M.

TECH (Full Time) - CHEMICAL ENGINEERING Curriculum & Syllabus 2013 2014

FACULTY OF ENGINEERING AND TECHNOLOGY SRM UNIVERSITY SRM NAGAR, KATTANKULATHUR 603 203

School of Bioengineering Department of Chemical Engineering M.Tech. Chemical Engineering Curriculum 2013 - 2014 Semester I Course Code CH2001 CH2002 CH2003 E-1 S-1 Total Course Title Advance Transport phenomena Computer aided process plant design Advanced chemical reaction engineering Elective - 1 Supportive course - 1 L 3 3 3 3 3 15 T 1 0 1 0 0 2 P 0 3 0 0 0 3 C 4 4 4 3 3 18

Semester II Course Code CH2004 CH2005 CH2006 E-2 IE-1 Total Course Title Advanced Heat transfer Advanced process dynamics and control Multi component distillation & Reactor Design Elective - 2 Interdisciplinary Elective - 1 L 3 3 3 3 3 15 T 1 1 1 0 0 3 P 0 0 0 0 0 0 C 4 4 4 3 3 18

Semester III Course Code E-3 E-4 E-5 E-6 CH2047 CH2049 Total Course Title Elective - 3 Elective - 4 Elective - 5 Elective - 6 Seminar Project Work Phase - I L 3 3 3 3 0 0 12 T 0 0 0 0 0 0 0 P 0 0 0 0 1 12 13 C 3 3 3 3 1 6 19

Semester IV Course Course Title L T P Code CH2050 Project Work Phase - II 0 0 32 Total 0 0 32 Total credits to be earned for the award of M.Tech degree : Elective Courses Course Code CH2101 CH2102 CH2103 CH2104 CH2105 CH2106 CH2107 CH2108 CH2109 CH2110 CH2111 CH2112 CH2113 CH2114 CH2115 Course Title Air Pollution Control and Waste Water Treatment Solvent Extraction Engineering Electrochemical Process Engineering Modern Separation Process Industrial safety and Hazard Analysis Process Plant Simulation Applied Statistics for Engineers Optimization of Chemical Processes Industrial Catalysis Energy Conservation Engineering Introduction to Bioprocess Engineering Waste Water Treatment - Physical Unit Operation & Chemical Unit Processes Waste Water Treatment - Biological Processes Biofuels Ionic Liquids Supportive Courses Course Code MA2001 Course Title L T P 0 L 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 T 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 P 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0

C 16 16 71

C 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3

C 3

Applied Mathematics for Chemical 3 0 Engineers CONTACT HOUR/CREDIT: L: Lecture Hours per week T: Tutorial Hours per week P: Practical Hours per week C: Credit

SEMESTER I

Course Code CH2001

Course Title TRANSPORT PHENOMENA Total Contact Hours - 60

L 3

T 1

P 0

C 4

PURPOSE This course enables the students to apply scientific principles to concrete situations. INSTRUCTIONAL OBJECTIVES 1. Fluid flow. 2. Turbulence. 3. Flow past immersed bodies 4. Heat transfer in laminar and turbulent flow. 5. Theories of diffusion. UNIT I - Fluid flow (12 hours) Physical properties of fluids, forces on fluids, buoyancy, hydrostatic equation for compressible fluids. Laws of viscosity, types of fluid motion, flow through pipes, Bernoullis theorem, conservation of mass and momentum, head loss in fittings, solution of pipes flow problems. Creeping flow. UNIT II - Turbulence (12 hours) Applications of Differential equations of change-Navier-stokes equations for simple cases. Stream and potential function. Nature and intensity of turbulence-Universal velocity distribution. Flow through rough pipes. Boundary layer flow solution for laminar and turbulent flows. UNIT III - Flow past immersed bodies (12 hours) Flow past immersed bodies. Friction factor, Fluid-fluid systems-Flow patterns in vertical and horizontal pipes, Formation of bubbles and drops and their size distribution, Soild-fluid systems - forces acting on stagnant and moving soilds. Fluidised bed, Soild Fluid conveying, Settling and Sedimentation, Flow through porous medium-capillary tube model and its applications for packed bed and filters, Application of dimensional analysis in fluid dynamics.

UNIT IV - Heat transfer in laminar and turbulent flow (12 hours) Thermal conductivity; steady and unsteady state heat conduction in one dimensional system. Convective heat transfer coefficients. Heat transfer with laminar flow over a flat wall and through pipes. Heat transfer with turbulent flow. Analogies between momentum, heat and mass transfer. Condensation and boiling heat transfer. UNIT V - Theories of diffusion (12 hours) Theories of diffusion in gases and liquid mass and molar fluxes. Film theory, Penetration theory, Boundary layer theory .Component mass balances. Convective mass transfer coefficients. Mass transfer with laminar flow over a flat wall. Mass transfer with turbulent flow over a flat wall. Fixed bed catalytic reactor, Macroscopic balances to solve steady and unsteady problems. REFERENCES 1. 2. 3. 4. Byron R.Bird, Warren E. Stewart and Edwin N. Lightfoot, Transport Phenomena, 2nd edition, John Wiley & Sons, New York, 2002. Sissom L.E. and.Pitts D.R, Elements of Transport Phenomena, McGraw Hill, New York, 1972. Brodkey R.S. and Hershey H.C., Transport Phenomena - A United Approach, McGraw Hill, 1988. Welty J.R.,Wicks C.E., Wilson R.E. and Rorer G.L, Fundamentals of momentum, heat and mass transfer, 5th edition, John Wiley & sons, New York 2007. Course Title COMPUTER AIDED PROCESS PLANT DESIGN Total Contact Hours - 90 L 3 T 0 P 3 C 4

Course Code CH2002

PURPOSE This course helps the students to understand the design of a chemical plant using a computer with available commercial software packages. INSTRUCTIONAL OBJECTIVES 1. The use of spread sheets in estimation of physical properties. 2. The fundamentals of computer aided design of chemical engineering equipments. 3. The basics of Mass and energy balance computations using spread sheets. 4. The concepts of steady and dynamic simulations.

5.

The applications of AUTOCAD to draw the chemical engineering equipments.

UNIT I INTRODUCTION (9 hours) Introduction to flow sheet synthesis, basic steps in flow sheet synthesis, Decomposition strategies for process synthesis. A case study for Synthesis of an ethyl alcohol process. UNIT II - ESTIMATION OF PHYSICAL PROPERTIES ( 9 hours) Physical properties of compounds, Thermodynamic properties of gases and binary mixtures, Viscosity, Vapor pressure, Latent heat, Bubble point and dew point calculation, Phase equilibrium, Vapor-Liquid equilibrium, Liquid phase activity coefficients, K-Values, Liquid-Liquid equilibrium, Gas solutions. UNIT III - APPLICATION OF SPREAD SHEETS (9 hours) Spreadsheets and its role in process calculation, Material balance and energy balance computation-using spreadsheets. Application in Density, Specific Gravity, Molecular Weight, Empirical and Molecular Formula Calculations, Gas laws, Vapor pressure, Partial pressure, Viscosity. UNIT IV -COMPUTER AIDED DESIGN OF EQUIPMENTS ( 9 hours) Computer aided design of Reactors, Evaporators, and Adsorption columns, Distillation columns (Specific attention to multi components systems) Heat Exchangers. UNIT V-STEADY AND UNSTEADY STATE SIMULATION (9 hours) Dynamic simulation of stirred tanks system with heating, multi component systems, Reactors and distillation columns, Application of orthogonal collocation and weighted residuals techniques in heat and mass transfer systems. Introduction to commercial software for steady and dynamic simulation of Chemical Engineering systems such as ChemCAD and Aspen Plus. REFERENCES 1. Richard Turton; Richard C. Bailie; Wallace B. Whiting; Joseph A. Shaeiwitz, Analysis, Synthesis, and Design of Chemical Processes, 3rd Edition, Prentice Hall, 2008. Robin Smith, Chemical Process Design, Mc Graw Hill International Editions, 1995.

