Tong Champagne
Tong Champagne
Tong Champagne
N 4 / Winter 2009
CHAMPAGNE
A delicate balance BY STEVE CHARTERS MW 02 Champagne's credibility gap BY TOM STEVENSON 09 Single vineyard
champagnes BY ESSI AVELLAN MW 18 Autolysis BY HERV ALEXANDRE 28 The science behind the bubbles BY GRARD
LIGER-BELAIR, RGIS GOUGEON & PHILIPPE SCHMITT-KOPPLIN 36 A quest for the best BY PASCAL AGRAPART 44
EDITORIAL
CHAMPAGNES
SWEET SECRET
Champagne is a fantastic wine. No other wine,
even if it costs over a thousand euros a bottle, can
rival its image. Despite competition from Spains
cava and other sparkling wines from around the
world, champagne soars on regardless.
Perhaps one of its inherent strengths, as Steve
Charters points out in his article, is that the sales
of champagne are so closely linked to global economic factors. Although sales slowed down in
2008 and 2009, it looks certain they will rise
when our economies pick up again.
And yet, despite brilliant marketing, Champagne has many obstacles to face over the next
10 years. Theres the revision of the appellation;
the growing trend for single vineyard champagnes; and the concomitant rise of the grower.
On the other hand, houses and cooperatives have
never been so demanding and are monopolising
the champagne market both in and outside
Champagne. It is they in particular that are clamouring for a revision.
What about the growing demand for Extra
Brut and Brut Nature champagnes? There are
two reasons for this. Better educated consumers
are looking for more individuality in wine. And
theres a move towards transparent products,
as a part of the healthier lifestyle the media is
marketing.
Many champagne connoisseurs, like Essi
Avellan and Tom Stevenson, say that low- or nondosaged champagnes are often too harsh and thin.
Pascal Agrapart in his article offers an explanation
for this: Brut Nature and Extra Brut need topquality grapes to guarantee perfect base wines that
will give the champagne more natural body.
And this is one of the problems Champagne
faces. It is not one of the worlds most effective winegrowing regions. Although every grower has to
harvest manually, the emphasis is still on mass production rather than quality control. Until recently, for instance, in the winter Champagnes soil
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A DELICATE
BALANCE
BY STEVE CHARTERS MW, FRANCE
03
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THE CHAMPAGNE
BUSINESS TODAY
Steve Charters is an Australian Master of Wine based
in Reims, France, where he is professor at the Chair
of Champagne Management in Reims Management
School. His specialities include the cultural and social
context of wine, and more particularly champagne.
His research focuses on the marketing of wine, consumer behaviour and wine tourism.
The French see things from a different perspective. The word rupture is significant in social
discourse, literally meaning a break but in fact
having a much stronger and decisive significance.
Revolutions, the Second World War, Algeria, the
vnements of 1968, even perhaps the election of
French President Nicolas Sarkozy, all have marked
rupture. Likewise, for the Champenois, the world
financial crisis of October 2008 is perceived as
providing a radical rupture with the past.
In fact, as we shall see, the threat to champagne sales began more than a year before the
financial catastrophe, although all seemed well
until a little over a year ago. For most of the
decade we watched wine producers in the rest of
France grapple with overproduction and the
onslaught of mass-market brands from new producing countries, resulting in the claim that there
was a crise viticole; yet meanwhile in Champagne
it was common to talk of a crise de prosprit. Sales
were booming; things were almost too good.
Although a dip did follow the millennial euphoria and the attack on the World Trade Centre, the
1952
1959
1966
1973
1980
1987
1994
2001
2008
STEVE CHARTERS MW
The graph on the previous page shows the development of champagne exports since the Second
World War. For the Champenois and their accountants, its a beautiful sight but what it also clearly reveals is that international wine sales are linked
to world economic factors: 30 years of post-war
growth; the first and second oil crises in 1973-74
and 1980-82 and substantial problems (particularly in the UK and US property markets) in
1991-94. The 2001 dip is exaggerated by the aberrantly high growth in sales before 2000.
