@ E) ",TN, Lra-Ffff L - ) FR ,: Afato - (
@ E) ",TN, Lra-Ffff L - ) FR ,: Afato - (
@ E) ",TN, Lra-Ffff L - ) FR ,: Afato - (
'ARE I\l
ii
q g | .t(iln*carkuet,
ernli.,t
aharxtahbe ( e*erue)
n,*t
,1{rq.{ ,-vurhlQ
1,
lgr.2ary1'ag
ahe,wele
cs( xe.cJieqt
afato-{
C- Hr,u-
n.
{oL,.,'"otn N .E ,, 4
or,
ga**a"h
,ur*(ea,,tqti (r 6*ae*.,{r.,' efi| 4ul, , d<cl ",tn lra-ffff*l- etc\.ui t-' 4 = {: I I -) fr;, J*,l&kt 'hen ptrei,trr,t' ote.,u-t cio t i'Jt a1n.,- d,r* /e**oo je eL,frie -u,n. & teaofri r-aug*A.pfr-lu&
,
eiut-* E) '{"tn
5/t
",
Ke'kwle
e4.
i\, = \-,
o*'
(,\ \-c4s
=,_i
q4r
E ta,\ =%fit
at'\\--'
d-
,tre;
*6 6-.)/
J.x
f,,
r->
2,
le,.xa<rnt(
aJr*d"e..*d
,|
I
Crta '.r"u&
'
Jt \ .i(
aquJd| anyAe:
t4t $--'
l
leateenL
I I
(\ \;
+A
* -4, c( dt
CI.
r,^\'1,*
c(
, Jec, h,.r*t-.-,r*r!
eo-,.&'*e
'd
3 Arq
lz**-u(
,-
r*
* I i =t le*r<,uttL
c,Lg
coilaefth- qrqqtcld'.&.
___ *--*
.__*"*T*_:* -._=*:*=_.*_*=**.y*.
,l*le
-:
eqi-e-
kekQe ryrr';tcrrL.
(u a/ta. &
,*t
,. dpx fe*-*,-.c(o .nshurlotr;l: Cu &t t*dlld ' ,* ',.r.e:g-fua'V .Lr4q\a) ' , J o-, . ,*, oE **$n ,rach,t -li5ocf,c, . "lui-{,Q (, ' /r*se,uti +
r.
J,
'
)I
-)
Aeoef+le
/ t
cte
V
ael,AA o -tt*
.,r.
ftgdn&i,.rfu"
, lrV, -(uou,ua)
(t cobe.
f'
u QId ,r{"ttn1
&
etudd&'
e,wojfrh<
arfW*lutd) n *3 fLecc
^
I
-'/
\-r
I
*#,
^
e*
,rf ayt /ofi''4 "nto a-6' a&da -, feue.z6usfi)a;, fi.1 /4^ O) p - o'&, u.rr{itri - a eyeU,*e,*ta ezfa"ole*ta J*htLel
J
a
alaraco;;g1
t, -->.
---='
l'
lft
f . ,lrci lun 6i,*rt1.,.a ^k ,tt'*frt e Lt a" e q^ 4tel,t, orfa*y cau$\,,tt /**utkk krftctV :_ f
4Q
+(, ,
* "-"
ofi^ fuu*{nt
al
.,4
l
- o''d r! -
-l
/'\
b,,'! o
.aaearwbd
- ccra.,c*bd'
;
/-
gsl
(
l' , asc 'rqutt
cie
4u*l*c{ .rL
/
oL
acliqeerui;
t
ft
f{.
.
r,,
,iAtl
I'i
f*6tu
ee"'di.ruic/-
erLu
-t-efnfui
f"
of le c ,f.*'rcLl
ir
l
-)
n-
,ctt
l&cutea+o
t-
en+tuwttt
c*a+trAto,.
f JedeqJtt|- jljLJti
, ,uun^i{ *it,"tn (
f;u
j.*lrr*7Ett-tudq.e &Ur^If
-,.-*{e n1to^
/re-u.qe.'*.,'e
i,
c,"( cterr&<tle
rzrczrhai
c. =
"..
,
4d(-!;
flX\
t*tlt
'
\\r,
,/
,.(*
Jil
I y 4u*t
4cen{u'za!t'
tc
'd Je, o, a.,r,.t-,rrr*a- -(g e - e ,nrr'r {a,t& .. , 1., 4 e & e ol,nt cicL., fr^*& .u*iftn
A.rr4tr,r,
Jelen$-tq.fi'
olttili
r).,.^. eo,rqd"t
-))t)
5-^
?adr'o""!' ahe,v&b'
(u,
.r.'l
ol) nsl&"*
J
&1,"t
*tLIu; ( to, tl e)
'-)
-)
f ,l el, irl
'i.