2.

3. 4. 5. 6.

Remirez W.F., Computational methods for Process Simulations, Butterworths, New York, 1989. Himmelblau D.M., Basic Principles and Calculations in Chemical Engineering, 8th Edition, Prentice Hall International, 2012. Rajaraman V., Fundamentals of Computers, Prentice Hall, 1996. Sinnott R.K., Chemical Engineering, Vol. 6, Pergamon Press, New York, 1989. (45 hours)

LIST OF EXPERIMENTS 1. 2. 3. 4. 5.

Computer Aided Drawing of Flanged Joints, Pipe Fittings Computer Aided Drawing of Gland and Stuffing box Computer Aided Drawing of Agitator Blades Computer Aided Drawing of Heating/Cooling Coils and Jackets Computer Aided Drawing of Storage Tanks for Volatile and non volatile liquids 6. Computer Aided Drawing of Reaction Vessels 7. Computer Aided Drawing of Shell and Tube Heat Exchangers 8. Computer Aided Drawing of Evaporators 9. Computer Aided Drawing of packed and plate column for the Mass Transfer Operations 10. Simulation of Batch Reactor 11. Simulation of Isothermal constant hold up CSTR 12. Simulation of Ideal Binary Distillation Column REFERENCE Laboratory Manual

Course Code CH2003

Course Title ADVANCED CHEMICAL REACTION ENGINEERING Total Contact Hours - 60

L 3

T 1

P 0

C 4

PURPOSE The objective of this subject is to be familiar with the non-ideal reactors and heterogeneous reactions and to apply this knowledge to solve the problems in chemical reaction engineering. INSTRUCTIONAL OBJECTIVES To familiarize the non-ideal flow patterns in chemical reaction 1. engineering problems. 2. To understand the suspended solid catalysed reactions. 3. To understand the kinetics of fluid-fluid reactions. UNIT I - NON-IDEAL REACTORS (12 hours) Basics of non-ideal flow Zero parameter models (Segregation model and Maximum mixedness model One parameter models (the tanks in series model and dispersion model). UNIT II - HETEROGENEOUS CATALYTIC REACTIONS (12 hours) Mechanism of solid catalysed reactions rate controlling steps, Langmuir Hinshelwood model, Rideal Eiley mechanism, Physical adsorption, chemisorptions isotherms. UNIT III - REACTORS WITH SUSPENDED SOLID CATALYST, FLUIDIZED REACTOR OF VARIOUS TYPES (12 hours) Fluidized reactors of various types: Background information the bubbling fluidized bed (BFB) the K-L model for BFB the circulating fluidized bed (CFD) the jet impact reactor. UNIT IV - G/L REACTIONS ON SOLID CATALYSTS (12 hours) Trickle beds, slurry reactors, three-phase fluidized beds the general rate equation performance equations for an excess of B performance equations for an excess of A Applications. UNIT V - KINETICS OF FLUID-FLUID REACTIONS (12 hours) Gas absorption systems with chemical reaction, Rate equation for straight mass transfer, Rate equation for mass transfer and reaction, Review of the role of Hatta number, Clues to the kinetic regime from solubility data. REFERENCES

1. 2. 3.

Octave Levenspiel, Chemical Reaction Engineering, 3rd Edn., John Wiley & Sons, Singapore, 1999. Scott H. Fogler, Elements of Chemical Reaction Engineering, 2nd Edn.,Prentice Hall of India, New Delhi,1995. Smith J.M., Chemical Engineering Kinetics, 3rd Edn., McGraw Hill International Editions, New Delhi,1981.

SEMESTER II Course Code CH2004 Course Title ADVANCED HEAT TRANSFER Total Contact Hours - 60 L 3 T 1 P 0 C 4

PURPOSE To provide an adequate knowledge on unsteady state heat transfer operations and the heat-transfer methods & equipments currently used in chemical industries. To provide the student with general techniques to formulate, model and mathematically solve advanced heat transfer problems INSTRUCTIONAL OBJECTIVES 1. To impart knowledge on steady and unsteady state heat transfer operations. 2. To impart knowledge on various aspects of convective heat transfer operations. 3. To impart knowledge on the steps involved in the design of compact heat exchangers. 4. To impart knowledge on special topics in heat transfer operation that are representative of real world engineering problems. UNIT I STEADY AND UNSTEADY STATE HEAT CONDUCTION (12 hours) Steady and unsteady state heat conduction - Unsteady state heating and cooling of solid objects - Transient heat conduction - Extended surfaces and fins. UNIT II CONVECTIVE HEAT TRANSFER (12 hours) Convection heat transfer coefficient - Dimensional analysis in convection heat transfer - Heat transfer during laminar and turbulent flow in closed conduits - Empirical correlations. UNIT III HEAT EXCHANGE EQUIPMENT (12 hours) Design of compact heat exchangers - Design and selection of insulation. UNIT IV BOILING AND CONDENSATION (12 hours) Boiling and condensation heat transfer - Effect of turbulence and high vapor velocity on film wise condensation - Heat transfer in liquid metals.

UNIT V SPECIAL TOPICS IN HEAT TRANSFER (12 hours) Heat transfer in magneto fluid dynamic systems - Transpiration cooling Ablation heat transfer in liquid metals - Heat transfer in fluidized beds - Heat transfer processes in nuclear reactors. REFERENCES 1. Warren L. McCabe, Julian C. Smith and Peter Harriott, Unit Operations of Chemical Engineering, 7th ed., McGraw Hill International Edition, NewYork 2005. Holman J.P., Heat Transfer , 9th ed., Tata McGraw Hill Book Co., New Delhi, 2008. Coulson J.M., Richardson J.F., Backhurst J.R. and Harker J.H., Coulson & Richardsons Chemical Engineering, Vol. I, 6th ed., Butterworth Heinemann, Oxford, 2009. Donald Q. Kern, Process Heat Transfer, Tata McGraw Hill Book Co., New Delhi, 2008. Course Title ADVANCED PROCESS DYNAMICS AND CONTROL Total Contact Hours - 60 L 3 T 1 P 0 C 4

2. 3.

4.

