Competence in pH measurement

Sensors, assemblies and transmitters

for all applications
Solutions for liquid analysis
Over 30 years' experience in analysis of years has further improved the
measuring technology makes the globally performance and high quality of the
present Endress+Hauser Group a strong products and the company has been able
partner. Endress+Hauser pH measuring to offer new technologies to the user.
systems can be found everywhere where Consequently, not only was the non-
the customer requires reliable measured glass pH sensor made available to process
values, a high degree of availability and measurement but the fully automated
long operating times. With the production measuring point with a very good cost/
of 250,000 process electrodes per year, performance ratio was also launched on product quality for the customer as well
the company has achieved the top the market. By mastering all the technically as rapid turnaround times and outstanding
position in the world market. The quality difficult production stages in conjunction delivery reliability with regard to all
of the electrodes and solutions is among with a high degree of automation in almost standard products or individual products
the highest customers can actually use. all production areas, Endress+Hauser has tailor-made for special applications.
Ongoing expansion of its research and achieved a very good range of manufacture. Solutions are offered for almost every
development capacity in the past number This results in very high and consistent relevant branch.

Research and development pay

With the new Ceragel and Tophit sensors, of the processes. At Endress+Hauser, This ensures a safe connection to IP 68
Endress+Hauser is presenting sensor types there are just two membrane glasses which is TV certified up to 16 bar at
whose capabilities can hardly be beaten. to cover all applications. The objective three-fold safety.
The CPS71 sensor is the only sensor on behind the new development was to
the market with an innovative double improve upon the sensor operating times Thus, in all areas of the economy,
chamber and double gel reference system of conventional pH/redox sensors and the dependable pH sensors from
with a classic design, i.e. 120 mm length thus reduce operating costs for the user. Endress+Hauser help to protect man and
and 12 mm shaft glass diameter. New By making ISFET technology available the environment and guarantee the quality
gel compositions ensure a high level of in the CPS441/471/491 sensor family of high-quality products.
protection against contamination and for on-line pH measurement, new fields
a wide measuring range of 0 to 14 pH. of application have been opened in the
Longer operating times are automatically areas of biotechnology, the pharmaceutical
guaranteed here. Progress could also be industry, the food industry and
made in glass research. The new B glass environmental technology. All sensors from
introduced a membrane glass to meet Endress+Hauser are approved to ATEX/FM
the present-day and future demands and equipped with TOP 68 or Memosens.

2
Modular measuring point concept
The ambitious implementation of the With the retractable assemblies, the The configuration is then transferred to the
modular measuring point concept in customer is always integrating a sensor transmitter locally by means of an easy-to-
all assemblies of a pH measuring point with the standard length of 120 mm into use data block and measurement can start.
allows the customer to instrument from the application. All sensor types fit into This makes any adjustment for complex
a high-quality low-cost version right the same assemblies. As a result, it is easy processes absolute child's play.
up to a complete high-tech application to convert to another sensor type even in It goes without saying that downloadable
all from the one shop. If developing difficult applications. software as well as HART and PROFIBUS
a manual measuring point right up to a are available for all transmitter families and
fully automatic pH solution, the user finds The modularity element continues in the offer the highest possible degree of variation
the ideal solution for every requirement. transmitter concept. Here too, models for differing applications.
Well planned and thought-out modular range from the new powerful Liquiline in
concepts give the customer the opportunity two-wire technology to the pH transmitter
of introducing the optimum sensor into "Liquisys" (most sales worldwide) right
the process. There is a great range of up to the top-class device "Mycom". Each
assemblies to choose from with so many device line is characterised by its simple
different process connections for all possible and uniform operation. The unique Parawin
installation positions and various materials software tool for the Mycom transmitter
from PVC to stainless steel right up to allows users to configure the entire pH
Hastelloy. measurement off line at their own PC.

Service means more than just maintenance

Perfectly functioning measurement requires on site. Together with the customer, the
thorough planning. The right choice of applications are observed in detail and
sensor leads to an optimum operating the various measuring point modules
time of the pH sensor. Today, engineers at are recommended. The media in which
Endress+Hauser assist the customer from measurement takes place, the pressure
planning the pH measuring point right and the temperature are important factors
up to commissioning and maintenance for the correct specification of the pH
measurement. All moving parts of the
retractable assemblies must be serviced
regularly to ensure the high degree of
availability of the system. If the customer
so desires, maintenance concepts and
training programmes are worked out for the
operating staff. Endress+Hauser accepts the
entire responsibility for the pH measuring
point.

3
pH measurement in the chemical industry

pH measurement is one of the most used to trigger alarms, protect material

important online analysis methods in and the environment against damage and to
the chemical industry. The monitoring, guarantee a high degree of product quality.
accuracy and maintenance of the pH value Large demands are made on electrodes in
in the production plants is a guarantee modern industrial processes. By selecting
for optimised product yields. As a result, the right electrode and with the long
the pH value is also especially suited as a operating times of Endress+Hauser sensors,
measured variable to control and regulate the user can easily reduce the operating
chemical processes. As a limit variable it is costs of a plant.

