SAFETY DATA SHEET

HYDREX 2510
Page: 1
Compilation date: 11/01/2013
Revision No: 2
Section 1: Identification of the substance/mixture and of the company/undertaking
1.1. Product identifier
Product name: HYDREX 2510
1.2. Relevant identified uses of the substance or mixture and uses advised against
Use of substance / mixture: Closed circuit corrosion inhibitor.
1.3. Details of the supplier of the safety data sheet
Company name: Veoila Water Solutions & Technologies
Whittle Road
Meir
Stoke-on- Trent
ST3 7QD
Tel: 01628 897295
Fax: 01628 897001
Email: [email protected]
1.4. Emergency telephone number
Section 2: Hazards identification
2.1. Classification of the substance or mixture
Classification under CHIP: T: R25; Xi: R36/38; N: R50
Classification under CLP: Ox. Sol. 3: H272; Acute Tox. 3: H301; Aquatic Acute 1: H400
Most important adverse effects: Toxic if swallowed. Irritating to eyes and skin. Very toxic to aquatic organisms.
2.2. Label elements
Label elements under CLP:
Hazard statements: H272: May intensify fire; oxidiser.
H301: Toxic if swallowed.
H400: Very toxic to aquatic life.
Signal words: Danger
Hazard pictograms: GHS03: Flame over circle
GHS06: Skull and crossbones
GHS09: Environmental
Precautionary statements: P210: Keep away from heat/sparks/open flames/hot surfaces. - No smoking.
P221: Take any precaution to avoid mixing with combustibles.
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SAFETY DATA SHEET
HYDREX 2510
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P262: Do not get in eyes, on skin, or on clothing.
P280: Wear protective gloves/protective clothing/eye protection/face protection.
P352: Wash with plenty of soap and water.
P301+310: IF SWALLOWED: Immediately call a POISON CENTER or doctor.
P273: Avoid release to the environment.
Label elements under CHIP:
Hazard symbols: Toxic.
Dangerous for the environment.
Risk phrases: R25: Toxic if swallowed.
R36/38: Irritating to eyes and skin.
R50: Very toxic to aquatic organisms.
Safety phrases: S24/25: Avoid contact with skin and eyes.
S26: In case of contact with eyes, rinse immediately with plenty of water and seek
medical advice.
S36/37/39: Wear suitable protective clothing, gloves and eye / face protection.
S45: In case of accident or if you feel unwell, seek medical advice immediately (show
the label where possible).
S61: Avoid release to the environment. Refer to special instructions / safety data sheets.
2.3. Other hazards
PBT: This substance is not identified as a PBT substance.
Section 3: Composition/information on ingredients
3.2. Mixtures
Hazardous ingredients:
SODIUM NITRITE
EINECS CAS CHIP Classification CLP Classification Percent
231-555-9 7632-00-0 O: R8; T: R25; N: R50 Ox. Sol. 3: H272; Acute Tox. 3: H301;
Aquatic Acute 1: H400
10-30%
SODIUM HYDROXIDE
215-185-5 1310-73-2 C: R35 Skin Corr. 1A: H314 1-10%
Contains: A blend of corrosion inhibitors.
Section 4: First aid measures
4.1. Description of first aid measures
Skin contact: Remove all contaminated clothes and footwear immediately unless stuck to skin.
Drench the affected skin with running water for 10 minutes or longer if substance is still
on skin. Transfer to hospital if there are burns or symptoms of poisoning. [cont...]
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HYDREX 2510
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Eye contact: Bathe the eye with running water for 15 minutes. Transfer to hospital for specialist
examination.
Ingestion: Do not induce vomiting. If conscious, give half a litre of water to drink immediately. If
unconscious, check for breathing and apply artificial respiration if necessary. If
unconscious and breathing is OK, place in the recovery position. Transfer to hospital as
soon as possible.
Inhalation: Remove casualty from exposure ensuring one's own safety whilst doing so. If
unconscious, check for breathing and apply artificial respiration if necessary. If
unconscious and breathing is OK, place in the recovery position. If conscious, ensure
the casualty sits or lies down. If breathing becomes bubbly, have the casualty sit and
provide oxygen if available. Transfer to hospital as soon as possible.
