CONTENTS 1. Injection Molding Machine 1.1 Injection Unit 1.2 Clamping Unit 1.3 Multi-program Control 1.

.4 Defective Molding, Causes and Remedies 2. Molding Operation 2.1 Preliminary drying of materials Dryer 2.2 Molding Conditions 2.3 Other cautions 2.4 Product Quality Control 2.5 Material replacement Interruption of Operation Cleaning by Dismantling 3. Product Design and Mold Design 3.1 Product Design 3.2 Mold Design 4. Mold Shrinkage and Dimensional Accuracy 5. CAE 6. Hot Runner Molding 7. Reuse of Iupilon / NOVAREX 8. Annealing Treatment of Iupilon / NOVAREX 8.1 Annealing Treatment 8.2 Annealing Effect of using both hot air / far infrared radiation heating system International System of Units (SI units)

1.Injectionmoldingmachine
As for the injection molding machine, several types such as plunger type, plunger preplasticating type, screw preplasticating type and in-line screw type, etc. have been developed so far, but presently the in-line screw type injection molding machine as shown in Figure 11-1 has become the main type.
moving plate heatedcylinder fixedplate bandheater hopper injectioncylinder

mold

screw

Figure 1 1 1 Theory of the in-line screw type injection molding machine

The injection molding machine consists of the injection unit and the clamping unit, and their features are described below.

11 Injection unit
1 Injection capacity The proper injection capacity is found from the relationship of the molding machine capacity for the weight of 1 shot as shown in Figure 11-2. It is necessary to select the molding machine that satisfies the capacity of the shaded area. This figure is the summary of the actual molding results in the past, but basically, it is based on the following idea.

injectionmolding machinecapacity

goodmolding area insufficient capacityarea

excessive capacityarea

1shotweight(g)

Fig.

11-2Selectionofmoldingmachinefromtheinjectioncapacity

 At the side where the capacity is small, plasticizing time and injection time become long, and it is used at the narrow

capacity of the molding machine. That is, the filling shortage is caused due to the extension of molding cycle and slow filling rate. On the other hand, at the side where the capacity is large, dwell time of the resin inside the cylinder becomes long, and the resin thermally decomposes. The capacity range in the figure is indicated rather widely, but when it is easy to be thermally decomposed with materials containing lots of pigments and additives, it is better to conduct the molding at shot weight of 7080% of the injection capacity.
2 Barrel Generally, using the material (for example, nitride steel etc.) for the molding of Iupilon / NOVAREX is good. However, concerning the molding of glass fiber reinforced grade (Iupilon GS etc.) and optical grade (Iupilon H-400 etc.), it is good to consider the following for the barrel material. As for glass fiber reinforced PC, it is good to use the bimetal (double-structure cylinder covered the inside with another metal and centrifugal casting) to prevent the barrel abrasion. For example, the H alloy (Hitachi Metals Ltd.), N alloy (Japan Steel Works Ltd.), K alloy (Kobe Steel Ltd.) etc. are well known. Figure 11-3 indicates the abrasion data when molding glass fiber (30%) PC in case of using the H alloy barrel. The abrasion of the metering section vicinity where the feed section and the backflow prevention ring contact with is improved 1). In addition, the bimetal cylinder such as H alloy is also effective in suppressing the generation of the burn of Iupilon / NOVAREX although the burn mark and black specks due to thermal decomposition become problems in the transparent use. 1) Hitachi Metals Ltd. H alloy catalogue hopper cylinder

molding resin

nitrided steel cylinder after 6-month use (disposed after measuring)

type characteri stic alloy system hardness longitudinal

heat expansion coefficient ()

anti-wear, anti-corrosion

variation of inner diameter

H-503 cylinder after 1 and a half year use (prolonged use)

distance from the cylinder tip (mm)

Fig. 11-3 Barrel material and abrasion data when using GF (30) PC

 3 Screw The 3-stage type screw of the single flight is usually used. The screw design consists of the basic design based on the premises of smooth conveyance of pellet, plasticization for melting, dearation and compression, and measurement with a little unevenness. Supply (feed section): Stroke is designed long for conveying and melting the pellet, and increasing plasticization quantity. Compression (compression section): Return the air and water involved in the feed section to the hopper side and deaerate. In addition, a sufficiently melting mechanism is required. Because PC is a high viscosity material, the rapid compression type is unsuitable and moderating compression type with gradually increasing outside diameter is recommended. Measurement (metering section): In order to suppress the measurement unevenness, the measurement stroke is designed long, 4D ~ 5D or more. The screw design of PC is indicated in Fig. 11-4. 2)
screw head backflow prevention ring pitch sealing outer diameter

head

metering section Notes: in (

compression section

feed section

) shows an example of total length L

Basic shape of screw

stroke

metering zone

compression zone screw length

feed zone

Screw diameter mm 30 60 90 120 120

Screw depth Feed section Metering section mm mm 56 18 66 30 95 40 120 48 Max 140 Max 56

Compression ratio 201 221 241 251 Max 301

Screw pitch H1.0D Screw diameter more than 80mm H0.9D Screw diameter less than 80mm Fig. 11-4 Design of screw for PC

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2) Jonathan M. Newcome:SPE Tech Pap Reg Tech Conf. PIONEER VALLEY SEC (77 june 8/9) 45 78

In the same figure, L/D is 20, the ratio of Feed (F) / Compression (C) / Metering (M) is divided into 60/20/20, pitch H is almost equal to screw diameter D, and compression ratio C.R. of the screw is 2.0:1~2.5:1. The screw that its surface is covered with thick film hard Cr coating is good. When the glass fiber reinforced material is used, there is a problem of abrasion, but constantly preparing spare screw and regularly exchanging after recoating are recommended. The screw that processed nitriding treatment is hard to be worn due to its high hardness. On the other hand, for transparent product and colored product (except the black) avoiding the burn, because it is easy to cause the burn in PC molding, it had better use the screw that processed with (Ni+Cr), (Co+Cr), TiC treatment at the surface though it is a little expensive. Recently, the example which uses dulmage, sub flight, pin screw mounted at the screw head with the purpose to improve the melting and mixing and the dispersibility is observed with the precondition of not giving excessive shearing force to PC and the design without PC stagnation.
4 Backflow prevention valve, check ring The screw head is equipped with the backflow prevention valve to maintain the effective injection pressure by preventing a part of measured resin from backflow through the ditch of the screw at the time of injection. The structure of this valve is indicated in Fig. 1-5. It can be understood that it is easy for resin stagnation with this valve structure. Therefore, the design of the flow path without dead space by taking enough R so as not to provide the corner as much as possible is expected. In addition, as for high viscosity material such as PC, because torque is big, the fatigue failure occurs in the screw of small aperture when receiving the load by repeated rotation, the use of screw of wide aperture is recommended.

Back flow ring type equipped with nail

cross-section drawing

Fig.

11-5

Design of Shut Off Valve

As for compound reinforced PC such as glass fiber reinforced material etc. the backflow prevention ring sometimes cracks when the load becomes large compared with the non-reinforced material. When molding without being aware of this, the uneven dimension and the deviation from tolerance in the molding of a precise part occur due to the unstable measurement. It is necessary to note that such a trouble easily occurs in case of overload and insufficient purge.
5 Nozzle A nozzle with the structure without PC stagnation is desirable as possible. Therefore, it is necessary to avoid using the needle shut off nozzle and torpedo nozzle due to resin stagnation. The open nozzle is the best for use. The open nozzle is easy to cause drooling, stringiness, and it is difficult to prevent them but using a long-extended nozzle and adjusting independently the temperature at two separate places of the tip and the bottom, are effective. 6 Heater Since PC is molded at high temperature, the heater with heat capacity can be heated to about 370 is used, and a band heater is usually used. When disassembling to clean the nozzle and cylinder head and when the heater is stuck with drooling resin, the heater is disconnected. It is necessary to note that it is easy to cause the burn when continuing molding without being aware of heater disconnection.

12 Clamping unit
As for the molding of Iupilon / NOVAREX, either the hydraulic type or the toggle type is available. Since the average value of the mold internal pressure in the molding of Iupilon / NOVAREX is 350-500kg/cm2, the clamping force F can be calculated by the following equation. Fton0.350.50 S where S: projected area as indicated in Fig. 12-1. However, it is necessary to note that when the arrangement of molding is eccentric from the center of mold (center of die plate), the clamping force, which is higher than the above formula is required.

clamping pressure of the molding machine (ton)

projected area of the molded piece Fig. 12-1 Selection of molding machine from clamping pressure

13

Multistep program control

The improvement of poor appearance of the moldings, the reduction of size unevenness between the molding shots, and the measures against sink marks, warpage and flash can be achieved by controlling the injection rate, holding pressure, screw rotation speed and back pressure with multistep program control at the time of injection. The effect of multistep program control in PC and its control system are indicated in Fig. 13-1. The outline is introduced below. 3 Table 13-1 Effect of multistep control (in case of PC) Molding conditions Injection rate Holding pressure Screw rotation speed Back pressure Effect Prevention of jetting mark at gate part, prevention of flow mark of sharp corner, prevention of core falling and prevention of flash Reduction of molding stress and prevention of sink mark Stability of measurement Stability of measurement

3: Screw position detector 5: Injection rate detector 10: Screw rotation speed detector

1: Servo valve

7: Pressure detector

2: Servo valve

4: Program setting device

6: Injection rate controller

9: Holding pressure controller

8: Screw back 11: Screw pressure rotation speed controller controller

input

feedback Disturbance

Comparison controller Setting value Controller Controlled object Control variable

Detecting value Detector

Fig. 13-1

Outline of multistep program control system

 Control of the injection rate Since the poor appearance is resulted from the change of rate of the flow front, the measures can be done by controlling the injection rate. The relationship between the flow rate and the defective phenomena is summarized in Table 13-2. It can be understood that the injection rate should be set to an appropriate range because there is a problem even if the flow rate is too fast or too slow.

