WinSim Inc.

Advanced Process
Simulation Solutions
FREE TWO WEEK TRIAL
NEW !
Dynamic
Simulation
Capability

2
TABLE OF CONTENTS
The Value of WinSim 3
Process Simulator Comparison 4
DESIGN II for Windows 5
How to Test Drive DESIGN II for Windows 7
Some of Our Process Industry Customers 8
What Some of Our Customers Say about Us 9
Diagram User Interface 10
Excel Results Transfer 11
Pipeline Modeling 11
Exchange Data with Spreadsheet 12
Dynamic Simulation 13
Tank Unit Module 14
Single and Mixed Amines 15
Petroleum Crude Processing 16
Sulfur Recovery Process 17
Ammonia Plant Modeling 18
Natural Gas Dehydration 19
Fuel Cell Modeling 19
Batch Distillation Column 20
Distillation Columns 21
Heat Exchangers 22
Available Unit Modules 23
Multiple Phase Flash 24
Thermodynamic Methods 25
Feed Stream Specifications 26
Unit Module Specifications 27
Depressuring Unit Module 27
Inline Fortran 28
Custom Stream Properties 28
ChemTran 29
Link2WinSim 30
DESIGN II for Windows Advanced Features 31
Online Help and Manuals 32
DESIGN II History 33
100s of Sample Flowsheets 34
Features and Specifications 34
Contact Information 36

3
The Value of WinSim
WinSim Offers Engineers Many Reasons To Use Our Simulation Solutions

WinSims Value

WinSim offers the highest-valued dynamic and steady-state simulation solution in the market. With DESIGN II, our clients
reduce their simulation costs, not their capabilities.

WinSims solution includes more than just a great simulator. WinSim offers the best and most responsive technical
support in the business. 95% of technical support issues originating in North America are resolved within two business
hours. 95% of technical support issues originating overseas are resolved within one business day.

WinSims competitive pricing allows our clients to avoid resource limitations caused by restricted software access.
DESIGN II for Windows can also be used for validation of legacy software.

WinSims Market Position

With our powerful software, incredible technical support, and competitive pricing WinSim has met the industrys demand
for a viable alternative in the simulation market. Focusing entirely on one product, DESIGN II for Windows, has allowed
WinSim to pass savings in overhead costs along to our clients. The market has clearly taken notice. WinSims market
share has grown steadily over the past several years both in customer base and revenue.

Why WinSim?

No one else has the industry knowledge, proven experience, and competitive pricing. Our software, training, and support
will help you immediately reduce simulation costs, increase equipment and economic performance, and identify critical
process performance issues.

Why in the World is DESIGN II for Windows so Competitively Priced?

This is Our Core Competency. WinSim's entire focus is on the Design, Development, and Deployment of Advanced
Process Simulation Solutions. DESIGN II for Windows is the only process simulator offered.

This is Our Corporate Direction. The management at WinSim has made a business decision to concentrate specifically
on process simulation. This reduction in overhead costs is reflected in our competitive pricing.

This Created a Competitive Climate. WinSim's aggressive approach to "Minimize Our Costs, Maximize Our Solutions,
and Optimize Our Customers Processes" has clearly provided a competitive alternative in the simulation market.

Who is WinSim Inc.?

The ChemShare Corporation started marketing the DESIGN program in 1969. In the 1970s, the Distill program was
written and added to DESIGN to create the product DESIGN 2000. In the late 1970s / early 1980s, the Refine program
was written and added to the DESIGN 2000 to create the product DESIGN II. The DESIGN II name has been used to
date even though the software has been through many generations in the time span.

In 1995, several ChemShare employees formed WinSim Inc. An agreement was reached with ChemShare Corporation
to purchase an exclusive worldwide license to market and develop DESIGN II
TM
Simulation Systems. This action created
the business structure to focus and build on the 26 years of ChemShares outstanding service to simulation clients.

WinSim is solely dedicated to the furtherance of the DESIGN II for Windows software. Because of our focus, DESIGN II
for Windows is the best value in the simulation market today.

4
Process Simulator Comparison

Category
DESIGN II for
Windows
Hysys Pro/II
ProMax

Aspen
Plus
Chem
CAD

1-Click Data Export to MS Excel
Component Library
Thermodynamic Options
Recycle Convergence
Gas Processing
Batch Simulation + + + +
Dynamic Simulation + + + +
Heat Exchanger Rating + + + +
Strong Electrolytes + +
Pipeline Networks + + + +
Mixed Amines + +
General
Claus Process + + + +

Rigorous Distillation Columns
Batch Distillation Column +
Pipeline
Heat Exchangers
Flash
Reactors
Pumps & Compressors
Unit
Modules
Storage Tanks + + +

Windows Based GUI
Interface
Text Based UI

Onsite
Offsite Training
Seminar

Usage Support
Expert Process Support
Support by Phone
Support
and
Upgrades
Support by E-mail

Legend
Standard Feature
+ Available Feature for Additional License and/or Fee


5
DESIGN II for Windows
THE WORKFLOW MODEL IS EASY AND FAST DUE TO WINDOWS BUILT IN FEATURES !





Build
Flowsheet,


Transfer to
Excel,

Create
Report


6
DESIGN II for Windows
RIGOROUS PROCESS SIMULATION FOR CHEMICAL AND HYDROCARBON PROCESSES INCLUDING REFINING,
REFRIGERATION, PETROCHEMICAL, GAS PROCESSING, GAS TREATING, PIPELINES, FUEL CELLS, AMMONIA,
METHANOL AND HYDROGEN FACILITIES
The Easy Way To Do Simulation
Microsoft

Windows

has become the standard for desktop graphical computing and WinSim's DESIGN II FOR WINDOWS
was the first process simulator developed specifically for Windows computing. DESIGN II FOR WINDOWS has been leading
the way in this technology since 1991.
Instant Usability
One click and you'll be convinced: DESIGN II FOR WINDOWS is the easy way to do simulation. WinSims original process
simulator for Windows is intuitive and inter-operable with other Windows applications. Its look and feel provides an
instant familiarity for experienced Windows users. The graphical interface means there are no special commands or
function keys to remember. Just draw your flowsheet with point-and-click simplicity. Double click on flowsheet equipment
and streams for specification dialog boxes to appear. Once your flowsheet is complete, DESIGN ll for Windows will even
validate your input before computing the simulation results. Export stream and equipment results to Microsoft Excel, or
display the complete results as a text file. The simulation is fast, easy, and error free.
The Proven Pioneer of Simulator Engines - DESIGN II

With a forty plus year history of continued development and refinement, DESIGN II has long been a leader in process
simulator innovation. Many DESIGN II features, such as Inline FORTRAN and rigorous column calculations, have set the
standard for process simulation. Because of its proven strengths, DESIGN II is the simulation engine underlying DESIGN
II FOR WINDOWS. DESIGN II is a powerful and comprehensive process simulation computational engine, which performs
complete heat and material balance calculations for a wide variety of pipeline and processing applications. The
simulators easy-to-create flowsheets allow process engineers to concentrate on engineering, rather than computer
operations. A minimum amount of input is required to utilize DESIGN II FOR WINDOWS. WinSims simulator offers
advanced features, such as sizing and rating of heat exchangers and separators, within the flowsheet. The DESIGN II
FOR WINDOWS database contains 1,200+ pure components, and others can be added via CHEMTRAN. Also included is a
crude library with 38 world crudes, already characterized and at your fingertips.
Applications:
Physical Properties
2 Phase Pipeline Modeling
Expander and Lean Oil Plants
Glycol Units
Amine Units (Single and Mixed)
Gathering & Transmission
Rigorous Refinery Columns
Petrochemical, Hydrocarbon,
Refrigeration, Chemical,
Ammonia, Methanol and
Hydrogen Plants
Heat Exchanger Sizing & Rating
Separator Sizing & Rating
VLE / LLE Data Regression
Fuel Cell Systems
A Perfect Fit for Any Environment
Whether the situation requires a quick answer to a simple pressure drop problem or a complete simulation model of a
large plant for operational engineering, DESIGN II FOR WINDOWS is the perfect combination of power and ease-of-use.
The size and complexity of the flowsheet, including the number of unit operations, streams, and components, is practically
unlimited.

7
How To Test Drive
DESIGN II for Windows

TRY THE FULLY WORKING VERSION OF DESIGN II FOR WINDOWS FOR FREE ! ! !
Are you looking for a rigorous yet fast and
easy to use process simulator ?
You can now Test Drive the Professional version of
DESIGN II absolutely free! The only difference
between the Test Drive version and the purchased
version of DESIGN II is the length of time your
password will be valid.
Its as easy as 1-2-3
Visit our website at www.winsim.com. Follow the
"Download Files" link to download the latest version
of DESIGN II for Windows.
Follow the simple setup instructions
Once the installation is finished, double click on the
DESIGN II for Windows icon placed on the desktop
of your PC. You will see a unique Computer ID
number generated by the program for your computer.
Get a test drive password
Take your Computer ID number back to the website
and follow the "2 Week Password" link. A password
will be automatically e-mailed to you.
Read and work through the tutorial on our
online help
While you are test driving, you may want to read and
work through the interactive tutorial. Once you are in
the program, you can find the tutorial by clicking on
"Help" and then clicking on "Tutorial". Or, the tutorial
is available on our website at
http://www.winsim.com/tutorial/.
Try one of our 300 sample flowsheets
Also, WinSim has included over 300 examples of
working flowsheets for you to look at. To view the
example files, just click on File... Open... c:\...
Program Files (x86) DesignII... samples... and then
you will see various files intuitively categorized.
Contact our technical support if necessary
When you need help with a detail or want a hint, just
contact technical support at [email protected],
phone 281-545-9200 x106, or fax 281-545-8820.
One of the best ways to get your point across is to
email the flowsheet file to us.
FREE
Two Week
Test Drive

8
Some of Our Process Industry
Customers
DESIGN II FOR WINDOWS HAS MANY USERS WITH WIDELY VARYING NEEDS

A Al ll l t tr ra ad de em ma ar rk ks s r re ep pr re es se en nt te ed d o on n t th hi is s p pa ag ge e a ar re e t th he e p pr ro op pe er rt ty y o of f t th he ei ir r r re es sp pe ec ct ti iv ve e o ow wn ne er rs s. .