Assemblies
Optimum installation solutions with Flow assemblies Unifit CPA442 installation assemblies
retractable assembly technology or Flowfit CPA240 Simple permanent installation
permanent installations Bypass measurement Integrated protection guard protects
The pH sensors can be optimally Installation of up to three electrodes against electrode breakage
integrated into the processes with the aid Spray cleaning possible Low-cost pipe and boiler mounting
of Endress+Hauser assembly technology. Cost-effective and high degree of sensor
Almost any process connection can be availability Retractable assemblies for high
made. Many special materials are available demands Cleanfit CPA450/471
on request. Dipfit CPA140 immersion assemblies Highest degree of safety for man and
Installation in open basins and high process thanks to ball valve or patented
containers O-ring sealing concept as process seal
Sensor holder with bayonet lock prevents Simple and easy to operate
the cable from twisting High degree of sensor availability
during installation Sensor change and check during the
Use in enamelled or rubberised running process
containers Integrated rinse chamber allows
Wide range of materials allows diverse contamination-free work and cleans the
use sensor optimally
Installation of up to three electrodes Large choice of special materials and
Dipfit CPA140
possible sealing concepts
Integrated scraper ring possible
All assemblies can be easily converted
from gel-filled to liquid-filled sensors

Cleanfit CPA471

Cleanfit CPA450

Cleanfit CPA475

Flowfit CPA240

Unifit CPA442

4
Transmitters Mycom S CPM153

Mycom S CPM153 transmitter Liquiline M CM42 transmitter

Monitoring functions for electrode slope, Two-wire transmitter with large, high-
zero point, membrane glass impedance contrast display and red alarm LED
and diaphragm resistance Plastic housing with handy keys, IP 67
Newly developed process check system Flexible module concept, fast
Logbook functions for calibrations, pH replacement or extension even in
value, alarms and operating commands hazardous applications
Optimum diagnosis module Menu navigation and configuration via
Two independent measuring channels for navigator, intuitive operation thanks to
redundancy and differential measurement plain text messages and online help
Configuration with software module Second current output
Parawin at PC workplace. Monitoring function for electrode
Can be easily expanded to fully automatic slope, zero point, sensor check system
measuring point for impedance of glass membrane and
NAMUR contacts diaphragm
Optimised alarm and controller functions FOUNDATION FIELBUS, PROFIBUS and
Two freely configurable current outputs HART fieldbus protocols
The fully automatic system solutions with
Topcal S are described on Page 10. Liquiline M CM42

Sensors
New sensor technologies Ceraliquid CPS41 Tophit sensors CPS441/CPS491
open up new applications Rapid response time and highest level of New applications are opened up with the
All relevant sensors from Endress+Hauser precision new non-glass ISFET sensors
are approved to ATEX/FM and equipped High degree of protection against (ion-sensitive fieldeffect transistor). The
with TOP 68 or Memosens. This ensures a contamination thanks to ISFET sensors in the Tophit line can
safe connection to IP 68; the plug-in heads liquid electrolyte refilling even be installed overhead. They are
are TV certified up to 16 bar. Can be used with external reference characterised by their extremely stable
Ideal for media with low PEEK shaft and can be used in media with
Orbisint CPS11 conductivity high organic solvent parts.
Dirt-repellent teflon ring diaphragm Electrolyte flow can be increased if there Low-maintenance
High chemical stability thanks to is a risk of diaphragm blockage Liquid electrolyte refilling
advanced gel developments (CPS441)
Reliable measurement results in event of Orbipore CPS91 High sensor stability leads to extended
extreme pH values (pH 0 14) Open aperture allows use in precipitation calibration intervals
Can be used with high pressures reactions, emulsions and suspensions Ideal for low medium conductivity
Rapid response time and high level of Rapid response time even at low
precision temperatures (up to -15 C)
Standard sensor for chemical element Open aperture allows use in precipitation
production reactions, emulsions and suspensions
Can be used with high pressures (CPS491)
Use is recommended in pigment Suitable for media with a low proportion
manufacturing and in the production of of water
colourants

Orbisint Ceraliquid Orbipore Tophit Tophit

CPS11D CPS41D CPS91D CPS441 CPS491

5
pH measurement in food/pharmaceuticals

Very high demands are made on product safety element, Endress+Hauser is which protects the reference system from
a measuring point in the food and the only supplier to equip its sensors with the electrode poisons. Typical processes
pharmaceutical industries with regard to biologically safe, completely acrylamide-free such as active agent synthesis, product
hygiene and cleanability. Endress+Hauser gel. Various safety measures (to prevent treatment and fermentation can be
offers a wide range of special pH sensors against contamination) are combined in a monitored more easily since the CPS471
for this purpose which are characterised sensor to achieve especially long electrode and CPS441 sensors can be installed in an
by optimum cleanability, a high number operating times in contaminated conditions overhead position. In the pharmaceutical
of CIP and SIP cycles and the possibility in particular (for example, in processes with and foodstuff industries, major demands are
of autoclaving. In addition, special pH amino acid compounds containing sulphur). made on the hygiene of the pH measuring
sensors have a certified biocompatibility to The CPS71 and CPS471 sensors are points. The EHEDG certified CPA442
ISO standard which guarantees that only equipped with a bridge electrolyte which assembly meets these demands and thus
biologically safe materials are in direct makes the way longer for toxic substances. guarantees the safety and quality of the
contact with the medium. As an additional They also have a double chamber reference products.

