Material Safety Data Sheet Sample

Hydrogen chloride
Safety Data Sheet P-4606

according to U.S. Code of Federal Regulations 29 CFR 1910.1200, Hazard Communication.
Date of issue: 01/01/1984
Revision date: 03/19/2015
Supersedes: 05/01/2009
SECTION: 1. Product and company identification

1.1.
Product identifier
Product form
: Substance
Name
: Hydrogen chloride
CAS No
: 7647-01-0
Formula
: HCl
Other means of identification
: Anhydrous hydrochloric acid
1.2.
Relevant identified uses of the substance or mixture and uses advised against
Use of the substance/mixture

1.3.
: Industrial use. Use as directed.
Details of the supplier of the safety data sheet
Praxair, Inc.
39 Old Ridgebury Road
Danbury, CT 06810-5113 - USA
T 1-800-772-9247 (1-800-PRAXAIR) - F 1-716-879-2146
www.praxair.com
1.4.
Emergency telephone number
Emergency number
: Onsite Emergency: 1-800-645-4633

CHEMTREC, 24hr/day 7days/week Within USA: 1-800-424-9300, Outside USA: 001-703527-3887 (collect calls accepted, Contract 17729)
SECTION 2: Hazards identification

2.1.
Classification of the substance or mixture
Classification (GHS-US)
Liquefied gas
Acute Tox. 3 (Inhalation:gas)
Skin Corr. 1A
Eye Dam. 1
2.2.
H280
H331
H314
H318
Label elements
GHS-US labeling
Hazard pictograms (GHS-US)
Signal word (GHS-US)
: DANGER
Hazard statements (GHS-US)
: H280 - CONTAINS GAS UNDER PRESSURE; MAY EXPLODE IF HEATED

H314 - CAUSES SEVERE SKIN BURNS AND EYE DAMAGE
H331 - TOXIC IF INHALED
CGA-HG22 - CORROSIVE TO THE RESPIRATORY TRACT
Precautionary statements (GHS-US)
: P202 - Do not handle until all safety precautions have been read and understood
P261 - Avoid breathing gas
P262 - Do not get in eyes, on skin, or on clothing.
P271+P403 - Use and store only outdoors or in a well-ventilated place.
P280+P284 - Wear protective gloves, protective clothing, eye protection, respiratory protection,
and/or face protection.
P405 - Store locked up
P501 - Dispose of contents/container Dispose in a safe manner in accordance with
local/national regulations
CGA-PG05 - Use a back flow preventive device in the piping.
CGA-PG20+CGA-PG10 - Use only with equipment of compatible materials of construction and
GHS04
EN (English US)
GHS05
GHS06
SDS ID: P-4606
This document is only controlled while on the Praxair, Inc. website and a copy of this controlled version is available for download.
Praxair cannot assure the integrity or accuracy of any version of this document after it has been downloaded or removed from our website.
1/9
Hydrogen chloride
rated for cylinder pressure.

CGA-PG12 - Do not open valve until connected to equipment prepared for use.
CGA-PG18 - When returning cylinder, install leak tight valve outlet cap or plug.
CGA-PG06 - Close valve after each use and when empty.
CGA-PG02 - Protect from sunlight when ambient temperature exceeds 52C (125F).
2.3.
Other hazards
Other hazards not contributing to the

classification
2.4.
: None.
Unknown acute toxicity (GHS US)

No data available
SECTION 3: Composition/information on ingredients

3.1.
Substance
Name
Product identifier
Hydrogen chloride
(CAS No) 7647-01-0
100
(Main constituent)
3.2.
Mixture
Not applicable
SECTION 4: First aid measures