9
What Some of our Customers
Say about Us
DESIGN II FOR WINDOWS HAS DEDICATED FANS ! ! !


The results generated by Design II are quite consistent with other, higher priced simulators. WinSim
support has been very responsive to our needs, always responding quickly to requests for support.
They have listened to our requests for additional features, continually adding new capabilities
John Estill
Ascent Engineering
Houston, TX


The principal advantage of the software is its ease of use and excellent technical support. We have
never waited more than a few hours to receive answers to our questions or help in getting a simulation
to run. The thermodynamic packages available are second to none The use of Chemtran data base
files alleviates the need to use expensive specialized software
We would recommend this software for businesses, consultants or process engineers this
software is easily justified and is becoming the Gold Standard for those who want value and service in
the same package!
Murray Page P.E.
Principal
The Process Group, LLC
Irvine, CA


Chem-Engineering Services replaced another process simulator used for 15 years with Design II
gaining tremendous new advantages.
WinSim Inc. Design II process simulation software offers users incredible chemical plant modeling
The software includes all unit operations of chemical engineering at incredibly low cost, compared
with other vendors process engineering simulator software.
Glenn Combs
Process Technology Consultant
Chem-Engineering Services
Monroe, Louisiana


For the last fifteen years we use DESIGN II exclusively on ALL jobs.
As consultants to worldwide refiners and petrochemical plants we rely on predictions made by
DESIGN II to design new processes and optimize existing ones.
Raj D. Kulkarni, P. E.
President
Petro Project Engineering, Inc.
Houston, TX



10
Diagram User Interface
DESIGN II FOR WINDOWS OFFERS AN EASY TO USE AND POWERFUL USER INTERFACE
Easy and Powerful
DESIGN II for Windows contains an easy to use and
powerful user interface for any version of Windows. You
can model an unlimited amount of information since you
can add many sheets to the flowsheet.
Controlled by a Toolbox
The user interface is controlled by the toolbox with five
modes. The first mode is the selection mode (indicated
by the left leaning arrow). You can individually select any
item or a group of items in this mode. You can then
modify, move or delete the item(s) that you have
selected. The second mode is the stream mode
(indicated by the drawing pen). You can create, append,
delete, edit the properties or the view the simulation
results of any selected stream in this mode. You can
also change the placement and amount of line arrows for
any stream. The third mode is the text mode (indicated
by the uppercase T). You can create, append, delete or
edit the properties of any selected text item in this mode.
The fourth mode is the graphical drawing mode in which
you can add lines, arcs, rectangles, circles, etc to the
drawing.
Note that you can drag a unit module symbol from the
toolbox to the drawing in any mode. You can also delete,
edit the properties or view the simulation results of any
selected unit module while in selection mode.
Many Unit Module Symbols
There are 78+ symbols that can be used to model unit
operations in the flowsheet. You can easily create new
symbols and symbol libraries. You can also display
simulation results on the flowsheet for each of the unit modules (such as duty, stages, name, number, etc).
Stream Data Box
You can add a stream data box with stream simulation
results to your flowsheet. You can display all streams on
the sheet, all streams in the flow sheet, or display just
selected streams. You can also change the dimensional
units (with corresponding value changes) for many of the
results.
Results on the Fly
The flowsheet itself is interactive as you move the mouse
about the flowsheet. Small windows (tooltips) are auto-
matically displayed for you with information about the unit
module or stream that the mouse is hovering over.
Continuing Streams from One Sheet to Another
Streams can be continued from any sheet to any sheet by
simply numbering the stream with the same number. The user interface will automatically make sure that the streams are
connected to only one unit module at each end.
Feed and Product Streams
Any stream can be a feed or a product stream. No special symbols are needed to indicate that the stream is a feed or
product, simply an unconnected end of the stream will tell that it is a feed or product.

11
Excel Results Transfer
DESIGN II FOR WINDOWS OFFERS FAST AND EASY RESULTS TRANSFER TO MICROSOFT EXCEL
DESIGN II for Windows contains a high-
speed application for sending ALL of your
results data to Microsoft Excel with a single
click. Upon your clicking a button,
DESIGN II Excel Blaster will start
Microsoft Excel, open the old
spreadsheet or create a new spreadsheet,
and transfer the results of your current
flowsheet into Excel. All of the results data
transferred to Excel will be properly
formatted and placed on appropriate
pages. You can also select additional
items to be displayed on the stream
summary sheet with specified dimensional
units.
You can choose to have five different types
of your results data sent to Excel: the
material balance, the stream summary
data, the equipment data, the detail stream
results data or all results. We use all
results to refer to the sending of all your
results data to Excel. You can also choose
configuration options which allows you to select additional items and / or specify dimensional units.
The DESIGN II Excel Blaster is compatible with all English and International versions of Microsoft Excel 2013, 2012,
2010, 2007, 2003, XP, 2000, 97 and 95.
Pipeline Modeling
DESIGN II FOR WINDOWS OFFERS ENGINEERS RIGOROUS SIMULATION OF PIPELINES
DESIGN II FOR WINDOWS provides
complete pipeline modeling and sizing
capabilities. This covers more than just
simple pressure drop calculations. For
example, both single and two-phase
streams and networks can be sized to
meet any of the following constraints:
Pressure Drop
Velocity
Sonic Velocity Fraction
Nominal Diameter
DESIGN II FOR WINDOWS also rigorously
accounts all heat transfer and elevation
changes associated with piping systems.
Materials of construction that may be used
range from aluminum to stainless steel.
You also get complete slug analysis for
condensed liquids moving within piping
systems. This is particularly important for light hydrocarbon streams such as those associated with natural gas gathering
fields.

12
Exchange Data with
Spreadsheet
YOU CAN TRANSFER DATA TO OR FROM EXCEL BEFORE AND AFTER A SIMULATION
You can transfer
specification data from an
Excel spreadsheet to a
flowsheet before running a
simulation. You can also
export calculated simulation
results from a flowsheet to a
spreadsheet after running a
simulation. You control
exactly which data items are
transferred.
You can transfer data to/from
streams, heat exchangers,
air coolers and several other
equipment modules. You
can have several choices of
spreadsheet files to use for
both import and export of
data. Each individual item
can have its own
spreadsheet file or use the
general spreadsheet for that
mode (import or export).
Note that all flowsheet
validation logic will be run
after the specification data is
transferred from Excel to
DESIGN II for Windows.
Then the simulation
calculation will be run if the
flowsheet validation is
successful.
Each item to be transferred
will be selected based on a
stream or equipment
currently in the flowsheet
and a specific item belonging
to it. The Excel location will
require specification of the
sheet name, column and
row. Dimensional units
transfer is optional.
In addition, there is a test
mode on all the dialogs to
test transfer your data items
independent of the
simulation calculation.

13
Dynamic Simulation
DESIGN II FOR WINDOWS OFFERS BOTH STEADY STATE AND DYNAMIC SIMULATION
As of version 11.00, DESIGN II for Windows contains a new flowsheet level implementation of Dynamic Simulation.
Previous releases of DESIGN II contained two unit modules that incorporated time capabilities, the Depressurizer and the
Batch Distillation Column. Both of these unit modules are still completely available and have not been changed at all.
The new capability is that time awareness has been implemented at the flowsheet level.

The default simulation mode for DESIGN II is steady state. That is, all calculations will proceed until the entire flowsheet
is in equilibrium or the users specified maximum number of recycle iterations has been reached. If DESIGN II sees a
time duration command and a time interval command, then it will automatically switch into dynamic simulation mode.
In the DESIGN II for Windows user interface, the time interval is defaulted to five minutes and the time duration is
defaulted to sixty minutes. The time units can be any conventional time unit: seconds, minutes, hours, days or years.
The time commands are controlled by the Specify / Dynamic Settings dialog. The user controls whether these commands
are used by clicking on the DII button (or the Simulate / Execute Steady State menu entry) or clicking on the DYN
button (or the Simulate / Execute Dynamic menu entry).
When DESIGN II switches into dynamic simulation mode, several things will automatically start to happen. First, the
calculations will proceed normally until completion. At the end of the calculations, each stream will calculate the amount
of material and energy that passed through that stream for that time interval. Then the normal material balance (molar
and mass by component and then by node), energy balance and power balance reports will be calculated. Then a new
section of reports specific to dynamic calculations will be generated: a material holdup report (molar and mass) and a
dynamic material balance report (molar and mass by component and then by node). Note that the Tank unit module is
the only unit module that will report material holdup for the dynamic material holdup calculations. Then DESIGN II will
proceed onto the next time interval.
When DESIGN II has reached the time duration set by the user, another set of reports will be generated. The total
dynamic material holdup by time interval is generated on a molar and mass basis. Also, the total dynamic material
balance by time interval is generated on a molar and mass basis.
There are three dynamic simulation sample flowsheets in c:\Program Files (x86)\DesignII\samples\dynamic: tank1.psd,
tank2.psd and tank3.psd.


14
Tank Unit Module
DESIGN II FOR WINDOWS OFFERS A CONSTANT VOLUME TANK IN VARIOUS CONFIGURATIONS
DESIGN II for Windows
contains a new Tank unit
module for calculating the
dynamic effects of feeds,
accumulations and products
from a constant volume tank.
Temperature, pressure,
composition and phases will
be calculated over a period
of time specified by the user
for the entire flowsheet.
Both pure components and
mixed phases can be
handled Tank unit module.
The Tanks geometry can be
specified as horizontal,
vertical or spherical. The
diameter of the tank must be
specified along with the
length if the tank is vertical or
horizontal.
The Tank will allow the user
to specify an initial
composition based on molar,
mass, volumetric or fractional amount with pressure and temperature.
The initial time step calculates the initial amount of material in the tank. Subsequent time steps and additions from feed
streams (if any), subtractions from product streams (if any), will calculate the resulting temperature, pressure and
compositions of the tank. If there is a vent specified then the vent stream will allow vapor to bleed off to meet the vent
pressure specification while maintaining adiabatic equilibrium.
The product streams can be specified using molar, mass or volumetric flowrates. The product streams can be started
and/or stopped according to the user's time specifications. The liquid product streams will only run if there is liquid in the
tank and the vapor product streams will only run if there is vapor in the tank. The product stream will only run if the start
time is less than the current time
and the stop time is zero or
greater than the last time step
value.
The Tank has an optional vent
stream where all you have to do
is specify the vent pressure. The
Tank will automatically calculate
the flow rate out the vent in order
to keep the tank at the vent
pressure. The physical size of
the vent stream is not taken into
account for how much material
can flow out through.
There are three tank sample
flowsheets in c:\Program Files
(x86)\DesignII
\samples\equipmnt\tank:
tank1.psd, tank2.psd and
tank3.psd.

