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EAMCET BITS

CHEMISTRY

t
e

1. Molecular rearrangement reaction occurs in

n
.
a

---J u E ---
1) Phenyl benzoate
j -
2) Ammonium Cyanate t-E -

h
b
i

3) 1 amide with Br2 & KOH

Br2 & KOH 1 i

4) All the above

t
a
r

jFo

2. Prussian blue complex formed in Lassaigne's test contains

p
u
d

j K-~ p- v- F Px-d C/-N

1) Fe+2

a
n

3) both 1 & 2

2) Fe+3
4) Fe+1

e
e
.
w
w

3. Acidic dehydration of alcohols is

x E-bM-- u C

t
e
n

1) - elimination
- N-
2) - elimination
- N-
3) - elimination
- N-
4) Not at all elimination reaction

.
a
h

b
i
t

N- u

4. Markonikov's & Antimarkonikov's additions involve respectively

\E & uA- \E --- - N oN
1) 2 carbocation & 2 free radical
2 s-- & 2 ya vA--C
2) 2 free radical & 2 carbocation
2 ya vA--C & 2 s--
3) 2 carbocation in both
-- 2 s-
4) 2 free radical in both
-- 2 ya vA--C
5. The compounds formed when C6H6 is treated with i) Cl2 & Anhyd. AlCl3
ii) excess of Cl2, Anhyd. AlCl3, dark, cold iii) with Cl2 in sunlight respectively
are

a
r
p

u
d
a

n
e
e
.
ww

C6H6 i) Cl2 & -vl AlCl3 ii) C Cl2, -vl AlCl3, <,
R-13-04-14

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xE

iii) Cl2 u-

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A -~ a -n -
1) C6H4Cl2, C6Cl6, C6H6Cl6

2) C6H5Cl, C6Cl6, C6H6Cl6

3) C6Cl6, C6H5Cl, C6H6Cl6

Cu, 523 K
A
100 atm

6. CH4
B
MO2 O3

n
.
a

h
b
i

where A & B respectively are

A & B

t
a
r

1) CH3OH & CH3CHO

3) CH3OH & HCHO

t
e

4) C6H5Cl, C6H6Cl6, C6Cl6

2) CH3OH & CH3COOH

p
u
d

4) CH3CHO & CH3OH

7. The amount of NH3 evolved from 1 g of an organic compound in Kjeldahl's

estimation of N, neutralised 20 ml of 1 M H2SO4. The % of N in the compound
is

a
n

e
e
.
w
w

f l-A s t-- o N Nx---p 1 v s t-

* -- t-E- 20 N.M. 1 M H2SO4 -n--J-*C. t- o N

1) 28

8.

2) 14

Anhyd. AlCl3
C6H14

HCl
V2O5

773 K, 20 atm
where x, y, z are respectively

3) 42

4) 56

x+y
z

x, y, z -
1) 2-Methyl pentane, 3-Methyl pentane, Benzene
2-N--j- , 3-Nj , @
2) 2 - Methyl pentane, Benzene, 3 - Methyl pentane
2 - Nj , @, 3-Nj
3) Benzene, 2- Methyl pentane, 3- Methyl pentane
@, 2 - Nj , 3- Nj
4) C6H13Cl, C5H11 Cl, C6H5OH
9. An organic compound weighing 0.62 g gave 0.888 g of Magnesium pyrophosphate in the estimation of ''P'' by Carius method. The % of P in the given
compound is

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J- l-A s t- o P N-x--p 0.62 v. s

t- 0.888 v. Uo- j--p- *aC. - t-- o P
1) 20

2) 30

3) 40

t
e

4) 60

10. 0.16 g of an organic compound gives 0.116 g of BaSO4. The % of "S" in this
compound is
0.16 v.

s t-

1) 30

0.116 v. BaSO4
-

2) 10

n
.
a

bh

"S"

- *aC. t-- o

3) 20

i
t

11. Colour of the complex [Fe(CN)5NOS] 4, [Fe(SCN)]+2,

4) 16

a
r

Fe4 [Fe (CN) 6 ] 3. x H2O respectively are

[Fe (CN)5 NOS]4, [Fe(SCN)]+2,

p
u
d

Fe4[Fe(CN)6]3. x H2O t--

a
n

1) violet, blood red, prussian blue

e
e
.
w
w

, h-g, v- F
2) red, violet, blue
, , F

t
e
n

3) blood red, violet, prussian blue

h-g, , v- F
4) blue, blood red, violet F, h g ,

.
a
h

12. C & H are estimated by the method

C & H

b
i
t

\ lA

1) Kjeldahl's method

f lA
u lA

3) Duma's method

2) Carius method

a
r
p

4) Liebig's method

J- lA
MG lA

13. Correct trend of acidic nature among the following is

u
d
a

- L---- xy j v
1) C2H6 > C2H4 > C2H2

2) C2H2 > C2H4 > C2H6

3) C2H6 = C2H4 = C2H2

4) C2H4 > C2H2 > C2H6

en

e
.
ww

14. Which of the following will have a meso-isomer also?

- L- C O%Eo LT C?
1) 2, 3 dichlorobutane
2, 3 jx-u
2) 2 chlorobutane
2 xu
3) 2, 3 dichloropentane
2, 3 jx---
4) 2 hydroxy-propanoic acid
2 jv-q-v--- x

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15. The number of conformational isomers possible for C2H6 are
C2H6 p----L

-- u

1) 2

2) 4

3) 6

t
e

4) infinite

16. An organic compound was analysed for N by Duma's method and found 30% of

n
.
a

N in it. The volume of N2 given by 0.5 g of this compound at STP is

u l-A N - Nx----p s t-
t- STP l a N2 --J-
1) 60 ml

30% N

h
b
i

2) 90 ml

C.

