (CUSTOMER SUPPLIED)


SWITCH IN+

SWITCH IN -

5100-99-IT
5100-05-IT REMOTERemote Alarm (SUPERVISED)
ALARM RESET Reset (Supervised)

Figure 3-7
Wiring Connections for Remote Alarm Reset

Page: 14
Model 5100-99-IT 4-20 mA Transmitter

4. OPERATION

4.1 INTRODUCTION HUMAN-MACHINE INTERFACE SYSTEM


The transmitter utilizes a visual menu system operated by means of a magnet. A magnetic tool (5358-50) is
supplied for this purpose. The menu system is used to configure alarm set-points, calibrate the transmitter,
and for maintenance procedures and alarms acknowledge.

4.2 HUMAN-MACHINE INTERFACE


The transmitter menu system is operated by means of directing the magnet stick toward each of four
independent hall-effect magnetic switches. The enclosure lid should remain on the unit. Each switch
functions as if it is a manually activated panel key. The keys are located above and below the faceplate
display and are labeled M , E , and as shown in Figure 4-1. The key functions are as follows:

Key M : MODE
Key E : ENTER
Key : UP (+)
Key : DOWN (-)

Key M Key E

Key /\ Key \/

Figure 4-1:
IT Transmitter Menu Switch Locations

Page: 15
Model 5100-99-IT 4-20 mA Transmitter

4.3 MAIN MENU


Table 4-1 describes the primary man-machine interface operation (The blackened box is the selected menu
function).
Key Function Display Description Reference
M E
S T
Mode Switch [M]
M E
S T
Enter Switch [E]
M E
S T
Up Switch [] Previous Menu
M E
S T
Down Switch [] Next Menu
5100-99 First screen at power up: Model No.
VXX-XX-- Second screen at power up: Version No.
START XX Third screen at start up: Start Count Up
XXX PPM Normal condition - default display
M E
S T
Mode ALMRSET: Mode Function - Alarm Reset
Banner: "Press [E] to reset alarm"
M E
S T
RESET Alarm Reset
XXX PPM Default Display
M E
S T
Mode ALMRSET: Mode Function - Alarm Reset
M E
S T
Mode CALIB:-- Mode Function - Calibrate Table 5-1
M E
S T
Mode SETUP:-- Mode Function - Set Point Adjustments Table 4-3
M E
S T
Mode MAINT:-- Mode Function - Maintenance Table 4-4
M E
S T
Mode EXIT-?-- Exit Menu
M E
S T
Enter XXX PPM Apply Selected Mode (Exit)
XXX PPM Default Display (Once a minute the sensor displays module address)

Table 4-1 Master Menu

Table 4-2 describes the operational display values of the human-machine interface system.

DISPLAY DESCRIPTION
START Delay from loss of power at start-up
XXX PPM Concentration
LXXX PPM Low Alarm
HXXX PPM High Alarm
Measures gas, concentration exceeds
100% of Full Scale
CXXX PPM Calibration Mode
Acknowledged Function
Table 4-2 Operation Display Values

Page: 16
Model 5100-99-IT 4-20 mA Module

4.4 CONFIGURE SET-POINTS


The transmitter set-points menu is used to initially set-up the alarm set points, relay actions, range, 4-20 mA
action and RS-485/Sentry address and baud rates.

Alarm Set-points: Once the Set-up menu is selected, press [E] to activate the Alarm Set-point
screen. Use the [] or [] keys to select Low Alarm or High Alarm menu. Key [] will adjust the
setpoint upwards and Key [] will adjust the value downwards. Once it reaches the desired
setpoint, Key [E] will accept it and ACK will appear.

Alarm Relay Set-up: Once the Set-up menu is selected, press key [] once and press [E] to
activate the Relay Set-up menu. Use the [] or [] keys to select High Alarm or Low Alarm relay
menu and press [E]. Use the [] or [] keys to select the correct alarm relay action for the
application, Latch, Sentry or Non-Latch. Selecting Sentry enables the Sentry controller to make all
alarm action decisions. * indicates the current selection.

Range: Once the Set-up menu is selected, press key [] twice and press [E] to activate the Range
Set-up menu. Use the [] or [] keys to select Range menu and press [E]. When Range is
selected menu provides any choices of ranges available for the gas type selected. Use the [] or
[] keys to select the desired range. If the User range is selected, use the [] or [] keys to
adjust the high end of the range desired. See specifications (page 25) for optional ranges.

4-20mA: Once the Set-up menu is selected, press key [] three times and press [E] to activate the
4-20mA Set-up menu. Use the [] or [] keys to select Calib or CalibOut menu and press [E].
The Calib section of the menu allows the user to calibrate the 4 mA and 20 mA outputs. To
calibrate the 4 mA and 20 mA outputs it is necessary to have an amp meter connected to the 5100-
XX-IT and upon selecting the 4 mA output calibration then the [] or [] keys can be used to adjust
the 4 mA reading on the amp meter until it reads 4 mA. Similar steps can then be performed for the
20 mA output. The CalibOut section allows the user to select the 4-20 mA output action desired
during calibration. * indicates the current selected value. Available selections include:
Track the 4-20mA value tracks the calibration gas exposed to the transmitter
Zero the 4-20mA value is held at 0mA during calibration
C1.50mA the 4-20mA value is held at 1.50mA during calibration
C4.00mA the 4-20mA value is held at 4.0mA during calibration.
TblOut the TblOut menu allos user to select 2.5 mA or A user selected value for
Trouble mA signal.
DigInput the DigInput menu allows user to select supervised or non-supervised input
WarmMin the WarmMin menu allows user to select warm up time in minutes.
RS-485 - Once the Set-up menu is selected, press key [] four times and press [E] to activate the
RS-485/Sentry Set-up menu. Use the [] or [] keys to select Mode or Calib menu and press
[E]. The Mode menu allows the user to select units including %LEL, % Vol, PPM % Full Scale, or
NA. The Calib section of the menu allows the user to calibrate the 4 mA and 20 mA outputs and
inputs. Note that the 5100-99-IT has a rotary switch on the faceplate and it is used to select
addresses 1-15. When connected to Sentry the user can select 1-8 and when using Modbus RS-
485 the user can select addresses 1-15. For Modbus addresses above 15, set the rotary switch to
0 and then use the Address menu to select any address between 16 and 254. The Baud rate
menu allows the user to select a baud rate of 38400, 19200, 9600, 4800 or 2400. * indicates current
selection. Sentry default is 9600.

Page: 17
Model 5100-99-IT 4-20 mA Module

Key Function Display Description Reference


--0%LEL- Default Display
M E
Mode ALMRSET: Mode Function - Alarm Reset
S T
M E
Mode CALIB:-- Mode Function - Calibrate
S T
M E
Mode SETUP:--- Mode Function - Set Point Adjustments
S T
M E
Enter Alarms S.P. Function - Alarm Adjust * A Below
S T
M E
Down Relays S.P. Function - Relays Adjust * B Below
S T
M E
Down Relays S.P. Function - Range Adjust * Page 19
S T
M E
Down 4-20mA S.P. Function - 4-20 mA Adjust * Page 19
S T
M E
Down Dig Input S.P. Function - RS-485/Sentry Output Adjust * Page 19
S T
High Alarm Set Point Adjustment Example
M E
Enter H.Alarm S.P. Function - High Alarm Adjust *A
S T
M E
Enter HASP:40- High Alarm Set Point: current = 40
S T
Use S or T keys to adjust to new set point
M E
Down (x5) HASP:55- High Alarm Set Point: new = 55
S T
M E
Enter ACK Momentary Acknowledge of new Set Point
S T
H.Alarm S.P. Function - High Alarm Adjust

Relays Set Point Adjustment Example


M E
Enter H. Relay S.P. Function - High Alarm Relay Adjust *B
S T
M E
Down L.Relay S.P. Function - Low Alarm Relay Adjust
S T
M E Use S or T keys to adjust to new relay action (Latch,
Enter Latch
S T Sentry, NonLatc) * indicates current
M E NOTE: Sentry indicates that Sentry controls relay action
Down Sentry
S T and not the IT Sensor Module
M E
Down *Sentry Low Alarm Relay set to Sentry
S T

Table 4-3A Set-Up Configuration

Page: 18
Model 5100-99-IT 4-20 mA Module

Range Adjustment Example


M E
Enter Range S.P. Function - Range Adjust *C
S T
M E
S T
Enter *100 PPM Select [E] to select or S or T to select another and press [E]
M E
Down 10 PPM Press [E] if selecting 0-10 PPM range
S T
M E
Down USER Press [E] if selecting User adjustable range
S T
M E Enter 100 PPM Select [E] to select or S or T to select another and press [E]
S T
4-20 mA Adjustment Example
M E
Enter Mode S.P. Function - Output Units Adjust *D
S T
M E
S T
Enter %LEL Use S or T keys to select units of output as %LEL, %Vol, PPM, %F.S. or mA
Use S or T to select for 4 mA output, 20 mA output, 4 mA input or 20 mA
input
M E
Down Calib S.P. Function - 4-20 mA Calib Adjust *D
S T
M E Use [E] to calibrate analog output, adjust output level with S or
Enter Out: 4mA *D
S T T then press [E] when done
Use S or T to select for 4 mA output, 20 mA output, 4 mA input or 20 mA
input
M E
Enter 4mA Selects 4 mA
S T
M E
S T
Enter ACK Momentary Acknowledge of new Set Point
M E
S T
Mode Calib S.P. Function - Calib Adjust
M E
S T
Down CalibOut S.P. Function - Output during Calibration Adjust
M E
S T
Enter Track Use S or T keys to select Track, Zero, C1.50mA, C4.00mA or User mA
Track = Output during calibration tracks the calibration gas, Zero = Output is
Zero during calibration, C1.50mA = Output during calibration is 1.50 mA,
C4.00mA = Output during calibration is 4.0 mA
M E
S T
Enter *Track * = Current selection
M E
Down Tbl Out S.P. Function - 4-20 mA Output during Trouble Adjust
S T
M E
S T
Enter *T2.50mA Use S or T keys to select 2.50 mA or User select
M E
Down Dig Input S.P. Function - Digital Input Adjust
S T
M E
S T
Enter Sprvsd Use S or T keys to select Supervised or Unsupervised Digital Input
M E
S T
Down Warm Min S.P. Function - Warm Up Time Adjust
M E Enter Warm 1 Use S or T keys to select between 1 and 8 minutes warm up time
S T
RS-485 Adjustment Example
M E
Enter Address S.P. Function - RS-485 Address Adjust *E
S T
M E
S T
Enter Addr:016 Use S or T keys to enter new address
M E
Enter ACK New address selected
S T
M E
Enter Address S.P. Function - RS-485 Address Adjust
S T
M E
Down Baud S.P. Function - RS-485 Baud Rate Adjust
S T
M E Enter *38400 Press [E] to select or [S] or [T] to select another
S T

Table 4-3B Set-Up Configuration

Page: 19
Model 5100-99-IT 4-20 mA Module

4.5 MAINTENANCE FUNCTIONS


The maintenance menu enables the operator to view sensor and software versions. Sierra Monitor technical
support has access to other values as needed. The maintenance menu operation is described in Table 4-4.