Table 13-2 Flow rate and defective phenomena Defective phenomena results from too Defective phenomena results from too slow fast flow rate of resin flow rate of resin Flow mark Jetting mark Transcription defect of mold Gas burn surface Sink mark due to trouble of Weld line air purge Short shot

Fig. 1 3-2 indicates an example of a measure to avoid the area of various defective phenomena by controlling the injection rate with multistep program control. It is understood that the setting range of the injection rate to have a product of good quality is narrow (shaded part) in case of general molding.
jetting gas burn

injection rate area to obtain good product when setting program of injection rate area to obtain good product when not setting program of injection rate gate flow mark transcription defect of mold surface

weld line

screw stroke

Fig.

13-2

Defective area of injection rate

Control of the holding pressure The defective phenomena such as sink marks, warpage and flash are related to the holding pressure. The measure against these phenomena becomes possible by controlling the holding pressure. The relationship between the defective phenomena such as sink marks, warpage and flash and the holding pressure is summarized in Table 13-3. Figure 13-3 indicates the pattern of the holding pressure program which was obtained to avoid the defective phenomenon area. -----------------------------------------------------------------------------------------------------------------------------3SumitomoHeavyIndustries,Ltd.PlasticMachinery,lecturetextbookofinjectionmoldingMoldingBCoursePracticalApplication

Table 1.3-3

Holding pressure and defective phenomena

Defective phenomena results from too low holding pressure Short shot Sink mark Underdimension Shrinkage strain

Defective phenomena results from too high holding pressure Flash Overdimension Crack Mold release defect Residual stress

warpage

flash

holding pressure sink mark

holding pressure time

Fig. 13-3 Holding pressure pattern to avoid defective area Control of screw back pressure and screw rotation speed The stability of measurement (plasticization) is related to screw back pressure and screw rotation speed. It is possible to improve the accuracy of uneven repeated measurement by controlling these factors. Fig. 13-4 indicates the result of comparing the effects of the multistep program control of screw back pressure and screw rotation speed about the measurement position or mold release resistance4). From this figure, it is thought that the unevenness of the measurement position, mold release resistance was decreased by the multistep program control.

mold release resistance (kgf) no program shot number control

measurin g position Sg (mm)

shot number

mold release resistance (kgf) with program control

shot number

measurin g position Sg (mm)

shot number

Fig. 13-4

Stabilization by the program control of plasticization process Material S-2000

14

Defective Moldings, Causes, and Remedies

Defects to be encountered in molding of Iupilon / NOVAREX are almost similar to those of other plastic materials. The defective causes and remedies of general grade and glass fiber reinforced grade are summarized in Tables 14-1 and 14-2, respectively. The effect that the mold temperature of glass fiber reinforced grade has on the appearance is indicated in Fig. 14-1. Table 14-3 shows the problems and remedies in an accurate molding. Table 14-1 Defective causes and remedies of general grade
Defective molding Cause Remedy Dry the pellets thoroughly at 120. Do not allow the pellets to cool in the hopper. Perform free injection and observe the state of bubbling of the melt.

Silver streaks Moisture in the pellets (uniformly distributed in the direction of injection) Silver streaks (irregularly distributed Overheating of the resin and often shaped like a comet locally)

iOverheated spots in the cylinder or nozzle iLower the temperature of the overheated spots iiStagnation of the resin in the cylinder oriiClean the stagnant part or replace the stagnant part with a part free from nozzle stagnation Brown discoloration iii Over heating of the resin or too long dwelliiiCheck the stagnant part and the joining time part of the cylinder and nozzle ivInadequate rotation speed of screws ivSet the rotation speed of screw at 45 60rpm. Raise the back pressure in a screw type Molding machine Local discoloration Insufficient venting of the mold and heat Cut a 001mm003mm deep vent in the

Cloudy black specks and Air trapped in the pellets bubbles

Generated by adiabatic compression of the air parting face of the mold Change the position of the gate to obtain a Voids and black specks Adiabatic compression of the air entrapped in uniform flow of the resin in every direction. and silver streaks around the resin in the mold. Correct the eccentricity and non-uniform the voids thickness of the core. Lower the injection rate Stains iContamination by foreign matters or other iPay enough attention to storage of the resin resin. and feeding to the hopper. iiContamination by eroded material of the Clean the hopper, cylinder and nozzle. molding machine. iiInspect the sliding surface of the iiiFats or oils in contact with the melt. measuring unit, plunger sleeve, screws, non-return valve, and nozzle. iiiInspect the injection unit and the mold and prevent oil leakage.

Defective molding

Cause

Remedy

Dark brown or black specks Peeling of a layer of decomposed resin formed on Clean the internal surface of the cylinder. or particles the internal surface of the cylinder. Keep the temperature of the cylinder at 160180 when the operation is stopped.

Cloudy surface

Due to the use of a mold release agent.

Polish the mold. Reduce the amount of a mold release agent.

Sink marks on the surface Shrinkage occurring during freezing is not Or bubble inside sufficiently compensated by the holding pressure

i Prolong the application of the holding pressure iiPrevent heat loss from the nozzle. iiiEnlarge the gate. ivMake the wall of the molded piece as thin as possible. vAttach the gate to the part with the largest wall thickness. viProlong the cooling time when sink marks are formed after release from the mold. viiIncrease the feed cushion of pellets.

Mold flash iInsufficient mold clamping force or too high injection pressure. iiWearing off of the mold. Difficult molt release or iLarger mold release force required Deformation during molt release

iIncrease the mold clamping force or reduce the injection pressure and holding pressure. Inspect the mold. iiRenew the mold.

i Lower the holding pressure. Provide a sufficient draft and polish the mold. iiAttach a device to break the vacuum in the iiVacuum created between the mold and the molded mold. piece. iiiMold release force not working on the part iiiIncrease the number of ejector pins. where the molded piece is adhered closely to the mold. ivMolded piece not sufficiently cooled during mold release ivLower the mold temperature and speed up cooling. vProlong the cooling time. iRaise the cylinder temperatureenlarge the

Short shot

iToo low cylinder temperaturetoo fast

passageway, raise the mold temperature and the freezing of the passageway low mold temperature too injection rateand improve the air vent of the mold iiToo small wall thickness iiIncrease the wall thickness. iiiIrregular filling of cavities. Ripple near edges iToo low resin temperature iiLow injection rate iRaise the resin temperatureparticularly the nozzle temperature iiPerform high speed injection. iiiChange the passageway to obtain simultaneous filling.

Jet flow, cloudiness near the gate

Caused by the cooled resin or the resin cooled by Enlarge the gate. Lower the injection rate. Change colliding with the mold being carried forward the position of the gate. Raise the nozzle again by other resin melt temperature.

Table

14-2

Defective causes and remedies of glass fiber reinforced grade

FLow marks

Inadewuate flow of the melt iRapid change in the cross section of the iDesin the molded piece such that the cross molded piece. section changes not stepwise but smoothly. iiInadewuate flow of the resin melt around iiRound the sharp corners. sharp corners.

Weld marks

Cooling of the resin occuring brfore merging.

Raise the resin and mold temperature and perform high speed injection. Enlarge the gate

Ripple near the gate

Cooling of the resin before the holding Enlarge the gate pressure working.

Peeling of a surface layer Contamination by foreign matters and other Perform purge sufficiently. from the molded piece resins. (especially when bent) iMoisture in the pellets (Defects due to iDry the pellets at 120. Perform purge and moisture are often unnoticeable) examine the degree of resin bubbling. Breakage of molded pieces iiRaise the nozzle temperature and remove iiToo low nozzle temperature. cold slug. Detach the nozzle from the mold after injection. iiiResin cooled between the nozzle and the iiiRemove such cooled resin every time it sprue bushing. is formed. Use a shut off nozzle. iv Generation of internal stresses due to low iv Keep the mold temperature at 70 mold temperature, too high injection 120 .Lower the injection pressure and pressure and holding pressure, and holding pressure and avoid excessive extremely non-uniform distribution of the pressure after complete filling. Make wall thickness. the wall thickness distribution uniform. vContamination by foreign matters. vcylinder and nozzle and cleaning.

Defective molding

Cause

Remedy iRaise the mold temperature at 110 120 if possible iiRaise the holding pressure. iiiPerform high speed injection. iProvide a proper taper in the range of 1100150 iiMake adequate position of ejector pins. iiiLower the mold temperature. ivProlong the cooling time. vLower the holding pressure.

Defect of surface gloss

iLow mold temperature iiLow holding pressure

iiiLow injection rate. iImproper taper iiInadequate position of ejector pins Defect of mold release iiitoo high mold temperature. ivShort cooling time. vToo high holding pressure.

Local burn

iStagnation of the resin in the molding iExamine the molding machine. Dismantle and machine perform cleaning. iiInstall the vent hole in the mold. iiOverheating of the resin due to adiabatic compression of the air in the mold. iSpecks of the resin and floating of glass iMake the molding conditions proper. fiber. iiToo severe hue limit. iiWiden the tolerance level of hue.

Hue non-uniform

iApply the mold release agent too much. iDecrease the applied amount of the mold Defect of strength of the release agent. weld part ii Inadequate position of the gate and ii Change the position of gate and re-examine distribution of the thickness. the distribution of the thickness.

poor releasing area

Material

Fig.

14-1

Relation between the mold temperature and the appearance of glass fiber reinforced grade
Color difference: the color difference with glass reinforced PC (black) was obtained by considering the non-reinforced PC (black) as a controlled material.

