Study Guide for

Thermodynamics: an Engineering Approach

By

Michael A. Boles
Department of Mechanical and Aerospace Engineering
NC State University
Raleigh, NC 2795-7910

Chapter 1-1
 Nomenclature
2
A area (m )
CP specific heat at constant pressure (kJ/(kgK))
CV specific heat at constant volume (kJ/(kgK))
COP coefficient of performance
d exact differential
E stored energy (kJ)
e stored energy per unit mass (kJ/kg)
F force (N)
g acceleration of gravity ( 9.807 m/s2)
H enthalpy (H= U + PV) (kJ)
h specific enthalpy (h= u + Pv) (kJ/kg)
h convective heat transfer coefficient (W/(m2K)
K Kelvin degrees
k specific heat ratio, CP/CV
k 103
kt thermal conductivity (W/(m-C))
M molecular weight or molar mass (kg/kmol)
M 106
m mass (kg)
N moles (kmol)
n polytropic exponent (isentropic process, ideal gas n = k)
isentropic efficiency for turbines, compressors, nozzles
th thermal efficiency (net work done/heat added)
P pressure (kPa, MPa, psia, psig)
Pa Pascal (N/m2)
Qnet net heat transfer (Qin - Qout) (kJ)
qnet Qnet /m, net heat transfer per unit mass (kJ/kg)
R particular gas constant (kJ/(kgK))
Ru universal gas constant (= 8.314 kJ/(kmolK) )
S entropy (kJ/K)
s specific entropy (kJ/(kgK))
T temperature ( C, K, F, R)
U internal energy (kJ)
u specific internal energy (kJ/(kg K))
V volume (m3 )
V!
" volume flow rate (m3/s)
V velocity (m/s)
v specific volume (m3/kg)

Chapter 1-2
v molar specific volume (m3/kmol)
X distance (m)
X exergy (kJ)
x quality
Z elevation (m)
Wnet net work done [(Wout - Win)other + Wb] (kJ)

wnet
z2
where Wb = 1 PdV for closed systems and 0 for control volumes
Wnet /m, net work done per unit mass (kJ/kg)
Wt weight (N)
inexact differential
regenerator effectiveness
relative humidity
density (kg/m3)
humidity ratio

Subscripts, superscripts

a actual
b boundary
f saturated liquid state
g saturated vapor state
fg saturated vapor value minus saturated liquid value
gen generation
H high temperature
HP heat pump
L low temperature
net net heat added to system or net work done by system
other work done by shaft and electrical means
P constant pressure
REF refrigerator
rev reversible
s isentropic or constant entropy or reversible, adiabatic
sat saturation value
v constant volume
1 initial state
2 finial state
i inlet state
e exit state
per unit time

Chapter 1-3
 REFERENCE

Cengel, Yunus A. and Michael A. Boles, Thermodynamics: An

Engineering Approach, 3rd ed., New York, McGraw-Hill: 1998.

Chapter 1-4
 Chapter 1: Basic Concepts of Thermodynamics

INTRODUCTION

The study of thermodynamics is concerned with the ways energy is

stored within a body and how energy transformations, which involve heat
and work, may take place. One of the most fundamental laws of nature is
the conservation of energy principle. It simply states that during an
energy interaction, energy can change from one form to another but the
total amount of energy remains constant. That is, energy cannot be
created or destroyed.

This review of thermodynamics is based on the macroscopic approach

where a large number of particles, called molecules, make up the
substance in question. The macroscopic approach to thermodynamics
does not require a knowledge of the behavior of individual particles and
is called classical thermodynamics. It provides a direct and easy way to
obtain the solution of engineering problems without being overly
cumbersome. A more elaborate approach, based on the average behavior
of large groups of individual particles, is called statistical
thermodynamics. This microscopic approach is rather involved and is
not reviewed here and leads to the definition of the second law of
thermodynamics. We will approach the second law of thermodynamics
from the classical point of view and will learn that the second law of
thermodynamics asserts that energy has quality as well as quantity, and
actual processes occur in the direction of decreasing quality of energy.

Closed, Open, and Isolated Systems

A thermodynamic system, or simply system, is defined as a quantity of

matter or a region in space chosen for study. The region outside the
system is called the surroundings. The real or imaginary surface that
separates the system from its surroundings is called the boundary. The
boundary of a system may be fixed or movable.

Surroundings are physical space outside the system boundary.

Chapter 1-5
Systems may be considered to be closed or open, depending on whether
a fixed mass or a fixed volume in space is chosen for study.

