soll90%:Pocket card

14.04.2008

14:40 Uhr

Seite 1

BASF SE
Care Chemicals & Formulators Europe
67056 Ludwigshafen, Germany.
Email: [email protected]
www.care-chemicals-formulators.basf.com
BASF East Asia
Regional Headquarters Ltd
45/F, Jardine House, 1 Connaught Place Central, Hong Kong
Tel: +852 2731 1222
Fax: +852 2734 9631
www.basf.com.sg
BASF S.A.
Av. Faria Lima, 3600/3624
04538-132 So Paulo SP, Brazil
Tel: +55 11 3043-2233
Fax: +55 11 3043-6989
www.basf.com.br

Note:

Protectol BN

Protectol BN 18

Protectol BN 30

Protectol GA 24

Protectol GA 50

Protectol PE / PE S

Protectol PP

Protectol HT

Chemical Name

2-Bromo-2nitropropane-1,3-diol

2-Bromo-2nitropropane-1,3-diol

2-Bromo-2nitropropane-1,3-diol

1,5-Pentanedial

1,5-Pentanedial

Phenoxyethanol

1-Phenoxy-2-propanol
2-Phenoxy-1-propanol

1,3,5-tris(2-hydroxyethyl)-1,3,5hexahydrotriazine

Name using IUPAC

guidelines

2-Bromo-2-nitro-1,3propanediol

2-Bromo-2-nitro-1,3propanediol

2-Bromo-2-nitro-1,3propanediol

Pentanedial

Pentanedial

2-Phenoxyethanol

1-Phenoxy-2-propanol /
2-Phenoxy-1-propanol

Common Name
(Active Ingredient)

Bronopol

Bronopol

Bronopol

Glutaraldehyde

Glutaraldehyde

Phenoxyethanol

CAS Number
(Active Ingredient)

52-51-7

52-51-7

52-51-7

111-30-8

111-30-8

EINECS Number
(Active Ingredient)

200-143-0

200-143-0

200-143-0

203-856-5

Mol. Formula
(Active Ingredient)

C3H6BrNO4

C3H6BrNO4

C3H6BrNO4

Molar Mass
(Active Ingredient)

200.0

200.0

200.0

Physical form

Solid

Liquid

Liquid

Liquid

Liquid

Liquid

Appearance

White to
almost white

Clear to
practically clear
colourless to yellow

Clear colourless

Clear to
practically clear
colourless to yellow

Clear to
practically clear
colourless to yellow

Clear to
practically clear
colourless

Concentration (% w/w)

min. 99.0

16.8 to 19.5

28.5 to 31.5

23.5 to 24.5

50.0 to 51.0

min 99.5

Solubility (in water @ 23C)

28%

Unlimited

Unlimited

Unlimited
3 to 4
(Undiluted)

Unlimited

2.4%
approx. 7
(0.1% in water)

1.06

1.13

1.11

The information contained in this document is not necessarily valid for

the North American region where special regulations may apply.
A separate leaflet describing BASFs North American biocide product
range is available on request.
The data contained in this publication are based on our current
knowledge and experience. In view of the many factors that may
affect processing and application of our product, these data do not
relieve processors from carrying out their own investigations and tests;
neither do these data imply any guarantee of certain properties, nor
the suitability of the product for a specific purpose. Any descriptions,
drawings, photographs, data, proportions, weights etc. given herein
may change without prior information and do not constitute the agreed
contractual quality of the product. It is the responsibility of the recipient
of our products to ensure that any proprietary rights and existing laws
and legislation are observed.
FK/EVD 556e August 2007
Supersedes FK/ES 556e dated July 2004
= registered trademark of BASF

BASF plc Biocides

Mere Way, Ruddington, Nottingham, NG11 6JS, England
Tel: +44 (0)115 912 4586
Fax: +44 (0)115 912 4592
www.care-chemicals-formulators.basf.com
BTC Speciality Chemicals Distribution GmbH
Maarweg 163/165
50825 Kln, Germany
Tel: +49 221 9 54 64-0
www.btc-de.com

pH
(1% solution in water)
Density @ 20C [g/cm3]
Bulk density [g/l]

max 4.5

2.5 to 4.5

1.10

1.20

Protectol GL

Protectol DF

Protectol DA

Protectol DZ

Protectol DB

Protectol KD

Chemical Name

Tetrahydro-1,3,4,6tetrakis(hydroxymethyl)
imidazo[4,5-d]imidazole

Glyoxal

2,5-Dimethoxy
tetrahydrofuran

2,4-Dichlorobenzyl
alcohol

3,5-Dimethyl-1,3,5thiadiazinane-2-thione

2,2-Dibromo-2cyanoacetamide

N-cyclohexyl-diazenium
dioxide, potassium salt

Formic Acid

Formic Acid

1,3,5-Triazine1,3,5(2H,4H,6H)triethanol

Name using IUPAC

guidelines

Tetrahydro-1,3,4,6 tetrakis
(hydroxymethyl) imidazo[4,5d]imidazole-2,5(1H,3H)-dione

1,2-Ethanedial

Tetrahydro-2,5dimethoxyfuran

2,4-Dichlorobenzenemethanol

Tetrahydro-3,5dimethyl-2H-1,3,5thiadiazine-2-thione

2,2-Dibromo-3nitrilopropionamide

N'-HydroxyN-cyclohexyl-diazenium
oxide, potassium salt

Methanoic Acid

Methanoic Acid

Phenoxypropanol

Triazine

Common Name(s)
(Active Component)

Tetramethylolacetylene diurea

Glyoxal

2,5-Dimethoxy
tetrahydrofuran

Dichlorobenzyl alcohol
(DCBA)

Dazomet

Dibromonitrilopropionamide (DBNPA)

Potassium HDO
(K-HDO)

Formic Acid

Formic Acid

122-99-6

770-35-4
4169-04-4

4719-04-4

CAS Number
(Active Component)

5395-50-6

107-22-2

696-59-3

1777-82-8

533-74-4

10222-01-2

66603-10-9

64-18-6

64-18-6

203-856-5

204-589-7

212-222-7
224-027-4

225-208-0

EINECS Number
(Active Component)

226-408-0

203-474-9

211-797-1

217-210-5

208-576-7

233-537

248-617-6

200-597-1

200-597-1

C5H8O2

C5H8O2

C8H10O2

C9H12O2

C9H21N3O3

Mol. Formula
(Active Component)

C8H14N4O6

C2H2O2

C6H12O3

C7H6CI2O

C5H10N2S2

C3H2Br2N2O

C6H11N2O2- K+

100.11

100.11

138.17

152.2

219.00

Molar Mass
(Active Component)

262.0

58.0

132.0

177.0

162.3

242

183

Liquid

Liquid

Physical form

Liquid

Liquid

Liquid

Solid

Solid

Solid

Liquid

Clear to
practically clear
colourless

Clear to
practically clear
colourless

Appearance

Clear to
practically clear
colourless to yellow

Clear to
practically clear
colourless

Clear to
practically clear
colourless

White to almost white

slightly lumpy

Off-white free flowing

granules

White to off white

Tan

min 99.0

74.0 to 78.0

Concentration (% w/w)

45.0 to 49.0

39.5 to 40.5

min. 99.0

min. 98.0

min. 99.0

min. 99.0

29.0 to 31.0

1.2%

Unlimited
approx. 10
(0.2% in water)

Solubility (in water @ 23C)

Unlimited

1.5%

Unlimited

Unlimited

Unlimited

6.5 to 7.5

Partly
approx. 5
(30% in water)

0.36%

pH
(1% solution in water)

Unlimited
2 to 3.5
(Undiluted)

Sparingly

approx. 7
(0.8% in water)

N/A

approx. 7.0

6.6

10.5

2.2

2.2

1.06

1.15

Density @ 20C [g/cm3]

Bulk density [g/l]

1.27

1.02

1.13

1.195

1.22

500

450

934 - 1370

3.7

1100

1.21

Protectol FM 99

CH2O2
46.0
Liquid
Colourless to yellow
min. 85%

CH2O2
46.0
Liquid
Colourless to yellow
min. 99%

3 years

2 years

2 years

1 year***

1 year***

2 years

1 year

1 year

Shelf life when stored in

sealed containers /
Ambient temperature

1 year

6 months

1.5 years

5 years

5 years

2 years

2 years

2 years

2 years

Log POW
(Active Ingredient)

0.18

0.18

0.18

-0.22

-0.22

1.12

1.5

-1.21

Log POW
(Active Ingredient)

N/A

-2.54

N/A

N/A

N/A

6.31

-0.2

-1.9

-0.54

Antibacterial activity
(Typical M.I.C.)

12.5 to 25ppm*

12.5 to 25ppm*

12.5 to 25ppm*

50 to 1250ppm**

50 to 1250ppm**

3200 to 15000ppm*

5000 to 10000ppm*

500 to 1000ppm*

Antibacterial activity
(Typical M.I.C.)

approx. 1000ppm*

2500 to 5000ppm*

approx. 2500ppm*

500 to 2000ppm*

2 to 375ppm*

7.8 to 62.5ppm*

12.5 to 3200ppm*

400 to 6400ppm*

400 to 6400ppm*

400 to 6400ppm*

250 to 1250ppm**

250 to 1250ppm**

600 to 3200ppm*

approx. 7500ppm*

500 to 1000ppm*

approx. 5000ppm*

N/A

approx. 500ppm*

62.5 to 500ppm*

47 to 375ppm*

62.5 to 125ppm*

12.5 to 50ppm*

800 to 80000ppm

800 to 80000ppm

2 to 9

2 to 9

2 to 9

3 to 8

3 to 8

2 to 10

2 to 10

2 to 9

Antifungal activity
(Typical M.I.C.)
Typical use pH range

2 to 8

3 to 8

2 to 6

2 to 10

7 to 9

<6

<6

R22, R38, R41

R22, R38, R41

R20/22, R34, R42/43

R23/25, R34, R42/43

R22, R36

R36

R22, R36, R43

Risk Phrases

R40/43

R20, R36/38, R40/43

R10, R20, R36

R41

R22, R36

7 to 8.5
R23/25, R41, R38,
R43, R50

5.5 to 11.5

R21/22, R37/38,
R41, R50

R25, R36/38

R34

R35

Risk Phrases

M.I.C. data was generated using in-house methodology figures are based on active ingredient.
** M.I.C. data was generated using in-house methodology figures based on 50% Glutaraldehyde solution.
*** When stored below room temperature.

M.I.C. data was generated using in-house

methodology - figures are based on active
ingredient.

** M.I.C. data was generated using in-house methodology figures are based on actual product.

CIPAC method 183.

Literature values based on active ingredient.

Protectol
Biocides

Shelf life when stored in

sealed containers /
Ambient temperature

Antifungal activity
(Typical M.I.C.)
Typical use pH range

5.0 to 7.0

Protectol FM 85

Protectol TD

700 to 7500ppm

700 to 7500ppm

Folding card _1_soll90%:Pocket card

14.04.2008

12:38 Uhr

Seite 2

BASF is one of the worlds leading

suppliers of speciality biocides.
As part of the Care Chemicals & Formulators
division, the biocide group provides
marketing, regulatory and global technical
services to support the sale of biocides via
BASFs network of international sales offices
and the BTC Speciality Chemical distribution
organisation in Europe. Regional marketing
centres are also established in NAFTA,
South America and Asia.

BASF offers a strong and effective range of biocidal active ingredients

marketed under the Protectol trade name. These biocides can
be formulated to add value to a wide range of industrial and
consumer products and processes through the control of harmful
and unwanted micro-organisms. With our technical expertise and
application know-how, our biocides can preserve, protect,
enhance performance and improve process efficiency.

