1. This experiment tested Hess's Law by measuring the heat released or absorbed by three chemical reactions using calorimetry.
2. The heat capacity of the calorimeter was first determined by measuring the temperature change of water before and after adding hot water.
3. The heats of reaction were then measured for the reactions of HCl + NaOH, NH4Cl + NaOH, and H3O+ + HCl by recording the temperature change upon mixing the reactants.
4. The temperature graphs show heat loss over time for each reaction. Hess's Law was confirmed because the reactions were experimentally shown to be thermally equivalent as predicted.
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1. This experiment tested Hess's Law by measuring the heat released or absorbed by three chemical reactions using calorimetry.
2. The heat capacity of the calorimeter was first determined by measuring the temperature change of water before and after adding hot water.
3. The heats of reaction were then measured for the reactions of HCl + NaOH, NH4Cl + NaOH, and H3O+ + HCl by recording the temperature change upon mixing the reactants.
4. The temperature graphs show heat loss over time for each reaction. Hess's Law was confirmed because the reactions were experimentally shown to be thermally equivalent as predicted.
Original Description:
My Lab Report on Calorimetry in Thermodynamics in Chemistry Class
1. This experiment tested Hess's Law by measuring the heat released or absorbed by three chemical reactions using calorimetry.
2. The heat capacity of the calorimeter was first determined by measuring the temperature change of water before and after adding hot water.
3. The heats of reaction were then measured for the reactions of HCl + NaOH, NH4Cl + NaOH, and H3O+ + HCl by recording the temperature change upon mixing the reactants.
4. The temperature graphs show heat loss over time for each reaction. Hess's Law was confirmed because the reactions were experimentally shown to be thermally equivalent as predicted.
Copyright:
Attribution Non-Commercial (BY-NC)
Available Formats
Download as ODT, PDF, TXT or read online from Scribd
1. This experiment tested Hess's Law by measuring the heat released or absorbed by three chemical reactions using calorimetry.
2. The heat capacity of the calorimeter was first determined by measuring the temperature change of water before and after adding hot water.
3. The heats of reaction were then measured for the reactions of HCl + NaOH, NH4Cl + NaOH, and H3O+ + HCl by recording the temperature change upon mixing the reactants.
4. The temperature graphs show heat loss over time for each reaction. Hess's Law was confirmed because the reactions were experimentally shown to be thermally equivalent as predicted.
Copyright:
Attribution Non-Commercial (BY-NC)
Available Formats
Download as ODT, PDF, TXT or read online from Scribd
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Calorimetry and Enthalpy Dylan Custer Partner: Daniel Horn Purpose: To verify Hess's La !aria"les/Hypothesis: !
aria"les: #nitial temperature of solutions$ %alorimeter heat %apa%ity Hypothesis: The solutions' temperatures ill %han&e in a%%ordan%e to Hess's La 'afety E(uipment and Pro%edures: 'afety E(uipment: )o&&les$ apron$ %hemi%al*resistant &loves 'afety Pro%edures: +ash hands thorou&hly "efore leavin& la"oratory ,aterials: Chemicals -mmonia solution$ .H3 $ /00 ,$ 10 mL 'odium hydro2ide solution$ .a3H$ /00 , 100 mL -mmonium %hloride solution$ .H4Cl$ /00 ,$ 10 mL +ater$ distilled or deioni5ed Hydro%hlori% a%id solution$ HCl$ /00 ,$ 100 mL Equipment 6ea7er$ /10*mL Calorimeter and lid 8/ 'tyrofoam %ups and %over9 Deioni5ed or distilled ater Di&ital thermometer )raduated %ylinder$ 10*mL Hot plate ,a&neti% stirrer and stirrin& "ar Timer or stop at%h Date: 10/1/13
Pro%edures: Part 1. Determine the Heat Capacity of the Calorimeter 10 'et up a %alorimeter of t o nested 'tyrofoam %ups /0 ,easure 1000 mL of distilled ater in a 10*mL &raduated %ylinder and pour the ater into the %alorimeter0 30 Pla%e the %alorimeter assem"ly on a ma&neti% stirrer$ add a ma&neti% stirrin& "ar$ and set the "ar spinnin& slo ly0 40 ,easure and re%ord the temperature of the ater in the Part 1 Data Ta"le0 10 Heat appro2imately :1 mL distilled to a"out :0 ;C in a /10*mL "ea7er0 <0 ,easure 1000 mL of the :0 ;C distilled ater in a 10*mL &raduated %ylinder0 :0 ,easure and re%ord the temperature of the hot ater in the Part 1 Data Ta"le0 =0 #mmediately pour the hot ater into the room temperature ater in the %alorimeter0 >0 Cover the %alorimeter$ insert the thermometer$ and stir the ater0 100 ?e%ord the temperature every /0 se%onds for a total of 3 minutes in the Part 1 Data Ta"le0 110 Empty the %alorimeter and dry the inside of %alorimeter hen finished0 Part 2. Determine the Heats of Reaction Reaction 1: HCl 8a(9 @ .a3H 8a(9 A .aCl 8a(9 @ H/3 8l9 10 ,easure 1000 mL of a /00 , HCl in a 10*mL &raduated %ylinder and transfer to %alorimeter /0 ?e%ord the temperature of the HCl in the Part / Data Ta"le0 30 ?inse the 10*mL &raduated %ylinder ith distilled ater0
40 10 <0 :0 =0
,easure 100* mL of a /00 , .a3H in the Part / Data Ta"le0 ?e%ord the temperature of the .a3H in the Part / Data Ta"le0 Put a ma&neti% stirrin& "ar into the %alorimeter and start the "ar spinnin& slo ly in the HCl Bui%7ly add the 1000 mL of /00 .a3H to the %alorimeter$ %over$ and insert the thermometer0 ?e%ord the temp0 after /0 se%onds$ then /0 se%onds for 3 minutes$ in the Part / Data Ta"le0
Reaction 2: .H4 Cl @ .a3H A .H3 @ .aCl @ H/3 >0 ?inse and dry the %alorimeter$ thermometer$ and &raduated %ylinder used for ?ea%tion 100 ?epeat steps 1*= of Part / usin& /00 , .H4 Cl and /00 , .a3H0 Reaction 3: .H3 8a(9 @ HCl 8a(9 A .H4Cl 8a(9 110 Thorou&hly rinse and dry the %alorimeter$ thermometer$ stirrer "ar$ and &raduated %ylinder used for rea%tion /0 1/0 ?epeat steps 1*= of Part / usin& /00 , .H3 solution and /00 , HCl solution0 ?esults/-nalysis: Data Table 1 Determination of the Heat Capacity of the Calorimeter 42 41.5 41 40.5 40 39.5 39 1 2 3 4 5 6 7 8 9 10
y*a2is C temperature 8in ;C9
2*a2is C time 8in se%onds9
Part 2 Data Table Determination of Heats of Reaction Reaction 1
Dis%ussion: The &raphs sho that ener&y 8in the form of heat9 is lost in time0 Con%lusion: 6e%ause the &iven e(uations 1$ / and 3 are related$ and ere e2perimentally sho n to "e related$ Hess's La proves to "e an a%%urate depi%tion of the "ehavior of enthalpy in the rea%tion of li(uid solutions0
DTU, Department of Energy Engineering S in (KJ/ (KG K) ) - V in (M 3/kg) - T in (ºC) M.J. Skovrup & H.J.H Knudsen. 17-04-10 Ref:R.Döring. Klima+Kälte Ingenieur Ki-Extra 5, 1978