The boom since 2001 has been fuelled essentially by solid performance in the major importing countries (in the UK, shipments rose from
25 million bottles to just over 39 million in
2007), together with dramatic increases in consumption in new markets. The cases of China and
Russia are regularly referred to as examples of this
but there are others. In 2007 countries as diverse
as Angola, Argentina, New Zealand, Slovenia and
the Ukraine all recorded imports increasing by
over 70% on the previous year.
The sustained growth in export markets
with a record 332 million bottles shipped in 2007
both in France and the rest of the world brought
its share of problems. Essentially all of the 34,000
hectares demarcated within the appellation are
now planted (an increase of 33% since 1980), and
the maximum yield has also increased from an
average of 10,480 kilos per hectare during the
1970s to 13,100 kilos for the first nine years of
the current decade. This is compounded by the
fact that as a combined result of the French fiscal
regime and growers desire to constitute personal
stocks to increase their retirement income, it has
been suggested that growers are reducing the
volume of grapes they are selling to the houses.
The problems with grape supply and some of
the resulting responses are familiar. Before the
crisis it was projected that by some time between
2011 and 2015 demand would exceed supply;
according to the retail banking group Crdit
Agricole, even in the current economic climate
that could occur between 2013 and 2018. The
best-known proposal to deal with this is the suggested revision of the area of the appellation
(which Tom Stevenson writes about in his article).
It is worth noting, however, that although this
proposal originally came from the growers union
SGV in the early years of this decade, research
suggests that the growers themselves are widely
suspicious of it, suggesting its in the interest of
the houses as a way to reinforce their power.
Another result of the buoyant champagne
market is its effect on local land prices. When I
travel into work I see vineyards adjoining arable
land used for sugar beet or wheat; the former is
worth, on average, around 850,000 per hectare,
% change
2008-09
UK
35.984.574
-7.86%
US
17.193.526
-20.85%
GERMANY
11.573.597
-10.38%
ITALY
9.910.581
-0.40%
BELGIUM
9.438.811
-8.78%
JAPAN
8.332.233
-9.14%
SWITZERLAND
5.439.009
-10.36%
SPAIN
4.090.505
-10.54%
AUSTRALIA
3.648.022
10.25%
10
NETHERLANDS
3.511.889
-13.97%
STEVE CHARTERS MW
FRENCH ATTITUDE
First, the changing nature of ownership in Champagne is going to have an effect on the way the
region develops. Thirty-five years ago all the
houses were owned and managed locally. That is
no longer the case, with three of the six largest
groups being owned outside the region, often
with a spread of shareholders worldwide. This
development has been essential for champagne;
it has facilitated the inflow of capital needed to
sustain the rapid growth of the product and it has
provided a new source of expertise to improve
management and marketing. Yet, at the same
time, it also produces owners who may have little
or no idea of the way the region operates (particularly the complex cultural and social interactions
that sustain the economic ones).
Additionally, the new owners have quite reasonably a primary commitment not to the
long-term collective development of the region
but rather to their own profit. What happens
when that focus conflicts with the wider needs of
Champagne as a whole? It is easy to dismiss this
as a minor concern, yet exactly the same thing has
happened in Australia, where the unity provided
by a common commitment to brand Australia
in the mid-1980s has given way to a growing fissure between a few large companies with a glob-
STEVE CHARTERS MW
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CHAMPAGNES
CREDIBILITY
GAP
BY TOM STEVENSON, UK
09
TOM STEVENSON
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Letter is one of the leading voices in the champagne industry. Together with Mumms former
boss, Jean-Marie Barillre, he knows how easy it
is to lose a reputation and how difficult it is to
regain it.
The only way to ensure no quantitative expansion without a qualitative revision is to re-evaluate all the champagne-producing villages, not
just the proposed new ones. The percentile system
of the Echelle des Crus has been dumped for
being little more than a glorified price list.