Application areas
Household & Personal Care
In personal care and household products our antimicrobial
chemistries and preservatives offer high performance, cost
effective solutions. They ensure that the final products are
protected from contamination and are safe to use on the skin
whilst maintaining product stability and compatibility.
Pulp & Paper
In paper making, our biocides are used to control slime build-up
in the process water. This ensures that the paper mill machinery
runs efficiently and the subsequent finished paper is free from
contamination and spoilage. In addition, we supply specialised
products to protect water-based mill additives such as starch,
pigments, sizes and mineral slurries.
Odour Control & Chemical Sanitation
Our biocides control odour in portable toilet fluids, animal litter
formulations and many other niche applications. Our products
are chosen for their excellent biocidal activity and ability to help
control the generation of noxious and unpleasant odours.
Superior biodegradability of our biocides also minimises
environmental impact.
Disinfection
We offer fast acting, effective biocidal ingredients used in the
formulation of disinfection and sanitizer products for hard
surfaces, medical instruments, cleaners and animal husbandry
applications.
Metal Working Fluids
Our biocides are easily incorporated into all types of metal
working fluid concentrates. They are extremely effective at
controlling microorganisms within the diluted matrix helping to
prevent malodours and fluid degradation. In addition, fluids can
enjoy secondary benefits such as enhanced solvent properties
and extended buffering.

Industrial Product Pres

In this wide-ranging appl

performance when used
other actives. Applications
paints, polymer dispersio
caulks, sealants and man
can also be used in leath
skins from blemishes cau
include formulations sold
and free from bacterial c
Oilfield

In oilfield applications BA
muds, injection waters, f
are often added to produ
spoilage within the oil rec
and corrosion caused by
Water Treatment

In water treatment applica

biofouling and to control m
of potentially pathogenic
Specific applications inclu
water, air washers and hu
exchangers, condensers

The Business Unit Care C

Surfactants
Water soluble polymers
Chelating agents
Waxes and wax emulsi
Electroplating and elec

soll90%:Pocket card

14.04.2008

14:40 Uhr

Seite 2

BASF is one of the worlds leading

suppliers of speciality biocides.
As part of the Care Chemicals & Formulators
division, the biocide group provides
marketing, regulatory and global technical
services to support the sale of biocides via
BASFs network of international sales offices
and the BTC Speciality Chemical distribution
organisation in Europe. Regional marketing
centres are also established in NAFTA,
South America and Asia.

BASF offers a strong and effective range of biocidal active ingredients

marketed under the Protectol trade name. These biocides can
be formulated to add value to a wide range of industrial and
consumer products and processes through the control of harmful
and unwanted micro-organisms. With our technical expertise and
application know-how, our biocides can preserve, protect,
enhance performance and improve process efficiency.

Application areas
Household & Personal Care
In personal care and household products our antimicrobial
chemistries and preservatives offer high performance, cost
effective solutions. They ensure that the final products are
protected from contamination and are safe to use on the skin
whilst maintaining product stability and compatibility.
Pulp & Paper
In paper making, our biocides are used to control slime build-up
in the process water. This ensures that the paper mill machinery
runs efficiently and the subsequent finished paper is free from
contamination and spoilage. In addition, we supply specialised
products to protect water-based mill additives such as starch,
pigments, sizes and mineral slurries.
Odour Control & Chemical Sanitation
Our biocides control odour in portable toilet fluids, animal litter
formulations and many other niche applications. Our products
are chosen for their excellent biocidal activity and ability to help
control the generation of noxious and unpleasant odours.
Superior biodegradability of our biocides also minimises
environmental impact.
Disinfection
We offer fast acting, effective biocidal ingredients used in the
formulation of disinfection and sanitizer products for hard
surfaces, medical instruments, cleaners and animal husbandry
applications.
Metal Working Fluids
Our biocides are easily incorporated into all types of metal
working fluid concentrates. They are extremely effective at
controlling microorganisms within the diluted matrix helping to
prevent malodours and fluid degradation. In addition, fluids can
enjoy secondary benefits such as enhanced solvent properties
and extended buffering.

Industrial Product Preservation

In this wide-ranging application area our products offer biocidal
performance when used either alone or in combination with
other actives. Applications include the preservation of water-based
paints, polymer dispersions, inks, fountain solutions, adhesives,
caulks, sealants and many other industrial fluids. Our biocides
can also be used in leather soak liquors to protect hides and
skins from blemishes caused by bacterial attack. Further uses
include formulations sold with cut flowers to keep them fresh
and free from bacterial contamination.
Oilfield
In oilfield applications BASFs biocides can be used in drilling
muds, injection waters, fracturing and completion fluids. They
are often added to production waters to prevent microbial
spoilage within the oil recovery process and to control souring
and corrosion caused by sulphate reducing bacteria.

Household &
Personal Care

Protectol BN
Protectol BN 18
Protectol BN 30

Protectol GA 24
Protectol GA 50

Protectol PE
Protectol PE S

Protectol PP

Pulp &
Paper

Odour Control
& Chemical
Sanitation

Industrial
Product
Preservation

Disinfection

Water
Treatment

Oilfield

Metal
Working
Fluids

Protectol GL
Water Treatment
In water treatment applications our biocides are used to reduce
biofouling and to control microbial contamination and the spread
of potentially pathogenic micro-organisms such as Legionella spp.
Specific applications include industrial process water, cooling
water, air washers and humidifiers, air conditioning units, heat
exchangers, condensers and pasteurizers.

Protectol HT

The Business Unit Care Chemicals & Formulators also offers:

Protectol DZ

Surfactants
Water soluble polymers
Chelating agents
Waxes and wax emulsions
Electroplating and electronics chemicals

Protectol BN / Protectol BN 18 / Protectol BN 30

Bronopol does not accumulate in the environment and has
been shown to be inherently biodegradable. Under normal use
conditions, Bronopol will not cause problems either to effluent
treatment plants or to the environment following discharge into
wastewater. Bronopol is toxic to algae and daphnia but less
toxic to fish. The log POW is low, indicating that Bronopol has a
low potential to bioaccumulate. In the E.U., Bronopol is
classified as dangerous for the environment (R50).

Environmental Profile

Protectol GA 24 / Protectol GA 50
Glutaraldehyde has been shown to be readily biodegradable
and has a low potential to bioaccumulate. Under normal use
conditions, Glutaraldehyde will not cause problems either to
effluent treatment plants or to the environment following
discharge into wastewater. Glutaraldehyde is harmful to fish
and daphnia but is very toxic to algae.
Protectol DA

Protectol TD

2,4-Dichlorobenzyl alcohol is of low to moderate acute toxicity

to daphnia and fish and is of low acute toxicity to birds.
2,4-Dichlorobenzyl alcohol is not classified as dangerous to
the aquatic environment.

Protectol DF

Protectol DA

Protectol KD
Protectol FM 85
Protectol FM 99

Aseptrol

Dazomet is readily biodegradable. Under normal use conditions,

Dazomet will not cause problems either to effluent treatment
plants or to the environment following discharge into wastewater.
Dazomet has, however, been shown to be very toxic to fish and
daphnia but is less toxic to algae.

Protectol DB

Protectol DZ

When used as recommended, tetramethylolacetylene diurea will

cause no inhibition of activated sludge in sewage treatment plants.

Protectol TD

Protectol PE / Protectol PE S

Protectol DB

Aseptrol Chlorine Dioxide Technology

Phenoxyethanol is readily biodegradable. Experience gained in

running effluents into adapted biological treatment plants has
shown that concentrations of up to 1000mg/l are unlikely to
disturb the efficacy of activated sludge. Phenoxyethanol is of a
low acute toxicity to fish and daphnia.

Dibromonitrilopropionamide generally hydrolyses rapidly in water

through aerobic and anaerobic metabolism. It is of moderate
toxicity to terrestrial mammals and birds if they are exposed
orally to concentrated doses but under usual circumstances,
dietary toxicity to birds is low. Without any mitigation measures,
DBNPA poses a high risk to aquatic organisms. In the E.U., it is
classified as dangerous for the environment with risk phrase; R50
- very toxic to aquatic organisms.

Aseptrol products are a new addition to BASFs biocide range

and feature a unique and patented technology, which enables
the controlled release of chlorine dioxide into air or water from
a powder, dissolving tablet or sachet. Aseptrol products are
specially engineered with proprietary activators that combine
with chlorite salt to generate chlorine dioxide gas at precise
rates and in controlled concentrations, whenever in contact
with water or moisture in the air.

Protectol KD

Aseptrol products can be used to control a broad range of

microorganisms, viruses, spores, protozoan cysts and biofilm
deposits in several applications. Typical examples include hard
surface, dental, hospital and animal house disinfection, industrial
cooling water, odour control, pools, spas and emergency
drinking water.

Protectol PP
Phenoxypropanol is biodegradable. Experience gained in running
effluents into adapted biological treatment plants has shown that
concentrations of up to 2000mg/l are unlikely to disturb the
efficacy of activated sludge. Phenoxypropanol is of low toxicity to
fish and daphnia but it is harmful to algae. Phenoxypropanol is not
likely to bioaccumulate due to a low log POW.

N-cyclohexyl-diazenium dioxide, potassium salt, is readily

eliminated from water. Under normal use conditions, inhibition
of degradation activity in activated sludge is not expected when
the product is correctly introduced at low concentrations.

Protectol HT
1,3,5-Tris-(2-hydroxyethyl)-1,3,5-hexahydrotriazine is readily
biodegradable. However, under normal use conditions, the
product should not be discharged into waterways without prior
treatment.1,3,5-Tris-(2-hydroxyethyl)-1,3,5-hexahydrotriazine is
harmful to fish and daphnids.

Protectol FM 85 / Protectol FM 99
Formic acid is readily biodegradable. Under normal use conditions,
inhibition of degradation activity in activated sludge is not
expected when the product is correctly introduced at low
concentrations. Because of a low log POW value, bioaccumulation
in organisms is not expected.

Protectol DF
Dimethoxytetrahydrofuran is moderately biodegradable. Under
normal use conditions, inhibition of degradation activity in
activated sludge is not expected when the product is correctly
introduced at low concentrations. In acute studies,
Dimethoxytetrahydrofuran is not harmful to fish.
Protectol GL
Glyoxal is readily biodegradable. Effluent discharge into sewage
treatment plants has shown that concentrations of up to
1000mg/l are unlikely to disturb the efficacy of activated sludge.
In acute studies, Glyoxal is not hazardous to algae, daphnia or
fish. A low octanol / water coefficient also indicates a low
potential to bioaccumulate.

Labelling
Details about the classification and labelling of our products
and further advice on safe handling are contained in the current
safety data sheets.
Note according to the European Biocidal Products Directive
98/8/EC:
Use biocides safely. Always read the label and product
information before use.
Responsible Care
We will manage all aspects of our activities so that we provide a
high level of protection for the health and safety of employees
and associates, customers, the public and the environment.

For further information on our Aseptrol products and

technology, please contact your BASF sales representative.

soll90%:Pocket card

14.04.2008

14:40 Uhr

Seite 2

BASF is one of the worlds leading

suppliers of speciality biocides.
As part of the Care Chemicals & Formulators
division, the biocide group provides
marketing, regulatory and global technical
services to support the sale of biocides via
BASFs network of international sales offices
and the BTC Speciality Chemical distribution
organisation in Europe. Regional marketing
centres are also established in NAFTA,
South America and Asia.

BASF offers a strong and effective range of biocidal active ingredients

marketed under the Protectol trade name. These biocides can
be formulated to add value to a wide range of industrial and
consumer products and processes through the control of harmful
and unwanted micro-organisms. With our technical expertise and
application know-how, our biocides can preserve, protect,
enhance performance and improve process efficiency.

Application areas
Household & Personal Care
In personal care and household products our antimicrobial
chemistries and preservatives offer high performance, cost
effective solutions. They ensure that the final products are
protected from contamination and are safe to use on the skin
whilst maintaining product stability and compatibility.
Pulp & Paper
In paper making, our biocides are used to control slime build-up
in the process water. This ensures that the paper mill machinery
runs efficiently and the subsequent finished paper is free from
contamination and spoilage. In addition, we supply specialised
products to protect water-based mill additives such as starch,
pigments, sizes and mineral slurries.
Odour Control & Chemical Sanitation
Our biocides control odour in portable toilet fluids, animal litter
formulations and many other niche applications. Our products
are chosen for their excellent biocidal activity and ability to help
control the generation of noxious and unpleasant odours.
Superior biodegradability of our biocides also minimises
environmental impact.
Disinfection
We offer fast acting, effective biocidal ingredients used in the
formulation of disinfection and sanitizer products for hard
surfaces, medical instruments, cleaners and animal husbandry
applications.
Metal Working Fluids
Our biocides are easily incorporated into all types of metal
working fluid concentrates. They are extremely effective at
controlling microorganisms within the diluted matrix helping to
prevent malodours and fluid degradation. In addition, fluids can
enjoy secondary benefits such as enhanced solvent properties
and extended buffering.

