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ISSN: 2169-0316
Research Article
Open Access
Trivedi Global Inc., 10624 S Eastern Avenue Suite A-969, Henderson, NV 89052, USA
Trivedi Science Research Laboratory Pvt. Ltd., Hall-A, Chinar Mega Mall, Chinar Fortune City, Hoshangabad Rd., Bhopal-462026, Madhya Pradesh, India
Abstract
Magnesium nitride (Mg3N2) has gained extensive attention due to its catalytic and optoelectronic properties. The
present investigation was aimed to evaluate the effect of biofield energy treatment on physical and thermal properties of
Mg3N2 powder. The Mg3N2 powder was divided into two parts i.e. control and treated. The control part was remained as
untreated and the treated part was subjected to the Mr. Trivedis biofield energy treatment. Subsequently, the control and
treated Mg3N2 samples were characterized using differential scanning calorimetry (DSC), thermogravimetric analysis
(TGA), and X-ray diffraction (XRD). The DSC results showed the specific heat capacity of 2.24 Jg-1C-1 in control,
which increased upto 5.55 Jg-1C-1 in treated Mg3N2 sample. The TGA data revealed that the onset temperature for the
formation of magnesium oxide, possibly due to oxidation of Mg3N2 in the presence of air and moisture, was reduced
from 421.0C (control) to 391.33C in treated sample. Besides, the XRD data revealed that the lattice parameter and
unit cell volume of treated Mg3N2 samples were increased by 0.20 and 0.61% respectively, as compared to the control.
The shifting of all peaks toward lower Bragg angle was observed in treated sample as compared to the control. The XRD
diffractogram also showed that the relative intensities of all peaks were altered in treated sample as compared to control.
In addition, the density of treated Mg3N2 was reduced by 0.60% as compared to control. Furthermore, the crystallite
size was significantly increased from 108.05 nm (control) to 144.04 nm in treated sample as compared to the control.
Altogether data suggest that biofield energy treatment has substantially altered the physical and thermal properties of
Mg3N2 powder. Thus, the biofield treatment could be applied to modulate the catalytic and optoelectronic properties of
Mg3N2 for chemical and semiconductor industries.
Citation: Trivedi MK, Tallapragada RM, Branton A, Trivedi D, Nayak G, et al. (2015) Evaluation of Thermal and Physical Properties of Magnesium
Nitride Powder: Impact of Biofield Energy Treatment. Ind Eng Manage 4: 177. doi:10.4172/2169-0316.1000177
Page 2 of 6
Methods
as given below:
DSC analysis
The thermal analysis of Mg3N2 powder was performed using DSC.
For DSC study, Pyris-6 Perkin Elmer, with a heating rate of 10C/min
under nitrogen atmosphere was used. The specific heat capacity of
Mg3N2 powder was calculated from the DSC curve.
TGA-DTG analysis
TGA analysis was carried out using Mettler Toledo TGA-DTG
system. The samples were heated from room temperature to 900C
with a heating rate of 10C/min. The change in weight of the sample
was observed in TGA curve, whereas the DTG curve provided the Tmax,
where sample lost maximum of its weight.
XRD study
The XRD analysis of control and treated Mg3N2 powder was carried
out on Phillips, Holland PW 1710 X-ray diffractometer system. It had
a copper anode with nickel filter. The radiation of wavelength used by
the XRD system was 1.54056. This XRD system provided the data in
the form of a chart of 2 vs. intensity and a detailed table containing
peak intensity counts, d value (), peak width (), relative intensity
(%) etc. Further, the PowderX software was used to calculate lattice
parameter and unit cell volume of Mg3N2 powder samples. The weight
of the unit cell was calculated as, molecular weight multiplied by the
number of atoms present in a unit cell. Also, the density of the unit cell
was computed as follows:
Density =
[VTreated VControl ]
100
VControl
Where VControl and VTreated are the unit cell volume of control and
treated samples respectively. Similarly, the percent change in all other
parameters such as lattice parameter, density, molecular weight, and
crystallite size were calculated.