4.1.
Description of first aid measures
First-aid measures after inhalation
: Immediately remove to fresh air. If not breathing, give artificial respiration. If breathing is
difficult, qualified personnel may give oxygen. Call a physician. WARNING: To avoid possible
chemical burns, the rescuer should avoid breathing any exhaled air from the victim.
First-aid measures after skin contact
: In case of contact, immediately flush affected areas with plenty of water for at least 15 minutes
while removing contaminated clothing and shoes. Call a physician. Wash clothing before reuse.
Discard contaminated shoes.
First-aid measures after eye contact
: Immediately flush eyes thoroughly with water for at least 15 minutes. Hold the eyelids open and
away from the eyeballs to ensure that all surfaces are flushed thoroughly. Contact an
ophthalmologist immediately.
First-aid measures after ingestion
: Ingestion is not considered a potential route of exposure.
4.2.
Most important symptoms and effects, both acute and delayed

No additional information available
4.3.
Indication of any immediate medical attention and special treatment needed
Obtain medical assistance.
SECTION 5: Firefighting measures

5.1.
Extinguishing media
Suitable extinguishing media

5.2.
Special hazards arising from the substance or mixture
Reactivity
5.3.
: Does not burn. Use extinguishing agents compatible with acid and appropriate for the burning
material.
: No reactivity hazard other than the effects described in sub-sections below.

Advice for firefighters
Firefighting instructions
Special protective equipment for fire fighters
EN (English US)
: DANGER! Toxic, corrosive, high-pressure gas.

Evacuate all personnel from the danger area. Use self-contained breathing apparatus (SCBA)
and protective clothing. Immediately cool containers with water from maximum distance. Stop
flow of gas if safe to do so, while continuing cooling water spray. Remove ignition sources if
safe to do so. Remove containers from area of fire if safe to do so. On-site fire brigades must
comply with OSHA 29 CFR 1910.156 and applicable standards under 29 CFR 1910 Subpart
LFire Protection.
: Standard protective clothing and equipment (Self Contained Breathing Apparatus) for fire
fighters.
SDS ID: P-4606
2/9
Hydrogen chloride
SECTION 6: Accidental release measures

6.1.
Personal precautions, protective equipment and emergency procedures
General measures
6.1.1.
: DANGER: Toxic. Corrosive. Wear a self-contained breathing apparatus and appropriate

personal protective equipment (PPE). (gas tight, chemical-protective) Evacuate personnel to a
safe area. Approach suspected leak area with caution. Remove all sources of ignition. Toxic,
corrosive vapor can spread from spill. Ventilate area or move container to a well-ventilated
area. Before entering the area, especially a confined area, check the atmosphere with an
appropriate device.
For non-emergency personnel

6.1.2.
For emergency responders
6.2.
Environmental precautions
Try to stop release. Reduce vapor with fog or fine water spray. Prevent waste from contaminating
the surrounding environment. Prevent soil and water pollution. Dispose of contents/container in
accordance with local/regional/national/international regulations. Contact supplier for any special
requirements.
6.3.
Methods and material for containment and cleaning up

6.4.
Reference to other sections

See also sections 8 and 13.
SECTION 7: Handling and storage

7.1.
Precautions for safe handling
Precautions for safe handling
7.2.
: Wear leather safety gloves and safety shoes when handling cylinders. Protect cylinders from
physical damage; do not drag, roll, slide or drop. While moving cylinder, always keep in place
removable valve cover. Never attempt to lift a cylinder by its cap; the cap is intended solely to
protect the valve. When moving cylinders, even for short distances, use a cart (trolley, hand
truck, etc.) designed to transport cylinders. Never insert an object (e.g., wrench, screwdriver,
pry bar) into cap openings; doing so may damage the valve and cause a leak. Use an
adjustable strap wrench to remove over-tight or rusted caps. Slowly open the valve. If the
valve is hard to open, discontinue use and contact your supplier. Close the container valve
after each use; keep closed even when empty. Never apply flame or localized heat directly to
any part of the container. High temperatures may damage the container and could cause the
pressure relief device to fail prematurely, venting the container contents. For other precautions
in using this product, see section 16.
Conditions for safe storage, including any incompatibilities
Storage conditions
: Store in a cool, well-ventilated place. Store and use with adequate ventilation. Store only
where temperature will not exceed 125F (52C). Firmly secure containers upright to keep
them from falling or being knocked over. Install valve protection cap, if provided, firmly in place
by hand. Store full and empty containers separately. Use a first-in, first-out inventory system
to prevent storing full containers for long periods.
OTHER PRECAUTIONS FOR HANDLING, STORAGE, AND USE: When handling product
under pressure, use piping and equipment adequately designed to withstand the pressures to
be encountered. Never work on a pressurized system. Use a back flow preventive device in
the piping. Gases can cause rapid suffocation because of oxygen deficiency; store and use
with adequate ventilation. If a leak occurs, close the container valve and blow down the system
in a safe and environmentally correct manner in compliance with all international,
federal/national, state/provincial, and local laws; then repair the leak. Never place a container
where it may become part of an electrical circuit.
7.3.
Specific end use(s)