Industrial Product Preservation

In this wide-ranging application area our products offer biocidal
performance when used either alone or in combination with
other actives. Applications include the preservation of water-based
paints, polymer dispersions, inks, fountain solutions, adhesives,
caulks, sealants and many other industrial fluids. Our biocides
can also be used in leather soak liquors to protect hides and
skins from blemishes caused by bacterial attack. Further uses
include formulations sold with cut flowers to keep them fresh
and free from bacterial contamination.
Oilfield
In oilfield applications BASFs biocides can be used in drilling
muds, injection waters, fracturing and completion fluids. They
are often added to production waters to prevent microbial
spoilage within the oil recovery process and to control souring
and corrosion caused by sulphate reducing bacteria.

Household &
Personal Care

Protectol BN
Protectol BN 18
Protectol BN 30

Protectol GA 24
Protectol GA 50

Protectol PE
Protectol PE S

Protectol PP

Pulp &
Paper

Odour Control
& Chemical
Sanitation

Industrial
Product
Preservation

Disinfection

Water
Treatment

Oilfield

Metal
Working
Fluids

Protectol GL
Water Treatment
In water treatment applications our biocides are used to reduce
biofouling and to control microbial contamination and the spread
of potentially pathogenic micro-organisms such as Legionella spp.
Specific applications include industrial process water, cooling
water, air washers and humidifiers, air conditioning units, heat
exchangers, condensers and pasteurizers.

Protectol HT

The Business Unit Care Chemicals & Formulators also offers:

Protectol DZ

Surfactants
Water soluble polymers
Chelating agents
Waxes and wax emulsions
Electroplating and electronics chemicals

Protectol BN / Protectol BN 18 / Protectol BN 30

Bronopol does not accumulate in the environment and has
been shown to be inherently biodegradable. Under normal use
conditions, Bronopol will not cause problems either to effluent
treatment plants or to the environment following discharge into
wastewater. Bronopol is toxic to algae and daphnia but less
toxic to fish. The log POW is low, indicating that Bronopol has a
low potential to bioaccumulate. In the E.U., Bronopol is
classified as dangerous for the environment (R50).

Environmental Profile

Protectol GA 24 / Protectol GA 50
Glutaraldehyde has been shown to be readily biodegradable
and has a low potential to bioaccumulate. Under normal use
conditions, Glutaraldehyde will not cause problems either to
effluent treatment plants or to the environment following
discharge into wastewater. Glutaraldehyde is harmful to fish
and daphnia but is very toxic to algae.
Protectol DA

Protectol TD

2,4-Dichlorobenzyl alcohol is of low to moderate acute toxicity

to daphnia and fish and is of low acute toxicity to birds.
2,4-Dichlorobenzyl alcohol is not classified as dangerous to
the aquatic environment.

Protectol DF

Protectol DA

Protectol KD
Protectol FM 85
Protectol FM 99

Aseptrol

Dazomet is readily biodegradable. Under normal use conditions,

Dazomet will not cause problems either to effluent treatment
plants or to the environment following discharge into wastewater.
Dazomet has, however, been shown to be very toxic to fish and
daphnia but is less toxic to algae.

Protectol DB

Protectol DZ

When used as recommended, tetramethylolacetylene diurea will

cause no inhibition of activated sludge in sewage treatment plants.

Protectol TD

Protectol PE / Protectol PE S

Protectol DB

Aseptrol Chlorine Dioxide Technology

Phenoxyethanol is readily biodegradable. Experience gained in

running effluents into adapted biological treatment plants has
shown that concentrations of up to 1000mg/l are unlikely to
disturb the efficacy of activated sludge. Phenoxyethanol is of a
low acute toxicity to fish and daphnia.

Dibromonitrilopropionamide generally hydrolyses rapidly in water

through aerobic and anaerobic metabolism. It is of moderate
toxicity to terrestrial mammals and birds if they are exposed
orally to concentrated doses but under usual circumstances,
dietary toxicity to birds is low. Without any mitigation measures,
DBNPA poses a high risk to aquatic organisms. In the E.U., it is
classified as dangerous for the environment with risk phrase; R50
- very toxic to aquatic organisms.

Aseptrol products are a new addition to BASFs biocide range

and feature a unique and patented technology, which enables
the controlled release of chlorine dioxide into air or water from
a powder, dissolving tablet or sachet. Aseptrol products are
specially engineered with proprietary activators that combine
with chlorite salt to generate chlorine dioxide gas at precise
rates and in controlled concentrations, whenever in contact
with water or moisture in the air.

Protectol KD

Aseptrol products can be used to control a broad range of

microorganisms, viruses, spores, protozoan cysts and biofilm
deposits in several applications. Typical examples include hard
surface, dental, hospital and animal house disinfection, industrial
cooling water, odour control, pools, spas and emergency
drinking water.

Protectol PP
Phenoxypropanol is biodegradable. Experience gained in running
effluents into adapted biological treatment plants has shown that
concentrations of up to 2000mg/l are unlikely to disturb the
efficacy of activated sludge. Phenoxypropanol is of low toxicity to
fish and daphnia but it is harmful to algae. Phenoxypropanol is not
likely to bioaccumulate due to a low log POW.

N-cyclohexyl-diazenium dioxide, potassium salt, is readily

eliminated from water. Under normal use conditions, inhibition
of degradation activity in activated sludge is not expected when
the product is correctly introduced at low concentrations.

Protectol HT
1,3,5-Tris-(2-hydroxyethyl)-1,3,5-hexahydrotriazine is readily
biodegradable. However, under normal use conditions, the
product should not be discharged into waterways without prior
treatment.1,3,5-Tris-(2-hydroxyethyl)-1,3,5-hexahydrotriazine is
harmful to fish and daphnids.

Protectol FM 85 / Protectol FM 99
Formic acid is readily biodegradable. Under normal use conditions,
inhibition of degradation activity in activated sludge is not
expected when the product is correctly introduced at low
concentrations. Because of a low log POW value, bioaccumulation
in organisms is not expected.

Protectol DF
Dimethoxytetrahydrofuran is moderately biodegradable. Under
normal use conditions, inhibition of degradation activity in
activated sludge is not expected when the product is correctly
introduced at low concentrations. In acute studies,
Dimethoxytetrahydrofuran is not harmful to fish.
Protectol GL
Glyoxal is readily biodegradable. Effluent discharge into sewage
treatment plants has shown that concentrations of up to
1000mg/l are unlikely to disturb the efficacy of activated sludge.
In acute studies, Glyoxal is not hazardous to algae, daphnia or
fish. A low octanol / water coefficient also indicates a low
potential to bioaccumulate.

Labelling
Details about the classification and labelling of our products
and further advice on safe handling are contained in the current
safety data sheets.
Note according to the European Biocidal Products Directive
98/8/EC:
Use biocides safely. Always read the label and product
information before use.
Responsible Care
We will manage all aspects of our activities so that we provide a
high level of protection for the health and safety of employees
and associates, customers, the public and the environment.

For further information on our Aseptrol products and

technology, please contact your BASF sales representative.

soll90%:Pocket card

14.04.2008

14:40 Uhr

Seite 2

BASF is one of the worlds leading

suppliers of speciality biocides.
As part of the Care Chemicals & Formulators
division, the biocide group provides
marketing, regulatory and global technical
services to support the sale of biocides via
BASFs network of international sales offices
and the BTC Speciality Chemical distribution
organisation in Europe. Regional marketing
centres are also established in NAFTA,
South America and Asia.

BASF offers a strong and effective range of biocidal active ingredients

marketed under the Protectol trade name. These biocides can
be formulated to add value to a wide range of industrial and
consumer products and processes through the control of harmful
and unwanted micro-organisms. With our technical expertise and
application know-how, our biocides can preserve, protect,
enhance performance and improve process efficiency.

Application areas
Household & Personal Care
In personal care and household products our antimicrobial
chemistries and preservatives offer high performance, cost
effective solutions. They ensure that the final products are
protected from contamination and are safe to use on the skin
whilst maintaining product stability and compatibility.
Pulp & Paper
In paper making, our biocides are used to control slime build-up
in the process water. This ensures that the paper mill machinery
runs efficiently and the subsequent finished paper is free from
contamination and spoilage. In addition, we supply specialised
products to protect water-based mill additives such as starch,
pigments, sizes and mineral slurries.
Odour Control & Chemical Sanitation
Our biocides control odour in portable toilet fluids, animal litter
formulations and many other niche applications. Our products
are chosen for their excellent biocidal activity and ability to help
control the generation of noxious and unpleasant odours.
Superior biodegradability of our biocides also minimises
environmental impact.
Disinfection
We offer fast acting, effective biocidal ingredients used in the
formulation of disinfection and sanitizer products for hard
surfaces, medical instruments, cleaners and animal husbandry
applications.
Metal Working Fluids
Our biocides are easily incorporated into all types of metal
working fluid concentrates. They are extremely effective at
controlling microorganisms within the diluted matrix helping to
prevent malodours and fluid degradation. In addition, fluids can
enjoy secondary benefits such as enhanced solvent properties
and extended buffering.

Industrial Product Preservation

In this wide-ranging application area our products offer biocidal
performance when used either alone or in combination with
other actives. Applications include the preservation of water-based
paints, polymer dispersions, inks, fountain solutions, adhesives,
caulks, sealants and many other industrial fluids. Our biocides
can also be used in leather soak liquors to protect hides and
skins from blemishes caused by bacterial attack. Further uses
include formulations sold with cut flowers to keep them fresh
and free from bacterial contamination.
Oilfield
In oilfield applications BASFs biocides can be used in drilling
muds, injection waters, fracturing and completion fluids. They
are often added to production waters to prevent microbial
spoilage within the oil recovery process and to control souring
and corrosion caused by sulphate reducing bacteria.

Household &
Personal Care

Protectol BN
Protectol BN 18
Protectol BN 30

Protectol GA 24
Protectol GA 50

Protectol PE
Protectol PE S

Protectol PP

Pulp &
Paper

Odour Control
& Chemical
Sanitation

Industrial
Product
Preservation

Disinfection

Water
Treatment

Oilfield

Metal
Working
Fluids

Protectol GL
Water Treatment
In water treatment applications our biocides are used to reduce
biofouling and to control microbial contamination and the spread
of potentially pathogenic micro-organisms such as Legionella spp.
Specific applications include industrial process water, cooling
water, air washers and humidifiers, air conditioning units, heat
exchangers, condensers and pasteurizers.

Protectol HT

The Business Unit Care Chemicals & Formulators also offers:

Protectol DZ

Surfactants
Water soluble polymers
Chelating agents
Waxes and wax emulsions
Electroplating and electronics chemicals

Protectol BN / Protectol BN 18 / Protectol BN 30

Bronopol does not accumulate in the environment and has
been shown to be inherently biodegradable. Under normal use
conditions, Bronopol will not cause problems either to effluent
treatment plants or to the environment following discharge into
wastewater. Bronopol is toxic to algae and daphnia but less
toxic to fish. The log POW is low, indicating that Bronopol has a
low potential to bioaccumulate. In the E.U., Bronopol is
classified as dangerous for the environment (R50).

Environmental Profile

Protectol GA 24 / Protectol GA 50
Glutaraldehyde has been shown to be readily biodegradable
and has a low potential to bioaccumulate. Under normal use
conditions, Glutaraldehyde will not cause problems either to
effluent treatment plants or to the environment following
discharge into wastewater. Glutaraldehyde is harmful to fish
and daphnia but is very toxic to algae.
Protectol DA

Protectol TD

2,4-Dichlorobenzyl alcohol is of low to moderate acute toxicity

to daphnia and fish and is of low acute toxicity to birds.
2,4-Dichlorobenzyl alcohol is not classified as dangerous to
the aquatic environment.

Protectol DF

Protectol DA

Protectol KD
Protectol FM 85
Protectol FM 99

Aseptrol

Dazomet is readily biodegradable. Under normal use conditions,

Dazomet will not cause problems either to effluent treatment
plants or to the environment following discharge into wastewater.
Dazomet has, however, been shown to be very toxic to fish and
daphnia but is less toxic to algae.

Protectol DB

Protectol DZ

When used as recommended, tetramethylolacetylene diurea will

cause no inhibition of activated sludge in sewage treatment plants.