Key Function Display Description Reference


XXXPPM Default Display
M E
Mode ALMRSET: Mode Function - Alarm Reset
S T
M E
Mode CALIB:-- Mode Function - Calibrate
S T
M E
Mode SETUP:- Mode Function - Set Point Adjustments
S T
M E
Mode MAINT:-- Mode Function - Maintenance
S T
M E
Enter Ver1.00aA Module Software Version Number
S T
M E
Enter CCC001 Module Custom Configuration Control number
S T
Table 4-4
Maintenance Menu

Page: 20
Model 5100-99-IT 4-20 mA Module

5. CALIBRATION

5.1 CALIBRATION FREQUENCY

The 5100-99-IT has been calibrated in the factory prior to shipment. It is recommended that the user check
calibration before placing in service. Periodic functional tests are advisable for critical applications and hostile
environments.

The transmitter microprocessor software includes high level self checking algorithms which provide continuous
diagnostic and self adjustment. Users may select calibration frequencies dependent upon sensor type.

5.2 CALIBRATION PREPARATION

Calibration of the transmitter with sensor is accomplished by simple menu based steps and application of span
gas.

NOTE
If an error is made during any stage of the calibration process, hold the magnet stick at the
Switch [M] for 10 seconds. A scrolling display will indicate Calibration aborted and the
sensor module will exit the calibration activity and return to normal operating mode. The
calibration procedure can then be restarted.

Calibration must be performed only when the area is known to be clear of the applicable toxic gas. If
necessary, use a portable instrument to confirm that there is no background toxic gas.

5.2.1 CALIBRATION GAS DELIVERY METHODS


Calibration gas is can be delivered to the sensors via the following delivery devices:
Model 5358-00: Calibration Adapter - used with portable calibrators. See 5-1.
Model 5360-00: Calibration Gas Delivery fitting - permanently installed fitting which
allows tubing to be run to a convenient delivery location
5.3 CALIBRATION PROCEDURE
Table 5-1 shows the step by step process of the calibration procedure.
The procedures requires that the menu keys be activated using the magnet stick.
Each key pressed steps through the process of setting the zero value for clean air
and then setting the span value.
At each of these steps, apply calibration gas of the value corresponding to the
setting accepted on the sensor module display.

Figure 5-1
Model 5358-00 Calibration
Adapter

Page: 21
Model 5100-99-IT 4-20 mA Module

5.3.1 SENSOR EXPOSURE TO GAS


Calibration gas must be delivered to the sensor using the flow rate and duration specified by the sensor
manual.
Key Function Display Description Reference
XXXPPM Default Display
M E
S T
Mode ALMRSET: Mode Function - Alarm Reset
M E
S T
Mode CALIB:-- Mode Function - Calibrate
M E
S T
Enter CAL-ZERO Banner: Apply zero gas, enter <E> when done
Operation: Confirm area clear of gas, or apply zero air to
sensor.
M E
S T
Enter ACK Zero gas setting acknowledged
Banner: Select span, enter <E> to calibrate sensor
10PPM-SP Banner: (5100-03-IT) Specify Cal gas <E> when done
Sub A
M E
S T
Enter C 4 PPM Banner: Apply span gas, then enter <E> to calibrate gas sensor Sub B
C 4 PPM Operation: Apply calbration gas.
Operation: As gas is applied the reading will increase - wait 3
CXXXPPM minutes
M E
S T
Enter CAL-OK Calibration Passed - now remove gas
Operation: Fifty second time out before sensor is returned to
WAIT-50 service.

Sub-Routines
10PPM-SP Banner: Select span, enter <E> when done Sub A
M E
S T
Up 25PPM-SP Operation: Change Span Gas Value to 25PPM
M E
S T
Up Adj-SPAN Operation: User adjustable value
M E
Enter 25PPM-SP Operation: Ready for user adjustment
S T
M E Banner: Apply 25PPM gas, then enter <E> to calibrate gas
S T
Enter C 25PPM sensor
Sub B
C 25PPM Operation: Apply calbration gas.
M E Operation: No calibration gas applied, or sensor did not respond
S T
Enter CAL-FAIL correctly.
Operation: Fifty second time out before sensor is returned to
WAIT-50 service.
M E Operation: Hold magnet over Mode Switch for ten senconds to
S T
Mode (Any) abort calibration
Sub C
Banner: Calibration Aborted

XXXPPM Default Display


Table 5-1
Calibration

Page: 22
Model 5100-99-IT 4-20 mA Module

6. SERVICE

6.1 TRANSMITTER CONFIGURATION


The transmitter is comprised of the following sub-assemblies (Figure 6-1):
5100-99-IT Transmitter
SPL21810 Aluminum Enclosure
SPL21823 316SS Enclosure
SPL21824 Transmitter Assembly

6.2 ENCLOSURE REPLACEMENT

Figure 6-1
Transmitter Components

The enclosure should be replaced if the cover threads or conduit threads have been damaged, or if the
enclosure has been damaged sufficiently that it no longer meets the required NEMA classification.
To replace the enclosure follow the transmitter removal instructions, remove the damaged enclosure from its
conduit, install a new enclosure and replace the transmitter and sensor assembly.
NOTE: Refer to Appendix G for service information for the 5100-25-IT.

Page: 23
Model 5100-99-IT 4-20 mA Module

6.3 TRANSMITTER REPLACEMENT


The transmitter assembly should be replaced when it is determined that it is unreliable, noisy or cannot be
adjusted for calibration. This may occur due to age, corrosion or failed components.
To replace the transmitter assembly:
a. Remove the cover of the main enclosure
b. Unscrew the two thumb screws in the top of the cover plate, lift the assembly and rotate 90o to relieve the
wiring service loop
c. Unplug the sensor connector from the transmitter
d. Plug connector into new transmitter (be sure to match numbers between connector and socket).
e. Restore power and allow a minimum of 3 hours for stabilization before re-calibration

6.4 INSTALLATION INSPECTION


Prior to system start-up or trouble shooting the entire system should be visually inspected. The following are
guidelines for that inspection:
6.4.1.1 CONTROLLER INSTALLATION
Controller installed in conformance to instruction manual recommendations.
AC power is correctly grounded.
Hot AC and relay connections have safety covers installed.
6.4.1.2 MOISTURE TRAPS AND RAINSHIELDS
Conduit seals and drains installed to avoid moisture build up in electronics enclosure. Water
accumulation in transmitter enclosures is a major cause of damage and system failures - take
precautions to seal electrical conduits and provide moisture traps and drains to avoid water damage
Rain-shields installed where applicable.
6.4.1.3 STANDARD VOLTAGES
DC Voltage to be applied to the transmitter must be between 10 VDC and 30 VDC.

6.5 INSPECTION AND TROUBLESHOOTING GUIDE


This inspection and troubleshooting guide can be used to step through the system start-up and to determine
the corrective action if a fault occurs.
6.5.1.1 IF TRANSMITTER DOES NOT RESPOND TO GAS
1. Repeat calibration procedure.
2. Remove the gas and wait for the timer to completely count down.
3. Apply calibration gas and verify that the sensor sees calibration gas after calibration.
4. If the sensor still does not see gas, power cycle the unit and repeat calibration.
6.5.1.2 IF THE TRANSMITTER DISPLAYS STARTING FOR MORE THAN 1 HOUR
1. Make sure the sensor is placed in an ambient room temperature environment.
2. Power cycle the sensor.
3. Ensure that the sensor is not exposed to the gas of interest during warm-up.
6.5.1.3 IF THE TRANSMITTER DOES NOT DISPLAY THE CORRECT PPM
1. Power cycle the unit
2. Recalibrate the sensor.
6.5.1.4 IF THE DISPLAY SHOWS F
1. Power down the unit
2. Open the enclosure and unplug the sensor assembly from the transmitter board.
3. Plug the sensor back into the transmitter board carefully and ensure a secure fit.
4. Power up the unit.
6.5.1.5 IF THE DISPLAY SHOWS C
1. Complete calibration and exit to operating mode.
6.5.1.6 IF THE DISPLAY SHOWS S
1. Check connections with Sentry Connections.

Page: 24
Model 5100-99-IT 4-20 mA Module

7. APPENDICES

APPENDIX A - SPECIFICATIONS
Output:
Display: Fixed and Scrolling LED
Relays (Optional): 8 Amp, High Alarm, Low Alarm, 2 Amp Trouble all SPDT
Analog Output (Optional) Analog 4-20 mA (Trouble 0 mA, Calibration 1.5 mA)
Signal Output: Sentry bus
Serial RS-485 Modbus RTU
Input:
Remote Alarm Reset: Normally open digital input (supervised or non-supervised)
Digital Input 4-20 mA
Analog Input

Electrical Data:
Power consumption: 2 watts
Connection type: 3 wire
Input voltage: 24 VDC nominal: 10-30VDC

Operating Range:
5100-99-IT
Ambient Temp (oF) 5 to 122 oF
Ambient Temp (oC) -15 to 50 oC
Relative Humidity 15 90%
Enclosure:
Material - Standard: Polyester powder-coated, sand-cast, copper-free aluminum
Material - Stainless Steel Option: 316 Stainless Steel
Enclosure Hazardous Location FM, ATEX, CSA
Approvals:
Dimensions: 5.28 x 4.9 x 4.76 inches Al & SS
(H x W x D) (10.56 x 9.8 x 9.52 cm)
Weight: 2.7 lb. (1.3 Kg) (standard Aluminum enclosure)
5.4 lb. (2.6 Kg) 316 Stainless Steel
Housing: NEMA 4X
Electrical Classification
FM Approved: Explosion proof, Class 1, Div. I, Groups B, C, D
Class I, Zone 1, Groups IIB+H2 IP66
Modbus:
Baud: 38400 (Adjustable 2400 to 38400 Baud)
Parity: None
Stop bit: 1
Data bits: 8
Flow Control: None
Memory map: Appendix E

Warranty: Limited Warranty 2 years


Specifications subject to change without notice

Ordering Information:
5100 - XX - IT - YY - ZZ
5100 Series -99=4-20mA - IT Series - Al (Aluminum Enclosure) - 01 Sentry, RS-485, 4-20mA, & Digital Input
- SS (Stainless Steel) - 02 = Sentry, RS-485, 4-20mA, Digital Input & Relays

Page: 25
Model 5100-99-IT 4-20 mA Module

APPENDIX B: - MODEL NUMBERS & PARTS LIST


Transmitter 5100-99-IT-AL-01 4-20 mA Transmitter, AL
5100-99-IT-AL-02 4-20 mA Transmitter, Relay, AL
5100-99-IT-SS-01 4-20 mA Transmitter, SS
5100-99-IT-SS-02 4-20 mA Transmitter, Relay, SS
Spare Parts SPL21824 Transmitter
SPL21810 Enclosure, Transmitter, Aluminum
SPL21823 Enclosure Transmitter, 316SS
SPL21825 Interface Board without Relay
SPL21829 Interface Board with Relay

Page: 26
Model 5100-99-IT 4-20 mA Module

APPENDIX C: LIMITED WARRANTY


SIERRA MONITOR CORPORATION warrants its products to be free from defects in workmanship or material
under normal use and service for two years after date of shipment. SMC will repair or replace without charge
any equipment found to be defective during the warranty period. Final determination of the nature and
responsibility for defective or damaged equipment will be made by SMC personnel.

