CORROSION-RESISTANT ALLOYS

HASTELLOY C-22HS ALLOY

Oil & Gas Applications
Contents
Three Very High Strengths Tensile Impact Toughness Hardness Cold Forming Sour Gas Testing Localized Corrosion Resistance Physical Properties Transverse Tensile Transverse Impact Toughness 90-Day Autoclave Testing 3 4, 5 6 6 6 7 8 8 9 9 9

H-3180

HASTELLOY C-22HS

2010 Haynes International, Inc.

HASTELLOYC-22HS- OIL & GAS APPLICATIONS

The data in this document is believed to be useful for applications in the oil & gas industry, or other industries which may require an alloy with excellent corrosion resistance and strength levels higher than standard HASTELLOYC-22HS alloy. Additional information on C-22HS alloy may be found in the alloy brochure H-2122 on the Haynes International website.

NOMINAL CHEMICAL WEIGHT %

Ni 57a
a

Cr 21
* Maximum

Mo 17

Fe 2*

W 1*

Mn 0.8*

Al 0.5*

Si 0.08*

C 0.01*

B 0.006*

As Balance

AVAILABLE IN THREE VERY HIGH-STRENGTH CONDITIONS

Early testing of C-22HS alloy was focused on material in the annealed + age-hardened condition where the material was annealed at 1975F (1079C) and age-hardened at 1300F (704C)/16h/Furnace cool (FC) to 1125F (607C)/32h/Air-cool (AC.) In this standard condition C-22HS alloy will typically have strengths around 100 ksi (690 MPa). While this strength level is almost double of C-type alloys in the annealed condition, many oil and gas applications require even greater strength. For this reason, a considerable development effort has been generated on C-22HS alloy in three other very high strength conditions:. 1) 2) 3)
A

Cold Worked Cold Worked + Age-HardenedA Low Temperature (LT) AnnealedB + Age-HardenedC
B

1125F (607C)/10h/AC

1850F (1010C)

1300F (704C)/16h/FC to 1125F (607C)/32h/AC

A comparison of yield strengths for the three very high strength conditions is shown below along with that of the annealed and standard conditions.

225 200
Yield Strength (ksi)

1400
Yield Strength (MPa)

175 150 125 100 75 50 25 0

Annealed "Standard" Annealed + AgeHardened Low-Temp Annealed + AgeHardened Cold Worked Cold Worked + AgeHardened

1200 1000 800 600 400 200 0

HASTELLOY C-22HS ALLOY

ROOM TEMPERATURE TENSILE PROPERITES - SHEET Effects of Cold Work Level and Age-Hardening Treatment
200

1200 160
Yield Stress (ksi)

1000

120

800

600 80 Cold Worked Cold Worked + Age-Hardened 40 0 10 20 30 % Cold Work 40 50

400

60 Cold Worked Cold Worked + Age-Hardened

40
% Elongation

20

0 0 10 20 30 % Cold Work 40 50

Age-hardening treatment increases the yield strength, but the amount of increase is less at higher levels of cold work Age-hardening treatment results in lower ductility at low levels of cold work, but increases ductility at higher cold work levels

HASTELLOY C-22HS

Yield Strength (MPa)

AVERAGE ROOM TEMPERATURE TENSILE PROPERTIES - BAR

Yield Strength Material Condition Cold-Worked Cold-Worked + Age-Hardened LT Annealed + Age-Hardened (ksi) 198.0 202.4 117.8 (MPa) 1365 1396 812 Ultimate Tensile Strength (ksi) 203.5 230.7 194.1 (MPa) 1403 1591 1338 Elongation % 16.7 19.9 32.9 R.A % 64.2 48.7 45.7

Cold-worked condition: cold work levels ranged from 43 to 47% Cold-Worked + Age-Hardened condition: cold work levels same as above, age-hardening treatment 1125F (607C)/10h LT Annealed + Age Hardened: anneal- 1850F (1010C), age-hardening- 1300F (704C)/16h/FC to 1125F (607C)/32h/AC