Protectol TD

Protectol PE / Protectol PE S

Protectol DB

Aseptrol Chlorine Dioxide Technology

Phenoxyethanol is readily biodegradable. Experience gained in

running effluents into adapted biological treatment plants has
shown that concentrations of up to 1000mg/l are unlikely to
disturb the efficacy of activated sludge. Phenoxyethanol is of a
low acute toxicity to fish and daphnia.

Dibromonitrilopropionamide generally hydrolyses rapidly in water

through aerobic and anaerobic metabolism. It is of moderate
toxicity to terrestrial mammals and birds if they are exposed
orally to concentrated doses but under usual circumstances,
dietary toxicity to birds is low. Without any mitigation measures,
DBNPA poses a high risk to aquatic organisms. In the E.U., it is
classified as dangerous for the environment with risk phrase; R50
- very toxic to aquatic organisms.

Aseptrol products are a new addition to BASFs biocide range

and feature a unique and patented technology, which enables
the controlled release of chlorine dioxide into air or water from
a powder, dissolving tablet or sachet. Aseptrol products are
specially engineered with proprietary activators that combine
with chlorite salt to generate chlorine dioxide gas at precise
rates and in controlled concentrations, whenever in contact
with water or moisture in the air.

Protectol KD

Aseptrol products can be used to control a broad range of

microorganisms, viruses, spores, protozoan cysts and biofilm
deposits in several applications. Typical examples include hard
surface, dental, hospital and animal house disinfection, industrial
cooling water, odour control, pools, spas and emergency
drinking water.

Protectol PP
Phenoxypropanol is biodegradable. Experience gained in running
effluents into adapted biological treatment plants has shown that
concentrations of up to 2000mg/l are unlikely to disturb the
efficacy of activated sludge. Phenoxypropanol is of low toxicity to
fish and daphnia but it is harmful to algae. Phenoxypropanol is not
likely to bioaccumulate due to a low log POW.

N-cyclohexyl-diazenium dioxide, potassium salt, is readily

eliminated from water. Under normal use conditions, inhibition
of degradation activity in activated sludge is not expected when
the product is correctly introduced at low concentrations.

Protectol HT
1,3,5-Tris-(2-hydroxyethyl)-1,3,5-hexahydrotriazine is readily
biodegradable. However, under normal use conditions, the
product should not be discharged into waterways without prior
treatment.1,3,5-Tris-(2-hydroxyethyl)-1,3,5-hexahydrotriazine is
harmful to fish and daphnids.

Protectol FM 85 / Protectol FM 99
Formic acid is readily biodegradable. Under normal use conditions,
inhibition of degradation activity in activated sludge is not
expected when the product is correctly introduced at low
concentrations. Because of a low log POW value, bioaccumulation
in organisms is not expected.

Protectol DF
Dimethoxytetrahydrofuran is moderately biodegradable. Under
normal use conditions, inhibition of degradation activity in
activated sludge is not expected when the product is correctly
introduced at low concentrations. In acute studies,
Dimethoxytetrahydrofuran is not harmful to fish.
Protectol GL
Glyoxal is readily biodegradable. Effluent discharge into sewage
treatment plants has shown that concentrations of up to
1000mg/l are unlikely to disturb the efficacy of activated sludge.
In acute studies, Glyoxal is not hazardous to algae, daphnia or
fish. A low octanol / water coefficient also indicates a low
potential to bioaccumulate.

Labelling
Details about the classification and labelling of our products
and further advice on safe handling are contained in the current
safety data sheets.
Note according to the European Biocidal Products Directive
98/8/EC:
Use biocides safely. Always read the label and product
information before use.
Responsible Care
We will manage all aspects of our activities so that we provide a
high level of protection for the health and safety of employees
and associates, customers, the public and the environment.

For further information on our Aseptrol products and

technology, please contact your BASF sales representative.

soll90%:Pocket card

14.04.2008

14:40 Uhr

Seite 2

BASF is one of the worlds leading

suppliers of speciality biocides.
As part of the Care Chemicals & Formulators
division, the biocide group provides
marketing, regulatory and global technical
services to support the sale of biocides via
BASFs network of international sales offices
and the BTC Speciality Chemical distribution
organisation in Europe. Regional marketing
centres are also established in NAFTA,
South America and Asia.

BASF offers a strong and effective range of biocidal active ingredients

marketed under the Protectol trade name. These biocides can
be formulated to add value to a wide range of industrial and
consumer products and processes through the control of harmful
and unwanted micro-organisms. With our technical expertise and
application know-how, our biocides can preserve, protect,
enhance performance and improve process efficiency.

Application areas
Household & Personal Care
In personal care and household products our antimicrobial
chemistries and preservatives offer high performance, cost
effective solutions. They ensure that the final products are
protected from contamination and are safe to use on the skin
whilst maintaining product stability and compatibility.
Pulp & Paper
In paper making, our biocides are used to control slime build-up
in the process water. This ensures that the paper mill machinery
runs efficiently and the subsequent finished paper is free from
contamination and spoilage. In addition, we supply specialised
products to protect water-based mill additives such as starch,
pigments, sizes and mineral slurries.
Odour Control & Chemical Sanitation
Our biocides control odour in portable toilet fluids, animal litter
formulations and many other niche applications. Our products
are chosen for their excellent biocidal activity and ability to help
control the generation of noxious and unpleasant odours.
Superior biodegradability of our biocides also minimises
environmental impact.
Disinfection
We offer fast acting, effective biocidal ingredients used in the
formulation of disinfection and sanitizer products for hard
surfaces, medical instruments, cleaners and animal husbandry
applications.
Metal Working Fluids
Our biocides are easily incorporated into all types of metal
working fluid concentrates. They are extremely effective at
controlling microorganisms within the diluted matrix helping to
prevent malodours and fluid degradation. In addition, fluids can
enjoy secondary benefits such as enhanced solvent properties
and extended buffering.

Industrial Product Preservation

In this wide-ranging application area our products offer biocidal
performance when used either alone or in combination with
other actives. Applications include the preservation of water-based
paints, polymer dispersions, inks, fountain solutions, adhesives,
caulks, sealants and many other industrial fluids. Our biocides
can also be used in leather soak liquors to protect hides and
skins from blemishes caused by bacterial attack. Further uses
include formulations sold with cut flowers to keep them fresh
and free from bacterial contamination.
Oilfield
In oilfield applications BASFs biocides can be used in drilling
muds, injection waters, fracturing and completion fluids. They
are often added to production waters to prevent microbial
spoilage within the oil recovery process and to control souring
and corrosion caused by sulphate reducing bacteria.

Household &
Personal Care

Protectol BN
Protectol BN 18
Protectol BN 30

Protectol GA 24
Protectol GA 50

Protectol PE
Protectol PE S

Protectol PP

Pulp &
Paper

Odour Control
& Chemical
Sanitation

Industrial
Product
Preservation

Disinfection

Water
Treatment

Oilfield

Metal
Working
Fluids

Protectol GL
Water Treatment
In water treatment applications our biocides are used to reduce
biofouling and to control microbial contamination and the spread
of potentially pathogenic micro-organisms such as Legionella spp.
Specific applications include industrial process water, cooling
water, air washers and humidifiers, air conditioning units, heat
exchangers, condensers and pasteurizers.

Protectol HT

The Business Unit Care Chemicals & Formulators also offers:

Protectol DZ

Surfactants
Water soluble polymers
Chelating agents
Waxes and wax emulsions
Electroplating and electronics chemicals

Protectol BN / Protectol BN 18 / Protectol BN 30

Bronopol does not accumulate in the environment and has
been shown to be inherently biodegradable. Under normal use
conditions, Bronopol will not cause problems either to effluent
treatment plants or to the environment following discharge into
wastewater. Bronopol is toxic to algae and daphnia but less
toxic to fish. The log POW is low, indicating that Bronopol has a
low potential to bioaccumulate. In the E.U., Bronopol is
classified as dangerous for the environment (R50).

Environmental Profile

Protectol GA 24 / Protectol GA 50
Glutaraldehyde has been shown to be readily biodegradable
and has a low potential to bioaccumulate. Under normal use
conditions, Glutaraldehyde will not cause problems either to
effluent treatment plants or to the environment following
discharge into wastewater. Glutaraldehyde is harmful to fish
and daphnia but is very toxic to algae.
Protectol DA

Protectol TD

2,4-Dichlorobenzyl alcohol is of low to moderate acute toxicity

to daphnia and fish and is of low acute toxicity to birds.
2,4-Dichlorobenzyl alcohol is not classified as dangerous to
the aquatic environment.

Protectol DF

Protectol DA

Protectol KD
Protectol FM 85
Protectol FM 99

Aseptrol

Dazomet is readily biodegradable. Under normal use conditions,

Dazomet will not cause problems either to effluent treatment
plants or to the environment following discharge into wastewater.
Dazomet has, however, been shown to be very toxic to fish and
daphnia but is less toxic to algae.

Protectol DB

Protectol DZ

When used as recommended, tetramethylolacetylene diurea will

cause no inhibition of activated sludge in sewage treatment plants.

Protectol TD

Protectol PE / Protectol PE S

Protectol DB

Aseptrol Chlorine Dioxide Technology

Phenoxyethanol is readily biodegradable. Experience gained in

running effluents into adapted biological treatment plants has
shown that concentrations of up to 1000mg/l are unlikely to
disturb the efficacy of activated sludge. Phenoxyethanol is of a
low acute toxicity to fish and daphnia.

Dibromonitrilopropionamide generally hydrolyses rapidly in water

through aerobic and anaerobic metabolism. It is of moderate
toxicity to terrestrial mammals and birds if they are exposed
orally to concentrated doses but under usual circumstances,
dietary toxicity to birds is low. Without any mitigation measures,
DBNPA poses a high risk to aquatic organisms. In the E.U., it is
classified as dangerous for the environment with risk phrase; R50
- very toxic to aquatic organisms.

Aseptrol products are a new addition to BASFs biocide range

and feature a unique and patented technology, which enables
the controlled release of chlorine dioxide into air or water from
a powder, dissolving tablet or sachet. Aseptrol products are
specially engineered with proprietary activators that combine
with chlorite salt to generate chlorine dioxide gas at precise
rates and in controlled concentrations, whenever in contact
with water or moisture in the air.

Protectol KD

Aseptrol products can be used to control a broad range of

microorganisms, viruses, spores, protozoan cysts and biofilm
deposits in several applications. Typical examples include hard
surface, dental, hospital and animal house disinfection, industrial
cooling water, odour control, pools, spas and emergency
drinking water.

Protectol PP
Phenoxypropanol is biodegradable. Experience gained in running
effluents into adapted biological treatment plants has shown that
concentrations of up to 2000mg/l are unlikely to disturb the
efficacy of activated sludge. Phenoxypropanol is of low toxicity to
fish and daphnia but it is harmful to algae. Phenoxypropanol is not
likely to bioaccumulate due to a low log POW.

N-cyclohexyl-diazenium dioxide, potassium salt, is readily

eliminated from water. Under normal use conditions, inhibition
of degradation activity in activated sludge is not expected when
the product is correctly introduced at low concentrations.

Protectol HT
1,3,5-Tris-(2-hydroxyethyl)-1,3,5-hexahydrotriazine is readily
biodegradable. However, under normal use conditions, the
product should not be discharged into waterways without prior
treatment.1,3,5-Tris-(2-hydroxyethyl)-1,3,5-hexahydrotriazine is
harmful to fish and daphnids.

Protectol FM 85 / Protectol FM 99
Formic acid is readily biodegradable. Under normal use conditions,
inhibition of degradation activity in activated sludge is not
expected when the product is correctly introduced at low
concentrations. Because of a low log POW value, bioaccumulation
in organisms is not expected.

Protectol DF
Dimethoxytetrahydrofuran is moderately biodegradable. Under
normal use conditions, inhibition of degradation activity in
activated sludge is not expected when the product is correctly
introduced at low concentrations. In acute studies,
Dimethoxytetrahydrofuran is not harmful to fish.
Protectol GL
Glyoxal is readily biodegradable. Effluent discharge into sewage
treatment plants has shown that concentrations of up to
1000mg/l are unlikely to disturb the efficacy of activated sludge.
In acute studies, Glyoxal is not hazardous to algae, daphnia or
fish. A low octanol / water coefficient also indicates a low
potential to bioaccumulate.