All warranties hereunder are contingent upon proper use in the application for which the product was intended
and do not cover products which have been modified or repaired without SMC approval or which have been
subjected to accident, improper maintenance, installation or application, or on which original identification
marks have been removed or altered. This Limited Warranty also will not apply to interconnecting cables or
wires, consumables (ie. calibration gases, batteries, sensors), nor to any damage resulting from battery
leakage.

In all cases SMCs responsibility and liability under this warranty shall be limited to the cost of the equipment.
The purchaser must obtain shipping instructions for the prepaid return of any item under this warranty
provision and compliance with such instruction shall be a condition of this warranty.

Except for the express warranty stated above, SMC disclaims all warranties with regard to the products sold
hereunder including all implied warranties of merchantability and fitness and the express warranties stated
herein are in lieu of all obligations or liabilities on the part of SMC for damages including, but not limited to,
consequential damages arising out of/or in connection with the use or performance of the product

Page: 27
Model 5100-99-IT 4-20 mA Module

APPENDIX D: MODBUS MEMORY MAP

Read Register Table

Register Description Comments


40001 Concentration Gas Concentration multiplied by 100
40002 Temperature Temperature in degrees Celsius scaled by a factor of 100
40003 High Alarm Relay Boolean indicating the High Alarm Status, 0 No Alarm, 1 High Alarm
40004 Low Alarm Relay Boolean indicating the Low Alarm Status, 0 No Alarm, 1 Low Alarm
40005 Low Alarm Value Low alarm set point, used for activating Alarms
40006 High Alarm Value High alarm set point, used for activating High Alarms
40007 Reserved
40008 Reserved
40009 Reserved
40010 Reserved
40011 Trouble Bits 0 for no trouble
40012 Trouble 1 for any trouble, 0 for no trouble
40013 High Alarm Immediate Like 40003, but never latched
40014 Low Alarm Immediate Like 40004, but never latched
40015 Random ID Randomly generated permanent ID of sensor
40016 Restart Count
40017 Run time high In minutes
40018 Run time low In minutes
40019 Max. gas value *scale (see 40024)
40020 Model 51005, 51003, 51004, 51006, etc
40021 Range *scale (see 40024)
40022 Units 3 is PPM
40023 Temperature Units 0 is C, 1 is F
40024 Gas Scale Value like 1 or 100
40025 Temperature Scale Value like 1 or 100

Page: 28
Model 5100-99-IT 4-20 mA Module

THIS PAGE IS INTENTIONALLY LEFT BLANK

Page: 29
Model 1250-XX
Calibrator Kit Instruction Sheet

APPLICABILITY & EFFECTIVITY


This manual provides instructions for the following Sierra Monitor products:

Model Description
1250-01 Calibrator Kit, Type A
1250-02 Calibrator Kit, Type B
1250-03 Calibrator Kit, Type C

This manual is effective: March 1, 1997

Instruction Manual Part Number T15006


Instruction Manual
Model 1250
Calibrator Kit
1250-01 Type A Calibrator Kit
1250-02 Type B Calibrator Kit
1250-03 Type C Calibrator Kit

The Model 1250 Calibrator Kit (Fig. 1) is used to de-


liver calibration gas to Sierra Monitor combustible gas,
oxygen deficiency and toxic gas sensor modules. Each
kit consists of a regulator, calibration fitting, 3-feet of
tubing and carrying case. The cylinders of calibration
gas are provided separately. There are three versions
of the Calibrator Kit dependent upon the specific type
of regulator (see Figure 2) included in the kit. The three
different regulator types are required to match the three
different types of calibration gas cylinders available,
depending upon the calibration gas required.

While most situations will require only one type of regu- TUBING
CALIBRATION FITTING
lator, there are cases where the user might require more REGULATOR

than one regulator due to the use of more than one type
of calibration gas cylinder. See Table 1 to determine
which type of calibrator kit is required.

Figure 1
Model 1250-XX Calibration Kit

Calibration Cylinder Cylinder Regulator/


Gas Part No. Capacity Kit Type
Zero Grade Air 1260-00 105 liters A
H2S in Air, 25 ppm 1260-01 74 liters B
Combustibles, 50% LEL 1260-02 105 liters A
CO, 100 ppm 1260-04 105 liters A
H2S in N2, 25 ppm 1260-05 57 liters A
Cl2, 5 ppm 1260-06 104 liters C
H2, 500 ppm 1260-07 105 liters A
SO2, 50 ppm 1260-10 74 liters B
NO2, 20 ppm 1260-12 74 liters B
CO, 1000 ppm 1260-13 105 liters A
NO, 20 ppm 1260-19 74 liters B
H2S, 10 ppm 1260-21 74 liters B
ETO (C2H4O), 20 ppm 1260-27 74 liters B
CO2, 2000 ppm 1260-80 105 liters A
(Concentrations listed are nominal)

Table 1: Calibration Gas Cylinders

Page: 1 1250-XX Calibration Kit (11/10)


Instruction Manual
Procedures using Type A Regulator c. Check the pressure in the gas cylinder.
1. Preparation 1) Make sure the cylinder valve is turned off.
a. Remove the regulator, tubing, calibration 2) Make sure the valve on the regulator is
adapter and calibration gas cylinder from the closed by turning it to off position.
case.
3) Open the gas cylinder slightly by turning it
b. Connect the gas delivery tubing to the counter clockwise to the on position.
regulator's output port if it is not already con-
4) Check the pressure reading on the
nected.
regulator's pressure gauge.
c. Connect the calibration fitting to the end of the
NOTE: Do not use a cylinder if the pres-
gas sensor module.
sure drops below 50 psi; get a new gas
d. Connect the gas delivery tubing to the calibra- cylinder.
tion fitting.
5) Close the gas cylinder valve by turning it to
e. Install the regulator on the gas cylinder. the off position.
f. Check the pressure reading on the regulator's d. Connect the gas delivery tubing to the
pressure gauge. regulator's output port if it is not already con-
nected.
NOTE: Do not use a cylinder if the pressure
drops below 50 psi; get a new gas cylinder. e. Connect the calibration fitting to the end of the
Also, do not leave the regulator on the cylinder gas sensor module.
when not in use.
f. Connect the gas delivery tubing to the calibra-
2. Calibration tion fitting.
a. Depress the flow control valve and make a 1/4 2. Calibration
turn to start the flow of gas.
a. Open the gas flow valve on top of the sample
b. Allow the gas to flow to the gas sensor module gas cylinder by turning it counter clockwise.
for the time specified by the module instruc-
b. Open the gas delivery valve on the regulator
tions.
by turning it clockwise.
c. Calibrate the sensor module following the in-
c. Allow the gas to flow to the gas sensor module
structions in the sensor module instruction
for the time specified by the module instruc-
manual.
tions.
d. Depress the flow control valve and make a 1/4
d. Calibrate the sensor module following the in-
turn to stop the flow of gas.
structions in the sensor module instruction
e. Remove the regulator from the cylinder. manual.
f. Remove the tube fitting from the calibration fit- e. Close the gas delivery valve by turning it coun-
ting. terclockwise.
g. Unscrew the calibration fitting from the detec- f. Remove the tube fitting from the calibration fit-
tor head by turning it counterclockwise. ting.
h. Return the gas cylinder, regulator, calibration g. Unscrew the calibration fitting from the detec-
fitting and tubing to the calibration kit case. tor head by turning it counterclockwise.
Procedures using Type B or C Regulator 3. Finishing the calibration
1. Preparation a. Be sure the cylinder gas flow valve is closed.
a. Remove the regulator, tubing, calibration b. Remove the regulator from the sample gas cyl-
adapter and calibration gas cylinder from the inder.
case. c. Return the gas cylinder, regulator, calibration
b. Install the regulator on the gas cylinder. fitting and tubing to the calibration kit case.

1250-XX Calibration Kit (11/10) Page: 2


Instruction Manual

Cylinder Connection

Flow Control
Valve

Cylinder Connection Gas Delivery Valve


1256-01 Type A Regulator 1256-02 Type B Regulator 1256-03 Type C Regulator
Figure 2: Regulators for Model 1250-XX Calibrator Kits

Specifications for 1260 Series Gas Cylinders: Spare Parts


Type A Gas Cylinders (Combustible Gas - LEL, CO, H2, Air) Description Part No.
Dimensions (cylinder): 13.75 x 3.25 in. (34.9 x 8.2 cm) Carrying Case 1255-01
Weight (cylinder): 2.3 lb. (1.05 Kg) Calibration Tubing, 36" PTFE 1255-02
Cylinder pressure: Max 1000 psig Calibration Adapter 5358-00
Volume: 3.6 cu. ft. (103 liters) at STP
O-Ring for 1256-01 SPB69226
Type A Gas Cylinders (H2S for 4101/5100-05)
Dimensions (cylinder): 13.5 x 3.5 in. (34.3 x 8.9 cm) LIMITED WARRANTY
Weight (cylinder): 1.8 lb. (0.8 Kg) SIERRA MONITOR CORPORATION warrants its products
Cylinder pressure: Max 500 psig to be free from defects in workmanship or material under
Volume: 2.0 cu. ft. (57 liters) at STP normal use and service for two years after date of shipment.
Type B Gas Cylinders (SO2, NO2, NO, H2S, ETO) SMC will repair or replace without charge any equipment
Dimensions (cylinder): 16.25 x 4.0 in. (41.3 x 10.2 cm) found to be defective during the warranty period. Final de-
Weight (cylinder): 1.75 lb. (0.8 Kg) termination of the nature and responsibility for defective or
Cylinder pressure: Max 480 psig damaged equipment will be made by SMC personnel.
Volume: 2.6 cu. ft. (74 liters) at STP
All warranties hereunder are contingent upon proper use in
Type C Gas Cylinders (Cl2) the application for which the product was intended and do
Dimensions (cylinder): 12.25 x 3.25 in. (31.1 x 8.2 cm) not cover products which have been modified or repaired
Weight (cylinder): 2.2 lb. (1.0 Kg) without SMC approval or which have been subjected to acci-
Cylinder pressure: Max 1800 psig dent, improper maintenance, installation or application, or on
Volume: 3.7 cu. ft. (104 liters) at STP which original identification marks have been removed or
altered. This Limited Warranty also will not apply to inter-
Specifications for 1256 Series Regulators (See Figure 2): connecting cables or wires, consumables (ie. calibration gases,
batteries, sensors), nor to any damage resulting from battery
Type A Regulator - 1256-01 leakage.
Maximum Inlet Pressure: 1000 psig (69 bar)
Weight (cylinder): 1.0 lb. In all cases SMCs responsibility and liability under this war-
Inlet Connection: C-10 (5/5" - 18 UNF) ranty shall be limited to the cost of the equipment. The pur-
Outlet Connection: 3/16" hose barb chaser must obtain shipping instructions for the prepaid re-
turn of any item under this warranty provision and compli-
Type B Regulator - 1256-02
ance with such instruction shall be a condition of this war-
Maximum Inlet Pressure: 480 psig ranty.
Weight (cylinder): 1.0 lb.
Inlet Connection: CGA 170/ 1/8" hose barb Except for the express warranty stated above, SMC disclaims
Outlet Connection: 1/8" hose barb all warranties with regard to the products sold hereunder
Type C Regulator - 1256-03 including all implied warranties of merchantability and fit-
Maximum Inlet Pressure: 1800 psig ness and the express warranties stated herein are in lieu of all
Weight (cylinder): 1.0 lb. obligations or liabilities on the part of SMC for damages in-
Inlet Connection: CGA-180 1/8" hose barb cluding, but not limited to, consequential damages arising
Outlet Connection: 1/8" hose barb out of/or in connection with the use or performance of the
product.