None.
EN (English US)
SDS ID: P-4606
3/9
Hydrogen chloride
SECTION 8: Exposure controls/personal protection

8.1.
Control parameters
Hydrogen chloride (7647-01-0)

ACGIH
ACGIH TLV-C (ppm)
2 ppm
USA OSHA
OSHA PEL (Ceiling) (mg/m)
7 mg/m
USA OSHA
OSHA PEL (Ceiling) (ppm)
5 ppm
ACGIH
Not established
8.2.
Exposure controls
Appropriate engineering controls
: Use a corrosion-resistant local exhaust ventilation system with sufficient air flow velocity to
maintain concentration below all applicable exposure limits in the worker's breathing zone. A
canopy-type, forced-draft fume hood is preferred.
Hand protection
: Neoprene rubber (HNBR) /.
Eye protection
: Provide readily accessible eye wash stations and safety showers. Wear safety glasses when
handling cylinders; vapor-proof goggles and a face shield during cylinder changeout or
whenever contact with product is possible. Select eye protection in accordance with OSHA 29
CFR 1910.133.
Skin and body protection
: Wear metatarsal shoes and work gloves for cylinder handling, and protective clothing where
needed. Wear appropriate chemical gloves (e.g. neoprene, nitrile, etc.) during cylinder
changeout or wherever contact with product is possible. Select per OSHA 29 CFR 1910.132,
1910.136, and 1910.138.
Respiratory protection
: When workplace conditions warrant respirator use, follow a respiratory protection program that
meets OSHA 29 CFR 1910.134, ANSI Z88.2, or MSHA 30 CFR 72.710 (where applicable).
Use an air-supplied or air-purifying cartridge if the action level is exceeded. Ensure that the
respirator has the appropriate protection factor for the exposure level. If cartridge type
respirators are used, the cartridge must be appropriate for the chemical exposure (e.g., an
organic vapor cartridge). For emergencies or instances with unknown exposure levels, use a
self-contained breathing apparatus (SCBA).
Thermal hazard protection
: Wear cold insulating gloves when transfilling or breaking transfer connections.
SECTION 9: Physical and chemical properties

9.1.
Information on basic physical and chemical properties
Physical state
: Gas
Appearance
: Colorless gas.
Molecular mass
: 36.5 g/mol
Color
: Colorless. Gives off white fumes in moist air.
Odor
: Pungent.
Odor threshold
: No data available
pH
: Not applicable.
Relative evaporation rate (butyl acetate=1)
: No data available
Relative evaporation rate (ether=1)
: Not applicable.
Melting point
: -114 C
Freezing point
: No data available
Boiling point
: -85 C
Flash point
: Not applicable.
Auto-ignition temperature
: Not applicable.
Decomposition temperature
: No data available
Flammability (solid, gas)
: Not Applicable
Vapor pressure
: 4260 kPa
Critical pressure
: 8310 kPa
Relative vapor density at 20 C
: No data available
Relative density
: 1.2
EN (English US)
SDS ID: P-4606
4/9
Hydrogen chloride
Specific gravity / density
: 1.161 - 1.19 g/cm (at 20 C)
Relative gas density
: 1.3
Solubility
: Water: 720000 mg/l
Log Pow
: Not applicable.
Log Kow
: Not applicable.
Viscosity, kinematic
: Not applicable.
Viscosity, dynamic
: Not applicable.
Explosive properties
: Not applicable.
Oxidizing properties
: None.
Explosion limits
: Non flammable.
9.2.
Other information
Gas group
: Liquefied gas
Additional information
: Gas/vapor heavier than air. May accumulate in confined spaces, particularly at or below ground
level.
SECTION 10: Stability and reactivity