Course Code CH2005

PURPOSE This course makes the students to understand the dynamics of fluid flow mass transfer systems, and Latest control methods used in chemical industries. INSTRUCTIONAL OBJECTIVES 1. Basic concepts of process dynamics and control. 2. The design of feedback control systems. 3. Various kinds of advanced control systems. 4. Dynamics and control of fluid flow, and heat transfer systems. 5. Dynamics and control of mass transfer systems. UNIT I Introduction (12 hours) Distinctive characteristics of dynamics of chemical process and systems; process control objectives and strategies.Review of first and higher order systems.

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UNIT II Feedback control systems (12 hours) Closed and open loop response. Response to step, impulse and sinusoidal disturbances. Types of control valves, Design of valves. Transient response. Block diagrams. UNIT III Advanced control systems (12 hours) Frequency response, Design of feedback control systems, Zigler-Nicholas and Cohen-coon tuning methods, Bode-Nyquist plot-Process modeling. UNIT IV Control of fluid flow, and heat transfer systems (12 hours) Ratio control, cascade control, adaptive control, feed forward control, valve position control, computed variable control, over ride control, split range control. UNIT V Control of mass transfer systems (12 hours) Dynamics and control of fluid flow systems, pressure and level systems, blending systems, heat transfer systems. Dynamics and control of mass transfer systems, distillation units and chemical reactors. Overall process control. REFERENCES 1. 2. 3. 4. Stephenopoulous G Chemical process control: an introduction to theory and practice1stEdn. Prentice Hall, New Delhi, 1998. Coughanour D.R., Process System Analysis and Control, 2nd Edn. McGraw Hill, New York, 1991. Buckley P.S., Techniques of Process Control, Wiley, Newyork, 1964. Douglas, J.M., "Chemical Process Dynamics and Control", PrenticeHall, Englewood Cliffs, Cliffs, N.J., (1972).

Course Code CH2006

Course Title MULTI COMPONENT DISTILLATION & REACTOR DESIGN Total Contact Hours - 60

L 3

T 1

P 0

C 4

PURPOSE To provide an adequate knowledge on various aspects involved in the design of multicomponent distillation units and chemical reactors.

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INSTRUCTIONAL OBJECTIVES 1. To impart knowledge on the design of multicomponent distillation units. 2. To impart knowledge on the design of heterogeneous reactors. 3. To impart knowledge on the design of reactors for non-catalytic systems. 4. To impart knowledge on the design of adiabatic packed bed catalytic reactor. UNIT I MULTICOMPONENT DISTILLATION (12 hours) Theory of multicomponent distillation - Design of multicomponent distillation units. UNIT II HETEROGENEOUS SOLID-CATALYSED REACTIONS (12 hours) Design of reactors for heterogeneous solid-catalysed reactions. UNIT III FLUID FLUID NON - CATALYTIC SYSTEMS (12 hours) Design of reactors for fluid fluid non - catalytic systems. UNIT IV FLUID - PARTICLE NON - CATALYTIC SYSTEMS (12 hours) Design of reactors for fluid - particle non - catalytic systems. UNIT V CATALYTIC REACTOR AND DEACTIVATING CATALYST (12 hours) Design of adiabatic packed bed catalytic reactor (single & two) - Design of reactors for deactivating catalysts. REFERENCES 1. 2. 3. 4. Octave Levenspiel, Chemical Reaction Engineering,3rd ed., Wiley India Pvt Ltd, 2006. Scott H. Fogler, Elements of Chemical Reaction Engineering,4th ed., Prentice Hall of India, New Delhi,2005. Robert E. Treybal, Mass Transfer Operations, 3rd Edn., Tata McGraw Hill Book Co., 2012. Smith J.M., Chemical Engineering Kinetics, 3rd ed., McGraw Hill International Editions, New Delhi, 1981.

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SEMESTER III Course Course Title L T Code CH2047 SEMINAR 0 0 PURPOSE To train the students in preparing and presenting technical topics. P 1 C 1

INSTRUCTIONAL OBJECTIVE The student shall be capable of identifying topics of interest related to the program of study and prepare and make presentation before an enlightened audience. The students are expected to give at least two presentations on their topics of interest which will be assessed by a committee constituted for this purpose. This course is mandatory and a student has to pass the course to become eligible for the award of degree. Marks will be awarded out of 100 and appropriate grades assigned as per the regulations Course Course Title L T Code CH2049 PROJECT WORK PHASE I (III semester) 0 0 CH2050 PROJECT WORK PHASE II (IV semester) 0 0 PURPOSE To undertake research in an area related to the program of study P 12 32 C 6 16

INSTRUCTIONAL OBJECTIVE The student shall be capable of identifying a problem related to the program of study and carry out wholesome research on it leading to findings which will facilitate development of a new/improved product, process for the benefit of the society. M.Tech projects should be socially relevant and research oriented ones. Each student is expected to do an individual project. The project work is carried out in two phases Phase I in III semester and Phase II in IV semester. Phase II of the project work shall be in continuation of Phase I only. At the completion of a project the student will submit a project report, which will be evaluated (end semester assessment) by duly appointed examiner(s). This evaluation will be based on the project report and a viva voce examination on

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the project. The method of assessment for both Phase I and Phase II is shown in the following table:

Tool Weightage I review 10% II review 15% III review 35% End semester Final viva voce 40% examination Student will be allowed to appear in the final viva voce examination only if he / she has submitted his / her project work in the form of paper for presentation / publication in a conference / journal and produced the proof of acknowledgement of receipt of paper from the organizers / publishers.

Assessment In- semester

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PROGRAM ELECTIVES Course Code CH2101 Course Title AIR POLLUTION CONTROL AND WASTE WATER TREATMENT Total Contact Hours - 45 L 3 T 0 P 0 C 3

PURPOSE This course makes the students knowledgeable in various safety methods used to control air pollution in chemical industries. Also explains industrials waste water treatment methods. INSTRUCTIONAL OBJECTIVES 1. Method of control of particulates. 2. Method of control of specific gaseous pollutants. 3. Various aspects of water pollutants. 4. Methods of industrial waste water treatment. 5. Advanced methods of waste water treatment. UNIT I Control of particulates (9 hours) Sources and types of pollutants. Control of particulates: filters, gravitational, centrifugal- multiple type cyclones, prediction of collection efficiency, pressure drop, wet collectors, electrostatic precipitation theory- particle charging- particle collection- ESP design procedure. UNIT II Control of gaseous pollutants. (9 hours) Cleaning of gaseous effluents- control of sulphur di oxide emission by various methods- control of nitrogen oxides in combustion products- control of release of carbon monoxide and hydrocarbons to atmosphere. UNIT III Water pollutants (9 hours) Sources and classification of water pollutants- wastewater sampling and analysis. BOD, COD of wastewater and its reduction- fundamentals of anaerobic digestion and aerobic digestion. UNIT IV Industrial waste water treatment (9 hours) Physical unit operations: screening flow equalization, sedimentation. Chemical unit processes: chemical precipitation disinfection , colour removal by adsorption. Biological unit processes: suspended and attached growth processes- aerobic and anaerobic. UNIT V Advanced waste water treatment (9 hours)