Cdueru"rtJ
(-g{,.zoc) 6*
qse-i
, '44pI I ' -/
cv\e,ufle
li
Ior'* "t1&) --) &..r.*e.',..r-0 j;tg uu,v -b'cL*cl- i*ee{al , & *dr. q\Awd*. Tdf, G) k.u4,,ur!., tc a,va*e\d. uyL', vT-, f,,^"t rtttii I u,-f[k ro4rg'
fttaq{stn
*di&-,a}
, ,n!*t,;d ok
ju,vl ,kedtdr.,0r .-r1.,. afd, det taf"l"k -rL *Lre,u-i; *9q,u,i) r q l',4
*) '*rru AtU.^l eatn*gvrh'e A". *\a.-d,icg q;b ta^ 4rLfiid f . .t* tlqh 4t*"tJi .,,.r.le.r'Lci< {u,,'t' . ,*c.-} Jet;,vtaie
o+-tafe c,u
,/'
p t/6a/l1.- Jlo
7 t . &l-**
,*el.ertttel",L )
.
,o$ar{'ffii<
t
-'t
+.
ft
'
C, 4o ce #e
Q tle
lkoolfndu offi**)
J
rt,
*'Y-g
, (o4r^x + ttx (
i
Je arabre,*,*e)
r W,.:,:* ,# e)b- c*4ce +'(Lo q 4**tr4a,nol",b, 0uttr-t Tz W c6t- ?+ h ? (a- /" ,'oL,t"t rr/
ttc
-) oo*d. * j*flscfuee .ant lrkfiki*( iv ,*4-&. *,*ri dot'uo{ ,vtoveottlrstt[tu| *L k*."nur+!ral, 4"q:r!utor(,pa *a.{ f e*< - -( Jrlrr&;tae.qt ,lt p*J, ,.a.,ola. . .,/e *ohir- srAi*rtr,e-rhlri l*
-2
feeutde** ,*4,leo
tuIiEtue,n*,^(,.
eaUi .*t*
-feah
r'r-tg1-d&r
er&..rh
flz<srt{
I -) ttio**eo*i
f*
'1
.ut*I,
kJ*t
e\dt',utu(. z
*&i,tt
iEx
2')
Peacf,r'
d"
a&'he
14 M" l4
g
0
'ldlel
A.CilJ
),
t,
I
l'
/z\
\--l
tl
* #4t
1
-zL aAr"-lafz
rl
c,tu {e.e-
ltY 11 A, *j"Ut5{r; ,A
\,
*/.
t iL/,l'
J")
. t
-!
A
'iO3
4 J{zO -, 3o : O;{-
eu=
a-t JLOI
w
'l)t
l*tx;
&*'tElt'*c,LoA.
ee{ruole,.4a- 4f , ,d
,r - r)4e,uttiuti
&*
1
t'.r.!u( ,n&L
ln*.t<,*^e
, L<.ailti
, 7rtexa-.(
(,/
wqr'0-xi4n,,rlti
ho&
a:
)\
c_o
ft
I,
tt t-/
-) e4
+A .4
-a
--) L grao
- rtp
{zAr
(P-cooi
Ja .L
t1 *L''
r/ -e" \o
a*&ur'olnteli
q,
l,
/''
v.Q-
"J &r
. hn\
Cr
ela.
& &, or f,
taob
,tteou
f:\
c (aa.r )r
+
,o
e#
- er+,
ft&(k^x. \ e^Lrn_eo_)
iA
1)
i\
* an
*o'l
l autuov.aar)
aIleJ"J"
le rlf'-rne
- - .h -*-ftq.*.*.,.r-...*,;xr4*aiq*-'].-*-*-F:-.*-*.--i,o,ra.,.-,
-t
A
&jfote4 -*"c.(-fo' a oi,vlu,,.Lbt & *i,r,ti..*{ tfuaa-toooio die $ct ti lh veJet,ea- aA l'rulartr' cao>rtki .-re(a,Lt+-/t )c uu.&uon Fottc(f,l".,* A' 4^ uan*aihee& .fi"de:te) ga.ril. de cso.et-ri : hoo/pez; lto",/.Qtlr, ; .4"/,Q+u J 0 tub(. oO" , v6-lr*t' de, beu;*t S ,rt,L" f
--r--r-x..4,ir-
o.l*k
/
cr.rcceigac
'
4fu
g at
A
I
'/"
l/r'\q'fu
" Je
do+<o'l.irbe
a<tL'*LLL(
O*,yrf
aJr-ouralrai
;' ol4-ie a 4.
-1
X"&.o,.*{"
fu,ut
aair.