10.1.
Reactivity
No reactivity hazard other than the effects described in sub-sections below.
10.2.
Chemical stability
10.3.
Possibility of hazardous reactions
10.4.
Conditions to avoid
10.5.
Incompatible materials
Stable under normal conditions.
May occur.
Avoid moisture in installation systems.
Most common metals and their alloys. Bases. unsaturated organics. metal carbides. Fluorine. metal
acetylides. potassium permanganate. sulfuric acid.
10.6.
Hazardous decomposition products

Hydrogen. Chlorine. Chlorides.
SECTION 11: Toxicological information

11.1.
Information on toxicological effects
Acute toxicity
Hydrogen chloride ( \f )7647-01-0
LD50 oral rat
LD50 dermal rabbit
LC50 inhalation rat (ppm)
ATE US (oral)
ATE US (gases)
: Inhalation:gas: TOXIC IF INHALED.

238 - 277 mg/kg
> 5010 mg/kg
3120 ppm/1h
238.000 mg/kg body weight
1560.000 ppmV/4h
Skin corrosion/irritation
: CAUSES SEVERE SKIN BURNS AND EYE DAMAGE.
Serious eye damage/irritation
: CAUSES SERIOUS EYE DAMAGE.
Respiratory or skin sensitization
: Not classified
Germ cell mutagenicity
: Not classified
Carcinogenicity
: Not classified
pH: Not applicable.

pH: Not applicable.
EN (English US)
SDS ID: P-4606
5/9
Hydrogen chloride
IARC group
3 - Not classifiable
Reproductive toxicity
: Not classified
Specific target organ toxicity (single exposure)
: Not classified
Specific target organ toxicity (repeated

exposure)
: Not classified
Aspiration hazard
: Not classified
SECTION 12: Ecological information

12.1.
Toxicity
Ecology - general
12.2.
: No known ecological damage caused by this product.
Persistence and degradability

Persistence and degradability
12.3.
Not applicable for inorganic gases.
Bioaccumulative potential

Log Pow
Log Kow
Bioaccumulative potential
12.4.
Not applicable.
Not applicable.
No data available.
Mobility in soil

Mobility in soil
Ecology - soil
12.5.
No data available.
Because of its high volatility, the product is unlikely to cause ground or water pollution.
Other adverse effects
Other adverse effects
: May cause pH changes in aqueous ecological systems.
Effect on ozone layer
: None.
Effect on the global warming
: No known effects from this product.
SECTION 13: Disposal considerations

13.1.
Waste treatment methods
Waste disposal recommendations
: Do not attempt to dispose of residual or unused quantities. Return container to supplier.
SECTION 14: Transport information

In accordance with DOT
Transport document description
: UN1050 Hydrogen chloride, anhydrous, 2.3
UN-No.(DOT)
: UN1050
Proper Shipping Name (DOT)
: Hydrogen chloride, anhydrous
Department of Transportation (DOT) Hazard

Classes
: 2.3 - Class 2.3 - Poisonous gas 49 CFR 173.115
Hazard labels (DOT)
: 2.3 - Poison gas

