SECTION 1: Identification of The Substance/mixture and of The Company/undertaking

safety data sheet
according to Regulation (EC) No. 1907/2006 (REACH), amended by 2015/830/EU
Murexide (C.I. 56085) ACS, for complexometry

article number: T124
Version: 1.0 en
date of compilation: 2016-02-25
SECTION 1: Identification of the substance/mixture and of the

company/undertaking
1.1
1.2
Product identifier
Identification of the substance
Murexide (C.I. 56085)
Article number
T124
Registration number (REACH)
This information is not available.
EC number
221-266-6
CAS number
3051-09-0
Relevant identified uses of the substance or mixture and uses advised against
Identified uses:
1.3
laboratory chemical
Details of the supplier of the safety data sheet

Carl Roth GmbH + Co KG
Schoemperlenstr. 3-5
D-76185 Karlsruhe
Germany
Telephone: +49 (0) 721 - 56 06 0
Telefax: +49 (0) 721 - 56 06 149
e-mail: [email protected]
Website: www.carlroth.de
1.4
Competent person responsible for the safety data

sheet
: Department Health, Safety and Environment
e-mail (competent person)
: [email protected]
Emergency telephone number

Emergency information service
Poison Centre Munich: +49/(0)89 19240
SECTION 2: Hazards identification

2.1
Classification of the substance or mixture

Classification according to Regulation (EC) No 1272/2008 (CLP)
This substance does not meet the criteria for classification in accordance with Regulation No
1272/2008/EC.
2.2
Label elements
Labelling according to Regulation (EC) No 1272/2008 (CLP)
not required
Signal word
2.3
not required
Other hazards
There is no additional information.
United Kingdom (en)
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SECTION 3: Composition/information on ingredients

3.1
Substances
Name of substance
Murexide (C.I. 56085)
EC number
221-266-6
CAS number
3051-09-0
Molecular formula
CHNO
Molar mass
284,2 g/mol
SECTION 4: First aid measures

4.1
Description of first aid measures
General notes
Take off contaminated clothing.
Following inhalation
Provide fresh air. In all cases of doubt, or when symptoms persist, seek medical advice.
Following skin contact
Rinse skin with water/shower. In all cases of doubt, or when symptoms persist, seek medical advice.
Following eye contact
Rinse cautiously with water for several minutes. In all cases of doubt, or when symptoms persist, seek
medical advice.
Following ingestion
Rinse mouth. Call a doctor if you feel unwell.
4.2
Most important symptoms and effects, both acute and delayed

Symptoms and effects are not known to date
4.3
Indication of any immediate medical attention and special treatment needed

none
SECTION 5: Firefighting measures

5.1
Extinguishing media
Suitable extinguishing media
Co-ordinate fire-fighting measures to the fire surroundings
water spray, foam, dry extinguishing powder, carbon dioxide (CO2)
Unsuitable extinguishing media
water jet
United Kingdom (en)
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5.2
Special hazards arising from the substance or mixture

Combustible.
Hazardous combustion products
In case of fire may be liberated: nitrogen oxides (NOx), carbon monoxide (CO), carbon dioxide (CO2)
5.3
Advice for firefighters

Fight fire with normal precautions from a reasonable distance. Wear self-contained breathing apparatus.
SECTION 6: Accidental release measures

6.1
Personal precautions, protective equipment and emergency procedures

For non-emergency personnel
Control of dust.
6.2
Environmental precautions
Keep away from drains, surface and ground water.
6.3
Methods and material for containment and cleaning up

Advices on how to contain a spill
Covering of drains.
Advices on how to clean up a spill
Take up mechanically.
Other information relating to spills and releases
Place in appropriate containers for disposal.
Reference to other sections
Hazardous combustion products: see section 5. Personal protective equipment: see section 8.
Incompatible materials: see section 10. Disposal considerations: see section 13.
SECTION 7: Handling and storage

7.1
Precautions for safe handling

No special measures are necessary.
Advice on general occupational hygiene
Keep away from food, drink and animal feedingstuffs.
7.2
Conditions for safe storage, including any incompatibilities

Store in a dry place.
Incompatible substances or mixtures
Observe hints for combined storage.
Control of effects
Protect against external exposure, such as
direct light irradiation
Consideration of other advice
Ventilation requirements
Use local and general ventilation.
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Specific designs for storage rooms or vessels
Recommended storage temperature: 15 - 25 C.
7.3
Specific end use(s)

