Crystal Structure and Mineral Classes: GY 111 Lecture Note Series

GY 111 Lecture Notes
D. Haywick (2007-08)
GY 111 Lecture Note Series

Crystal Structure and Mineral Classes
Lecture Goals:
A) Mineral Classes
B) The silicates
Reference: Press et al. (2003), Chapter 3; Grotzinger et al. (2007) Chapter 3
A) Mineral classes
If this were a class in mineralogy, we would be spending a few weeks discussing the way
minerals are classified by geologists. Since it is not, we'll spend about 15 minutes.
Most minerals are classified according to their chemical compositions, specifically the
anionic components of their formulas. The one exception are native elements such as
gold, silver etc. Geologists recognize 8 classes of minerals based upon the composition of
the anion that characterizes them.
Class
II
III
IV
V
VI
VII
VIII
Name
Native Elements
Sulfides
Oxides\hydroxides
Halides
Carbonates
Sulfates
Phosphates
Silicates
Anion(s)
none
SO2- OHCl-, FlCO32SO42PO43SiO44-
Examples
Metals: Gold, Copper, Silver
Semi-metals: Arsenic (As)
Non-metals: diamond, graphite,
sulfur
Pyrite, Chalcopyrite, Galena
hematite, magnetite, limonite
halite, fluorite
calcite, aragonite, malachite
gypsum, anhydrite
apatite
>3000 (i.e., most minerals)
Dominant
Bond
Metallic
Covalent
Largely
Ionic
The way that minerals are classified is rather good for geologists interested in economics or, as I
like to say, $$$. For example, many of the sulfides are valuable to our economy (hence the
concept of economic minerals). Zinc, lead, nickel, copper molybdenum and many more metals
are obtained from sulfide ores. Iron oxides are the principle ores for iron and steel. Gold, silver,
platinum and carbon (as both diamonds and graphite) are obtained as native elements. These are
not the only economic minerals. Calcite, fluorite, gypsum and dozens of others are all used by
industry. In fact, you use many of them on a daily basis.
In the labs, you will see examples of many more minerals and learn more about their
economic potential. Their chemical composition will give you some clues about how they
are classified. See how many that you can sort out.
The silicates contain most of the minerals that have been identified. Not surprisingly
then, there is a need to sub divide Class VIII into many more divisions. This will occupy
the remaining time in todays class. Get ready to draw
B) The Silicates:
Wow where do we start? All silicate minerals contain a basic building unit called the
silicate tetrahedron:
In order to simplify my drawings, I'll use the triangular symbols adjacent to the 3D
tetrahedron. I'll explain more about this in class.
The silicates are divided up into 6 subclasses depending upon how the silicate
tetrahedrons are arranged. As in our discussion about unit cells, some ions (in this case
O2-) are shared between tetrahedrons. The number of O2- ions shared and the
arrangement of the resulting structure are the factors that determine which subclass each
silicate mineral belongs to.
1) Free silicate tetrahedra (0 shared O2- ions):
Name:
Nesosilicates
Examples:
Garnet Group; e.g.; Pyrope Mg3Al2Si3O12

Olivine Group; e.g., Fayalite: Fe2SiO4;
Forsterite: Mg2SiO4
2) 1 shared O2- ion:

Name:
Sorosilicates
Examples:
Epidote (you will not see this in the lab)
3) 2 shared O2- ions

Name:
Cyclosilicates
Examples:
Beryl/emerald (you
will not see this in the lab)
4) 2 or 2 1/2 shared O2- ions:

Name:
Inosilicates (Chain silicates)
2 -shared (Pyroxene Group)
Examples:
Augite
2 1/2 shared (Amphibole Group)

Hornblende
5) 3 shared O2- ions:

Name:
Phyllosilicates (Sheet silicates)
Examples:
Mica Group, e.g., muscovite, biotite, chlorite;
Clay Group, e.g., kaolinite
6) 4 shared O2- ions (i.e.,

all of them):
Name: Tectosilicates
(Framework silicates)
Examples:
Quartz
Feldspars
e.g., orthoclase, Plagioclase
If my sketches do not work for you, try out these representations:
From Klein, C. and Hurlbut Jr., C.S. 1977. Manual of Mineralogy. John Wiley and Sons. 681p.
From Klein, C. and Hurlbut Jr., C.S. 1977. Manual of Mineralogy. John Wiley and Sons. 681p
Be sure to also refer to the handout (http://www.usouthal.edu/geography/haywick/PDF/silicate.pdf) that I gave

you in class about silicate structures. It has a lot of formulas on it (which you do NOT
have to know for GY 111), but it also shows how well the silicate minerals group
together. Would you like to see some 3D images of the silicates we have discussed today;
check these out:
Garnet (Nesosilicate)
Olivine (Nesosilicate)
Beryl/Emerald (Cyclosilicate)
Biotite (Phyllosilicate)
Quartz (Tektosilicate)
Important terms/concepts from todays lecture

(Google any terms that you are not familiar with)
silicate tetrahedron (SiO44-)
mineral classes (native metals, sulfides, oxides/hydroxides, halides, carbonates, sulfates,
phosphates, silicates)
silicate subclasses (nesosilicates, sorosilicates, cyclosilicates, inosilicates, phyllosilicates,
tektosilicates)
amphibole group
pyroxene group
olivine group
plagioclase group
feldspar group

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GY 111 Lecture Notes

GY 111 Lecture Note Series

SO2- OHCl-, FlCO32SO42PO43SiO44-

GY 111 Lecture Notes

Garnet Group; e.g.; Pyrope Mg3Al2Si3O12

2) 1 shared O2- ion:

Epidote (you will not see this in the lab)

3) 2 shared O2- ions

GY 111 Lecture Notes

4) 2 or 2 1/2 shared O2- ions:

2 1/2 shared (Amphibole Group)

5) 3 shared O2- ions:

6) 4 shared O2- ions (i.e.,

GY 111 Lecture Notes

If my sketches do not work for you, try out these representations:

GY 111 Lecture Notes

GY 111 Lecture Notes

Be sure to also refer to the handout (http://www.usouthal.edu/geography/haywick/PDF/silicate.pdf) that I gave

GY 111 Lecture Notes

Important terms/concepts from todays lecture

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