Citation: Trivedi MK, Tallapragada RM, Branton A, Trivedi D, Nayak G, et al. (2015) Evaluation of Thermal and Physical Properties of Magnesium
Nitride Powder: Impact of Biofield Energy Treatment. Ind Eng Manage 4: 177. doi:10.4172/2169-0316.1000177
Page 3 of 6
H (J/g)
Control
285.09
342.47
363.45
175.6
2.24
T1
269.74
329.84
354.24
277.6
5.09
T2
297.88
355.63
407.80
610.1
5.55
T3
297.57
349.9
382.42
479.7
5.65
of one gram substance by one degree Celsius, was 2.24 Jg-1C-1 in the
control Mg3N2 sample, which was significantly increased to 5.09, 5.55,
and 5.65 J g-1C-1 in T1, T2, and T3 samples, respectively. It indicated
that Cp was substantially increased by 127.22, 147.63, and 152.23% in
treated T1, T2, and T3 samples, respectively as compared to the control.
Moreover, our group previously reported that biofield treatment had
altered the latent heat of fusion in cadmium powder [19]. The specific
heat capacity is depended on the number of degrees of freedom. Like
Ind Eng Manage
ISSN: 2169-0316, IEM an open access journal
Citation: Trivedi MK, Tallapragada RM, Branton A, Trivedi D, Nayak G, et al. (2015) Evaluation of Thermal and Physical Properties of Magnesium
Nitride Powder: Impact of Biofield Energy Treatment. Ind Eng Manage 4: 177. doi:10.4172/2169-0316.1000177
Page 4 of 6
300.00
T1
Percent change
250.00
T2
T3
200.00
150.00
100.00
50.00
0.00
H
TGA analysis
The TGA analysis of Mg3N2 powder was carried out in the
temperature range 0-900C, under nitrogen atmosphere. Figure 3
shows the TGA curve of control and treated Mg3N2 samples. The control
sample showed that the sample lost 4.10% of its initial weight till 421C,
afterward the weight of the sample was continuously increased. It was
reported that the reduction in weight loss of Mg3N2 in TGA curve in
N2 atmosphere under 500C was due to the release of H2O, CO2, N2
and O2 from the surface of powder [22]. However, the weight of the
sample was started to increase after 421C. It is reported that during
TGA analysis, the presence of water and oxygen oxidises the Mg3N2 to
MgO and increase the weight of the sample [23]. The DTG showed the
control sample gained its maximum weight at 582.33C, possibly due to
oxidation of Mg3N2. Furthermore, the control sample was continued to
gain the weight by 4.25% till temperature reach to 657.47C. However,
the treated sample lost its weight of 2.66% upto 391.33C, possibly due
to release of H2O, CO2, N2 and O2 from the surface of powder. After
that the treated sample was started to gain the weight at 391.33C that
might be due to oxidation of Mg3N2. The DTG showed that sample
Ind Eng Manage
ISSN: 2169-0316, IEM an open access journal
Citation: Trivedi MK, Tallapragada RM, Branton A, Trivedi D, Nayak G, et al. (2015) Evaluation of Thermal and Physical Properties of Magnesium
Nitride Powder: Impact of Biofield Energy Treatment. Ind Eng Manage 4: 177. doi:10.4172/2169-0316.1000177
Page 5 of 6
Plane
(hkl)
2 (Degree)
Control
Relative
Intensity
2 (Degree)
Treated
Relative
Intensity
211
21.89
31.7
21.80
44.6
222
31.10
50.4
31.03
67.8
321
33.67
76.5
33.58
97.4
400
36.05
43.9
35.97
65.7
332
42.57
58.7
42.47
79.6
531
51.91
100
51.81
100
440
52.08
41.6
51.98
51.8
721
69.31
27
69.21
22.5
732
75.05
18.4
74.97
16.8
Table 2: Effect of biofield energy treatment on the Bragg angle (2) and relative
intensities of XRD peaks of magnesium nitride powder.
Group
Lattice
parameter ()
Unit cell
volume
(10-23cm3)
Density
(g/cc)
Molecular
weight (g/
mol)
Crystallite
size
(nm)
Control
9.9551
98.6586
2.716
100.855
108.05
Treated
9.9752
99.2586
2.699
101.469
144.04
Percent
change
0.20
0.61
-0.60
0.61
33.30
Table 3: Effect of biofield energy treatment on the lattice parameter, unti cell
volume, density, molecular weight and crystallite size of magnesium nitride.
such as lattice parameters, unit cell volume etc. The XRD diffractogram
of control and treated Mg3N2 samples are presented in Figure 4. The
control sample showed the crystalline peaks at 2 equal to 21.89,
31.10, 33.67, 36.05, 42.57, 51.91, 52.08, 69.31, and 75.05,
which were indexed to the crystalline plane (211), (222), (321), (400),
(332), (531), (440), (721), and (732) respectively, according to Joint
Committee on Powder Diffraction Standards (JCPDS) card No. 350778 [24]. However, treated sample showed crystalline peaks at 21.80,
31.03, 33.58, 35.97, 42.47, 51.81, 51.98, 69.21, and 74.97. This
indicated that all peaks in the treated sample were shifted to lower
Bragg angle as compared to the control. Also, the peak corresponding
to plane (531) was found to be the most intense among other peaks
in both control and treated samples. Further, the relative intensities of
all peaks in control and treated sample were summarized in Table 2.