15
Single and Mixed Amines
DESIGN II FOR WINDOWS OFFERS THE INDUSTRY'S FOREMOST RATE-BASED SINGLE AND BLENDED AMINE
SIMULATOR FOR NATURAL GAS AND LPG TREATING APPLICATIONS
Rate Based Column Models
Accurate kinetic models are used to determine reaction rates and their impact on column operation. Rigorously
accounting for the kinetic and hydrodynamic effects in selective gas treatment allows for the proper design and operation
of treating units. Avoid under design (insufficient CO
2
pickup) or over design (excessive CO
2
removal, loss of selectivity
and possible increased content of H
2
S in sweet gas). Thermodynamic models (Kent-Eisenberg or Deshmukh-Mather)
rigorously account for the ionic nature of the solvents, rates of mass transfer, heat transfer coefficients, and driving
forces. Reaction kinetics will determine mass transfer enhancement factors and selective removal rates.
Selective Stripping and Solvent Formulation
By simulating processes that employ either a single amine or a binary blend of MEA, DEA, DGA, DIPA, MDEA and
Piperazine as solvents, DESIGN II FOR WINDOWS allows the selective removal of H
2
S and CO
2
. The user may, for
example, debottleneck DEA columns or lower the CO
2
content of sweet gas from MDEA columns. This allows the
engineer to reduce their amine operating cost by formulating a solvent that best meets their particular needs.
Real Column Simulation
Both trayed and packed columns are modeled by describing their actual configuration. Packed columns need not be
converted to trays (HETP) or the actual trays to equilibrium trays; DESIGN II FOR WINDOWS calculates the actual mass
transfer in a section of packing or on a real tray. You can specify the pressure drop over the entire column, the pressure
drop per tray, or request the program calculate the pressure drop. The column parameters are outlined below.
Trayed Columns:
Number of Actual
Trays
Tray Area Percent
Tray Type
Tray Spacing
Weir Height
Number of Passes
Packed Columns:
Packing Depth
Packing Type
Packing Size
Packing Factor
Specific Area
Multiple Packing
Sections

Preset Flowsheets
Because these
applications are rigorous, the flowsheets can be very sensitive on convergence. With DESIGN II FOR WINDOWS you can
work with one of our many already converged flowsheets and modify the input to fit your own data. Or, you may build a
flowsheet and create your own unique process.

Applications
Sour Natural Gas Treating, Sour LPG Treating, Tail Gas Treating, Off-Gas Upgrading, and more.


16
Petroleum Crude Processing
DESIGN II FOR WINDOWS OFFERS ENGINEERS RIGOROUS SIMULATION AND OPTIMIZATION OF ONE OR MORE
DISTILLATION COLUMNS RECEIVING HIGH HYDROCARBON FEEDS WITH COMPLEX HEAT TRAINS FOR MAXIMUM
PRODUCT RECOVERY AND HEAT LOSS MINIMIZATION
Crude Feed Streams
DESIGN II FOR WINDOWS can simulate multiple crude feeds into the process. The hydrocarbon feeds are typically
characterized by TBP, ASTM D-86/1160 or D-2887 distillation curves. DESIGN II allows entry of as much information as
you have for your feed(s), from the minimum required details to define a feed (distillation curve, bulk gravity, temperature,
pressure and flow rate) to more elaborate data such as sulfur weight percent curves, viscosity curves, pour point and
metals content. You can also choose to map all your crude feeds onto a single set of petroleum fractions (blending) or to
map each crude feed stream onto a unique set of petroleum fractions.
Refine Columns
The Refine Columns are used for rigorous simulation of distillation columns receiving high hydrocarbon-content feeds.
Many common refinery units can be modeled including pre-flash towers, atmospheric columns, vacuum columns, FCC
main fractionators and quench columns. Multiple side strippers, pumparounds, and side heaters / coolers can be added
to the main column configuration for a rigorous simultaneous calculation. Refine Columns can be used for designing or
modifying refinery fractionators with very good results. It is possible to duplicate the operation of existing units within a
few percent of actual plant data.
The simulator can match many important operational parameters, such as tower temperatures, reflux ratio, product rates
and property specifications. Significant discrepancies are usually due to inaccuracies in data collection, but may be due
to operational problems. In these cases a Refine Column may be used to identify the source of the problem and
determine the solution.


17
Sulfur Recovery Process
DESIGN II FOR WINDOWS OFFERS ENGINEERS RIGOROUS SIMULATION AND OPTIMIZATION OF CLAUS PLANTS
The Claus process is the most significant gas desulfurizing process, recovering elemental sulfur from gaseous hydrogen
sulfide. First invented over 100 years ago, the Claus process has become the industry standard. The multi-step process
recovers sulfur from the gaseous
hydrogen sulfide found in raw
natural gas and from the by-
product gases containing hydrogen
sulfide derived from refining crude
oil and other industrial processes.
The final step involves oxidation of
the hydrogen sulfide.
Gases with a H
2
S content of over
25% are suitable for the recovery
of sulfur in Claus plants. These
gases may also contain hydrogen
cyanide, hydrocarbons, sulfur
dioxide or ammonia. They mainly
originate from physical and
chemical gas treatment units
(Coastal AGR, Genosorb 1753,
Selexol, Rectisol, Purisol and
amine scrubbers) in refineries,
natural gas processing plants and
gasification or synthesis gas
plants. The sulfur recovered in Claus plants is used for manufacturing sulfuric acid, medicine, cosmetics, fertilizers and
rubber products.
DESIGN II supports the sulfur polymers Sulfur 2, Sulfur 3, Sulfur 4, Sulfur 5, Sulfur6, Sulfur 7 and Sulfur 8. In the liquid
phase, all sulfur is modeled as
Sulfur 8. In the vapor phase, the
sulfur vapor is automatically
redistributed into the seven sulfur
polymers when temperature or
pressure has been changed in a
unit module.
For the combustion reactor,
hydrogen sulfide is combusted with
oxygen to form sulfur dioxide
(2H
2
S + 3O
2
2SO
2
+ 2H
2
O). For
the catalytic reactor, sulfur dioxide
is combusted with hydrogen sulfide
to form atomic sulfur and water
(2H
2
S + SO
2
3S + 2H
2
O). Both
of these reactors are modeled in
DESIGN II using the Equilibrium
Reactor unit module. The standard
flash unit modules are used to
separate the liquid sulfur from the
vapor streams.
The GPSA Data Book Claus Process (ClausGPSA.psd)
This sample flow sheet models the Claus Process in the GPSA data book using Sulfur 2, Sulfur 6 and Sulfur 8.
The GPSA Data Book Claus Process (ClausAllSulfurSpecies.psd)
This sample flow sheet models the Claus Process in the GPSA data book using Sulfur 2, Sulfur 3, Sulfur 4, Sulfur 5,
Sulfur 6, Sulfur 7 and Sulfur 8.

18
Ammonia Plant Modeling
DESIGN II FOR WINDOWS OFFERS ENGINEERS RIGOROUS SIMULATION AND OPTIMIZATION OF AMMONIA,
METHANOL AND HYDROGEN PLANTS

The Ammonia process (as simulated by the flowsheets in c:\Program Files (x86)\DesignII \samples\ammonia) consists of
four different flow sheet PSDs. These include: Front End, CO2 Removal, Ammonia Synthesis Section and the Ammonia
Refrigeration System. Each of these different sections is interlinked and together simulate a 1,500 ton per day ammonia
plant.
Synthesis Gas Preparation (Front-End) Process (frontend.psd)
Design II provides thermodynamic, equilibrium and component material balance calculations for all ammonia plant
technologies including processes which incorporate various combinations of feedstock preheating, steam-hydrocarbon
and auto-thermal reforming, waste heat steam generation, carbon-monoxide shifting, boiler water preheating, carbon
dioxide removal, methanation, synthesis gas cooling and condensate recovery.
CO2 Removal Process (co2remvl.psd)
Design II provides accurate assessment of carbon-dioxide removal systems modeling including thermodynamic, vapor
liquid equilibria and component balances for diverse arrangements of lean solvent pumping, high pressure carbon dioxide
absorption, lean/rich solvent heat exchange, rich solvent stripping, carbon dioxide cooling, condensate separation and
solvent heat rejection.
Ammonia Synthesis Process (nh3synth.psd)
Design II readily handles
ammonia synthesis
equipment calculations,
including predictions of
energy usage, reaction
equilibria, thermodynamics,
component balances and
vapor-liquid equilibrium for
complex plant arrangements
and technologies which
incorporate synthesis gas
multi stage compressors with
inter-cooling, synthesis gas
cooling using water and
refrigeration chilling,
refrigeration recovery
exchange, ammonia product
separation, process heating
and cooling, inter-cooled and
quench ammonia converters
with internal exchangers,
steam generation and boiler
water preheating, synthesis
gas purge and the synergies
of recycle of synthesis gas.
Ammonia Refrigeration Process (nh3refrg.psd)
Design II rigorously models energy usage, vapor-liquid equilibria, thermodynamics and component balances for multi-
stage refrigeration systems using inter-cooled compressors rejecting heat from process gas chillers via refrigerant
ammonia condensing, including ammonia product let-down, flash drum equilibria and loads, inerts purge gas rejection,
hot/cold ammonia product pumps and flash drum liquid and vapor flows.
Chemical Plant Modeling
DESIGN II for Windows can model many types of chemical processes besides the Ammonia processes.


19
Natural Gas Dehydration
DESIGN II OFFERS MANY
METHODS FOR MODELING
REMOVAL OF WATER FROM
NATURAL GAS
Typically, natural gas must be de-
hydrated before it is injected into a
pipeline. Formation of liquid water in
natural gas pipelines can lead to
corrosion and compressor problems.
Liquid water in natural gas can also
lead to formation of natural gas
hydrates, solid forms of natural gas, at
temp-eratures up to 70 F (21 C). The
most common method of removing
water from natural gas is the stripping
gas process utilizing Tri-ethylene
Glycol (TEG). For natural gas with
high BTEX content, the Drizo process
can also be modeled.
DESIGN II has a custom set of binary interaction parameters built in it for use with the Modified Peng-Robinson
thermodynamic k-value method. These binary interaction parameters (BIPs) modify the thermodynamic flash calculations
so that the TEG to hydrocarbon component interactions are modeled correctly.
DESIGN II can also predict the formation of natural gas hydrates for any stream in the flowsheet. And, DESIGN II can be
used to predict the natural gas hydrate inhibition effects of injection of ethylene glycol (EG), di-ethylene glycol (DEG), tri-
ethylene glycol (TEG) or methanol (MeOH).
Fuel Cell Modeling
DESIGN II FOR WINDOWS OFFERS ENGINEERS RIGOROUS SIMULATION OF FUEL CELLS
DESIGN II FOR WINDOWS provides fuel cell
modeling and sizing capabilities. This covers
multiple reactor types such as equilibrium
reactors and reformers, multiple heat
exchanger types, line pressure drop, valves,
compressors, pumps, etc. DESIGN II FOR
WINDOWS also rigorously accounts all heat
transfer and material transfer changes for the
entire flowsheet.
Production and translation of electrical
energy to heat is modeled via one or more
equilibrium reactors that redistribute all
atomic species among the specified
molecular species to achieve the most
thermodynamically stable molecular
compositions (via Gibbs Free Energy of
minimization). All the necessary heat and
reaction change will be calculated from the
pure component database properties and the
product temperature rise will be very close to that you would see in a purely electrical environment. The loss or gain of
heat can be accounted via heat exchangers (as duty -BTUs lost or gained) and placing them in right locations within the
flowsheet scheme that would balance the overall heat transfer.

