Advanced Chem Thermodynamics
Advanced Chem Thermodynamics
Advanced Chem Thermodynamics
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You submitted this quiz on Thu 6 Feb 2014 8:16 AM PST. You got a score of 14.00 out of 14.00.
Question 1
What is the enthalpy of reaction?
Hf (C2H5OH(l)) Hf (CO2(g)) Hf (H2O(l)) Your Answer 158 kJ -908 kJ -452 kJ -1418 kJ Total
Question 2
Which process will result in a decrease in the entropy? Your Answer Score Explanation
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H2O(s) H2O(l) NaCl(s) NaCl(aq) CO2(g) CO2(s) Total 1.00 1.00 / 1.00
Question 3
Which process will be spontaneous? Your Answer Sublimation of CO2(s) at 1 atm and 25 Ice melting at -10 NaCl precipitating out of an unsaturated solution 2Fe2O3(s) 4Fe(s) + 3O2(g) Total 1.00 / 1.00 Score 1.00 Explanation
Question 4
What is Suniv given Ssys = 392 J/K and Ssurr = -184 J/K? Your Answer -208 J/K 208 J/K -576 J/K 576 J/K Total 1.00 / 1.00 1.00 Score Explanation
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2/8
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Question 5
What is Ssurr at 35C when Hsys = 36 kJ/mol? Your Answer 117 J/molK 1029 J/molK -117 J/molK -1029 J/molK Total 1.00 / 1.00 1.00 Score Explanation
Question 6
When H and S are both positive, what can be said about the spontaneity of the reaction? Your Answer Spontaneous at high temperatures because G is negative. Spontaneous at high temperatures because G is positive. Spontaneous at low temperatures because G is negative. Spontaneous at low temperatures because G is positive. Total 1.00 / 1.00 Score 1.00 Explanation
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3/8
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Question 7
Find Gsys at 20C when H = 184 kJ and S = 432 J/K. Your Answer 109 kJ 74.7 kJ 57.4 kJ 175 kJ Total 1.00 / 1.00 1.00 Score Explanation
Question 8
Predict which of the following substances will have the greatest molar entropy? Your Answer Ar (g) B12(s) Cl2(g) CHCl3 (l) Total 1.00 / 1.00 1.00 Score Explanation
Question 9
Calculate the standard entropy change (S) for the reaction from the given standard entropies provided in the table.
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4/8
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bgcolor="#ff6600"> Substance C3H8(g) O2(g) CO2(g) H2O(g) Your Answer 2155.3 J/K 100.3 J/K -72.9 J/K 337.6 J/K Total 1.00 / 1.00 1.00 Score S(J/mol.K) 270.3 205.2 213.8 188.8 Explanation
Question 10
Which of the following is a chemical equation for the free energy for the formation of water? Your Answer 2 H2O(l) 2 H2(g) + O2(g) H2(g) + O2(g) H2O(l) H2(g) + O(g) H2O(l) 2 H2(g) + O2(g) 2 H2O(l) Total 1.00 / 1.00 1.00 Score Explanation
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5/8
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Question 11
Determine the standard free energy of formation (Gf) for C3H8, given the following information. All values were measured at 25 C.
G = -2074.2 kJ
bgcolor="#ff6600"> Substance CO2(g) H2O(g) Your Answer -23.4 kJ/mol -1451.2 kJ/mol -2074.2 kJ/mol 117.0 kJ/mol Total 1.00 / 1.00 Score 1.00 Gf (kJ/mol) -394.4 -228.6 Explanation
Question 12
The following reaction is allowed to proceed and equilibrium is established. Which statement is false?
C3H8(g) + 5 O2(g) 3 CO2(g) + 4 H2O(g) Your Answer When equilibrium is established, G = 0.0 kJ
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Explanation
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If the reaction initially has one mole of each gas present in the reaction chamber, the reaction will proceed toward products to reach equilibrium. When equilibrium is established, the partial pressures of CO2 and H2O will both be greater than the partial pressures of C3H8 and O2. When equilibrium is established, G = 0.0 kJ Total 1.00 / 1.00
Question 13
Determine G at 25C for the following reaction based on the pressures given in the table.
G = -2074.2 kJ
bgcolor="#ff6600"> Substance C3H8(g) O2(g) CO2(g) H2O(g) Your Answer -2175.7 kJ 8.921 104 kJ 74.5 kJ -2074.2 kJ
https://class.coursera.org/advancedchemistry-001/quiz/feedback?submission_id=18223 7/8
Score 1.00
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Total
1.00 / 1.00
Question 14
Determine Kc for the following reaction at 25C.
H+(aq) + F -(aq) HF(aq) Your Answer 1.3 1041 6.8 10-5 2.8 103 1.1 Total 1.00 / 1.00 1.00 Score
G = -19.7 kJ Explanation
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8/8