ButanoxM-60VRD Ts Row Eng

Butanox M-60 VRD
Product description
Methyl ethyl ketone peroxide, solution in dimethyl phthalate
CH3
HOO
CH3
O
C2H5
CH3
OOH ; HOO
C2H5
OOH ; HOOH
C2H5
CAS No.
EINECS/ELINCS No.
TSCA status
: 1338-23-4
: 215-661-2
: listed on inventory
Specifications
Appearance
Total active oxygen
: Clear red liquid

: 9.8-10.0%
Characteristics
Density, 20C
Viscosity, 20C
: 1.170 g/cm
: 25 mPa.s
Storage
Due to the relatively unstable nature of organic peroxides a loss of quality

can be detected over a period of time. To minimize the loss of quality,
AkzoNobel recommends a maximum storage temperature (Ts max.) for
each organic peroxide product.
For Butanox M-60
Ts max. = 25C
When stored under the recommended storage conditions, Butanox M-60

will remain within the AkzoNobel specifications for a period of at least 6
months after delivery.
Thermal stability
Organic peroxides are thermally unstable substances, which may undergo

self-accelerating decomposition. The lowest temperature at which selfaccelerating decomposition of a substance in the original packaging may
occur is the Self-Accelerating Decomposition Temperature (SADT). The
SADT is determined on the basis of the Heat Accumulation Storage Test.
For Butanox M-60
SADT : 60C
The Heat Accumulation Storage Test is a recognized test method for the determination of the
SADT of organic peroxides (see Recommendations on the Transport of Dangerous Goods,
Manual of Tests and Criteria - United Nations, New York and Geneva).
Major decomposition
products
Carbon dioxide, water, acetic acid, formic acid, propionic acid, methyl ethyl
ketone.
TS 61015.04/June 2012
Page 1 of 4
Packaging and
transport
The standard packaging is a 30 l HDPE can (Nourytainer) for 30 kg

peroxide solution.
Both packaging and transport meet the international regulations. For the
availability of other packed quantities contact your AkzoNobel
representative.
Butanox M-60 VRD is classified as Organic peroxide type D; liquid;
Division 5.2; UN 3105.
Applications
Butanox M-60 VRD is a general purpose methyl ethyl ketone peroxide

(MEKP) for the curing of unsaturated polyester resins in the presence of a
cobalt accelerator at room and elevated temperatures. Butanox M-60 VRD
is a 10% higher concentrated version of Butanox M-50 VR.
Butanox M-60 VRD offers all the advantages of a standard MEKP i.e.
Butanox M-60. The Butanox M-60 VRD includes a vanishing red indicator
system that in most cases virtually disappears during cure. The red color
is there when you need it i.e. during the mixing step, but will dissapear
during cure.
The curing system Butanox M-60 VRD/cobalt accelerator is particularly
suitable for the curing of gelcoat resins, laminating resins, lacquers and
castings; moreover the manufacture of light resistant parts may be
possible contrary to the curing system benzoyl peroxide/amine
accelerator.
Practical experience throughout many years has proven that by the
guaranteed low water content and the absence of polar compounds in
Butanox M-60 VRD, this peroxide is very suitable in GRP products for e.g.
marine applications.
For room temperature application it is necessary to use Butanox M-60
VRD together with a cobalt accelerator (e.g. Accelerator NL-49P).
Dosage
Depending on working conditions, the following peroxide and accelerator

dosage levels are recommended:
Butanox M-60 VRD
Accelerator NL-49P
1 - 4 phr
0.5 - 3 phr
phr = parts per hundred resin
TS 61015.04/June 2012
Page 2 of 4
Cure Characteristics
In a high reactive standard orthophthalic resin in combination with

Accelerator NL-49P (= 1% cobalt) the following application characteristics
were determined:
Gel times at 20C
2 phr Butanox M-60 VRD + 0.5 phr Acc. NL-49P
2 phr Butanox M-50 VR + 0.5 phr Acc. NL-49P
10 minutes
12 minutes