The data showed that relative intensities of all peaks were significantly
altered in the treated sample as compared to the control. Inoue et
al. reported that the change in crystal morphology leads to alter
the relative intensities of XRD peaks [25]. Also, our group reported
that the biofield treatment had altered the particle size, and surface
morphology in zinc [10] and antimony powder [11]. Thus, it is possible
that the size, shape and surface morphology of treated Mg3N2 might
alter after biofield treatment and that might be the probable cause for
Ind Eng Manage
ISSN: 2169-0316, IEM an open access journal
Citation: Trivedi MK, Tallapragada RM, Branton A, Trivedi D, Nayak G, et al. (2015) Evaluation of Thermal and Physical Properties of Magnesium
Nitride Powder: Impact of Biofield Energy Treatment. Ind Eng Manage 4: 177. doi:10.4172/2169-0316.1000177
Page 6 of 6
Conclusions
In summary, the biofield energy treatment has substantially altered
the specific heat capacity, crystallite size, and unit cell parameters. The
specific heat capacity of treated Mg3N2 was significantly increased up to
152.23% as compared to the control. The biofield treatment showed the
alteration in the lattice parameter (0.20%), unit cell volume (0.61%),
density (-0.60%), and molecular weight (0.61%) in treated sample as
compared to control. On the basis of alteration in relative intensities of
XRD peaks in treated sample as compared to control, it is concluded
that the biofield energy treatment probably altered the surface
morphology of the treated Mg3N2 powder. In addition, the crystallite
size of the treated sample was significantly increased by 33.30% as
compared to control. Therefore, based on the above outcomes it is
concluded that biofield treated Mg3N2 could be more useful in chemical
and optoelectronic properties.
Acknowledgement
Authors gratefully acknowledged Dr. Cheng Dong of NLSC from Institute
of Physics, and Chinese academy of sciences for providing the facilities to use
PowderX software for analyzing XRD data. Authors also would like to thank Trivedi
science, Trivedi master wellness and Trivedi testimonials for their support during
the work.
13. Dhabade VV, Tallapragada RM, Trivedi MK (2009) Effect of external energy
on atomic, crystalline and powder characteristics of antimony and bismuth
powders. Bull Mater Sci 32: 471-479.
14. Trivedi MK, Tallapragada RM, Branton A, Trivedi D, Nayak G, et al. (2015)
Potential impact of biofield treatment on atomic and physical characteristics of
magnesium. Vitam Miner 3: 129.
15. Trivedi MK, Nayak G, Patil S, Tallapragada RM, Latiyal O (2015) Studies of the
atomic and crystalline characteristics of ceramic oxide nano powders after bio
field treatment. Ind Eng Manage 4: 161.
16. Trivedi MK, Nayak G, Patil S, Tallapragada RM, Latiyal O, et al. (2015) Impact
of biofield treatment on atomic and structural characteristics of barium titanate
powder. Ind Eng Manage 4: 166.
17. Trivedi MK, Nayak G, Tallapragada RM, Patil S, Latiyal O, et al. (2015) Effect
of biofield treatment on structural and morphological properties of silicon carbide.
J Powder Metall Min 4: 132.
18. Trivedi MK, Nayak G, Patil S, Tallapragada RM, Latiyal O (2015) Evaluation
of biofield treatment on physical, atomic and structural characteristics of
manganese (II, III) oxide. J Material Sci Eng 4: 177.
19. Trivedi MK, Nayak G, Patil S, Tallapragada RM, Latiyal O, et al. (2015) An
evaluation of biofield treatment on thermal, physical and structural properties of
cadmium powder. J Thermodyn Catal 6: 147.
20. Curry JA, Webster PJ (1999) Thermodynamics of atmospheres and ocean.
Academic Press Medical.
References
25. Inoue M, Hirasawa I (2013) The relationship between crystal morphology and
XRD peak intensity on CaSO42H2O. J Cryst Growth 380: 169-175.
Special features: