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1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND COMPANY/UNDERTAKING
Material Name : F-34 / AVTUR/FSII
Recommended Uses : Fuel for aviation turbine engines fitted to aircraft.

Other names : FUEL, AVIATION, TURBINE ENGINE
Product Code : 002C0944

Manufacturer/Supplier : The Shell Company of Australia Limited
(ABN 46 004 610 459)
8 Redfern Road
Hawthorn East
Victoria 3123
Australia
Telephone : +61 (0)3 9666 5444
Fax : +61 (0)3 8823 4800

Emergency Telephone
Number
: 1800 651 818 (within Australia only) +61 3 9663 2130
(International)

2. HAZARDS IDENTIFICATION
HAZARDOUS SUBSTANCE. DANGEROUS GOODS.
Classified as hazardous according to the criteria of NOHSC, and as Dangerous Goods according
to the Australian Dangerous Goods Code.

Symbol(s) : Xn Harmful.
N Dangerous for the environment.
R-phrase(s) : R10 Flammable.
R38 Irritating to skin.
R65 Harmful: may cause lung damage if swallowed.
R51/53 Toxic to aquatic organisms, may cause long-term
adverse effects in the aquatic environment.
S-phrase(s) : S2 Keep out of the reach of children.
S29 Do not empty into drains.
S23 Do not breathe vapour.
S24 Avoid contact with skin.
S61 Avoid release to the environment. Refer to special
instructions/Safety data sheets.
S62 If swallowed, do not induce vomiting: seek medical advice
immediately and show this container or label.
Health Hazards : Slightly irritating to respiratory system. Breathing of high
vapour concentrations may cause central nervous system
(CNS) depression resulting in dizziness, light-headedness,
headache and nausea. Irritating to skin. Harmful: may cause
lung damage if swallowed.
Signs and Symptoms : If material enters lungs, signs and symptoms may include
coughing, choking, wheezing, difficulty in breathing, chest
congestion, shortness of breath, and/or fever. The onset of
respiratory symptoms may be delayed for several hours after
exposure. Skin irritation signs and symptoms may include a
burning sensation, redness, swelling, and/or blisters. Breathing
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of high vapour concentrations may cause central nervous
system (CNS) depression resulting in dizziness, light-
headedness, headache, nausea and loss of coordination.
Continued inhalation may result in unconsciousness and death.
Safety Hazards : Liquid evaporates quickly and can ignite leading to a flash fire,
or an explosion in a confined space. Vapour in the headspace
of tanks and containers may ignite and explode at
temperatures exceeding auto-ignition temperature, where
vapour concentrations are within the flammability range.
Flammable. Electrostatic charges may be generated during
handling. Electrostatic discharge may cause fire.
Environmental Hazards : Toxic to aquatic organisms, may cause long-term adverse
effects in the aquatic environment.
Additional Information : This product is intended for use in closed systems only.
SUSDP Schedule : S5. When packed in containers having capacity of less than
20 litres.

3. COMPOSITION/INFORMATION ON INGREDIENTS
Preparation description : Complex mixture of hydrocarbons consisting of paraffins,
cycloparaffins, aromatic and olefinic hydrocarbons with carbon
numbers predominantly in the C9 to C16 range. May also
contain several additives at <0.1% v/v each.

Hazardous Components

Chemical Identity CAS EINECS Symbol(s) R-phrase(s) Conc.
Kerosine
(petroleum),
hydrodesulphurise
d
64742-81-0 265-184-9 Xi, Xn, N R10; R38;
R65; R51/53
0.00 - 100.00 %
Diethylene glycol
monomethyl ether
111-77-3 203-906-6 0.00 - 0.15 %
Kerosine 8008-20-6 232-366-4 Xi, Xn, N R10; R38;
R65; R51/53
0.00 - 100.00 %

Additional Information : Total aromatic hydrocarbons present are typically in the range
of 10-20%v/v. Dyes and markers can be used to indicate tax
status and prevent fraud. Refer to chapter 16 for full text of EC
R-phrases.

4. FIRST AID MEASURES
Inhalation : Remove to fresh air. If rapid recovery does not occur, transport
to nearest medical facility for additional treatment.
Skin Contact : Remove contaminated clothing. Immediately flush skin with
large amounts of water for at least 15 minutes, and follow by
washing with soap and water if available. If redness, swelling,
pain and/or blisters occur, transport to the nearest medical
facility for additional treatment.
Eye Contact : Flush eyes with water while holding eyelids open. Rest eyes for
30 minutes. If redness, burning, blurred vision, or swelling
persist, transport to the nearest medical facility for additional
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treatment.
Ingestion : If swallowed, do not induce vomiting: transport to nearest
medical facility for additional treatment. If vomiting occurs
spontaneously, keep head below hips to prevent aspiration.
Advice to Physician : Treat symptomatically.