20
Batch Distillation Column
DESIGN II FOR WINDOWS OFFERS ENGINEERS RIGOROUS BATCH DISTILLATION COLUMNS
The Batch Distillation Column unit module provides the following features:
Batch and Continuous Feeds
Total or Partial Condenser
Single or Multiple Product Collection Tanks for Each Product Draw
Rigorous Kinetic Modeling of
Reactions
User Specified Events or Change
Column Operations
Variable Feed and Product Draw
Rates
Total Reflux Conditions Specification
Cumulative or Instantaneous Product
Composition Specifications
Liquid Hold Up Profile Specification
Pressure Profile Specification
Conditional Logic Available to
Control Feeds, Products and Events
Converges Column to a large Variety
of Heat and Mass Balance
Specifications
Step Functions
Ramp Functions
Several Integration Methods Available
User Specified Integration Step Size
Flexible Reporting Features
Flexible Plotting Features
Because of the unsteady state nature of batch distillation, streams should be considered to be tanks which serve to hold
feeds or collect products.
In the example c:\Program Files (x86)\DesignII\samples\equipmnt\batch\batch1.psd, an initial charge of acetone,
methanol and water is to be batch distilled and the resulting overhead product collected at different stages into separate
tanks.
The first event models the initial boil-up period when the column operates at total reflux and without any product removal.
This is required since the initial composition on every stage is the same as that entered for the initial column charge.
Product draw off should not occur until steady state conditions have been reached within the column. When the column is
operating at total reflux only one heat and material balance specification is required, which in this case is the reboiler duty.
The initial charge composition is defined by stream number 1 in the General section and the total charge in the column by
the total holdup.
The second event starts immediately after the first event has terminated. Overhead product is collected instantly and
continues until the tank composition of the most volatile component, acetone, drops to 73 mole %. In this case the column
requires two heat and material balance specifications - reboiler duty and reflux ratio. The pressure and holdup information
entered for the first event continues throughout the second event.
In the third event, overhead product is collected into two separate tanks with the changeover occurring after 0.35 hours
from the start of this event. The latter of these tanks, represented by stream number 4, collects the highest concentration
of the second most volatile component, methanol. The heat and material balance specifications, pressure and holdup
information from the second event are repeated in this event. The event stops after 0.8 hours of operations.

21
Distillation Columns
DESIGN II FOR WINDOWS OFFERS ENGINEERS SEVERAL RIGOROUS DISTILLATION COLUMNS
The Distillation column module is used for rigorous simulation of absorbers, fractionators, strippers and other types of
single-column configurations. Most single-column units can be modeled, including demethanizers, stabilizers, sour water
strippers, amine contactors and regenerators, and azeotropic distillation towers. This module can be used for design,
modification, or optimization of rigorous distillation columns. Extensive thermodynamic options are available. With the use
of the proper option, the operation of existing units can be duplicated within several percent of actual plant data.
Column Types
The Distillation module offers a great deal of flexibility in the definition of column configurations. Eight major column types
are available distinguished by the presence or absence of condensers or reboilers: Absorber (no condenser and no
reboiler), Absorber with Reboiler, Presaturator (absorber with or without reboiler), Liquid-Liquid (an absorber with liquid
feed to the top and liquid feed to the bottom), Stripper (partial condenser but no reboiler), Stripper with Total Condenser,
Partial Fractionator (partial condenser and reboiler) and Total Fractionator (total condenser and reboiler). Additionally, an
essentially unlimited number of feeds, feed components, products, trays, and heaters/coolers are allowed.
Product Specification and Column Control
The flexibility of the Distillation module also includes the control of the fractionation process. Component purities,
recoveries, or ratios can be specified directly in top, bottom, or side products. Product rates can be set in mass, molar, or
volumetric units. Reboiler or condenser temperatures and duties can be specified as can reflux ratio or reflux flow rate.
Additional specifications can be created with Inline FORTRAN.
Calculation Techniques
Four methods are available for solving the rigorous tray-to-tray heat and material balances for your column: Regular,
Super, Super Plus and Sum Rates. The trays, partial condensers, and reboilers are modeled as equilibrium stages.
Special commands allow the convergence algorithms to be fine tuned to meet user specified tolerances.
Water K-values And Decant
The K-value option you choose for your simulation normally determines whether water (if present) is treated as miscible
or immiscible in the column. Free water is not decanted automatically. If you specify a water decant from the condenser or
any tray(s), the amount of free water formed at the temperature and pressure of the condenser or tray is calculated
automatically. You may also specify the solubility of water in the reflux returning to the column. The default solubility will
be based on the water-in-kerosene chart from the API Technical Data Book. You can enter an estimate for the fraction of
free water in the liquid on the trays. You can also check for free water on trays where no decants have been established.
Step-by-Step Procedure
Specifying a rigorous Distillation column with DESIGN II is simple when following. The procedure is summarized below:
Define the column type by selecting the combination of condenser and/or reboiler.
Add required column configuration commands.
Determine the number of heat and material balance specifications required based on the column type and select
the one(s) for your simulation.
Add any side draws, heaters/coolers, intercoolers, and water decant commands.
Add optional commands as needed for additional calculations such as reboiler or condenser curves CO2 freeze
prediction, extra plots, column sizing, internal stream reports and others.
Several Distillation Examples
Distil1.psd - Absorber MEA Treating
Distil2.psd - Lean Oil Absorber with Presaturator
Distil3.psd - Cryogenic Demethanizer with Side Heater
Distil4.psd - Inline Fortran to meet Reid Vapor pressure specification
Distil5.psd - Liquid-Liquid Extraction
Distil6.psd - Sour Water Stripper
Distil7.psd - Partial Condenser with Three Side Draw Products
Distil8.psd - Partial Condenser: Sour Water Stripper with CO2
Distil9.psd - Total Condenser: Split Propylene from Propane
Packed Column.psd - Sour Water Stripper using packing instead of trays


22
Heat Exchangers
DESIGN II FOR WINDOWS OFFERS ENGINEERS RIGOROUS SIMULATION OF MANY TYPES OF HEAT EXCHANGERS
Shell and Tube Heat Exchanger
The Shell and Tube heat exchanger module simulates two
process streams exchanging heat with each other. This usually
involves a heat recycle situation with one of the streams coming
from downstream in the process. DESIGN II has built-in rating
calculations for shell and tube heat exchangers. Any single
phase counter-current exchanger, and any type E or type F shell
two-phase exchanger, can be rated in the flowsheet. The rating
calculations automatically handle boiling or condensation
occurring in either the shell-side or the tube-side of a heat
exchanger. No special commands are required to indicate a two-
phase stream.
Plate-Fin Heat Exchangers
The Plate-Fin Exchanger module can be used to simulate
multiple stream exchangers. This type of exchangers allows
multiple hot and cold streams to exchange heat with a maximum
heat transfer surface area. The module calculates the heat and
material balance from known input stream information and the
specifications to be met. DESIGN II has built-in rating
calculations for Brazed Aluminum Plate-Fin heat exchangers.
The rating calculations automatically handle boiling or
condensation occurring in either the hot-side or the cold-side
streams of the heat exchanger.
Multiple Pass Shell and Tube Heat Exchangers
The LNG Exchanger module is used to specify heating or cooling
of up to twenty tube side streams and twenty shell side streams. Each tube-side stream can have either the same outlet
specification or entirely different specifications. Tube side outlet streams may be recycled back and mixed with a single
shell side feed stream.
Air-Cooled Heat Exchanger
The air-cooled heat exchanger module allows you to rigorously model and rate air coolers or air condensers. You can
specify the process side and/or the air side of the air cooler. The air side of the air cooler can be modeled as a utility
stream (automatically calculated) or it can be a process stream (specified conditions). You can specify all the physical
characteristics of the air cooler (tubes, fins, fans, power, passes, etc) or use the default values when rating is calculated.
Refrigerant Heat Exchanger
Refrigerant exchangers are similar to counter-current heat exchangers with the refrigerant entering at the bubble point
and leaving at the dew point. The temperature or pressure of the refrigerant is calculated along with the flow rate required
and all corresponding properties. The properties of the process stream out are calculated. The duty, area, and corrected
LMTD are calculated and reported in the equipment summary.
Water-Cooled Heat Exchanger
Water-cooled exchangers are handled as single-stream exchangers. The water temperatures in and out are specified for
the heat exchanger, rather than specifying the stream temperature and pressure. The amount of water is calculated as
part of the heat exchanger output, in lieu of specifying it on a flow command or reporting it in the final stream summaries.
Therefore, the water stream in and out of the water-cooled exchanger does not need to be included as part of the
flowsheet. Also, water does not have to be added as a component in the flowsheet simulation. The amount of water
required to condense the process stream is calculated along with the duty, area, corrected LMTD, and outlet stream
properties for the process stream.
Single Stream Temperature Change
In many process simulations, only one side of the exchanger is of interest. For example, you may be interested only in
process-stream temperature adjustment, instead of the amount of utility required for the heat exchange. Usually,
exchangers that use a heating or cooling substance to adjust the temperature of a process stream can be modeled by
specifying only one stream in and one stream out. This greatly reduces the complexity of the simulation. In this case, the
duty and/or temperature out of the exchanger are calculated along with all the properties of the outlet stream.