Assemblies
Cleanfit CPA475 Leak check of process seal Unifit CPA442 installation assembly
and CPA465 retractable assemblies 3A-approval with materials in conformity Permanent installation assembly
Automation especially of with the FDA with patented moulded seal for glass
hygienic processes possible Fully automatic calibration and cleaning electrodes and non-glass ISFET sensors
In-line steam sterilisability according to possible with Topcal S CPC300 EHEDG certified online cleanability
EHEDG test procedure Thermal decoupling of process Electropolished surface
connection from pneumatic drive with Available for all important process
Cleanfit CPA465 connections

Unifit CPA442 Electrolyte vessel

Cleanfit CPA475/465

Cleanfit CPA475/465

Cleanfit CPA475/465 Unifit CPA442

6
 Mycom S CPM153
Liquisys M CPM253

Liquiline M CM42

Liquisys M CPM223

Transmitters

Liquisys M CPM223/253 Mycom S CPM153 transmitter Liquiline M CM42 transmitter

transmitter The ideal supplement for standard glass Two-wire transmitter with large, high-
Simple to operate: clear menu structure electrodes and ISFET pH sensors with contrast display and red alarm LED
with plain language in 6 languages makes clear text operation Stainless steel housing with membrane
configuration easier High safety and certainty of keypad, hygienic design, IP 67
Large two-line display allows measurement thanks to integrated Flexible module concept, fast
simultaneous display of measured value monitoring functions replacement or extension even in
and temperature Logbook functions of operation, hazardous applications
Ultra simple two-point calibration via the calibration and error messages Menu navigation and configuration via
CAL key Documentation of complete measuring navigator, intuitive operation thanks to
Sensor check system for pH glass point possible with optional off-line plain text messages and online help
Live check of the sensor Parawin tool Second current output
Can be retrofitted to fully automatic Monitoring function for electrode
calibration and cleaning system slope, zero point, sensor check system
Topcal S CPC300 for impedance of glass membrane and
diaphragm
FOUNDATION FIELBUS, PROFIBUS and
HART fieldbus protocols

Sensors
Ceraliquid CPS41 Ceraliquid CPS71 Tophit CPS471
with electrolyte vessel CPY7 CIP/steam-sterilisable/autoclavable glass Non-glass and break-proof
pH combination electrode with KCl liquid sensor for sterile pH sensor (materials in contact with
electrolyte for special applications with pH measurement medium FDA listed);
high requirements, especially in the case Certified biocompatibility of all Wetted ports biocompatible
of rapidly changing media materials in contact with medium Horizontal mounting and
Sterilisable Especially low-maintenance thanks to overhead installation possible
double chamber reference with Sterilisable, autoclavable
Tophit CPS441 integrated bridge electrolyte cleanability according to EHEDG
Non-glass and break-proof Reference gel free from acrylamide and test procedure
pH sensor (material in contact with polyacrylamide Especially low-maintenance
medium FDA listed); Reference gel free from acrylamide and
Material in contact with medium polyacrylamide
biocompatible
Horizontal mounting and overhead
installation possible
Ceraliquid Tophit Ceragel Tophit
Sterilisable, autoclavable, CPS41D CPS441 CPS71D CPS471
cleanability according to EHEDG
test procedure

7
pH measurement in water/wastewater

The treatment of drinking water or

wastewater always involves monitoring
regulated processes. As a result, the
pH value is one of the most important
measured variables in all stages of the
process as both a value determining the
quality of the water and as a controlled
variable which has a direct effect on the
economic efficiency of the plant.

Assemblies
Cleanfit CPA473 retractable assembly Dipfit CYA611 immersion assembly Dipfit CPA111 immersion assembly
Automation even for difficult processes 3 possible ways of securing unit: Flexible adjustment of immersion depth
Various immersion depths Wall mounting, suspension bracket, thanks to adjustable flange; additionally
(tank/pipe installation) pendulum mounting with bayonet lock thus easy to install and
Sealing water to screen off the rinse Simple sensor mounting via G1 and detach the assembly.
chamber NPT 34" thread Simple installation and removal of
Optionally with scraper seal electrode holder using bayonet securing
Fully automatic calibration and cleaning Flowfit CPA250 flow assembly technology.
in conjunction with Topcal S CPC 300 Installation locations for maximum three Three electrode installation locations for
sensors Pg 13.5 (pH, redox, temperature, pH/redox and temperature sensor or
Cleanfit CPA450 retractable assembly cleaning) cleaning in a standard length of 120 mm.
Reliable separation of process with Easy access to the electrodes in the flow
stainless steel ball valve area thanks to screw-off sealing cap; as
Use of standard gel electrodes with or a result, calibration or cleaning can take
without integrated Pt 100 with length place without the need to remove the
120 mm sensor.
Variable immersion depth up to
700 mm
Integrated rinse and calibration
connections Chemoclean CPR31
spray cleaning system
The spray cleaning unit can be
retrofitted any time without the
need to convert the assembly.