,*t\el
oCr&:o: ,-
,(i ^rli,
,1-vdt (ta-1woe1 ,:
L*a<^,
fr*nff
(tn.atto'c
)i
Llu.n+L'
|'2,'^,
rwdfidLtJ 'ua. .t
tai D. \-
n"ro-#d
,t; ^ f/,
4n
" "t
I
1 3&'
1/
@ fty
-/,"1y"'-4'
2-f
f, = eL.4.;(,, elo,ho("Li(,
l.lh
cQ
c)la> c*ta
* x(X -a eth -
ett*-c{
Qt"
+eftJ*cq-eX
*:t
CeHr.-et1v*clt +i(aL
)
Qhr- ch -)
)i
ubi
ft-ott
( ,.umti' ,tWo)
Cok,-Cq-bx Jn""cl't"
@ Y:* **r::*:" :: *"'tt:: ,tt'I *', ,Leaefivi'"*de -.+"r,;(; ( , ,idi;c{v {.i't )' ",ai, rytdl,'Ji
l)
. / .'
"("{"r(,
.
:o
l,J
,teaefrb*ai
' ,
Q 4, +
ctr|c(.
-J
l|, "
q fir 'LH&
.r
treQ
J'C6tl6
i.i,lr
ot,c*clj1 ,-" Qnr-Cl,l-k+ tJte( ,l ii,.-'i r tt ' i riFqCtlL 'fq& ^.i i gr.
:--r -->
.I
:):
,
A.
ia"l
M
,
gtf iv(r
'-
JL
5"\!L
,,0 + {c#,
'
.trl-:
,.u.
'
i {t
qfi.
.J
f lr
c"(J-c -c{ Jt
t'
-,
,4\ r:r
ll
'1y-r
-4 ,' cft4,*,{Hn, *.r-2 qlf" -i, C4t CHJ Cfia- !qn' *-l-2r iq* - c,tt - cnt* , Qkr',t ' Cj't+ o * lGlrr- g rri=,cf{.,.-. ||*,t, r- c{- c4r
i'
rlt
H)'- w3
/(,
,{fu*Xt'
dt ,J
,l
'
Arl,
..''.'-....-) Celfi-,-
qI
l
?*c^(i,
r
I
4,o
l
+'4kr.,
Qlf.
r.tI
cll+'
LLo- Qttr
t- qu" 'a, /
I
43
ot.3
5)
@
'fr^,**e
-rLbt.*
!atu^ -
'.'......,|
Colff
. Qtilf
t-
atte&\
Pat ,A
,c\)
)tJo.-
d
o{ \.r.
0-h
+ < *tsh
I
i,
*
i. I
ctfa=Q
'..1
+
i
fiQa
.-..+)
1;'
2rr0fr-
.7')
'
+ezo
l(,
oo'orli/-'
ReJucei.ea
Ck,:,'-i.rri1r/r.u
A'
Kti*th
- Voq),t
l&t';hj;P,o"Arelc
g")
ed.t.
lu;* '
oorhtr F-01,
l'
+ c{ JEI
ao
*n '.c*d- c6+ + tL O
crhn -eoo*
'lo - e?e
oo*
l
jr
-lv = /,J.[ g(
+\
i__
-t
Qc$s
4,v
* Nt + eU. +2hLC
+Z.fu a 0*
6)
-/ UJ.l2- Atl
lo
x)
',3.+
w,i,&.
oo4 u&'a
'<4o
* c;,tr'
?)c'v
9)
-)
1 /11aCN
cn
Pr*
etv +ilaoJo3
-;
ON
t > c!3 -c*Aff i
-:-) _Eo:
akt
c4
CtiJ
/o)
vl -
\o/
clq
keu ,, c.x, -
L*r- ou
-4o)
oR- cN
'*,r-
-)
u:outrhrw
,u.'vedv' as!ve.-*
l
fti/^'-{ #*'o)
t0/{}65',
J
'APC*uCI
r-,lr+
G,ti.5*'u t
- Ml X + Rt- NHr-*> R_u + ?i-MR_ ,t4c y '<Jr 4 4 + ftt- 466i1 R-Mq x ?--A + a1- c_-lovr -, 'Q- Ua X I ke=s,q --) ?-k + c= e-itfx 4
'P
{'
q:eil@g_- odlAi ----l-.-:/ffi r:,'i :l ,h"a PUi eh"a + PUJ X ?: cl(e - O Ut1 X I
7-cl.t4 7- clt'
ll
t\
a4 ad -) +
?)dr
,1,
'
\,,
Efi@g
COA'STANTE
DE ACDITATE
Ucculloh.ilunlilnu-ilurlpcF
Br&llr
,
dcnumldlc. Accstc occrclfll ec pot rcaotve. dac! rc, npru:lrrltr ln rcdr rtuclurr floolrd rubdenNc daic gltc irnrlhc.zl porlbllltalca unor cfcctc cicotonlcc : mu stcdcrln rnolcoula Apol !r podc propunc bruhli lor dln punctut dc'.icdsrc ccnrt dc'p6blcmL Valldarm r&punrudlor a{rtroc rnC blno, dacl rar oompt r d, vrlorllc ooncladclordc aoldlttlc rqu de
' [n uHmut dmp au aplnrl nuhcroarc cxcrcfil oarc rcllclttr rran aror ln ,ordlnc orctoltoarc .au dorcroro&oarc r aoldlt$|, rcrpcctlv r bazlclttrll unor rubctantc. pcntru .r oen to dau numd
ba:lcltgtr,ddcmlndcotPalmctilel..' r,
PcnW
o llrtl cu valorl slc conrianlclor dc.rlditrlr 9l de batlaltd. pontru tubrfanF oupdnl' ln'dtvtrrc rurlc
lG {mol'1't; l. 'Aoltl anorganlcl monoprodol ' &oto3 HNOo 3,gg.1o{ . HNs azothidrlc " l,9.1Or '7,95.1o'ru clanhldrlo HCN lluolhldrlc HF 8,31.10{ hlpobromor HBro' 2,5.10'c lodlo HlOc 1,6.10'r hipolodoo Hlo 2,3.10'll tloclanlo HNCS 1,4.10'r , clorol HCb : t,1.10 . 6.10'c hlpoclorol HC|O. rI Aclzl enorgenlcl potlpnttlol I aulludo HaSOr ,HSOI.