3) 120 ml

t
a
r

0.5

4) 30 ml

17. In Carius method of estimation of halogen, 0.15 g. of an organic compound gave

p
u
d

0.125 g. of AgBr. The % of Br present in the

compound is
0.15

J- l-A - J---t Nx----p

0.125 v. AgBr E p-Jh, t- Br

a
n

1) 35.5

e
e
.
w
w

2) 71

3) 53

v. s t-

4) 17.75

18. The order of stability of the following carbocations is

- L s---x ny v

1) III > II > I

2) II > III > I

.
a
h

3) I > II > III

19. Acetylene reacts with hypochlorous acid to form

b
i
t

--M j-x- x u J aC
1) CH3COCl

2) Cl2 CHCHO

3) ClCH2 CHO

a
r
p

20. Free radicals are

u
d
a

ya vA--C-
1) Chemically inert

t
e
n

CH2 = CH C H2 (I), CH3 CH2 C H2 (II), C6H5C H2 (III) is

n
e
e
.
ww

--E
2) Anions

-x

3) Cations

-x

4) Chemically reactive

--E u-Q- --o-N

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4) III > I > II

4) ClCH2 COOH

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21. The correct order of increasing basic nature for the following compounds is

- L- t-- ~ y J j v
1) NH3 < CH3 NH2 < (CH3)2 NH

t
e

2) CH3NH2 < (CH3)2 NH < NH3

n
.
a

3) (CH3)2NH < NH3 < CH3 NH2

4) CH3NH2 < NH3 < (CH3)2 NH -

h
b
i

KEY

t
a
r

1-4; 2-3; 3-2; 4-1; 5-2; 6-3; 7-4; 8-1; 9-3; 10-2; 11-1; 12-4; 13-2; 14-1; 15-4; 16-3; 171; 18-4; 19-2; 20-4; 21-1.

SOLUTIONS

p
u
d

1) NH4CNO H2 NCONH2

a
n

AlCl3
Phenyl benzoate O & P hydroxy

e
e
.
w
w

benzophenone

t
e
n

Br2

RCONH2 RNH2 + K2CO3

KOH

.
a
h

(group R migrates from C to N)

b
i
t

2) Fe4 [Fe (CN)6 ] 3 . x H2O is iron (III) hexa cyano Ferrate (II)
3)

H C C H

a
r
p

u
d
a

OH

n
e
e
.
ww

H is eliminated from carbon

4) In Markonikov's addition reaction, stable 2 carbocation, in Anti Markonikov's

addition reaction, stable 2 free radical are formed
Anhyd.AlCl3
5) C6H6 + Cl2
C6H5Cl + HCl
Arhyd . AlCl3
C6H6 + 6Cl2
C6Cl6 + 6HCl
dark, cold

sun light

C6H6 + 3Cl2 C6H6Cl6

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Cu/ 100 atm

6) 2CH4 + O2 2CH3OH
523 K

t
e

MO2O3

CH4 + O2 HCHO + H2O

n
.
a

7) 1 M 20 ml H2SO4 = 1 M 40 ml NH3
14 M Vol. of NH3 100
% of N =
1000 wt. of org. compound

h
b
i

t
a
r

14 1 40 100
= = 56%
1000 1

p
u
d

Anhyd. AlCl3

8) M - Hexane 2 - Methylpentane
HCl
(X)

a
n

+ 3 - Methyl pentane

e
e
.
w
w
(Y)

t
e
n

V2O5

M - Hexane Benzene
773 K, 20 atm

62

.
a
h

0.888

9) % of P = 100 = 40
222
0.62
[M.wt. of Mg2P2O7 = 222]

b
i
t

a
r
p

32
0.116
10) % of S = 100 = 10
233
0.16

u
d
a

[M.wt. of BaSO4 = 233]

11) [Fe (CN)5 NOS]4 violet;

n
e
e
.
ww

[Fe (SCN)]+2

blood red

Fe4 [Fe (CN)6]3 . x H2O Prussian blue

12) C & H are estimated by Liebig's method

13) Electronegativity acidic nature
% of S in sp = 50%, sp2 = 33.3%, sp3 = 25%

C2H2 > C2H4 > C2H6

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14) 2 assymetric carbons * mark are present, plane of symmetry is there.
CH3

t
e

H C* Cl

n
.
a

........................
H C* Cl

h
b
i

CH3

15) by the rotation of 6 H atoms around 2 C atoms in ethane results into infinite
number of special arrangements.

t
a
r

28 Vol. of N2 at STP 100

16) %of N =
22400 wt. of organic compound

p
u
d

a
n

30 22400 0.5
Vol. of N2 at STP =
28 100

e
e
.
w
w

= 120 ml

t
e
n

80 wt. of Ag Br 100
17) % of Br =
188 wt. of organic compound

80 0.125 100
= = 35.5
188 0.15

b
i
t

18) C6H5C H2 is more resonance stabilised,

CH2 = CH C H2 is resonance stabilised,

.
a
h

a
r
p

CH3 CH2 C H2 is stabilised only by + I effect.

u
d
a

19) C2H2 + 2HOCl Cl2CHCHO

H2O

n
e
e
.
ww

20) Free radicals are neutral and reactive due to presence of unpaired electron.

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A.N.S. Sankara Rao