Table
Defective molding

14-3 Defective causes and remedies in an accurate molding

Cause Remedy

Deformation under load

Insufficient elastic modulus

A Examination of kind and content of reinforced material. C Combination with metal insertoutsert B Application of low bubble molding. C Rib reinforcement A Combination of reinforced material. A Addition of non-oriented reinforced material. A Combination of reinforced material. A Combination of reinforced material. C Raise the mold temperature. C Annealing treatment C Uniform distribution of thickness C Molding by low holding pressure and high mold temperature A Combination of reinforced material. B Design creep within the limit. A Use the low warpage grade in case of reinforced grade

Insufficient shape rigidity

Change of dimension Large thermal expansion coefficient. according to environment Anisotropy of thermal expansion conditions coefficient. Moisture absorption Change of dimension by heat (shrinkage by heat

Change of dimension over time

Excessive molding strain

Creep deformation

Estimated error of molding shrinkage factor

Anisotropy of molding shrinkage

C Fulfillment of molding shrinkage data Form, position and size of gate Thickness, thickness distribution Shape effectroundnessstraightness etc Error by the mold D Improvement of processing accuracy D Consider the influence of mold structure A Control the viscosity, filling material, pellet size etc. Performance of the mold device B Improve the performance of injection molding machine, mold etc. and maintainance management. C Control the holding pressure, resin temperature and mold temperature. C Control the dimension measurement D Consider the mold strength D Mold material A Use the low warpage grade in case of reinforced grade A Use the low viscosity material. B Use the injection compression molding machine. C Low holding pressurehigh speed filling C Examine the number and position of the gate.

Non-uniform dimension of Non-uniform material mold process

Non-uniform molding conditions Measuring error Durability of the mold

Warpage

Anisotropy of molding shrinkage

Non-uniform pressure in the same cavity.

Defective molding Warpage Non-uniform cooling

Cause

Remedy C Examine the distribution of thickness C Balance of the mold temperature D Examine the mold heating and the cooling ditch A Use the low viscosity material. B Use the high pressure molding machine and

Sink marks

Due to the failure of holding pressure

the injection compression molding machine. C Examine the position and size of the gate.
C Make the wall of the molded piece as thin as possible. C Adjust the resin temperature, mold temperature and holding pressure etc. prevention of sink marks by bubble generation A Use the low bubble grade Sink marks prevention grade C Lower the mold temperature. A Use the mold release grade. C Increase a sufficient draft, shape of molded pieces C C low holding pressure, low mold temperature Use the spray mold release agent. pay attention to defects of the appearance, crack of molded pieces D Pay attention to mold polish direction D State of mold surface coatingpolishing degree D System and position of ejector Too much gas generation

Defect of mold release

Improper taper Adhesion to mold surface Imbalance of ejector power

Defect of gas unfilling Surface cloudiness Mold corrosion Defect of dimension Defect of mold release

Consider the pyrolysis, additive, filling material etc.

Insufficiency of preliminary drying of materials

B Use the vent injection molding machine C Too high molding temperature Too long molding cycle Insufficient gas venting B C C Cavity vacuuming Lower the injection temperature Install the air vent.

A B C D

Measures regarding the materials Measures regarding the molding machine, auxiliary equipment etc. Measures regarding the product design, molding conditions etc. Measures regarding the mold design

2. Molding operation
21 Preliminary drying of materials Dryer
Since Iupilon / NOVAREX have an ester bond in the main chain, the hydrolysis occurs when heated with the moisture. As a result, the physical properties, particularly the molecular weight and the impact strength are reduced. Also, the preliminary drying before molding is necessary because the generation of silver streak and void at the appearance occur. The moisture content in the pellets should be assumed to be 0.015~0.020% at the preliminary drying of Iupilon / NOVAREX. The results of the molding at various moisture content are shown in Table 21-1. These results indicate that the degradation of the impact strength in addition to the generation of defective appearance is very large. Therefore, it is important to use the dried pellets that the moisture content is lower than the above mentioned limit to have a good performance of Iupilon / NOVAREX. Table 21-1 Effect of the moisture content at the time of injection molding S-2000Molecular weight 2.5104 Moisture Molecular Falling ball impact destruction rate Appearance of content weight of Total destruction molded pieces molded pieces Ductile failure Brittle failure rate 0 0 0 Good 0014 25104 Good 30 0 30 0047 24 Good 50 0 50 0061 24 A few silver 90 0 90 0067 24 streak Silver streak, 20 80 100 0200 22 bubble (Note) Weight of falling ball impact test 2.13kg. The head makes the heavy bob of 10mmR fall from the height of 10 m The drying conditions of Iupilon / NOVAREX are indicated in Table 21-2 Table 21-2 Drying conditions of Iupilon / NOVAREX Drying conditions Notes Temperature Time required Many examples of use. Multi-tray hot air Pay attention to the ambient moisture circulation dryer 120 45hr or more Thickness less than 30mm is preferable. Many examples of use Pay attention to the ambient moisture Hopper dryer 120 34hr or more and short circuit pass When the input is small, the moisture distribution is bad. It is often used for the molding of Dehumidifying 120 23hr or more optical disk substrate and optical lens Hopper Dryer etc.
(Note) Please note that the grade of the polymer -alloy type sometimes differs in the dry ing conditions.

In order to dry the pellets of Iupilon / NOVAREX until the moisture content is lower than the above mentioned limit it is necessary to note the kind of the dryer, its performance and environment ( temperature and moisture).

Fig. 21-1 is the example which shows the dry curve by the difference of the environment with the multi-tray hot air circulation dryer. The dry efficiency is decreased under high temperature, high humidity and it requires long time until the moisture content is lower than the limit.

Also, Fig. 21-2 shows the results obtained by the hopper dryer in the same way. The dehumidification hopper dryer that is not affected by the environment and the dry efficiency is good. However, it is necessary to pay attention to the time degradation of the dehumidifier performance and consider the short pass phenomenon of the pellets when determining the drying capacity.
capacity 50kg feed 50kg feed (30 mm think pile) set temperature atmosphere

water absorption percentage (%)

limiting water absorption(0.02%) drying time (hr)

Fig. 21-1Multi-tray hot air circulation dryer

capacity 50kg feed set temperature atmosphere

water absorption percentage (%)

limiting water absorption(0.02%) drying time (hr)

Fig. 21-2 Drying conditions by the hopper dryer Prevention of moisture absorption in the hopper It is necessary to pay attention to the moisture re-absorption in the molding machine hopper in addition to the preliminary drying of the pellets as described in Section 21. Moreover, it is also necessary to consider preventing the moisture re-absorption by shortening the installation of the hopper dryer, hopper insulation and dwell time of the pellets as much as possible.

22 Molding conditions 1 Cylinder temperature The resin temperature is often higher than the setting temperature of the cylinder by 10 - 20 C. It is good to measure the characteristic of the injection molding machine to use in advance. The general molding temperature of Iupilon / NOVAREX is in the range of 260320C, but it is better to set it as low as possible for deep colored products. As for the setting of the cylinder temperature, it is common to set the temperature gradient such that the hopper side is higher by 10 - 20 C. When the rotation torque of the screw becomes overload by the high viscosity grade and so on, the temperature on the hopper side may be set high oppositely. . In addition, the selection of the molding temperature should be made in consideration of the molding cycle time, namely the dwell time of the resin in the cylinder. The molding machine with the injection capacity by corresponding to the weight of the molded pieces and molding conditions is selected, and the dwell time is shortened as much as possible to avoid the thermal degradation of the resin. It is necessary to note that the temperature of the nozzle has a slight affect on the cold flow of the molded pieces and the leakage of the resin (drooling). 2 Injection pressure, holding pressure The injection pressure and holding pressure are set as low as possible if the sink marks and voids do not occur in the molded pieces. However, in case of the resin with high melt viscosity such as Iupilon / NOVAREX, the inside of the mold can not be filled from the pressure loss with the flow process of the resin if the pressure is not raised to some degree. As soon as the cavity is filled, the injection pressure is reduced to the level that does not cause sink marks. In addition, the pressure is raised to reduce the mold shrinkage of the resin, but from the point of strain and mold release characteristic which remain in the molded pieces, the pressure should be set as low as possible. 3 Injection rate As indicated in Fig. 22-1, since the flow length increases when the injection rate increases, the fast filling is carried out for thin-walled molded pieces. However, when the fast filling is carried out, defects such as flow marks and flash are produced. Since the recent injection molding machine is equipped with the multistep control of the injection rate (program injection), both the filling and appearance can be controlled by changing the rate according to the shape and gate of molded pieces. The basic rate program is as follows. (a) Make high speed at the passage of the sprue and runner part. (b) Make low speed at the initial filling of the gate part and product part, and at the time of filling completion. (c) Make low speed when passing over the thin type core and pin part.

flow length exclusive of gate (mm)

Iupilon

injection rate Fig. 22-1 Injection rate vs Flow length

4 Rotation speed of screw and Back pressure It is necessary to increase the rotation speed of screw to shorten the plasticizing time but it becomes the cause of air entry, generation of the resin burning, bubble and silver streaks resulting from the deaeration insufficiency, and easy to cause the thermal degradation by adiabatic exothermic heat. The back pressure is about 5 - 10 % of the injection pressure to improve the deaeration effect on the hopper side. Since the back pressure has an affect on the leakage (drooling) of the resin from the nozzle, the consideration of setting temperature is also necessary.

5 Mold temperature The mold temperature is one of the important conditions in the molding of Iupilon / NOVAREX. When the mold temperature is too low, the filling becomes bad, and in addition to the defective appearance such as flow marks etc., the molding strain is easy to be generated. On the other hand, when the mold temperature is too high, the resin is easy to stick to the mold surface and defect of the mold release and deformation of the molded pieces after the mold release easily occur. The standard mold temperature is 70120.