If their classification is to command any respect,
Champagne should abandon its Beaujolais-like
village-by-village cru system and re-evaluate all
vineyards on a plot-by-plot basis. Take Avize or
Cramant: this would entail reducing the status
of some vineyards to premier cru, while those on
the wrong side of the D9 would simply become
village cru wines. On the other hand, there are a
few places, like Mareuil-sur-A, where a number
of its vineyards ought to be classified grand cru,
and hardly any of its vineyards deserve less than
premier cru status. And there will be some villages
where sites will have to drop out of the appellation altogether. If the expansion is to be credible,
not only must there be complete transparency
about why new vineyard areas have been selected, there must also be a radical reassessment of
champagnes cru status, with a trimming of the
inferior areas.
The data for this has already been assembled
during the five-year zonage project of the 1990s,
making the task much easier than it sounds.
Zonage examined the entire AOC Champagne
region, as well as almost 20,000 ha of areas
immediately surrounding it by dividing the zone
into more than 200,000 50m x 50m parcels that
were then subjected to the most intensive exploration of terroir ever conducted. Each parcel was
meticulously evaluated under the ground, above
the ground and from space by every means
of analysis then available, from hole digging to
satellite imagery.
Why they should want such a thing is perplexing, to say the least. Are we to believe that the
growers actually want to open up their monopoly
to new owners and allow in almost one-third
more grapes, which can only soften prices and
reduce their income? Whatever the documented
evidence, the biggest brands are those with the
most to gain from an expansion, and I have been
told confidentially that they are the ones behind
the request.
I could understand if, for the good of the
industry, the leaders of the SGV came to some
sort of arrangement with the upper echelons of
the Union des Maisons de Champagne (UMC),
but this request was not agreed behind closed
doors and was the result of a conclusive democratic vote. The growers I spoke to pointed out, not
unreasonably, that the 393 yes votes by no means
represent majority opinion among the SGVs
15,000-plus membership. The subplot is that,
because the growers have nothing to gain, it
would look good for them to be seen as initiating this expansion. How they got the SGV to play
ball is the subject of myriad conspiracy theories.
I came across some extreme comments and accusations that I will not quote, but it would be fair
to say that among growers, a few are suspicious of
some of the motives for pushing the SGV motion
through. To paraphrase one of the more printable
comments made to me by six growers and one
small house: We assume that most of those who
attended the assembly were in favour of the
motion to expand, which is why they turned up.
As in all elections, those who arent in agreement
seldom vote to defend themselves. On the other
hand, it might be said that the growers who dont
want to see their franchise broken have only
themselves to blame.
PARCEL BY PARCEL
TOM STEVENSON
produce decent non-vintage material without difficulty. However, if we classify new land, this
implies that we should have to re-evaluate existing land and perhaps declassify some areas in the
process. I cant see this taking place, which is a pity.
Also, I think the status of grand or premier cru, as
well as simple village cru, should apply to parcels,
not to whole villages, but as far as I know this has
not been contemplated in the revision process.
As it happens, a few days earlier I had a phone
call from the boss of a family-owned house of
impeccable reputation who preferred not to be
named but who told me that he had just heard
that the experts were indeed contemplating declassifying some land in current villages. When I asked
him if there were any plans to compensate growers, he told me there was talk of a compensation
scheme similar to the one used for the 25 ha of
AOC Champagne destroyed to build the highspeed TGV line. I mentioned this to Philipponnat,
who said: If this idea is making its way into the
minds of our experts and leaders, thats great
news, because it will make the whole process credible. So, there may be the will
TIMING IS KEY
ELUSIVE RULES
Champagne desperately needs credibility. Requesting such a massive expansion was bound to have
an adverse effect when champagne sales are at a
pretty high level although there may yet be a
decrease of 15% to 20% this year. Demand still
outstrips supply and almost every spare hectare
of AOC land has been exhausted. The media
(and not just the wine press) has suggested that
the push was motivated by greed. Internet
forums have risen in disgust. With everyone in
Champagne toeing the official line, the question
of whether to expand is apparently not open to
debate even within the industry itself. This smacks
of arrogance and Champagne should take heed.