AVERAGE ROOM TEMPERATURE TENSILE PROPERTIES - TUBE

Yield Strength Material Condition Cold-Worked Cold-Worked + Age-Hardened LT Annealed + Age-Hardened (ksi) 187.3 198.7 120.8 (MPa) 1291 1370 833 Ultimate Tensile Strength (ksi) 195.0 222.6 191.3 (MPa) 1345 1535 1319 Elongation % 15.1 19.2 33.4

Cold-worked condition: cold work levels ranged from 52 to 53% Cold-Worked + Age-Hardened condition: cold work levels same as above, age-hardening treatment 1125F (607C)/10h/AC LT Annealed + Age Hardened: anneal- 1850F (1010C), age-hardening- 1300F (704C)/16h/FC to 1125F (607C)/32h/AC

ROOM AND ELEVATED TEMPERTURE TENSILE PROPERTIES 0.5 (12.7mm) Diameter Bar
Temperature Material Condition Cold-Worked Cold-Worked Cold-Worked Cold-Worked + Age-Hardened Cold-Worked + Age-Hardened Cold-Worked + Age-Hardened LT Annealed + Age-Hardened LT Annealed + Age-Hardened LT Annealed + Age-Hardened (F) RT 400 500 RT 400 500 RT 400 500 (C) RT 204 260 RT 204 260 RT 204 260 Yield Strength (ksi) 195.1 181.8 181.0 203.1 185.9 183.1 118.3 104.4 100.4 (MPa) 1345 1254 1248 1400 1282 1262 816 720 692 Ultimate Tensile Strength (ksi) 200.4 182.6 181.1 233.6 208.9 207.3 195.1 178.7 174.4 (MPa) 1382 1259 1249 1611 1440 1429 1345 1232 1202 Elongation % 18.0 14.6 14.1 21.4 20.9 20.9 32.3 38.4 37.2 R.A. % 65.2 63.1 60.8 57.5 58.7 57.5 43.4 53.4 51.2

Cold-worked condition: cold work level of 43% Cold-worked + Age-hardened condition: cold work levels same as above, age-hardening treatment 1125F (607C)/10h/AC LT Annealed + Age Hardened: anneal- 1850F (1010C), age-hardening- 1300F (704C)/16h/FC to 1125F (607C)/32h/AC

HASTELLOY C-22HS

CHARPY IMPACT TESTING 1" (25.4mm) Diameter Bar, 44% Cold-Worked (CW)
LT Anneal + Age-Hardened Temperature RT -75F (-59C) -320F (-196C) (ft-lbf ) 75 67 54 (J) 102 91 73 Cold-Worked (ft-lbf ) 146 153 113 (J) 198 207 153 Cold-Worked + Age-Hardened (ft-lbf ) 124 125 102 (J) 168 169 138

*Average of two tests, all samples were longitudinal

AVERAGE HARDNESS DATA

Form Sheet Plate Bar Tube
A B

Annealed 90 Rb 92 Rb 92 Rb --

"Standard" Annealed B + Age-Hardened 30 Rc 30 Rc 30 Rc --

"LT" Annealed + C Age-Hardened --37 Rc 38 Rc

Cold-Worked --42 Rc 42 Rc

Cold-Worked E + Age-Hardened --46 Rc 47 Rc

Annealed at 1975F (1079C) 1975F (1079C) + 1300F (704C)/16h/FC to 1125F (607C)/32h/AC C 1850F (1010C) + 1300F (704C)/16h/FC to 1125F (607C)/32h/AC D As cold-worked (43 to 47% bar, 52 to 53% tube) E Cold -worked (43 to 47% bar, 52 to 53% tube) + 1125F (607C)/10h/AC

HARDNESS EFFECTS OF COLD WORK & AGE-HARDENING TIME Effects of Cold Work Level and Age-Hardening Treatment (Sheet)
Age-Hardening Time* Hours 0 1 4 10 24 0% <20 <20 <20 <20 <20 10% 29 27 26 35 40 Hardness (Rc) for % Cold Work Level 20% 35 33 33 40 43 30% 37 38 39 41 44 40% 40 41 41 45 48 50% 45 47 48 51 52