23
Available Unit Modules
DESIGN II FOR WINDOWS OFFERS ENGINEERS MANY UNIT MODULES TYPES FOR SPECIFIC USES
Column Calculations
Amine Column rate based model of Absorber and Regenerator used with the Mixed Amine Thermodynamics
Batch Distillation performs unsteady state heat and material balance calculations for batch processes
Component Splitter - sends a specified fraction of each component in the feed to the first output stream
Distillation Column - Absorbers, Fractionators, Strippers and other types of single-column configurations
Packed Column Absorbers, Fractionators, Strippers and other columns using structured or unstructured packing
Refine Column preflash towers, atmospheric columns, vacuum columns, FCC main fractionators and quench columns
Shortcut Fractionator simulates a simple distillation column with one feed and a top and bottom product
Stream Manipulator - modify stream component flowrates by a single factor for all components or by an individual factor
Heat Exchange
Air-Cooled Exchanger - Rejects heat from a fluid directly to ambient air, can be sized as air cooler or air condenser
Double Pipe Exchanger A single pipe inside another pipe; 1 or 2 phase
Fired Heater - calculate the fuel consumption and heater duty when a process stream is heated to a given temperature
Heat Exchanger single stream or two stream shell and tube; 1 or 2 phases can be rated; water, refrigerant or air cooled
LNG Exchanger - heating or cooling of up to twenty tube side and shell side streams with different specifications
Multiple Flashes - isothermal, adiabatic, isentropic, molar or mass liquid fraction, bubble or dew point or water dew point
Plate-Fin Exchanger - multiple hot and cold streams have heat exchange with maximum surface area with/without rating
Pressure Change
Compressor - compresses a vapor to a specified outlet pressure or to a pressure limited by a specified work available
Depressuring - calculates pressure buildup in a closed vessel until the pressure reaches the value specified for the set
pressure of the relief valve; the conditions during the blow down period after the valve opens are shown
Expander - isentropic expansion of liquid, vapor, or two-phase streams to a specified outlet pressure
Expander Compressor - uses the calculated work by the expander as the maximum available work for the compressor
Expander Pump - uses the calculated work by the expander as the maximum available work for the pump
Flash can specify pressure, temperature, duty, bubble point, dew point and separate to vapor, liquid 1 and liquid 2
phase
Line Pressure Drop - calculate pressure drops due to friction and elevation change (if any) in transmission lines or plant
piping of specified length and diameter; also calculates back pressure, diameter case studies, and liquid holdup
Multiple Flashes isothermal, adiabatic, isentropic, molar or mass liquid fraction, bubble or dew point or water dew point
Polytropic Compressor - single stage of a centrifugal compressor/pump based on manufacturer's performance curves
Pump - pumps a liquid to a specified outlet pressure or to a pressure limited by a specified work available
Valve - adiabatic (constant enthalpy) pressure reduction of a stream which can be vapor, liquid, two-phase or three-phase
Reactors
Continuous Stirred Tank Reactor - steady state flow of species and uniform concentrations of species and temperature
Equilibrium Reactor - calculate gas-phase reactions of multi-component systems on adiabatic or isothermal basis
Hydrotreater - hydrogenation of olefinic and aromatic crudes; desulfurization and denitrogenation of high-sulfur crude
Plug Flow Reactor - single-phase reactions using reactor dimensions, stoichiometric coefficients, and rate expressions
Reactor calculate stoichiometric distribution of components for adiabatic or isothermal conditions with six subtypes
Stream Manipulator - modify stream component flowrates by a single factor for all components or by an individual factor
Stream Operations
Component Splitter - sends a specified fraction of each component in the feed to the first output stream
Divider - divides a stream into two to six other streams of the same composition, temperature, and pressure
Flash separate vapor and liquid phase, can size to a vertical or horizontal vapor-liquid or vapor-liquid-liquid separator
Line Pressure Drop - Calculate pressure drops due to friction and elevation change (if any)
Mass Balance set the flow rate of a recycle loop and/or calculate the makeup flow rates for a recycle loop
Mixer - mix multiple input streams adiabatically to the lowest inlet stream pressure or the specified pressure out
Multiple Flashes - isothermal, adiabatic, isentropic, molar or mass liquid fraction, bubble or dew point or water dew point
Multiple Phase Flash - rigorously separate multiple phase streams
Phase Envelope - calculate dew and bubble points for specified pressures and plot the phase envelope (any system)
Phase Map - calculate dew points, bubble points and constant liquid fraction lines for hydrocarbon systems
Stream Manipulator - modify stream component flow rates by a single factor for all components or by an individual factor

24
Available Unit Modules (continued)
DESIGN II FOR WINDOWS OFFERS ENGINEERS MANY UNIT MODULES TYPES FOR SPECIFIC USES
Stream Operations (continued)
Valve - adiabatic (constant enthalpy) pressure reduction of a stream which can be vapor, liquid, or two-phase
Controls and Metering
Controller measure stream information and change it via unit module calculation perturbation to a given target
Flow Meter - calculate the size of the orifice, flow rate of the stream, or the pressure drop across the orifice
Tank
Vertical, Horizontal, Spherical constant volume tank for material accumulation and sendoff at specific times
Other
Add Module you can write custom inline Fortran code for calculating just about any specialized process
Multiple Phase Flash
DESIGN II SUPPORTS MANY TYPES OF THREE PHASE FLASHES
DESIGN II has several types of flashes:
Isothermal (constant temperature and constant
pressure)
Adiabatic (constant enthalpy and constant pressure or
temperature)
Isentropic (constant entropy and constant pressure or
temperature)
Bubble point (all liquid with an incipient vapor phase
and constant temperature or pressure)
Dew Point (all vapor with an incipient liquid phase and
constant temperature or pressure)
Vapor Fraction (constant vapor fraction and constant
pressure or temperature)
Volumetric (constant volume and constant enthalpy)
DESIGN II has a full three phase (Vapor, Liquid 1 and
Liquid 2) flash built into it for all thermodynamic calculations. DESIGN II will determine the appropriate component
distribution between the vapor, liquid 1 (hydrocarbon liquid) and liquid 2 (aqueous liquid) phases using K-values from the
current K-value methods for the vapor liquid 1 flash and the API Sour method for the vapor - liquid 2 phase. Note that
you also turn off the aqueous phase (vapor - liquid 2) flash. If so, the component distribution will only have non-soluble
water in the aqueous phase.
If water is miscible, then the flash will only distribute to two phases (vapor and liquid 1). If the flash detects that there is
non-soluble water, a warning message will be printed. If water is immiscible, then the flash will distribute components to
the vapor, liquid 1 and liquid 2 phases. Water miscibility is generally controlled by current K-value method but this can be
over-ridden by the user. With many of the K-value methods in DESIGN II, water is designated as the immiscible
component. By default, when water is immiscible, any non-soluble water will form an aqueous liquid phase. The user still
has the option of specifying water miscibility in the general section or for any equipment / feed stream.
The three phase flash is split into two stages. The first stage calculates a preliminary component distribution to the three
phases. The second stage uses the first stage results as a starting point and calculates a rigorous component distribution
to all the three phases. If water is immiscible, the three phase flash also will move one other immiscible component from
the liquid 1 phase to the liquid 2 phase if present in sufficient quantity. The other immiscible component list consists of
EG (ethylene glycol), DEG (di-ethylene glycol), TEG (tri-ethylene glycol), PEG (propylene glycol) and MeOH (methanol).
Note that solid components only participate in the flash in the enthalpy and entropy calculations. Components will not be
moved between the vapor / liquid phases and solids. However, you can move components from the solid phase to the
vapor or liquid phases using a Stoichiometric Reactor or the Equilibrium Reactor.

25
Thermodynamic Methods
DESIGN II OFFERS A RICH SELECTION OF THERMODYNAMIC AND TRANSPORT METHODS
DESIGN II has a comprehensive
set of K-value, Enthalpy, Density,
Transport (Viscosity and Thermal
Conductivity) Properties, and
Surface Tension of mixture
correlations. DESIGN has a built
in pure component database of
over 1,200 components and new
components can be easily added.
These correlations can be used to
model processes ranging from gas
processing to refinery operations to
petrochemicals and specialty
chemicals. General
recommendations as to the
applicability of particular
correlations are given in the online
help and user manuals.
Any K-value, enthalpy or density
commands entered in the general
section apply to all calculations
within the simulation. You can also enter K-value, enthalpy, density or transport commands for any specific equipment
module or any specific feed stream. The two stream heat exchanger also allows separate specification of the
thermodynamic methods for the shell side and the tube side. Water miscibility can also be controlled for any unit module
or feed stream.
29 Hydrocarbon K-value, Enthalpy and Entropy Methods
These include API Soave, BWR (Benedict-Webb-Rubin), BWRS (Benedict-Webb-Rubin-Starling), Esso (Maxwell-
Bonnell), GERG 2008, Grayson-Johnson (API), Kent-Eisenberg (Mixed Amines), LKP (Lee-Kesler-Ploecker), NIST
RefProp, Peng-Robinson, Peng-Robinson-Stryjek, Predictive Peng-Robinson, RK (Redlich-Kwong), Soave (Soave-
Redlich-Kwong), Steam Tables, SKD (Soave-Kabadi-Danner) and Tabular K-Values.
24 Chemical K-value, Enthalpy and Entropy Methods
These include DMPEG, Sour Water API, Edwards, Edwards Sour, Henrys Gas Law, Ideal Vapor, MEA or DEA, NRTL
(Renon), Solids, UNIFAC, UNIQUAC, Vapor Pressure and Wilson.
18 Density Methods
You can specify separate density methods for the vapor phase and the liquid hydrocarbon phase. The density methods
include AGA, API Soave, BWR, BWRS, Corresponding States, COSTALD, GERG 2008, Ideal, Lee-Kesler-Ploeker, Mixed
Amines, Modified Peng-Robinson, NIST RefProp, Peng-Robinson, Redlich-Kwong, Soave, Soave-Kabadi-Danner,
Soave-Redlich-Kwong and Yen-Woods (Std).
9 Viscosity Methods
You can specify separate viscosity methods for the vapor phase and the liquid hydrocarbon phase. If you do not choose
a viscosity method then DESIGN II will automatically choose the appropriate method for you. The viscosity methods
include API, Dean and Stiel, LN Average, NBS81, Twu, Mod API, Mixed Amines and NIST RefProp.
9 Thermal Conductivity Methods
You can specify separate thermal conductivity methods for the vapor phase and the liquid hydrocarbon phase. If you do
not choose a thermal conductivity method then DESIGN II will automatically choose the appropriate method for you. The
thermal conductivity methods include API, C. C. Li, LN Average, NBS81, Mixed Amines, NIST RefProp, TEMA 68 and 78.
4 Surface Tension Methods
The surface tension methods include API, Molar Average, Mixed Amines and NIST RefProp.

