Runge Lenz Vector in Quantum Mechanics

Aanvulling syllabus Lie theorie voor natuurkundigen van G.J.
Heckman
(Mathematisch Instituut KU Nijmegen) door P.E.S. Wormer (Instituut voor
Theoretische Chemie KU Nijmegen).
September 12, 2003.
Introduction
Prof. Heckman gives in his lecture notes (in Dutch) a quantum mechanical/group theoretical treatment of the Kepler problem. He mentions without proof a few properties of the Laplace-Runge-Lenz-Pauli vector, which
are used in his subsequent development. In these notes these properties are
formulated in Theorem 2 and proved. The proofs are made somewhat more
transparent by introduction of the vector operator and its properties. Considering the length of the present notes, it is evident why prof. Heckman
skipped the proof.
Vector operators
Consider two arbitrary linear operators A and B acting on the same linear
space. Then we define the operator Ad A and its nth power (n = 1, 2, . . .)
acting on the operator B, by
(Ad A)0 B B
(Ad A)n B [A, [A, [A, , B]] . . .]
{z
}
|
(1)
(2)
n times
The following result is a well-known lemma needed in the proof of the BakerCampbell-Hausdorff theorem.
A
e Be
= exp[Ad (A)]B
X
(Ad A)k
k=0
k!
The proof of this result, although not difficult, is skipped.

Remember that rotation of a vector a R3 around a unit vector n over
an angle , which moves a to a0 , is given by the operator
a0 = R(n, ) a a cos + n(n a)(1 cos ) + (n a) sin .
Definitions
1. Angular momentum operator: L x p, where p = i.
1
2. For the definition of the vector operator A (A1 , A2 , A3 ) we consider

a rotation around a unit vector n over an angle . If A satisfies
einL A einL = R(n, )A
(3)
A cos + n(n A)(1 cos ) (n A) sin ,
then it is a vector operator.
Sum over repeated indices is implied everywhere and recall that ijk , the
antisymmetric Levi-Civita tensor, obeys the following contraction rule,
kia bja = kb ij kj ib .
(4)
Theorem 1. An operator A = (A1 , A2 , A3 ) is a vector operator if and only

if it satisfies the commutation relations
[Li , Aj ] = iijk Ak .
(5)
In order to prove this theorem we will need the following lemma.

Lemma 1. Let n be a unit vector and let the components of A satisfy the
commutation relations of Eq. (5), then
(Ad n L)2k+1 A = (Ad n L)A
for k 0,
2k
(Ad n L) A = A (n A)n for k 1.
(6)
(7)
Proof. The proof is by mathematical induction. Using Eq. (4) we find

(Ad n L)2 Ai =
=
=
=
[n L, [n L, Ai ]]
nj nk [Lj , [Lk , Ai ]] = nj nk ikia [Lj , Aa ]
nj nk kia jab Ab = nj nk (kj ib kb ij )Ab
Ai n Ani ,
which proves the second statement for k = 1.

[n L, n A]= 0. Indeed, the expression
It is easily shown that
[n L, n A] = ini nj ijk Ak
is a product of ni nj , which is symmetric in i and j and ijk , which is antisymmetric in i and j. Consider now
(Ad n L)3 A = (Ad n L)(Ad n L)2 A
= [n L, A (n A)n] = (Ad n L)A,
2
which proves the first statement for k = 1. For k = 0 this statement is an

identity. The general induction step is easy
(Ad n L)2k A = (Ad n L)(Ad n L)2k1 A
= [n L, [n L, A]] = A n An.
And
(Ad n L)2k+1 A = (Ad n L)(Ad n L)2k A
= [n L, A (n A)n] = (Ad n L)A.
Proof of Theorem 1. If A satisfies the commutation relations, then

exp[Ad i(n L)]A = A +
X
(i)2k
(2k)!
k=1
X
(i)2k+1
k=0
(2k + 1)!
(Ad n L)2k A
(Ad n L)2k+1 A
X

2k
(1)k
A (n A)n
= A+
(2k)!
k=1
2k+1
[in L, A]
(2k + 1)!
k=0

= A + (cos 1) A (n A)n sin n A
= R(n, ) A.
+
(1)k
If A is a vector operator it satisfies Eq. (3). Differentiate this equation

with respect to at = 0
i(n L)A + iA(n L) = i[A, n L] = n A.
Then, taking for n the coordinate axis ei , i.e., (ei )k = ik ,
i[Aj , Li ] = (ei A)j = jkl ik Al = ijl Al .
Corollary: [Li , Ai ] = 0 and L A = A L.