5. FIRE FIGHTING MEASURES
Clear fire area of all non-emergency personnel.

Specific Hazards : Hazardous combustion products may include: A complex
mixture of airborne solid and liquid particulates and gases
(smoke). Carbon monoxide. Oxides of sulphur. Unidentified
organic and inorganic compounds. Will float and can be
reignited on surface water. Flammable vapours may be present
even at temperatures below the flash point. The vapour is
heavier than air, spreads along the ground and distant ignition
is possible.
Suitable Extinguishing
Media
: Foam, water spray or fog. Dry chemical powder, carbon
dioxide, sand or earth may be used for small fires only.
Unsuitable Extinguishing
Media
: Do not use water in a jet.
Protective Equipment for
Firefighters
: Proper protective equipment including breathing apparatus
must be worn when approaching a fire in a confined space.
Additional Advice : Keep adjacent containers cool by spraying with water. If
possible remove containers from the danger zone. If the fire
cannot be extinguished the only course of action is to evacuate
immediately.

6. ACCIDENTAL RELEASE MEASURES
Avoid contact with spilled or released material. For guidance on selection of personal protective
equipment see Chapter 8 of this Material Safety Data Sheet. See Chapter 13 for information on
disposal. Observe all relevant local and international regulations. Evacuate the area of all non-
essential personnel. Ventilate contaminated area thoroughly.

Protective measures : May ignite on surfaces at temperatures above auto-ignition
temperature. Do not breathe fumes, vapour. Do not operate
electrical equipment. Shut off leaks, if possible without
personal risks. Remove all possible sources of ignition in the
surrounding area. Use appropriate containment (of product
and fire fighting
water) to avoid environmental contamination. Prevent from
spreading or entering drains, ditches or rivers by using sand,
earth, or other appropriate barriers. Attempt to disperse the
vapour or to direct its flow to a safe location for example by
using fog sprays. Take precautionary measures against static
discharge. Ensure electrical continuity by bonding and
grounding (earthing) all equipment.
Clean Up Methods : For small liquid spills (< 1 drum), transfer by mechanical means
to a labelled, sealable container for product recovery or safe
disposal. Allow residues to evaporate or soak up with an
appropriate absorbent material and dispose of safely. Remove
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contaminated soil and dispose of safely.
For large liquid spills (> 1 drum), transfer by mechanical means
such as vacuum truck to a salvage tank for recovery or safe
disposal. Do not flush away residues with water. Retain as
contaminated waste. Allow residues to evaporate or soak up
with an appropriate absorbent material and dispose of safely.
Remove contaminated soil and dispose of safely. Shovel into a
suitable clearly marked container for disposal or reclamation in
accordance with local regulations.
Additional Advice : Notify authorities if any exposure to the general public or the
environment occurs or is likely to occur. Local authorities
should be advised if significant spillages cannot be contained.
Maritime spillages should be dealt with using a Shipboard Oil
Pollution Emergency Plan (SOPEP), as required by MARPOL
Annex 1 Regulation 26.