*Age-Hardening was performed at 1125F (607C) for the indicated time

COLD-FORMING CHARACTERISTICS
Average Room-Temperature Tensile Properties of Annealed* HASTELLOY C-22HS Alloy
0.2% Yield Strength Form Sheet Plate & Bar *1975F (1079C) anneal (ksi) 63.6 54.4 (MPa) 439 376 Ulitmate Tensile Strength (ksi) 121.4 117.0 (MPa) 837 806 Elongation % 57.3 62.3 R.A. % 77.5

HASTELLOY C-22HS

SOUR GAS TESTING - STANDARD NACE TEST NACE TM0177 Test Levels II and III, Method A, Soultion A, Applied Stress = 100% YS
Material Condition Heat# 1 LT Annealed + Age-Hardened 2 Coupling Coupled to Carbon Steel NOT Coupled to Carbon Steel Coupled to Carbon Steel NOT Coupled to Carbon Steel Coupled to Carbon Steel 3 NOT Coupled to Carbon Steel Coupled to Carbon Steel 1 Cold-Worked 2 NOT Coupled to Carbon Steel Coupled to Carbon Steel NOT Coupled to Carbon Steel Coupled to Carbon Steel 3 NOT Coupled to Carbon Steel Coupled to Carbon Steel 1 Cold-Worked + Age-Hardened 2 NOT Coupled to Carbon Steel Coupled to Carbon Steel NOT Coupled to Carbon Steel Coupled to Carbon Steel 3 *Triplicate Samples NOT Coupled to Carbon Steel Result Pass Pass Pass Pass Pass Pass Pass Pass Pass Pass Pass Pass Pass Pass Pass Pass Pass Pass

SOUR GAS TESTING - SSR TENSILE

Material Condition LT Annealed + Age-Hardened Cold-Worked Cold-Worked + Age-Hardened Envrionment* Air Level VII w/o S Air Level VII w/o S Air Level VII w/o S Time to Failure (h) 26.8 25.5 8.9 8.4 14.4 14.1 Elong. % 38.6 36.7 12.8 12.1 20.7 20.3 R.A. % 54.1 52.8 63.4 63.2 56.8 53.8 Time to Failure Ratio -0.95 -0.95 -0.98 Elong. Ratio -0.95 -0.95 -0.98 R.A Ratio -0.98 -1.00 -0.95 Secondary Cracking -No -No -No

NACE TM0198 Slow Strain Rate Tensile, Level VII, With Elemental Sulfer
Material Condition LT Annealed + Age-Hardened Cold-Worked Cold-Worked + Age-Hardened Envrionment* Air Level VII w/S Air Level VII w/ S Air Level VII w/ S Time to Failure (h) 26.8 25.6 8.9 8.2 14.4 13.6 Elong. % 38.6 36.8 12.8 11.7 20.7 19.6 R.A. % 54.1 54.0 63.4 62.4 56.8 51.2 Time to Failure Ratio -0.95 -0.92 -0.94 Elong. Ratio -0.95 -0.91 -0.95 R.A Ratio -1.00 -0.98 -0.90 Secondary Cracking -No -No -No

HASTELLOY C-22HS ALLOY

LOCALIZED CORROSION RESISTANCE

Critical Crevice and Pitting Temperatures in 6% FeCl3 + 1% HCl
Critical Pitting Temperature Alloy C-22HS (Annealed + Age -Hardened) C-22HS (Annealed) C-22

Critical Crevice Temperature (F) 167 212 176 131 104 77 (C) 75 100 80 55 40 25

(F) 230 >248 >248 >248 212 185

(C) 110 >120 >120 >120 100 85

C-276 625 725 (Annealed + Age-Hardened)

MATERIAL PROPERTIES
Density (Annealed) Density (Age-Hardened) Melting Range 0.311 lb/in3 0.312 lb/in3 2380-2495F 8.60 g/cm3 8.64 g/cm3 1304-1368C

*Age-hardened 1300F (704C)/16h/AC + 1125F (607C)/32h/AC

Physical Properties of HASTELLOY C-22HS Alloy* Standard Units

Thermal Conductivity (Btuin/hft2F) 82 93 107 120 132 147 154 Thermal Diffusivity (ft2/h) 0.129 0.139 0.155 0.167 0.180 0.194 0.200 Electrical Resistivity (microhmsin) 38.4 39.3 41.1 42.8 44.3 45.5 46.0 Mean Coefficient of Thermal Expansion (in/in F) 6.4 6.7 6.9 7.1 7.3 7.4 Dynamic Modulus of Elasticity (Youngs Modulus) (msi) 32.3 31.6 30.5 30.2 29.5 27.6 26.4