Labelling
Details about the classification and labelling of our products
and further advice on safe handling are contained in the current
safety data sheets.
Note according to the European Biocidal Products Directive
98/8/EC:
Use biocides safely. Always read the label and product
information before use.
Responsible Care
We will manage all aspects of our activities so that we provide a
high level of protection for the health and safety of employees
and associates, customers, the public and the environment.

For further information on our Aseptrol products and

technology, please contact your BASF sales representative.

Protectol BN

Protectol BN 18

Protectol BN 30

Protectol GA 24

Protectol GA 50

Protectol PE / PE S

Protectol PP

Protectol HT

Chemical Name

2-Bromo-2nitropropane-1,3-diol

2-Bromo-2nitropropane-1,3-diol

2-Bromo-2nitropropane-1,3-diol

1,5-Pentanedial

1,5-Pentanedial

Phenoxyethanol

1-Phenoxy-2-propanol
2-Phenoxy-1-propanol

1,3,5-tris(2-hydroxyethyl)-1,3,5hexahydrotriazine

Name using IUPAC

guidelines

2-Bromo-2-nitro-1,3propanediol

2-Bromo-2-nitro-1,3propanediol

2-Bromo-2-nitro-1,3propanediol

Pentanedial

Pentanedial

2-Phenoxyethanol

1-Phenoxy-2-propanol /
2-Phenoxy-1-propanol

Common Name
(Active Ingredient)

Bronopol

Bronopol

Bronopol

Glutaraldehyde

Glutaraldehyde

Phenoxyethanol

CAS Number
(Active Ingredient)

52-51-7

52-51-7

52-51-7

111-30-8

111-30-8

Protectol TD

Protectol GL

Protectol DF

Protectol DA

Chemical Name

Tetrahydro-1,3,4,6tetrakis(hydroxymethyl)
imidazo[4,5-d]imidazole

Glyoxal

2,5-Dimethoxy
tetrahydrofuran

2,4-Dichlorobenzyl
alcohol

3,5
thiad

1,3,5-Triazine1,3,5(2H,4H,6H)triethanol

Name using IUPAC

guidelines

Tetrahydro-1,3,4,6 tetrakis
(hydroxymethyl) imidazo[4,5d]imidazole-2,5(1H,3H)-dione

1,2-Ethanedial

Tetrahydro-2,5dimethoxyfuran

2,4-Dichlorobenzenemethanol

T
dim
thia

Phenoxypropanol

Triazine

Common Name(s)
(Active Component)

Tetramethylolacetylene diurea

Glyoxal

2,5-Dimethoxy
tetrahydrofuran

Dichlorobenzyl alcohol
(DCBA)

122-99-6

770-35-4
4169-04-4

4719-04-4

CAS Number
(Active Component)

5395-50-6

107-22-2

696-59-3

1777-82-8

225-208-0

EINECS Number
(Active Component)

226-408-0

203-474-9

211-797-1

217-210-5

EINECS Number
(Active Ingredient)

200-143-0

200-143-0

200-143-0

203-856-5

203-856-5

204-589-7

212-222-7
224-027-4

Mol. Formula
(Active Ingredient)

C3H6BrNO4

C3H6BrNO4

C3H6BrNO4

C5H8O2

C5H8O2

C8H10O2

C9H12O2

C9H21N3O3

Mol. Formula
(Active Component)

C8H14N4O6

C2H2O2

C6H12O3

C7H6CI2O

Molar Mass
(Active Ingredient)

200.0

200.0

200.0

100.11

100.11

138.17

152.2

219.00

Molar Mass
(Active Component)

262.0

58.0

132.0

177.0

Physical form

Solid

Liquid

Liquid

Liquid

Liquid

Liquid

Liquid

Liquid

Physical form

Liquid

Liquid

Liquid

Solid

Appearance

White to
almost white

Clear to
practically clear
colourless to yellow

Clear colourless

Clear to
practically clear
colourless to yellow

Clear to
practically clear
colourless to yellow

Clear to
practically clear
colourless

Clear to
practically clear
colourless

Clear to
practically clear
colourless

Appearance

Clear to
practically clear
colourless to yellow

Clear to
practically clear
colourless

Clear to
practically clear
colourless

White to almost white

slightly lumpy

Concentration (% w/w)

min. 99.0

16.8 to 19.5

28.5 to 31.5

23.5 to 24.5

50.0 to 51.0

min 99.5

min 99.0

74.0 to 78.0

Concentration (% w/w)

45.0 to 49.0

39.5 to 40.5

min. 99.0

min. 98.0

Solubility (in water @ 23C)

28%

Unlimited

Unlimited

Unlimited
3 to 4
(Undiluted)

Unlimited

2.4%
approx. 7
(0.1% in water)

1.2%

Unlimited
approx. 10
(0.2% in water)

Solubility (in water @ 23C)

Unlimited

pH
(1% solution in water)

6.5 to 7.5

Unlimited
2 to 3.5
(Undiluted)

Partly
approx. 5
(30% in water)

Sparingly

approx. 7
(0.8% in water)

1.06

1.13

1.11

1.06

1.15

Density @ 20C [g/cm3]

Bulk density [g/l]

1.27

1.02

pH
(1% solution in water)
Density @ 20C [g/cm3]
Bulk density [g/l]

5.0 to 7.0

max 4.5

2.5 to 4.5

1.10

1.20

1100

Shelf life when stored in

sealed containers /
Ambient temperature

3 years

2 years

2 years

1 year***

1 year***

2 years

1 year

Log POW
(Active Ingredient)

0.18

0.18

0.18

-0.22

-0.22

1.12

Antibacterial activity
(Typical M.I.C.)

12.5 to 25ppm*

12.5 to 25ppm*

12.5 to 25ppm*

50 to 1250ppm**

50 to 1250ppm**

400 to 6400ppm*

400 to 6400ppm*

400 to 6400ppm*

250 to 1250ppm**

250 to 1250ppm**

Antifungal activity
(Typical M.I.C.)
Typical use pH range

Risk Phrases

1.21

N/A
500

1 year

Shelf life when stored in

sealed containers /
Ambient temperature

1 year

6 months

1.5 years

5 years

1.5

-1.21

Log POW
(Active Ingredient)

N/A

-2.54

N/A

N/A

3200 to 15000ppm*

5000 to 10000ppm*

500 to 1000ppm*

Antibacterial activity
(Typical M.I.C.)

approx. 1000ppm*

2500 to 5000ppm*

approx. 2500ppm*

500 to 2000ppm*

600 to 3200ppm*

approx. 7500ppm*

500 to 1000ppm*

approx. 5000ppm*

N/A

approx. 500ppm*

62.5 to 500ppm*

2 to 9

2 to 9

2 to 9

3 to 8

3 to 8

2 to 10

2 to 10

2 to 9

Antifungal activity
(Typical M.I.C.)
Typical use pH range

R21/22, R37/38,
R41, R50

R22, R38, R41

R22, R38, R41

R20/22, R34, R42/43

R23/25, R34, R42/43

R22, R36

R36

R22, R36, R43

Risk Phrases

M.I.C. data was generated using in-house methodology figures are based on active ingredient.
** M.I.C. data was generated using in-house methodology figures based on 50% Glutaraldehyde solution.
*** When stored below room temperature.

3.7

Off-

2 to 8

3 to 8

2 to 6

2 to 10

R40/43

R20, R36/38, R40/43

R10, R20, R36

R41

M.I.C. data was generated using in-house

methodology - figures are based on active
ingredient.

** M.I.C. data was generated using in-house methodology figures are based on actual product.

soll90%:Pocket card

14.04.2008

14:40 Uhr

Seite 1

BASF SE
Care Chemicals & Formulators Europe
67056 Ludwigshafen, Germany.
Email: [email protected]
www.care-chemicals-formulators.basf.com
BASF East Asia
Regional Headquarters Ltd
45/F, Jardine House, 1 Connaught Place Central, Hong Kong
Tel: +852 2731 1222
Fax: +852 2734 9631
www.basf.com.sg
BASF S.A.
Av. Faria Lima, 3600/3624
04538-132 So Paulo SP, Brazil
Tel: +55 11 3043-2233
Fax: +55 11 3043-6989
www.basf.com.br

Note:

Protectol BN

Protectol BN 18

Protectol BN 30

Protectol GA 24

Protectol GA 50

Protectol PE / PE S

Protectol PP

Protectol HT

Chemical Name

2-Bromo-2nitropropane-1,3-diol

2-Bromo-2nitropropane-1,3-diol

2-Bromo-2nitropropane-1,3-diol

1,5-Pentanedial

1,5-Pentanedial

Phenoxyethanol

1-Phenoxy-2-propanol
2-Phenoxy-1-propanol

1,3,5-tris(2-hydroxyethyl)-1,3,5hexahydrotriazine

Name using IUPAC

guidelines

2-Bromo-2-nitro-1,3propanediol

2-Bromo-2-nitro-1,3propanediol

2-Bromo-2-nitro-1,3propanediol

Pentanedial

Pentanedial

2-Phenoxyethanol

1-Phenoxy-2-propanol /
2-Phenoxy-1-propanol

Common Name
(Active Ingredient)

Bronopol

Bronopol

Bronopol

Glutaraldehyde

Glutaraldehyde

Phenoxyethanol

CAS Number
(Active Ingredient)

52-51-7

52-51-7

52-51-7

111-30-8

111-30-8

EINECS Number
(Active Ingredient)

200-143-0

200-143-0

200-143-0

203-856-5

Mol. Formula
(Active Ingredient)

C3H6BrNO4

C3H6BrNO4

C3H6BrNO4

Molar Mass
(Active Ingredient)

200.0

200.0

200.0

Physical form

Solid

Liquid

Liquid

Liquid

Liquid

Liquid

Appearance

White to
almost white

Clear to
practically clear
colourless to yellow

Clear colourless

Clear to
practically clear
colourless to yellow

Clear to
practically clear
colourless to yellow

Clear to
practically clear
colourless

Concentration (% w/w)

min. 99.0

16.8 to 19.5

28.5 to 31.5

23.5 to 24.5

50.0 to 51.0

min 99.5

Solubility (in water @ 23C)

28%

Unlimited

Unlimited

Unlimited
3 to 4
(Undiluted)

Unlimited

2.4%
approx. 7
(0.1% in water)

1.06

1.13

1.11

The information contained in this document is not necessarily valid for

the North American region where special regulations may apply.
A separate leaflet describing BASFs North American biocide product
range is available on request.
The data contained in this publication are based on our current
knowledge and experience. In view of the many factors that may
affect processing and application of our product, these data do not
relieve processors from carrying out their own investigations and tests;
neither do these data imply any guarantee of certain properties, nor
the suitability of the product for a specific purpose. Any descriptions,
drawings, photographs, data, proportions, weights etc. given herein
may change without prior information and do not constitute the agreed
contractual quality of the product. It is the responsibility of the recipient
of our products to ensure that any proprietary rights and existing laws
and legislation are observed.
FK/EVD 556e August 2007
Supersedes FK/ES 556e dated July 2004
= registered trademark of BASF

BASF plc Biocides

Mere Way, Ruddington, Nottingham, NG11 6JS, England
Tel: +44 (0)115 912 4586
Fax: +44 (0)115 912 4592
www.care-chemicals-formulators.basf.com
BTC Speciality Chemicals Distribution GmbH
Maarweg 163/165
50825 Kln, Germany
Tel: +49 221 9 54 64-0
www.btc-de.com

pH
(1% solution in water)
Density @ 20C [g/cm3]
Bulk density [g/l]

max 4.5

2.5 to 4.5

1.10

1.20

Protectol GL

Protectol DF

Protectol DA

Protectol DZ

Protectol DB

Protectol KD

Chemical Name

Tetrahydro-1,3,4,6tetrakis(hydroxymethyl)
imidazo[4,5-d]imidazole

Glyoxal

2,5-Dimethoxy
tetrahydrofuran

2,4-Dichlorobenzyl
alcohol

3,5-Dimethyl-1,3,5thiadiazinane-2-thione

2,2-Dibromo-2cyanoacetamide

N-cyclohexyl-diazenium
dioxide, potassium salt

Formic Acid

Formic Acid

1,3,5-Triazine1,3,5(2H,4H,6H)triethanol

Name using IUPAC

guidelines

Tetrahydro-1,3,4,6 tetrakis
(hydroxymethyl) imidazo[4,5d]imidazole-2,5(1H,3H)-dione