Page: 3 1250-XX Calibration Kit (11/10)


MATERIAL SAFETY
DATA SHEET
Prepared to U.S. OSHA, CMA, ANSI and Canadian WHMIS Standards

1. PRODUCT IDENTIFICATION
CHEMICAL NAME; CLASS: NON-FLAMMABLE GAS MIXTURE
Containing One or More of the Following Components in a Nitrogen Balance Gas:
Oxygen, 0-23.5%; Methane, 0-2.5%; Hydrogen Sulfide, 0.0005-0.025 %
SYNONYMS: Not Applicable
CHEMICAL FAMILY NAME: Not Applicable
FORMULA: Not Applicable
Document Number: 50019
Note: The Material Safety Data Sheet is for this gas mixture supplied in cylinders with 33 cubic feet (935 liters) or less gas capacity (DOT - 39
cylinders). This MSDS has been developed for various gas mixtures with the composition of components within the ranges listed in Section 2
(Composition and Information on Ingredients). Refer to the product label for information on the actual composition of the product.

PRODUCT USE: Calibration of Monitoring and Research Equipment


SUPPLIER/MANUFACTURER'S NAME: CALGAZ
ADDRESS: 821 Chesapeake Drive
Cambridge, MD 21613
EMERGENCY PHONE: CHEMTREC: 1-800-424-9300
BUSINESS PHONE: 1-410-228-6400
General MSDS Information: 1-713/868-0440
Fax on Demand: 1-800/231-1366

2. COMPOSITION and INFORMATION ON INGREDIENTS


CHEMICAL NAME CAS # mole % EXPOSURE LIMITS IN AIR
ACGIH-TLV OSHA-PEL NIOSH OTHER
TWA STEL TWA STEL IDLH
ppm ppm ppm ppm ppm ppm
Hydrogen Sulfide 7783-06-4 0.0005 -0.025% 10 15 10 20 (ceiling); 100 NIOSH REL:
(Vacated 50 (ceiling, STEL = 10
1989 10 min. peak (ceiling) 10
PEL) once per 8- minutes
hour shift DFG-MAKs:
15 (vacated TWA = 10
1989 PEL) PEAK = 2MAK,
10 min.,
momentary
value: 15 ppm
Methane 74-82-8 0-2.5% There are no specific exposure limits for Methane. Methane is a simple
asphyxiant (SA). Oxygen levels should be maintained above 19.5%.
Oxygen 7782-44-7 0-23.5% There are no specific exposure limits for Oxygen. Oxygen levels should be
maintained above 19.5%.
Nitrogen 7727-37-9 Balance There are no specific exposure limits for Nitrogen. Nitrogen is a simple asphyxiant
(SA). Oxygen levels should be maintained above 19.5%.
NE = Not Established. NIC = Notice of Intended Change See Section 16 for Definitions of Terms Used.
NOTE (1): ALL WHMIS required information is included in appropriate sections based on the ANSI Z400.1-1998 format. This gas mixture has
been classified in accordance with the hazard criteria of the CPR and the MSDS contains all the information required by the CPR.

3. HAZARD IDENTIFICATION
EMERGENCY OVERVIEW: This gas mixture is a colorless gas with a disagreeable odor similar to rotten-eggs. Hydrogen Sulfide, a component of this gas mixture,
is toxic to humans in relatively low concentrations. The odor cannot be relied on as an adequate warning of the presence of Hydrogen Sulfide, because olfactory
fatigue occurs. Additionally, releases of this gas mixture may produce oxygen-deficient atmospheres (especially in confined spaces or other poorly-ventilated
environments); individuals in such atmospheres may be asphyxiated.

SYMPTOMS OF OVER-EXPOSURE BY ROUTE OF EXPOSURE: The most significant route of over-exposure for this gas mixture is by inhalation.
INHALATION: Due to the small size of an individual cylinder of this gas mixture, no unusual health effects from over-exposure to the product are
anticipated under routine circumstances of use. A significant health hazard associated with this gas mixture is the potential of inhalation of
Hydrogen Sulfide, a component of this gas mixture. Such over-exposures may occur if this gas mixture is used in a confined space or other poorly
ventilated area. Over-exposures to Hydrogen Sulfide can cause dizziness, headache, and nausea. Exposure to this component can result in
respiratory arrest, coma, or unconsciousness. Continuous inhalation of low concentrations of Hydrogen Sulfide may cause olfactory fatigue, so that
the odor is no longer an effective warning of the presence of this gas. A summary of exposure concentrations and observed effects are as follows:
CONCENTRATION OF
HYDROGEN SULFIDE OBSERVED EFFECT
0.3-30 ppm Odor is unpleasant.
50 ppm Eye irritation. Dryness and irritation of nose, throat.
Slightly higher than 50 ppm Irritation of the respiratory system.
100-150 ppm Temporary loss of smell.
200-250 ppm Headache, vomiting nausea. Prolonged exposure may lead to lung damage. Exposures of 4-8 hours can
be fatal.
300-500 Swifter onset of symptoms. Death occurs in 1-4 hours.
500 ppm Headache, excitement, staggering, and stomach ache after brief exposure. Death occurs within 0.5 - 1
hour of exposure.
> 600 ppm Rapid onset of unconsciousness, coma, death.
> 1000 ppm Immediate respiratory arrest.
NOTE: This gas mixture contains a maximum of 250 ppm Hydrogen Sulfide. The higher concentration values
here are presented to delineate the complete health effects which have been observed for humans after exposure to Hydrogen Sulfide.
Additionally, if mixtures of this gas mixture contain less than 19.5% Oxygen and are released in a small, poorly ventilated area (i.e. an enclosed or
confined space), an oxygen-deficient environment may occur. Individuals breathing such an atmosphere may experience symptoms which include
headaches, ringing in ears, dizziness, drowsiness, unconsciousness, nausea, vomiting, and depression of all the senses. Under some
circumstances of over-exposure, death may occur. The effects associated with various levels of oxygen are as follows:

NON-FLAMMABLE GAS MIXTURE MSDS - 50019 EFFECTIVE DATE: JUNE 7, 2010


PAGE 1 OF 5
3. HAZARD IDENTIFICATION (Continued)
CONCENTRATION
OF OXYGEN OBSERVED EFFECT HAZARDOUS M ATERIAL IDENTIFICATIO N SYSTEM
12-16% Oxygen: Breathing and pulse rate increased,
muscular coordination slightly disturbed.
10-14% Oxygen: Emotional upset, abnormal fatigue, H EALTH HAZARD (BLUE) 3
disturbed respiration.
6-10% Oxygen: Nausea, vomiting, collapse, or loss of
consciousness.
Below 6%: Convulsive movements, possible respiratory FLAM M AB ILITY H AZAR D (RED) 0
collapse, and death.
SKIN and EYE CONTACT: The Hydrogen Sulfide component of this gas mixture may
be irritating to the skin. Inflammation and irritation of the eyes can occur at very low
PH YSICAL H AZAR D (YELLO W ) 0
airborne concentration of Hydrogen Sulfide (less than 10 ppm). Exposure over several
hours may result in gas eyes or sore eyes with symptoms of scratchiness, irritation,
tearing and burning. Above 50 ppm Hydrogen Sulfide, there is an intense tearing,
blurring of vision, and pain when looking at light. Over-exposed individuals may see PR OTECTIVE EQU IPM ENT
rings around bright lights. Most symptoms disappear when exposure ceases. However,
EYES RESPIRATO RY HANDS BO DY
in serious cases, the eye can be permanently damaged.
HEALTH EFFECTS OR RISKS FROM EXPOSURE: An Explanation in Lay Terms.
Over-exposure to this gas mixture may cause the following health effects: See Section 8
ACUTE: Due to the small size of the individual cylinder of this gas mixture, no unusual
health effects from exposure to the product are anticipated under routine circumstances For Routine Industrial Use and Handling Applications
of use. Inhalation over-exposures to mixture containing Hydrogen Sulfide can cause
dizziness, headache, and nausea. Such over-exposures may occur if this gas mixture is used in a confined space or other poorly ventilated
environment. Exposure to high concentrations of Hydrogen Sulfide can be fatal. Continuous inhalation of low concentrations of Hydrogen Sulfide
may cause olfactory fatigue, so that the odor is no longer an effective warning of the presence this gas. Another significant hazard associated with
this gas mixture when it contains less than 19.5% oxygen is the potential for exposure to oxygen-deficient atmospheres. Symptoms of oxygen
deficiency include respiratory difficulty, ringing in ears, headaches, shortness of breath, wheezing, headache, dizziness, indigestion, nausea,
unconsciousness, and death. The skin of a victim of over-exposure may have a blue color.
CHRONIC: Severe over-exposures to mixtures containing Hydrogen Sulfide, which do not result in death, may cause long-term symptoms such as
memory loss, paralysis of facial muscles, or nerve tissue damage. In serious cases of over-exposure, the eyes can be permanently damaged.
Chronic exposure to oxygen-deficient atmospheres (below 18% oxygen in air) may affect the heart and nervous system. Refer to Section 11
(Toxicology Information) for additional information on the components of this gas mixture.
TARGET ORGANS: ACUTE: Respiratory system, blood system, cardiovascular system. CHRONIC: Nerves, eyes, cardiovascular system.
4. FIRST-AID MEASURES
RESCUERS SHOULD NOT ATTEMPT TO RETRIEVE VICTIMS OF EXPOSURE TO THIS GAS MIXTURE WITHOUT
ADEQUATE PERSONAL PROTECTIVE EQUIPMENT. At a minimum, Self-Contained Breathing Apparatus must be worn.
Victim(s) who experience any adverse effect after over-exposure to this gas mixture must be taken for medical attention. Rescuers should be taken
for medical attention if necessary. Take a copy of the label and the MSDS to physician or other health professional with victim(s).
No unusual health effects are anticipated after exposure to this gas mixture, due to the small cylinder size. If any adverse symptom develops after
over-exposure to this gas mixture, remove victim(s) to fresh air as quickly as possible. Only trained personnel should administer supplemental
oxygen and/or cardio-pulmonary resuscitation if necessary.
SKIN EXPOSURE: If irritation of the skin develops after exposure to this gas mixture, immediately begin decontamination with running water.
Minimum flushing is for 15 minutes. Remove exposed or contaminated clothing, taking care not to contaminate eyes. Victim must seek immediate
medical attention.
EYE EXPOSURE: If irritation of the eye develops after exposure to this gas mixture, open victim's eyes while under gentle running water. Use
sufficient force to open eyelids. Have victim "roll" eyes. Minimum flushing is for 15 minutes. Seek medical assistance immediately, preferably an
ophthalmologist.
MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE: Pre-existing respiratory conditions may be aggravated by over-exposure to this gas
mixture. Carbon Monoxide, a component of this gas mixture, can aggravate some diseases of the cardiovascular system, such as coronary artery
disease and angina pectoris. Because of the presence of Hydrogen Sulfide, eye disorders or skin problems may be aggravated by over-exposure
to this gas mixture.
RECOMMENDATIONS TO PHYSICIANS: Administer oxygen, if necessary; treat symptoms; reduce or eliminate exposure. Be observant for initial
signs of pulmonary edema in the event of severe inhalation over-exposures.