No information available.
SECTION 8: Exposure controls/personal protection

8.1
Control parameters
National limit values
Occupational exposure limit values (Workplace Exposure Limits)
8.2
Exposure controls
Individual protection measures (personal protective equipment)
Eye/face protection
Use safety goggle with side protection.
Skin protection
hand protection
Wear suitable gloves. Chemical protection gloves are suitable, which are tested according to EN 374.
type of material
NBR (Nitrile rubber)
material thickness
>0,11 mm.
breakthrough times of the glove material
>480 minutes (permeation: level 6)
other protection measures
Take recovery periods for skin regeneration. Preventive skin protection (barrier creams/ointments) is
recommended.
Respiratory protection
Respiratory protection necessary at: Dust formation. Particulate filter device (EN 143). P1 (filters at
least 80 % of airborne particles, colour code: White).
Environmental exposure controls
Keep away from drains, surface and ground water.
United Kingdom (en)
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SECTION 9: Physical and chemical properties

9.1
Information on basic physical and chemical properties

Appearance
Physical state
solid
Colour
red brown
Odour
odourless
Odour threshold
No data available
Other physical and chemical parameters

pH (value)
5 (water: 1 g/l, 20 C)
Melting point/freezing point
not determined
Initial boiling point and boiling range
Flash point
not applicable
Evaporation rate
no data available
Flammability (solid, gas)
Non-flammable
Explosive limits
lower explosion limit (LEL)
this information is not available
upper explosion limit (UEL)
this information is not available
Explosion limits of dust clouds
these information are not available
Vapour pressure
Density
0,7 g/cm at 20 C
Vapour density
Relative density
Information on this property is not available.
Solubility(ies)
Water solubility
1 g/l at 20 C
Partition coefficient
n-octanol/water (log KOW)
Auto-ignition temperature
Information on this property is not available.
Decomposition temperature
no data available
Viscosity
not relevant (solid matter)
Explosive properties
none
Oxidising properties
none
United Kingdom (en)
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9.2
Other information
SECTION 10: Stability and reactivity

10.1
Reactivity
the product in the delivered form is not dust explosion capable; the enrichment of fine dust however
leads to the danger of dust explosion.
10.2
Chemical stability
The material is stable under normal ambient and anticipated storage and handling conditions of temperature and pressure.
10.3
Possibility of hazardous reactions

Violent reaction with: Strong oxidiser
10.4
Conditions to avoid
Direct light irradiation.
10.5
Incompatible materials
10.6
Hazardous decomposition products

Hazardous combustion products: see section 5.
SECTION 11: Toxicological information

11.1
Information on toxicological effects

Acute toxicity
Shall not be classified as acutely toxic.
Skin corrosion/irritation
Shall not be classified as corrosive/irritant to skin.
Serious eye damage/eye irritation
Shall not be classified as seriously damaging to the eye or eye irritant.
Respiratory or skin sensitisation
Shall not be classified as a respiratory or skin sensitiser.
Summary of evaluation of the CMR properties
Shall not be classified as germ cell mutagenic, carcinogenic nor as a reproductive toxicant
Specific target organ toxicity - single exposure
Shall not be classified as a specific target organ toxicant (single exposure).
Specific target organ toxicity - repeated exposure
Shall not be classified as a specific target organ toxicant (repeated exposure).
Aspiration hazard
Shall not be classified as presenting an aspiration hazard.
Symptoms related to the physical, chemical and toxicological characteristics
If swallowed
data are not available
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If in eyes
If inhaled
If on skin
Other information
None
SECTION 12: Ecological information

12.1
Toxicity
acc. to 1272/2008/EC: Shall not be classified as hazardous to the aquatic environment.
12.2
Process of degradability
Theoretical Oxygen Demand with nitrification: 0,8116 mg/mg
Theoretical Oxygen Demand: 0,2815 mg/mg
Theoretical Carbon Dioxide: 1,239 mg/mg
12.3
Bioaccumulative potential
Data are not available.
12.4
Mobility in soil
12.5
Results of PBT and vPvB assessment

12.6
Other adverse effects

Hazardous to water.
SECTION 13: Disposal considerations

13.1
Waste treatment methods

Consult the appropriate local waste disposal expert about waste disposal.
Sewage disposal-relevant information
Do not empty into drains.
13.2
Relevant provisions relating to waste