I myself dont believe that Champagne is guilty
of greed but of stupidity. It is true that expansion proposals have so far been intelligently
drawn up to enhance both the quality and efficiency of Champagne within its historical borders. But the timing is wrong when champagne
appears to be relatively unscathed by the recession. Champagne has to bridge a credibility gap
if its strictly delimited image is to be taken seriously. And the only way to achieve this is not only
to ensure that every hectare of newly classified
AOC land is superior to the average quality of
Champagnes current vineyards (which would be
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balance being tracks, bridges, cuts and other inaccessible areas), and 33,542 ha are in fact planted.
The AOC law specifies three zones: Zone de
llaboration; Zone de Production; and Zone
Parcellaire de Production de Raisins. The Zone
de llaboration is the only zone in which it is
legal to vinify and transport champagne grapes
and wines. This represents the outer limits of
the region, currently comprising 647 communes
covering more than 600,000 ha. The Zone de
Production is inside the Zone de llaboration; it
currently includes 319 communes spread over
roughly 300,000 ha. Within these communes
there are, as indicated above, 35,200 ha in which
AOC vineyards may be planted.
NOT FOR TOMORROW
TOM STEVENSON
BEFORE
SOISSONS
REIMS
SAINTE MENEHOULD
CHATEAU-THIERRY
EPERNAY
CHALONS-EN-CHAMPAGNE
VITRY-LE-FRANCOIS
SEZANNE
SAINT-DIZIER
TROYES
BAR-SUR-AUBE
BAR-SUR-SEINE
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TOM STEVENSON
AFTER
SOISSONS
REIMS
SAINTE MENEHOULD
CHATEAU-THIERRY
EPERNAY
CHALONS-EN-CHAMPAGNE
SEZANNE
VITRY-LE-FRANCOIS
SAINT-DIZIER
TROYES
BAR-SUR-AUBE
BAR-SUR-SEINE
TONG N 4
SINGLE
VINEYARD
CHAMPAGNES
THE
ALTERNATIVE
REALITY
BY ESSI AVELLAN MW, FINLAND
19
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INSIGNIFICANT, YOU MAY THINK WHEN YOU HEAR THE TERM SINGLE VINEYARD
CHAMPAGNE. AFTER ALL, ONLY A FEW DOZEN PEOPLE MAKE IT IN AN OCEAN OF OVER
2000 CHAMPAGNE PRODUCERS. PRODUCTION QUANTITIES ARE MINUSCULE AND WHEN
YOU CHANCE TO SPOT ONE OF ITS MOST CELEBRATED BOTTLES, THE PRICE IS SO
ASTRONOMICAL THAT YOU RESIGN YOURSELF TO LETTING IT GO.
Despite these seemingly outrageous prices, champagne houses are reticent of investing in single
vineyard champagnes. The iconic Krug Clos
du Mesnils share of the houses output is so negligible that its bottles could be donated to the
diehard krugists without making a dent on the
balance sheets.
Yet, despite common assumptions, the microtrend of terroir champagnes is a significant one.
There are sound reasons why the concept is mushrooming and its wines are selling increasingly well,
with media and consumer interest developing as
well as a distinct price premium.
Four years ago, during my Master of Wine
studies, I became infatuated with single vineyard
champagnes. In addition to the wines themselves,
I became interested in why this region that swears
on blending was going for the very antithesis of
that. I wrote my Master of Wine dissertation on
the subject. Reading it today, I note that my projections about the concepts future were right but
20
TONG N 4
chaptalisation, liqueur de tirage and liqueur dexpdition. Double alcoholic fermentation and
prolonged lees ageing add layers of process over
the fruit and the residual sweetness hides some
delicate nuances.
Nevertheless, champagne is immediately identifiable and unique, and cannot be imitated in any
other region in the world. For this reason, blended
champagnes are multi-terroir wines par excellence.