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Chemical oxidation- ozonation- photocatalysis- wet air oxidation evaporation- ion exchange- membrane technologies- nutrient removal. REFERENCES 1. 2. 3. Noel de Nevers, Air Pollution control Engg , McGraw Hill, New York, 1995. Eckenfelder W.W., Industrial Water Pollution Control, McGraw Hill, 1999. Arceivala S.J., Waste Water Ttreatment for Pollution Control, Tata McGraw Hill, 1998. Course Title SOLVENT EXTRACTION ENGINEERING Total Contact Hours - 45 L 3 T 0 P 0 C 3

Course Code CH2102

PURPOSE This course helps the students to understand the basic principles involved in the solvent extraction operation and the steps involved in the design of an extractor. INSTRUCTIONAL OBJECTIVES 1. Binary and Ternary liquid equilibrium. 2. Prediction methods of activity coefficients and mass transfer Coefficients. 3. Equilibrium stage wise operation. 4. Characteristics of dispersion. 5. Steps involved in the design of an extractor. UNIT I Liquid equilibrium (9 hours) Binary and ternary liquid equilibrium, Tie-Lines, Critical solution temperature, tie line correlations, contour/prism diagrams UNIT II Activity coefficients (9 hours) Binary/ternary prediction methods of activity coefficient, theory and prediction of diffusion in liquids, theory of inter phase mass transport, estimation and prediction of mass transport coefficients. UNIT III Equilibrium stage wise operation (9 hours) Equilibrium stage-wise contact, single and multiple contacts with co-current and counter-current flow of phases of immiscible and partially miscible

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solvent phases, calculation methods, fractional extraction, extraction with reflux of raffinate and extract. UNIT IV Dispersion (9 hours) Characteristics of dispersion involving single and multiple nozzle distributors, drop size and formation and coalescence, mean drop size at dispersions and their settling velocities/relative characteristics velocities. Effect of drop oscillation, wobbling and internal circulation, effect of surfactive agents, prediction of drop size and characteristic velocity in spray, packed and mechanically agitated contractors as in RDC, pulsed columns. . UNIT V Design of an extractor (9 hours) Design of extractor height and diameter, prediction of flow capacities in terms of flooding rates, regime of operating envelopes, hydrodynamic design variables such as holdup, characteristic velocity, pressure drop, effect of direction of solute transfer of these variables and their prediction methods, correction of mass transfer data. Axial mixing correction for column height, interfacial area estimations using slow, fast and instantaneous reactions and their application with models for mass transfer coefficients. REFERENCES 1. 2. Laddha G.S. and Degaleesan T.E., Transport Phenomena in Liquid Extraction, Tata McGraw Hill Publishing co., Ltd., New Delhi, 1976. Hanson C., Recent Advances in Liquid Extraction, Pergamon Press, London, 1972. Course Title Electrochemical Process Engineering Total Contact Hours 45 L 3 T 0 P 0 C 3

Course Code CH2103

PURPOSE This course helps the students to understand the basic principles involved in electrochemical processes and electrolytic reactor design. INSTRUCTIONAL OBJECTIVES 1. The basics of electrochemical processes. 2. To familiarize various reaction models. 3. To familiarize reactor models. 4. To familiarize scale up of electrolytic reactors. 5. To give an account of cost estimation and profit appraisal.

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UNIT I Introduction (9 hours) The industrial importance of electrolytic processes. Aspects of mass and heat transfer and Energetic of electrolytic cell systems. Mass transfer in two phase flow. Obtaining numerical value of small Kl by calculation and by experiment. Turbulent flow promoters, inner and electro active promoters. UNIT II Reaction models (9 hours) Rate processes and reaction models. Steps in an electrode process, charged transferred, activation or kinetic control, diffusion or mass transfer control. General consideration for reaction modeling. Methods of obtaining model constants. Ohmic correction to the electrode potential and methods of determining the ohmic correction. UNIT III Reactor models (9 hours) Modeling of batch and continuous reactor. Electrolytic reactor design, reactors classification based on engineering principles and based on chemical mode of operation. General purpose flow electrolyzer. Electrolytic reactor selection. UNIT IV Electrolytic reactors (9 hours) Scale up of electrolytic reactors, scale up procedures, design scheme for scale up of electrochemical reactors, effect of scale up on reactor performance, scale up methods and similarity, current distribution and electrical similarity, effect of scale up on mass transfer, effect of scale up on current distribution, multiple electrode module. UNIT V Economics of Electrochemical system (9 hours) Costing procedure, capital and capital related costs, production and production related cost, three design cost estimates, profitability criteria for optimization. Interaction between an electrochemical reactor and associated unit processes. Cost specific to electrolytic processes. REFERENCE 1. Goodridge F. and Scott K., Electrochemical Process Engineering, Plenum Press, New York, 1995.

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Course Code CH2104

Course Title MODERN SEPARATION PROCESS Total Contact Hours - 45

L 3

T 0

P 0

C 3

PURPOSE This course makes the students knowledgeable in the novel methods of separating substances in chemical industries. INSTRUCTIONAL OBJECTIVES 1. The general aspects of modern separation processes. 2. Membrane separation process. 3. Adsorption separation process. 4. Ionic separation process. 5. Some of the less conventional techniques. UNIT I Introduction (9 hours) Review of conventional processes, recent advances in separation techniques based on size, surface properties and other special characteristics of substances. Process concept, theory and equipment used in cross flow filtration, cross flow electrification, dual functional filter, surface based solidliquid separations involving a second liquid, sirofloc filter. UNIT II Membrane separation process (9 hours) Types and choice of membranes, their merits, commercial, pilot plant and laboratory membrane permeators, dialysis, reverse osmosis, ultrafiltration and economics of membrane operations. UNIT III Adsorption (9 hours) Seperation by adsorption techniques: Types and choice of adsorbents, normal adsorption techniques, chromatographic techniques, equipment and commercial processes, recent advances and economics. UNIT IV Ionic separation (9 hours) Controlling factors- applications- equipments for electrophoresis, dielectrophoresis, Ion-exchange chromatography and electro dialysiscommercial process. UNIT V Non conventional techniques (9 hours) Zone melting, thermal diffusion, sweep diffusion. Adductive crystallization. REFERENCES

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1. 2. 3. 4. 5. 6.

Schoen H.M., New Chemical Engineering Separation Techniques Interscience, New York, 1962. King C.J., Separation processes, Tata McGraw Hill, New Delhi, 1978. Lacey R.E. and Loeb S., Industrial processing with membranes, Wiley, Interscience, New York, 1972. Ronald W. Roussel, Handbook of Separation Process Technology, John Wiley, New York, 1987. Perry R.H. Green D.W. et.al., Perrys Chemical Engineers Handbook, 7th Edn., McGraw Hill, New York,1997. Pratt H.R.C., Counter- Current Separation Process, Elsevier, Amsterdam, 1967. Course Title INDUSTRIAL SAFETY AND HAZARD ANALYSIS Total Contact Hours - 45 L 3 T 0 P 0 C 3

Course Code CH2105

PURPOSE This course makes the students knowledgeable in various safety methods adopted in chemical industries. Also gives introduction to hazard analysis. INSTRUCTIONAL OBJECTIVES 1. To familiarize the concepts of industrial safety and techniques.. 2. To familiarize hazards of chemical process plants. 3. To familiarize various aspect of safety measures to be incorporated. during process and plant design. 4. To familiarize the various industrial accidents and fire safety. 5. To explain hazard analysis techniques. UNIT I - CONCEPTS AND TECHNIQUES (9 hours) Evolution of modern Work place safety concept Fundamentals of safe working - Safety Management functions - Safety Organization Committee Budgeting- Industrial recall technique (IRT) disaster control safety survey - Fundamentals of safe working. Safety Communication - education and training.