Chemoclean CPR31
CYH101

Cleanfit CPA473

Dipfit CYA611

Dipfit CPA111
Cleanfit CPA450

Flowfit CPA250

8
Transmitters
Liquisys M CPM223/253
transmitter
Simple to operate: clear menu structure
with plain language in 6 languages makes
configuration easier
Large two-line display allows
simultaneous display of measured value
and temperature
Simple two-point calibration by means of
Cal key
Safe to operate: overvoltage protection
(high-voltage protector) to
EN 61000-4-5
Directly accessible manual control of
contacts
Calibration plausibility check
Customised alarm configuration for fault-
signalling contact and error current
Automatic start of cleaning following
alarm or limit value overshoot
Sensor check system for pH glass and
reference
Live sensor check
Special neutralisation regulator
Liquisys M CPM253 Liquisys M CPM223

Sensors
Orbipac CPF81
Orbisint CPS11 Orbipore CPS91
pH combination electrodes with
We recommend the Orbisint CPS11 sensor The open aperture allows the use of the
"integrated" assembly as simplest
with ring-shaped PTFE diaphragm and fixed electrode in media with a high solids
mechanical adaptation in pipelines
electrolyte for all standard applications. The content, in suspensions/emulsions as well
or immersion assemblies
CPS12 is the standard redox electrode with as in precipitation reactions where the
Double chamber reference with
the CPS11 reference system. diaphragm would otherwise block in a short
KNO3 electrolyte bridge
time.
Optionally available with flat membrane
and integrated potential matching
Ceraliquid CPS41
The Ceraliquid CPS41 sensor with refillable
liquid electrolyte is used in applications
where there is a high risk of the diaphragm
blocking or where a high level of accuracy
is required.

Orbisint Ceraliquid Orbipore Orbipac

CPS11D CPS41D CPS91D CPF81

9
System solutions for pH measuring technology

Fully automatic measuring, calibration, sterilisation

and cleaning with Endress+Hauser.
Continuous maintenance of the sensor especially in applications with high measuring system can be found for each
guarantees a high degree of accuracy requirements, such as in the chemical, process: from the simple application in
and the highest degree of availability of food and pharmaceutical industry or the area of wastewater to processes in
a pH measuring point. This comprises with measuring points with aggressive the chemical industry right up to very
both the cleaning and calibration of the process conditions. Endress+Hauser offers demanding applications with regard to
sensor as well as the monitoring of the automatic pH measuring points to reduce accuracy and measuring safety and certainty
entire measuring point. However, this the running costs and maintenance costs in the pharmaceutical industry.
leads to high operating and maintenance to a minimum. Thanks to the various
costs. This makes a significant difference degrees of automation, a suitable automatic

Topcal S Topclean S Chemoclean

The fully automated Topcal S system Topclean S, the alternative, in which Chemoclean used in conjunction with
for greater demands provides reliable automatic cleaning and manual a Liquisys M or Mycom S as the control
measurement results with a minimum calibration outside the process suffice. unit ensures optimum cleaning of the
amount of maintenance particularly in With Topclean S, you have the option of electrode directly in the process, as is
aggressive and highly contaminated media automatically rinsing and cleaning the mostly sufficient in the wastewater sector.
as often occur in chemical processes. With electrodes outside the process. With an By selecting a Mycom as the control unit,
Topcal S, you can clean and calibrate additional valve, sterilisation can also you also have the extensive options of
fully automatically outside the process. optionally take place. The programming, off-line configuration at the PC as well as
Maintenance work is reduced to changing safety functions and the data handling are the function of documenting the entire
the electrodes and buffer as well as the the same as for Topcal S. measuring point by means of the Parawin
cleaning solution. tool.

CYC300 cabinet for Topcal S

or Topclean S
Reliable protection of Topcal S or
Topclean S against environmental
conditions (dirt, water jets); also suitable
for use in the field under extreme
weathering conditions thanks to
integrated heater
Stainless steel or plastic version
meets requirements of both the food/
pharmaceutical sector and the chemical
industry
Maintenance friendly thanks to
retractable buffer box, a central unit for
all electrical connections, easy access to
wear parts
Operating panel for rapidly starting the
calibration and cleaning programmes
integrated in Topcal S simply at the press
of a button
Operating panel can be detached and
installed separately
Additional measured value recording
thanks to optional measured value
recorder (e.g. Memograph S)

10
Low-maintenance and cost-effective measurement
with Endress+Hauser.
Topcal S CPC300 Topclean S CPC30 Chemoclean

Fully automatic Fully automatic pH measuring

pH measuring pH measuring point with auto-
point with inte- point with inte- matic cleaning
grated control grated control system

Calibration Sterilisation Cleaning

Sterilisation Cleaning Rinsing
Cleaning Rinsin
Rinsing

pH transmitters

Mycom S CPM153
pH/redox transmitter
with controller and
limit functions for Ex and
non-Ex areas

Mycom S Liquisys M
CPM153 CPM223/253

pH assemblies

Retractable Cleanfit Cleanfit Immersion

assemblies CPA473 CPA475 assemblies
Cleanfit Process retrac- Sterilisable Dipfit CPA111
Compact pH assemblies table assembly retractable Dipfit CPA140
in various materials with ball valve assembly for
for all process connections shut-off the highest Flow
hygienic assemblies
requirements Flowfit CPA250
Flowfit CPA240

Spray cleaning
systems
Chemoclean CPR3
Chemoclean CPR30
Chemoclean CPR31

Zubehr

CPR40 CYR10 Toolkit

rinse block injector Parawin
For 1 or 2 Cleaning injector For off-line configuration
additional valves for Chemoclean of Topcal S/Topclean S
(sterilisation) system with at the PC
valves for motive
water and For Chemoclean in
cleaning agents conjunction with
Mycom S