8 - Corrosive
EN (English US)
SDS ID: P-4606
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Hydrogen chloride
DOT Special Provisions (49 CFR 172.102)
: 3 - This material is poisonous by inhalation (see 171.8 of this subchapter) in Hazard Zone C
(see 173.116(a) of this subchapter), and must be described as an inhalation hazard under the
provisions of this subchapter.
N86 - UN pressure receptacles made of aluminum alloy are not authorized.
N89 - When steel UN pressure receptacles are used, only those bearing the H mark are
authorized.
Additional information
Emergency Response Guide (ERG) Number
: 125 (UN1050);157 (UN1789)
Other information
: No supplementary information available.
Special transport precautions
: Avoid transport on vehicles where the load space is not separated from the driver's
compartment. Ensure vehicle driver is aware of the potential hazards of the load and knows
what to do in the event of an accident or an emergency. Before transporting product containers:
- Ensure there is adequate ventilation. - Ensure that containers are firmly secured. - Ensure
cylinder valve is closed and not leaking. - Ensure valve outlet cap nut or plug (where provided)
is correctly fitted. - Ensure valve protection device (where provided) is correctly fitted.
Transport by sea
UN-No. (IMDG)
: 1050
Proper Shipping Name (IMDG)
: HYDROGEN CHLORIDE, ANHYDROUS
Class (IMDG)
: 2 - Gases
MFAG-No
: 125
Air transport
UN-No.(IATA)
: 1050
Proper Shipping Name (IATA)
: Hydrogen chloride, anhydrous
Class (IATA)
: 2
Civil Aeronautics Law
: Gases under pressure/Gases toxic under pressure
SECTION 15: Regulatory information

15.1. US Federal regulations
Listed on the United States TSCA (Toxic Substances Control Act) inventory
Listed on the United States SARA Section 302
Listed on United States SARA Section 313
SARA Section 302 Threshold Planning Quantity
(TPQ)
SARA Section 311/312 Hazard Classes
SARA Section 313 - Emission Reporting
500 (gas only)

Delayed (chronic) health hazard
Immediate (acute) health hazard
Sudden release of pressure hazard
1.0 % (acid aerosols including mists, vapors, gas, fog, and other airborne forms of
any particle size)
15.2. International regulations

CANADA
Listed on the Canadian DSL (Domestic Substances List)
EU-Regulations
Listed on the EEC inventory EINECS (European Inventory of Existing Commercial Chemical Substances)
EN (English US)
SDS ID: P-4606
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Hydrogen chloride
15.2.2. National regulations

Listed on the AICS (Australian Inventory of Chemical Substances)
Listed on IECSC (Inventory of Existing Chemical Substances Produced or Imported in China)
Listed on the Japanese ENCS (Existing & New Chemical Substances) inventory
Listed on the Korean ECL (Existing Chemicals List)
Listed on NZIoC (New Zealand Inventory of Chemicals)
Listed on PICCS (Philippines Inventory of Chemicals and Chemical Substances)
Japanese Poisonous and Deleterious Substances Control Law
Listed on the Canadian IDL (Ingredient Disclosure List)
15.3. US State regulations
Hydrogen chloride(7647-01-0)
U.S. - California - Proposition 65 - Carcinogens List
No
U.S. - California - Proposition 65 - Developmental

Toxicity
No
U.S. - California - Proposition 65 - Reproductive

Toxicity - Female
No
U.S. - California - Proposition 65 - Reproductive

Toxicity - Male
No
State or local regulations
U.S. - Massachusetts - Right To Know List

U.S. - New Jersey - Right to Know Hazardous Substance List
U.S. - Pennsylvania - RTK (Right to Know) - Environmental Hazard List
U.S. - Pennsylvania - RTK (Right to Know) List
SECTION 16: Other information