Lemma 2.
3
1. x and p are vector operators.

2. The outer product of any two vector operators is a vector operator.
Proof. Use [xi , xj ] = [pi , pj ] = 0 for all i, j = 1, 2, 3. Use also [pi , xj ] = iij .
[Li , xj ] = abi [xa pb , xj ] = abi xa [pb , xj ] = abi (i)bj = iija xa .
The proof that p is a vector operator is analogous. Consider the vector
operators A and B. It is easily proved by the use of Eq. (4) that
[Li , (A B)j ] abj [Li , Aa Bb ] = iAi Bj iAj Bi = iijk (A B)k .
Corollary: The angular momentum operator L is a vector operator.

Lemma 3. Any vector operator A satisfies
A L = L A + 2iA.
(8)
Proof.
(A L)i = jki Aj Lk = jki (Lk Aj ikjl Al ).
By inspection it is shown that jki kjl = 2il , then
A L = L A + 2iA.
Corollary: L L = iL.
Because [xi , xj ] = 0 and [pi , pj ] = 0 it follows that
x x = 0 and p p = 0.
(9)
Lemma 4. Any three vector operators satisfy:

A (B C) = (A B) C.
(10)
Proof.
A (B C) = Ai (ijk Bj Ck ) = (kij Ai Bj )Ck = (A B) C.
Lemma 5.
xL = Lx=0
pL = Lp=0
(11)
(12)
Proof. x L = x (x p) = (x x) p = 0 = L x,
L p = (x p) p = x (p p) = 0 = p L, where we used Eqs. (10)
and (9) and the fact that both x and p are vector operators.
4
The Runge-Lenz-Pauli operator

Definitions
1. Runge-Lenz-Pauli operator
K
1
1
x
Lp pL+ .
2
2
r
is a vector operator (by second statement of lemma 2).

2. Hydrogen atom Hamiltonian:
2
1
H (p2 ).
2
r
Theorem 2.

Li , Kj
K L
K2

H, K

Ki , Kj
=
=
=
=
=
iijk Kk
LK =0
2H(L2 + 1) + 1
0
2iijk Lk H
Proof. The first assertion follows directly from the fact that K is a vector
operator. Consider L K:
L (L p) = (L L) p = iL p = 0
L (p L) = L (L p + 2ip) = 0
x
1
1
1
L
=
(L x) + x (L ) + (x L) = 0
r
r
r
r
where the middle term vanishes because L(V (r)) = 0 for any central symmetric function V (r). Hence, LK = 0. The operator K is a vector operator,
so that K L = L K = 0.
Turning to K 2 we need two more lemmas.
Lemma 6.
p (p L) = 0
p (L p) = 2ip2
5
(13)
(14)
Proof. p (p L) = (p p) L = 0.
p (L p) = p (p L + 2ip) = 2ip2 [by Eq. (8)].
Lemma 7.
(p L) (p L)
(L p) (p L)
(L p) (L p)
(p L) (L p)
=
=
=
=
p2 L 2
p2 L2
p2 L 2
p2 L2 4p2
(15)
(16)
(17)
(18)
Proof. Use Eq. (4), then