Equally, non-blended champagnes are monoterroir wines.
GROWING POPULARITY
ESSI AVELLAN MW
WHATS IN A NAME?
TERROIR MICRO-TREND
What started with a few haphazard single vineyard launches has grown into a solid micro-trend.
Even though grandes marques lead in price and
recognition, the concept is being increasingly
appreciated and used by small growers. The reason for this is that the production scene for champagne is in transition. Today, the 15,000 growers
who own 88 percent of the vineyards sell a mere
one fifth of the total champagne production. Due
to the capital intense nature of the business and
its high entry barriers, growers own production
used to be limited. But now, as demand exceeds
supply, prices of vineyards and grapes have risen
and owning land in the region has become
increasingly profitable. The 2006 figures show
that a hectare of land on average produces grapes
worth 64,985. With these returns, champagne
production has become a realistic option and an
increasing number of growers are jumping on the
bandwagon.
Nicolas Maillard is a textbook example of the
new, innovative, quality-oriented and terroirdriven grower. He used to sell his grapes to the local
cooperative in Ecueil but recently started his own
production with single vineyard wines at the top
of his range. The terroirist movement has opened
up new opportunities for growers outside the
well-known Grand Cru villages, people like
Cdric Bouchard from Cte des Bar and Ulysse
Collin from Szanne.
Single vineyard wines are a wonderful marketing opportunity for growers hand-grafted
wines with got du terroir. Being part of this phenomenon helps with marketing where their own
resources human or financial fall short.
IN THE MAKING
ESSI AVELLAN MW
Champagne is on the irrevocable path to becoming a serious, gastronomic wine. The terroir
wine movement is tightly linked to this vinous
revolution. It is interesting to go back a few
decades and compare Burgundy with Champagne.
Burgundy, too, used to be dominated by large sellers but nowadays the most reputed and highpriced wines are those of the small growers. Is this
what is foreseeable for champagne?
I dont think so and certainly hope not.
Champagnes greatness and the secret of its centuries-long success is in blending. Climate dictates
this for wine quality but it is equally essential
commercially. Consistent quality and style year in
and out are champagnes strength, as are its enviable volumes. This does not mean the region
shouldnt evolve with the times. Todays enlightened champagne lover seeks understanding,
unique experiences and authenticity alongside the
magic of the bubbles.
On export markets, the impression is that
champagne is all about big brand glamour. This
is only the half-truth. Visit the region and you will
realise the drinks scope and complexity with its
countless small growers. The growers single vineyard champagnes are the quality spearhead of this
alternative reality of champagne.
I would like to see the category made official with strict rules
to obstruct opportunist ventures to capitalise on it
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CDRIC BOUCHARD
TARLANT
Tarlant produces three single vineyard champagnes. Cuve La Vigne dAntan, a 100 percent
Chardonnay from Les Sables vineyard, is made
from near-extinct ungrafted vines. The sandy soil
and more than 40-year-old vines produce a rich
and vinous wine with a strong character. At
youth, the old oak used for fermentation and maturation plays a noticeable role. Very much a wine,
this too should be given some bottle age.