Revision date
: 3/19/2015 12:00:00 AM
Other information
: When you mix two or more chemicals, you can create additional, unexpected hazards. Obtain
and evaluate the safety information for each component before you produce the mixture.
Consult an industrial hygienist or other trained person when you evaluate the end product.
Before using any plastics, confirm their compatibility with this product.
Praxair asks users of this product to study this SDS and become aware of the product hazards
and safety information. To promote safe use of this product, a user should (1) notify
employees, agents, and contractors of the information in this SDS and of any other known
product hazards and safety information, (2) furnish this information to each purchaser of the
product, and (3) ask each purchaser to notify its employees and customers of the product
hazards and safety information.
The opinions expressed herein are those of qualified experts within Praxair, Inc. We believe
that the information contained herein is current as of the date of this Safety Data Sheet. Since
the use of this information and the conditions of use are not within the control of Praxair, Inc., it
is the user's obligation to determine the conditions of safe use of the product.
Praxair SDSs are furnished on sale or delivery by Praxair or the independent distributors and
suppliers who package and sell our products. To obtain current SDSs for these products,
contact your Praxair sales representative, local distributor, or supplier, or download from
www.praxair.com. If you have questions regarding Praxair SDSs, would like the document
number and date of the latest SDS, or would like the names of the Praxair suppliers in your
area, phone or write the Praxair Call Center (Phone: 1-800-PRAXAIR/1-800-772-9247;
Address: Praxair Call Center, Praxair, Inc., P.O. Box 44, Tonawanda, NY 14151-0044).
PRAXAIR and the Flowing Airstream design are trademarks or registered trademarks of Praxair
Technology, Inc. in the United States and/or other countries.
EN (English US)
SDS ID: P-4606
8/9
Hydrogen chloride
NFPA health hazard
: 3 - Short exposure could cause serious temporary or

residual injury even though prompt medical attention was
given.
NFPA fire hazard
: 0 - Materials that will not burn.
NFPA reactivity
: 1 - Normally stable, but can become unstable at elevated

temperatures and pressures or may react with water with
some release of energy, but not violently.
HMIS III Rating

Health
: 3 Serious Hazard - Major injury likely unless prompt action is taken and medical treatment is
given
Flammability
: 0 Minimal Hazard
Physical
: 3 Serious Hazard
SDS US (GHS HazCom 2012) - Praxair

This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental requirements only. It should not therefore be construed as
guaranteeing any specific property of the product.
EN (English US)
SDS ID: P-4606
9/9

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Hydrogen chloride

Safety Data Sheet P-4606

Revision date: 03/19/2015

SECTION: 1. Product and company identification

Other means of identification

: Anhydrous hydrochloric acid

Use of the substance/mixture

: Industrial use. Use as directed.

Details of the supplier of the safety data sheet

Emergency telephone number

: Onsite Emergency: 1-800-645-4633

SECTION 2: Hazards identification

Classification of the substance or mixture

Signal word (GHS-US)

Hazard statements (GHS-US)

: H280 - CONTAINS GAS UNDER PRESSURE; MAY EXPLODE IF HEATED

Precautionary statements (GHS-US)

SDS ID: P-4606

Revision date: 03/19/2015

rated for cylinder pressure.

Other hazards not contributing to the

Unknown acute toxicity (GHS US)

SECTION 3: Composition/information on ingredients

(CAS No) 7647-01-0

SECTION 4: First aid measures

Description of first aid measures

First-aid measures after inhalation

First-aid measures after skin contact

First-aid measures after eye contact

First-aid measures after ingestion

: Ingestion is not considered a potential route of exposure.

Most important symptoms and effects, both acute and delayed

Indication of any immediate medical attention and special treatment needed

Obtain medical assistance.

SECTION 5: Firefighting measures

Suitable extinguishing media

Special hazards arising from the substance or mixture

: No reactivity hazard other than the effects described in sub-sections below.

Special protective equipment for fire fighters

: DANGER! Toxic, corrosive, high-pressure gas.

SDS ID: P-4606

Revision date: 03/19/2015

SECTION 6: Accidental release measures

Personal precautions, protective equipment and emergency procedures

: DANGER: Toxic. Corrosive. Wear a self-contained breathing apparatus and appropriate

For non-emergency personnel

For emergency responders

No additional information available

Methods and material for containment and cleaning up

Reference to other sections

SECTION 7: Handling and storage

Precautions for safe handling

Precautions for safe handling

Conditions for safe storage, including any incompatibilities

Specific end use(s)

SDS ID: P-4606

Revision date: 03/19/2015

SECTION 8: Exposure controls/personal protection

Hydrogen chloride (7647-01-0)