11
pH sensors with Memosens technology

Measuring the pH value makes great Moisture in the connection can change moisture-sensitive, connection. The jump in
demands not only on the pH-sensitive the measured value and may even result technology to a new generation of sensors
glass but also on the transmission of the in measurement failure. The Memosens has additional advantages and eliminates
measured value from the sensor to the technology revolutionises the safety of data general limitations of the technology in
transmitter. Low currents and very high transfer by digitalising the measured value place to date.
sensor internal resistances require a high- in the sensor and transferring it to the
impedance connection to the transmitter. transmitter without a contacting, and thus

Memosens makes the pH electrode

a digital sensor with integrated data
storage
pH sensors with Memosens technology
save the current calibration data and
other information which can be used for
look-ahead maintenance, such as hours
of operation, maximum and minimum
pH values and maximum and minimum
temperature.
When the sensor is mounted, the
calibration data are automatically
transferred to the transmitter and used
to calculate the current pH value.

The result:
Measuring point maintenance is no
longer based on individual issues
identified but rather all relevant sensor
data are used.
The current application of the sensors
can be made to depend on the previous
history.

12
pH sensors with Memosens technology
are the first pH sensors to allow
calibration/adjustment away from the
measuring point in the measuring lab.

The result:
The availability of the measuring point is
dramatically increased by the quick and
easy replacement of precalibrated sensors.
Measuring point down-time is reduced to
the time between detecting and replacing
the sensor.
The calibration/adjustment itself
takes place under optimum external
conditions in the measuring lab.

Standard sensor Sensor with Memosens

Calibration on site Calibration in the measuring lab

sensor sensor
removal removal
sensor
installation

Calibration /
adjustment
Saving sensor data
QS documentation
Optimum
sensor lab conditions
installation

Measuring point maintenance Measurement

An unestablished connection between The first non-contact measured value EMC safety through galvanic
the sensor and transmitter is actively transmission from the pH sensor to the decoupling of medium from transmitter
displayed the first really definite transmitter Highly integrated electronics in the sensor
connection pH sensors with integrated Memosens convert the analog signal of the pH sensor
Digital measured value transmission technology transmit the measured value to digital information which is then
automatically results in an error message contactlessly from the plug-in head of the transferred via the cable coupling to the
if the signal flow is interrupted. And electrode to the cable coupling. transmitter contactlessly and free from
this regardless of whether the sensor or The result: interference potential. The result:
measuring cable is no longer working Principally free from corrosion of the No more need to ask about
properly. The result: connection "symmetrically high-resistance" or
The availability of the measuring point is A coupling system that can even be "unsymmetrical" or an impedance
dramatically increased and ensured connected under water converter.
Automatic sensor detection allows for Free from leaks and measured value
unproblematic sensor replacement distortion from moisture

Inductive signal transmission

Inductive energy transmission

13
pH glass electrodes

The method of pH measurement using glass This voltage is then measured relative to Internal buffer H+
electrodes is a potentiometric measurement a reference element. Nowadays, the most pH 7 H+
H+
method. Since glass is basically an modern pH glasses display high selectivity Cl-
H+
electric insulator, amplifiers for the pH (low cross-sensitivity to ions other than
measurement must have an extremely high H+) over a wide temperature range. H+
H+ +
input impedance. The measuring effect is A pH sensor achieves the outstanding H Cl-
based on a pH-sensitive glass membrane performance of the linear measurement of e +
ra n + H Cl-
H+ b
m H
whose surface reacts to the acid content a material component over a concentration e
sm
Glas H+ Medium
of the solution with a specific voltage. range of 14 (!) exponents. H +

Voltage occurrence with

pH measurement with glass electrodes

Glass electrodes Recommended General Diaphragm/ Version Special

area of application reference characteristics/
application features

Orbisint Standard applications Long-term monitoring, PTFE diaphragm, Ex, all shaft lengths with Very robust,
in process and the processes with little Double gel reference temperature sensor, Heavy-duty version / high
CPS11
environment change Memosens, pressure,
Advanced Gel integrated
Technology potential matching,
flat membrane,

Ceraliquid Special Rapidly changing Ceramic diaphragm, Ex, all shaft lengths with Greatest accuracy,
applications composition of media, Liquid lead temperature sensor Can be subject to pressure
CPS41
with high requirements highly clogging media, to prevent clogging,
with regard to low conductivities Gel-free,
accuracy, refillable
speed electrolyte,
3A

Ceragel Hygiene and Pharmaceuticals, Ceramic diaphragm, Ex, all shaft lengths with Overhead installation,
sterile applications biotechnology, Double chamber and temperature sensor, CIP/SIP and
CPS71
fermenters, double gel reference Memosens, autoclavable,
contaminating Advanced Gel with high
media, Technology accuracy,
overhead installation Free from acrylamide and
polyacrylamide,
3A,
biocompatible

Orbipore Process applications Media with high Open aperture, Ex, all shaft lengths with Rapid response,
contamination: Double gel reference temperature sensor, new, stabilised gel
CPS91
emulsions, Memosens, insensitive to contamination
suspensions, Advanced Gel
precipitation reactions Technology