1,2-Ethanedial

Tetrahydro-2,5dimethoxyfuran

2,4-Dichlorobenzenemethanol

Tetrahydro-3,5dimethyl-2H-1,3,5thiadiazine-2-thione

2,2-Dibromo-3nitrilopropionamide

N'-HydroxyN-cyclohexyl-diazenium
oxide, potassium salt

Methanoic Acid

Methanoic Acid

Phenoxypropanol

Triazine

Common Name(s)
(Active Component)

Tetramethylolacetylene diurea

Glyoxal

2,5-Dimethoxy
tetrahydrofuran

Dichlorobenzyl alcohol
(DCBA)

Dazomet

Dibromonitrilopropionamide (DBNPA)

Potassium HDO
(K-HDO)

Formic Acid

Formic Acid

122-99-6

770-35-4
4169-04-4

4719-04-4

CAS Number
(Active Component)

5395-50-6

107-22-2

696-59-3

1777-82-8

533-74-4

10222-01-2

66603-10-9

64-18-6

64-18-6

203-856-5

204-589-7

212-222-7
224-027-4

225-208-0

EINECS Number
(Active Component)

226-408-0

203-474-9

211-797-1

217-210-5

208-576-7

233-537

248-617-6

200-597-1

200-597-1

C5H8O2

C5H8O2

C8H10O2

C9H12O2

C9H21N3O3

Mol. Formula
(Active Component)

C8H14N4O6

C2H2O2

C6H12O3

C7H6CI2O

C5H10N2S2

C3H2Br2N2O

C6H11N2O2- K+

100.11

100.11

138.17

152.2

219.00

Molar Mass
(Active Component)

262.0

58.0

132.0

177.0

162.3

242

183

Liquid

Liquid

Physical form

Liquid

Liquid

Liquid

Solid

Solid

Solid

Liquid

Clear to
practically clear
colourless

Clear to
practically clear
colourless

Appearance

Clear to
practically clear
colourless to yellow

Clear to
practically clear
colourless

Clear to
practically clear
colourless

White to almost white

slightly lumpy

Off-white free flowing

granules

White to off white

Tan

min 99.0

74.0 to 78.0

Concentration (% w/w)

45.0 to 49.0

39.5 to 40.5

min. 99.0

min. 98.0

min. 99.0

min. 99.0

29.0 to 31.0

1.2%

Unlimited
approx. 10
(0.2% in water)

Solubility (in water @ 23C)

Unlimited

1.5%

Unlimited

Unlimited

Unlimited

6.5 to 7.5

Partly
approx. 5
(30% in water)

0.36%

pH
(1% solution in water)

Unlimited
2 to 3.5
(Undiluted)

Sparingly

approx. 7
(0.8% in water)

N/A

approx. 7.0

6.6

10.5

2.2

2.2

1.06

1.15

Density @ 20C [g/cm3]

Bulk density [g/l]

1.27

1.02

1.13

1.195

1.22

500

450

934 - 1370

3.7

1100

1.21

Protectol FM 99

CH2O2
46.0
Liquid
Colourless to yellow
min. 85%

CH2O2
46.0
Liquid
Colourless to yellow
min. 99%

3 years

2 years

2 years

1 year***

1 year***

2 years

1 year

1 year

Shelf life when stored in

sealed containers /
Ambient temperature

1 year

6 months

1.5 years

5 years

5 years

2 years

2 years

2 years

2 years

Log POW
(Active Ingredient)

0.18

0.18

0.18

-0.22

-0.22

1.12

1.5

-1.21

Log POW
(Active Ingredient)

N/A

-2.54

N/A

N/A

N/A

6.31

-0.2

-1.9

-0.54

Antibacterial activity
(Typical M.I.C.)

12.5 to 25ppm*

12.5 to 25ppm*

12.5 to 25ppm*

50 to 1250ppm**

50 to 1250ppm**

3200 to 15000ppm*

5000 to 10000ppm*

500 to 1000ppm*

Antibacterial activity
(Typical M.I.C.)

approx. 1000ppm*

2500 to 5000ppm*

approx. 2500ppm*

500 to 2000ppm*

2 to 375ppm*

7.8 to 62.5ppm*

12.5 to 3200ppm*

400 to 6400ppm*

400 to 6400ppm*

400 to 6400ppm*

250 to 1250ppm**

250 to 1250ppm**

600 to 3200ppm*

approx. 7500ppm*

500 to 1000ppm*

approx. 5000ppm*

N/A

approx. 500ppm*

62.5 to 500ppm*

47 to 375ppm*

62.5 to 125ppm*

12.5 to 50ppm*

800 to 80000ppm

800 to 80000ppm

2 to 9

2 to 9

2 to 9

3 to 8

3 to 8

2 to 10

2 to 10

2 to 9

Antifungal activity
(Typical M.I.C.)
Typical use pH range

2 to 8

3 to 8

2 to 6

2 to 10

7 to 9

<6

<6

R22, R38, R41

R22, R38, R41

R20/22, R34, R42/43

R23/25, R34, R42/43

R22, R36

R36

R22, R36, R43

Risk Phrases

R40/43

R20, R36/38, R40/43

R10, R20, R36

R41

R22, R36

7 to 8.5
R23/25, R41, R38,
R43, R50

5.5 to 11.5

R21/22, R37/38,
R41, R50

R25, R36/38

R34

R35

Risk Phrases

M.I.C. data was generated using in-house methodology figures are based on active ingredient.
** M.I.C. data was generated using in-house methodology figures based on 50% Glutaraldehyde solution.
*** When stored below room temperature.

M.I.C. data was generated using in-house

methodology - figures are based on active
ingredient.

** M.I.C. data was generated using in-house methodology figures are based on actual product.

CIPAC method 183.

Literature values based on active ingredient.

Protectol
Biocides

Shelf life when stored in

sealed containers /
Ambient temperature

Antifungal activity
(Typical M.I.C.)
Typical use pH range

5.0 to 7.0

Protectol FM 85

Protectol TD

700 to 7500ppm

700 to 7500ppm

BASF SE
Care Chemicals & Formulators Europe
67056 Ludwigshafen, Germany.
Email: [email protected]
www.care-chemicals-formulators.basf.com
BASF East Asia
Regional Headquarters Ltd
45/F, Jardine House, 1 Connaught Place Central, Hong Kong
Tel: +852 2731 1222
Fax: +852 2734 9631
www.basf.com.sg
BASF S.A.
Av. Faria Lima, 3600/3624
04538-132 So Paulo SP, Brazil
Tel: +55 11 3043-2233
Fax: +55 11 3043-6989
www.basf.com.br

Note:

Protectol BN

Protectol BN 18

Protectol BN 30

Protectol GA 24

Protectol GA 50

Protectol PE / PE S

Protectol PP

Protectol HT

Chemical Name

2-Bromo-2nitropropane-1,3-diol

2-Bromo-2nitropropane-1,3-diol

2-Bromo-2nitropropane-1,3-diol

1,5-Pentanedial

1,5-Pentanedial

Phenoxyethanol

1-Phenoxy-2-propanol
2-Phenoxy-1-propanol

1,3,5-tris(2-hydroxyethyl)-1,3,5hexahydrotriazine

Name using IUPAC

guidelines

2-Bromo-2-nitro-1,3propanediol

2-Bromo-2-nitro-1,3propanediol

2-Bromo-2-nitro-1,3propanediol

Pentanedial

Pentanedial

2-Phenoxyethanol

1-Phenoxy-2-propanol /
2-Phenoxy-1-propanol

Common Name
(Active Ingredient)

Bronopol

Bronopol

Bronopol

Glutaraldehyde

Glutaraldehyde

Phenoxyethanol

CAS Number
(Active Ingredient)

52-51-7

52-51-7

52-51-7

111-30-8

111-30-8

EINECS Number
(Active Ingredient)

200-143-0

200-143-0

200-143-0

203-856-5

Mol. Formula
(Active Ingredient)

C3H6BrNO4

C3H6BrNO4

C3H6BrNO4

Molar Mass
(Active Ingredient)

200.0

200.0

200.0

Physical form

Solid

Liquid

Liquid

Liquid

Liquid

Liquid

Appearance

White to
almost white

Clear to
practically clear
colourless to yellow

Clear colourless

Clear to
practically clear
colourless to yellow

Clear to
practically clear
colourless to yellow

Clear to
practically clear
colourless

Concentration (% w/w)

min. 99.0

16.8 to 19.5

28.5 to 31.5

23.5 to 24.5

50.0 to 51.0

min 99.5

Solubility (in water @ 23C)

28%

Unlimited

Unlimited

Unlimited
3 to 4
(Undiluted)

Unlimited

2.4%
approx. 7
(0.1% in water)

1.06

1.13

1.11

The information contained in this document is not necessarily valid for

the North American region where special regulations may apply.
A separate leaflet describing BASFs North American biocide product
range is available on request.
The data contained in this publication are based on our current
knowledge and experience. In view of the many factors that may
affect processing and application of our product, these data do not
relieve processors from carrying out their own investigations and tests;
neither do these data imply any guarantee of certain properties, nor
the suitability of the product for a specific purpose. Any descriptions,
drawings, photographs, data, proportions, weights etc. given herein
may change without prior information and do not constitute the agreed
contractual quality of the product. It is the responsibility of the recipient
of our products to ensure that any proprietary rights and existing laws
and legislation are observed.
FK/EMV 556e March 2008
Supersedes FK/EVD 556e dated August 2007
= registered trademark of BASF

BASF plc Biocides

Mere Way, Ruddington, Nottingham, NG11 6JS, England
Tel: +44 (0)115 912 4586
Fax: +44 (0)115 912 4592
www.care-chemicals-formulators.basf.com
BTC Speciality Chemicals Distribution GmbH
Maarweg 163/165
50825 Kln, Germany
Tel: +49 221 9 54 64-0
www.btc-de.com

pH
(1% solution in water)
Density @ 20C [g/cm3]
Bulk density [g/l]

max 4.5

2.5 to 4.5

1.10

1.20

Protectol GL

Protectol DF

Protectol DA

Protectol DZ

Protectol DB

Protectol KD

Chemical Name

Tetrahydro-1,3,4,6tetrakis(hydroxymethyl)
imidazo[4,5-d]imidazole

Glyoxal

2,5-Dimethoxy
tetrahydrofuran

2,4-Dichlorobenzyl
alcohol

3,5-Dimethyl-1,3,5thiadiazinane-2-thione

2,2-Dibromo-2cyanoacetamide

N-cyclohexyl-diazenium
dioxide, potassium salt

Formic Acid

Formic Acid

1,3,5-Triazine1,3,5(2H,4H,6H)triethanol

Name using IUPAC

guidelines

Tetrahydro-1,3,4,6 tetrakis
(hydroxymethyl) imidazo[4,5d]imidazole-2,5(1H,3H)-dione

1,2-Ethanedial

Tetrahydro-2,5dimethoxyfuran

2,4-Dichlorobenzenemethanol

Tetrahydro-3,5dimethyl-2H-1,3,5thiadiazine-2-thione

2,2-Dibromo-3nitrilopropionamide

N'-HydroxyN-cyclohexyl-diazenium
oxide, potassium salt

Methanoic Acid

Methanoic Acid

Phenoxypropanol

Triazine

Common Name(s)
(Active Component)

Tetramethylolacetylene diurea

Glyoxal

2,5-Dimethoxy
tetrahydrofuran

Dichlorobenzyl alcohol
(DCBA)

Dazomet

Dibromonitrilopropionamide (DBNPA)

Potassium HDO
(K-HDO)

Formic Acid

Formic Acid

122-99-6

770-35-4
4169-04-4

4719-04-4

CAS Number
(Active Component)

5395-50-6

107-22-2

696-59-3

1777-82-8

533-74-4

10222-01-2

66603-10-9

64-18-6

64-18-6

203-856-5

204-589-7

212-222-7
224-027-4

225-208-0

EINECS Number
(Active Component)