5. FIRE-FIGHTING MEASURES
FLASH POINT: Not applicable.
AUTOIGNITION TEMPERATURE: Not applicable.
FLAMMABLE LIMITS (in air by volume, %): NFPA RATING
Lower (LEL): Not applicable. FLAMMABILITY

Upper (UEL): Not applicable.


FIRE EXTINGUISHING MATERIALS: Non-flammable gas mixture. Use extinguishing
0
media appropriate for surrounding fire.
UNUSUAL FIRE AND EXPLOSION HAZARDS: This gas mixture contains a toxic 0
HEALTH 3 REACTIVITY
gas, Hydrogen Sulfide and presents an extreme health hazard to firefighters. This gas
mixture is not flammable; however, containers, when involved in fire, may rupture or
burst in the heat of the fire.
Explosion Sensitivity to Mechanical Impact: Not sensitive.
Explosion Sensitivity to Static Discharge: Not sensitive.
OTHER
SPECIAL FIRE-FIGHTING PROCEDURES: Structural firefighters must wear Self-
Contained Breathing Apparatus and full protective equipment.

6. ACCIDENTAL RELEASE MEASURES


LEAK RESPONSE: Due to the small size and content of the cylinder, an accidental release of this gas mixture presents significantly less risk of an
oxygen deficient environment and other safety hazards than a similar release from a larger cylinder. However, as with any chemical release,
extreme caution must be used during emergency response procedures. In the event of a release in which the atmosphere is unknown, and in
which other chemicals are potentially involved, evacuate immediate area. Such releases should be responded to by trained personnel using pre-
planned procedures. Proper protective equipment should be used. In case of a leak, clear the affected area, protect people, and respond with
trained personnel.
Allow the gas mixture to dissipate. If necessary, monitor the surrounding area (and the original area of the release) for Hydrogen Sulfide and
Oxygen. The level of Hydrogen Sulfide must be below the TLV (see Section 2, Composition on Information on Ingredients) and the atmosphere
must have at least 19.5 percent oxygen before personnel can be allowed in the area without Self-Contained Breathing Apparatus. If leaking
incidentally from the cylinder, contact your supplier.

7. HANDLING and USE


WORK PRACTICES AND HYGIENE PRACTICES: Be aware of any signs of dizziness or fatigue, especially if work is done in a poorly ventilated
area; exposures to fatal concentrations of this gas mixture could occur without any significant warning symptoms, due to Hydrogen Sulfide over-
exposure and oxygen deficiency. Do not attempt to repair, adjust, or in any other way modify the cylinders containing this gas mixture. If there is a
malfunction or another type of operational problem, contact the nearest distributor immediately. Eye wash stations/safety showers should be near
areas where this gas mixture is used or stored. All work operations should be monitored in such a way that emergency personnel can be
immediately contacted in the event of a release. All work practices should minimize releases of Hydrogen Sulfide-containing gas mixtures.

NON-FLAMMABLE GAS MIXTURE MSDS - 50019 EFFECTIVE DATE: JUNE 7, 2010


PAGE 2 OF 5
7. HANDLING and USE(Continued)
STORAGE AND HANDLING PRACTICES: Cylinders should be firmly secured to prevent falling or being knocked-over. Cylinders must be
protected from the environment, and preferably kept at room temperature (approximately 21C [70F]). Cylinders should be stored in dry, well-
ventilated areas, away from sources of heat, ignition, and direct sunlight. Protect cylinders against physical damage. Full and empty cylinders
should be segregated. Use a first-in, first-out inventory system to prevent full containers from being stored for long periods of time. These cylinders
are not refillable. WARNING! Do not refill DOT 39 cylinders. To do so may cause personal injury or property damage.
SPECIAL PRECAUTIONS FOR HANDLING GAS CYLINDERS: WARNING! Compressed gases can present significant safety hazards. During
cylinder use, use equipment designed for these specific cylinders. Ensure all lines and equipment are rated for proper service pressure.
PROTECTIVE PRACTICES DURING MAINTENANCE OF CONTAMINATED EQUIPMENT: Follow practices indicated in Section 6 (Accidental
Release Measures). Make certain that application equipment is locked and tagged-out safely. Always use product in areas where adequate
ventilation is provided.

8. EXPOSURE CONTROLS - PERSONAL PROTECTION


VENTILATION AND ENGINEERING CONTROLS: No special ventilation systems or engineering controls are needed under normal
circumstances of use. As with all chemicals, use this gas mixture in well-ventilated areas. If this gas mixture is used in a poorly-ventilated area,
install automatic monitoring equipment to detect the levels of Hydrogen Sulfide and Oxygen.
RESPIRATORY PROTECTION: No special respiratory protection is required under normal circumstances of use. Use supplied air respiratory
protection if the levels of components exceeds exposure limits presented in Section 2 (Composition and Information of Ingredients) and Oxygen
levels are below 19.5%, or unknown, during emergency response to a release of this gas mixture. If respiratory protection is needed, use only
protection authorized in the U.S. Federal OSHA Standard (29 CFR 1910.134), applicable U.S. State regulations, or the Canadian CSA Standard
Z94.4-93 and applicable standards of Canadian Provinces. Oxygen levels below 19.16.33% are considered IDLH by OSHA. In such
atmospheres, use of a full-facepiece pressure/demand SCBA or a full facepiece, supplied air respirator with auxiliary self-contained air supply is
required under OSHAs Respiratory Protection Standard (1910.134-1998).
RESPIRATORY PROTECTION: The following NIOSH respiratory protection recommendations for Hydrogen Sulfide are provided for further
information.
NIOSH/OSHA RECOMMENDATIONS FOR HYDROGEN SULFIDE CONCENTRATIONS IN AIR:
Up to 100 ppm Powered air-purifying respirator with cartridge(s) to protect against hydrogen sulfide; or gas mask with canister to
protect against hydrogen sulfide; or SAR; or full-facepiece SCBA.
Emergency or Planned Entry into Unknown Concentration or IDLH Conditions: Positive pressure, full-facepiece SCBA; or positive pressure, full-
facepiece SAR with an auxiliary positive pressure SCBA.
Escape Gas mask with canister to protect against hydrogen sulfide; or escape-type SCBA
The IDLH concentration for Hydrogen Sulfide is 100 ppm.
EYE PROTECTION: Safety glasses. If necessary, refer to U.S. OSHA 29 CFR 1910.133 or appropriate Canadian Standards.

HAND PROTECTION: Wear leather gloves when handling cylinders. Chemically resistant gloves should be worn when using this gas mixture. If
necessary, refer to U.S. OSHA 29 CFR 1910.138 or appropriate Standards of Canada.
BODY PROTECTION: No special protection is needed under normal circumstances of use. If a hazard of injury to the feet exists due to falling
objects, rolling objects, where objects may pierce the soles of the feet or where employees feet may be exposed to electrical hazards, use foot
protection, as described in U.S. OSHA 29 CFR 1910.136.
9. PHYSICAL and CHEMICAL PROPERTIES
The following information is for Nitrogen, the main component of this gas mixture.
3 3
GAS DENSITY @ 32F (0C) and 1 atm: .072 lbs/ ft (1.153 kg/m )
FREEZING/MELTING POINT @ 10 psig: -345.8F (-210C) BOILING POINT: -320.4F (-195.8C)
SPECIFIC GRAVITY (air = 1) @ 70F (21.1C): 0.906 pH: Not applicable.
SOLUBILITY IN WATER vol/vol @ 32F (0C) and 1 atm: 0.023 MOLECULAR WEIGHT: 28.01
EVAPORATION RATE (nBuAc = 1): Not applicable. EXPANSION RATIO: Not applicable.
3
VAPOR PRESSURE @ 70F (21.1C) (psig): Not applicable. SPECIFIC VOLUME (ft /lb): 13.8
COEFFICIENT WATER/OIL DISTRIBUTION: Not applicable.

The following information is for this gas mixture.


ODOR THRESHOLD: 0.13 ppm (Hydrogen Sulfide)
APPEARANCE AND COLOR: This gas mixture is a colorless gas which has an rotten egg-like odor, due to the presence of Hydrogen Sulfide.
HOW TO DETECT THIS SUBSTANCE (warning properties): Continuous inhalation of low concentrations of this gas mixture may cause
olfactory fatigue, due to the presence of Hydrogen Sulfide, so the odor is not a good warning property of a release of this gas mixture. In terms of
leak detection, fittings and joints can be painted with a soap solution to detect leaks, which will be indicated by a bubble formation. Wet lead
acetate paper can be used for leak detection. The paper turns black in the presence of Hydrogen Sulfide. Cadmium chloride solutions can also
be used. Cadmium solutions will turn yellow upon contact with Hydrogen Sulfide.