23 Other cautions

1 The mold release agent is selected and used according to the usage of the molded piece and the presence of the secondary processing. The mold release agents of silicone derivatives are usually used, but in case of printing and hot stamp, painting etc.as secondary processing, and cloudiness in the vicinity of the gate just after the application, it is better to use the paintable type or unused.
2) It is necessary to pay attention to the shape, removing fat and washing in case of inserts (refer to Iupilon Technology Report, PCR304 for detail). Sharp corners should be avoided in inserts (Fig. 23-1).
no sharp corners good fitting channel shape examples of good fitting without paterns

channel round head flat face pattern without arising notches

Fig. 23-1 Shape of a blind insert

The thickness of the molded pieces around the insert is necessary to be 0.5 times the diameter of the insert even in the worst case because it has an affect on the strain around the insert. In addition, if the insert is a metal in large size, preheating is necessary. In case a large number of inserts are to be used, the dwell time of the resin in the cylinder is prolonged because it takes long time for the mold installation and as a result, the thermal degradation of the resin may take place. Carrying out the insert after the molding is better.
24 Product quality control Strictly speaking, the molding operation is not over when the material feeding is converted into molded pieces, but it is necessary to check whether the pieces exhibit enough strength in actual use. From this point of view, it is very important to select proper molding conditions. The evaluation is not easy although molding conditions are modified and selected while judging their performance in actual use. The requested characteristics of the molded pieces are based on the basis of the customers specification, and it is impossible to conduct everything in the molding process. The management is thoroughly executed in the early stage when producing a new molded piece, and it is necessary to focus on the point and to conduct day-by-day management afterwards. The item that should be managed in the molding process is to prevent the reduction of strength of molded piece due to 1. the degradation and decomposition of the resin, 2. molding strain. This is explained as follows. 1 Degradation, Decomposition of the resin Measurement of the molecular weight is used as a means to examine the degradation and decomposition of Iupilon / NOVAREX. It is necessary to note that the measurement of the molecular weight is difficult in a special grade, and can not be judged only by it in some cases. Since the measurement of the molecular weight is time consuming, it is better to conduct it at the stage of selecting the molding conditions at the beginning and to keep the correlation with other simple test method, and then manage it For example, it is also good to bend a sprue and a runner and examine the condition of breakage or conduct an impact test sensitive to the reduction in the molecular weight due to the decomposition of the resin (falling ball impact test etc. to add the impact in the molded piece with the hammer).

2 Molding strain A method often used for determination of the molding strain (residual stress) is to immerse Iupilon / NOVAREX in specific solvents to observe the presence of cracks generated. As for Iupilon / NOVAREX general grade, it is inspected by using the combined solvent of MIBK (methyl isobutyl ketone) and methanol. This method is suitable for stress detection by the following reasons. (a) In case of crack generation, a relatively big crack is generated and is easy to determine. (b) The detected stress can be changed by changing the mixed composition. Table 24-1 is summarized based on current practical results. However, because the detection method of residual stress by solvent is a method of large unevenness actually, the result should be considered as a rough standard and an evaluation standard in correspondence with practical test must be decided. Also, the correspondent mixed composition of the conventional carbon tertrachloride / butanol system was described
Table
24-1

Mixed compositionvolume ratio MIBKMethanol CCl4Butanol

Detected stress MPa kg cm2 39 40

Evaluation

11 10 MIBK50 CCl4100

Too severe for checking stress of normal molded piece Suitable for searching molding conditions for stress reduction and annealing conditions.

Molded piece is suitable for stress check in a simple substance. Suitable for the check of assembly articles 13 13 13 and insert articles loaded by joint stress and 25 25 130 external force. When the crack is generated at this level, 17 17 17 there is 125 125 170 a possibility that the crack is generated in actual use, too. 21 01 01 0 0 210 After the sample is immersed in the mixed solvent of MIBK (methyl isobutyl ketone) and methanol for one minute, take it out, conduct water washing and observe the crack.

12 33

11 50

83 85

25 Material replacement, Interruption of Operation, and Cleaning by Dismantling 1 Material replacement Polyamide, polyacetal etc. should not be replaced directly with Iupilon / NOVAREX and the reverse is also similar. It is because these resin materials decompose when replacing directly to the molding temperature range of Iupilon / NOVAREX, and also promote the decomposition of Iupilon / NOVAREX. In such a case, polyethylene and polystyrene must be used between the two. However, it is necessary to note the case when a transparent resin such as polystyrene is mixed with Iupilon / NOVAREX because the end point of the replacement can not be clearly discernible. Recently, to make the replacement of color, material easy, various replacement materials (cylinder washing material) are available in the market. A proper replacement material can be selected according to the molding temperature range of the material before replacement, the material of the replacement purpose.

2 Interruption of Operation, and Cleaning by Dismantling The resin is gradually decomposed and formed a carbonized layer on the internal surface of the heating cylinder and around the backflow prevention ring of the screw over a long period of operation. This carbonized layer does not peel off during the normal molding operation. However, when the temperature of the heating cylinder goes down during interruption of the operation, the carbonized layer peels off due to shrinkage, contaminates the molded pieces and becomes black specks when the molding operation is resumed. Therefore, it is better to keep the heating cylinder at 150 180 during interruption of the operation for a short time. When the operation is stopped for a long time, it is good to replace Iupilon / NOVAREX with other resins of lower molding temperature range and lower the temperature. Polyethylene and polystyrene are good as replacing resins. Since the carbonized layer on the internal surface of the heating cylinder and around the backflow prevention ring of the screw gradually becomes thick and begins to contaminate the molded pieces when the decomposition progresses, the heating cylinder and the screw should be dismantled and cleaned regularly. Especially, since the contamination of foreign matters, black specks are not good for transparent molded pieces, it is necessary to dismantle and clean once every several months. When various resins are molded with the same molding machine, it is necessary to dismantle and clean the cylinder and the screw regularly. The dismantling procedure is done by replacing with polyethylene and polystyrene after the resin in the cylinder is emptied as much as possible. After dismantling, remove the remaining melted resin quickly, and then remove the carbonized layer with the spatula and brush made of cupper or burn with the burner. If Iupilon / NOVAREX remains and it is impossible to take it out, an effective method is to wash with a solvent such as methylene chloride etc. In this case, pay attention to the work environment (ventilation, fire).

3. Product design and Mold design 31 Product design When using Iupilon / NOVAREX, the contents shown in Table 31-1 are considered as problems in practical use. As shown in Table 31-2, it is necessary to investigate and examine sufficiently so as not to cause these problems. In addition, the calculating formula shown in Table 31-3 is useful for the standard of lightening, decision of the product thickness, and the selection of molding machine, etc. Table 31-1 Defective phenomena observed in PC molded piece Classification Contents Crack and deterioration of impact strength due to degradation at the time of molding Breaking due to excessive load stress Strength Deterioration of strength due to concentration of stress Crack of insert and screw tightening part Solvent crack due to oil, plasticizer etc. Deterioration due to hot water and alkali. Defect of dimensional due to error of estimation of mold shrinkage factor Dimension Deformation due to excessive stress and warpage at the time of molding. Deformation due to creep deformation and thermal expansion. Silver streakssink marksflow marksspecksweld linehue non-uniform Appearance Uneven brightness of embossinguneven brightness of weld part, floating of glass fiber Table 31-2 PointstobecheckedatthetimeofPCmolding Classificatio n General Items Reason of PC moldingcommercialization scheduleweight and material, production quantity, price in the past

Required Lifetime, strength, dimension accuracy, rigidity, flammability, electrical property performance Temperature, chemical atmosphere (oil, solvent, hot water), kind of contacted substance Use (PVC, packing), outdoor use or not. environment Tightening Inserting, screw tightening, bonding, caulking. method Appearance Hue, existence of embossingexistence of coating

Table 3 1 3
Classification

PointstobecheckedatthetimeofPCmolding
Items Wweight of PC product, W0: weight of metal product

Weight (in case of constant shape)

2/1 * t2/t1 * Wo

1t1density and thickness of metal, 2t2density and thickness of PC tthickness of PC, t0 thickness of metal Necessary thickness to give the same loss

to *

E2/E1
tthickness

E1bending elastic modulus of PC, E2bending elastic modulus of metal Thickness and Flow Length L3040 t2 Lmaximum flow length Required mold clamping force of molding machine Pton035050 S Pmold clamping force sprojected area QCapacityg wWeight of molding pieceg

Capacity of molding machine

Q1433W

Next, in order to maximize the good performance of Iupilon / NOVAREX, it is necessary to pay sufficient attention to the shape design. The key points are as follows: (1) The thickness is uniform and no sudden change of the thickness. (2) An acute angle is absent. (3) Provide a proper taper. (4) Undercuts are absent. As for the main items, the standard and cautions in the molding are described in order as follows. 1) Thickness The thickness of the molded piece should be decided in consideration of the required performance of the product and moldability of the material. The relationship between the thickness and the flow length for Iupilon / NOVAREX is shown in Fig. 31-1. In case where the thickness is extremely thin, defect of unfilling, when it is extremely thick, defects such as sink marks, bubbles, deformation etc. and impact strength deterioration occur (thickness 4 5 mm or more). In addition, the sudden change of the thickness obstructs the flow of resin causes flow marks, notch effect at the corner, and weakening of strength. Examples of the design to have the uniform thickness are shown in Fig. 31-2 The distribution standard of thickness is shown in Fig. 31-3.

flow length exclusive of gate (mm)

I: Region where ordinary molding is possible II: Region where high temperature and pressure are required thickness (mm)

Fig.