7. HANDLING AND STORAGE
General Precautions : Avoid breathing vapours or contact with material. Only use in
well ventilated areas. Wash thoroughly after handling. For
guidance on selection of personal protective equipment see
Chapter 8 of this Material Safety Data Sheet. Use the
information in this data sheet as input to a risk assessment of
local circumstances to help determine appropriate controls for
safe handling, storage and disposal of this material. Air-dry
contaminated clothing in a well-ventilated area before
laundering. Contaminated leather articles including shoes
cannot be decontaminated and should be destroyed to prevent
reuse. Properly dispose of any contaminated rags or cleaning
materials in order to prevent fires. Use local exhaust ventilation
if there is risk of inhalation of vapours, mists or aerosols.
Prevent spillages. Never siphon by mouth. For comprehensive
advice on handling, product transfer, storage and tank cleaning
refer to the product supplier.
Maintenance and Fuelling Activities - Avoid inhalation of
vapours and contact with skin.
Handling : Extinguish any naked flames. Do not smoke. Remove ignition
sources. Avoid sparks. Avoid inhaling vapour and/or mists.
Avoid prolonged or repeated contact with skin. When using do
not eat or drink. When handling product in drums, safety
footwear should be worn and proper handling equipment
should be used. The vapour is heavier than air, spreads along
the ground and distant ignition is possible. Earth all equipment.
Electrostatic charges may be generated during handling.
Electrostatic discharge may cause fire.
Storage : Drum and small container storage: Drums should be stacked to
a maximum of 3 high. Use properly labelled and closeable
containers. Take suitable precautions when opening sealed
containers, as pressure can build up during storage. Tank
storage: Tanks must be specifically designed for use with this
product. Bulk storage tanks should be diked (bunded). Locate
tanks away from heat and other sources of ignition. The vapour
is heavier than air. Beware of accumulation in pits and confined
spaces. Vapours from tanks should not be released to
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atmosphere. Breathing losses during storage should be
controlled by a suitable vapour treatment system.
Keep in a bunded area with a sealed (low permeability) floor, to
provide containment against spillage. Prevent ingress of water.
Product Transfer : Avoid splash filling. Wait 2 minutes after tank filling (for tanks
such as those on road tanker vehicles) before opening hatches
or manholes. Wait 30 minutes after tank filling (for large
storage tanks) before opening hatches or manholes. Keep
containers closed when not in use. Do not use compressed air
for filling, discharging or handling. Conditions, such as filling
empty Filter Water Separator vessels, that lead to the
formation of hydrocarbon mists are also particularly hazardous.
Contamination resulting from product transfer may give rise to
light hydrocarbon vapour in the headspace of tanks that have
previously contained gasoline. This vapour may explode if
there is a source of ignition. Partly filled containers present a
greater hazard than those that are full, therefore handling,
transfer and sampling activities need special care.
Recommended Materials : For containers, or container linings use carbon steel and low
alloy steel. Aluminium may also be used for applications
where it does not present an unnecessary fire hazard. For
container linings the following may also be used: Unplastisized
polyvinyl chloride (U-PVC), Fluoropolymers (PTFE),
Polyvinylidenefluoride (PVDF), Polyetheretherketone (PEEK),
Polyamide (PA-11). For seals and gaskets use:
Fluoroelastomer (FKM), Viton A, and Viton B, Nitrile butadiene
(NBR), Buna-N. For coating (paint) materials use: High build,
amine adduct-cured epoxy.
Unsuitable Materials : For containers or container linings, examples of materials to
avoid are: Polyethylene (PE, HDPE), Polypropylene (PP),
Polymethyl methacrylate (PMMA), Acrylonnitrile butadiene
styrene (ABS). For seals and gaskets, examples of materials to
avoid are: Natural rubber (NR), Ethylene Propylene (EPDM,
Polychloroprene (CR) - Neoprene, Butyl (IIR),
Chlorosulphonated polyethylene (CSM), e.g. Hypalon.
Container Advice : Containers, even those that have been emptied, can contain
explosive vapours. Do not cut, drill, grind, weld or perform
similar operations on or near containers.
Additional Information : In the interests of air safety, aviation fuels are subject to strict
quality requirements and product integrity is of paramount
importance. For one source of information on international
standards for the quality assurance of aviation fuels, see
www.jointinspectiongroup.org. Ensure that all local regulations
regarding handling and storage facilities are followed.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Occupational Exposure Limits