10. STABILITY and REACTIVITY


STABILITY: Normally stable in gaseous state.
DECOMPOSITION PRODUCTS: The thermal decomposition products of Methane include carbon oxides. The decomposition products of
Hydrogen Sulfide include water and sulfur oxides. The other components of this gas mixture do not decompose, per se, but can react with other
compounds in the heat of a fire.
MATERIALS WITH WHICH SUBSTANCE IS INCOMPATIBLE: Titanium will burn in Nitrogen (the main component of this gas mixture). Lithium
reacts slowly with Nitrogen at ambient temperatures. Components of this gas mixture (Hydrogen Sulfide and Methane) are also incompatible with
strong oxidizers (i.e. chlorine, bromine pentafluoride, oxygen difluoride, and nitrogen trifluoride). Hydrogen Sulfide is corrosive to most metals,
because it reacts with these substances to form metal sulfides.
HAZARDOUS POLYMERIZATION: Will not occur.
CONDITIONS TO AVOID: Contact with incompatible materials. Cylinders exposed to high temperatures or direct flame can rupture or burst.

11. TOXICOLOGICAL INFORMATION


TOXICITY DATA: The following toxicology data are available for the components of this gas mixture:
NITROGEN: LCLo (Inhalation-Man) 5700 g/kg: Behavioral: change in blood or tissue levels: cytochrome
There are no specific toxicology data for coma; Lungs, Thorax, or Respiration: chronic oxidases (including oxidative
Nitrogen. Nitrogen is a simple asphyxiant, pulmonary edema phosphorylation)
which acts to displace oxygen in the LCLo (Inhalation-Human) 800 ppm/5 minutes HYDROGEN SULFIDE (continued):
environment. LCLo(Inhalation-Mammal-species unspecified) TCLo (Inhalation-Rat) 80 ppm/6 hours/90 days-
METHANE: 800 ppm/5 minutes intermittent: Brain and Coverings: changes in
There are no specific toxicology data for TCLo (Inhalation-Rat) 30 ppm/6 hours/10 brain weight; Nutritional and Gross Metabolic:
Methane. Methane is a simple asphyxiant, weeks-intermittent: Sense Organs and weight loss or decreased weight gain
which acts to displace oxygen in the Special Senses (Olfaction): olfactory nerve TCLo (Inhalation-Rat) 20 ppm: female 6-22
environment. change, effect, not otherwise specified day(s) after conception lactating female 21
HYDROGEN SULFIDE: TCLo (Inhalation-Rat) 1200 mg/m3/2 hours/5 day(s) post-birth: Reproductive: Effects on
LC50 (Inhalation-Rat) 444 ppm: Lungs, Thorax, days-intermittent: Brain and Coverings: other Newborn: physical
or Respiration: other changes; degenerative changes; Biochemical: Enzyme TCLo (Inhalation-Mouse) 80 ppm/6 hours/90
Gastrointestinal: hypermotility, diarrhea; inhibition, induction, or change in blood or days-intermittent: Nutritional and Gross
Kidney, Ureter, Bladder: urine volume tissue levels: true cholinesterase Metabolic: weight loss or decreased weight
increased TCLo (Inhalation-Rat) 100 ppm/8 hours/5 gain; Related to Chronic Data: death
LC50 (Inhalation-Mouse) 634 ppm/1 hour weeks-intermittent: Brain and Coverings: TCLo (Inhalation-Rabbit) 40 mg/m3/5 hours/30
LCLo (Inhalation-Human) 600 ppm/30 minutes other degenerative changes; Lungs, Thorax, weeks-intermittent: Sense Organs and Special
HYDROGEN SULFIDE (continued): or Respiration: other changes; Senses (Eye): conjunctive irritation
Biochemical:Enzyme inhibition, induction,or
SUSPECTED CANCER AGENT: The components of this gas mixture are not found on the following lists: FEDERAL OSHA Z LIST, NTP,
CAL/OSHA, and IARC; therefore, are not considered to be, nor suspected to be, cancer-causing agents by these agencies.
IRRITANCY OF PRODUCT: Due to the presence of Hydrogen Sulfide, this gas mixture is irritating to the eyes, and may be irritating to the skin.
SENSITIZATION TO THE PRODUCT: No component of this gas mixture is known to be a sensitizer.
REPRODUCTIVE TOXICITY INFORMATION: Listed below is information concerning the effects of this gas mixture and its components on the
human reproductive system.

NON-FLAMMABLE GAS MIXTURE MSDS - 50019 EFFECTIVE DATE: JUNE 7, 2010


PAGE 3 OF 5
11. TOXICOLOGICAL INFORMATION(Continued)
Mutagenicity: No mutagenicity effects have been described for the components of this gas mixture.
Embryotoxcity: No embryotoxic effects have been described for the components of this gas mixture.
Teratogenicity: No teratogenicity effects have been described for the components of this gas mixture.
Reproductive Toxicity: No reproductive toxicity effects have been described for the components of gas mixture.
A mutagen is a chemical which causes permanent changes to genetic material (DNA) such that the changes will propagate through generation
lines. An embryotoxin is a chemical which causes damage to a developing embryo (i.e. within the first eight weeks of pregnancy in humans), but
the damage does not propagate across generational lines. A teratogen is a chemical which causes damage to a developing fetus, but the damage
does not propagate across generational lines. A reproductive toxin is any substance which interferes in any way with the reproductive process.
BIOLOGICAL EXPOSURE INDICES (BEIs): Currently, Biological Exposure Indices (BEIs) have not been determined for the components of this
gas mixture.

12. ECOLOGICAL INFORMATION


ENVIRONMENTAL STABILITY: The gas will be dissipated rapidly in well-ventilated areas. The following environmental data are applicable to the
components of this gas mixture.
HYDROGEN SULFIDE:
Water Solubility = 1 g/242 mL at 20C.
Plant toxicity: Continuous fumigation of plants with 300 or 3000 ppb Hydrogen Sulfide caused leaf lesions, defoliation, and reduced growth with severity of injury
correlated to dose. At higher (3.25 and 5.03 ppm) Hydrogen Sulfide, significant reductions in leaf CO2 and water vapor exchanges occurred, and stomatal
openings were depressed. When Hydrogen Sulfide gas was applied to 29 species of green plants for 5 hours, young, rapidly elongating tissues were more
sensitive to injury than older tissues. Symptoms included scorching of young shoots and leaves, basal and marginal scorching of older leaves. Mature leaves
were unaffected. Seeds exposed to Hydrogen Sulfide gas showed delay in germination.
Persistence: Converts to elemental sulfur upon standing in water.
Major Species Threatened: Aquatic and animal life plants may be injured if exposed to 5 ppm in air over 24 hours.
Biodegradation: Microorganisms in soil and water are involved in oxidation-reduction reactions that oxidize hydrogen sulfide to elemental sulfur. Members of the
genera Beggiatoa, Thioploca, and Thiotrix function in transition zones between aerobic and anaerobic conditions where both molecular oxygen and hydrogen
sulfide are found. Also, some photosynthetic bacteria oxidize hydrogen sulfide to elemental sulfur. Members of the families Chlorobiaceae and Chromatiaceae
(purple sulfur bacteria) are obligate aerobes and are phototropic, and are found in waters with high H2S concentrations. The interactions of these organisms form
part of the global sulfur cycle.
Bioconcentration: Does not have bioaccumulation or food chain contamination potential.
OXYGEN: Water Solubility = 1 volume Oxygen/32 volumes water at 20C. Log Kow = -0.65
NITROGEN: Water Solubility = 2.4 volumes Nitrogen/100 volumes water at 0C. 1.6 volumes Nitrogen/100 volumes water at 20C.
EFFECT OF MATERIAL ON PLANTS or ANIMALS: Due to the presence of Hydrogen Sulfide in this gas mixture, releases of this gas mixture can
be harmful or fatal to plant and animal life.
EFFECT OF CHEMICAL ON AQUATIC LIFE: Hydrogen Sulfide, a component of this gas mixture, is harmful if released in an aquatic environment.
All handling procedures should be aimed at preventing a release of Hydrogen Sulfide to the environment. The following aquatic toxicity data are
available for Hydrogen Sulfide:
HYDROGEN SULFIDE: HYDROGEN SULFIDE (continued): HYDROGEN SULFIDE (continued):
LC50 (Asellus arthropods) 96 hours = 0.111 LC50,F (bluegill, 35-day-old fry) 96 hours = Lethal (goldfish) 96 hours = 10 mg/L
mg/L 0.0131 mg/L Toxic (carp) 24 hours = 3.3 mg/L
LC50 (Crangon arthropods) 96 hours = 1.07 LC50,F (bluegill, juveniles) 96 hours = 0.0478 Toxic (goldfish) 24 hours = 4.3 mg/L
mg/L mg/L Toxic (sunfish) 1 hour = 4.9 to 5.3 mg/L
LC50 (Gammarus arthropods) 96 hours = 0.84 LC50,F (bluegill, adults) 96 hours = 0.0448 Toxic (goldfish) 200 hours = 5 mg/L
mg/L mg/L Toxic (minnows) 24 hours = 5-6 mg/L
LC50 (Ephemera) 96 hours = 0.316 mg/L LC50,F (fathead minnows) 96 hours = 0.0071- Toxic (carp) 24 hours = 6-25 mg/L
LC50 (Inhalation-Flies) > 960 minutes = 380 0.55 mg/L Toxic (trout) 15 minutes = 10 mg/L
mg/m3 LC50,F (bluegill) 96 hours = 0.0090-0.0140 Toxic (goldfish) 24 hours = 25 mg/L
LC50 (Inhalation-Flies) 7 minutes = 1,500 mg/L Toxic (tench) 3 hours = 100 mg/L
mg/m3 LC50,F (brook trout) 96 hours = 0.0216-0.0308 MATC,F (fathead minnows) 0.0037 mg/L
LC50,F (bluegill, eggs) 72 hours = 0.0190 mg/L MATC,F (bluegill) 0.0004 mg/L
mg/L Toxic (goldfish) = 100 mg/L MATC,F (brook trout) 0.055 mg/L

13. DISPOSAL CONSIDERATIONS


PREPARING WASTES FOR DISPOSAL PREPARING WASTES FOR DISPOSAL: Waste disposal must be in accordance with appropriate
Federal, State, and local regulations. Cylinders with undesired residual product may be safely vented outdoors with the proper regulator. For
further information, refer to Section 16 (Other Information).

