1 6 A I Ionic Bonding 1
1 6 A I Ionic Bonding 1
1 6 A I Ionic Bonding 1
6 Bonding
Specificatio
n
Students will be
assessed on
their ability to:
Ionic
bonding
a. recall and
interpret
evidence
for the
existence of
ions, limited
to physical
properties
of ionic
compounds
, electron
density
maps and
the
migration of
ions, eg
electrolysis
of aqueous
copper
chromate(V
I)
b. describe
the
formation of
ions in
terms of
electron
loss or gain
c. draw
electron
configuratio
n diagrams
of cations
ionic.
B
meta
llic and ionic.
C
ionic
and covalent.
D
meta
llic and
covalent.
(Total for
question = 1
mark)
Q2.
Which of these equations represents the electron affinity of
chlorine?
A Cl2(g) + 2e- 2Cl-(g)
B Cl2(g) - 2e- 2Cl-(g)
C Cl2(g) + e- Cl-(g)
D Cl(g) + e-
Cl-(g)
(Total for question = 1 mark)
Q3.
Which of these electron density maps best represents the bonding
in the compound
lithium iodide, LiI?
C
D
A molecule of nitrogen, N2
An ion of sodium, Na+
(Total for question = 1 mark)
Q5.
A drop of concentrated nickel(II) sulfate solution, which is green, is placed on moist
filter paper on a microscope slide and the ends of the slide are connected to a 24 V DC
power supply. After ten minutes,
A
a blue colour has moved towards the negative terminal and a yellow colour
towards the positive terminal.
a blue colour has moved towards the positive terminal and a yellow colour
towards the negative terminal.
a green colour has moved towards the negative terminal but there is no other
visible change.
a green colour has moved towards the positive terminal but there is no other
visible change.
(Total for question = 1 mark)
Q6.
Which of the following represents the process occurring when the enthalpy change of
atomization of bromine is measured?
A Br2(l) Br(g)
B Br2(g) Br(g)
C Br2(l) Br+(g) + Br(g)
D Br2(g) Br+(g) + Br(g)
(Total for question = 1 mark)
Q7.
Which of the following statements is evidence for the existence of ions in ionic compounds?
A Ionic compounds, in the solid state, conduct electricity.
B When any ionic compound in solution is electrolysed, the migration of ions
can be seen.
C In electron density maps for ionic compounds, there is no single line
representing electron density that surrounds both cations and anions.
D In electron density maps for ionic compounds, there are some single lines
representing electron density that surround both cations and anions.
(Total for question = 1 mark)
Q8.
Going down Group 1 from lithium to rubidium
A
The results from the Born-Haber cycle are too inaccurate to be reliable.
(Total for question = 1 mark)
Q10.
The first ionization energies, in kJ mol-1, of four elements with consecutive atomic
numbers are shown below.
A 1680
B 2080
C 496
D 738
(a) Which element could be an inert gas?
(1)
A
D
(Total for question = 3 marks)
Q11.
Which equation represents the reaction for which the enthalpy change is the lattice
energy of sodium fluoride, NaF?
A Na(s) + F2(g) NaF(s)
B Na(g) + F(g) NaF(s)
C Na+(g) + F(g) NaF(s)
D Na(g) + F2(g) NaF(s)
(Total for question = 1 mark)
Q12.
Which of these statements is incorrect?
A The atomic radius of metals increases down a Group.
B The trend in the melting temperature of successive elements across Period 2 is
similar to that in Period 3.
Q14.
The ionic radii in nm of some ions are given below.
(a) Which of the following compounds has the most exothermic lattice energy? They all
have the same crystal structure.
(1)
A
LiF
LiCl
CaO
CaS
(b) Which of the following compounds will show the greatest difference between the
experimental (Born-Haber) lattice energy and that calculated from a purely ionic
model?
(1)
A
LiF
Li2O
CaO
CaS
Q15.
Element R is in Group 1 of the Periodic Table and element T is in Group 6. R and T
are not the symbols for the elements.
(a) The compound of R and T will have the formula
(1)
A
RT
RT6
RT2
R6T
(1)
A
ionic.
covalent.
dative covalent.
metallic.
Q16.
Going across the Periodic Table from sodium to aluminium,
A
Q17.
Which of these ions has the greatest ability to polarize an anion?
A Ba2+
B Ca2+
C Cs+
D K+
(Total for question = 1 mark)
Q18.
Which of the following has the smallest ionic radius?
A F
B Na+
C Mg2+
O2
(Total for question = 1 mark)
Q19.
The graph below represents
the successive ionization
energies of an element X
plotted
against the number of the
electron removed. X is not the
symbol for the element.
(a) From this graph it is
possible to deduce the
group in the Periodic Table
to which X
belongs. X is in
(1)
A
Group 1
Group 3
Group 5
(b) From the graph it is possible to deduce that the most stable ion of X will be
Group 7
(1)
A
3+
Q21.
Which of the graphs shows (from left to right) the trend in the ionic radius of the
isoelectronic ions N3, O2, F, Na+, Mg2+, Al3+?
Q22.
