Material Safety Data Sheet: CCX-77

Supercedes Date 09/28/2005 Issuing Date 08/21/2008

1. PRODUCT AND COMPANY IDENTIFICATION

Product Name CCX-77 Product Code 0289

Recommended Use Lubricant Chemical Nature Petroleum distillates
Information on Manufacturer Imported by: NCH INDIA PVT LTD
114, SIDCO Industrial estate, Ambattur, Chennai - 98.
Emergency Telephone Number
+91-44-26350176 / 42077898
CERTIFIED LABS, DIV. OF NCH CORP.
BOX 152170
IRVING, TEXAS 75015

2. HAZARDS IDENTIFICATION

Emergency Overview
Warning
Combustible liquid and vapor
Causes skin irritation
May cause allergic skin reaction
Causes eye irritation
May be harmful if inhaled
Harmful or fatal if swallowed

Color Black Physical State Liquid Odor Petroleum distillates

Potential Health Effects
Principle Route of Exposure Skin contact, Eye contact, Inhalation.
Primary Routes of Entry Inhalation, Skin Absorption, Ingestion.
Acute Effects
Eyes Causes eye irritation.
Skin Causes skin irritation. May be absorbed through the skin in harmful amounts. Acidosis. Repeated exposure may
cause skin dryness or cracking.
Inhalation May cause irritation of respiratory tract. Causes headache, drowsiness or other effects to the central nervous
system. Inhalation of vapors in high concentration can cause narcotic effects and metabolic acidosis .
Ingestion Ingestion may cause gastrointestinal irritation, nausea, vomiting and diarrhea . Causes headache, drowsiness or
other effects to the central nervous system. Acidosis. Aspiration hazard if swallowed - can enter lungs and cause
damage.
Chronic Effects Blood disorder may occur after prolonged inhalation. Bloody urine. Lead may damage kidney function, the blood
forming system and the reproductive system. May cause skin sensitization in some individuals .
Target Organ Effects Blood, Central nervous system, Kidney, Liver, Respiratory system, Lymphatic System, Skin, Eyes, Reproductive
System, spleen, Heart, Bone Marrow.
Aggravated Medical Conditions Kidney disorders. Liver disorders. Neurological disorders. Skin disorders. Respiratory disorders. Cardiovascular.
Blood disorders.
Potential Environmental Effects See Section 12 for additional Ecological information

3. COMPOSITION / INFORMATION ON INGREDIENTS

Component CAS-No
Ethyl benzene 100-41-4
2-Butoxyethanol 111-76-2
Lead diamyldithiocarbamate 36501-84-5
Petroleum distillates, hydrotreated light 64742-47-8
Petroleum distillates, hydrotreated heavy naphthenic (<3% DMSO extractable) 64742-52-5
Solvent naphtha (petroleum), medium aliphatic 64742-88-7
Oxidized heavy petroleum distillates 64742-97-8
Mineral oil 8012-95-1
Asphalt 8052-42-4

4. FIRST AID MEASURES

General Advice Do not get in eyes, on skin, or on clothing. Do not breathe vapors or spray mist .
Eye Contact Rinse thoroughly with plenty of water, also under the eyelids. Get medical attention if irritation develops and persists.
Skin Contact Wash off immediately with plenty of water for at least 15 minutes. Remove contaminated clothing and shoes. Get
medical attention if irritation develops and persists. Wash contaminated clothing before re-use.
Inhalation Move to fresh air. Give oxygen or artificial respiration if needed. If not breathing, give artificial respiration. Get medical
attention immediately.
Ingestion Drink 1 or 2 glasses of water. Do not induce vomiting. Get medical attention immediately. Never give anything by
mouth to an unconscious person.
Notes to Physician Aspiration hazard if swallowed - can enter lungs and cause damage. May cause cardiac arrhythmia.

5. FIRE-FIGHTING MEASURES

Flash Point 100F / 38C Method Seta closed cup

Autoignition Temperature No information available
Flammability Limits in Air Solvent mixture Upper 12.3 Lower 0.5
Suitable Extinguishing Media
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Water spray. Carbon dioxide (CO2). Foam. Alcohol-resistant foam . Dry chemical. Use extinguishing measures that are appropriate to local circumstances and the
surrounding environment.
Specific Hazards Arising from the Chemical
Solvent vapors are heavier than air and may spread along floors . Vapors may ignite and explode. Material can create slippery conditions.
Protective Equipment and Precautions for Firefighters
As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear.
NFPA Health 2 Flammability 2 Instability 0
HMIS Health 2 Flammability 2 Instability 0