14. TRANSPORTATION INFORMATION


THIS GAS MIXTURE IS HAZARDOUS AS DEFINED BY 49 CFR 172.101 BY THE U.S. DEPARTMENT OF TRANSPORTATION.
PROPER SHIPPING NAME: Compressed gases, n.o.s. (*Oxygen, Nitrogen)*or the gas component with the next highest
concentration next to Nitrogen.
HAZARD CLASS NUMBER and DESCRIPTION: 2.2 (Non-Flammable Gas)
UN IDENTIFICATION NUMBER: UN 1956
PACKING GROUP: Not applicable.
DOT LABEL(S) REQUIRED: Non-Flammable Gas
NORTH AMERICAN EMERGENCY RESPONSE GUIDEBOOK NUMBER (2000): 126
MARINE POLLUTANT: The components of this gas mixture are not classified by the DOT as Marine Pollutants (as defined by 49 CFR 172.101,
Appendix B).
SPECIAL SHIPPING INFORMATION: Cylinders should be transported in a secure position, in a well-ventilated vehicle. The transportation of
compressed gas cylinders in automobiles or in closed-body vehicles can present serious safety hazards. If transporting these cylinders in
vehicles, ensure these cylinders are not exposed to extremely high temperatures (as may occur in an enclosed vehicle on a hot day).
Additionally, the vehicle should be well-ventilated during transportation.
Note: DOT 39 Cylinders ship in a strong outer carton (overpack). Pertinent shipping information goes on the outside of the overpack. DOT 39
Cylinders do not have transportation information on the cylinder itself.
TRANSPORT CANADA TRANSPORTATION OF DANGEROUS GOODS REGULATIONS: This gas mixture is considered as Dangerous Goods,
per regulations of Transport Canada.
PROPER SHIPPING NAME: Compressed gases, n.o.s. (*Oxygen, Nitrogen)*or the gas component with the
next highest concentration next to Nitrogen.
HAZARD CLASS NUMBER and DESCRIPTION: 2.2 (Non-Flammable Gas)
UN IDENTIFICATION NUMBER: UN 1956
PACKING GROUP: Not Applicable
HAZARD LABEL: Class 2.2 (Non-Flammable Gas)
SPECIAL PROVISIONS: None
EXPLOSIVE LIMIT AND LIMITED QUANTITY INDEX: 0.12
ERAP INDEX: 3000
PASSENGER CARRYING SHIP INDEX: Forbidden
PASSENGER CARRYING ROAD VEHICLE OR PASSENGER CARRYING RAILWAY VEHICLE INDEX: Forbidden
NORTH AMERICAN EMERGENCY RESPONSE GUIDEBOOK NUMBER (2000): 126
NOTE: Shipment of compressed gas cylinders via Public Passenger Road Vehicle is a violation of Canadian law (Transport Canada
Transportation of Dangerous Goods Act, 1992).

NON-FLAMMABLE GAS MIXTURE MSDS - 50019 EFFECTIVE DATE: JUNE 7, 2010


PAGE 4 OF 5
15. REGULATORY INFORMATION
ADDITIONAL U.S. REGULATIONS:
U.S. SARA REPORTING REQUIREMENTS: This gas mixture is subject to the reporting requirements of Sections 302, 304, and 313 of Title III of
the Superfund Amendments and Reauthorization Act, as follows:
CHEMICAL NAME SARA 302 SARA 304 SARA 313
(40 CFR 355, Appendix A) (40 CFR Table 302.4) (40 CFR 372.65)
Hydrogen Sulfide YES YES YES

U.S. SARA THRESHOLD PLANNING QUANTITY: Hydrogen Sulfide = 500 lb (227 kg)
U.S. TSCA INVENTORY STATUS: The components of this gas mixture are listed on the TSCA Inventory.
U.S. CERCLA REPORTABLE QUANTITY (RQ): Hydrogen Sulfide = 100 lb (45 kg)
OTHER U.S. FEDERAL REGULATIONS:
Hydrogen Sulfide is subject to the reporting requirements of CFR 29 1910.1000.
Hydrogen Sulfide and Methane are subject to the reporting requirements of Section 112(r) of the Clean Air Act. The Threshold Quantity for
each of these gases is 10,000 pounds and so this mixture will not be affected by the regulation.
Depending on specific operations involving the use of this gas mixture, the regulations of the Process Safety Management of Highly
Hazardous Chemicals may be applicable (29 CFR 1910.119). Hydrogen Sulfide is listed in Appendix A of this regulation. The Threshold
Quantity for Hydrogen Sulfide under this regulation is 1500 lbs (and so one cylinder of this gas mixture will not be affected by this regulation).
This gas mixture does not contain any Class I or Class II ozone depleting chemicals (40 CFR part 82).
Nitrogen and Oxygen are not listed Regulated Substances, per 40 CFR, Part 68, of the Risk Management for Chemical Releases. Hydrogen
Sulfide is listed under this regulation in Table 1 as a Regulated Substance (Toxic Substance), in quantities of 10,000 lbs (4,553 kg) or greater.
U.S. STATE REGULATORY INFORMATION: The components of this gas mixture are covered under the following specific State regulations:
Alaska - Designated Toxic and Hazardous Michigan - Critical Materials Register: No. Pennsylvania - Hazardous Substance List:
Substances: Methane, Hydrogen Sulfide. Minnesota - List of Hazardous Substances: Oxygen, Nitrogen, Methane, Hydrogen Sulfide.
California - Permissible Exposure Limits for Methane, Hydrogen Sulfide. Rhode Island - Hazardous Substance List:
Chemical Contaminants: Nitrogen, Methane, Missouri - Employer Information/Toxic Oxygen, Nitrogen, Methane, Hydrogen Sulfide.
Hydrogen Sulfide. Substance List: Methane, Hydrogen Sulfide. Texas - Hazardous Substance List: Hydrogen
Florida - Substance List: Oxygen, Hydrogen New Jersey - Right to Know Hazardous Sulfide.
Sulfide. Substance List: Oxygen, Nitrogen, Methane, West Virginia - Hazardous Substance List:
Illinois - Toxic Substance List: Hydrogen Sulfide. Hydrogen Sulfide. Hydrogen Sulfide.
Kansas - Section 302/313 List: Hydrogen Sulfide. North Dakota - List of Hazardous Chemicals, Wisconsin - Toxic and Hazardous Substances:
Massachusetts - Substance List: Oxygen, Reportable Quantities: Hydrogen Sulfide. Hydrogen Sulfide.
Methane, Hydrogen Sulfide.
CALIFORNIA SAFE DRINKING WATER AND TOXIC ENFORCEMENT ACT (PROPOSITION 65): No component of this gas mixture is on the
California Proposition 65 lists.
ADDITIONAL CANADIAN REGULATIONS:
CANADIAN DSL/NDSL INVENTORY STATUS: The components of this gas mixture are listed on the DSL Inventory.
CANADIAN ENVIRONMENTAL PROTECTION ACT (CEPA) PRIORITIES SUBSTANCES LISTS: The components of this gas mixture are not on
the CEPA Priorities Substances Lists.
CANADIAN WHMIS CLASSIFICATION: This gas mixture is categorized as a Controlled Product, Hazard Classes A and D2A, as per the
Controlled Product Regulations.
16. OTHER INFORMATION
INFORMATION ABOUT DOT-39 NRC (Non-Refillable Cylinder) PRODUCTS
DOT 39 cylinders ship as hazardous materials when full. Once the cylinders are relieved of pressure (empty) they are not considered
hazardous material or waste. Residual gas in this type of cylinder is not an issue because toxic gas mixtures are prohibited. Calibration gas
mixtures typically packaged in these cylinders are Nonflammable n.o.s., UN 1956. A small percentage of calibration gases packaged in DOT
39 cylinders are flammable or oxidizing gas mixtures.
For disposal of used DOT-39 cylinders, it is acceptable to place them in a landfill if local laws permit. Their disposal is no different than that
employed with other DOT containers such as spray paint cans, household aerosols, or disposable cylinders of propane (for camping, torch
etc.). When feasible, we recommended recycling for scrap metal content. CALGAZ will do this for any customer that wishes to return
cylinders to us prepaid. All that is required is a phone call to make arrangements so we may anticipate arrival. Scrapping cylinders involves
some preparation before the metal dealer may accept them. We perform this operation as a service to valued customers who want to
participate.

MIXTURES: When two or more gases or liquefied gases are mixed, their hazardous properties may combine to create additional, unexpected
hazards. Obtain and evaluate the safety information for each component before you produce the mixture. Consult an Industrial Hygienist or
other trained person when you make your safety evaluation of the end product. Remember, gases and liquids have properties which can
cause serious injury or death.

Further information about the handling of compressed gases can be found in the following pamphlets published by: Compressed Gas
Association Inc. (CGA), 1725 Jefferson Davis Highway, Suite 1004, Arlington, VA 22202-4102. Telephone: (703) 412-0900.
P-1 Safe Handling of Compressed Gases in Containers
AV-1 Safe Handling and Storage of Compressed Gases
Handbook of Compressed Gases
PREPARED BY: CHEMICAL SAFETY ASSOCIATES, Inc.
PO Box 3519, La Mesa, CA 91944-3519
619/670-0609
Fax on Demand: 1-800/231-1366

This Material Safety Data Sheet is offered pursuant to OSHAs Hazard Communication Standard, 29 CFR, 1910.1200. Other government regulations must be
reviewed for applicability to this gas mixture. To the best of CALGAZ knowledge, the information contained herein is reliable and accurate as of this date;
however, accuracy, suitability or completeness are not guaranteed and no warranties of any type, either express or implied, are provided. The information
contained herein relates only to this specific product. If this gas mixture is combined with other materials, all component properties must be considered. Data
may be changed from time to time. Be sure to consult the latest edition.

NON-FLAMMABLE GAS MIXTURE MSDS - 50019 EFFECTIVE DATE: JUNE 7, 2010


PAGE 5 OF 5
Model 4400
In-Stream Hydrogen Sulfide Analyzer

The Model 4400 In-Stream Hydrogen Sulfide Analyzer


is used to continuously verify the H2S content of a natu-
ral gas sample for the presence of 0-100 ppm levels of
Hydrogen Sulfide. This system is used to insure that
H2S levels in natural gas collection lines remains at ac-
ceptable levels to help guard against the corrosive ef-
fects of H2S on compressors, pipelines and process
equipment. It is intended for continuous monitoring prior
to the addition of odorants to the gas.

The Sierra Monitor Model 4400 provides the user with a


low-cost, easy-to-use solution to effective monitoring of
natural gas streams. This system accurately measures
H2S concentration in the 0-100 ppm range. Fast re-
sponse of 90% of step change within 30 seconds en- A 4-20 mA linear signal proportional to sample concen-
ables the user to respond quickly to changes in natural tration is provided from the sensor assembly. This sig-
gas supply conditions to prevent product contamination. nal can interface with a Sierra Monitor Model 4107-99
Transmitter/Display, a single channel controller, the Sen-
There is minimal maintenance with the Model 4400 with try multi-channel controller or most industry standard
no tapes to replace, no conditioning solutions, no me- controllers or PLCs.
chanical stream blenders to calibrate. Calibration is easy
with external application of span gas and simple one The Model 5100-99-IT-AL Transmitter/Display option can
person adjustments. Calibration and swapping of the accept the 4-20 mA signal from the Model 4400-10 and
gas sensor is a quick and simple operation performed provide digital display of the H2S concentration, dual
every two weeks. concentration alarm contacts, 4-20 mA output and se-
rial MODBUS communication. The Model 5100-99-IT-
The 4400-10 receives a low pressure natural gas slip- AL can be mounted directly to the Model 4400 H2S Ana-
stream sample. A flow controller in the system delivers lyzer or at a remote location. The Model 5100-99-IT-AL
a constant flow to the gas sensor and allows for easy is mounted in an explosion proof enclosure available in
calibration and maintenance. An in-line coalescing filter aluminum or stainless steel enclosures.
protects the system from sample contaminants.