The Born-Haber cycle for the formation of sodium chloride from sodium and chlorine
may be represented by a series of steps labelled A to F as shown.
(a) (i) Complete the table below by adding the letters A to F next to the corresponding
energy changes.
(3)
(ii) Calculate the first electron affinity of chlorine, in kJ mol 1, from the data given.
(2)
(b) Lattice energies can be calculated from electrostatic theory (theoretical values) as
well as by Born-Haber cycles (experimental values).
(i) Comment on the fact that there is close agreement between the values for
sodium chloride, NaCl.
(1)
*(ii) Explain, in terms of chemical bonding, why the experimental value for
silver iodide, AgI, is more exothermic than the value calculated theoretically
for the same compound.
(2)
*(c) Suggest why the first ionization energies of the Group 1 elements decrease down the
group.
(2)
(b) The ions in an ionic lattice are held together by an overall force of attraction.
(i) Describe the forces of attraction in an ionic lattice.
(1)
(ii) Suggest two forces of repulsion which exist in an ionic lattice.
(2)
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(c) Part of the Born-Haber cycle for magnesium oxide, MgO, is shown below.
(i) Complete the empty box with the appropriate formulae and state symbols.
(2)
(ii) Identify the enthalpy changes represented by the letters A and C.
(2)
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(iii) Give the expression for the enthalpy change F in terms of the other enthalpy
changes to A and E.
(1)
F=
(d) The lattice composed of the ions Mg2+ and O2 is stronger than a lattice composed of
the ions Mg+ and O .
(i) Explain, in terms of the charges on the ions and the size of the cations, why this
is so.
(2)
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(ii) Suggest how the lattice energy of Mg 2+O2 would differ from that of Mg+O.
(1)
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(Total for question = 15 marks)
Q24.
This question is about the properties of ions and ionic compounds.
(a) Solid calcium carbonate, CaCO3, has a giant ionic structure.
(i) Draw a diagram (using dots or crosses) for a calcium ion. Show ALL the
electrons and the charge on the ion.
(2)
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(ii) Suggest why aqueous solutions of calcium chloride, CaCl 2(aq), and barium
chloride, BaCl2(aq), of the same molar concentration, have different electrical
conductivities.
(1)
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(iii) 1 kg of a solution contains 0.100 mol of calcium ions, Ca 2+.
What is the concentration of the calcium ions by mass in
parts per million (ppm)?
[Assume the relative atomic mass of calcium is 40.]
(2)
.....................................ppm
*(c) Some buildings are made from limestone, which is mainly calcium carbonate. Gases
in the atmosphere such as sulfur dioxide, SO 2, and nitrogen dioxide, NO2, can be
responsible for damaging these buildings.
Describe how these gases come to be present in the atmosphere and explain how
they can damage a limestone building.
(3)
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(d) The lattice energy of calcium chloride, CaCl2, is -2258 kJ mol-1 based on an
experimental Born-Haber cycle and -2223 kJ mol -1 based on theoretical calculations.
Would you expect its bonding to match the ionic model? Justify your answer.
(1)
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(Total for question = 15 marks)
Q25.
This question is about lithium iodide, an ionic salt.
(a) Draw dot and cross diagrams for the lithium and iodide ions. Show all the
electrons in the lithium ion but only outer shell electrons in the iodide ion.
(2)
(b) On the Born-Haber cycle below, fill in the missing formulae (including state
symbols) and the missing enthalpy change.
(3)
(2)
(d) The experimental lattice energy for lithium iodide is 759 kJ mol 1. The
theoretical lattice energy is different from this value.
Will the experimental lattice energy be more negative or less negative than the
theoretical lattice energy? Justify your answer.
(3)
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(e) State and explain how electron affinity values change as you go down Group 7
from chlorine to iodine.
(2)
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(Total for question = 12 marks)
Q26.
(a) (i) Complete the electronic configuration of the magnesium atom.
(1)
1s .....................................................................................................................................................
2
.(b) (i) Write the equation, including state symbols, for the reaction of magnesium with
chlorine.
(2)
Q1.
No Examiner's Report available for this question
Q2.
No Examiner's Report available for this question
Q3.
No Examiner's Report available for this question
Q4.
No Examiner's Report available for this question
Q5.
No Examiner's Report available for this question
Q6.
No Examiner's Report available for this question
Q7.
No Examiner's Report available for this question
Q8.
No Examiner's Report available for this question
Q9.
No Examiner's Report available for this question
Q10.
No Examiner's Report available for this question
Q11.
No Examiner's Report available for this question
Q12.
No Examiner's Report available for this question
Q13.
No Examiner's Report available for this question
Q14.
No Examiner's Report available for this question
Q15.
No Examiner's Report available for this question
Q16.
No Examiner's Report available for this question
Q17.
No Examiner's Report available for this question
Q18.
No Examiner's Report available for this question
Q19.
No Examiner's Report available for this question
Q20.
No Examiner's Report available for this question
Q21.
No Examiner's Report available for this question
Q22.
In (a)(i), it was pleasing to see the energy changes on the Born-Haber cycle identifi ed correctly.