14
Non-glass pH sensors
H+ Gate
Apart from using a glass membrane, the pH here. "Chemistry and electrical measure- H+
value can also be measured using an ion- ment are kept totally separate. As a result, H+
selective field-effect transistor (ISFET). It is, the sensor material does not change and
in effect, a simple transistor with a source the need for recalibration is by no means
and drain that are separated from the as frequent as with glass electrodes. Since Source Drain
gate by means of an isolator. As with the there is no source layer, ISFETs are also
glass membrane, hydrogen ions from the suitable for pH measurement in media with Semicon-
medium can accumulate on the gate. The a low proportion of water. Modern ISFET ductor
The current between the
resulting positive charge on the outer side materials are highly selective and follow element source and drain of the
of the gate is "mirrored" on the inner side the Nernst law in closer tolerance limits semiconductor element
where a negative charge occurs. This makes than glass. The sensor's extreme robustness depends on the charge at
the gate and thus directly
the semiconductor channel conductive. The comes from embedding the chip in a stable on the pH value.
"field effect" results from the extent of the and unbreakable PEEK body.
conductivity: the higher the pH value of the
liquid, the more H+ ions accumulate on the
gate and the more current can measurably
flow between the source and drain. In
contrast to the glass electrode, there is no
ion flow between the fluid and the sensor

Non-glass Recommended General Diaphragm/ Version Special

sensors area of application application reference characteristics/
features
Tophit Special applications Low temperatures, Ceramic diaphragm, Ex, all shaft lengths with Overhead installation, rapid
with high requirements Rapidly changing Liquid lead temperature sensor response at
CPS441
with regard to composition of media, low temperatures,
accuracy and speed, highly clogging media, lower amount of
non-glass low conductivities maintenance required than
break-proof with glass,
3A

Tophit Hygiene and sterile Low temperatures, Ceramic diaphragm, Ex, all shaft lengths with Overhead installation,
applications, pharmaceuticals, double chamber reference, temperature sensor, SIP, autoclavable,
CPS471
non-glass, biotechnology, double gel Advanced Gel rapid response, low
break-proof contaminating media Technology temperatures, lower
amount of maintenance
required than with glass,
free from acrylamide and
polyacrylamide,
3A,
biocompatible

Tophit Process applications, non- Low temperatures, Open aperture, Ex, all shaft lengths with Overhead installation, rapid
glass, emulsions, double gel reference temperature sensor, response at
CPS491
break-proof suspensions, Advanced Gel low temperatures,
organic solvents Technology stabilised gel
insensitive to contamination
lower amount of
maintenance required than
with glass

15
Overview of pH assemblies
Assemblies, whether used as immersion 100%-suitable solutions with regard to the
assemblies, flow assemblies or retractable design and material, to pressure resistance and
assemblies, are the most important comfort with the assemblies described and is
connecting element between the sensor thus the only manufacturer who can equip all
and the process. Endress+Hauser is offering measuring points safely and flexibly.

Immersion assemblies Flow assemblies Permanent installation assemblies

Dipfit Dipfit Dipfit Flowfit Flowfit Unifit

CYA611 CPA111 CPA140 CPA240 CPA250 CPA442
Application Water, wastewater Water, wastewater, Process Process Water Process, food,
process pharmaceuticals
Description Simple assembly 3 electrode installation 3 electrode installation 3 electrode installation 3 electrode installation 120 mm electrode
locations, 120 mm locations, 120 mm locations, locations, with and without
electrode, electrode, 120 mm electrode 120 mm electrode protection guard
bayonet technology bayonet technology

Area of use Open tank, Open tank, Closed tank Piping, Piping, Open and
open channel open channel bypass bypass closed tank,
closed tank piping

Process Suspended assembly Suspended assembly, Pressurised flange Pressurised flange Thread G 1 DN20, DN25 thread adapter
connection lap joint flange DN80/PN16, DN25/PN16, flange DN25 nut, TriClamp,
DN100, pressurised ANSI 3" lbs 150 ANSI 1" lbs 150 Varivent, APV,
flange DN100/PN4 JIS 10K80A JIS 10K25A dairy fitting DN50,
adjustable flange Neumo BioControl
DN100

Material PCV - U PP PVDF PVDF PP Stainless steel 1.4435

stainless steel 1.4404 stainless steel 1.4404 (AISI 316L)
(AISI 316L) (AISI 316L)
Max. pressure Unpressurised 4 bar 6 or 10 bar 8 or 10 bar 6 bar 10 bar
Max. temperature 60 C 80 C 120 or 150 C 120 or 150 C 80 C 140 C
Immersion depth 1430 mm 500 . . . 3000 mm 500 . . . 2500 mm 10 . . . 86 mm
(as of process special lengths special lengths
connection) on request on request
Sensor connection G1/NPT 3/4 3x Pg 13.5 3x Pg 13.5 3x Pg 13.5 3x Pg 13.5 Pg 13.5
thread
Certificates 3.1.B EN 10204 3.1.B EN 10204 3A, EHEDG ("in line
steam sterilisability +
cleanability")
3.1.B EN 10204
Associated cleaning External spray cleaning Integrated spray Integrated spray Spray cleaning Spray cleaning
systems cleaning CPR 31, cleaning CPR 31 connection G 1/2 connection with CPR 3
external spray cleaning
CPR 30

