CHEE 321: Chemical Reaction Engineering: (Fogler 2.5, 4.3, 8.5) (Fogler 3.2.3, Examples in CH 4 and 8)
CHEE 321: Chemical Reaction Engineering: (Fogler 2.5, 4.3, 8.5) (Fogler 3.2.3, Examples in CH 4 and 8)
CHEE 321: Chemical Reaction Engineering: (Fogler 2.5, 4.3, 8.5) (Fogler 3.2.3, Examples in CH 4 and 8)
CSTR in series
CA0
X=0
v0
V1 ; k1
CA1
CA2
X=X1
X=X2
V2 ; k2
FA0 FA
v [C C A1 ]
V1 =
= 0 A0
k1C A1
(rA ) at X = X 1
V2 =
1k1 =
[C A0 C A1 ] C A0
=
1
C A1
C A1
C A1 =
C A0
1 + 1k1
v [C C A 2 ]
FA1 FA 2
= 0 A1
k 2C A 2
(rA ) at X = X 2
2 k2 =
[C A1 C A 2 ] C A1
=
1
C A2
C A2
C A2 =
C A2 =
C A1
1 + 2k2
C A0
[1 + 1k1 ][1 + 2 k 2 ]
CAn
CA n-1
V
=
v0
C A1 =
C A0
1+ k
C A2 =
X=Xn
C An
Fogler 4.3.2
X=Xn-1
C A3 =
C A2
1+ k
C An =
C An 1
1+ k
C A0
C A0
=
=
n
n
(1 + k )
(1 + Da)
First-order reaction
rA0 V V (kC A0 )
Da =
=
= k
FA0
v0C A0
Second-order reaction
rA0 V V (kC A2 0 )
Da =
=
= k C A0
FA0
v0C A0
CA1
X=X1
v0/n
CA2
CA0
X=0
v0
X=X2
v0/n
CA3
v0/n
Fogler 4.3.3
X=X3
X = Xmix
-See Fogler 4.3, Ex. 4-2
-Remember your Levenspiel plots
CAn
X=Xn
aA + bB cC + dD
The rate law must have expressions for both forward and reverse
reactions
The rate must be thermodynamically consistent. That is, rate laws (if
expressed in terms of concentration) must reduce to thermodynamic
relationship relating reacting species concentrations at chemical
equilibrium.
KC =
KC =
c
d
CC,eq
CD,eq
a
b
CA,eq
CB,eq
KC =
c
d
pC,eq
pD,eq
a
b
pA,eq
pB,eq
pi
RT
( RT )( c d + b + a )
= K P ( RT )( a )
Fogler 3.2.3
2 C 6 H 6 C12 H10 + H 2
k B
Benzene Diphenyl
Rate of formation of B
rB ,rev = k B CD CH 2
rB , for = k B CB2
rB = k B CB2 + k B CD CH 2
2 , eq
k B CD ,eq CH 2 ,eq
=
= KC
2
k B
CB ,eq
Therefore,
2 CD CH 2
rB = k B CB
K
C
R +S
A + B
k2
Reaction
:
A+ B C +
Equilibrium
But Kc=f(T)
c
c
d
{C A0 ( C + X e )}a {C A0 ( D + X e )} a
a
a
]
KC = [
b
b
{C A0 (1 X e )} {C A0 ( B X e )}a
a
Fogler 8.5
X EB
=
i
pi
Equilibrium
(T T0 )
H Rxn (T )
Assumptions made?
Fogler 8.5
Xe
Adiabatic Temperature
T01
T02
Fogler 8.5
Equilibrium
Xe
Adiabatic Temperature
T01
T02
Xe
X3
X2
X EB =
X1
~
i C pi (T T0 )
H Rxn (T )