6. ACCIDENTAL RELEASE MEASURES

Personal Precautions Use personal protective equipment. Remove all sources of ignition. Ensure adequate ventilation. Prevent further
leakage or spillage if safe to do so. Material can create slippery conditions.
Environmental Precautions Do not flush into surface water or sanitary sewer system.
Methods for Containment Contain spillage, soak up with non-combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite)
and transfer to a container for disposal according to local / national regulations (see section 13)
Methods for Cleaning Up Pick up and transfer to properly labelled containers.
Neutralizing Agent Not applicable

7. HANDLING AND STORAGE

Handling Keep away from open flames, hot surfaces and sources of ignition. To avoid ignition of vapours by static electricity
discharge, all metal parts of the equipment must be grounded. Do not get in eyes, on skin, or on clothing. Do not
breathe vapors or spray mist .
Storage Store in original container. Keep containers tightly closed in a dry, cool and well-ventilated place. Keep away from
heat and sources of ignition.
Storage Temperature Minimum 35F / 2C Maximum 100F / 38C
Storage Conditions Indoor X Outdoor Heated Refrigerated

8. EXPOSURE CONTROLS / PERSONAL PROTECTION

Exposure Guidelines
Component ACGIH TLV OSHA PEL NIOSH
Ethyl benzene TWA: 100 ppm
STEL: 125 ppm
TWA: 100 ppm
TWA: 435 mg/m
3
IDLH: 800 ppm
STEL 125 ppm
STEL 545 mg/m
3


TWA: 435 mg/m
3


TWA: 100 ppm
2-Butoxyethanol TWA: 20 ppm
TWA: 240 mg/m
3


TWA: 50 ppm
Skin
IDLH: 700 ppm
TWA: 5 ppm
TWA: 24 mg/m
3
Lead diamyldithiocarbamate No data available no data available
IDLH: 100 mg/m
3


TWA: 0.050 mg/m
3
Petroleum distillates, hydrotreated light No data available no data available no data available
Petroleum distillates, hydrotreated heavy naphthenic (<3%
DMSO extractable)
No data available no data available no data available
Solvent naphtha (petroleum), medium aliphatic No data available no data available no data available
Oxidized heavy petroleum distillates No data available no data available no data available
Mineral oil
TWA: 5 mg/m
3


STEL: 10 mg/m
3
TWA: 5 mg/m
3
IDLH: 2500 mg/m
3


STEL 10 mg/m
3


TWA: 5 mg/m
3
Asphalt
TWA: 0.5 mg/m
3 no data available
Ceiling: 5 mg/m
3
Engineering Measures Use with local exhaust ventilation. Ensure adequate ventilation, especially in confined areas.
Personal Protective Equipment
Eye/Face Protection Safety glasses with side-shields.
Skin Protection Impervious gloves.
Respiratory Protection Use NIOSH approved respiratory protection.
General Hygiene Considerations Ensure that eyewash stations and safety showers are close to the workstation location. Wear protective
gloves/clothing. Remove and wash contaminated clothing before re-use.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State Liquid Viscosity Non viscous

Color Black Odor Petroleum distillates
Appearance Opaque pH Not applicable
Specific Gravity 0.881 Bulk Density 7.34
Evaporation Rate 0.36 (Butyl acetate=1) Percent Volatile (Volume) 77.1
VOC Content (%) 76 Vapor Pressure 2.91 mmHg @ 70 F
Vapor Density 10.1 Solubility Negligible
Boiling Point/Range 308F / 153C
10. STABILITY AND REACTIVITY

Chemical Stability Stable. Hazardous polymerization does not occur .

Conditions to Avoid Keep away from open flames, hot surfaces, and sources of ignition.
Incompatible Products Strong oxidizing agents. Acids. Bases. Halogenated hydrocarbon.
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Hazardous Decomposition Products Carbon oxides. Nitrogen oxides (NOx). Sulfur oxides . Aldehydes . Ketones. Smoke.
Possibility of Hazardous Reactions None under normal processing