Temperature (F) RT 200 400 600 800 1000 1100

Specific Heat (Btu/lbF) 0.098 0.103 0.108 0.112 0.115 0.118 0.120

Physical Properties of HASTELLOY C-22HS Alloy* Metric Units

Thermal Temperature Specific Heat Conductivity (C) RT 100 200 300 400 500 600 (J/kg K) 412 434 451 465 577 488 504 (W/m K) 11.8 13.5 15.4 17.1 18.6 20.5 22.4 Thermal Diffusivity (cm2/s) 0.0344 0.0362 0.0398 0.0427 0.0454 0.0489 0.0517 Electrical Resistivity (ohm cm) 98.0 100 104 108 112 115 117 Mean Coefficient of Thermal Expansion (m/m K) 11.6 12.0 12.4 12.7 13.1 13.3 Dynamic Modulus of Elasticity (Youngs Modulus) (GPa) 223 218 211 209 205 195 181

*Properties are in the standard age-hardened condition unless otherwise noted

HASTELLOY C-22HS

TRANSVERSE TENSILE PROPERTIES-COLD-WORKED BAR Cold-Worked (54%) Bar - 2-3/8" (60mm) Diameter (Longitudinal and Transverse)
Yield Strength Material Condition Temperature RT Orientation Longitudinal Transverse Longitudinal As-Cold-Worked 350 Transverse Longitudinal 450 Transverse Longitudinal RT Cold-Worked + Age-Hardened Transverse Longitudinal 350 Transverse Longitudinal 450 Transverse (ksi) 181.4 156.6 160.2 138.3 156.1 139.0 193.5 168.3 179.8 152.1 173.1 149.7 (MPa) 1251 1080 1105 954 1076 958 1334 1160 1240 1049 1194 1032 Ultimate Tensile Strength Elongation (ksi) 190.5 183.0 166.6 160.9 163.1 156.7 210.6 197.8 193.5 177.1 193.4 174.8 (MPa) 1313 1262 1149 1109 1125 1080 1452 1364 1334 1221 1333 1205 % 21.2 18.8 18.5 16.1 18.3 14.8 27.5 25.5 25.1 25.8 25.2 25.4 R.A % 71.1 60.9 72.2 59.6 72.2 59.3 66.5 58.5 66.6 58.3 62.0 58.1

CHARPY IMPACT TESTING 2-3/8" (60mm) Diameter Bar, 54% Cold-Worked (CW)
Impact Energy* Cold-Worked Temperature Sample Orientation Longitudinal RT Transverse (Notch: Longitudinal) Transverse (Notch: Transverse Longitudinal -75F (-59C) Transverse (Notch: Longitudinal) Transverse (Notch: Transverse *Average of two tests (ft-lbf ) 148 60 54 141 63 52 (J) 201 81 73 191 85 71 Cold-Worked + Age-Hardened (ft-lbf ) 108 56 49 106 54 49 (J) 146 76 66 144 73 66

90-DAY AUTOCLAVE TEST C-Ring, Test Level VII, 1 g/L Elemental Sulfur, Applied Stress = 100% YS
Material Condition Heat# 1 LT Annealed + Age-Hardened 2 3 1 Cold-Worked 2 3 1 Cold-Worked + Age-Hardened 2 3 Result Pass Pass Pass Pass Pass Pass Pass Pass Pass

HASTELLOY C-22HS ALLOY

WARNING: This product and fumes generated from the normal use of this product contain Manganese. The inhalation of welding rod fumes containing Manganese has been associated with the development of serious Parkinsons Diseaselike symptoms, Parkinsonism, Manganism, and other central nervous system conditions. Such symptoms may include impaired speech, balance and movement. Avoid breathing fumes generated in the welding process by utilizing appropriate environmental controls, including but not limited to ventilation, exhaust and respirators.

HASTELLOY C-22HS

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