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UNIT II - CHEMICAL HAZARDS AND INDUSTRIAL SAFETY (9 hours) Chemical hazards and safety of workers Recognition Evaluation and Control methods of Chemical hazards, Hazards of commercial chemical reactions and operations of chemical plants Case studies. Storage and Transportation of hazardous chemicals, Effect of toxic agents. Flammable materials. UNIT III - SAFETY IN CHEMICAL PROCESS AND PLANT DESIGN (9 hours) Safety measures to be incorporated during process design, Safety in pressure system. Instrumentation for safe operations, Safety considerations during site selection- Plant layout and development Plant operations Inspection Plant Maintenance, Modification and Emergency preparedness Onsite and Offsite plan APELL. UNIT IV - INDUSTRIAL ACCIDENTS AND FIRE SAFETY (9 hours) Industrial Accidents Principle prevention - Theories Costs - Root cause - investigation analysis and reporting Case studies Safety performance monitoring - Protective equipment for personnel Respiratory, skin, eyes hazards and protection, Fire fighting system and prevention Explosion protection system. UNIT V - HAZARD IDENTIFICATION TECHNIQUE (9 hours) Risk Assessment Job Safety Analysis - FMEA- Hazard and Operability study - Event tree and fault tree analysis, Frequency analysis- Accident Consequence analysis Human error analysis- Computer aided instruments Safety Audit - Case studies. REFERENCES 1. 2. Faweett & Wood W.S., Safety and Accident Prevention in Chemical Operation, 2nd Edn. Wiley Interscience, 1982. Loss Prevention and Safety Promotion in Chemical Process Industries, Vol. III, Published by Institution of Chemical Engineers, U.K., 1983. M.H. Fulekar Industrial Hygiene and Chemical Safety, I.K International Publishing house Pvt. Ltd., 2006. Yoshida T., Safety of Reactive Chemicals, Vol. I, Elsevier, U.K., 1987.

3. 4.

21

5.

6.

Quantitative Risk Assessment in Chemical Process Industries American Institute of Chemical, Centre for Chemical Process safety William Handley, Industrial Safety Handbook 2nd Edn. McGraw Hill, New York, 1968. Daniel A. Crowl & Joseph F. Louvar Chemical Process safety: fundamentals with applications, Prentice Hall International Series. Course Title PROCESS PLANT SIMULATION Total Contact Hours - 45 L 3 T 0 P 0 C 3

Course Code CH2106

PURPOSE To provide the fundamentals of process synthesis, analysis and optimization which helps to design an optimal process plant. INSTRUCTIONAL OBJECTIVES 1. To introduce the basics of process synthesis, analysis and optimization. 2. To understand the importance of model formulation principles for chemical engineering systems. 3. To realize the significance of mathematical techniques for finding solutions to chemical engineering systems. UNIT I - INTRODUCTION (9 hours) An overview of Process synthesis Process analysis Modeling aspects Optimization. UNIT II - MATHEMATICAL MODELING (9 hours) Classification of Mathematical Models - Independent, Dependant variables and Parameters Classification based on variation of independent, state of the process and types of the process Boundary conditions, Black box principles Artificial Neural Networks. UNIT III - MODELING CHEMICAL ENGINEERING SYSTEMS (9 hours) Models in Mass Transfer and Fluid flow operations, Models in Reaction Engineering Batch, Continuous and Tubular reactors. UNIT IV - PROCESS OPTIMIZATION (9 hours) Types of optimization static and dynamic optimization, Methods of optimization Analytical methods and optimization.

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UNIT V - SIMULATION APPROACHES (9 hours) Modular approaches to process simulation, equation-solving approach Ordering of equations, disjointing and tearing a system of equations. REFERENCES 1. 2. 3. Babu, B. V., Process Plant Simulation, Oxford University Press, 2004. Luyben, W. L. Process Modelling, Simulation and Control for Chemical Engineers, 2nd Edition, McGraw Hill, New York. 1990. Mickely, H. S., Sherwood, T. S., and Reed, C. E., Applied Mathematics in Chemical Engineering, 2nd Edition, Tata McGraw Hill, New Delhi, 1979. Course Title APPLIED STATISTICS FOR ENGINEERS Total Contact Hours - 45 L 3 T 0 P 0 C 3

Course Code CH2107

PURPOSE This course helps the students to understand modern statistical methodology and data analysis. INSTRUCTIONAL OBJECTIVES 1. To train the students in the analysis of experimental data using statistical tools. UNIT I DATA DISTRIBUTION (9 hours) Data distributions Populations, Samples and Processes Visual displays for univariate data Describing distributions Normal distribution Other continuous distributions - Several useful discrete distributions. Numerical summary measures Measures of center Measures of variability More detailed summary quantities Quantile plots Bivariate and Multivariate data and distributions Scatter plot - Correlation fitting Fitting a line to Bivariate data Nonlinear relationships Using more than one predictor. Join distributions. Obtaining data Operational definitions Data from sampling - Data from experiments Measurement systems. UNIT II SAMPLING DISTRIBUTION (9 hours) Probability and Sampling distributions Chance Experiments Probability Concepts Conditional probability and Independence Random variables Sampling Distributions Describing sampling distributions.

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UNIT III STATISTICAL INTERVALS (9 hours) Estimation and Statistical intervals Point estimation Large sample confidence intervals for a population mean More large sample confidence intervals Small sample intervals based on a normal population distribution Intervals for 1 - 2 based on normal; population distributions. UNIT IV STATISTICAL HYPOTHESIS (9 hours) Testing statistical hypothesis Hypothesis and test procedures Tests concerning hypothesis about means and categorical population Testing the form of distribution. Analysis of Variance Terminology and Concepts Single factor ANOVA Interpreting ANOVA results Randomized block experiments. UNIT V EXPERIMENTAL DESIGN (9 hours) Experimental Design Terminology and Concepts Two factor designs Multi factor designs 2 k designs Fractional factorial designs. Inferential methods in Regression and Correlation - Regression Models involving a single independent variable Inferences about the slope coefficient Inferences based on estimated regression lines Multiple regression models Inferences in multiple regressions. REFERENCES 1. 2. Montgomery, D. C., Design and Analysis of Experiments.7th Edition,Wiley, New York 2009. Daniel, C., Applications of Statistics to Industrial Experimentation, Wiley, New York 1976. Course Title OPTIMIZATION OF CHEMICAL PROCESSES Total Contact Hours - 45 L 3 T 0 P 0 C 3

Course Code CH2108

PURPOSE This course makes the students knowledgeable in different optimization methods employed, while solving chemical engineering problems. INSTRUCTIONAL OBJECTIVES 1. Engineering application of optimization. 2. Basic concepts of optimization. 3. Optimization of unconstrained functions.