(p L) (p L) = ijk abk pi Lj pa Lb = pi Lj pi Lj pi Lj pj Li
= pi (pi Lj iijk pk )Lj pi (L p)Li
= p2 L2 + i(p p) L = p2 L2 .
It is easily shown with the use of Eqs. (8), (14) and (15) that
(p L) (L p) = (p L) (p L + 2ip) = p2 L2 + 2ip (L p)
= p2 L2 4p2 .
Equations (16) and (17) are proved likewise.
The operator K 2 consists of 9 terms, 4 of which are given by the previous
lemma. Consider
(L p) x = L (p x) = L2 ,
so that (recalling that L2 commutes with 1/r) a further term of K 2 is:
(L p) x
1
L2
= .
r
r
Using Eq. (8) we find

(p L) x
1
L2
1
=
+ 2ip x .
r
r
r
where
ip x
1
1
1
= x = (3 + x )
r
r
r
3 xx 1
2 i
3 + x = + x p.
=
r
r
r
r r
6
(19)
Hence,
(p L) x
1
L2 4 2i
=
+ + x p.
r
r
r
r
(20)
Use that
1
L2
x (p L) =
r
r
1
L2 2i
x (L p) = + x p
r
r
r
(21)
(22)
and we get finally from Eqs. (15), (18), (16), (17), (19), (20), (21), (22) and
from the definition of r: x x/r2 = 1,
2
2
K 2 = (p2 )L2 + p2 + 1 2H(L2 + 1) + 1,
r
r
which proves the third statement of Theorem 2.
We will now show that [H, K] = 0. Because p2 is rotationally invariant,
[Li , p2 ] = 0 and since [pi , p2 ] = 0 it follows directly that [(L p)i , p2 ] =
ijk [Lj pk , p2 ] = 0. Similarly [p L, p2 ] = 0. The operator x commutes with
any operator depending on xi only, hence

x 1
,
= 0.
r r
It is fairly tedious to show the mutual cancellation of the two remaining
terms. We will need
ixi
1
[pi , ] = 3 ,
r
r
and the equations in the following lemma.
Lemma 8.
x L = x(x p) r2 p
L x = (p x)x + pr2
(23)
(24)
Proof.
(x L)i = ijk abk xj xa pb = xj xi pk xj xj pi = xi (x p) r2 pi
(L x)i = ikj abj pa xb xk = pi xk xk pk xi xk = pi r2 (p x)xi .
The first non-vanishing term in [H, K] is given by the following lemma.

7
Lemma 9.
1
x
i
[ p2 , ] = 3 (x L L x)
2
r
2r
Proof. Consider
[pi ,
1
1
xi xj
xj
ij
] = xj [pi , ] + [pi , xj ] = i( 3 )
r
r
r
r
r
(25)
and
[p2 ,
xj
xj
xj
] = pi [pi , ] + [pi , ]pi
r
r
r
xi xj
xi xj
ij
ij
= ipi ( 3 ) + i( 3 )pi .
r
r
r
r
Using Eqs. (23) and (24)

[p2 ,

x
x
1 1
x
] = i p x 3 + 3x p p p
r
r
r
r r
i
i
= 3x L L x 3.
r
r
Observing that x and L commute with 1/r3 , the result follows.

The last non-vanishing term of [H, K] is given by the following lemma.
Lemma 10.

i
1 1
[ , (L p p L)] = 3 (L x) (x L) .
r 2
2r
Proof. Use [Li , 1/r] = [Li , 1/r3 ] = 0, then
n 1
o
1
1
ijk [ , Li pj + pj Li ] = ijk Li [ , pj ] + [ , pj ]Li
r
r
r
ixj ixj
= ijk Li 3 + 3 Li
r
r