FORMUI-A
.
. vcnl ln ajulorul
rActtruL
PK
3,4
4J2
9'1
o;85
l.g7
7,3O
-10.
.1,9.{.
eulfurl
rulfhHrlo
H2.SOo
1,210'e.
..1,76
HSO$
HaS
HSF
i E,alo{
.
8,9.r0'e
7@'
zolt
'12,9
' t,0.10'tc
te r -v
l
l-e..t^
malonlo ruoolnlo iglutrdo edlplo
llOOCCll.@OFl
HOOCCIhCOO'
HOOC(CHa)aCOOH
tag.tot
2.10'!
iitrl
o,{.10{
9,3.10{.;.
lrooc{cHdzcoo'
HOOC(CHdsG!OH HOCC{c}b}rCOO' H@C{C}ldTCOOH HOOC(CI'h)rCOO' Ccl'L{CooH}r CcHr(COOH)r HOOGCH=CH:COOH
.1.6.10''
3,8.t0{
3,9.t0'o 3,9.1O{
ltalio (o)
1el.t0
28,7.t0
holtallc (m)
malelo (elr)
t42.to't l,7.lo'ts
0,75.t0'' 5.4.t0'r o,go.lo t 2,7J.6t
1.10<
,t,
M Fonoll
lenol
:.
o:
nlhbfenol .
QHrOH NQQHeOH
NO2C!HIOH
,,m-nhrolcnol
p - nilrofenoh
,
ii
,ll:'i
NqC.l'LOH
S5idlnitro-tenof
(NQ)zQHIOH
(NOrlaQHoOH
4,OO i
'3,7,1
it
"i
(NQIaQHsOH
2.lo{
0,16
),798';
llr;i
.',1
-l
:r
" i-
i -
i;tii
it.,l
,ri+i
i{r,.
--
,ij
lr il ptiiai':1
i.l.
Hi l.4,ao | .,a I aeo-l cxs I s,gr I l,zz I 4ps-| I' I .r r. I g,zz I g,s6 l 1tl l | cl, I i,sa I -spg--l-s,ez _l I lj Bi .l e,ss _l s,ar -f 3,ez I l
orto
mct|
3.9f " 4,14
3,64 3,77
NOr
2,21
3;42i, ltl
9,55
3.68:j11 ti
ii
GHI
CN
CFs
OH
4,08
4,57:"t.
Cbnstante de bazicitate
| ,aara I formuts:l-&-lmgFlt) -lI | ' smoniao I Nrtg J- _!,1 L_gg!!"rl^" I cF.NH; dirnoritomina I 'rrtmotiromtna I (cxs)aNl L, iao.ro{-l | I tcx.l.H-T lF.tor.l oritamini I caxs-r{Hi-f--s4o.1orl I lksi't,iri^a,l tqHd.NH I
Baza
Formula
lG (t r9l;tlr
.,4,9, rcjt11ii
CHrQHdl'lz
Cl-loQHlNHz
fi.8.r0':9
I1.5,10'rq
36g110i,!9
'
i
ii
r
QHfl(CHrla
QHsN(C2H512
(CoHcl:Nl{
CIH',N
HaNCHeCHzNHa
7,6,
lo!'
rl,
!
I so,s.ro-5 | TTrro1rl
l-,rs.1d.'Tl
1,5ilqf
nr.ruricicJino
|
--
-'----
2.lo'tu