Additional Information : In the absence of a national exposure limit, the American
Conference of Governmental Industrial Hygienists (ACGIH)
recommends the following values for Kerosine: TWA - 200
mg/m3 Critical effects based on Skin, Irritation and Central
Nervous System.
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Exposure Controls : The level of protection and types of controls necessary will vary
depending upon potential exposure conditions. Select controls
based on a risk assessment of local circumstances.
Appropriate measures include: Adequate ventilation to control
airborne concentrations below the exposure guidelines/limits.
Use sealed systems as far as possible. Local exhaust
ventilation is recommended. Eye washes and showers for
emergency use.
Personal Protective
Equipment
: Personal protective equipment (PPE) should meet
recommended national standards. Check with PPE suppliers.
AS/NZS 1337: Eye protectors for industrial applications.
AS/NZS 2161: Occupational protective gloves - Selection, use
and maintenance. AS/NZS 1715: Selection, use and
maintenance of respiratory protective devices. AS/NZS 1716:
Respiratory protective devices.
Respiratory Protection : If engineering controls do not maintain airborne concentrations
to a level which is adequate to protect worker health, select
respiratory protection equipment suitable for the specific
conditions of use and meeting relevant legislation. Check with
respiratory protective equipment suppliers. Where air-filtering
respirators are unsuitable (e.g. airborne concentrations are
high, risk of oxygen deficiency, confined space) use
appropriate positive pressure breathing apparatus. Where air-
filtering respirators are suitable, select an appropriate
combination of mask and filter. All respiratory protection
equipment and use must be in accordance with local
regulations.
Hand Protection : Personal hygiene is a key element of effective hand care.
Gloves must only be worn on clean hands. After using gloves,
hands should be washed and dried thoroughly. Application of a
non-perfumed moisturizer is recommended. Suitability and
durability of a glove is dependent on usage, e.g. frequency and
duration of contact, chemical resistance of glove material,
glove thickness, dexterity. Always seek advice from glove
suppliers. Contaminated gloves should be replaced.
Select gloves tested to a relevant standard (e.g. Europe
EN374, US F739). When prolonged or frequent repeated
contact occurs, Nitrile gloves may be suitable. (Breakthrough
time of > 240 minutes.) For incidental contact/splash protection
Neoprene, PVC gloves may be suitable.
Eye Protection : Chemical splash goggles (chemical monogoggles).
Approved to EU Standard EN166.
Protective Clothing : Chemical resistant gloves/gauntlets, boots, and apron (where
risk of splashing).
Monitoring Methods : Monitoring of the concentration of substances in the breathing
zone of workers or in the general workplace may be required to
confirm compliance with an OEL and adequacy of exposure
controls. For some substances biological monitoring may also
be appropriate.
Environmental Exposure
Controls
: Local guidelines on emission limits for volatile substances must
be observed for the discharge of exhaust air containing vapour.

9. PHYSICAL AND CHEMICAL PROPERTIES
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Appearance : Pale straw. Liquid.
Odour : Hydrocarbon
pH : Data not available
Initial Boiling Point and
Boiling Range
: 150 - 300 C / 302 - 572 F
Freezing/melting point : Data not available
Flash point : > 38 C / 100 F (ASTM D-93 / PMCC)
Lower / upper Flammability
or Explosion limits
: 1.0 - 6.0 %(V)
Auto-ignition temperature : > 220 C / 428 F
Vapour pressure : < 0.1 hPa at 20 C / 68 F
Specific gravity :
Density : 0.775 - 0.84 g/cm3 at 15 C / 59 F
Solubility in other solvents : Data not available
n-octanol/water partition
coefficient (log Pow)
: 2 - 6
Kinematic viscosity : 1 - 2 mm2/s at 40 C / 104 F
Vapour density (air=1) : Data not available

10. STABILITY AND REACTIVITY
Stability : Stable under normal conditions of use.
Conditions to Avoid : Avoid heat, sparks, open flames and other ignition sources.
Materials to Avoid : Strong oxidising agents.
Hazardous
Decomposition Products
: Hazardous decomposition products are not expected to form
during normal storage.
Thermal decomposition is highly dependent on conditions. A
complex mixture of airborne solids, liquids and gases including
carbon monoxide, carbon dioxide, sulphur oxides and
unidentified organic compounds will be evolved when this
material undergoes combustion or thermal or oxidative
degradation.

11. TOXICOLOGICAL INFORMATION
Basis for Assessment : Information given is based on product data, a knowledge of the
components and the toxicology of similar products.
Acute Oral Toxicity : Low toxicity:LD50 >2000 mg/kg, Rat
Aspiration into the lungs when swallowed or vomited may
cause chemical pneumonitis which can be fatal.
Acute Dermal Toxicity : Low toxicity:LD50 >2000 mg/kg, Rabbit
Acute Inhalation Toxicity : Low toxicity: LC50 >5 mg/l / 4 h, Rat
High concentrations may cause central nervous system
depression resulting in headaches, dizziness and nausea;
continued inhalation may result in unconsciousness and/or
death.
Skin Irritation : Irritating to skin.
Eye Irritation : Slightly irritating.
Respiratory Irritation : Slightly irritating.
Sensitisation : Not a skin sensitiser.
Repeated Dose Toxicity : Kidney: caused kidney effects in male rats which are not
considered relevant to humans
Mutagenicity : Not considered a mutagenic hazard.
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Carcinogenicity : Not classified as a carcinogen.
Repeated skin contact has resulted in irritation and skin cancer
in animals.
Reproductive and
Developmental Toxicity
: Not expected to be a developmental toxicant.