A closed system consists of a fixed amount of mass and no mass may

cross the system boundary. The closed system boundary may move.

Examples of closed systems are sealed tanks and piston cylinder devices
(note the volume does not have to be fixed). However, energy in the
form of heat and work may cross the boundaries of a closed system.

Chapter 1-6
An open system, or control volume, has mass as well as energy crossing
the boundary, called a control surface. Examples of open systems are
pumps, compressors, turbines, valves, and heat exchangers.

An isolated system is a general system of fixed mass where no heat or

work may cross the boundaries. An isolated system is a closed system
with no energy crossing the boundaries and is normally a collection of a
main system and its surroundings that are exchanging mass and energy
among themselves and no other system.

Isolated System Boundary

Heat = 0 Work
Work = 0 Surr 4
Mass = 0
Mass
Across System
Isolated Surr 3
Boundary Surr 1 Mass
Heat
Surr 2

Chapter 1-7
Since some of the thermodynamic relations that are applicable to closed
and open systems are different, it is extremely important that we
recognize the type of system we have before we start analyzing it.

Energy
"
Consider the system shown below moving with a velocity V at an
elevation Z relative to the reference plane.

CM "
General V
System

Reference Plane, Z=0

The total energy E of a system is the sum of all forms of energy that can
exist within the system such as thermal, mechanical, kinetic, potential,
electric, magnetic, chemical, and nuclear. The total energy of the system
is normally thought of as the sum of the internal energy, kinetic energy,
and potential energy. The internal energy U is that energy associated
with the molecular structure of a system and the degree of the molecular
activity (see Section 1-4 of text). The kinetic energy KE exists as a result
of the system's motion relative" to an external reference frame. When the
system moves with velocity V the kinetic energy is expressed as
"2
V
KE = m ( kJ )
2
The energy that a system possesses as a result of its elevation in a
gravitational field relative to the external reference frame is called
potential energy PE and is expressed as

PE = mgZ ( kJ )

Chapter 1-8
where g is the gravitational acceleration and z is the elevation of the
center of gravity of a system relative to the reference frame. The total
energy of the system is expressed as

E = U + KE + PE ( kJ )
or, on a unit mass basis,

E U KE PE kJ
e= = + + ( )
m m m m kg
"2
V
=u+ + gZ
2
where e = E/m is the specific stored energy, and u = U/m is the specific
internal energy. The change in stored energy of a system is given by

E = U + KE + PE ( kJ )
Most closed systems remain stationary during a process and, thus,
experience no change in their kinetic and potential energies. The change
in the stored energy is identical to the change in internal energy for
stationary systems.

If KE = PE = 0,

E = U ( kJ )

Property

Chapter 1-9
Any characteristic of a system in equilibrium is called a property. The
property is independent of the path used to arrive at the system
condition.

Some thermodynamic properties are pressure P, temperature T, volume

V, and mass m.

Properties may be intensive or extensive.

Extensive properties are those that vary directly with size--or extent--of
the system.

Some Extensive Properties

a. mass
b. volume
c. total energy
d. mass dependent property

Intensive properties are those that are independent of size.

Some Intensive Properties

a. temperature
b. pressure
c. age
d. color
e. any mass independent property

Extensive properties per unit mass are intensive properties. For example,
the specific volume v, defined as

Chapter 1-10
 v=
Volume V
=
FG m IJ
3

mass m H kg K
and density , defined as

=
mass m FG kg IJ
=
volume V Hm K3

are intensive properties.

Units

An important component to the solution of any engineering

thermodynamic problem requires the proper use of units. The unit check
is the simplest of all engineering checks that can be made for a given
solution. Since units present a major hindrance to the correct solution of
thermodynamic problems, we must learn to use units carefully and
properly. The system of units selected for this course is the SI System,
also known as the International System (sometimes called the metric
system). In SI, the units of mass, length, and time are the kilogram (kg),
meter (m), and second (s), respectively. We consider force to be a
derived unit from Newton's second law, i.e.,

Force = ( mass)(acceleration)
F = ma

In SI, the force unit is the newton (N), and it is defined as the force
required to accelerate a mass of 1 kg at a rate of 1 m/s2. That is,

Chapter 1-11
 m
1N = (1kg )(1 2
)
s
The term weight is often misused to express mass. Unlike mass, weight
Wt is a force. Weight is the gravitational force applied to a body, and its
magnitude is determined from Newton's second law.