26
Feed Stream Specifications
DESIGN II OFFERS SEVERAL WAYS TO SPECIFY A FEED STREAM OR A RECYCLE STREAM
You can specify a feed or recycle stream via one of the following methods:
Do not initialize the stream (this is the default method)
Use the specified Temperature and Pressure
Use the specified Pressure and Vapor Fraction (Temperature is a guess)
Use the specified Temperature and Vapor Fraction (Pressure is a guess)
Use results from a Reference stream for this streams specifications
The stream flow rate can be specified via one of the following methods:
Composition (fraction, percent, ppm) with a total molar, mass, vapor, liquid or actual volumetric flow rate
Component molar, mass, vapor or liquid volumetric flow rate
Crude Oil TBP curve with separate dry liquid volumetric flow rate and water flow rate specifications
ASTM D-86 or D-1160 (760 or 10 mm) curve with dry liquid volumetric flow rate and water flow rate specifications
Pseudo-Component volumetric percents with dry liquid volumetric flow rate and water flow rate specifications
Crude Oil Library (one of 38 different world crude: Abu Dhabi Murban, Rocky Mountain Sweet, Saudi Light, etc)
ASTM D-2887 TBP curve with separate dry liquid volumetric flow rate and water flow rate specifications
Dimensional Units
DESIGN II has full support for a comprehensive set of dimensional units for each specification such as temperature (4),
pressure (26), molar flow rate (3), mass flow rate (4), vapor flow rate (5), liquid flow rate (5), etc.
Thermodynamic Methods
DESIGN II allows the user to flash any feed stream in any thermodynamic method other than the default thermodynamic
method. If the connected unit module uses a different method then DESIGN II will automatically re-flash the stream.


27
Unit Module Specifications
DESIGN II OFFERS SPECIFIC DIALOGS FOR EACH TYPE OF UNIT MODULE
All of the unit modules in DESIGN
II for Windows feature a custom
designed tabbed dialog for that unit
module. Each of the tabbed
sheets allows complete
specification of the unit module for
all required and optional
specifications.
In addition, there is a sheet for
adding Inline Fortran commands to
be processed before, during or
after the calculation of the unit
module. And there is a sheet for
specifying specific thermodynamic
and/or transport property methods
if desired.
When you click OK or Apply on the
dialog, your specifications will be
analyzed and validated. If any
problems are noted then you will
be prompted to fix each until all
issues have been cleared.
Depressuring Unit Module
DESIGN II OFFERS CALCULATION OF A RELIEF VALVE BLOW DOWN EVENT
Depressuring systems are used extensively in
process plants for protecting vessels from over
pressure. Over pressuring has many causes,
such as external fire, exothermic reactions,
loss of power, inadequate cooling, and blocked
lines. Depressuring systems are needed to
prevent equipment from rupturing and to
provide safety for plant personnel. API RP-520
recommends that vessel pressure should be
reduced to 100 PSIA or 50% of design
pressure, whichever is lower, in fifteen minutes.
The depressuring analysis is based on a vessel
which is exposed to an external fire. The
program calculates the pressure buildup in the
closed vessel until the pressure reaches the
set pressure of the valve. The conditions
during the blow down period after the opening
of the depressuring valve are also calculated.
The blow down period is divided into several
time intervals with important variables reported for each interval.
One inlet and one or two outlet streams will be attached to the unit module. The second stream, if present, will print
stream properties for the vent gas stream at the time of maximum flowrate. The temperature, pressure and composition
of the inlet stream are assumed to be the operating conditions of the vessel. A flash is performed to determine the vapor
and liquid compositions and initial flow rates. The vessel diameter, the vessel orientation, vessel length, and the liquid
height can also be specified for the analysis to give more meaningful results.

28
Inline Fortran
DESIGN II FOR WINDOWS OFFERS A BUILT-IN PROGRAMMING TOOL FOR YOUR CUSTOM CALCULATIONS
The process simulator also has a built-in Fortran interpreter for adding custom calculations to any or all unit modules so
you can perform just about any calculation you need. Inline Fortran enables integration of Fortran commands directly into
a DESIGN II simulation file. Custom tailored process simulations that meet exact requirements can be developed by:
Modifying the existing DESIGN II equipment module calculations (using the GET/SET commands)
Developing subroutines, subroutine libraries and creating your own equipment modules
Accessing DESIGN II internal subroutines and functions.

DESIGN II makes these operations easy to implement by using simple keyword phrases. These statements can be used
to perform operations on practically any parameter or values associated with a flow sheet simulation. In particular,
equipment and stream parameters can be obtained from the internal storage areas of DESIGN II and stored back into
these areas with Fortran statements. Almost any legal Fortran operation can be performed with these parameters,
including algebraic statements, loops, conditional jumps, etc. All of these statements can be placed directly in the
equipment module. The DESIGN II simulation program offers a wealth of equipment module and stream property
calculations, equipment sizing and rating, and full flow sheeting capabilities, such as handling recycle convergence,
optimization, and case studies. With Inline Fortran, you have the power to extend calculations even further. You can
define your own proprietary reaction calculations, create your own Distillation product composition specifications, and
define additional stream property calculations or special reports and much more.

All Fortran statements are compiled during run time by the DESIGN II internal compiler, immediately after the DESIGN II
input data has been processed. Then the code is linked to the DESIGN II program to form an executable "module".
Custom Stream Properties
DESIGN II OFFERS MANY SPECIAL CALCULATIONS FOR FLOWSHEET STREAMS
DESIGN II has several automatic calculations for all streams in a flowsheet:
Composition and Flow Rate, Enthalpy, Entropy, Density and Heat Capacity by phase on molar basis
Composition and Flow Rate, Enthalpy, Entropy, Density and Heat Capacity by phase on mass basis
Volumetric Flow Rate at stream temperature and pressure and at standard conditions
Viscosity, Thermal Conductivity and Surface Tension by phase
Mixture Critical Pressure and Mixture Critical Temperature
Mixture Dew Point, Mixture Bubble Point and Mixture Water Dew Point temperatures at the stream pressure
Mixture Vapor Pressure at the stream temperature
CO2 Solid formation, Wobbe Index, Methane Number, Gross and Net Heating Value
DESIGN II has several optional calculations for any or all streams in a flowsheet:
Phase Map and/or Phase Envelope (temperature pressure diagram)
Hydrate Formation Temperature (at stream pressure) and/or Hydrate Formation Pressure (at stream temperature)
with optional curves
Pressure Enthalpy diagram with Temperature isotherms
Reid Vapor Pressure
D-86 Petroleum for both Liquid (water free basis) and Vapor phases
Bulk Properties for the Inlet Streams to Heat Exchangers and Internal streams of the Distillation Columns
Vapor and Liquid Partial Numerical Derivatives (dP/DT)v and (dP/dV)t
Latent Heat of Vaporization for the Mixture

29
ChemTran
DESIGN II FOR WINDOWS OFFERS ENGINEERS CUSTOM PROPERTY GENERATION
The CHEMTRAN

program, which furnishes properties required by process simulators, is integrated into DESIGN II FOR
WINDOWS. CHEMTRAN is the best tool available for determining properties in non-ideal chemical or hydrocarbon systems
where unusual properties must be taken into account. CHEMTRAN

increases your process engineering productivity by
automating the time consuming task of predicting and correlating the thermophysical properties of pure components and
component mixtures.
Pure Components
CHEMTRAN contains one of the largest commercially available pure component databases. Included are complete
thermophysical properties for 1,200+ pure components. The molecular structure input simplifies the application of group
contribution techniques for physical property estimation.
Component Mixtures
ChemTran supports almost any data regression methodology. Its regression methods include binary, ternary, quaternary,
etc. Regression methods estimate the thermophysical properties of the most common varieties of equilibrium data.
These methods handle V-L-E, L-L-E, V-L-L-E, and V-L-L-L-E data.
Usability
ChemTran features easily understood dialog or keyword data inputs and easy-to-read, well-formatted output. Data may
be regressed using eleven popular equations; thus your needs are always properly met. Documentation of each
capability is organized under easy-to-locate headings. Guidance for using each specific feature is complete and easily
understood.
Input Data:
Normal boiling point
Dipole Moment
Association Parameter
Parachore
Molecular weight
Acentric factor
Critical pressure
Critical temperature
Critical volume
Solubility parameter
Molecular structure
Mixture Data Methods:
Regressing experimental data
Binary interaction parameters
UNIFAC group contribution method
Regular solution theory

Estimation:
Normal boiling point
Critical pressure
Solubility parameter
Ideal gas heat capacity
Vapor pressure
Thermal conductivity
Critical temperature
Acentric factor
Surface tension
Viscosity
Enthalpy
Regression:
Ideal gas heat capacity
Vapor pressure
Density
Thermal conductivity
K-values
Latent heat
Surface tension
Viscosity
Vapor and Liquid Enthalpy
Correlations:
Peng-Robinson
Modified Peng-Robinson
Soave
API Soave
Renon (NRTL)
Wilson
Uniquac
Edwards (Electrolytes)
BWR/BWRS
Soave Kabadi Danner
Vapor Phase Association
Sample ChemTran Files
CHEMTRAN includes 25 sample input files for either defining new components or defining new mixture properties in
c:\Program Files (x86)\DesignII\samples\chemtran.
Dialog Input
CHEMTRAN data can be specified and embedded in a DESIGN II flow sheet via the dialogs in the graphical user interface.
The dialogs allow full specification of new components and/or mixture properties.

30
Link2WinSim
THE DESIGN II SIMULATOR KERNEL CAN BE EMBEDDED IN YOUR COMPANYS IN-HOUSE VISUAL BASIC OR
VISUAL C++ SOFTWARE FOR FLASHES AND PROPERTY CALCULATIONS
Microsoft Visual Basic Interface
DESIGN II has a complete interface for any Visual Basic program (or VB compatible environment) to directly call the flash
methods in the simulator kernel. The Design II DLL is a dynamic link library that contains 100% of the functionality of
Design II for Windows in a form that can be used directly by other programs. All of the chemical compounds, property
calculations and equipment simulations are included in the DLL, but only those parts needed most often flashes and
property calculations are exposed for each client. This permits WinSim to charge much less for Design II DLL than for
Design II for Windows. Clients can provide Design II DLLs as a part of their sales force automation packages for
hundreds of laptops at affordable prices.
Visual Basic is the glue
Microsofts Visual Basic (VB) is a programming methodology that lets programmers quickly create easy-to-use programs
that have a Windows look-and-feel. A great advantage of VB is that it can call DLLs. VB is the glue that holds
together the manufacturers classic detailed design programs, many written in Fortran, with needed parts of WinSims
world-class calculation engine to give a better, more accurate and much quicker quotation machine.
Targeted manufacturers and suppliers
The Design II DLL is targeted at those companies with internal, proprietary programs for detailed design of piping,
equipment or suppliers for process plants, but need a key element of Design II such as its extensive thermodynamic
property methods and database. Examples include pump, compressor and heat exchanger manufacturers and
consumable suppliers such as those that sell mixed amines for gas treating.
Imagine How WinSims Powerful Calculation Engine Can Be Combined With Yours
Sales force automation is but one of
the many ways the Design II DLL can
be used. For example, the piping
and detailed equipment design
departments of E & C companies can
incorporate rigorous thermodynamic
and fluid flow methods from Design II
into their design programs. Anytime
some of the powers of a world-class
simulation engine can be combined
with your programs using VB, Lab-
View or other glue that can call
DLLs, the possibilities can only be
imagined and only by you.
Microsoft Visual C++ Interface
In addition to the Visual Basic
interface, DESIGN II for Windows
also includes an interface for
embedding the DESIGN II DLL in
Visual C++ programs. A sample
Visual C++ application calling the
DESIGN II simulator kernel is also
included in the standard software
distribution.
Microsoft Excel VBA Interface
In addition to the Visual Basic interface, the DESIGN II DLL can be called from any Microsoft Excel spreadsheet. A
sample Microsoft Excel spreadsheet for calling the DESIGN II simulator kernel is also included in the standard software
distribution, dii2vbas.xls. Several sample calculations are present in the spreadsheet.