Features Benefits

No tapes to replace or conditioning solutions Minimal maintenance, no hazardous material to


dispose

Fast response Prevention of product contamination

Simple one-person adjustments Easy calibration, minimal service time

Sierra Monitor Corporation 1991 Tarob Court Milpitas, CA 95035 USA (408) 262-6611 (800) 727-4377 Fax: (408) 262-9042
Model 4400
In-Stream Hydrogen Sulfide Analyzer
Specifications:
4400 In-Stream Analyzer 5100-99-IT Transmitter/Display
Power: 24VDC Power: 24VDC

Output: 4-20 mA = 0-100 ppm H2S Operating


Temperature Range: -40 to 50oC (-40 to 122oF)
Environmental:
Temperature Range Display: Fixed and Scrolling LED
Operating:: -20 to 50oC (-4 to 122oF)
Storage: -40 to 50oC (-40 to 122oF) Optional Alarms: Dual level alarms (8A) plus
Humidity: 0-95% RH (non-condensing) fault alarm (4A)

Sensor: Serial Output: Bi-directional RS-485


Range: 0-100 ppm Hydrogen Sulfide MODBUS protocol
Type: Electrochemical Mechanical:
Life: Approximately 1 year in cycled Housing: Aluminum: Epoxy-coated, die-cast,
service copper-fire aluminum
Response: <30 seconds to 90% FS Stainless Steel: 316 Stainless Steel
Dimensions( WxHxD):
Mechanical: Aluminum: 6.0 x 4.4 x 4.9 in.
Area Classification: Div 1, Class 1, Groups B,C,D 316 Stainless Steel: 5.9 x 4.8 x 4.9 in.
Enclosure: NEMA-1 with removable cover panel Weight:
Mounting: installs on 9 x 7 H Frame Aluminum: 2.7 lbs (1.3 Kg)
Connections: 3 position terminal strip with 316 Stainless Steel: 5.4 lbs (2.6 Kg)
separate conduit
Dimensions (WxHxD): 9.0 x 11.0 x 4.0 inches
(22.9 x 27.9 x 10.2 cm)
Weight: 5 lbs (2.2 Kg)

Warranty: 2 years as non non-consumable items

Ordering Information:

4400-10 In-Stream Hydrogen Sulfide Monitor


Single Point Explosion Proof Transmitter/Display
Model Enclosure Relay/Connection
5100-99-IT -XX -XX -00 -0 -0 -0
- A1 = AL 3/4 NPT - 01 = No Relays
- A2 = AL M20 x 1.5 - 02 = Relays/Aux. Conn.
- S1 = SS 3/4 NPT
- S2 = SS M20 x 1.5

Model 5100-99-IT-AL Transmitter/Display

Sierra Monitor Corporation 1991 Tarob Ct. Milpitas, CA 95035 (408) 262-6611 800-727-4377 FAX: (408) 262-9042
Visit our Web site at: www.sierramonitor.com E-Mail: [email protected]
2011 by Sierra Monitor Corporation
Sentry IT Series
5100-99-IT 4-20mA Transmitter

Easily interface sensor device to 4-20mA,


Modbus, relays or Sentry bus

The IT Toxic Series 4-20mA Transmitter requires


minimal maintenance and has continuous self-
diagnostics that will automatically detect and
indicate any fault condition. This transmitter
interfaces sensor devices to other devices using
RS-485 Modbus RTU communications, a three or
four wire 4-20 mA analog output signal, or directly
to Sentry Controllers via Sentrybus. By integration
of IT modules into a Sentry system the user gains
the capability of system Modbus serial
communications, extensive diagnostic features,
WebServer interface, multiplexed sensor wiring and
field-proven reliability.

Sentry IT technology has the benefits of: Non-intrusive calibration and set-up
Non-intrusive, one-person calibration and best Extensive diagnostics for reliability
in industry calibration frequencies for reduced Choice or combination of outputs:
maintenance costs (depending upon
9 4-20 mA output (3 or 4 wire)
sensor/device)
9 Serial RS-485 Modbus RTU interface
User-friendly, 8-character, fixed and scrolling
LED display for ease of set-up and calibration 9 SMC Sentry digital bus Interface
Cast aluminum or 316 Stainless Steel 9 Standard 2 Amp Trouble relay
enclosures for Class I, Div. 1, Groups B, C, D 9 Optional 8 Amp Integral High/Low relays
areas
Comprehensive user-friendly menus

Specifications:
Output: Enclosure:
Display: Fixed and Scrolling LED Material Standard:
Relays: 2 Amp Trouble all SPDT Polyester powder-coated, sand-cast,
8 Amp, High Alarm, Low Alarm (optional) copper-free aluminum
Analog Output: ISA Standard Type 3 or Type 4(see Fig. 1.1) Material Stainless Steel Option:
Analog 4-20 mA (Trouble 2.5 mA, 316 Stainless Steel
Calibration 1.5 mA) Enclosure Hazardous Location Approvals:
Signal Outputs: Sentry bus FM, ATEX, CSA
Serial RS-485 Modbus RTU Dimensions: 7.5 x 5.0 x 4.8 in. AL, 7.5 x 5.0 x 4.4 in. SS

Input: (H x W x D) (21.6 x 12.7 x 12.2 cm.)


Digital Input: Normally open digital Weight: 2.7 lb. (1.3 Kg) standard Aluminum enclosure
Analog Input (supervised or non-supervised) 5.4 lb. (2.6 Kg) 316 Stainless Steel
4-20 mA Housing: NEMA 4X
Electrical Classification:
Electrical Data: FM Approved: Explosion proof, Class 1, Div. I, Groups B, C, D
Power consumption: 2 watts maximum Class I, Zone 1, Groups IIB + H2 IP66
Connection type: 3 wire
Input voltage: 24 VDC nominal: 10-30VDC Modbus:
Baud: 38400 (Adjustable 2400 38400 Baud)
Operating Range: Parity: None
o
Ambient Temp ( F):
o
5 to 122 F Stop bit: 1
o o Data bits: 8
Ambient Temp ( C): -15 to 30 C
Flow Control: None
Relative Humidity: 15 90%
Memory map available from Sierra Monitor

Warranty: Limited Warranty 2 years


Specifications subject to change without notice

Sierra Monitor Corporation 1991 Tarob Ct. Milpitas, CA 95035 (408) 262-6611 (800) 727-4377 Fax: (408) 262-9042
Web site: www.sierramonitor.com E-Mail: [email protected]
07/09 Rev. A1
5100-99-IT 4-20mA Transmitter

Ordering Information:
Relay/ Remote
Model Enclosure Connection Output Protection Option
5100 - XX - IT - XX - XX - XX - X - X
5100 Series - 99 = 4-20mA - IT Series - AL = AL - 01 = No Relays - 00 = Standard - 0 = Standard - 0 = None
Transmitter - SS = SS - 02 = Relays - 1 = Marine
- 2 = Conformal

Figure 1.1
3-wire and 4-wire
4-20mA output

Sierra Monitor Corporation 1991 Tarob Ct. Milpitas, CA 95035 (408) 262-6611 (800) 727-4377 Fax: (408) 262-9042
Web site: www.sierramonitor.com E-Mail: [email protected]
07/09 Rev. A1
By Kristie Seagroves at 1:15 pm, Nov 30, 2011

3K401-22644
CERTIFICATE OF ORIGIN

I certify that on November 21, 2011, Sierra Monitor Corporation furnished the supplies and/or
services under the referenced purchase order in accordance with all applicable requirements. I
further certify that Sierra Monitor Corporation in the United States of America manufactured the
supplies. The supplies are of the quality specified; conforming in all respects with the contract
requirements, including specifications, drawing, preservation, packaging, origin, packing,
marking, and physical item identification, (part number), requirements, and are in the quantity
shown on this or on the attached documents.

Customer: Solar Turbines, Inc.


13105 Northeast Freeway, Suite 400
Houston, TX 77040 USA

Ship to: Solar Turbines, Inc.


c/o HJH forwarding
8620 San Gabriel
Laredo TX 78405 USA

Purchase Order No.: ECP005904

SMC Order No: 113442

Destination: MEXICO

Frank D. Baleto, Customer Service Representative


[email protected]
Telephone: 408-964-4452
Direct E-Fax: 408-262-0659 Date: November 21, 2011
CERTIFICATE OF COMPLIANCE

QUALITY ASSURANCE INSPECTED

This certifies that on November 21, 2011, the Sierra Monitor Corporation Gas Detection
System(s) furnished under the referenced purchase order in compliance with all applicable requirements,
were manufactured and inspected at Sierra Monitor Corporation, 1991 Tarob Court, Milpitas,
California, U.S.A. I further certify that the supplies and/or services are of the quality specified
and conform in all respects with the contract requirements, including specifications, drawing,
preservation, packaging, origin, packing, marking, and physical item identification (part number)
requirements and are in the quantity shown on this or on the attached documents.

Customer: Solar Turbines, Inc.


13105 Northeast Freeway, Suite 400
Houston, TX 77040 USA

Ship to: Solar Turbines, Inc.


c/o HJH Forwarding
8620 San Gabriel
Laredo, TX 78405

Purchase Order No.: ECP005904


SMC No: 113442
Destination: MEXICO

Frank D. Baleto, Customer Service Representative


[email protected]
Telephone: 408-964-4452
Direct E-Fax: 408-262-0659 Date: November 21 2011
Sierra Monitor TAX ID No: _____95-2481914______

DATE: November 18, 2011

To: Solar Turbines


Reference: PURCHASE ORDER NO: ECP005904

To whom it may concern,

THE PRODUCTS LISTED BELOW HAVE NOT BEEN QUALIFIED OR


DO NOT QUALIFY FOR PREFERENTIAL TREATMENT UNDER THE
NORTH AMERICAN FREE TRADE AGREEMENT

PART/TAG NO. DESCRIPTION COUNTRY OF


ORIGIN
4400-10 H2S In-Stream Analyzer USA
5100-99-IT-AL-02 IT Gas Sensor Module USA

Certifiedastrueandcorrectinaccordancewithourrecords.

Frank D. Baleto, Customer Service Representative

[email protected]
Telephone: 408-964-4452, Direct E-Fax: 408-262-0659

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