ESSI AVELLAN MW
AGRAPART
Vnus Brut Nature
LARMANDIER-BERNIER
Terre de Vertus
Vieilles Vignes de Cramant
BILLECART-SALMON
Clos Saint Hilaire
JACQUES LASSAIGNE
Cuve Le Cotet
FRANCK BONVILLE
Belles Voyes
GEORGES LAVAL
Cuve Les Chnes Brut Nature
Cuve Les Hautes-Chvres Brut Nature
CDRIC BOUCHARD
Inflorescence Val Vilaine
Roses de Jeanne Les Ursules
Roses de Jeanne La Haute-Lembl
Roses de Jeanne La Bolore
Roses de Jeanne Le Creux dEnfer Ros de Saigne
DAVID LCLAPART
Cuve l'Aptre
LECLERC-BRIANT
Les Authentiques
Les Chvres Pierreuses
Le Clos des Champions
Les Crayres
La Croisette
La Ravinne
CATTIER
Clos du Moulin
CLAUDE CAZALS
Clos Cazals
CHARTOGNE-TAILLET
Les Barres
Les Orizeaux
A.R. LENOBLE
Les Aventures Blanc de Blancs Grand Cru
MARIE-NOELLE LEDRU
Cuve de Goult
ULYSSE COLLIN
Blanc de Blancs
Blanc de Noirs
NICOLAS MAILLART
Les Chaillots Gillis
Les Francs du Pied
DEHOURS
Lieux-dit Brisefer
Lieux-dit Les Genevraux
HENRI MANDOIS
Les Clos
DRAPPIER
Grande Sendre
Grande Sendre Ros
JEAN MILAN
Les Terres de Nol
DUVAL-LEROY
Authentis Clos des Bouveries
PHILIPPONNAT
Clos des Goisses
Clos des Goisses Juste Ros
EGLY-OURIET
Blanc de Noirs Les Crayeres
Les Vignes de Vrigny
PIERRE PETERS
Cuve Spciale
GONET-MDEVILLE
Ambonnay La Grande Ruelle Extra Brut
JRME PRVOST
Brut Nature La Closerie Les Bguines
JANISSON-BARADON
Spcial Club Les Toulettes Blanc de Blancs
TAITTINGER
Les Folies de la Marquetterie
JACQUESSON
Dizy Corne Bautray
A Vauzelle Terme
Dizy Terres Rouges Ros
Avize Champ Can
TARLANT
Cuve Louis Brut
Cuve La Vigne d'Antan
Cuve La Vigne d'Or
ALAIN THINOT
La Vigne aux Gamins
KRUG
Clos du Mesnil
Clos dAmbonnay
VEUVE FOURNY
Les Clos du Notre Dame
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AUTOLYSIS
BY HERV ALEXANDRE, FRANCE
Champagne or for that matter any sparkling wine made according to the traditional method must ferment successively twice.
The first fermentation transforms grape must into base wine,
but the second fermentation is what really matters: it happens
in the bottle and increases alcoholic content (with 1.2 to 1.3%
abv) as well as internal bottle pressure (up to 5-7 atmospheres).
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THE MYSTERY
OF CHAMPAGNE
Herv Alexandre is professor of Oenology at the
Institut Universitaire de la Vigne et du Vin Jules
Guyot at the University of Burgundy in Dijon,
France, where hes responsible for the Diplme
National dOenologue. He is also rector of the Union
of Oenologists of France. His research focuses on
micro-organisms in wine, yeasts and bacteria.
ethanol. They also need flocculating or agglutinating properties, as well as good autolytic capacity
and an ability to influence foam quality.
THE MECHANISMS
HERV ALEXANDRE
Nucleus
Vacuole
Plasma membrane
b.
Polysaccharides
Lipids
Sugars
Spherical bodies
Proteins and peptides
c.
Ribonucleotide
Figure 1. Schematic representation of the morphological and biochemical changes in yeast during autolysis in sparkling wine.
Immediately after the second alcoholic fermentation (a), between
3 to 6 months (b) and between 9 to 12 months (c).
31
HERV ALEXANDRE
Origin
Compound type
Nucleocide
during autolysis after the release of mannoprotein. The levels of polysaccharides in champagne
increase from 366 mg/L in the base wine to 602
mg/L after nine months of ageing.
Mannoproteins play a key role in the stability
of a wine. They reduce haze formation and prevent
the precipitation of tartaric salts by sticking to the
growth sites of the crystal, thus blocking that very
growth. The effects of macromolecules on foam
quality are enormously important. Material that
precipitates in ethanol has been found among the
compounds present in foam. The optimum ageing time for the best and most stable foam is
roughly 18 months. After 18 months, foam quality decreases. Finally, mannoproteins contribute
to the mouth-feel of champagne, and to the intensity and persistence of its aromas.