The allocation of waste identity numbers/waste descriptions must be carried out according to the
EEC, specific to the industry and process.
13.3
Remarks
Waste shall be separated into the categories that can be handled separately by the local or national
waste management facilities. Please consider the relevant national or regional provisions.
United Kingdom (en)
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SECTION 14: Transport information

14.1
UN number
(not subject to transport regulations)
14.2
UN proper shipping name
not relevant
14.3
Transport hazard class(es)
not relevant
Class
14.4
Packing group
not relevant
14.5
Environmental hazards
none (non-environmentally hazardous acc. to the danger-
14.6
Special precautions for user

14.7
Transport in bulk according to Annex II of MARPOL and the IBC Code

The cargo is not intended to be carried in bulk.
14.8
Information for each of the UN Model Regulations
ous goods regulations)
Transport of dangerous goods by road, rail and inland waterway (ADR/RID/ADN)

Not subject to ADR, RID and ADN.
International Maritime Dangerous Goods Code (IMDG)
Not subject to IMDG.
SECTION 15: Regulatory information

15.1
Safety, health and environmental regulations/legislation specific for the substance or mixture
Relevant provisions of the European Union (EU)
Regulation 649/2012/EU concerning the export and import of hazardous chemicals (PIC)
Not listed.
Regulation 1005/2009/EC on substances that deplete the ozone layer (ODS)
Not listed.
Regulation 850/2004/EC on persistent organic pollutants (POP)
Not listed.
Restrictions according to REACH, Annex XVII
not listed
List of substances subject to authorisation (REACH, Annex XIV)
not listed
Directive 2011/65/EU on the restriction of the use of certain hazardous substances in electrical
and electronic equipment (RoHS) - Annex II
not listed
Regulation 166/2006/EC concerning the establishment of a European Pollutant Release and
Transfer Register (PRTR)
not listed
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Directive 2000/60/EC establishing a framework for Community action in the field of water policy
(WFD)
not listed
National inventories
Substance is listed in the following national inventories:
15.2
EINECS/ELINCS/NLP (Europe)
Chemical Safety Assessment

No Chemical Safety Assessment has been carried out for this substance.
SECTION 16: Other information

Abbreviations and acronyms
Abbr.
Descriptions of used abbreviations
ADN
Accord europen relatif au transport international des marchandises dangereuses par voies de navigation
intrieures (European Agreement concerning the International Carriage of Dangerous Goods by Inland Waterways)
ADR
Accord europen relatif au transport international des marchandises dangereuses par route (European
Agreement concerning the International Carriage of Dangerous Goods by Road)
CAS
Chemical Abstracts Service (service that maintains the most comprehensive list of chemical substances)
CLP
Regulation (EC) No 1272/2008 on classification, labelling and packaging of substances and mixtures
CMR
Carcinogenic, Mutagenic or toxic for Reproduction
EINECS
European Inventory of Existing Commercial Chemical Substances
ELINCS
European List of Notified Chemical Substances
GHS
"Globally Harmonized System of Classification and Labelling of Chemicals" developed by the United Nations
IMDG
International Maritime Dangerous Goods Code
MARPOL
International Convention for the Prevention of Pollution from Ships (abbr. of "Marine Pollutant)
NLP
No-Longer Polymer
PBT
Persistent, Bioaccumulative and Toxic
REACH
Registration, Evaluation, Authorisation and Restriction of Chemicals
RID
Rglement concernant le transport International ferroviaire des marchandises Dangereuses (Regulations

concerning the International carriage of Dangerous goods by Rail)
vPvB
very Persistent and very Bioaccumulative
Key literature references and sources for data

- Regulation (EC) No. 1907/2006 (REACH), amended by 2015/830/EU
- Regulation (EC) No. 1272/2008 (CLP, EU GHS)
List of relevant phrases (code and full text as stated in chapter 2 and 3)
not relevant.
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safety data sheet


Disclaimer
The above information describes exclusively the safety requirements of the product and is based on
our present-day knowledge. The information is intended to give you advice about the safe handling of
the product named in this safety data sheet, for storage, processing, transport and disposal. The information cannot be transferred to other products. In the case of mixing the product with other
products or in the case of processing, the information on this safety data sheet is not necessarily valid
for the new made-up material.
United Kingdom (en)
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safety data sheet

according to Regulation (EC) No. 1907/2006 (REACH), amended by 2015/830/EU

Murexide (C.I. 56085) ACS, for complexometry

date of compilation: 2016-02-25