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Chemistry
Paper 2
Mei
2014
2 hours

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Name : ...

Class : ...

SMK CONVENT BUKIT NANAS KUALA LUMPUR

MID YEAR EXAMINATION FORM 5
2014
CHEMISTRY
PAPER 2
Two hours and thirty minutes
DO NOT OPEN THIS PAPER UNTIL YOU ARE TOLD TO DO SO
For examiner
Section

B
C

Question
1
2
3
4
5
6
7
9

Total
Mark
9
11
9
10
10
11
20
20

Students
Mark

Total

The question paper consists of 18 printed pages including front page

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INFORMATION FOR CANDIDATES

1. This question paper consists of two sections: Section A, Section B Section C.
2. Answer all questions in Section A, B and C.
3. Write your answers for Section A in the spaces provided in the question paper.
4. Write your answers for Section B and C on the test pad provided. Answer questions in
Section B and C in detail. You may use questions, diagrams, tables, graphs and other
suitable methods to explain your answer.
5. Show your working. It may help you to get marks.
6. If you wish to cancel any answer, neatly cross out the answer.
7. The diagrams in the question are not drawn to scale unless stated.
8. Marks allocated for each question or part question are shown in brackets.
9. The time suggested to answer Section A is 60 minutes, and Section B and C is 60 minutes.
10. You may use a non-programmable scientific calculator.
11. Hand in this question paper at the end of the examination.

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3
Section A
[40 marks]
Answer all questions in this section.
The time suggested to complete Section A is 90 minutes.

1.

Diagram 1 shows the chemical symbols which represent three

elements P, Q and R. The letters used are not the actual symbols of the elements.

Diagram 1

(a) (i) What is meant by proton number?

___________________________________________________________________
(1 mark)
(ii) State the proton number for atom P.
___________________________________________________________________
(1 mark)
(b) What is represented by the number 35 for the element Q?
______________________________________________________________________
(1 mark)
(c) (i) Atom Q and R are isotopes. State the difference between the two atoms.
___________________________________________________________________
(1 mark)
(ii) State one uses of isotopes in daily life.
___________________________________________________________________
(1 mark)
(d) (i) Write the electron arrangement of atom Q.
___________________________________________________________________
(1 mark)

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(ii) Determine the number of valence electron for atom Q.

___________________________________________________________________
(1 mark)
(iii)Draw the electron arrangement for atom R.

(2 marks)

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2. Diagram 2 shows part of the Periodic Table of Elements. T, U, V, W, X and Y do not

represent the actual symbol of the elements.

Diagram 2

(a) State two special characteristics of element V.

______________________________________________________________________
(2 marks)
(b) Both element U and X can react with water.
(i) Which element U or X, produce alkaline solution?
____________________________________________________________________
(1 mark)
(ii) Write the chemical equation for the reaction based on your answer in (b)(i).
____________________________________________________________________
(2 marks)
(c) State which element is chemically unreactive. Explain your answer.
______________________________________________________________________
______________________________________________________________________
______________________________________________________________________
(3 marks)
(d) Element W reacts with element T to form a compound with a formula WT4.
(i)

State one physical property of this compound.

___________________________________________________________________
(1 mark)

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(ii)

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Draw the electron arrangement of the compound WT4.

(2 marks)
3.

Table 1 shows type of chemical bond of two compounds.

Compound
Type of chemical bond
Sodium chloride, NaCl Ionic
Carbon dioxide, CO2
..................................
Table 1

(a) State the colour of sodium chloride.

_____________________________________________________________________
(1 mark)
(b) (i) State the type of chemical bond in carbon dioxide.
___________________________________________________________________
(1 mark)
(ii) State the name for another compound that has the same type of chemical bond with
carbon dioxide.
___________________________________________________________________
(1 mark)

(c) Proton numbers of carbon atom and oxygen atom are 6 and 8.

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(i) Write the electron arrangement of oxygen atom.

___________________________________________________________________
(1 mark)
(ii) Draw the diagram of electron arrangement of carbon dioxide.

(2 marks)
(d) (i) Between sodium chloride and carbon dioxide, which compound has a lower melting
point?
____________________________________________________________________
[1 mark]
(ii)

Explain your answer in (d)(i).

____________________________________________________________________
____________________________________________________________________
[2 marks]

4. Diagram 3 shows the series of reactions that involve copper (II) nitrate.

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Diagram 3

(a) Copper (II) nitrate is a salt.

(i) State the meaning of salt.
_________________________________________________________________
(1 mark)
(ii)State the colour of copper (II) nitrate.
___________________________________________________________________
(1 mark)
(b) In Reaction I, copper (II) nitrate is heated strongly to form solid X, gas Y and gas Z.

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(i) Name gas Y

___________________________________________________________________
(1 mark)
(ii)Write the chemical formula of gas Z.
___________________________________________________________________
(1 mark)

(iii) Write the chemical formula of solid X.

_______________________________________________________________
(1 mark)
(c) In Reaction II, solid X is added into a test tube containing hydrochloric acid to form
solution R.
The equation represents the reaction.
X + 2HCl R + H2O
(j) Name

the cation in solution R.

________________________________________________________________
(1 mark)
(ii)State another substance that can be used to replace solid X to produce solution R.
_________________________________________________________________
(1 mark)
(iii) 20 cm3 of 0.5 moldm-3 hydrochloric acid reacts with excess solid X. Calculate
the number of molecules of water produced. [Avogadro constant= 6.02x1023
mol-1]

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10

(3 marks)

5. Diagram 4 shows the flow chart of a series of reactions undergoes by butene.

Diagram 4

(a) The molecular formula of butene is C4H8. State the meaning of molecular formula.
___________________________________________________________________
___________________________________________________________________
(1 mark)
(b) Butene is burnt completely in air to produce substance S and carbon dioxide gas.