31
Link2WinSim (continued)
Sample VB Application with source code
A sample Visual Basic application using the DESIGN II DLL has been included in the software distribution in the BIN
subdirectory. The name of the sample application is D2PROPS. Full source code is included in the D2PROPS.FRM file.
The Visual Basic project files of D2PROPS.VBP and D2PROPS.VBW are also included.

The following figure is a screen shot of D2PROPS after the given mixture has had its phase split and properties
calculated to 20 F and 980 psia.





DESIGN II for Windows - Advanced Features:
Flowsheet Optimization - Flowsheet Optimization is a powerful feature in DESIGN II to simplify a cumbersome and time-
consuming process engineering task. Simple keywords are used to identify the design variables that can be varied to
maximize or minimize the objective function (subject to the specified constraints of the process).
Case Study - The Case Study section allows an engineer to run a number of similar simulation cases at once in order to
assess the sensitivity of a flowsheet to changes in variables, or to produce a number of design cases. Case study allows
you to present your results in data tables and plots for efficient analysis. This will reduce both the engineering and
computer time required to evaluate different design options. Up to 25 cases may be specified in one Case Study. All
parameter changes will be implemented, and the entire flowsheet will be recalculated, with each new parameter setting.
Process Line Sizing - Single and two-phase lines can be sized to meet your specification of pressure drop, velocity,
sonic velocity fraction or nominal diameter.

32
Online Help and Manuals
DESIGN II INCLUDES FULL ONLINE HELP AND MANUALS IN BOTH PDF AND PAPER
DESIGN II for Windows includes a help button on each dialog that will bring up the online help. The online help has both
information about the dialogs and hyperlinks into the more detailed online help. The help is also distributed via user
manuals which are available for perusing from the Help pull down menu via Adobe Acrobat.

DESIGN II for Windows also includes PDF files of all the user manuals in the software distribution. We also distribute
perfect bound copies of the manuals to all new customers. You can also get the perfect bound copies of the newest
manuals from www.lulu.com (Lulu is a print on demand publisher).


























33
DESIGN II History
DESIGN II FOR WINDOWS IS CONSTANTLY REFINED AND IMPROVED WITH YEARLY UPDATES AND MAINTENANCE
RELEASES AS NEEDED (USUALLY MONTHLY)
A few high points from our online release notes file (c:\Program Files (x86)\DesignII\relnotes.chm)
12.00: Aug 2013 Added new Dimensional Units System and Pressure Entropy / Pressure Density tables and charts
11.00: Sep 2011 Added Dynamic Simulation, Tank unit module and DMPEG thermodynamic method, GUI toolbox
10.20: Aug 2010 Added Exchange of data with Spreadsheet and additional Packed Column unit modules
10.12: Jan 2010 Added creation of custom symbols and symbol libraries, Drag and drop of symbols to flowsheet
10.10: Nov 2009 Added DXF file export, multiple view results windows, Storage of multiple simulation results
10.00: Nov 2008 Merged the line arrows into streams, Added GERG 2004 and REFPROP thermodynamic methods,
Added Packed Column unit module, increased number of pure components in database to 1126
9.52: Feb 2008 Added support for the Claus Process including Sulfur 2, 3, 4, 5, 6, 7 and 8
9.50: Nov 2007 Converted the initial isothermal flash from two phase plus free water to three phase, ChemTran dialogs
9.41: Feb 2007 Added calculation of hydrate inhibition using Ethylene Glycol
9.40: Dec 2006 Added drawing elements to the graphical user interface and Predictive Peng-Robinson thermo method
9.33: Jun 2006 Added ASTM D-2887 crude feed data entry and Piperazine to the Mixed Amine thermodynamic method
9.30: Mar 2006 Split the Density method choices into Vapor and Liquid and added Compressor-Expander unit module
9.20: May 2005 Added Tool tips to user interface and the BTEX components to the Mixed Amine thermo method
9.13: Jul 2004 Added API (-200 F liquid) and ASME (32 F liquid) options to the enthalpy base calculations
9.10: Apr 2004 Added Mass Balance unit module and enhanced many unit module dialogs in the user interface
9.00: Aug 2003 Converted the user interface from 16 bit to 32 bit, added undo and redo, added a three phase flash
8.51: Oct 2002 Added phase map to the Visual Basic / C++ interface, add new flow rate specifications for streams
8.50: Sep 2002 Updated Depressurizer unit module calculation to latest API 520 document, new unit module dialogs
8.45: May 2002 Added embedding of ChemTran input files to the DESIGN II input files
8.40: Jan 2002 Added multiple sheet capability to the graphical user interface, converted kernel to double precision
8.31: Dec 2000 Increased the maximum number of components from 150 to 1000, increased the maximum number
of petroleum fractions from 75 to 600, increased maximum crude feed streams to 100
8.30: Nov 2000 Added new dialogs, add new liquid enthalpy method, add support for DIPPR equations to ChemTran
8.25: Feb 2000 Converted the results data Excel transfer program to an external program for greater speed
8.21: Oct 1999 Added several new functions to the Visual Basic interface to the simulator kernel
8.20: Sep 1999 Added new Air Cooler unit module, new user interface dialogs
8.19: May 1999 Added a new Visual Basic interface to the simulator kernel
8.18: Mar 1999 Converted the simulator kernel to a Win32 DLL for future external interfaces
8.11: Dec 1998 Added several new items to be displayed in the stream data box
8.10: Nov 1998 Added Plate Fix Heat Exchanger unit module with two phase rating
8.03: May 1998 Added the capability of reading a DESIGN II input file into the user interface
8.00: Feb 1998 Merged the Gasplant Plus program into DESIGN II to create the Mixed Amine thermodynamic
Methods and the Mixed Amine columns (absorber and regenerator)
7.50: Jul 1997 Added a stream data box to the graphical user interface, updated Reid Vapor Pressure calculation
7.41: Aug 1996 New COSTALD density method, added stream names
7.40: May 1996 Added flow sheet linking capability to support large simulations, head curves for polytropic compressor
7.32: Oct 1995 Expanded maximum flow sheet components from 75 to 150
7.30: Jun 1995 Added the data results transfer to Excel, converted the simulator kernel to a Windows program, can
have up to 9,999 streams and/or unit modules in a single simulation (up from 999)
7.10: Oct 1994 Converted the simulator kernel to virtual memory allocation for unlimited size flow sheets
7.00: Jan 1994 Merged DESIGN II for Windows, DESIGN II and ChemTran into a single product, added online help,
added gauge pressure units
6.0: 1991 Added AGA Density method, SKD equation of state, Batch Distillation unit module, Windows user interface
5.0: 1989 Case Study, Flow Meter unit module, Electrolyte thermodynamics, Modified Peng-Robinson equation of state
4.0: 1988 Additional Inline Fortran commands
3.0: 1986 Added Inline Fortran, DesignMaster, MixMaster, DESIGN II/PC
2.0: 1985 Crude Oil library, Phase Map unit module, Depressuring unit module, Equilibrium Reactor unit module
1.0: 1984 REFINE column and crude feeds program were merged into DESIGN 2000 to create DESIGN II
1975 DISTILL column program was merged into DESIGN to create DESIGN 2000
1969 DESIGN program first offered on the University Computing Company (UCC) time sharing services

34
100s of Sample Flowsheets
DESIGN II FOR WINDOWS INCLUDES MORE THAN 300 FULLY WORKING FLOWSHEETS
c:\Program Files (x86)\DesignII\samples\ 19 DESIGN II flow sheets and 11 DESIGN II input files
c:\Program Files (x86)\DesignII\samples\ActivatedMDEA 4 DESIGN II flowsheets
c:\Program Files (x86)\DesignII\samples\ammonia 12 DESIGN II flow sheets
c:\Program Files (x86)\DesignII\samples\casestdy 4 DESIGN II flow sheets
c:\Program Files (x86)\DesignII\samples\CEP_Oct2005 6 DESIGN II flow sheets
c:\Program Files (x86)\DesignII\samples\chemtran 5 DESIGN II flow sheets and 26 ChemTran input files
c:\Program Files (x86)\DesignII\samples\dynamic 3 DESIGN II flow sheets
c:\Program Files (x86)\DesignII\samples\equipmnt 150 DESIGN II flow sheets in 39 sub-directories
c:\Program Files (x86)\DesignII\samples\flare 2 DESIGN II flow sheets
c:\Program Files (x86)\DesignII\samples\fortran 9 DESIGN II flow sheets
c:\Program Files (x86)\DesignII\samples\fuelcell 3 DESIGN II flow sheets
c:\Program Files (x86)\DesignII\samples\gasproc 22 DESIGN II flow sheets and 5 ChemTran input files
c:\Program Files (x86)\DesignII\samples\general 33 DESIGN II flow sheets and 6 ChemTran input files
c:\Program Files (x86)\DesignII\samples\gerg2008 3 DESIGN II flow sheets
c:\Program Files (x86)\DesignII\samples\linked 4 DESIGN II flow sheets
c:\Program Files (x86)\DesignII\samples\lng 3 DESIGN II flow sheets
c:\Program Files (x86)\DesignII\samples\lpg 2 DESIGN II flow sheets
c:\Program Files (x86)\DesignII\samples\optimize 2 DESIGN II flow sheets
c:\Program Files (x86)\DesignII\samples\pipeline 8 DESIGN II flow sheets
c:\Program Files (x86)\DesignII\samples\power 1 DESIGN II flow sheet
c:\Program Files (x86)\DesignII\samples\reverse_calc 2 DESIGN II flow sheets
c:\Program Files (x86)\DesignII\samples\sizeline 9 DESIGN II flow sheets
c:\Program Files (x86)\DesignII\samples\sulfur 4 DESIGN II flow sheets
c:\Program Files (x86)\DesignII\samples\thermodynamics 38 DESIGN II flow sheets in 36 sub-directories
Features and Specifications
Flowsheet Features
Steady State Simulation Analysis
Automatic Data Export to Microsoft