31-1 The relationship between the wall thickness and the flow length for Iupilon / NOVAREX
bad good bad good bad

bad bad bad good

good

good

good

Fig. flow direction

31-2 bad

Distribution of the thickness

OK

flow direction
good

flow direction Fig. 31-3 Change of the thickness

2 Corner R The range of 0.51.0mmR is suitable for the corner . Since an excessive stress occurs at the corner of the molded piece due to the concentration of stress, be sure to provide R at the corner. The relationship between the notch R and the impact value for Iupilon / NOVAREX is shown in Fig. 31-4. The brittle fracture is shown when the notch R is below 0.1R. The relationship between the corner R and the stress concentration factor is shown in Fig. 31-5. When the corner R is small, the stress concentration factor becomes large, and as a result, it is easy to cause cracks, residue stress becomes large and defects such as flow marks easily occur. On the other hand, if the corner R is too large, defects such as sink marks, bubbles, and deformation etc. occur. Therefore, the ratio of the corner R and the thickness (R/T, R'/T), as shown in Fig. 31-6 must be noted for the design of the corner. Thickness 1/8 inch, cutting notch
pressure concentration coefficient

corner radius R thickness

ductile failure Izod impact value (J/m)

Fig. 31-5 The relationship between the corner R and stress concentration factor

brittle failure

R1.0mm Fig. 31-4 The relationship between the notch R and Fig.31-6DesignofthecornerR impact value for 3 WeldIupilon / NOVAREX line In addition to the deterioration of strength, various defective phenomena at the weld part are observed as shown in Table 31-4. The reinforcement measures at the weld part such as the gate type, gate position, rib reinforcement etc. as shown in Fig. 31-7 are effective.

Table

31-4

Defective phenomena observed at the weld part Notes Mainly observed in glass fiber reinforced grade, polymer alloy grade

Practical failure Deterioration of tensile Deterioration elongation and impact of strength strength Generation of Generate in the vicinity crack of insert, screw boss Defect of Irregular color, Uneven

Phenomena

Mainly observed in deep colored-substance

appearance brightness of embossing Defect of dimension Sink marks, roundness defect

and polymer alloy grade Many defects in glass fiber reinforced grade

A. Take the gate in the direction where the deposited area of the weld becomes large

weld line

gate

B. Reinforce the rib in the vicinity of the generated hole of the weld line.

C. Select the position of gate as the weld line does not generate in the vicinity of the insert metal fitting
Gate A (good) Weld line does not generate

Gate B (bad) Weld line generates

insert metal fitting Fig.31-7 Examplesofdesignoftheweldpart

4 Shape of Rib It is good to think that the design of a rib is almost the same as other plastic materials. Namely, the measure to prevent the generation of sink marks on the rib opposite side, and the notch effect at the corner part etc. is necessary. The design standard of a rib is shown in Fig. 31-8. Do not forget to provide R above 0.51.0mmR at the base corner of the rib.

B=10-15mm

Fig.

31-8

Design of a rib

5 Tapering In general, the standard of a taper is in the range of 1/1001/50 (0.51.0). An example of the molded piece with a deep rib is shown in Fig. 31-9.
slope

slope slope

Fig. 31-9

Example of taper

6 Undercut There is no problem when missing an undercut by using the side core, but when pulling out an undercut by force with a normal mold, it is difficult to take a deep undercut because of the high mechanical strength and elasticity modulus of Iupilon / NOVAREX. The mold release possible undercut R in case of a cylindrical piece as shown in Fig. 31-10 can be calculated by the following equation.
L0.38 R0.02ri L 1 ( r i / r 0 ) 2 where L 1 ( r i/ r 0) 2
Sprue

Molded piece Undercut Core

Stripper plate

Fig. 31-10

Peripheral undercut R on the cylindrical piece

7 Boss The design standard of a boss is shown in Fig. 31-11.

draft angle D=3d (d5mm) D=2d (d10mm)

Fig. 31-11 Boss 8 Hole It is necessary to note that when the edge and the hole of the molded piece come close, it results in the weakening of mechanical strength. Refer to Fig. 31-12 for the design of the hole.
A2D BD

Fig. 9 Snap fit

31-12 Hole

3y.t = ------ 0.060.08 2l2 However, the load is generated only in an instant at the time of assembly, and it becomes 0 afterwards. Take a proper R.

Fig. 10 Press fit

31-13

Snap fit

Metal insert Hot compression insert metal fitting resin boss Fig. 31-14 Press fit

BA0.20.3 BA Cold compression * 100 0.6% B Resin insert (PC-PC) BA Cold compression * 100 1.5% B As for the resin with elasticity modulus lower than that of PC, it is good to add to the above.

3 2

Mold Design Since the productivity and quality of the molded piece are greatly influenced by the mold design, the mold design is extremely important issue. The basic concept of the mold design is as follows. (1) The filling of the resin can be easily done, (2) The mold release can be easily done. (3) Pay attention to the control of the mold temperature. (reduction of non-uniform dimension including the shape, appearance of the product and stabilization of quality) Each item of the mold design is explained in order as follows.

1 Sprue Basically, the sprue should be shaped as thin and short as possible. The points which should be noted are the mold release characteristic and air bubble of the base. As for the mold release, the draft should be 3-5 0 as shown in Fig. 32 1. As for the air bubble of the base, it is important to design the diameter of the base to the suitable thickness. When the air bubble occurs at the base in the direct sprue, it results in the cutting of the sprue, defect of the product at the time of mold releasing. The diameter for not causing the air bubble at the base is as follows: The diameter of the sprue base 2530 thickness of the base

Fig. 321

35mm S p r u e c u ttin g p o s itio n Shapes of the nozzle and the sprue bushing

The pressure loss of the sprue part can be calculated by the following equation. It is preferable to reduce the pressure loss as much as possible.
8uq Ps _____________ l /2 w h e r e p s pressure loss of the sprue part u viscosity of the resin

q l

volume flow of the resin s p r u e length

-(1/4)

1 dm dl d2 a v e r a g e diameter of the sprue diameter of the sprue tip d i a m e t e r of the sprue base dm

1 - --d13

------3(d2-d1)

(--d23

2 Runner The circular, hemi circular and trapezoidal cross section shapes of the runner as shown in Fig. 3 2-2 are acceptable. Concerning the thickness of the runner, it should be decided in consideration of the pressure loss for the lower limit and the economic efficiency for the upper limit

Fig.

322 Cross sections of runners

The following empirical relationship between the length and thickness of the runner is the common practice.
Length 200mm 100 200mm 100mm 10 8 6

In the case of a multi-cavity mold, it is preferable to balance the runner length to each cavity, and all the cavities should be filled simultaneously as shown in Fig. 32-3 and 32-4. Also, when it is difficult to balance the runner length, it is preferable to balance the gate for simultaneous filling as shown in Fig. 3
2-5.

Fig. 3 2 3 Circular arrangement of cavities

Fig. 3 2 4 Parallel arrangement of cavities

Fig. 3 2 5 Linear arrangement of cavities

The pressure loss of the runner part can be calculated by the following equation. It is preferable to reduce the pressure loss as much as possible.
8uq P _ _ _ _ _ _ _ _ _ _ _ _ l d /2 4 P pressure loss of the runner part u q viscosity of the resin volum e flow of the resin Scross section area of the runner part lcircumferential length cut of the runner part

l runner length d hydraulic depth of the runner part 4 S l

3 Gate The direct gate, side gate, pinpoint gate, submarine gate and tab gate can be applicable to the g a t e s h a p e s . T h e s i d e g a t e a n d p i n p o i n t g a t e a r e c o m m o n l y u s e d a s t h e g a t e s h a p e s o f Iupilon / NOVAREX molded piece. When the thickness of the side gate is thin, defective appearance such as unfilling, jetting m a r k s o c c u r s . F r o m t h e m a r k e t r e s u l t s , i t i s o f t e n d e s i g n e d t h e g a t e t h i c k n e s s e q u i v a l e n t t o 50 70 of that of the molded piece thickness. The gate width is 1 . 5 - 2 . 0 t i m e s t h e t h i c k n e s s and the gate land length about 2mm is applicable. The pressure loss of the rectangular cross section at the gate can be calculated by the following equation. 12Luq P ______ W h

p pressure loss at the gate u viscosity q volum e flow of the resin W g a t e width h g a t e thickness L g a t e land length

As for the pin gate shape, it is important to determine the most suitable diameter of the gate by considering from the viewpoint of crack and deformation of the product at the time of cutting and gate breakage for the maximum dimension, while taking defective problems such as jetting and unfilling for the minimum dimension into consideration. T h e t y p i c a l p i n p o i n t g a t e s h a p e i s s h o w n i n F i g . 3 2 6. Also, Fig. 3 2 7 shows the relationship between the pin gate diameter and the thickness of the base based on the market results It is recommended to design in reference to Fig. 3.2-7. Generally, the average value of the pin gate diameter ranges from 1.0 to 2.0mm.

a)

Thin-walled small articles

b) Relatively large particles

min max. 1

max. 4

Fig.

326

Shape and dimension of pinpoint gate

base thickness (mm)

Gate diametermm

Fig.

3 2 7

Actual relationship between the pin gate diameter and the thickness of the base

The pressure loss at the gate of the circular section can be calculated by the following equation. 8uq P ______ l
R w h e r e p pressure loss of the gate

u q R l

viscosity of the resin volume flow of the resin gate radius gate land length

Notes and the design standards of the shape of the direct sprue gate are similar to the items described at the section of sprue. Fig. 32-8 shows the examples of standard direct blue gate.

Bad

Good

Fig. 3 2 8

Examples of direct sprue design

It is good to determine the gate diameter of the submarine gate in a similar way of the pin gate. The standard shape of the submarine gate is shown in Fig. 32-9.
less than 45

Fig. 3 2 9

Example of submarine gate design

The tab gate is effective for reduction of defects such as flow marks etc. but the pressure loss increases. Since this type of gate has both merits and demerits, it is recommended to use it properly.