16
Retractable assemblies

Cleanfit Probfit Cleanfit Cleanfit Cleanfit Cleanfit Cleanfit

CPA450 CPA465 CPA471 CPA472 CPA473 CPA474 CPA475
Water, wastewater, Food, process, Water, wastewater, Water, wastewater, Water, wastewater, Water, wastewater, Food, process,
process pharmaceuticals process process process process pharmaceuticals
Manual, Manual or pneumatic, Manual or pneumatic, Manual or pneumatic, Manual or pneumatic, Manual or pneumatic, Manual or pneumatic,
120 mm electrode can be fully automated can be fully automated can be fully automated can be fully automated can be fully automated can be fully automated
with CPC30/300 with CPC30/300 with CPC30/300 with CPC30/300 with CPC30/300 with CPC30/300

Open and Open and Open and Open and Open and Open and Open and
closed tank, closed tank, closed tank, closed tank, closed tank, closed tank, closed tank,
piping piping piping piping piping piping piping
(min DN 80) (min DN 80) (min DN 80) (min DN 80) (min DN 80) (min DN 80)

Thread G 1 1/4, DN25 thread adapter DN25 thread adapter Thread G 1 1/4 Thread G 1 1/4, Flange DN50/PN16, DN 25 thread adapter
thread NPT 1 1/4", nut, TriClamp, nut, TriClamp, external, flange DN50/PN16, flange ANSI 2 / nut, TriClamp,
flange DN32 PN16, Varivent, APV, dairy Varivent, APV, thread NPT 1" flange 150 lbs Varivent, APV, dairy
flange ANSI 1 1/4" fitting DN50, flange dairy fitting DN50 external, ANSI 2" / 150 lbs fitting DN50, flange
DN50/PN10, flange flange DN50/PN10, flange
ANSI 2 / 150 lbs DN50 / ANSI 2", ANSI 2 / 150 lbs
dairy fitting DN50

Stainless steel 1.4404 Stainless steel 1.4435 Stainless steel 1.4404 PP, PVDF, PEEK Stainless steel 1.4404 PP, PVDF, PEEK Stainless steel 1.4435
(AISI 316L) (AISI 316L) (AISI 316L) (AISI 316L) (AISI 316L)
Hastelloy C4, titanium
4 (overpressure 20)bar 10 bar 4/6 or 10 bar 4/6 bar 4/6 or 10 bar 4/6 or 10 bar 4/6 or 10 bar
130 C 140 C 80 or 140 C 60 or 80 C 80 or 140 C 80 or 130 C 80 or 140 C
Up to 700 mm 47 . . . 120 mm 66 . . . 208 mm 66 . . . 215 mm 61 . . . 235 mm 71 . . . 207 mm 48 . . . 102 mm

Pg 13.5 Pg 13.5 Pg 13.5 Pg 13.5 Pg 13.5 Pg 13.5 Pg 13.5

3.1.B EN 10204 3A, "in line steam 3.1.B EN 10204 3.1.B EN 10204 3A, "in line steam
sterilisability" acc. to sterilisability" acc. to
EHEDG test procedure EHEDG test procedure
3.1.B EN 10204 3.1.B EN 10204
Rinse chamber Integrated rinse Integrated rinse Integrated rinse Integrated rinse Integrated rinse Integrated rinse
connection G 1/4 chamber (Z-shape) chamber with chamber with chamber with chamber with chamber (Z-shape)
with connection connection connection connection connection with connection
G 1/4 and G 1/2" G 1/4 or NPT 1/4" G 1/4 or NPT 1/4" G 1/4 or NPT 1/4" G 1/4 or NPT 1/4" G 1/4 or NPT 1/4"

17
Electrodes Technical data

Quality and performance in the area of reliable quality, certainty and safety. At its
sensor technology are the deciding factors. locations in Waldheim (Saxony, Germany)
In no other component of a measuring and Los Angeles (USA), Endress+Hauser
point is so much development competence has the most modern pH electrode
and time invested than here. The range of production worldwide. Computer-aided
manufacture, modularity with regard to inspection units monitor the technical
the design technology and a high degree of production quality during the production.
automation guarantee the user absolutely

Orbisint Orbisint Ceragel Tophit Ceragel

CPS11/CPS11D CPS12/CPS12D CPS71/CPS71D CPS471 CPS72/CPS72D
Material Glass Glass Glass PEEK, EPDM Glass
Parameter pH ORP/redox pH pH ORP/redox
Meas. range 0-14 -1500 bis 1500 mV 0-14 0-14 -1500 bis 1500 mV
Temperature 0-135 (-5-80) C -15-135 C 0-135 (-15-80) C -15-135 C -15-135 C
Temperature Pt100, Pt1000 / integrated Pt100, Pt1000 / integrated Pt1000
sensor
Minimum 50 S/cm 50 S/cm 10 S/cm 10 S/cm 10 S/cm
conductivity
Pressure up to 6 bar/16 bar 6 bar 13 bar 10 bar 13 bar
Diaphragm PTFE PTFE Ceramic Ceramic Ceramic
Reference Gel Gel Gel Gel Gel
Lengths [mm] 120/225/360/425 120/225/360/425 120/225/360/425 120/225/360/425 120/225/360/425
Cable CPK9 / CYK10 CPK9 / CPK10 CPK9 / CPK10 CPK12 CPK9 / CPK10
Certifikates ATEX, FM ATEX, FM ATEX, FM, 3A, ATEX, FM, ATEX, FM
biocompatible 3A, biocompatible

18
 CPS11 CPS71 CPS91 Tophit CPF81

The wide range of applications does not Sensors with teflon diaphragm and gel Sensors with open aperture with gel
necessarily mean that there must be a reference reference as well as
wide range of different sensor types. Sensors with ceramic diaphragm and gel Sensors with ceramic diaphragm and
Endress+Hauser offers the following reference liquid reference
four basic types which cover the entire
application range:

Ceraliquid Tophit Ceraliquid Orbipore Tophit

CPS41/CPS41D CPS441 CPS42/CPS42D CPS91/CPS91D CPS491
Glass PEEK, EPDM Glass Glass PEEK, perfluorelastomer
pH pH ORP/redox pH pH
0-14 0-14 -1500 bis 1500 mV 0-14 0-14
0-130 (-15-80) C -15-135 C -15-130 C 0-110 C -15-110 C
Pt100 Pt1000 Pt100, Pt1000 Pt1000

0,1 S/cm 0,1 S/cm 0,1 S/cm 500 S/cm 500 S/cm

8 bar 10 bar 8 bar 13 bar 10 bar

Ceramic Ceramic Ceramic open open
liquid liquid liquid solid gel solid gel
120/225/360/425 120/225/360/425 120/225/360/425 120/225/360/425 120/225/360/425
CPK9 / CPK10 CPK12 CPK9 / CPK10 CPK9 / CPK10 CPK12
ATEX, FM, 3A ATEX, FM, 3A ATEX, FM ATEX, FM ATEX, FM

19
DIN Koax-Kupplung (GSA) TOP68-Kupplung (ESA) Memosens-Kupplung

To ensure the safe transmission of measured A distinction is made between simple cables With Memosens technology, the sensor
values for contacting plug-in systems, where only the pH value is transmitted data are digitalised directly in the sensor
double-screened measuring cables are right up to multi-pin cables which also and transmitted with a standard bus cable
required to prevent against electromagnetic allow temperature measured value of low impedance (CYK10).
interfering impulses. transmission (TOP68).

Orbipac Orbipac Purisys

CPF81 CPF82 CPF201
PPS / Glass PPS / Glass SS316 L / Glass Material
pH ORP/redox pH Parameter
0-11 (0-14) -1500 bis 1500 mV 0-14 Measuring range
0-80 (0-110) C 0-110 C 0-75 C Temperature
Pt100 Pt100 Pt100, Pt1000 Temperature
sensor
50 S/cm 50 S/cm 0,05 - 100 S/cm Minimum
conductivity
3,5 bar (110 C) 3,5 bar (110 C) 3,5 bar Pressure up to
PTFE PTFE PTFE Diaphragm
Gel Gel Gel Reference
12,5/23/58,5 12,5/23/58,5 Lengths [mm]
fixed cable / CPK9 fixed cable / CPK9 CPK9 Cable
Certificates

20
Applications for pH sensors

CPS11 CPS41 CPS71 CPS91 CPF81 CPF201 CPS441 CPS471 CPS491

Chemical industry
Chemical production monitoring
Chrome detoxification
Colourants
Metal finishing and mining
Petrochemicals
Refineries
Power plants
Boiler feedwater
Paper industry
Non-aqueous media
Resin production
Starch
Gelatine
Pharmaceutical industry
Biotechnology
Blood plasma fractioning
Fermenters
Pharmaceutical-chemical production
Food and beverages
Beverages
Brewing water
Cheese production
Dairy, milk and yoghurt processing
Drinking water
Fish farming
Sauces/ketchup
Yeast propagation
Marmalade
Puree
Drinks bottling
Sugar
Water treatment
Gas scrubbers
Boiler feedwater
Cooling water
Ultrapure water (semiconductor)
Neutralisation
Drinking water
Municipal wastewater
Industrial wastewater
Wastewater treatment
Tannery
Detoxification
Flue gas cleaning
Wastewater, galvanic
Heavy metal precipitation
Sludge draining
Ground sanitation

21
Additional documentation
Technical information

Transmitter

TI 194C Liquisys M CPM223/253

TI 233C Mycom S CPM153
TI 381C Liquiline M CM42

Assemblies

TI 112C Dipfit W CPA111

TI 179C Flowfit P CPA240
TI 041C Flowfit W CPA250
TI 306C Unifit H CPA442
TI 183C Cleanfit W CPA450
TI 146C Probfit H CPA465
TI 217C Cleanfit P CPA471
TI 223C Cleanfit P CPA472
TI 344C Cleanfit P CPA473
TI 345C Cleanfit P CPA474
TI 240C Cleanfit H CPA475
TI 166C Dipfit W CYA611

Sensors

TI 028C Orbisint CPS11

TI 079C Ceraliquid CPS41
TI 245C Ceragel CPS71
TI 191C Orbipac CPF81
TI 375C Orbipore CPS91
TI 266C Purisys CPF201
TI 352C Tophit CPS441
TI 282C Tophit CPS471
TI 377C Tophit CPS491

Cleaning and calibration systems

TI 235C Topclean S CPC30

TI 236C Topcal S CPC300
TI 046C Chemoclean CYR10
BA 201C Chemoclean CPR31
TI 342C Chemoclean CPR40

Further information is available under: www.analysis.endress.com

03.05/MSC
Instruments International

Endress+Hauser GmbH+Co. KG
Instruments International
P.O. Box 2222
79574 Weil am Rhein
Germany
Tel. +49 7621 975 02
Fax +49 7621 975 345
http://www.endress.com
[email protected]

FA 007C/07/en/03.05
51515969
DT/INDD 2.0