4.2. Most important symptoms and effects, both acute and delayed
Skin contact: Irritation or pain may occur at the site of contact. Absorption through the skin may occur
causing symptoms similar to those of ingestion.
Eye contact: There may be irritation and redness. There may be severe pain. Corneal burns may
occur.
Ingestion: There may be difficulty swallowing. Inhalation of fumes from the stomach may cause
symptoms similar to direct inhalation. Nausea and stomach pain may occur. There may
be vomiting. The breathing may become shallow and rapid. May cause dizziness. There
may be loss of consciousness. Convulsions may occur.
Inhalation: There may be a feeling of tightness in the chest with shortness of breath. There may be
loss of consciousness. Convulsions may occur.
Delayed / immediate effects: Immediate effects can be expected after short-term exposure.
4.3. Indication of any immediate medical attention and special treatment needed
Immediate / special treatment: Immediate medical attention is required. Show this safety data sheet to the doctor in
attendance. Eye bathing equipment should be available on the premises.
Section 5: Fire-fighting measures
5.1. Extinguishing media
Extinguishing media: Carbon dioxide. Alcohol resistant foam.
5.2. Special hazards arising from the substance or mixture
Exposure hazards: Toxic. In combustion emits toxic fumes.
5.3. Advice for fire-fighters
Advice for fire-fighters: Wear self-contained breathing apparatus. Wear protective clothing to prevent contact
with skin and eyes.
Section 6: Accidental release measures
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SAFETY DATA SHEET
HYDREX 2510
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6.1. Personal precautions, protective equipment and emergency procedures
Personal precautions: Refer to section 8 of SDS for personal protection details. Mark out the contaminated area
with signs and prevent access to unauthorised personnel.
6.2. Environmental precautions
Environmental precautions: Do not discharge into drains or rivers. Contain the spillage using bunding.
6.3. Methods and material for containment and cleaning up
Clean-up procedures: Absorb into dry earth or sand. Clean-up should be dealt with only by qualified personnel
familiar with the specific substance.
6.4. Reference to other sections
Reference to other sections: Refer to section 8 of SDS.
Section 7: Handling and storage
7.1. Precautions for safe handling
Handling requirements: Ensure there is sufficient ventilation of the area. Avoid direct contact with the substance.
7.2. Conditions for safe storage, including any incompatibilities
Storage conditions: Store in cool, well ventilated area. Keep container tightly closed.
7.3. Specific end use(s)
Specific end use(s): No data available.
Section 8: Exposure controls/personal protection
8.1. Control parameters
Hazardous ingredients:
SODIUM HYDROXIDE
Respirable dust Workplace exposure limits:
State 8 hour TWA 15 min. STEL 8 hour TWA 15 min. STEL
UK 2 mg/m3 2 mg/m3 - -
8.2. Exposure controls
Engineering measures: Ensure there is sufficient ventilation of the area.
Respiratory protection: No specific recommendations , but respiratory protection may be required under
exceptional circumstances.
Hand protection: Protective gloves.
Eye protection: Safety goggles. Ensure eye bath is to hand.
Skin protection: Protective clothing with elasticated cuffs and closed neck. Boots made of PVC. Ensure
safety shower is to hand.
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SAFETY DATA SHEET
HYDREX 2510
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Section 9: Physical and chemical properties
9.1. Information on basic physical and chemical properties
State: Liquid
Colour: Colourless
Odour: Odourless
Oxidising: Non-oxidising (by EC criteria)
Solubility in water: Soluble
Viscosity: Non-viscous
Relative density: 1.18-1.22 pH: 10-12
9.2. Other information
Other information: Not applicable.
Section 10: Stability and reactivity
10.1. Reactivity
Reactivity: Stable under recommended transport or storage conditions.
10.2. Chemical stability
Chemical stability: Stable under normal conditions.
10.3. Possibility of hazardous reactions
Hazardous reactions: Hazardous reactions will not occur under normal transport or storage conditions.
Decomposition may occur on exposure to conditions or materials listed below.
10.4. Conditions to avoid
Conditions to avoid: Hot surfaces.
10.5. Incompatible materials
Materials to avoid: Acids.