Lipids are important components of sparkling
wines because they influence foam stability.
During the second fermentation, the lipid content increases. After bottle ageing in contact with
yeasts, the lipid content increases further.
Nucleotides are the result of the breakdown of
DNA during autolysis. Although there are no
definitive studies on this, nucleotides are thought
to be flavour compounds.
But the most important compounds released
during autolysis that affect the aromas of champagne are arguably volatile and have until now
been less well studied than non-aroma compounds. Most of these volatile compounds are
released after four to six months, with esters the
predominating family. Short chain (C3-C4) and
medium chain (C6-C12) acyl esters with characteristic fruity odours appear at the beginning of
autolysis and then decrease. Long chain acyl
esters have also been identified, as well as the
release of terpenic alcohols and higher alcohols.
Geraniol, a-terpineol (smelling like lilac), citronellol and farnesol (anis, jasmine and roses)
have all been identified. These compounds have
low perception levels ranging from 100 to 300
g/L. Farnesol and nerolidol (woody) are thought
to contribute greatly to champagnes aromatic
quality. Among the higher alcohols, the rapid formation of isoamyl alcohol and 2-phenylethanol
(roses) is important.
About 10 aldehydes with a grassy odour that
negatively affect the aromatic profile have been
measured and identified, although most disappear
during ageing.
Descriptive analysis is another way of characterising the effect of the traditional method on
aroma. Changes in aroma during the production
Flavouring agent
Nucleotide
Cell content
Amino acid
Aroma precursors
Peptide
Foam quality
Protein
Protein
Foam quality
Lipids
Foam quality
Glucan
Foam quality
Mannoprotein
Increase in mouthfeel
Cell wall
Table 1. The origin of different compounds released during yeast autolysis and their proven or potential impact on sparkling wine.
TONG N 4
The study of autolysis has been extensive, yet several questions remain to be answered. For example,
it is not known whether there is a similarity in the
autolysis of yeast following the musts fermentation and of yeast after the wines fermentation,
as with champagne. Analytical studies of wine,
and particularly sparkling wine, have given us a
clear picture of the different compounds released
during autolysis. But we still dont know the molecular mechanisms responsible for the induction
of autolysis.
Last but not least, and essential in a discussion
of champagne aromatics, the yeast origin of many
aroma compounds, like the typically biscuity or
toast-like odours of long-aged champagne, is not
clear and needs scientific proof. The volatile compounds characteristic of a long-aged champagne
may also be found in still wine that has not been
aged on yeast lees. The impact of these compounds
on the physical and organoleptic properties of
sparkling wine is also poorly understood. Many
changes occur during autolysis, making it difficult
to attribute a specific compound to specific aromatic changes. We are still unsure as to which
components formed or released during ageing are
odour-active compounds. Therefore, the effect of
yeast autolysis on the aromatic properties of
sparkling wine should be re-evaluated using techniques such as gas chromatography-olfactometry
complemented with sensory descriptive analysis.
To say that the complex aromas in long-aged
champagne come directly from autolysis is wrong.
Toasty and biscuity aromas are much more likely
to be linked to oxidative ageing in the bottle
after disgorgement and to the Maillard reaction
between amino acids and the sugars from the
liqueur dexpdition in the champagne. The Maillard
reaction causes ripe burnt sugar-like, honeyed and
toasty aromas.