4 Position of Gate The standards to determine the position and the number of gates are as follows. (1) Consider the thickness of the molded piece and the flowability of the resin (l/t). (2) Arrange to allow the resin flow from the thick inside of the molded piece toward the thin inside. The flowability data (bar-flow flow length) of Iupilon standard grade are shown in Fig. 32 10 and
3 2 11.

no filler contained

flow length

resin temperature Fig. 3 2 10 Bar-flow flow length vs resin temperature

glass filler contained

flow length

resin temperature
Fig. 3 2 11 Bar-flow flow length vs resin temperature

5 Taper Because the mold shrinkage percentage of Iupilon is small and its adhesion with the metal is good, a proper taper should be provided. Generally, the taper standard is in the range of 1100150 0
510 0 .

6 Corner R When the corner R is small, the crack occurs due to the concentration of stress and residue stress becomes large to cause defects such as flow marks etc. It is necessary to provide the range of 0.51.0mmR or more for the corner. 7 Mold Material The mold steel materials include carbon steel, prehardened steel, hardened steel etc. as shown in Table 32-1. Especially, there is no restriction of the mold material and the material is used according to the purpose. For example, as for the mold to use the material containing glass fiber for molding, hardening steel such as SKD 61SKS 3 etc. is used for abrasion resistance.

Table 3 2 1
Cla ssi Hardness fic HRC ati on 13 28

Mold steel material

Material

Chemical composition

Examples of use

HIT81 HIT82

S55C SCM440

general purpose resinlarge-scalegeneral merchandise high cycle production

1520

ZXlO

Copper alloy

TV housingtape recorder and radio housing, washing machine cover non-transparent product moldingdie plate holder miscellaneous goodstoysTV cabinettape recorder and radio

Pre har de ne d ste el

33

HPM2 HPM38 ASL30F

SCM improved free cutting fire retardant agent additive resingeneral SUS420J2 transparent productrubber improved SUS420 improved home appliancesmedical equipment tableware anticorrosion goods cassettefloppy case PVCfoaming resinrubber telephoneconnectingpipevarious reels ABS reinforced resingeneral processing die plate various home appliancescar inner panel miscellaneous goods

3540

PSL

SUS630 improved

40 HPMl HPM50 FDAC Har den ed ste el

emphasis on made-up deskmirror surface embossingelectric discharging process dust covervarious transparent casesOA AISIP21 improved equipment AISIP21 improved SDK61 improved engineering plasticslide core Made-up anticorrosion mirror surface SUS420J2 improved SUS420J2 improved video diskcassette casemedical equipmentlighter parts Made-up anticorrosion, hyper mirror surface optical disk, aspheric lens abrasion resistantprecision engineering plastic various gearsconnectorsVTR cassette

5055

HPM38 HPM38S

5560 6068

HPM31 HPM40

SKD ll improved Powder high speed

high abrasion resistant super engineering

6068 Agi ng tre atm ent ste el

HPM40

steel

plastic connectorsIC moldgear

4045

YHD50FM

High hardness non magnetic molding magnetic steel plastic magnet high toughnesstight mirror surface Super strength various optical lensthin-wall product steel molding core pin

5257

YAG

8 Mold heating and cooling The design of heating and cooling of the mold is important in the molding of Iupilon / NOVAREX. In the case of Iupilon / NOVAREX, it is preferable to set the mold temperature to 80 or more in order to reduce the molding strain, to improve the good appearance and the dimensional accuracy. The method of circulating oil or pressurized water for heating and cooling is the most suitable. When the core is heated locally, the method of using the chiller for cooling or thermo pipe for a core pin is recommended. Since the space heater and cartridge heater are effective in the heating but ineffective in the cooling, it is preferable to use an auxiliary heat source of heating. 9 Ejection method It is necessary to pay attention to the ejection method because the mold release resistance from the cavity is big in the case of Iupilon / NOVAREX. When the ejection method is not suitable, defects such as cracks, deformation of the molded piece occur. Generally, the circular pin and angular pin are good for the direct ejection, the stripper plate and sleeve ejection methods are suitable for a deep product. 10 Air vent When gas accumulates in the rib, the blind boss and the last filling part at the time of molding, defects such as resin burning, mold corrosion etc. due to the unfilling and the adiabatic compression occur. Especially, such a defect easily occurs when filling at high speed. Therefore, the air vent should be provided at these places. Especially, it is necessary to install air vent enough when molding the material such as compound reinforced grade with a lot of gas generation. It is good to design the air vent clearance in the range of 1 1 0 0 3 1 0 0 m m . An example of the air vent design was shown in Fig. 3 2 12.

Water Cavity ditch 1~3mm (around cavity) Vent part (0.01~0.03mm) decided by resin Land Butt face (Approximately 2mm) a.Dimension of vent ditch

Porous metal

Gas flow Flow of melt resin Flow of water and gas to the outside by vacuum b. Waterline bending by using the porous metal

Apart of the pin surface is connected to make the flow resistance of gas small

Stagnant gas To outside c. Waterline bending by using the fit clearance of the divided bush d. Degassing also serves as pushing pin e.Degassing by bush

F ig . 3 2 1 2

E x a m p le s o f a ir v e n t d e s ig n

4 Mold shrinkage and dimensional accuracy Mold shrinkage of Iupilon / NOVAREX varies depending on grade, molding conditions and shapes of molded piece as shown in Table 4 1. Mold shrinkage percentage of various grades of Iupilon / NOVAREX varies in the range of 0 05 070 as shown in Table 4 2. Mold shrinkage after molding is stable for 24 48 hours as shown in Table 4 3. As for the mold shrinkage anisotropy of the general grade, it is constant without depending on the flow direction of the resin and the right angle direction with it and has little anisotropy as shown in Table 4 4. As for the glass fiber reinforced grade, a big difference in the mold shrinkage percentage in the flow direction of the resin and the right angle direction with it is recognized and the anisotropy is also observed. The relationship between the holding pressure and mold shrinkage percentage at the time of molding is shown in Fig. 4 2. The mold shrinkage percentage becomes low when increasing the holding pressure. Dimensional accuracy is affected by the material, the molded piece shape, the design and the fabrication precision of the mold, and the molding conditions. The dimensional tolerance of Polycarbonate which is published in SPI is shown in Table 4-5. The example of the unevenness and the dimension tolerance of the molded piece with the shape are shown in Table 4 6 and Fig.
4 3. The number of gates and roundness of the cylindrical molded piece, the number of gates and mold shrinkage percentage, and the measurement example of dimensional accuracy are shown in Fig. 4 4 5 6 and Table 4 7.

The following can be said from these results. (1)The dimensional accuracy becomes low when the shape error is included. (2)The dimension not decided by the mold, for example, the accuracy of the height dimension is low. (3)The accuracy of the material containing the glass fiber is lower than that of the unreinforced material.

Table 4 1
Items

Behaviour of mold shrinkage

Comments The holding pressure works well for the material with lower viscosity, the mold shrinkage percentage becomes low.

Melt viscosity

Combination of filling agent When combining the filling agent, the mold shrinkage and mold shrinkage percentage percentage becomes low. Material
Anisotropy of mold shrinkage percentage Thickness When combining the fibrous filling agent, the anisotropy occurs. As for the direction that the fiber oriented, the mold shrinkage percentage becomes low. Because the pressure loss at the side where wall thickness is thin, the mold shrinkage percentage becomes high. The mold shrinkage percentage becomes high at the side where wall thickness is thick due to slow cooling effect. There is the intermediate thickness that the mold shrinkage percentage becomes minimized When the gate diameter is large, the mold shrinkage percentage becomes low.

Gate Design

As for the material that there is anisotropy in the mold shrinkage percentage, the mold shrinkage percentage depends on the gate position and the number.
Shape

The shape accuracy depends on the shape of the molded piece (roundness, cylindrical, straightness etc.)
When the holding pressure is high, the mold shrinkage percentage becomes low. When the resin temperature is high, the mold shrinkage percentage becomes low.

Molding conditions

Holding pressure Mold temperature

Table 4 2

M old shrinkage percentage of various grades of Iupilon / NO VA REX M old shrinkage percentage Shape A Shape B Inner diameter 049 Outer diameter 056

Grade S2000 IJS2010 IJS2020 IJS2030 GS2010M GS2020M GS2030M LGS2230M

0507 0507 0507 0507 03 01 005 008

05 04 03 031 015 016 023 024

LGS2230MA LCF2410 LCF2415 LCF2410A Shape A t3 2

020 009 007 022

036 024 031 032

024 013 007 027

034 021 014 033

100mm circular plate

parallel to the gate vertical to the gate Gate pin gate 3 points 1.5mm

S h a p e B OD58 ID54 H25mm Cylindrical molded piece

upper limit mold shrinkage percentage (%) standard lower limit

glass fiber content (wt%)

Fig. 4 1

Influence of glass fiber content to mold shrinkage percentage

measuring direction gate

direction A direction B

mold shrinkage percentage (%)

holding pressure(MPa)

Fig. 4 2

Mold shrinkage percentage vs Holding pressure

T a b le 4 3 Molding conditions Cylinder temperature 270 290 310 Injection rate 2 8 2 8 2 8 2 8 2 8

Mold shrinkage of Iupilon / NOVZREX Mold shrinkagecmcm

Injection After 5 days After 10 days After 30 days pressure MPakgcm2 1371400 82840 1371400 82840 1371400 00076 00082 00072 00060 00065 00066 00065 00059 00057 00076 00079 00084 00076 00062 00065 00067 00066 00061 00057 00076 00082 00076 00059 00068 00065 00068 00059 00057

Table 4 4

Mold shrinkage of polycarbonate

a Length mm 8631 8632 8630 8630 Shrinkage 079 078 080 080 Length mm 18460 18461 18461 18456 b Shrinkage 075 075 075 077

Position of gate A B C D

NoteTest mold for measuring shrinkage

a 87mm b 186mm

Thickness 2.5mm

Table 4 5

PC dimensional tolerance (from SPI information) Tolerancemm Dimension 005 010 015 020 mm

025

A inside diameter Note 1 B Depth Note 2 C Height Note 2

20 40 60 80 100 120 140

Gene ral prec ise

152.4304.8 General Precise add the tolerance at 0076 0038 right to every 25.4mm D bottom thickness Note 2 E side thickness Note 3 000 318 F pore diameter 318 635 Note 1 6351270 1270 0076 0051

0076 0051 0051 0076 0076

0051 0025 0038 0051 0051 0051 0051 0076

000 635 0051 G pore depth 6351270 0076 Note 4 12702540 0102

Note The tolerance based on the premise of 3.2mm thickness. 1 This tolerance is not the accuracy including the aging characteristic of the material. 2 Take the parting-line into consideration. 3 As for the shape of the parting, it is necessary to make the thickness become uniform as much as possible.(Though it is impossible to make the thickness become uniform completely for this shape) 4 Note that the ratio of the hole depth to the diameter is not to become the span that the core pin is damaged.