10.6. Hazardous decomposition products
Haz. decomp. products: In combustion emits toxic fumes. Contact with acids liberates toxic gas.
Section 11: Toxicological information
11.1. Information on toxicological effects
Toxicity values:
Route Species Test Value Units
ORL MUS LD50 175 Sodium Nitrite mg/kg
ORL RAT LD50 180 Sodium Nitrite mg/kg
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SAFETY DATA SHEET
HYDREX 2510
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SCU RAT LD50 96600 Sodium
Nitrite
g/kg
Relevant effects for mixture:
Effect Route Basis
Acute toxicity (toxic) ING Hazardous: calculated
Irritation OPT DRM Hazardous: calculated
Symptoms / routes of exposure
Skin contact: Irritation or pain may occur at the site of contact. Absorption through the skin may occur
causing symptoms similar to those of ingestion.
Eye contact: There may be irritation and redness. There may be severe pain. Corneal burns may
occur.
Ingestion: There may be difficulty swallowing. Inhalation of fumes from the stomach may cause
symptoms similar to direct inhalation. Nausea and stomach pain may occur. There may
be vomiting. The breathing may become shallow and rapid. May cause dizziness. There
may be loss of consciousness. Convulsions may occur.
Inhalation: There may be a feeling of tightness in the chest with shortness of breath. There may be
loss of consciousness. Convulsions may occur.
Delayed / immediate effects: Immediate effects can be expected after short-term exposure.
Section 12: Ecological information
12.1. Toxicity
Ecotoxicity values:
Species Test Value Units
Daphnia magna 48H EC50 12.5-100 (Sodium
Nit
mg/l
Fish 96H LC50 0.56-1.78 (Sodium
Ni
mg/l
12.2. Persistence and degradability
Persistence and degradability: Biodegradable.
12.3. Bioaccumulative potential
Bioaccumulative potential: No bioaccumulation potential.
12.4. Mobility in soil
Mobility: Soluble in water.
12.5. Results of PBT and vPvB assessment
PBT identification: This substance is not identified as a PBT substance.
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HYDREX 2510
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12.6. Other adverse effects
Other adverse effects: Toxic to aquatic organisms. Do not allow concentrated product to enter rivers or water
courses.
Section 13: Disposal considerations
13.1. Waste treatment methods
Disposal operations: Transfer to a suitable container and arrange for collection by specialised disposal
company. Disposal should be carried out by licenced contractors. Do not allow entry to
drains or waterways.
Disposal of packaging: Containers must be disposed of in a safe way.
NB: The user's attention is drawn to the possible existence of regional or national
regulations regarding disposal.
Section 14: Transport information
14.1. UN number
UN number: UN3287
14.2. UN proper shipping name
Shipping name: TOXIC LIQUID, INORGANIC, N.O.S.
(SODIUM NITRITE)
14.3. Transport hazard class(es)
Transport class: 6.1
14.4. Packing group
Packing group: III
14.5. Environmental hazards
Environmentally hazardous: Yes Marine pollutant: Yes
14.6. Special precautions for user
Special precautions: No special precautions.
Tunnel code: E
Transport category: 2
Section 15: Regulatory information
15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
15.2. Chemical Safety Assessment
Chemical safety assessment: A chemical safety assessment has not been carried out for the substance or the mixture
by the supplier.
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SAFETY DATA SHEET
HYDREX 2510
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Section 16: Other information
Other information
Other information: This safety data sheet is prepared in accordance with Commission Regulation (EU) No
453/2010.
* indicates text in the SDS which has changed since the last revision.
Phrases used in s.2 and 3: H272: May intensify fire; oxidiser.
H301: Toxic if swallowed.
H314: Causes severe skin burns and eye damage.
H400: Very toxic to aquatic life.
R8: Contact with combustible material may cause fire.
R25: Toxic if swallowed.
R35: Causes severe burns.
R36/38: Irritating to eyes and skin.
R50: Very toxic to aquatic organisms.
Legal disclaimer: The above information is believed to be correct but does not purport to be all inclusive
and shall be used only as a guide. This company shall not be held liable for any
damage resulting from handling or from contact with the above product.
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