i
(L
x)
(x
L)
.
=
k
k
r3
Finally we see that the results of the last two lemmas cancel each other,
so that indeed [H, K] = 0 (the fourth assertion of Theorem 2).
To evaluate [Ki , Kj ] we need a few more lemmas.
Lemma 11.
[(L p)i , pj ] = i(pi pj ij p2 )
Proof.
[(L p)i , pj ] = abi [La pb , pj ] = abi [La , pj ]pb
= abi iajk pk pb = i(pi pj ij pk pk ).
Note that this lemma implies that [(L p)i , pj ] is symmetric in i and j.
Using Eq. (8) and this symmetry, one shows easily that
1
[(L p p L)i , (L p p L)j ] = [(L p)i , (L p)j ].
4
(26)
Lemma 12.
[(L p)i , (L p)j ] = iijk p2 Lk .
Proof. We write Ai (Lp)i and use that it is a vector operator. Remember
that [p2 , Li ] = 0.
[Ai , (L p)j ] = abj [Ai , La pb ] = abj La [Ai , pb ] + abj [Ai , La ]pb
= iabj La (pi pb ib p2 ) iabj aik Ak pb
= i(L p)j pi iaij p2 La iAj pi = iaij p2 La .
Use of Eq. (26) and this lemma shows that the first terms of [Ki , Kj ] satisfy
1
1
[(L p p L)i , (L p p L)j ] = 2iijk p2 Lk .
4
2
In order to reduce the last two terms of [Ki , Kj ] we introduce the following
short hand notation for them:
1
xj
1 xi
Qij [(L p p L)i , ] + [ , (L p p L)j ],
2
r
2 r
we use again Eq. (8) and the fact that [pi , xj /r] is symmetric in i and j [cf.
Eq. (25)] so that
Qij = [(L p)i ,
xj
xi
] + [ , (L p)j ]
r
r
(27)
Note that Qij = Qji so that only the case i 6= j must be considered. We
need the following result:
9
Lemma 13.
(L x)i xj (L x)j xi = r2 (pi xj pj xi ).
Proof. By Eq. (24):
(L x) x = p xr2 .
Or,
ijk (L x)i xj = r2 ijk pi xj
Multiply by i0 j 0 k sum over k, use Eq. (4) and remember that a sum over i
and j is implied,
(i0 i j 0 j i0 j j 0 i )(L x)i xj = r2 (i0 i j 0 j i0 j j 0 i )pi xj ,
from which the lemma follows.
Lemma 14.
Qij = 2iijk
Lk
r
Proof. Use Eqs. (25) and (27), the fact that x/r is a vector operator and
dropping a term in ij , we get
[(L p)i ,
xj
xj
xj
] = abi (La [pb , ] + [La , ]pb )
r
r
r
i(xb xj r2 bj )
xk
= abi La
+ iabi ajk pb
3
r
r
i
La
xk
= 3 (L x)i xj iaji
+ ibj ik pb
r
r
r
i
Lk
xi
= 3 (L x)i xj + iijk
+ i pj
r
r
r
Likewise
[(L p)j ,
xi
i
Lk
xj
] = 3 (L x)j xi + iijk
i pi
r
r
r
r
Use of the previous lemma and the observation that [xi , pj ] = 0, because
i 6= j, proves the lemma.
The last assertion of Theorem 2 follows now by recalling that Qij is a
short hand notation for the two remaining terms in [Ki , Kj ].
10

Runge Lenz Vector in Quantum Mechanics

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Aanvulling syllabus Lie theorie voor natuurkundigen van G.J.

The proof of this result, although not difficult, is skipped.

2. For the definition of the vector operator A (A1 , A2 , A3 ) we consider

Theorem 1. An operator A = (A1 , A2 , A3 ) is a vector operator if and only

In order to prove this theorem we will need the following lemma.

Proof. The proof is by mathematical induction. Using Eq. (4) we find

which proves the second statement for k = 1.

It is easily shown that

which proves the first statement for k = 1. For k = 0 this statement is an

Proof of Theorem 1. If A satisfies the commutation relations, then

If A is a vector operator it satisfies Eq. (3). Differentiate this equation

Corollary: [Li , Ai ] = 0 and L A = A L.

1. x and p are vector operators.

Corollary: The angular momentum operator L is a vector operator.

Lemma 4. Any three vector operators satisfy:

The Runge-Lenz-Pauli operator

is a vector operator (by second statement of lemma 2).

Proof. Use Eq. (4), then

Using Eq. (8) we find

The first non-vanishing term in [H, K] is given by the following lemma.

Using Eqs. (23) and (24)

Observing that x and L commute with 1/r3 , the result follows.

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