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(i) Complete the chemical equation below for the combustion reaction.
C4H8 + ........O2 4CO2 + ......................
(1 mark)
(ii) How many moles of substance S will be produced if 0.2 mol of butene is used in the
reaction?
____________________________________________________________________
(1 mark)
(c) Butene undergoes hydration reaction to form substance P.
(i) Draw the structural formula of substance P

(1 mark)
(ii) Substance P can undergo dehydration to form butene again. Draw a labelled
apparatus set-up for this dehydration reaction.

(2 marks)
(d) (i) Name another chemical substance that can be used to replace acidified potassium
manganate (VII) solution in Process I.
____________________________________________________________________
(1 mark)
(ii) State one physical property of substance Q.

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12

____________________________________________________________________
(1 mark)
(e) Based on Process II,
(i) Name substance R.
____________________________________________________________________
(1 mark)
(ii) what would be observed when substance R is added to water?
____________________________________________________________________
(1 mark)
6. Two experiments are carried out to investigate the rate of reaction of magnesium reacts with
sulphuric acid. Table 2 shows the results of Experiment I and II.
Experiment

I
II

Reactant
Excess magnesium powder
+ 20 cm3 of 0.1 moldm-3
sulphuric acid
Excess magnesium powder
+ 20 cm3 of 0.1 moldm-3
sulphuric acid

Temperature
(oC)

Total volume of gas

collected in 2 minutes
(cm3)

30

22.0

40

37.0

Table 2

(a) Write the ionic equation for the reaction between magnesium and sulphuric acid.
______________________________________________________________________
(2 marks)
(b)Calculate the average rate of the reaction for the first two minutes in cm3s-1.
(i) Experiment I:

(ii) Experiment II:

(2 marks)
(c) Calculate the maximum volume of gas produced in Experiment II.
[1 mol of gas occupies 24 dm3 at room condition]

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(2 marks)

(d)Sketch the graphs of the total volume of gas collected against time for Experiment I and
Experiment II on the same axes.

(2 marks)
(e) Compare the rate of reaction between Experiment I and Experiment II. Explain why
there is a difference in the rate of reaction based on the collision theory.
_______________________________________________________________________
_______________________________________________________________________
_______________________________________________________________________
(3 marks)

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14

Section B
[20 marks]
The time suggested to answer this section is 30 minutes.
7.

(a) Table 3 shows a series of experiment carried out to construct the electrochemical series.
The positive terminal and value for potential difference for the pair of metal X and copper,
Cu are not given. W, X and Y are not the actual symbols of the metals.
Pair of metals
W, X
X, Y
W, Cu
X, Cu

Positive terminal
X
Y
Cu

Potential difference (V)

1.6
0.4
2.9

Table 3

(i) Based on the values of the potential differences, arrange the metals in ascending order
in the electrochemical series
[1 mark]
(ii)

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Predict the positive terminal and the value of potential difference for the pair of
metals X and Cu. Explain your answer.
[3 marks]

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15

(b) Diagram 5.1 and 5.2 show the apparatus set-up used in two experiments to electrolyse
molten lead (II) chloride and 0.0001 moldm-3 hydrochloric acid.

Diagram 5.1
5.1
Diagram

Diagram 5.2

(i) Write the formula of all ions present in both electrolytes in Experiment I and
Experiment II.
[2 marks]
(ii) Different products are formed at electrodes in both experiments.
State the products formed at the anode of Experiment I and Experiment II.
Explain how the products are formed and state the reason.
Write the half equations at the anodes.
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16

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[10 marks]

(c) Diagram 5.3 shows a voltaic cell. Metal R is situated below copper in the electrochemical
series.

Diagram 5.3

State the positive terminal and negative terminal of this cell. Suggest a metal that is
suitable as metal R and a solution that is suitable as solution R.
[4 marks]

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17

Section C
[20 marks]
The time suggested to answer this section is 30 minutes.
8.

(a) Methane is the first member of the homologous series of alkane. While P is the first
member of another homologous series of hydrocarbon with the general formula of CnH2n.
(i) Draw the structural formula of methane.
[1 mark]
(ii) Write the molecular formula of P and name P.
[2 marks]
(iii) Table 4 shows the observation of a test to differentiate between methane and P.
Reaction
Reaction with
bromine water

Methane
Brown colour of bromine
water remains unchanged

P
Brown colour of bromine
water is decolourised

Table 4

Explain why there are differences in observation?

[5 marks]
(b) Diagram 6 shows the reactions of propene.

Diagram 6

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18

(i) Write the chemical equations for the reaction I and III.
[4 marks]
(ii) Reaction II produced another isomer other than propan-2-ol. Draw the structural
formula for this isomer.
[1 mark]
(iii) Describe how propan-2-ol is produced in industry. In your description state also the
conditions needed and chemical equation involved.
[7 marks]

END OF THE QUESTION PAPER

Prepared by,

Checked by,

Approved by,

....

..

...........

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(Pn. Nur Diana Binti Othman)
Subject Coordinator
Form 5

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19
(Pn. Ting Jen Nee)
Head of Panel
SMK Convent Bukit Nanas

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(Pn. Norbani Baba)
Acting Senior Administrative
SMK Convent Bukit Nanas

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