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COA'STANTE

DE ACDITATE

s,: DE' CONSTANTE


.BAZICITATE
.

P,roil. tllARlA NISTOR

Ucculloh.ilunlilnu-ilurlpcF

Br&llr
,

dcnumldlc. Accstc occrclfll ec pot rcaotve. dac! rc, npru:lrrltr ln rcdr rtuclurr floolrd rubdenNc daic gltc irnrlhc.zl porlbllltalca unor cfcctc cicotonlcc : mu stcdcrln rnolcoula Apol !r podc propunc bruhli lor dln punctut dc'.icdsrc ccnrt dc'p6blcmL Valldarm r&punrudlor a{rtroc rnC blno, dacl rar oompt r d, vrlorllc ooncladclordc aoldlttlc rqu de

' [n uHmut dmp au aplnrl nuhcroarc cxcrcfil oarc rcllclttr rran aror ln ,ordlnc orctoltoarc .au dorcroro&oarc r aoldlt$|, rcrpcctlv r bazlclttrll unor rubctantc. pcntru .r oen to dau numd

ba:lcltgtr,ddcmlndcotPalmctilel..' r,
PcnW

o llrtl cu valorl slc conrianlclor dc.rlditrlr 9l de batlaltd. pontru tubrfanF oupdnl' ln'dtvtrrc rurlc
lG {mol'1't; l. 'Aoltl anorganlcl monoprodol ' &oto3 HNOo 3,gg.1o{ . HNs azothidrlc " l,9.1Or '7,95.1o'ru clanhldrlo HCN lluolhldrlc HF 8,31.10{ hlpobromor HBro' 2,5.10'c lodlo HlOc 1,6.10'r hipolodoo Hlo 2,3.10'll tloclanlo HNCS 1,4.10'r , clorol HCb : t,1.10 . 6.10'c hlpoclorol HC|O. rI Aclzl enorgenlcl potlpnttlol I aulludo HaSOr ,HSOI.
FORMUI-A
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. vcnl ln ajulorul

cclof lntercraf, publlcLm

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3,4

4J2
9'1

9,2 8,60 0,97


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HOOC(CHa)aCOOH

tag.tot
2.10'!

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o,{.10{
9,3.10{.;.

lrooc{cHdzcoo'
HOOC(CHdsG!OH HOCC{c}b}rCOO' H@C{C}ldTCOOH HOOC(CI'h)rCOO' Ccl'L{CooH}r CcHr(COOH)r HOOGCH=CH:COOH

.1.6.10''

3,8.t0{
3,9.t0'o 3,9.1O{

ltalio (o)

1el.t0
28,7.t0

holtallc (m)
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1.10<

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lenol

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nlhbfenol .

QHrOH NQQHeOH
NO2C!HIOH

,,m-nhrolcnol
p - nilrofenoh
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9,77 ' 7,12'


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" i-

i -

i;tii
it.,l
,ri+i
i{r,.

pKa pentru acizi$ens,oiel sutrstituig.a


Suba$tuedl

--

,ij

lr il ptiiai':1
i.l.

pKo pentru po:ifiilc

Hi l.4,ao | .,a I aeo-l cxs I s,gr I l,zz I 4ps-| I' I .r r. I g,zz I g,s6 l 1tl l | cl, I i,sa I -spg--l-s,ez _l I lj Bi .l e,ss _l s,ar -f 3,ez I l

orto

mct|
3.9f " 4,14
3,64 3,77

NOr

2,21

3;42i, ltl
9,55
3.68:j11 ti
ii

GHI
CN
CFs

3,46 3,14 2,98

OH

4,08

4,57:"t.

Cbnstante de bazicitate

| ,aara I formuts:l-&-lmgFlt) -lI | ' smoniao I Nrtg J- _!,1 L_gg!!"rl^" I cF.NH; dirnoritomina I 'rrtmotiromtna I (cxs)aNl L, iao.ro{-l | I tcx.l.H-T lF.tor.l oritamini I caxs-r{Hi-f--s4o.1orl I lksi't,iri^a,l tqHd.NH I

Baza

Formula

lG (t r9l;tlr
.,4,9, rcjt11ii

m.toluldina p,toluldlna dimotllonllino diotilanillna dilonilanlllna pyrldina etllsndlamlna

CHrQHdl'lz
Cl-loQHlNHz

fi.8.r0':9
I1.5,10'rq
36g110i,!9
'
i

ii
r

QHfl(CHrla
QHsN(C2H512

(CoHcl:Nl{
CIH',N
HaNCHeCHzNHa

7,6,

lo!'
rl,
!

I so,s.ro-5 | TTrro1rl
l-,rs.1d.'Tl

1,5ilqf

9.l.lo'? 1.5:10'7 'l5.ror0 p.enisldino lCHlOC"Hr.NHz


I

nr.ruricicJino

|
--

-'----

2.lo'tu

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