11. TOXICOLOGICAL INFORMATION

Product Information No information available

Component Information
Acute toxicity
Component LD50 Oral LD50 Dermal LC50 Inhalation Draize Test Other
Ethyl benzene 3500 mg/kg ( Rat ) 15354 mg/kg ( Rabbit ) 17.2 mg/L ( Rat ) 4 h no data available no data available
2-Butoxyethanol 470 mg/kg ( Rat ) 220 mg/kg ( Rabbit )
2270 mg/kg ( Rat )
no data available no data available no data available
Lead diamyldithiocarbamate no data available no data available no data available no data available no data available
Petroleum distillates, hydrotreated light 5000 mg/kg ( Rat ) 2000 mg/kg ( Rabbit ) 5.2 mg/L ( Rat ) 4 h no data available no data available
Petroleum distillates, hydrotreated
heavy naphthenic (<3% DMSO
extractable)
5000 mg/kg ( Rat ) 2000 mg/kg ( Rabbit ) 2.18 mg/L ( Rat ) 4 h no data available no data available
Solvent naphtha (petroleum), medium
aliphatic
5000 mg/kg ( Rat ) 3000 mg/kg ( Rabbit ) 5.28 mg/L ( Rat ) 4 h no data available no data available
Oxidized heavy petroleum distillates no data available no data available no data available no data available no data available
Mineral oil no data available no data available no data available no data available no data available
Asphalt 5000 mg/kg ( Rat ) 2000 mg/kg ( Rabbit ) no data available no data available no data available
Chronic Toxicity
Component Mutagenicity Sensitization Developmental Toxicity Reproductive Toxicity Target Organ Effects
Ethyl benzene no data available no data available no data available no data available eyes, respiratory system,
skin, CNS, heart
2-Butoxyethanol no data available no data available no data available Male reproductive toxin. liver, kidneys, lymphoid
system, skin, blood, eyes,
respiratory system, CNS,
hematopoietic system, spleen
Lead diamyldithiocarbamate no data available no data available no data available no data available no data available
Petroleum distillates, hydrotreated light no data available no data available no data available no data available CNS, cardiovascular system
Petroleum distillates, hydrotreated
heavy naphthenic (<3% DMSO
extractable)
no data available no data available no data available no data available no data available
Solvent naphtha (petroleum), medium
aliphatic
no data available no data available no data available no data available CNS, liver, kidneys
Oxidized heavy petroleum distillates no data available no data available no data available no data available no data available
Mineral oil no data available no data available no data available no data available skin, respiratory system,
eyes
Asphalt no data available Skin sensitization no data available no data available eyes, respiratory system (in
animals: skin tumors)
Carcinogenicity .
Component ACGIH IARC NTP OSHA Other
Ethyl benzene A3 Group 2B not applicable X not applicable
2-Butoxyethanol A3 not applicable not applicable not applicable not applicable
Lead diamyldithiocarbamate not applicable not applicable Reasonably Anticipated X not applicable
Petroleum distillates, hydrotreated
light
not applicable not applicable not applicable not applicable not applicable
Petroleum distillates, hydrotreated
heavy naphthenic (<3% DMSO
extractable)
not applicable not applicable not applicable not applicable not applicable
Solvent naphtha (petroleum), medium
aliphatic
not applicable not applicable not applicable not applicable not applicable
Oxidized heavy petroleum distillates not applicable not applicable not applicable not applicable not applicable
Mineral oil not applicable not applicable not applicable not applicable not applicable
Asphalt not applicable not applicable not applicable not applicable not applicable

12. ECOLOGICAL INFORMATION

Product Information No information available

Component Information
Component Toxicity to Algae Toxicity to Fish Microtox Water Flea log Pow
Ethyl benzene EC50= 4.6 mg/L Selenastrum
capricornutum 72 h
EC50> 438 mg/L Selenastrum
capricornutum 96 h
LC50= 14.0 mg/L Oncorhynchus mykiss 96
h
LC50= 150.0 mg/L Lepomis macrochirus 96
h
LC50= 32 mg/L Lepomis macrochirus 96 h
LC50= 4.2 mg/L Oncorhynchus mykiss 96
h
LC50= 48.5 mg/L Pimephales promelas 96 h
LC50= 9.09 mg/L Pimephales promelas 96 h
LC50= 9.6 mg/L Poecilia reticulata 96 h
EC50 = 9.68 mg/L 30 min
EC50 = 96 mg/L 24 h
EC50 1.8 - 2.4 mg/L 48 h 3.118
2-Butoxyethanol no data available LC50= 1490 mg/L Lepomis macrochirus 96
h
no data available LC50 1698 - 1940 mg/L 24 h
EC50 = 1720 mg/L 24 h
0.81
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Lead diamyldithiocarbamate no data available no data available no data available no data available N/A
Petroleum distillates, hydrotreated light no data available LC50= 1740 mg/L Lepomis macrochirus 96
h
LC50= 45 mg/L Pimephales promelas 96 h
no data available LC50 = 4720 mg/L 96 h N/A
Petroleum distillates, hydrotreated heavy
naphthenic (<3% DMSO extractable)
no data available LC50> 5000 mg/L Pimephales promelas 96
h
no data available EC50 > 1000 mg/L 48 h N/A
Solvent naphtha (petroleum), medium
aliphatic
EC50= 450 mg/L Selenastrum
capricornutum 96 h
LC50= 800 mg/L Pimephales promelas 96 h no data available EC50 > 100 mg/L 48 h N/A
Oxidized heavy petroleum distillates no data available no data available no data available no data available N/A
Mineral oil no data available no data available no data available no data available N/A
Asphalt no data available no data available no data available no data available 6
Persistence and Degradability No information available
Bioaccumulation No information available
Mobility No information available