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4. 5.

Unconstrained multivariable optimization. Applications of optimization in chemical processes.

UNIT I Introduction (9 hours) Engineering application of Optimization-Design variables, Constraints, Objective function, variable bounds. Statement and formulation of an optimization problem. Examples of chemical engineering optimization problems. General procedure for solving Optimization problems. Obstacles of Optimization. UNIT II Objective Fucntions (9 hours) Continuity of functions-Unimodal and Multimodal functions. Convex and concave functions, Convex region. Conditions for an extremum of an unconstrained function. Interpretation of the objective function in terms of its quadratic approximation. UNIT III One-dimensional search (9 hours) One dimensional search- Methods for optimizing a function of one variable, Scanning and Bracketing, Newtons method, Quasi-Newtons method, Secant method of unidimensional search- region elimination methods- polynomial approximation methods. UNIT IV Direct methods (9 hours) Direct methods- Random search, Grid search, Univariate search, Simplex method, Powells method.Indirect methods- First order- Gradient method, Conjugate gradient. Second order- Newtons method, secant method. UNIT V Applications of Optimization (9 hours) Heat transfer and Energy conservation , optimizing recovery of waste heat, Optimum shell and tube heat exchanger design. Optimization of heat exchanger networks- Optimal allocation of temperatures in a sequence of heat exchangers. Optimization of evaporator design-Multi stage evaporator. REFERENCES 1. 2. 3. Edger T.F. and Himmelblau D.M, Optimization of Chemical Processes, McGraw Hill Book Co., New York, 1989. Deb K., Optimization for Engineering design: Algorithms and Examples, Prentice hall, New Delhi, 1996. Ray W.H. and Szekely J., Process Optimization with Application in Metallurgy and Chemical Engineering, Wiley, New 25ork, 1973.

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4. 5.

Rao S.S., Optimization: Theory and Applications, 2nd Edn. Wiley Eastern, New Delhi, 1984. Beveridge G.S. and Schechter R.S., Optimization: Theory and Practice, McGraw Hill, New York, 1969. Course Title INDUSTRIAL CATALYSIS Total Contact Hours - 45 L 3 T 0 P 0 C 3

Course Code CH2109

PURPOSE This course makes the students knowledgeable in basic principles involved in the industrial catalysis operation and the various methods of preparation & regeneration of industrial catalysts. INSTRUCTIONAL OBJECTIVES 1. To provide an introduction to industrial catalysis. 2. To present an account of preparation, evaluation and regeneration of industrial catalysts. 3. To familiarize cracking, regeneration and poisoning of catalyst. UNIT I Introduction (9 hours) Introduction to catalysis general properties of homogeneous and heterogeneous catalysis. UNIT II Catalytic systems (9 hours) Adsorption, reaction kinetic in catalytic systems, geometric and electronic factors in catalysis. UNIT III Industrial Applications (9 hours) Preparation, evaluation, regeneration typical industrial examples and applications. UNIT IV Heterogeneous systems (9 hours) Chemical reaction engineering applied to homogeneous and heterogeneous chemical reaction. UNIT V Regeneration (9 hours) Catalytic cracking and regeneration, catalytic poisoning regeneration and revivifications.

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REFERENCES 1. 2. 3. Smith J.M., Chemical Engineering Kinetics, 3rd edition, McGraw Hill International Editions, New Delhi, 1981. Bond G.C., Heterogeneous Catalysis: Principles and Applications, Calenrendon Press, Oxford, 1974. Thomas L.L., Catalytic Processes & Proven Catalysts, Academic Press, New York, 1970. Course Title ENERGY CONSERVATION ENGINEERING Total Contact Hours - 45 L 3 T 0 P 0 C 3

Course Code CH2110

PURPOSE This course makes the students knowledgeable in energy conservation methods employed in different kinds of equipments and machineries used in industries. INSTRUCTIONAL OBJECTIVES 1. To explain the general principles of energy conservation. 2. To familiarize the concepts of energy conservation in boilers. 3. To understand the energy conservation in pumps and piping systems. 4. To detail in the energy conservation in fans and blowers. 5. To make the students to know the importance of energy conservation in various industries. UNIT I Principles of energy conservation (9 hours) General principles of energy conservation. Energy conservation in boilers: Practical applications of energy conservation, steam balances using the steam turbine, returning the condensate to boilers flashing condensate to lower pressure furnace, efficiency, effect of flue gas and combustion air temperature, reducing flue gas temperature, steam tracing, heat recovery. UNIT II Energy conservation in flow systems (9 hours) Energy conservation in pumps and piping systems: pumps and piping systems gravity feed evaporators. UNIT III Energy conservation in heat and mass transfer equipments (9 hours) Energy conservation in dryers and evaporators: Multiple effects, thermocompression, vapour-recompression systems. Drying convective dryers.

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UNIT IV Energy conservation in process utilities (9 hours) Energy conservation in fans and blowers, incinerators, refuse recycling. UNIT V Applications (9 hours) Energy conservation techniques in process industries: Petroleum and petrochemical industries, sugar and alcohol industries, pulp and paper industries, fertilizer industries, cement plants. REFERENCES 1. 2. 3. 4. 5. Chiogioji .M, Industrial Energy Conversation, McGraw Hill, New York, 1978. Rajan G.G., Optimizing Energy Efficiency In Industry, Tata McGraw Hill Publishing Co., New Delhi, 1997. Veziroglu T.N., Alternative Energy Sources, Vol. V, Elsevier Pub., Amsterdam, 1982. Huo S.D., Hand Book of Industrial Energy Conservation, Van Nostrand Reinhold publishers, New York, 1992. Porter R, and Roberts T., Energy Savings, by waste recycling Elsevier Applied science publications, New York, 1995. Course Title INTRODUCTION TO BIOPROCESS ENGINEERING Total Contact Hours - 45 L 3 T 0 P 0 C 3

Course Code CH2111

PURPOSE This course makes the students knowledgeable in processing of biological materials and processes using biological agents such as enzymes. INSTRUCTIONAL OBJECTIVES 1. To explain basic principles of bio processes and enzyme technology. 2. To familiarize various aspects of bioreactors. 3. To familiarize different types of instruments and controllers used in bioprocess industries. UNIT IINTRODUCTION TO FERMENTATION PROCESS (9 hours) Fermentation: General requirements of fermentation processes- An overview of aerobic and anaerobic fermentation processes and their application in industry- medium requirements of fermentation processes- examples of simple and complex media- sterilization: Thermal death kinetics of micro-