Table 4 6 Unevenness and dimensional tolerance of the sample.

Drawing dimension 29 35 75 A
l

Molded piece dimension 28911 35017 74951 154868 174727 271667 279920 56871 74961 93365 125984 274759 003 027 017 013 014 023 014 005 027 040 028 041 024

01 01 01 03 03 03 03 54 05 03 126 274

155 175 272 280 745 93

278 286

03

278323

286260 034 Material GS2030MR2 N o t e 1 P o s i t i o n of dimension measuremen t

core-to-core dimension actual measurement face-to-face dim ension actual measurem ent dim ension unevenness (+-mm) dim ension tolerance of core-to-core drawing dim ension tolerance of face-to-face drawing

nom inal dim ension (mm)

Fig. 4 3

Nominal dimension vs Dimension unevenness

Fig. 4 4

Shape of molded piece and P o sitio n o f d im en sio n m easu rem en t

material: GS2020M
inner diam eter outer diam eter inner diam eter outer diam eter height

roundness (mm)

mold shrinkage percentage (%)

N um ber of gate

Number of gate

Fig. 45 Number of gate vs circularity (Relation to position of direction of height)

Fig. 46 Number of gate vs mold shrinkage percentage

Table

4 7

Example of measuring dimension accuracy of Iupilon Including the shape error OD 17 16 36 ID 16 18 29 Height 25 21 39 Not including the shape error OD 9 7 8 ID 9 9 9 Height 12 12 27

Shape error Position Material S2000 S3000 GS2020M

Molding machine Sumitomo Neomat N350 120 with Cycap Molded piece cylindrical molded piece OD 60mm ID 56mm Height 25mm M olding conditionsThe resin temperature, injection rate, injection pressure, and mold temperature etc. were

changed according to the experimental design. Data show by the value of 3. The outer diameter, inner diameter, height etc. were measured with 3D dimension measurement machine for several points and their data analysis was done. Including the shape error is when analyzing by each measuring value, and Not including the shape error is when analyzing by the average value.

5 . C A E CAE(Computer Aided Engineering) has been widely introduced to the design of the injection-molded piece as an assistive technology of the product and the mold design. The advantages are as follows. 1 The prototype test period can be shortened because the computer can be used for case study. (2) A reasonable and economical design can be done because the extra design from the safety viewpoint is not needed. (3) The product quality can be improved because the system design including materials, shape of molded piece, mold and molding conditions etc is possible. (4) Compared with empirical molding data, the analytical data by CAE has the generality and is possible for effective utilization. Especially, it can be used by an unskilled worker of the molding. As for the application scope of CAE, as shown in Table 5-1, stress of the resin product (structural analysis), deformation analysis, flow behavior of the resin inside the mold (flow analysis), supposition of the weld line, conduction of heat inside the mold (thermal analysis), and estimation of temperature distribution of the resin at the time of the last filling are conducted.
Table 51
Design of the resin product

CAE Application
Stress, deformation (stress, deformation analysis) Flow of melt resin (flow analysis of melt resin)

Understanding the phenomenon inside the mold

Change of phase Heat transfer (heat conduction analysis) Heat stress (stress, deformation analysis) Standing to cool (heat conduction analysis) Change of shape due to moisture absorption (moisture absorption, stress, strain analysis)

Warpage, sink marks Phenomenon after mold release

Phenomenon concerning the mold

Heat transfer (heat conduction analysis) Stress, strain, deformation (stress, deformation analysis) Heat stress, strain (stress, deformation analysis)

The data base of each resin and each grade is necessary when analyzing, and it is divided into the solid state properties and melted state properties. As for the solid state properties, the values of mechanical physical properties of normal Iupilon are used as shown in Table 5 2.

Table 5 2 Values of mechanical physical properties of Iupilon (Young modulus, shear modulus, Poissons ratio, coefficient of linear thermal expansion) Iupilon S2000 Young modulus El Kgcm2 Shear modulus G2 Kgcm2 Poisson ratio 3 a linear coefficient of 1 6t expansion4 10-5 b cmcm3 2t Notes1modulus of elasticityE 2 s h e a r m o d u l u s G E 2 1 3 P o i s s o n s r a t i o 4 coefficient of linear thermal expansion As for the melted state properties, viscosity data are shown in Fig. 5-1 ~ 5-5, specific heat data in Fig. 5-6, coefficient of heat conductivity in Fig. 5-7, and P T data in Fig. 5-8. 230 797 GS2015M GS2020M GS2025M GS2030M 103 103

103 398 103 146

103 469 103 172

103 590 103 218

103 808 103 299

038 572 636 657 707

0365 284 541 308 635

036 241 535 262 617

0355 215 505 245 600

0355 178 480 226 586

Fig. 5 1

Viscosity curve Iupilon H 4000

Fig. 5 2

Viscosity curve Iupilon H 3000

Iupilon S3000 flow analysis data

Singlepoint polymer specific heat Singlepoint polymer thermal conductivity Constant polymer densitysolid density melt density Freeze Temperature No Flow Temperature
2 2858E 03 2 6000E 01 1 2000E 03 1 0500E 03 144 170 J Kg deg C W m K kg m3 kg m3

Fig. 5 3

Viscosity curve I u p i l o n S 3 0 0 0

Fig. 5 24

Viscosity curve I u p i l o n S 2 0 0 0

Fig. 55

Viscosity curve Iupilon SlOOO

Specific heat (J/gk)

thermal conductivity (10-1W/km)

Temperture (K)

Temperture (K)

Fig. 5 6

specific heat data

F i g . 5 7

thermal conductivity data

average cooling rate

specific volume (cm3/g)

Fig. 5 8

T () P T data

6 Hot runner molding The hot runner molding of Iupilon/NOVAREX is used for the purpose of reducing cost by the reduction of the cold runner, improving the flowability by the reduction of pressure loss of the cold runner part. As for the hot runner system, the heating method, different types of the gate seal method are variously developed. The advantage and disadvantage by the difference of the heating method are as follows. (1) The internal heating method becomes adiabatic when the heater position is away from the cavity. (2) As for the external heating method, insulating the cavity from heat is necessary though the flow path is simple. The advantage and disadvantage by the difference of the gate seal method are as follows. (1) As for the open gate method, the structure control is simple, sac back is indispensable and there is a limit to the gate. (2) The mechanical seal method has small pressure loss. The gate sealing is perfect and there is neither drooling nor stringiness, but on the other hand, the structure is complicated, and there is a limit between pitches of the gate in the case of multipoint gate. (3) As for the thermal seal method, there is a limit to the gate diameter, and it is hard to keep the gate balance in the case of multipoint gate. The points to keep in mind when selecting the hot runner system are as follows. 1) There is no stay of the resin. 2) The structure must be simple as possible. 3) Neither drooling nor stringiness, and the adjustment must be easy. 4) There be an adiabatic-efficiency at the gate part. 5) The color replacement must be easy. 6) As for the valve gate method, there is no resin stay in the sliding part of the pin, and the pin is not eccentric. 7) The maintenance must be easy. 8) The gate diameter is large, and the pressure loss is small.

7 Reuse of Iupilon / NOVAREX As for the regrind material use of Iupilon/NOVAREX, the method of use by mixing 20-30% of the regrind material with new material is recommended. The results of measuring the physical properties of 100% and 30% regrind materials by using Iupilon S3000R are shown in Table 7 1, 7 2. In the 100% regrind material, after repeated use of this material, the reduction of molecular weight, the increase of discoloration degree and the reduction of overall light transmittance are observed. On the other hand, there are few changes of these physical property values in the 30% regrind material.