13. DISPOSAL CONSIDERATIONS

Product Disposal Dispose of as hazardous waste in compliance with local and national regulations
Container Disposal Empty containers should be taken for local recycling, recovery or waste disposal

14. TRANSPORT INFORMATION

DOT
Proper Shipping Name Petroleum distillates, n.o.s.
Hazard Class 3
UN-No UN1268
Packing Group III
Description Petroleum distillates, n.o.s.,3,UN1268,PG III

TDG
Proper shipping name Petroleum distillates, n.o.s.
Hazard Class 3
UN-No UN1268
Packing Group III
Description PETROLEUM DISTILLATES, N.O.S.,3,UN1268,PG III

ICAO
UN-No UN1268
Proper Shipping Name Petroleum distillates, n.o.s.
Hazard Class 3
Packing Group III
Shipping Description Petroleum distillates, n.o.s.,3,UN1268,PG III

IATA
UN-No UN1268
Proper Shipping Name Petroleum distillates, n.o.s.
Hazard Class 3
Packing Group III
ERG Code 3L
Shipping Description UN1268,Petroleum distillates, n.o.s.,3,PG III

IMDG/IMO
Proper Shipping Name Petroleum distillates, n.o.s.
Hazard Class 3
UN-No UN1268
Packing Group III
EmS No. F-E, S-E
Shipping Description UN1268, Petroleum distillates, n.o.s.,3,PG III

15. REGULATORY INFORMATION

Inventories
TSCA Complies
DSL Complies
U.S. Federal Regulations
SARA 313
Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product contains a chemical or chemicals which are subject to the
reporting requirements of the Act and and Title 40n of the Code of Federal Regulations, Part 372:
Component CAS-No Weight % SARA 313 - Threshold Values
Ethyl benzene 100-41-4 0.1-1 0.1
2-Butoxyethanol 111-76-2 1-5 1.0
Lead diamyldithiocarbamate 36501-84-5 0.1-1 1.0
SARA 311/312 Hazardous Categorization
Acute Health Hazard Chronic Health Hazard Fire Hazard Sudden Release of Pressure
Hazard
Reactive Hazard
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Yes Yes Yes No No
CERCLA
Component Hazardous Substances RQs CERCLA EHS RQs
Ethyl benzene 1000 lb Not applicable
2-Butoxyethanol Not applicable Not applicable
Lead diamyldithiocarbamate Not applicable Not applicable
Petroleum distillates, hydrotreated light Not applicable Not applicable
Petroleum distillates, hydrotreated heavy naphthenic (<3% DMSO
extractable)
Not applicable Not applicable
Solvent naphtha (petroleum), medium aliphatic Not applicable Not applicable
Oxidized heavy petroleum distillates Not applicable Not applicable
Mineral oil Not applicable Not applicable
Asphalt Not applicable Not applicable
Canada
This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations (CPR) and the MSDS contains all the
information required by the CPR.
WHMIS Hazard Class
B3 Combustible liquid, D2A Very toxic materials , D2B Toxic materials .

16. OTHER INFORMATION

Prepared By Mike McDowell

Supercedes Date 09/28/2005
Issuing Date 08/21/2008
Reason for Revision No information available
Glossary No information available
List of References No information available
CERTIFIED LABS, DIV. OF NCH CORP. assumes no responsibility for personal injury or property damage caused by the use, storage, or disposal of
the product in a manner not recommended on the product label. Users assume all risks associated wiht such unrecommended use, storage or
disposal of the product. The information provided on this MSDS is correct to the best of our knowledge, information and belief at the date of its
publication. The information given is designed only as a guide for safe handling, use, processing, storage, transportation, disposal and release and
is not to be considered as a warranty or quality specification. The information relates only to the specific material designated and may not be valid
for such material used in combination with any other material or in any process, unless specified in the text.
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