6 minutes
7 minutes
Cure of 1 mm pure resin layer at 20C

The speed of cure is expressed as the time to reach a Persoz hardness of
respectively 30, 60 and 120 s.
Persoz: 30
60
120 s
2.2
2.4
3.8
4.1

1.3
1.7
2.5
3.0
12
13
h
h
9 h
9.5 h
Cure of 4 mm laminates at 20C

2
4 mm laminates have been made with a 450 g/m glass chopped strand
mat. The glass content in the laminates is 30% (w/w).
The following parameters were determined:
- Time-temperature curve.
- Speed of cure expressed as the time to achieve a Barcol hardness
(934-1) of 0-5 and 25-30 respectively.
- Residual styrene content after 24 h at 20C and a subsequent postcure

of 8 h at 80C.
Gel
time
min.
Time to
Peak
min.
Peak
exotherm
C

13
13
33
36
50
44

7
8
23
26
71
64
Barcol
0-5 25-30

Res. styrene
24 h + 8 h
20C 80C
%
%
2
3
13
15
5.7
6
0.3
0.3
<1
1
4.7
5
0.1
0.1
TS 61015.04/June 2012
Page 3 of 4
Pot life at 20C

Pot lives were determined of a mixture of Butanox M-60 VRD and a nonpreaccelerated UP resin at 20C.
2 phr Butanox M-60 VRD
4 phr Butanox M-60 VRD
10 h
6h
Butanox and Nourytainer are registered trademarks of Akzo Nobel Chemicals B.V. or
affiliates in one or more territories.
All information concerning this product and/or suggestions for handling and use contained herein are offered in good faith and are believed to be reliable. AkzoNobel Functional
Chemicals, however, makes no warranty as to accuracy and/or sufficiency of such information and/or suggestions, as to the product's merchantability or fitness for any
particular purpose, or that any suggested use will not infringe any patent. Nothing contained herein shall be construed as granting or extending any license under any patent.
Buyer must determine for himself, by preliminary tests or otherwise, the suitability of this product for his purposes. The information contained herein supersedes all previously
issued bulletins on the subject matter covered. The user may forward, distribute, and/or photocopy this document only if unaltered and complete, including all of its headers and
footers, and should refrain from any unauthorized use. You may not copy this document to a website.
AkzoNobel Functional Chemicals
Amersfoort, The Netherlands
T +31 33 467 6767
F +31 33 467 6151
E [email protected]
AkzoNobel Functional Chemicals

Chicago, U.S.A.
T +1 312 544 7000
1 800 828 7929 (Toll free US only)
F +1 312 544 7188
E [email protected]
Akzo Nobel (Asia) Co., Ltd.

Shanghai, PR China
T +86 21 2216 3600
F +86 21 3360 7739
E [email protected]
www.akzonobel.com/polymer
2008-2012 AkzoNobel Functional Chemicals
TS 61015.04/June 2012
Page 4 of 4

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Butanox M-60 VRD

Methyl ethyl ketone peroxide, solution in dimethyl phthalate

: Clear red liquid

Due to the relatively unstable nature of organic peroxides a loss of quality

When stored under the recommended storage conditions, Butanox M-60

Organic peroxides are thermally unstable substances, which may undergo

The standard packaging is a 30 l HDPE can (Nourytainer) for 30 kg

Butanox M-60 VRD is a general purpose methyl ethyl ketone peroxide

Depending on working conditions, the following peroxide and accelerator

phr = parts per hundred resin

In a high reactive standard orthophthalic resin in combination with

2 phr Butanox M-60 VRD + 1.0 phr Acc. NL-49P

Cure of 1 mm pure resin layer at 20C

2 phr Butanox M-60 VRD + 1.0 phr Acc. NL-49P

Cure of 4 mm laminates at 20C

- Residual styrene content after 24 h at 20C and a subsequent postcure

2 phr Butanox M-60 VRD + 0.5 phr Acc. NL-49P

2 phr Butanox M-60 VRD + 1.0 phr Acc. NL-49P

2 phr Butanox M-60 VRD + 0.5 phr Acc. NL-49P

Pot life at 20C

AkzoNobel Functional Chemicals

Akzo Nobel (Asia) Co., Ltd.

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