Part (a)(ii)
proved to be more demanding, with many candidates being unable to derive a correct
expression for the
fi rst electron affi nity of chlorine. Frequently, a candidate's working led to an answer of +360 kJ
mol-1, which
was then amended to a fi nal answer of -360 kJ mol -1 without any comment.
The best answers started with an expression of the form "D = ......", with subsequent
rearrangement of the
expression to find the unknown, F, as shown below:-
In the second example above, one out of the two available marks has not been awarded due to a
transposition error. These occurred quite frequently. Consequential marking allowed the award
of one mark
for the subsequent value of the fi rst electron affi nity for chlorine.
In (b)(i), answers often contained a comment on the mathematical difference between the
experimental
and theoretical lattice energies rather than to the fact that the values were in close agreement
and,
therefore, that the bonding in sodium chloride is almost completely ionic. Part (b)(ii) revealed
that some
candidates did not understand the link between there being a signifi cant difference in the lattice
energies
and the nature of the bonding in a compound.
Part (c) was extremely well-answered, with all the relevant factors being included, as illustrated
in the
response below:-
Q23.
(a)
The majority of candidates described a method involving electrolysis.
(b)
Part (b)(i) was very well-answered. The most common error was to omit the word "ions".
Very few scored both the marks in (b)(ii). The repulsion between like-charged ions was
acknowledged, but the repulsion between electron clouds around the ions (regardless of
their charge) was frequently overlooked.
(c)
The majority of answers to (c)(i) were correct. In (c)(ii), however, although the enthalpy
change of formation was well-known, the next answer often simply referred to "ionization
energy" or just "second ionization energy" instead of the sum of the first plus second
ionization energies (of magnesium). If the answer to (c)(iii) was incorrect, then normally
the signs were all the wrong way round.
(d) (i)
Unfortunately, many candidates did not read the question carefully and mention the effect
on the ionic bonding of changing the charge on both the cation and anion. The fact that the
Mg2+ cation is smaller than a Mg+ cation was appreciated by the majority of candidates.
(d) (ii)
This was generally well-answered, except when candidates did not realise that this was
requiring a comparison of the magnitude of the lattice energies rather than just stating that
"the Mg2+O2- lattice is stronger".
Q24.
(a) (i-ii)
Although for many this question was an easy start to the structured questions, a significant
minority dropped at least one mark.
Surprisingly, this occurred in part (i) as well as part (ii), with an incorrect number of electron
shells being the most common way to fail to score.
It's worth reminding candidates that transfer of key skills from GCSE, such as 'dot and cross'
diagrams, is a feature of AS and they should not just focus their revision on new concepts, such
as s, p and d orbitals.
was not quite creditworthy. In addition, the idea of increasing effective nuclear charge, whilst
acceptable in this context, did lead to a number of responses that suggested some candidates
believed the actual nuclear charge was increasing, rather than the increase of its net effect on
the remaining electrons. The best answers using this approach made it clear the number of
protons remained the same, but now outweighed the number of electrons.
Part (iv) showed that most candidates understood the clear link between the strength of the
many ionic bonds in a lattice and related this clearly to the input of energy needed to break up
the structure. A few failed to score in this question either because they answered in terms of
intermolecular forces or metallic bonds.
Q25.
(a)
Failure to read the question often cost a mark when iodine inner electrons were omitted.
Many candidates also omitted charges on the ions which should always be included.
Results Plus: Examiner Comments
At first sight this a perfect answer. The candidate has shown how the ions are formed
from the atoms concerned.
Unfortunately, the candidate has failed to read the question fully 'show all the electrons
in the lithium'.
Results Plus: Examiner Tip
Check you have answered the question asked.
Imprecise expressions also cost marks in the reason for this change which could be awarded
even if the first part was inadequate.
Statements like 'It is further from the nucleus' (rather than 'the electron...') and 'there is
shielding' (rather than '...more shielding') were typical.
Q26.
In (a) (i) and (a) (ii), many candidates were able to give the correct electronic
configurations, although 1p and 2d sub-shells were occasionally seen. In (b) (i), the
formulae of the species were often correctly given, but there was some confusion
over which state symbols to use. In (b) (ii), the majority of candidates knew that the
bonding in magnesium chloride was ionic. Part (b) (iii) proved to be more
challenging, with a significant number of answers showing the bonding in magnesium
chloride as covalent rather than ionic. Candidates who did not read the question
carefully drew only the outer shell electrons on the magnesium and chloride ions,
instead of all the electrons in each species.
Quality of Written Communication was thoroughly tested in (d). Many candidates
confused the process of melting with that of ionization, with answers referring to the
removal of electrons from a magnesium atom frequently being seen. Answers which
attempted to consider the metallic bonding in magnesium and sodium often
overlooked the difference in ionic radii of the magnesium ion compared with that of
the sodium ion.
Q1. A
Q2. D
Q3. A
Q4. C
Q5. C
Q6.
Question Number
Q8.
Correct Answer
C
Reject
Mark
1
Q9.
Q10.
Q11.
Q12.
Q13.
Q14.
Q15.
Q16.
Q17.
Q18.
Q19.
Q20.
Q21.
Q22.
Q23.
Q24.
Q25.
Q26.