0620 Chemistry: MARK SCHEME For The May/June 2011 Question Paper For The Guidance of Teachers

w
w
ap
eP
e
tr
.X
UNIVERSITY OF CAMBRIDGE INTERNATIONAL EXAMINATIONS
for the guidance of teachers
0620 CHEMISTRY
0620/33
Paper 3 (Extended Theory), maximum raw mark 80
Mark schemes must be read in conjunction with the question papers and the report on the
examination.
Cambridge will not enter into discussions or correspondence in connection with these mark schemes.
Cambridge is publishing the mark schemes for the May/June 2011 question papers for most IGCSE,
GCE Advanced Level and Advanced Subsidiary Level syllabuses and some Ordinary Level
syllabuses.
om
.c
MARK SCHEME for the May/June 2011 question paper
s
er
International General Certificate of Secondary Education
Page 2
1
Mark Scheme: Teachers version

IGCSE May/June 2011
Syllabus
0620
Paper
33
(i) Rb / Sr
[1]
(ii) I
[1]
(iii) Fe
[1]
(iv) P
[1]
(v) Si
[1]
(a) (i) no reaction
[1]
Fe + Sn2+ Fe2+ + Sn / 2Fe + 3Sn2+ 2Fe3+ + 3Sn

for realising that there would be a reaction shown by an attempt to write an
equation e.g. writing Fe2Sn etc. allow [1]
[2]
no reaction
[1]
(ii) tin oxide, nitrogen dioxide (accept nitogen(IV) oxide/dinitrogen tetroxide), oxygen
All three for two
accept correct formulae
any two correct products
(b) (i) tin
[2]
[1]
[1]
(ii) 4OH O2 + 2H2O + 4e

not balanced allow [1]
[2]
(iii) sulfuric acid
[1]
(c) zinc is more reactive than iron/steel

tin is less reactive than iron/steel
[1]
[1]
zinc corrodes/reacts/loses electrons/is oxidised/is anodic/provides sacrificial protection/

forms positive ions (in preference to iron or steel) ORA
allow iron is cathodic for this mark.
[1]
Iron/steel corrodes/reacts/rusts/loses electrons/is oxidised/is anodic/forms positive ions (in
preference to tin). ORA
allow tin is cathodic for this mark
[1]
University of Cambridge International Examinations 2011
Page 3
3

IGCSE May/June 2011
Syllabus
0620
Paper
33
(a) (i) concentration of thiosulfate is proportional to volume of thiosulfate solution added (when
total volume is same in all experiments) / concentration of acid always the same
[2]
for comments based on amount / to make experiments fair / comparable allow [1]
(ii) 240 s
[1]
(iii) decreases/reaction slower

because concentration of thiosulfate decreases
frequency/chances/rate of collisions decreases
[1]
[1]
[1]
one mark can be scored for less/smaller amount/smaller volume of thiosulfate / less
collisions
(b) rate increases with temperature (or at 42 C) ORA
[1]
particles/molecules/ions move faster or gain energy / ORA

(dont accept reactants or atoms)
[1]
more collisions / ORA
[1]
(last mark is for qualification of the collisions) i.e.

greater frequency / more per unit time/more often /greater chance/more likely/more collision
rate/more effective/more successful/more with activation energy / ORA
[1]
4
One redox equation

accept Fe2O3 + 3CO 2Fe + 3CO2
2Fe2O3 + 3C 4Fe + 3CO2
Fe2O3 + 3C 2Fe + 3CO
C + O2 CO2
CO2 + C 2CO
[1]
one acid/base equation

CaO + SiO2 CaSiO3
or CaCO3 + SiO2 CaSiO3 + CO2
[1]
three more equations or comments

carbon burns to form carbon dioxide
this reaction is exothermic or produces heat
carbon dioxide is reduced to carbon monoxide
carbon monoxide reduces hematite to iron
carbon reduces hematite to iron
limestone removes silica which is an impurity
to form slag which is a waste product
limestone decomposes or symbol/word equation
[3]
Page 4