12. ECOLOGICAL INFORMATION
Fuels are typically made from blending several refinery streams. Ecotoxicological studies have
been carried out on a variety of hydrocarbon blends and streams but not those containing
additives. Information given is based on a knowledge of the components and the ecotoxicology
of similar products.

Acute Toxicity : Toxic:LL/EL/IL50 1-10 mg/l(to aquatic organisms)(LL/EL50
expressed as the nominal amount of product required to
prepare aqueous test extract).
Mobility : Floats on water. Contains volatile constituents. Evaporates
within a day from water or soil surfaces. Large volumes may
penetrate soil and could contaminate groundwater.
Persistence/degradability : Major constituents are expected to be inherently
biodegradable. The volatile constituents will oxidize rapidly by
photochemical reactions in air.
Bioaccumulation : Contains constituents with the potential to bioaccumulate.

Other Adverse Effects : Films formed on water may affect oxygen transfer and damage
organisms.

13. DISPOSAL CONSIDERATIONS
Material Disposal : Recover or recycle if possible. It is the responsibility of the
waste generator to determine the toxicity and physical
properties of the material generated to determine the proper
waste classification and disposal methods in compliance with
applicable regulations. Do not dispose into the environment, in
drains or in water courses. Do not dispose of tank water
bottoms by allowing them to drain into the ground. This will
result in soil and groundwater contamination. Waste arising
from a spillage or tank cleaning should be disposed of in
accordance with prevailing regulations, preferably to a
recognised collector or contractor. The competence of the
collector or contractor should be established beforehand.
Container Disposal : Send to drum recoverer or metal reclaimer. Drain container
thoroughly. After draining, vent in a safe place away from
sparks and fire. Residues may cause an explosion hazard if
heated above the flash point. Do not puncture, cut or weld
uncleaned drums. Do not, puncture, cut, or weld uncleaned
drums. Do not pollute the soil, water or environment with the
waste container. Comply with any local recovery or waste
disposal regulations.
Local Legislation : Disposal should be in accordance with applicable regional,
national, and local laws and regulations. Local regulations may
be more stringent than regional or national requirements and
must be complied with.
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14. TRANSPORT INFORMATION
ADG
UN number 1863
Proper shipping name FUEL, AVIATION, TURBINE ENGINE
Class 3
Packing group III
Hazchem Code

3Y

IMDG
Identification number UN 1863
Proper shipping name FUEL, AVIATION, TURBINE ENGINE
Class / Division 3
Packing group III
Marine pollutant: Yes


IATA (Country variations may apply)
UN No. : 1863
Proper shipping name : Fuel, aviation, turbine engine
Class / Division : 3
Packing group : III


15. REGULATORY INFORMATION
The regulatory information is not intended to be comprehensive. Other regulations may apply to this
material.

SUSDP Schedule : S5. When packed in containers having capacity of less than
20 litres.
Not scheduled. When packed in containers having capacity of
greater than 20 litres.

AICS : All components
are listed or
exempt

Classification triggering
components
: Contains kerosine.

Other Information : National Code of Practice for the Preparation of Material Safety
Data Sheets [NOHSC:2011] List of Designated Hazardous
Substances [NOHSC:10005]. Approved Criteria for Classifying
Hazardous Substances [NOHSC:1008]. Adopted National
Exposure Standards for Atmospheric Contaminants in the
Occupational Environment [NOHSC:1003]. Australian
Dangerous Goods Code. Standard Uniform Scheduling of
Drugs and Poisons.
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16. OTHER INFORMATION
Additional Information : This document contains important information to ensure the
safe storage, handling and use of this product. The information
in this document should be brought to the attention of the
person in your organisation responsible for advising on safety
matters.
R-phrase(s)
R10 Flammable.
R38 Irritating to skin.
R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic
environment.
R65 Harmful: may cause lung damage if swallowed.

MSDS Version Number : 1.2

MSDS Effective Date : 08.04.2010

MSDS Revisions : A vertical bar (|) in the left margin indicates an amendment
from the previous version.
MSDS Regulation :
Uses and Restrictions : This product must not be used in applications other than those
recommended in Section 1, without first seeking the advice of
the supplier.
This product is not to be used as a solvent or cleaning agent;
for lighting or brightening fires; as a skin cleanser.
Not to be used as a fuel for automotive vehicles.
Not to be used to prevent waxing in diesel fuel.

MSDS Distribution : The information in this document should be made available to
all who may handle the product.
Disclaimer : This information is based on our current knowledge and is
intended to describe the product for the purposes of health,
safety and environmental requirements only. It should not
therefore be construed as guaranteeing any specific property
of the product.