Wt = mg
where m is the mass of the body and g is the local gravitational
acceleration (g is 9.807 m/s2 at sea level and 45 latitude). The weight of
a unit volume of a substance is called the specific weight w and is
determined from w = g, where is density.

Oftentimes, the engineer must work in other systems of units.

Comparison of the United States Customary System (USCS), or English
System, and the slug system of units with the SI system is shown below.

SI USCS Slug
mass kilogram (kg) pound-mass (lbm) slug-mass (slug)
time second (s) second (s) second (s)
length meter (m) foot (ft) foot (ft)
force newton (N) pound-force (lbf) pound-force (lbf)

Sometimes we use the mole number in place of the mass. In SI units the
mole number is in kilogram-moles, or kmol.

Newtons second law is often written as

ma
F =
gc

Chapter 1-12
where gc is called the gravitational constant and is obtained from the
force definition. In the SI System 1 newton is that force required to
accelerate 1 kg mass 1 m/s2. The gravitational constant in the SI System
is

m
(1kg)(1 2 )
ma s kg m
gc = = =1
F 1N N s2

In the USCS 1 pound-force is that force required to accelerate 1 pound-

mass 32.176 ft/s2. The gravitational constant in the USCS is
ft
ma (1lbm)(32.2 )
gc = = s = 32.2 lbm ft
2

F 1lbf lbf s2
In the slug system, the gravitational constant is
ft
(1slug)(1 2 )
ma s lbm ft
gc = = =1
F 1 lbf lbf s2

Example 1-1

An object at sea level has a mass of 400 kg.

a) Find the weight of this object on earth.
b) Find the weight of this object on the moon where the local
gravitational acceleration is one-sixth that of earth.

Chapter 1-13
(a)

Wt = mg
F I
F mIG 1 N J
W = (400 kg )G 9.807 J G
t
H s K G kg m JJ 2

H sK 2

= 3922.8 N
(b)

Wt = mg
F I
F
= (400 kg )G
9.807 m I G 1 N J
H 6 s JK GG kg m JJ
2

H sK 2

= 6538
. N

Example 1-2E

Chapter 1-14
An object has a mass of 180 lbm. Find the weight of this object at a
location where the local gravitational acceleration is 30 ft/s2.

Wt = mg
ft 1 lbf
= (180 lbm)(30 2 )( )
s 32.2 lbm ft
s2
= 167.7 lbf

State, Equilibrium, Process, and Properties

State

Consider a system that is not undergoing any change. The properties can
be measured or calculated throughout the entire system. This gives us a
set of properties that completely describe the condition or state of the
system. At a given state all of the properties are known; changing one
property changes the state.

Equilibrium

A system is said to be in thermodynamic equilibrium if it maintains

thermal (uniform temperature), mechanical (uniform pressure), phase (the
mass of two phases, e.g., ice and liquid water, in equilibrium) and
chemical equilibrium.

Chapter 1-15
Process

Any change from one state to another is called a process. During a

quasi-equilibrium or quasi-static process the system remains practically
in equilibrium at all times. We study quasi-equilibrium processes
because they are easy to analyze (equations of state apply) and work-
producing devices deliver the most work when they operate on the quasi-
equilibrium process.

Chapter 1-16
In some processes one thermodynamic property is held constant. Some
of these processes are

Process Property held constant

isobaric pressure
isothermal temperature System
isochoric volume Boundary
isentropic entropy (see Chapter 6) F
Water

Constant Pressure Process

We can understand the concept of a constant pressure process by

considering the above figure. The force exerted by the water on the face
of the piston has to equal the force due to the combined weight of the
piston and the bricks. If the combined weight of the piston and bricks is
constant, then F is constant and the pressure is constant even when the
water is heated.

We often show the process on a P-V diagram as shown below.

Chapter 1-17
State Postulate

As noted earlier, the state of a system is described by its properties. But

by experience not all properties must be known before the state is
specified. Once a sufficient number of properties are known, the state is
specified and all other properties are known. The number of properties
required to fix the state of a simple, homogeneous system is given by the
state postulate:

The thermodynamic state of a simple compressible

system is completely specified by two independent,
intensive properties.

Chapter 1-18
Cycle

A process (or a series of connected processes) with identical end states is

called a cycle. Below is a cycle composed of two processes, A and B.
Along process A, the pressure and volume change from state 1 to state 2.
Then to complete the cycle, the pressure and volume change from state 2
back to the initial state 1 along process B. Keep in mind that all other
thermodynamic properties must also change so that the pressure is a
function of volume as described by these two processes.