IGCSE May/June 2011
Syllabus
0620
(a) Zn + H2SO4 ZnSO4 + H2 / Zn + 2H+ Zn2+ + H2
Paper
33
[2]
marks are for correct reactants [1] correct products [1]

If ionic equation is given dont penalise SO42 spectator ions on both sides
(b) (exothermic because) a cell produces (electrical) energy/electricity
[1]
the next two marks score for

electrons are lost AND gained / oxidation no. or state/valency both increases and decreases
/ two correct half equations i.e. Zn Zn2+ + 2e and 2H+ + 2e H2
[2]
(c) zinc
[1]
cond it is the more reactive metal / it supplies electrons / it forms ions more readily than iron
[1]
(d) replace zinc with magnesium
replace iron with copper
use (more) concentrated sulfuric acid
accept use a more concentrated acid / a more concentrated solution
any two
[2]
Page 5
6

IGCSE May/June 2011
Syllabus
0620
(a) (i) rate at which methanol formed by forward reaction

equals rate it is reacting in back reaction
rate of forward reaction equals rate of back reaction allow [1]
(ii) low/lower/decreased temperature
high/higher/increased pressure
Explanations not needed but if they are given they must be correct
IGNORE values of temperature and pressure
Paper
33
[1]
[1]
[1]
[1]
(iii) high pressure can be used / lower pressure due to expense or safety
[1]
cannot use a low temperature as rate would be too slow the rate would not be economic
[1]
(b) (i) ester
[1]
(ii) soap/sodium stearate or any acceptable salt/glycerol
[1]
(iii) burning both fuels forms carbon
[1]
growing plants to make biodiesel removes carbon dioxide

from atmosphere
(c) (i) correct SF of an octane
(ii) add bromine (water)/bromine in an organic solvent
result octane remains brown/orange/yellow/red
result octane goes colourless/decolourises
not clear/discolours
colour of reagent must be shown somewhere for [3] otherwise max [2]
accept equivalent test using KMnO4 in acid or alkali
[1]
[1]
[1]
[1]
[1]
Page 6
7

IGCSE May/June 2011
Syllabus
0620
Paper
33
(a) 3 bp and 1nbp around phosphorus

1 bp and 3nbp around each chlorine
[1]
[1]
(b) (i) PCl3 + 3H2O 3HCl + H3PO3
[1]
(ii) acid solutions same concentration

measure pH/pH paper/Universal indicator
hydrochloric acid lower pH
[1]
[1]
[1]
colours of Universal indicator can be given as red<orange<yellow

ignore precise pH values as long as HCl is lower than H3PO3
OR Acid solutions same concentration
[1]
add magnesium or any named metal above Hydrogen in reactivity series but not above
magnesium
calcium carbonate or any insoluble carbonate
[1]
hydrochloric acid react faster/shorter time
[1]
OR acid solutions same concentration
measure electrical conductivity
hydrochloric acid better conductor/bulb brighter
[1]
[1]
[1]
OR acid solutions same concentration

add sodium thiosulphate
hydrochloric acid forms precipitate faster/less time
[1]
[1]
[1]
(iii) sodium hydroxide/sodium carbonate

titration cond on correct reagent
second mark scores for mention of titration /burette/pipette/indicator.
experimental detail not required
[1]
[1]
any named soluble calcium salt e.g. calcium chloride/nitrate/hydroxide
[1]
precipitation/filter/decant/centrifuge
[1]
Page 7
8

IGCSE May/June 2011
Syllabus
0620
Paper
33
(a) (i) (to avoid) carbon monoxide formation/so complete combustion occurs/avoid incomplete
combustion So that CO2 is produced
[1]
CO does not dissolve/react with alkali
[1]
(ii) CO2 is acidic
[1]
(iii) volume of gaseous hydrocarbon 20 cm3

volume of oxygen used = 90 cm3
volume of carbon dioxide formed = 60 cm3
[1]
[1]
no mark for 20 cm3 of hydrocarbon.