In fact, autolysis inhibits oxidation because
of the release of the reducing enzymes from the
dead yeast cells. In that way, dead yeast cells not
34
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THE
SCIENCE
BEHIND
THE
BUBBLES
BY GRARD LIGER-BELAIR, RGIS GOUGEON & PHILIPPE SCHMITT-KOPPLIN, FRANCE & GERMANY
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EVER SINCE THE DAYS OF BENEDICTINE MONK DOM PIERRE PRIGNON (1638-1715),
ITS ELEGANT EFFERVESCENCE HAS MADE IT A CELEBRATORY WINE. IN CHAMPAGNE
WINES AS IN ALL SPARKLING WINES, EXCESS CARBON DIOXIDE MOLECULES FORM AS
A BY-PRODUCT OF ALCOHOLIC FERMENTATION. AS SOON AS YOU UNCORK A BOTTLE
OF CHAMPAGNE, THE PROGRESSIVE RELEASE OF CO 2-DISSOLVED GAS MOLECULES
CAUSES BUBBLE NUCLEATION, KNOWN AS THE EFFERVESCENCE PROCESS.
Approximately 5 litres of CO2 escape from a typical 0.75 litre champagne bottle. For an idea of
how many bubbles are involved in the degassing
process, divide the volume of CO2 to be released
by the average volume of a typical bubble - 0.5 mm
diameter. The resulting number is close to 108.
Critics judge the quality of a particular champagne by the way its bubbles behave, among other
things. Small bubbles that rise slowly through the
liquid are usually considered much more desirable
than larger bubbles. The aspect of the foam ring
on the liquid surface, the so-called collerette, is
caused by the bubbles in the glass another
important feature of champagne. And yet it is
only quite recently that the tools of physical
chemistry have been used to identify the physicochemical mechanisms behind nucleation, and the
rise and collapse of bubbles in champagne and
other sparkling wines.
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jectories in the champagne bulk.) Fliers are a significant source of bubbles in glasses poured with champagne. The photograph of a typical flute filled with
champagne displayed in Figure 3a shows a detail
in Figure 3b, in which you can identify some fliers.
BUBBLE NUCLEATION
a.
b.
BUBBLE RISE
After their birth on cellulose debris, it is buoyancy that brings the bubbles to the liquid surface. As
they rise, they go on developing by continuously
absorbing the carbon dioxide molecules dissolved
in the liquid matrix. Bubbles thus steadily accelerate along their way through the champagne.
High-speed photographs show this acceleration in
the steadily increasing space between the bubbles of a particular bubble train (see Figure 4.)
Tasters of champagne and sparkling wine are
traditionally concerned with the size of the bubbles (there is a saying that the smaller the bubbles, the better the wine), which explains why
so much attention is devoted to modelling the
average size of ascending bubbles. Recent calculations have shown that the final average size of
ascending bubbles is however the result of a hugely complex interplay between several parameters.
Flutes that have been towel-dried just before serving display an excess of bubble nucleation sites,
and thus an excess of effervescence. Some of the
particles that act as bubble nucleation sites (most
of them including cellulose fibres) may detach
themselves from the glass wall to eventually
immerse themselves into the rest of the champagne. Yet these particles remain active (in terms
of bubbling capacity), provided a gas pocket with
a radius of curvature larger than the critical radius
has been trapped within them. These particles
immersed in the champagne bulk produce those
easily-recognisable bubble trains, which seem to
dance erratically inside the glass while you taste the
champagne. These suspended particles are called
fliers (due to their often complex and circling tra-
Figure 6. A few seconds after pouring and the collapse of the foamy head,
the surface of a champagne flute is covered with a layer of bubbles
approximately arranged in a hexagonal pattern that strikingly resembles beeswax ( Grard Liger-Belair).
A PATERNOSTER OF AROMAS
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CHAMPAGNE EXPERIMENT
A QUEST
FOR
THE BEST
BY PASCAL AGRAPART, FRANCE
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I PRODUCE SIX CHAMPAGNES THAT ARE RICH IN STYLE FOR THREE REASONS. FIRSTLY,
THE BASE WINES ARE GIVEN A MALOLACTIC FERMENTATION; SECONDLY, THEIR VINIFICATION IS PARTLY DONE IN 600-LITRE OAK BARRELS; AND THIRDLY, THE BASE WINES
ARE MATURED FOR ONE LONG YEAR BEFORE THEY ARE TRANSFORMED INTO CHAMPAGNE.
PASCAL AGRAPART
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