2 Process
P
B

Process 1
A

V
Pressure

Force per unit area is called pressure, and its unit is the pascal, N/m2, in
the SI system and psia, lbf/in2 absolute, in the English system.

Force F
P= =
Area A

N
1 kPa = 103
m2
N
1 MPa = 106 2 = 103 kPa
m
The pressure used in all calculations of state is the absolute pressure
measured relative to absolute zero pressure. However, pressures are
often measured relative to atmospheric pressure, called gage or
vacuum pressures. In the English system the absolute pressure and gage
pressures are distinguished by their units, psia (pounds force per square
inch absolute) and psig (pounds force per square inch gage), respectively;

Chapter 1-19
however, the SI system makes no distinction between absolute and gage
pressures.

These pressures are related by

Pgage = Pabs Patm

Pvac = Patm Pabs
Or these last two results may be written as

Pabs = Patm Pgage

Where the +Pgage is used when Pabs > Patm and Pgage is used for a vacuum
gage.

The relation among atmospheric, gage, and vacuum pressures is shown

below.

Chapter 1-20
Small to moderate pressure differences are measured by a manometer
and a differential fluid column of height h corresponds to a pressure
difference between the system and the surroundings of the manometer.

This pressure difference is determined from the manometer fluid

displaced height as

P = g h ( kPa )

Other devices for measuring pressure differences are shown below.

Chapter 1-21
Example 1-3

A vacuum gage connected to a tank reads 30 kPa at a location where the

atmospheric pressure is 98 kPa. What is the absolute pressure in the
tank?

Pabs = Patm Pgage

= 98 kPa 30 kPa
= 68 kPa

Chapter 1-22
Example 1-4

A pressure gage connected to a valve stem of a truck tire reads 240 kPa at
a location where the atmospheric pressure is 100 kPa. What is the
absolute pressure in the tire, in kPa and in psia?

Pabs = Patm + Pgage

= 100 kPa + 240 kPa
= 340 kPa
The pressure in psia is
14.7 psia
Pabs = 340 kPa = 49.3 psia
1013
. kPa

What is the gage pressure of the air in the tire, in psig?

Pgage = Pabs Patm

= 49.3 psia 14.7 psia
= 34.6 psig
Check the tire side walls on your car or truck. What is the maximum
allowed pressure? Is this pressure in gage or absolute values?

Chapter 1-23
Example 1-5

Both a gage and a manometer are attached to a gas tank to measure its
pressure. If the pressure gage reads 80 kPa, determine the distance
between the two fluid levels of the manometer if the fluid is mercury,
whose density is 13,600 kg/m3.

P
h=
g
103 N / m2
80 kPa kPa
h=
kg m 1N
13600 3 9.807 2
m s kg m / s 2
= 0.6 m

Temperature

Although we are familiar with temperature as a measure of hotness or

coldness, it is not easy to give an exact definition of it. However,
temperature is considered as a thermodynamic property that is the
measure of the energy content of a mass. When heat energy is
transferred to a body, the body's energy content increases and so does its
temperature. In fact it is the difference in temperature that causes energy,
called heat transfer, to flow from a hot body to a cold body. Two bodies
are in thermal equilibrium when they have reached the same temperature.
If two bodies are in thermal equilibrium with a third body, they are also
in thermal equilibrium with each other. This simple fact is known as the
zeroth law of thermodynamics.

The temperature scales used in the SI and the English systems today are
the Celsius scale and Fahrenheit scale, respectively. These two scales are
based on a specified number of degrees between the freezing point of

Chapter 1-24
water ( 0C or 32F) and the boiling point of water (100C or 212F) and
are related by

9
T F = T C + 32
5

Example 1-6

Water boils at 212 F at one atmosphere pressure. At what temperature

does water boil in C.

5 5 C
T = (T F 32) = (212 32) F = 100 C
9 9 F

Like pressure, the temperature used in thermodynamic calculations must

be in absolute units. The absolute scale in the SI system is the Kelvin
scale, which is related to the Celsius scale by

T K = T C + 273.15

In the English system, the absolute temperature scale is the Rankine

scale, which is related to the Fahrenheit scale by

T R = T F + 459.69
Also, note that

T R = 1.8 T K

Chapter 1-25
The magnitudes of each division of 1 K and 1C are identical, and so are
the magnitudes of each division of 1 R and 1F. That is,

T K = (T2 C + 273.15) - (T1 C + 273.15)

= T2 C - T1 C = T C
T R = T F

Chapter 1-26