(iv) 2C3H6(g)/2CxHy(g) + 9O2(g) 6CO2(g) + 6H2O(l)
[1]
OR C3H6(g) + 9/2O2(g) 3CO2(g) + 3H2O(l)

C3H6
[1]
C3H6 can be given in the equation for the second mark

(b) (i) correct structural or displayed formula of another chlorobutane / dichlorobutane /
polychlorobutane
[1]
(ii) light / 200 C / lead tetraethyl
[1]
(iii) cracking is the decomposition/breaking down of an alkane/hydrocarbon/petroleum

heat/high temperature / Temperature between 450 C to 800 C
OR catalyst / named catalyst
to give a simpler alkane and alkene
[1]
word equation or equation as example
[1]
[1]
[1]
to make polymers / to increase petrol fraction / organic chemicals/petrochemicals /

hydrogen
[1]
any four

0620 Chemistry: MARK SCHEME For The May/June 2011 Question Paper For The Guidance of Teachers

Uploaded by

Copyright:

Available Formats

0620 Chemistry: MARK SCHEME For The May/June 2011 Question Paper For The Guidance of Teachers

Uploaded by

Document Information

Original Title

Copyright

Available Formats

Share this document

Share or Embed Document

Sharing Options

Did you find this document useful?

Is this content inappropriate?

Copyright:

Available Formats

0620 Chemistry: MARK SCHEME For The May/June 2011 Question Paper For The Guidance of Teachers

Uploaded by

Copyright:

Available Formats

w

UNIVERSITY OF CAMBRIDGE INTERNATIONAL EXAMINATIONS

for the guidance of teachers

Paper 3 (Extended Theory), maximum raw mark 80

MARK SCHEME for the May/June 2011 question paper

International General Certificate of Secondary Education

Mark Scheme: Teachers version

(a) (i) no reaction

Fe + Sn2+ Fe2+ + Sn / 2Fe + 3Sn2+ 2Fe3+ + 3Sn

(ii) 4OH O2 + 2H2O + 4e

(iii) sulfuric acid

(c) zinc is more reactive than iron/steel

zinc corrodes/reacts/loses electrons/is oxidised/is anodic/provides sacrificial protection/

University of Cambridge International Examinations 2011

Mark Scheme: Teachers version

(iii) decreases/reaction slower

particles/molecules/ions move faster or gain energy / ORA

more collisions / ORA

(last mark is for qualification of the collisions) i.e.

One redox equation

one acid/base equation

three more equations or comments

University of Cambridge International Examinations 2011

Mark Scheme: Teachers version

(a) Zn + H2SO4 ZnSO4 + H2 / Zn + 2H+ Zn2+ + H2

marks are for correct reactants [1] correct products [1]

the next two marks score for

University of Cambridge International Examinations 2011

Mark Scheme: Teachers version

(a) (i) rate at which methanol formed by forward reaction

(ii) soap/sodium stearate or any acceptable salt/glycerol

(iii) burning both fuels forms carbon

growing plants to make biodiesel removes carbon dioxide

University of Cambridge International Examinations 2011

Mark Scheme: Teachers version

(a) 3 bp and 1nbp around phosphorus

(b) (i) PCl3 + 3H2O 3HCl + H3PO3

(ii) acid solutions same concentration

colours of Universal indicator can be given as red<orange<yellow

OR acid solutions same concentration

(iii) sodium hydroxide/sodium carbonate

any named soluble calcium salt e.g. calcium chloride/nitrate/hydroxide

University of Cambridge International Examinations 2011

Mark Scheme: Teachers version

(ii) CO2 is acidic

(iii) volume of gaseous hydrocarbon 20 cm3

no mark for 20 cm3 of hydrocarbon.

OR C3H6(g) + 9/2O2(g) 3CO2(g) + 3H2O(l)

C3H6 can be given in the equation for the second mark

(iii) cracking is the decomposition/breaking down of an alkane/hydrocarbon/petroleum

word equation or equation as example

to make polymers / to increase petrol fraction / organic chemicals/petrochemicals /

University of Cambridge International Examinations 2011

You might also like