Table

7-1 Physical properties of Iupilon S-3000R (100% of the regrind material)

Table

7-2 Physical properties of Iupilon S-3000R (30% of the regrind material)

The relationship between the reuse frequency and strength of Iupilon GS2010M (containing glass fiber) is shown in Table 7-3. In the case of glass fiber reinforced PC, the strength falls because the glass fiber crushes by repeated use of the material as shown in this table. The 30% regrind material mixture has less strength fall than the 100% regrind material. The various factors to affect to the performance deterioration due to the regrind material use of PC are summarized in Table 7-4. It should be noted that the reuse causes the performance deterioration due to the contamination of foreign substances besides the degradation of the material. The general notes for the use of the regrind material are given as follows. (1) Because the mixture ratio of the regrind material changes according to the heat stability of the material itself (presence of the additive and the filling agent or not) and molding conditions (controlled state of the regrind material, mold temperature and dwell time) etc., the mixture ratio should be decided to correspond to each material and molding condition. (2) The regrind material should be used without any contamination of foreign substances (other resin, dust, mold release agent, oil, insert metal fitting) etc. When the regrind material is used with the adherence of the mold release agent that had been used at the time of molding by the transparent material, the molded piece may become bleached. (3) The use of the regrind material at the molded piece which is extremely affected by the contamination of glasses lens, optical lens, optical disk substrate should be avoided. (Refer to Table 7-5). It is better to use the regrind material for other application that the contamination does not become a problem. (4) When the crushed regrind material is used, the measurement at the time of plasticizing becomes uneven when the screw diameter is small, and the dimension of the precise molded piece may vary widely from the tolerance. In this case, the management of the grain diameter of the crushed material or the measure of the re-pelletizing etc. is necessary. (5) As for the molded piece that inserts metal fitting, it is better to adopt the method that inserts it after the molding as much as possible. Table 7 3 Reuse test results of glass fiber reinforced PC Reuse frequency 1 100 reuse 2 3 4 1 30 reuse 2 3 4 Average fiber Bending elastic length modulus Bending strength m MPakgfcm2 GPakgfcm2 241 187 154 146 140 1121220 1111130 1051070 1021040 1091110 1161180 1161180 1161180 1161180 35336000 33033700 31031600 30330900 29630200 33834506 34034700 34034700 34034700

Classification Virgin material

Material I u p i l o n G S 2 0 1 0 M 1 0 g l a s s f i b e r

Table 7 4

Various factors to affect to the performance deterioration of the regrind material

Factors Contents Heat deterioration of Heat stabilizer material and crushing Kind and amount of colorant, kind and shape of filling of filling material material Deterioration due to Preliminary drying (temperature, time processing conditions Molding temperature Molding cycle Capacity of molding machine Contamination of foreign substances Contamination of mold release agent adhesion of blowing mold release agent used in the previous molding Adhesion of oilmolding oil etc. Contamination of black speckscarbide Contamination of metal powderinsert metal fitting atc. Contamination of different resin Other contamination

Table

7 5 A n a ly sis re su lts o f c o n ta m in a tio n 12 200 5290 8790 25 50 680 1220 2000 510 0 100 90 200 1021 0 0 10 10

Contamination 0505 sizem New material 20regrind material 30regrind material 50regrind material Notes) 12000 522320 858710

1406230 16680

Measuring method: Laser light scattering method HIAC/ROYCO 4000 Model Particle counter Material: Iupilon H-3000R

8 Annealing treatment of Iupilon / NOVAREX 8 1 Annealing treatment Generally, the residual stresses exist in the injection molded piece due to some causes. Especially, the residual stresses are empirically known to be large at the vicinity of the gate, the edge part of the molded piece, and the part where there is a big change of the thickness of the product etc. When there are residual stresses in the molded piece, if oil, grease, printer's ink, paints, and thinner, etc. come in contact with it, the crack will occur. Therefore, in order to remove residual stresses in the molded piece, the so-called annealing treatment is carried out by heating at the temperature which is about 20 lower than the glass transition temperature of PC (Tg 145 ), then maintaining at this temperature in a given time and after that conducting the cooling operation to room temperature. Iupilon / NOVAREX is annealed at 120 125 for 1-2 hours. It is good to carry out the annealing in a short time for the simple shape and when the thickness of the product is thin, but for a complicated shape or if the thickness of the product is thick, annealing for 2-3 hours is required in consideration of safety. The results of the relationship between the annealing treatment time and the residual stress by using a tensile test piece of 3.2mm thickness and a bend test piece of 6.4 mm thickness are shown in Fig. 81-1.

residual stress (MPa)

thickness x thickness

anealing temperature 120

process time (min)

Fig.

8 1 1

Annealing treatment time vs residual stress

Fig. 81-1 shows that the residual stress decreases with the annealing treatment time regardless of the thickness of the sample.

Fig. 8 1 2

Change of physical properties by heat treatment of Iupilon / NOVAREX

The crack concentrates on the vicinity of the gate and the edge part before annealing, and on the whole, a lot of residual stresses at the surface coat are observed. However, with the test piece of the simple shape like this test, the stress relief advances to the extent that the crack is slightly observed if the annealing is treated for 30 minutes. As for the detection method of residual stress, refer to Section 24-2 of the molding strain. The hot air circulation-type oven is usually used as the heating method for annealing treatment. Water and oil, etc. can be used as heat carriers for other resin, but they are not proper for Iupilon / NOVAREX because they cause the hydrolysis and solvent crack. When annealing Iupilon / NOVAREX, the following changes are observed. (1) Elongating the annealing causes the decrease of impact strength Refer to Fig. 8 1 2 . (2) Change in dimension due to heat shrinkage (heat shrinkage percentage 0.1 0.15 at120 ). (3) Cost increase From the above results it had better avoid the annealing treatment as much as possible. The main purpose of the annealing is to remove residual stress in the molded piecebut in the case of Iupilon / NOVAREX, except the necessity to conduct the annealing treatment due to unavoidable circumstances, the product design and molding conditions should be considered to reduce residual stress. Recently, the method of applying the far-infrared radiation is known to be effective for the annealing treatment. According to this method, about 1/3 - 1/2 of the annealing treatment time can be shortened in comparison with conventional method. The summary is introduced in next section. Please contact us for more information

8 2

Annealing effect of using both hot air / far infrared radiation systems

The following effects were confirmed by measuring the residual stress after annealing the molded piece, surface temperature, and inner temperature of the molded piece. (1) When using both the heating systems of hot air, far infrared radiation together, the annealing treatment time can be shortened 3-4 times in comparison with the case of using only the hot air heating system. (2) In the case of using only the far infrared radiation heating system, the heating rate can be rapidly quickened by raising the heater temperature but it could lead to the excessive heating of the heated piece. (3) In the case of using both the heating systems of hot air, far infrared radiation together, when the current does not applied to the far infrared radiation heater and it is heated by the same temperature by hot air, the molded piece temperature raises at the speed almost similar to the time of applying current. (6) Because the annealing treatment time depends strongly on the heating temperature of the molded piece, if 5 minutes have passed after the molded piece temperature reached 120 C, the annealing is completed. (7) Table 8 2 1 Change in Izod impact strength after annealing Test material Iupilon S3000 t 3 2 impact bar 0 25R with notch Far infrared radiation annealing Oven annealing Treated time IZOD Strength Brittle failure Treated time IZOD Strength Brittle failure min 0m n5 hrs 0m n5 0 821 0 821 05 05 1 870 1 811 05 05 3 835 3 665 05 15 5 830 5 532 05 25 10 830 10 262 05 45 Annealing conditionsFar infrared radiation annealing Panel temperature 180 Hot air temperature 140 Oven annealing 120

Sample thickness: 3.2mm

residual stress(MPa)

time(min)
Only hot air120 Hot air120Far infrared Hot air120Panel radiation135 without power

Fig. 8 2 1

Residual stress decreasing curve of flat plate

Mitsubishi Gas Chemical Company, Inc., our parent company is the patent-holding company of this technology. (Registration number: 20 77432 Registered on August 9, 1996)

International System of Unitsabbreviated SI

Main Unit Conversion Table N kgf dyn 5 1 110 101972101 1 1105 101972106 1 980665 980665105 kgf /cm2 atm mmHgTorr 5 6 10197210 98692310 750062103 1 967841101 735559102 1 103323 760000102 1 135951103 131579103 kgf /mm2 kgf /cm2 101972107 101972105 1 1102 1 1102

Force

Pressure

Pa 1 980665104 101325105 133322102 Pa or Nm2 1 980665106 980665104

Stress

Energy WorkHeat

J 1 3600106 980665 418605103

kcal kWh kgfm 7 1 27777810 10197210 238889104 1 367098105 86000102 6 1 27240710 234270103 1 116279103 426858102

Power

W 1 980665 7355102 116279

PS kgfmS 1 10197210 135962103 1 133333102 1 7510 1 11857210 158095103

kcalh 85985101 843371 632529102 1

Viscosity viscous modulus

PaS 1 1103 1101

cP 1103 1 1102

P 110 1102 1

Kinetic viscosity kinematic viscosity

m2S 1 1106 1104

cSt 1106 1 1102

St 1104 1102 1

coefficient

Heat conductivity

WmK kcal hm 1 86000101 116279 1

JkgK Specific heat 1 418605103

kcalkg calg 238889104 1

CAUTION
Data described in this catalog are typical examples of the measurement by our companys test method. The use application described in this catalog does not guarantee the application result to the said usage of this product. Please consider the industrial property and use conditions etc. related to the usage and application described in this catalog in your company. Please refer to the used material, technical information of the grade and product safety data sheet (MSDS) in the handling of this product (transportation, storage, molding, disposal etc.). Especially, please confirm safety sufficiently when using the food container wrapping, medical parts, safety tool, toys for the infant etc. The chemicals (carbon black, titanium oxide, zinc oxide) that should notify in applicable laws and regulations, Item 2 of the Article 57 of the Occupational Health and Safety Law, Item 2 of the enforcement order 18, name in attached table 9 etc. may be contained in case of each grade colored article of this product. Please contact for the details. Because some items of the MEP products correspond to specified articles of the controlled target products under the Export Trade Control Ordinance, please contact us for the details. Please conform to the applicable laws and regulations of the Foreign Exchange and Foreign Trade Control Law etc. when conducting the export and sale of the MEP product and the product that included the MEP product. The deterioration of some articles in this product may occur due to the residual fumigant which is used for the fumigation treatment of the wooden pallet. Please refrain from carrying out the fumigation treatment by loading the corresponding product on the wooden pallet or loading on the wooden pallet that the fumigation was treated. There is a possibility that harmful gas and fume are generated by the heat decomposition of the resin at the time of molding and cleaning the tack. Please install the ventilator for the local or the whole ventilation. When the product which added fluorocarbon resin is heated above 250 , the poisonous gas may be generated due to the decomposition of fluorocarbon resin. Therefore, the ventilation of work environment should be done sufficiently. Also, please do not burn this product when dispose it but carry out the landfill instead. Please acknowledge that the content of this catalog might be changed without notice for the revision.