E E - 2.303RT Log (M) NF (M) : Previous HSE Questions From The Chapter "ELECTROCHEMISTRY"

Previous HSE Questions from the chapter ELECTROCHEMISTRY
1. a) The cell reaction in Daniel cell is Zn(s) + Cu2+(aq) Zn2+(aq) + Cu(s) and Nernst equation for single
electrode potential for general electrode reaction Mn+(aq) + ne- M(s) is
EMn+/M = E0Mn+/M - 2.303RT log [M]
nF
[M n+]
Derive Nernst equation for Daniel cell.
(3)
b) Daniel cell is a primary cell while lead storage cell is a secondary cell. Write any one difference
between primary and secondary cell. (1)
[March 2014]
2. Fuel cells are special types of Galvanic cells.
a) i) What are galvanic cells?
(1)
ii) Write any two advantages of fuel cells.
(1)
b) Write the electrode reactions in H2 O2 fuel cell.
(2)
[SAY 2014]
3. We can construct innumerable number of Galvanic cells on the pattern of Daniel cell by taking
combination of different half cells.
a)
What is a Galvanic cell?
(1)
b)
Name the anode and cathode used in the Daniel cell?
(1)
+
()
c)
Name the cell represented by Pt(s)/H2(g)/H (aq).
d)
According to the convention, what is the potential of the above cell at all temperatures? (1)
e) Write the use of the above cell?
()
[SAY 2013 & 2012]
4. With decrease in concentration of an electrolytic solution, conductivity () decreases and molar
conductivity (m) increases.
i)
Write the equation showing the relationship between conductivity and molar conductivity. (1)
ii) How will you account for the increase in molar conductivity with decrease in concentration? (1)
iii) Limiting molar conductivity (0m) of a strong electrolyte can be determined by graphical
extrapolation method. Suggest a method for the determination of limiting molar conductivity of a weak
electrolyte, taking acetic acid (CH3COOH) as example. (1)
[March 2013]
5. Daniel cell is a galvanic cell made of Zn and Cu electrodes.
i) Write anode and cathode reactions in Daniel cell?
(1)
n+
ii) Nernst equation for the electrode reaction M + ne M is:
EMn+/M = E0Mn+/M (2.303RT/nF) log1/[Mn+]. Derive Nernst equation for Daniel cell. (3) [March 2012]
6. Leclanche cell, Lead storage cell and Fuel cell are galvanic cells having different uses.
a) Among these, Leclanche cell is a primary cell and lead storage cell is a secondary cell. Write any 2
differences between primary cell and secondary cell. (2)
b) What is a fuel cell?
(1)
(1)
[March 2012]
c) Write the overall cell reaction in H2 O2 fuel cell?
7. The limiting molar conductivity of an electrolyte is obtained by adding the limiting molar conductivities
of cation and anion of the electrolyte.
a) Name the above law.
()
b) What is meant by limiting molar conductivity? ()
c) Explain how conductivity measurements help to determine the ionisation constant of a weak
electrolyte like acetic acid.
(1)
d) Explain the change of conductivity and molar conductivity of a solution with dilution? (2) [March11]
8. The standard electrode potentials of some electrodes are given below:
E0(Zn2+/Zn) = -0.76V, E0(Cu2+/Cu) = 0.34V, E0(Ag+/Ag) = 0.8V, E0(H+/H2) = 0 V.
HSSLIVE.IN
Page 1
a) Can CuSO4 solution be kept in silver vessel?

()
()
b) Zn or Cu, which can displace hydrogen from dil. H2SO4?
c) What is the reaction taking place at SHE when it is connected with Ag+/Ag electrode to form a
galvanic cell?
(1)
d) Find the value of Kc (equilibrium constant) in the Daniel cell at 298K. (2)
[SAY 2011]
9. From the position of elements in the electrochemical series, Cu can displace Ag from AgNO3 solution.
a) Represent the cell constructed with Cu and Ag electrodes.
(1)
b) Write down the cell reaction taking place at the anode and the cathode. (2)
c) Write the Nernst equation for the above cell reaction. (1) [March 2010]
10. Lead storage cell is the commonly used secondary cell in automobiles.
a) What is a secondary cell? (1)
b) What are the anode and cathode of the cell?
(1)
c) Write down the reactions at anode and cathode during discharging of the cell? (2) [March 2010]
11. Certain Galvanic cells are designed to convert the energy of combustion of fuels directly into electrical
energy.
a) Name the above type of Galvanic cells. ()
b) Give an example for the above cell.
()
c) Represent the reactions taking place at anode and cathode of the above cell. (2)
d) Mention any two advantages of the above cell. (1)
[March 2009]
12. The graphs showing the variation of molar conductance with concentration for weak and strong acids are
given.
a) Explain the Debye-Huckel-Onsagar equation? (1)
b) What is molar conductance?
(1)
c) Calculate the molar conductance at infinite dilution of NH4OH.
Given that 0m for NaCl, NaOH and NH4Cl are 126.4, 248.1 and
129.8 ohm-1cm2mol-1.
(2)
[March 2008]
HSSLIVE.IN
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Previous HSE Questions from the chapter ELECTROCHEMISTRY

a) Can CuSO4 solution be kept in silver vessel?

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