Applications of AFM in Semiconductor R&D and Manufacturing at 45 NM Technology Node and Beyond
Applications of AFM in Semiconductor R&D and Manufacturing at 45 NM Technology Node and Beyond
Applications of AFM in Semiconductor R&D and Manufacturing at 45 NM Technology Node and Beyond
1. INTRODUCTION
As the integrated circuit technology advances to the 45 nm node and beyond in semiconductor industry, there is
increasing need to search for the complementary metrology to ensure integrity of critical process control. It is because
metrologists in the field have recently noticed the weakness of scanning electron microscopy (CDSEM) and optical
scatterometry (OCD) which have been considered as dominant metrologies for in-line control of various processes like
line/trench etching, recessed features, holes, etc. Precision as a metric for metrology quality is replaced with more
comprehensive measurement uncertainty in the 2007 edition of international technology roadmap for semiconductors
(ITRS) [1]. Several new components of uncertainty besides the precision have to be considered. Today two of them,
sampling uncertainty and sample-to-sample measurement bias variation, are often dominant in the combined uncertainty
of measurement. An automated AFM is a promising candidate metrology which is capable of sub-nanometer sampling
uncertainty and bias variation. As a result of this, for quite some time AFM has been adopted by the industry as a
reference metrology in process control of semiconductor wafer manufacturing.
Table 1 lists various dimensional metrology techniques available today [2]. Due to its unique characteristics 3dimensional AFM (3D-AFM) has been demanded by the industry of memory, logic, photomask, data storage and CMOS
image sensor (CIS). This article focuses on uniqueness and merits of AFM with respect to CDSEM, OCD and also offline metrologies like TEM and cross-section SEM (X-SEM).
Metrology, Inspection, and Process Control for Microlithography XXIII, edited by John A. Allgair, Christopher J. Raymond
Proc. of SPIE Vol. 7272, 72722R 2009 SPIE CCC code: 0277-786X/09/$18 doi: 10.1117/12.813389
CDSEM
OCD
Dual-Beam
TEM
3D-AFM
Process control
OPC & RET modeling
Engineering
Process control
Litho evaluation
Failure analysis
Engineering
Reference tool
Failure analysis
Engineering
Sample
interaction
Shrinking
Charging
Carbonization
Bleaching
(especially for spectral tools)
Destructive
Gallium contamination
Shrinking
Destructive
Shrinking
Warping
Non-destructive
No contamination
No sample dependent bias
3D Capability
2D [XY]
2D [XZ]
2D [XZ] or [XY]
3D [XYZ]
Low
Lowest
High
Very high
Moderate
MAM time
4-5 sec
2-4 sec
30-90 sec
2-4 hours
10-40 sec
Precision (Gate
ca. 0.5 nm (3s)
CD)
Uncertainty
(Gate CD)
Uncertainty
(Gate SWA)
Limited sampling
Shrinking
Charging
Sample dependent edge
definition
Limited sampling
Shrinking
Warping
Sample dependent edge
definition
Limitations
Less than 15 nm CD
Variable bias for 2D &
dense features
Material & profile bias
dependence
Areas of Use
2. COMMON APPLICATIONS
2.1 Critical Dimension (CD), Line Width Roughness (LWR) and Line Edge Roughness (LER)
Demand for CD and shape analysis of gate, resist and STI is rapidly growing at 45nm technology node and beyond.
TEM and CDSEM are widely used for CD applications today. However, turn-around time for TEM is from several hours
to up to several days. This is often unacceptable. CDSEM is much faster but does not provide any vertical line/trench
profile information. 3D-AFM offers detailed line profile information based on multiple cross-sections within a minute
(see Fig. 1). At the same time uncertainty of 3D-AFM data is superior to TEM since local sampling uncertainty of the
mean line CD is minimized through extensive averaging along the line.
Linewidth variation becomes more and more critical for lithographic and etching process steps at 45nm node and beyond.
OCD averages LWR/LER and thus can not monitor CD variation. CDSEM provides roughness information averaged
along line/trench vertical profile and has tendency to underestimate LWR/LER. As shown in Fig. 1 (c), 3D-AFM offers
full 3D, nanometer resolution, accurate and repeatable LWR/LER data.
5i
114101
94).
0
9
5)5
544
144
54?
Sfl
11
I]
II
II)
1)5
51.1
145
5].)
5)?
*4
544
4.j
as_I
N))
10.1
as_I
5))
1114
5414
5)]
i
Fig. 1. (a) TEM image of isolated poly gate line, (b) 3D-AFM image of the same poly gate line and (c) linewidth analysis
data of AFM tool.
E-Beam2
Silicon
Gate
Simple SWR
Left
2.37
1.22
1.18
0.85
LER Left
-IS
1.23
0.92
.42
Pooled SWR
Left
Simple SWR
Right
2.77
.22
LER Right
3.86
0.98
0.80
1.68
Pooled SWR
Right
Fig. 2. (a) CDSEM image of poly gate lines, (b) 3D-AFM image of one poly gate line and (c) line edge roughness and
sidewall roughness data of gate lines [4].
2.3 Shallow Trench Isolation (STI) Profile, Effective Field Height (EFH) & Divot Analysis
STI profiling, including depth, line/trench CD and sidewall angle, is an important process control step required for stable
performance of devices at 45 nm node and beyond. The top corner Si rounding of STI may significantly impact threshold
voltage (Vt) of the transistor through an increase of the leakage current. However, the top corner Si rounding is not easily
monitor in-line. Off-line X-SEM and TEM are widely used today for the top corner Si rounding. OCD could be a good
metrology choice for array of cells (example: DRAM). However, OCD is limited to repeated patterns only. Today, it is
not an in-line solution for STI monitoring in peripheral area of memory, cell area of SRAM or logic devices. 3D-AFM
can directly characterize the top corner Si rounding as well as full sidewall profile of any device as shown in Fig. 3 (a).
Active
Field
ctive
1d
Ad
Field
Activec Field
center Die
Active
on
Field Oxide
(b)
Fig. 3. (a) 3D-AFM image of STI array in cell area of DRAM device, (b) AFM images of EFH for various CMP conditions
and (c) divot profiles by AFM for logic circuit.
Since chemical-mechanical polishing (CMP) has been introduced to STI process module, product yield is strongly
impacted by post CMP wafer uniformity. The effective field height (EFH) is field silicon oxide height with respect to
active silicon area. EFH out of specification is a very common reason for SRAM and logic failure. After CMP, the EFH
can vary across the wafer. Changes in the EFH significantly impact the integrity of the following gate patterning as well
as poly-Si thickness and, therefore, threshold characteristics of transistors.
A divot is a small notch observed between the STI (silicon oxide) and active area. The divot forms during wet STI
processing. The STI divot strongly impacts the performance of narrow channel transistors. Therefore, in-line monitoring
of divot becomes essential at 45 nm node and beyond.
The STI Divot and EFH present at most, only a few nanometers of topography. To add to this metrology challenge, the
post CMP EFH can change topography within a single wafer. CD-SEM and OCD are barely, if at all, capable of
measuring such small changes in topography. TEM and X-SEM are capable but are, of course, destructive. The AFM is
sensitive to topography changes less than a nanometer and is non-destructive. This permits the use of AFM as an inline
monitor that is able to measure individual devices at the STI module. As shown in Figs. 3 (b) and (c), AFM can
characterize divot depth and width, planarity of field oxide & active area as well as measure EFH and its polarity.
2.4 Cu CMP Process and Plug Recess
Cu CMP process is needed at 45 nm node and beyond for memory devices. However, Cu CMP process for 45 nm
memory is not fully characterized and understood yet. Stylus-type profiler has a lateral resolution limit and high shearing
force preventing its use for 45 nm CMP process characterization. AFM profiler is a superior metrology tool capable of
global planarity, local topography, dishing & erosion and roughness measurements. Measurements can be done in a
single mm-long scan as showed in Fig. 4. The depth of Cu plug recess has an impact on the following interconnection
processes like low-k deposition or Cu deposition. With diameter of the plug as small as the node of technology AFM
becomes the only metrology for plug recess control at 45nm technology node and beyond.
:100 nm
All data are gathered by one men urement of 10mm scan length
.4
10mm = 10,000,000 nm
Fig. 4. Profile of AFM image in profiler mode crossing cell and peripheral area of DRAM device.
.\
103
103
1.03
133
133
1.13
103
I 23457 09101112I314151t1701093
Fig. 5. (a) AFM image of 20 nm thickness W, (b) AFM image of bare Si wafer and (c) the repeatability of AFM roughness
measurement on W thin film using conical Si and CNT probe.
Good example of reference metrology application of CD-AFM is measurement conducted on the single crystal critical
dimension reference material (SCCDRM) by the NIST scientist R. Dixson [5]. In this work 3D-AFM has been used as a
reference measurement system (RMS) for traceable measurements of height and width of crystalline Si line. High
resolution transmission electron microscopy (HRTEM) was used as an indirect method of AFM tip width calibration.
The AFM and HRTEM results which were used for the tip width calibration are shown in Fig. 6.
200-00
200200
200 00
100-00
C
100- 00
00-00
0-20
5000
C 00
100200
150 00
200-00
25000
300 00
Fig. 6. Correlation between 3D-AFM and HRTEM measurements. The observed slope is consistent with unity indicating
that the two methods have consistent scale calibration. The average offset between the results was used to correct the
tip width calibration [5].
224.9
(a)
_I'lo
tab
lOOnm
Fig. 7. (a) Schematic diagram of Fin-FET [6], (b) SEM image of FinFET structure on oxide layer and (c) 3D-AFM image of
FinFET.
/ Drain
SEG
()
SEG MOSFT
(c)
Fig. 8. (a) Schematic diagram of SEG MOSFET device, (b) X-SEM image of SiGe SEG MOSFET structure and (c) 3DAFM image of faceted regions.
Fig. 9. (a) Schematic diagram of NAND string of flash memory device [8] and (b) 3D-AFM image of CSL in red line box.
1784./-1.9
449.6./-3.0
448.61
0.30
178.89
0.11
0.36
0.08%
0.10%
82.6.1-1.2
81.96
CVde
Av8r998
3 sig
[661)
3 sign
[l
182.Ofl.2
178.4fkl.9
0.47
4.64,3.O I
5oo.
460.T
40003
350.T
30003
25003
20003
15003
10003
5003
(c)
1 2 2 45 6 7 8 9
Fig. 10. (a) X-SEM image of contact hole, (b) DT mode AFM image of contact hole and (c) AFM depth measurement
repeatability demonstrated on SI-traceable standards.
, SI
eSI I .
I
I
I
pSIIS
II
nnn
Average Profile
SS
SS.
S..III.I
5.5 5
SI I - ISII e-.--. I 55
S
..e....
. S..
_..
.
..S.....S...
S.
:.
1I
I
it-
Recess Variation
(U)
1QO
20C
(c)
Fig. 11. (a) AFM image of etch backed contact hole array, (b) sectional profile of AFM image showing recess variation and
(c) the statistical and quantitative results of recessed poly-Si contact holes by special analysis function of AFM tool.
SG tp Oep
Ease of implementation
(a)
IWM
Fig. 12. (a) Schematic diagram of strained transistor process [9], (b) TEM image of strained pMOS transistor and (c) 3DAFM image of isolated transistor with recessed drain and source regions.
1'
Spntn
it1
ft
AFM Probe
U 2nd
U.
I
ft
rd
Width
DiL0tri0
Spacer 00cr,
Ent
I
220
s/u
WeLL
-hO
'I
PoOyEtrh
20
1%
be
240
X Position (nml
Fig. 13. (a) Schematics of multiple sidewall spacers and S/D junctions (showing one gate side only), (b) TEM image of gate
with multiple spacers and (c) sequential AFM images of the same gate through spacer processing [2].
characterize three dimensional profile of nitride liner as the shape difference before tensile material deposition and after
its removal indicates how much tensile material has been left behind. The stack is too complex for OCD. X-SEM and
TEM cannot access the same site before and after processing. CDSEM is not sensitive to profile and shape. 3D-AFM can
be used to estimate the remaining tensile material directly by scanning on the same site (Fig. 14).
DUAL STRESS LII'JER
TRANSISTOR CROSS-SECTION
G..i.do,dd.
Tensile
Cb.npxensisz
nodth l.nit
Fig. 14. (a) Schematic diagram of dual stress liner process and corresponding X-SEM images [10], (b) X-SEM image of
DSL gate and (c) sequential AFM profiles of gate before and after deposition and etching of nitride spacer.
..___Cap or Stop
.-Cap or Stop
-r
--
Trench
Cap or Stop
Low-K
Cap or Stop
Barrier for Cu
I 5OOna
(c)
(b)
Fig. 15. (a) Schematic diagram of dual damascene structure [12], (b) X-SEM image of Cu-deposited dual damascene trench
and via structure and (c) AFM profile of dual damascene structure.
(a)
5. PHOTOMASK APPLICATIONS
5.1 Defect Review
Defect control specifications of photomask products are tighter than that of final wafer products. Any imperfection of
photomask will be transferred to sample pattern resulting in yield and productivity drop. Defect review is a critical
procedure in mask production since photomask can be potentially repaired. Once defect is found 3D characterization of
the defect is needed to decide on feasibility of its repair. CDSEM is the most widely used metrology for defect review.
However, CDSEM can not provide topography of defect. 3D-AFM can characterize any defect in detail in full 3D.
Photomask repair equipment is using AFM already to estimate initial defect volume and control progress of repairing.
I
I
II
DS
Deposition
ouse E;ite
(b)
Cr Bridging
Estr.e Cr Pattern
Broken Line
Fig. 16. (a) CDSEM and corresponding (b) 3D-AFM images of deposition-type photomask defect. (c) Various types of
photomask defects.
88888888888
Fig. 17. (a) Original design with no OPC and the corresponding wafer print, (b) OPC-ed design and the corresponding wafer
print [13]. (c) CDSEM offset by feature type showing that CDSEM bias is feature dependent.
Ouartz deal
OurS,
Phase
TnnsntiSS.Ofl = 100%
Chrome opafluel
Resist TtwOShOId
CflrOrfle.
Resist flwflsthad
-,
r\ T\ r\ T\ f\ r-
Romaj 51(19
flotisi Nltjr
OOvOIOO
(c)
(b) Attenuated Phase Shitt Mask
Binary Mask
Fig. 18. Schematic diagram explaining the principle of (a) conventional binary mask and (b) phase shift mask [14]. (c) AFM
image of MoSi layer of phase shift mask.
a)
6. CIS APPLICATIONS
6.1 Microlens
The digital camera has become a ubiquitous part of modern personal electronic devices. The key light gathering devices
of these cameras is the microlens that focuses light through a color filter and onto a photodiode. To improve image
resolution and to fit into smaller and smaller end user device form factors, manufacturers have had to invent new and
unique methods of packing large numbers of microlenses into smaller and smaller foot prints without compromising light
gathering efficiency. As the shape of the microlens determines how well the lens is able to focus the light onto the
photodiode, controlling microlens shape is critical for improving device quality and yield. In todays most cutting edge
imaging devices, the lens shape varies across the microlens array. The AFM is able to perform precise topographical
measurements over multiple microlenses in a single image. Each individual microlens is then measured for lateral
dimensions as well as height, and sidewall angles. Lastly, an RMS error to a fit of either a sphere or an ellipse provides
an overall metric to the shape of each microlens.
Artotorny of the Active Pisel Sensor Photodiode
"an
Microlens -
AnpIIL
Transistor
Column - -
Red
Color
Filter
Reset
II IbIiIIIIlIIL 1111111
San
IIIIIIIII!.II
1111111
SOS
irunsistor
Row
Select
Bat
flflCI
L
cia
.5 cc,
Silicon
Sobtrnie
cc
a,
(a)
It
r,
TransiStor
Potential
Well
4151
4455
LIt,
cii
lan am an
53
3440. .3 Ct, 0205 0212 345 0134 320i1 415 it, i51
-, P0.5 2200 0512 a,. au. 3205
253 2413
I VJur151u Earn)
1000
200
am
S'S
5g4
u51, sap
Fig. 19. (a) Schematic diagram of CIS device [15], (b) data of photo generation rate affected by microlens shape [16] and (c)
dimensions of microlens measured by AFM.
olens
Spacer
Color Filter
Color Filter
(Green)
(Red)
P1
ssiyaF
Photo Diode
(b)
Fig. 20. (a) Vertical schematic diagram of CIS device [17], (b) Bayer mosaic filter configuration for color filter [18] and (c)
the color filter height data by AFM.
7. CONCLUSION
Shrinking device dimensions and tight process windows demand sub-nanometer accuracy of metrology for CD control.
X-SEM and TEM are commonly used today for cross-sectional characterization and accurate CD metrology of modern
devices. Things are changing. 3D-AFM replaces the off-line destructive techniques with the most accurate, statistically
prudent and quick in-line metrology. The 2007 edition of ITRS is calling for a new comprehensive metric for metrology
- uncertainty. It may take some time for the industry to adopt the new metric. As of today AFM is the most promising
technique capable of 3D CD metrology with sub-nanometer uncertainty. To gain industrys full recognition, robustness
and ease-of-use of AFM should be further improved to meet demanding requirements of semiconductor manufacturing.
This is the challenge we are facing.
REFERENCES
[1]
[2]
[3]
[4]
[5]
[6]
[7]
[8]
[9]
[10]
[11]
[12]
[13]
[14]
[15]
[16]
[17]
[18]