Excel
All User Manuals in Windows Help Files
and in Adobe PDF files
Compatible with Windows 8, 7, Vista, XP
Diagram User Interface with Multiple
Rename-able Sheets (up to 1024)
Automatic Recycle Analysis of Unit Module
Calculation Order and Recycle Streams
Advanced Recycle Convergence
(Wegstein, Simultaneous Convergence
or Direct Substitution)
Manual Unit Module Calculation Order
Manual Designated Recycle Streams
Input / Output Dimensional Units Control
(US (STP), Metric (NTP or STP),
SI (NTP or STP) standards along with
individual unit control for all specs)
Material Balance (mole and mass by
component, mole and mass by Module)
Energy Balance by Module
Stream Summary and Detailed Analysis
300+ Sample Flowsheets
Special Features
Dynamic Simulation Analysis
Time Duration and Time Interval
Sour Gas / LPG Treating using Amines
(Single or Mixed): MEA, DEA, MDEA,
DGA, DIPA, Piperazine
Claus Process with Automatic
Redistribution of S2, S3, S4, S5, S6,
S7 and S8 in the Vapor Phase
Case Studies
Inline Fortran
Flow Sheet Optimization (Min / Max)
Unit Specific Thermodynamic Properties
Feed Stream Specific Thermodynamic
Properties
Lost Work Analysis
ChemTran Data Regression tool
Solids Handling
Simulator Kernel is callable from Visual
Basic, Visual C++ and Excel VBA or
any program that supports a VB
interface
Stream Calculation Features
Saturate Feed Streams with Water
CO
2
Freeze prediction
Hydrate Pressure / Temperature Prediction
(Methanol or Ethylene Glycol inhibition
if present)
Hydrate Pressure and Temperature Curves
Phase Envelope and Phase Map
Critical Properties Calculation
Gross and Net Heating Values
Reid Vapor Pressure (ASTM 323, API 5B1.1
API5B1.2)
Dew / Bubble Points and Wobbe Index
Water Dew Point
Stream Vapor Pressure
Sonic Velocity
Bulk Properties for External Programs
Process Line Heating or Cooling Curves
Process Line Sizing with three diameters
Print Phase Map or Phase Envelope
Pressure-Enthalpy Diagram with Isotherms
Vapor or Liquid Partial Numeric Derivatives
Cetane Index
Latent Heat of Vaporization

35
Features and Specifications
Unit Module Operations
Add Block (User Specified Calculations)
Air Cooled Heat Exchanger
Amine Columns
Absorber with optional side feed
Regenerator with optional side draw
Real Trays or Packing
Batch Distillation
Component Splitter
Compressor (Polytropic or Isentropic)
Compressor-Expander
Polytropic or Isentropic Efficiency
Controller (equipments or streams)
Chemical Reactors
Stoichiometric, CO Shift, Methanation,
Plug Flow Reactor, Continuous Stirred
Tank Reactor, Ammonia Synthesis,
Secondary Reformer, Steam Reformer,
Methanol Synthesis
Depressurizer with time analysis
Distillation Column
Absorber (Two or Three Phase)
Absorber with Reboiler
Stripper, Stripper with Total Condenser
Liquid - Liquid Extraction
Partial or Total Fractionator
Multiple Feeds / Side Draws / Heaters
Intercoolers / Water Decants / Coolers
Column Profile, Efficiency Specifications
Divider (single or many product streams)
Double Pipe Heat Exchanger
Equilibrium Reactor
Expander / Expander Compressor / Pump
Fired Heater
Flash Separator (two or three phase)
Flowmeter
Heat Exchanger (single or two stream)
Hydrotreater
Line Module / LNG Exchanger
Mass Balance
Mixer (up to six feed streams)
Multiple Flashes or Multiple Phase Flash
Packed Column (same as Distillation)
Phase Envelope or Phase Map
Plate-Fin Heat Exchanger
Polytropic Compressor / Pump
Refine Column
Total or Partial Condenser
Pumparound Reflux
Pumparound Total or Partial Condenser
Side Strippers, Multiple Feeds
Steam Feed / Four Reboiler Types
Product Quality Specifications
Side Draws / Heaters / Coolers
Feed & Product Heating/Cooling Curves
Shortcut Fractionator
Stream Manipulator
Tank
Valve
Thermodynamic Methods
Hydrocarbon Enthalpy / K Values
API SOAVE
BRAUN K-10
BWR (Benedict-Webb-Rubin)
BWRS (Benedict-Webb-Rubin-
Starling)
Chao-Seader
Corresponding States
Curl-Pitzer
Deshmukh-Mather (Mixed Amines)
ESSO (Maxwell-Bonnell)
ESSO Tabular
GERG 2008
GPA Water
Grayson-Johnson (API)
Grayson-Streed
Kent-Eisenberg (Mixed Amines)
KVAL (ChemShare)
LKP (Lee-Kesler-Ploecker)
NIST RefProp database 23
Modified ESSO
Modified Peng-Robinson (Stryjek)
Peng-Robinson
PPR (Predictive Peng-Robinson)
RK (Redlich-Kwong)
SOAVE (Soave-Redlich-Kwong)
Steam Tables
SKD (Soave-Kabadi-Danner)
Tabular K
Water / HC Solubilities
Yen-Alexander
Chemical Enthalpy / K Values
API SOUR (Sour Water-API)
CHEMICAL THEORY Vapor
DMPEG
Edwards / Edwards Sour
Excess Latent
Excess Tabular
GERG 2008
HAYDEN OCONNEL Vapor
Henry's Gas Law (K*P)
Ideal Vapor
Ideal K-values
Margules
MEA or DEA
Mixing Rules (Yen-Woods, EOS)
NIST RefProp
NRTL (Renon)
Regular Solution
SOURK (Sour Water-Beychok)
UNIFAC
UNIQUAC
Van Laar
Vapor Pressure
VLE / LLE Unifac
Weak Electrolytes
Wilson
Density Property Methods
AGA, API SOAVE (API-SRK)
BWR (Benedict-Webb-Rubin)
BWRS (Benedict-Webb-Rubin-Starling)
COPE (Corresponding States density data)
COSTALD (Corresponding States liquid D)
GERG 2008, Ideal Densities
LKP (Lee-Kesler-Ploecker)
Mixed Amines, Modified Peng-Robinson
NIST RefProp, Peng-Robinson
Predictive Peng-Robinson
RK (Redlich-Kwong),Soave-Kabadi-Danner
SOAVE (Soave-Redlich-Kwong)
STD (Yen-Woods)
Component Data
1200+ Pure Components
Crude Assay Data (TBP, D-86, D-1160,
Pseudo Volumes, D-2887)
Crude Library (38 World Crudes)
Crude Automatic Light End Analysis
Distillation Curve Input and Output
Up to 15 sets of User-Defined Curves for
Viscosity, Pour Point, Sulfur and other
Transport Property Methods
Surface Tension
API, Molar Average, Mixed Amines
Thermal Conductivity
API, C.C.LI, LNAV, NBS81,
Mixing Method 3, TEMA 68 & TEMA 78,
Mixed Amines, NIST RefProp
Viscosity
API, Dean & Stiel, LNAV,
Mixing Method 2, TWU, MOD API,
NBS81, Mixed Amines, NIST RefProp
CHEMTRAN Property Generation
User Defined Components
Component Property Data Regression
VLE, LLE and VLLE Mixture Data
Regression
Property Estimation Based on Component
Structure
Equipment Performance
Distillation / Mixed Amine / Refine Columns
Tray by Tray Hydraulics and Tray Sizing
Flowmeter Sizing
Heat Exchanger Rating
All Shells: Single Phase,
E and F Shells: Single & Two Phase
Plate-Fin, Air Cooler: Single & Two Phase
Line Module (Single, Two or Three Phase)
Heat Transfer to Surroundings,
Pipe Segment Specifications, Pressure
Drop Tables, Slug Flow Analysis
Polytropic Compressor Analysis with
Speed Curves
Separator Sizing (Horizontal or Vertical)

36
In Over 75 Countries
Spanning 45 Years,
Thousands of Companies
in the Chemical Process
Industries Have Been
Using Our Solutions!


DESIGN II FOR WINDOWS is available on our website 24 hours a day, and
may be downloaded for upgrading or evaluation. If you are interested
in DESIGN II FOR WINDOWS and would like more information, please
contact WinSim Inc. via any of the following:
Corporate Headquarters:
WinSim Inc. Website: www.winsim.com
8653 FM 2759 Road e-mail: [email protected]
Richmond, Texas 77469 [email protected]
Phone: 281-545-9200
Fax: 281-545-8820




WinSim is a registered trademark of WinSim Inc. DESIGN II and DESIGN II for Windows are trademarks of ChemShare Corporation.
Microsoft and Windows are registered trademarks of Microsoft Corporation. Visual Basic and Visual C++ are trademarks of Microsoft
Corporation. THERMINOL is a registered trademark of Solutia Inc. DOWTHERM is a registered trademark of The Dow Chemical
Company. SELEXOL is a registered trademark of The Dow Chemical Company. Coastal AGR is a registered trademark of Coastal
Chemical Company. DGA and Diglycolamine are registered trademarks of Huntsman Corporation. aMDEA is a registered trademark of
BASF. AICHE is a registered trademark of the American Institute of Chemical Engineers. ASME is a registered trademark of the American
Society of Mechanical Engineers. The Design Institute for Physical Property Data and DIPPR are registered trademarks of the American
Institute of Chemical Engineers (AICHE). Hysys is a registered trademark of Aspentech. Pro/II is a trademark of Simulation Sciences. ProMax
is a registered trademark of Bryan Research. Aspen Plus is a registered trademark of Aspentech. ChemCAD is a trademark of Chemstations.
All other trademarks and logos are property of their respective owners.

Copyright 1995 - 2014 WinSim Inc. All Rights Reserved. February 2014.





WinSim Inc.
Advanced Engineering Software