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organisms- Batch and continuous Heat-sterilization of liquid media-filter sterilization of liquid Media and Air. UNIT II ENZYME CATALYST (9 hours) Enzymes: classification and properties- applied enzyme catalysis- Kinetics of enzyme catalytic reactions- metabolic pathways- protein synthesis in cells. UNIT IIIMICROBIAL GROWTH KINETICS (9 hours) Stoichiometry of microbial growth, Substrate utilization and product formation-Batch and continuous culture, fed batch culture. UNIT IV INTRODUCTION TO BIOREACTOR (9 hours) Basic principle of bioreactor, classification and their configurations, analysis of batch, continuous flow, fed-batch bioreactors. UNIT V MONITORING AND CONTROL OF FERMENTAION PARAMETER (9 hours) Measurement of physical and chemical parameters in bioreactors- monitoring and control of dissolved oxygen, pH, impeller speed and temperature in stirred tank fermenter. REFERENCES 1. 2. 3. Shuler, M.L. and Kargi, F. Bioprocess Engineering: Basic Concepts, 2ndEdition, PHI, 2002. Bailey, J.E. and Ollis, D.F. Biochemical Engineering Fundamentals 2nd Edition, McGraw Hill, 1988. Stanbury P., Whitakar A. and Hall S.J., Principles of Fermentation Technology, 2nd Edn. Elsevier Pergamon Press, 1972. Course Title WASTE WATER TREATMENT PHYSICAL UNIT OPERATION & CHEMICAL UNIT PROCESSES Total Contact Hours - 45 L 3 T 0 P 0 C 3

Course Code CH2112

PURPOSE This course makes the students knowledgeable in various physical unit operations and chemical unit processes, employed in wastewater treatment. INSTRUCTIONAL OBJECTIVES 1. the working principles and

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2.

design of various physical and chemical treatment systems for water and waste water.

UNIT I Introduction (9 hours) Overview - Wastewater treatment and future trends, Wastewater reclamation and reuse: Sampling and analytical procedures; Constituents in Wastewater Physical Characteristics, Inorganic non-metallic constituents, metallic constituents, aggregate organic constituents. UNIT II Primary Treatment (9 hours) Screening Classifications of screens, screening characteristics and quantities; coarse solids reduction; Flow equalization Description and applications; Mixing and flocculation Continuous rapid mixing and continuous mixing in wastewater treatment, energy dissipation, time scale mixing: Gravity separation theory particle settling, discrete particle settling, flocculant particle settling and hindered settling. UNIT III Secondary Treatment (9 hours) Sedimentation Description, sedimentation tank performance, characteristics and quantities of sludge and scum; High rate clarification processes: Floatation dissolved air floatation, dispersed air floatation: Oxygen transfer description, evaluation of oxygen transfer coefficient: Aeration system diffused air aeration, mechanical aerators. UNIT IV Chemical Treatment (9 hours) Chemical coagulation fundamentals: Chemical Precipitation for removal of heavy metals & dissolved inorganic substances, precipitation reactions: Chemical oxidation fundamentals, applications, chemical oxidation of BOD, COD and ammonia: Chemical neutralization, scale control and stabilization. UNIT V Advanced Treatment methods (9 hours) Filtration Introduction and description of depth filtration: Surface filtration Discfilter and cloth-media disk filter: Membrane filtration processes terminology, classification, membrane materials, removal mechanism and membrane operation: Adsorption fundamentals of adsorption, types of adsorbents, activated carbon adsorption kinetics, treatment process and activated carbon contactor: Advanced oxidation processes theory, technologies used to produce hydroxyl radicals, applications.

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REFERENCES 1. 2. 3. Metcalf & Eddy, Wastewater Engineering Treatment and Reuse, 4th Edn., Tata McGraw-Hill Publishing Company, New Delhi, 2003. Eckenfelder, W.W..Jr., Industrial Water Pollution Control, 3rd edn., McGraw Hill, Boston, MA, 2000. Eldridge, E.F, Industrial Waste Treatment Practice, McGraw-Hill Book Company, Inc., New York, NY, 1942. Course Title WASTE WATER TREATMENT BIOLOGICAL PROCESSES Total Contact Hours - 45 L 3 T 0 P 0 C 3

Course Code

PURPOSE This course makes the students knowledgeable in various biological processes, employed in wastewater treatment. INSTRUCTIONAL OBJECTIVES 1. on principles and 2. design of various biological treatment units used for wastewater treatment. UNIT I Introduction (9 hours) Role of microorganisms, types of biological processes for wastewater treatment; Microorganisms composition, classification, identification and environmental factors; bacterial growth and energetics; aerobic oxidation and anaerobic fermentation & oxidation Introduction, stoichiometry, growth kinetics. UNIT II Activated sludge process (9 hours) Activated sludge process Introduction, recent process developments; selection and design of physical facilities for activated sludge processes; suspended growth aerated lagoons types; flow through lagoons process design considerations, dual-powered systems; membrane biological reactors process descriptions, membrane fouling control, process capabilities. UNIT III Biological contactors (9 hours) Trickling filters classification, applications, design considerations; rotating biological contactors physical facilities, RBC process design; combined aerobic treatment processes; submerged attached growth processes down flow, up flow, fluidized bed bio reactors.

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UNIT IV Anaerobic processes (9 hours) Anaerobic treatment processes advantages, disadvantages; Design considerations, solids retention time, expected methane production, treatment efficiency, ammonia toxicity, liquids solids separations; Anaerobic suspended growth processes complete mix process, contact process, sequential batch reactor, design; Anaerobic sludge blanket processes UASB, baffled reactor, migrating blanket reactor; Attached growth anaerobic processes Up flow, Down flow, Expanded bed reactor, Fluidized bed reactor; Covered anaerobic lagoon process, Membrane separation process. UNIT V Disinfection (9 hours) Disinfection theory Characteristics, methods, mechanisms, factors; Disinfection Chlorine and its compounds, Ozone, Peracetic acid, UV Radiation; Dechlorination, Design of Chlorination and Dechlorination facilities. REFERENCES 1. 2. 3. Metcalf & Eddy, Wastewater Engineering Treatment and Reuse, 4th Edn., Tata McGraw-Hill Publishing Company, New Delhi, 2003. Eckenfelder, W.W..Jr., Industrial Water Pollution Control, 3rd edn., McGraw Hill, Boston, MA, 2000. Grady, C. P. L. Jr., G. T. Daigger, and H. C. Lim., Biological Wastewater Treatment, 2nd edn., Rev. and Expanded, Marceldekker, New York, 1999. Eldridge, E.F, Industrial Waste Treatment Practice, McGraw-Hill Book Company, Inc., New York, NY, 1942. Course Title BIOFUELS Total Contact Hours - 45 L 3 T 0 P 0 C 3

4.

Course Code CH2114

PURPOSE This course helps the students to know about the various aspects, types and processes involved in production of Biofuels. INSTRUCTIONAL OBJECTIVES 1. To give an introduction and importance to Biofuels. 2. To familiarize various biochemical pathways and strategies involved in Biofuels. 3. To familiarize industrial Biofuel production.

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4. 5.

To familiarize with biorefining and biofuel standards.` To familiarize with global and Indian economics pertaining to Biofuels.