226-408-0

203-474-9

211-797-1

217-210-5

208-576-7

233-537

248-617-6

200-597-1

200-597-1

C5H8O2

C5H8O2

C8H10O2

C9H12O2

C9H21N3O3

Mol. Formula
(Active Component)

C8H14N4O6

C2H2O2

C6H12O3

C7H6CI2O

C5H10N2S2

C3H2Br2N2O

C6H11N2O2- K+

100.11

100.11

138.17

152.2

219.00

Molar Mass
(Active Component)

262.0

58.0

132.0

177.0

162.3

242

183

Liquid

Liquid

Physical form

Liquid

Liquid

Liquid

Solid

Solid

Solid

Liquid

Clear to
practically clear
colourless

Clear to
practically clear
colourless

Appearance

Clear to
practically clear
colourless to yellow

Clear to
practically clear
colourless

Clear to
practically clear
colourless

White to almost white

slightly lumpy

Off-white free flowing

granules

White to off white

Tan

min 99.0

74.0 to 78.0

Concentration (% w/w)

45.0 to 49.0

39.5 to 40.5

min. 99.0

min. 98.0

min. 99.0

min. 99.0

29.0 to 31.0

1.2%

Unlimited
approx. 10
(0.2% in water)

Solubility (in water @ 23C)

Unlimited

1.5%

Unlimited

Unlimited

Unlimited

6.5 to 7.5

Partly
approx. 5
(30% in water)

0.36%

pH
(1% solution in water)

Unlimited
2 to 3.5
(Undiluted)

Sparingly

approx. 7
(0.8% in water)

N/A

approx. 7.0

6.6

10.5

2.2

2.2

1.06

1.15

Density @ 20C [g/cm3]

Bulk density [g/l]

1.27

1.02

1.13

1.195

1.22

500

450

934 - 1370

3.7

1100

1.21

Protectol FM 99

CH2O2
46.0
Liquid
Colourless to yellow
min. 85%

CH2O2
46.0
Liquid
Colourless to yellow
min. 99%

3 years

2 years

2 years

1 year***

1 year***

2 years

1 year

1 year

Shelf life when stored in

sealed containers /
Ambient temperature

1 year

6 months

1.5 years

5 years

5 years

2 years

2 years

2 years

2 years

Log POW
(Active Ingredient)

0.18

0.18

0.18

-0.22

-0.22

1.12

1.5

-1.21

Log POW
(Active Ingredient)

N/A

-2.54

N/A

N/A

N/A

6.31

-0.2

-1.9

-0.54

Antibacterial activity
(Typical M.I.C.)

12.5 to 25ppm*

12.5 to 25ppm*

12.5 to 25ppm*

50 to 1250ppm**

50 to 1250ppm**

3200 to 15000ppm*

5000 to 10000ppm*

500 to 1000ppm*

Antibacterial activity
(Typical M.I.C.)

approx. 1000ppm*

2500 to 5000ppm*

approx. 2500ppm*

500 to 2000ppm*

2 to 375ppm*

7.8 to 62.5ppm*

12.5 to 3200ppm*

400 to 6400ppm*

400 to 6400ppm*

400 to 6400ppm*

250 to 1250ppm**

250 to 1250ppm**

600 to 3200ppm*

approx. 7500ppm*

500 to 1000ppm*

approx. 5000ppm*

N/A

approx. 500ppm*

62.5 to 500ppm*

47 to 375ppm*

62.5 to 125ppm*

12.5 to 50ppm*

800 to 80000ppm

800 to 80000ppm

2 to 9

2 to 9

2 to 9

3 to 8

3 to 8

2 to 10

2 to 10

2 to 9

Antifungal activity
(Typical M.I.C.)
Typical use pH range

2 to 8

3 to 8

2 to 6

2 to 10

7 to 9

<6

<6

R22, R38, R41

R22, R38, R41

R20/22, R34, R42/43

R23/25, R34, R42/43

R22, R36

R36

R22, R36, R43

Risk Phrases

R40/43

R20, R36/38, R40/43

R10, R20, R36

R41

R22, R36

7 to 8.5
R23/25, R41, R38,
R43, R50

5.5 to 11.5

R21/22, R37/38,
R41, R50

R25, R36/38

R34

R35

Risk Phrases

M.I.C. data was generated using in-house methodology figures are based on active ingredient.
** M.I.C. data was generated using in-house methodology figures based on 50% Glutaraldehyde solution.
*** When stored below room temperature.

M.I.C. data was generated using in-house

methodology - figures are based on active
ingredient.

** M.I.C. data was generated using in-house methodology figures are based on actual product.

CIPAC method 183.

Literature values based on active ingredient.

Protectol
Biocides

Shelf life when stored in

sealed containers /
Ambient temperature

Antifungal activity
(Typical M.I.C.)
Typical use pH range

5.0 to 7.0

Protectol FM 85

Protectol TD

700 to 7500ppm

700 to 7500ppm

BASF SE
Care Chemicals & Formulators Europe
67056 Ludwigshafen, Germany.
Email: [email protected]
www.care-chemicals-formulators.basf.com
BASF East Asia
Regional Headquarters Ltd
45/F, Jardine House, 1 Connaught Place Central, Hong Kong
Tel: +852 2731 1222
Fax: +852 2734 9631
www.basf.com.sg
BASF S.A.
Av. Faria Lima, 3600/3624
04538-132 So Paulo SP, Brazil
Tel: +55 11 3043-2233
Fax: +55 11 3043-6989
www.basf.com.br

Note:

Protectol BN

Protectol BN 18

Protectol BN 30

Protectol GA 24

Protectol GA 50

Protectol PE / PE S

Protectol PP

Protectol HT

Chemical Name

2-Bromo-2nitropropane-1,3-diol

2-Bromo-2nitropropane-1,3-diol

2-Bromo-2nitropropane-1,3-diol

1,5-Pentanedial

1,5-Pentanedial

Phenoxyethanol

1-Phenoxy-2-propanol
2-Phenoxy-1-propanol

1,3,5-tris(2-hydroxyethyl)-1,3,5hexahydrotriazine

Name using IUPAC

guidelines

2-Bromo-2-nitro-1,3propanediol

2-Bromo-2-nitro-1,3propanediol

2-Bromo-2-nitro-1,3propanediol

Pentanedial

Pentanedial

2-Phenoxyethanol

1-Phenoxy-2-propanol /
2-Phenoxy-1-propanol

Common Name
(Active Ingredient)

Bronopol

Bronopol

Bronopol

Glutaraldehyde

Glutaraldehyde

Phenoxyethanol

CAS Number
(Active Ingredient)

52-51-7

52-51-7

52-51-7

111-30-8

111-30-8

EINECS Number
(Active Ingredient)

200-143-0

200-143-0

200-143-0

203-856-5

Mol. Formula
(Active Ingredient)

C3H6BrNO4

C3H6BrNO4

C3H6BrNO4

Molar Mass
(Active Ingredient)

200.0

200.0

200.0

Physical form

Solid

Liquid

Liquid

Liquid

Liquid

Liquid

Appearance

White to
almost white

Clear to
practically clear
colourless to yellow

Clear colourless

Clear to
practically clear
colourless to yellow

Clear to
practically clear
colourless to yellow

Clear to
practically clear
colourless

Concentration (% w/w)

min. 99.0

16.8 to 19.5

28.5 to 31.5

23.5 to 24.5

50.0 to 51.0

min 99.5

Solubility (in water @ 23C)

28%

Unlimited

Unlimited

Unlimited
3 to 4
(Undiluted)

Unlimited

2.4%
approx. 7
(0.1% in water)

1.06

1.13

1.11

The information contained in this document is not necessarily valid for

the North American region where special regulations may apply.
A separate leaflet describing BASFs North American biocide product
range is available on request.
The data contained in this publication are based on our current
knowledge and experience. In view of the many factors that may
affect processing and application of our product, these data do not
relieve processors from carrying out their own investigations and tests;
neither do these data imply any guarantee of certain properties, nor
the suitability of the product for a specific purpose. Any descriptions,
drawings, photographs, data, proportions, weights etc. given herein
may change without prior information and do not constitute the agreed
contractual quality of the product. It is the responsibility of the recipient
of our products to ensure that any proprietary rights and existing laws
and legislation are observed.
FK/EMV 556e March 2008
Supersedes FK/EVD 556e dated August 2007
= registered trademark of BASF

BASF plc Biocides

Mere Way, Ruddington, Nottingham, NG11 6JS, England
Tel: +44 (0)115 912 4586
Fax: +44 (0)115 912 4592
www.care-chemicals-formulators.basf.com
BTC Speciality Chemicals Distribution GmbH
Maarweg 163/165
50825 Kln, Germany
Tel: +49 221 9 54 64-0
www.btc-de.com

pH
(1% solution in water)
Density @ 20C [g/cm3]
Bulk density [g/l]

max 4.5

2.5 to 4.5

1.10

1.20

Protectol GL

Protectol DF

Protectol DA

Protectol DZ

Protectol DB

Protectol KD

Chemical Name

Tetrahydro-1,3,4,6tetrakis(hydroxymethyl)
imidazo[4,5-d]imidazole

Glyoxal

2,5-Dimethoxy
tetrahydrofuran

2,4-Dichlorobenzyl
alcohol

3,5-Dimethyl-1,3,5thiadiazinane-2-thione

2,2-Dibromo-2cyanoacetamide

N-cyclohexyl-diazenium
dioxide, potassium salt

Formic Acid

Formic Acid

1,3,5-Triazine1,3,5(2H,4H,6H)triethanol

Name using IUPAC

guidelines

Tetrahydro-1,3,4,6 tetrakis
(hydroxymethyl) imidazo[4,5d]imidazole-2,5(1H,3H)-dione

1,2-Ethanedial

Tetrahydro-2,5dimethoxyfuran

2,4-Dichlorobenzenemethanol

Tetrahydro-3,5dimethyl-2H-1,3,5thiadiazine-2-thione

2,2-Dibromo-3nitrilopropionamide

N'-HydroxyN-cyclohexyl-diazenium
oxide, potassium salt

Methanoic Acid

Methanoic Acid

Phenoxypropanol

Triazine

Common Name(s)
(Active Component)

Tetramethylolacetylene diurea

Glyoxal

2,5-Dimethoxy
tetrahydrofuran

Dichlorobenzyl alcohol
(DCBA)

Dazomet

Dibromonitrilopropionamide (DBNPA)

Potassium HDO
(K-HDO)

Formic Acid

Formic Acid

122-99-6

770-35-4
4169-04-4

4719-04-4

CAS Number
(Active Component)

5395-50-6

107-22-2

696-59-3

1777-82-8

533-74-4

10222-01-2

66603-10-9

64-18-6

64-18-6

203-856-5

204-589-7

212-222-7
224-027-4

225-208-0

EINECS Number
(Active Component)

226-408-0

203-474-9

211-797-1

217-210-5

208-576-7

233-537

248-617-6

200-597-1

200-597-1

C5H8O2

C5H8O2

C8H10O2

C9H12O2

C9H21N3O3

Mol. Formula
(Active Component)

C8H14N4O6

C2H2O2

C6H12O3

C7H6CI2O

C5H10N2S2

C3H2Br2N2O

C6H11N2O2- K+

100.11

100.11

138.17

152.2

219.00

Molar Mass
(Active Component)

262.0

58.0

132.0

177.0

162.3

242

183

Liquid

Liquid

Physical form

Liquid

Liquid

Liquid

Solid

Solid

Solid

Liquid

Clear to
practically clear
colourless

Clear to
practically clear
colourless

Appearance

Clear to
practically clear
colourless to yellow

Clear to
practically clear
colourless

Clear to
practically clear
colourless

White to almost white

slightly lumpy

Off-white free flowing

granules

White to off white

Tan

min 99.0

74.0 to 78.0

Concentration (% w/w)

45.0 to 49.0

39.5 to 40.5

min. 99.0

min. 98.0

min. 99.0

min. 99.0

29.0 to 31.0

1.2%

Unlimited
approx. 10
(0.2% in water)

Solubility (in water @ 23C)

Unlimited

1.5%

Unlimited

Unlimited

Unlimited

6.5 to 7.5

Partly
approx. 5
(30% in water)

0.36%

pH
(1% solution in water)

Unlimited
2 to 3.5
(Undiluted)

Sparingly

approx. 7
(0.8% in water)

N/A

approx. 7.0

6.6

10.5

2.2

2.2

1.06

1.15

Density @ 20C [g/cm3]

Bulk density [g/l]

1.27

1.02

1.13

1.195

1.22

500

450

934 - 1370

3.7

1100

1.21

Protectol FM 99

CH2O2
46.0
Liquid
Colourless to yellow
min. 85%

CH2O2
46.0
Liquid
Colourless to yellow
min. 99%

3 years

2 years

2 years

1 year***

1 year***

2 years

1 year

1 year

Shelf life when stored in

sealed containers /
Ambient temperature

1 year

6 months

1.5 years

5 years

5 years

2 years

2 years

2 years

2 years

Log POW
(Active Ingredient)

0.18

0.18

0.18

-0.22

-0.22

1.12

1.5

-1.21

Log POW
(Active Ingredient)

N/A

-2.54

N/A

N/A

N/A

6.31

-0.2

-1.9

-0.54

Antibacterial activity
(Typical M.I.C.)