UNIT I - INTRODUCTION TO BIOFUELS (9 hours) Fossil fuels and environmental issues- Introduction to Biofuels and its promises-Various types of Biofuels its classification and applicationsImportance and types of feed stocks, Biomass and raw materials for Biofuels1st 2nd and 3rd generation Biofuels. UNIT II - BIOCHEMICAL STRATEGIES PATHWAYS AND VARIOUS (9 hours)

Different energy harvesting biochemical pathways & their exploitation to Biofuels Fermentation strategies: Aerobic & Anaerobic for Biofuel production with examples-Microbial modelling and Metabolic Engineering for Biofuel production-Algae for oil production. UNIT III - INDUSTRIAL BIOFUEL PRODUCTION (9 hours) Production strategies for various Biofuels: Bioethanol, Biobutanol and other alcohols, Biodiesel, Hydrogen, Methane-Raw material conversion to Biofuels: Pre-treatment methods, Enzymology for biomass utilization, Transesterification and Thermal depolarization-Experiments on biomass Pretreatment: Mass balances and yields-Industrial scale ups, Technology development for Biofuel production. UNIT IV - BIOREFINING AND STANDARDIZATION (9 hours) Inhibitors and detoxification: Impact on biomass conversion-Bio refining of Biofuel residues-Biofuel properties, specifications and guidelines-Biomass fuel cycle methodology-Terminal operations -Boutique fuels. UNIT V - BIOFUEL ECONOMICS (9 hours) Alternate fuels: global & Indian scenario-Feedstock economics, Biofuels demand and supply-Clean air/energy policy act-Environmental assessments Biofuels economics and policy. REFERENCES 1. Sameer A Zogdekar, Biofuels Introduction And Country Experiences, Published By ICFAI University Press., ISBN No. 9788131416051, 2008.

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2.

3.

4.

David Pimentel , Biofuels, Solar And Wind As Renewable Energy Systems, Published By Springer-Verlag., ISBN No. 978-9048179459, 2010. David M Mousdale, Biofuels: Biotechnology, Chemistry And Sustainable Development , Published By Taylor And Francis Group CRC Press., ISBN No.978-1439812075, 2008. Alain A Vartes, Nasib Qureshi, Biomass To Biofuels: Strategies For Global Industries, Published By John Wiley & Sons Ltd., ISBN No. 978-0470513125, 2009. Course Title IONIC LIQUIDS Total Contact Hours - 45 L 3 T 0 P 0 C 3

Course Code CH2115

PURPOSE This course helps the students to know about the various types, properties and synthesis aspects of Ionic liquids. INSTRUCTIONAL OBJECTIVES 1. To give an introduction and applications of Ionic Liquids. 2. To familiarize various synthesis and purification strategies of Ionic Liquids. 3. To familiarize with the physiochemical properties of Ionic Liquids 4. To familiarize with the molecular structures and dynamics of Ionic Liquids. 5. To familiarize with the credentials and ecological impact of Ionic Liqudis. UNIT I - INTRODUCTION, GENERAL PROPERTIES AND APPLICATIONS (9 hours) Definition, History, Synonyms, Cation and Anions inovolved- Molten Salts and Ionic Liquids- General properties- Ionic Liquids as Designer SolventsTask-specific ionic liquids- Industrial Applications- Recent research trends. UNIT II - SYNTHESIS AND PURIFICATION (9 hours) Organic, Inorganic and Polymer Synthesis of various Ionic Liquids-Quality Aspects pertaining to Commercial Ionic Liquids-Commercial Ionic Liquids upgradation- Ionic Liquid Synthesis: Scale up studies-Synthesis of Task specific Ionic Liquids.

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UNIT III - PHYSICOCHEMICAL PROPERTIES (9 hours) Melting Points and Phase Diagrams-Viscosities, Densities-Solubility, Gas solubilities and Solvation in Ionic Liquids-Electrochemical Properties of Ionic Liquids. UNIT IV - MOLECULAR STRUCTURE AND DYNAMICS (9 hours) Order in the Liquid State and Structure-QSPR and Group Contribution Models for Physicochemical Properties-Structure Elucidation-Quantum Mechanical Methods -Molecular Dynamics Simulation-Molecular Reorientational Dynamics. UNIT V - CREDENTIALS OF IONIC LIQUIDS (9 hours) Vapour Pressure, Flammability and Combustibility of Ionic Liquids-Bio catalytic Reactions and their Special Needs-Ecological fate and Toxicity. REFERENCES 1. Peter Wasserscheid, Thomas Welton Wiley-VCH Ionic Liquids in Synthesis (Green Chemistry (Wiley) (2 vol. set); 2 edition , ISBN: 978-3527312399, 2007. An Introduction to ,Ionic Liquids Freemantle , Michael Royal Society of Chemistry , ISBN: 9781847551610, 2009. Mihkel Koel Ionic Liquids in Chemical Analysis (Analytical Chemistry)CRC Press; 1 edition , ISBN: 978-1420046465, (2008). Natalia Plechkova, Robin Rogers, Kenneth Seddon Ionic Liquids: From Knowledge to Application (ACS Symposium Series), Oxford University Press, USA (2010), ISBN: 978-0841269972, 2010. Sanjay Malhotra Ionic Liquid Applications: Pharmaceuticals, Therapeutics, and Biotechnology (ACS Symposium Series), Oxford University Press, USA, ISBN: 978-0841225473, 2010. Marcelle Gaune-Escard, Kenneth R. Seddon Wiley Molten Salts and Ionic Liquids: Never the Twain, , ISBN: 978-0471773924, 2010.

2. 3. 4.

5.

6.

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SUPPORTIVE COURSES Course Code MA2001 Course Title APPLIED MATHEMATICS FOR CHEMICAL ENGINEERS Total Contact Hours - 45 L 3 T 0 P 0 C 3

PURPOSE To impart to the students of Engineering, the rudiments of Mathematics so as to enable them to apply the same for their own branch. INSTRUCTIONAL OBJECTIVES 1. To equip the students of Engineering, the knowledge of Mathematics and its applications so as to enable them to apply them for the branch in which they are admitted. UNIT I Tensor Algebra (9 hours) Tensor Algebra - Metric tensor - Christoffel symbols and covariant differentiation. UNIT II Fourier transform (9 hours) Fourier transforms - Sine and cosine transforms - Finite Fourier transforms Applications to heat conduction problems. UNIT III Calculus of Variations (9 hours) Simple variational problems with fixed boundaries - Euler's equation Conditional extrema - Isoperimetric Problems - Direct methods - Ritz method. UNIT IV Application of Calculus of Variations (9 hours) Applications to ordinary differential equations - Subdomain method Collocation method - Least square method - Galerkin method. UNIT V Bessels function and Legendres equation (9 hours) Bessel's equation - Recurrence formulae for Jn(x) - expansions for J0 and J1 value of J and J- - Generating function for Jn(k) - Orthogonality of Bessel functions; Legendre's equation - Rodrigue's formula - Legendre polynomials - Generating function for Pn(x) - Recurrence formulae for Pn(x) Orthogonality of Legendre polynomials.

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REFERENCES 1. 2. 3. 4. 5. 6. Ramanaiah G., Tensor Analysis, S. Viswanathan & Co. Narayanan T.K., Manicavachagom Pillai and Ramanaiah G., Advanced Mathematics for Engineering Students, S.Viswanathan & Co. Bruce A. Finalyson The method of weighted residuals and variational principles, Academic Press, (Chapter 1 and 2), 1972. Pushpavanam S, Mathematical Methods in Chemical Engineering, Prentice Hall. Grewal B.S., Higher Engineering Mathematics, Khanna Publishers. Venkataraman M.K., Higher Engineering Mathematics, National Publishing Co.

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