12.5 to 25ppm*

12.5 to 25ppm*

12.5 to 25ppm*

50 to 1250ppm**

50 to 1250ppm**

3200 to 15000ppm*

5000 to 10000ppm*

500 to 1000ppm*

Antibacterial activity
(Typical M.I.C.)

approx. 1000ppm*

2500 to 5000ppm*

approx. 2500ppm*

500 to 2000ppm*

2 to 375ppm*

7.8 to 62.5ppm*

12.5 to 3200ppm*

400 to 6400ppm*

400 to 6400ppm*

400 to 6400ppm*

250 to 1250ppm**

250 to 1250ppm**

600 to 3200ppm*

approx. 7500ppm*

500 to 1000ppm*

approx. 5000ppm*

N/A

approx. 500ppm*

62.5 to 500ppm*

47 to 375ppm*

62.5 to 125ppm*

12.5 to 50ppm*

800 to 80000ppm

800 to 80000ppm

2 to 9

2 to 9

2 to 9

3 to 8

3 to 8

2 to 10

2 to 10

2 to 9

Antifungal activity
(Typical M.I.C.)
Typical use pH range

2 to 8

3 to 8

2 to 6

2 to 10

7 to 9

<6

<6

R22, R38, R41

R22, R38, R41

R20/22, R34, R42/43

R23/25, R34, R42/43

R22, R36

R36

R22, R36, R43

Risk Phrases

R40/43

R20, R36/38, R40/43

R10, R20, R36

R41

R22, R36

7 to 8.5
R23/25, R41, R38,
R43, R50

5.5 to 11.5

R21/22, R37/38,
R41, R50

R25, R36/38

R34

R35

Risk Phrases

M.I.C. data was generated using in-house methodology figures are based on active ingredient.
** M.I.C. data was generated using in-house methodology figures based on 50% Glutaraldehyde solution.
*** When stored below room temperature.

M.I.C. data was generated using in-house

methodology - figures are based on active
ingredient.

** M.I.C. data was generated using in-house methodology figures are based on actual product.

CIPAC method 183.

Literature values based on active ingredient.

Protectol
Biocides

Shelf life when stored in

sealed containers /
Ambient temperature

Antifungal activity
(Typical M.I.C.)
Typical use pH range

5.0 to 7.0

Protectol FM 85

Protectol TD

700 to 7500ppm

700 to 7500ppm

soll90%:Pocket card

14.04.2008

14:40 Uhr

Seite 2

BASF is one of the worlds leading

suppliers of speciality biocides.
As part of the Care Chemicals & Formulators
division, the biocide group provides
marketing, regulatory and global technical
services to support the sale of biocides via
BASFs network of international sales offices
and the BTC Speciality Chemical distribution
organisation in Europe. Regional marketing
centres are also established in NAFTA,
South America and Asia.

BASF offers a strong and effective range of biocidal active ingredients

marketed under the Protectol trade name. These biocides can
be formulated to add value to a wide range of industrial and
consumer products and processes through the control of harmful
and unwanted micro-organisms. With our technical expertise and
application know-how, our biocides can preserve, protect,
enhance performance and improve process efficiency.

Application areas
Household & Personal Care
In personal care and household products our antimicrobial
chemistries and preservatives offer high performance, cost
effective solutions. They ensure that the final products are
protected from contamination and are safe to use on the skin
whilst maintaining product stability and compatibility.
Pulp & Paper
In paper making, our biocides are used to control slime build-up
in the process water. This ensures that the paper mill machinery
runs efficiently and the subsequent finished paper is free from
contamination and spoilage. In addition, we supply specialised
products to protect water-based mill additives such as starch,
pigments, sizes and mineral slurries.
Odour Control & Chemical Sanitation
Our biocides control odour in portable toilet fluids, animal litter
formulations and many other niche applications. Our products
are chosen for their excellent biocidal activity and ability to help
control the generation of noxious and unpleasant odours.
Superior biodegradability of our biocides also minimises
environmental impact.
Disinfection
We offer fast acting, effective biocidal ingredients used in the
formulation of disinfection and sanitizer products for hard
surfaces, medical instruments, cleaners and animal husbandry
applications.
Metal Working Fluids
Our biocides are easily incorporated into all types of metal
working fluid concentrates. They are extremely effective at
controlling microorganisms within the diluted matrix helping to
prevent malodours and fluid degradation. In addition, fluids can
enjoy secondary benefits such as enhanced solvent properties
and extended buffering.

Industrial Product Preservation

In this wide-ranging application area our products offer biocidal
performance when used either alone or in combination with
other actives. Applications include the preservation of water-based
paints, polymer dispersions, inks, fountain solutions, adhesives,
caulks, sealants and many other industrial fluids. Our biocides
can also be used in leather soak liquors to protect hides and
skins from blemishes caused by bacterial attack. Further uses
include formulations sold with cut flowers to keep them fresh
and free from bacterial contamination.
Oilfield
In oilfield applications BASFs biocides can be used in drilling
muds, injection waters, fracturing and completion fluids. They
are often added to production waters to prevent microbial
spoilage within the oil recovery process and to control souring
and corrosion caused by sulphate reducing bacteria.

Household &
Personal Care

Protectol BN
Protectol BN 18
Protectol BN 30

Protectol GA 24
Protectol GA 50

Protectol PE
Protectol PE S

Protectol PP

Pulp &
Paper

Odour Control
& Chemical
Sanitation

Industrial
Product
Preservation

Disinfection

Water
Treatment

Oilfield

Metal
Working
Fluids

Protectol GL
Water Treatment
In water treatment applications our biocides are used to reduce
biofouling and to control microbial contamination and the spread
of potentially pathogenic micro-organisms such as Legionella spp.
Specific applications include industrial process water, cooling
water, air washers and humidifiers, air conditioning units, heat
exchangers, condensers and pasteurizers.

Protectol HT

The Business Unit Care Chemicals & Formulators also offers:

Protectol DZ

Surfactants
Water soluble polymers
Chelating agents
Waxes and wax emulsions
Electroplating and electronics chemicals

Protectol BN / Protectol BN 18 / Protectol BN 30

Bronopol does not accumulate in the environment and has
been shown to be inherently biodegradable. Under normal use
conditions, Bronopol will not cause problems either to effluent
treatment plants or to the environment following discharge into
wastewater. Bronopol is toxic to algae and daphnia but less
toxic to fish. The log POW is low, indicating that Bronopol has a
low potential to bioaccumulate. In the E.U., Bronopol is
classified as dangerous for the environment (R50).

Environmental Profile

Protectol GA 24 / Protectol GA 50
Glutaraldehyde has been shown to be readily biodegradable
and has a low potential to bioaccumulate. Under normal use
conditions, Glutaraldehyde will not cause problems either to
effluent treatment plants or to the environment following
discharge into wastewater. Glutaraldehyde is harmful to fish
and daphnia but is very toxic to algae.
Protectol DA

Protectol TD

2,4-Dichlorobenzyl alcohol is of low to moderate acute toxicity

to daphnia and fish and is of low acute toxicity to birds.
2,4-Dichlorobenzyl alcohol is not classified as dangerous to
the aquatic environment.

Protectol DF

Protectol DA

Protectol KD
Protectol FM 85
Protectol FM 99

Aseptrol

Dazomet is readily biodegradable. Under normal use conditions,

Dazomet will not cause problems either to effluent treatment
plants or to the environment following discharge into wastewater.
Dazomet has, however, been shown to be very toxic to fish and
daphnia but is less toxic to algae.

Protectol DB

Protectol DZ

When used as recommended, tetramethylolacetylene diurea will

cause no inhibition of activated sludge in sewage treatment plants.

Protectol TD

Protectol PE / Protectol PE S

Protectol DB

Aseptrol Chlorine Dioxide Technology

Phenoxyethanol is readily biodegradable. Experience gained in

running effluents into adapted biological treatment plants has
shown that concentrations of up to 1000mg/l are unlikely to
disturb the efficacy of activated sludge. Phenoxyethanol is of a
low acute toxicity to fish and daphnia.

Dibromonitrilopropionamide generally hydrolyses rapidly in water

through aerobic and anaerobic metabolism. It is of moderate
toxicity to terrestrial mammals and birds if they are exposed
orally to concentrated doses but under usual circumstances,
dietary toxicity to birds is low. Without any mitigation measures,
DBNPA poses a high risk to aquatic organisms. In the E.U., it is
classified as dangerous for the environment with risk phrase; R50
- very toxic to aquatic organisms.

Aseptrol products are a new addition to BASFs biocide range

and feature a unique and patented technology, which enables
the controlled release of chlorine dioxide into air or water from
a powder, dissolving tablet or sachet. Aseptrol products are
specially engineered with proprietary activators that combine
with chlorite salt to generate chlorine dioxide gas at precise
rates and in controlled concentrations, whenever in contact
with water or moisture in the air.

Protectol KD

Aseptrol products can be used to control a broad range of

microorganisms, viruses, spores, protozoan cysts and biofilm
deposits in several applications. Typical examples include hard
surface, dental, hospital and animal house disinfection, industrial
cooling water, odour control, pools, spas and emergency
drinking water.

Protectol PP
Phenoxypropanol is biodegradable. Experience gained in running
effluents into adapted biological treatment plants has shown that
concentrations of up to 2000mg/l are unlikely to disturb the
efficacy of activated sludge. Phenoxypropanol is of low toxicity to
fish and daphnia but it is harmful to algae. Phenoxypropanol is not
likely to bioaccumulate due to a low log POW.

N-cyclohexyl-diazenium dioxide, potassium salt, is readily

eliminated from water. Under normal use conditions, inhibition
of degradation activity in activated sludge is not expected when
the product is correctly introduced at low concentrations.

Protectol HT
1,3,5-Tris-(2-hydroxyethyl)-1,3,5-hexahydrotriazine is readily
biodegradable. However, under normal use conditions, the
product should not be discharged into waterways without prior
treatment.1,3,5-Tris-(2-hydroxyethyl)-1,3,5-hexahydrotriazine is
harmful to fish and daphnids.

Protectol FM 85 / Protectol FM 99
Formic acid is readily biodegradable. Under normal use conditions,
inhibition of degradation activity in activated sludge is not
expected when the product is correctly introduced at low
concentrations. Because of a low log POW value, bioaccumulation
in organisms is not expected.

Protectol DF
Dimethoxytetrahydrofuran is moderately biodegradable. Under
normal use conditions, inhibition of degradation activity in
activated sludge is not expected when the product is correctly
introduced at low concentrations. In acute studies,
Dimethoxytetrahydrofuran is not harmful to fish.
Protectol GL
Glyoxal is readily biodegradable. Effluent discharge into sewage
treatment plants has shown that concentrations of up to
1000mg/l are unlikely to disturb the efficacy of activated sludge.
In acute studies, Glyoxal is not hazardous to algae, daphnia or
fish. A low octanol / water coefficient also indicates a low
potential to bioaccumulate.

Labelling
Details about the classification and labelling of our products
and further advice on safe handling are contained in the current
safety data sheets.
Note according to the European Biocidal Products Directive
98/8/EC:
Use biocides safely. Always read the label and product
information before use.
Responsible Care
We will manage all aspects of our activities so that we provide a
high level of protection for the health and safety of employees
and associates, customers, the public and the environment.

For further information on our Aseptrol products and

technology, please contact your BASF sales representative.