Dehydrogenation

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Searched for : dehydrogenation In folder(s) : G:\Back Up\HD 120 GB\Part 1\College\HandBooks Results : 141 document(s) with 1095 instance(s) Saved on : 9/18/2012 9:23:39 PM
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: Chemical_Process_Equipment.pdf : Chemical Process Equipment Selection and Design : : Stanley M. Walas : Referex
is a suitable dehydrogenation accelerator; the most favorable temperature will be different for each
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catalysts. They catalyze hydrogenationdehydrogenation as well as many of the reactions catalyzed by acids 4. Dehydration and dehydrogenation combined utilizes dehydration agents combined with mild dehydrogenation agents. Included combined with mild dehydrogenation agents. Included in this class of catalysts are phosphoric acid,
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13. Hydrogenation and dehydrogenation employ catalysts that form unstable surface hydrides. Transition-group and are the hydrogenation-dehydrogenation component of the catalyst and alumina is the acid component
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for hydrodealkylatisn and dehydrogenation reactions Palladium-on-alumina catalyst, for selective hydrogenation of acetylene
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operation feasible; butane dehydrogenation, for example, is done this way. Because of their
long

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: B568F9B71AFF6F12BB1B9F5694CE1.pdf : : : :
and hydrogenation and dehydrogenation reactions. Hydrogen Blistering. Hydrogen blistering is caused by atomic hydrogen

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: Air_Pollution_Prevention_Control_Handbook.pdf : Handbook of Air Pollution Prevention and Control : : Nicholas P. Cheremisinoff : Referex
processes: (1) dehydrogenation of naphthenes to aromatics; (2) dehydrocyclization of paraffins to 4) hydrocracking. The dehydrogenation reactions are very endothermic, requiring that the hydrocarbon stream be
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and propylene, catalytic dehydrogenation of isobutane, and conversion of tertiary butyl alcohol recovered as
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85, 88 catalytic dehydrogenation of isobutane, 99 catalytic hydrocracking, 85, 90 catalytic reforming, 85,
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of paraffins, 93 dehydrogenation reactions, 93 dehydrogenation of naphthenes, 93 density, 160 deoxyribonucleic acid dehydrogenation reactions, 93 dehydrogenation of naphthenes, 93 density, 160 deoxyribonucleic acid (DNA), 13

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: Modeling_of_Chemical_Kinetics_and_Reactor_Design.pdf : : : :
homogeneous, vapor-phase dehydrogenation of benzene in a tubular-flow reactor considered two reactions:
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F for the dehydrogenation of benzene using the Runge-Kutta fourth order method
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of reactions for dehydrogenation of benzene. Rates of reaction (lb mol/ft3
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125) Examples: decomposition, dehydrogenation, and sublimation reactions If k1 and k2 denote the forward

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: Pollution_Prevention_Through_Process_Integration.pdf : 92188.pdf : : : Referex
produced by the dehydrogenation of ethylbenzene using live steam over an oxide catalyst at

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: Intro_to_ChemE_Analysis_Using_MATHEMATICA.pdf : : : : Referex
The hydrogenation and dehydrogenation of alkenes and alkanes are reversible processes that favor the
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For example, the dehydrogenation of saturated alkanes and alkyl aromatics to produce alkenes and that is, the dehydrogenation of alkanes to alkenes and hydrogen, continuous removal of either hydrogen by a dehydrogenation of alkane. The extent to which the hydrogen is removed
File Title
: Applied_Process_Design_VOLUME1_3E.pdf : APPLIED PROCESS DESIGN FOR CHEMICAL AND PETROCHEMICAL PLANTS, Volume 1, 3rd Edition Subject : Author : Ernest E. Ludwig Keywords : Referex
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inch stack) 0 Dehydrogenation unit X Hydrogen (31-inch stack) y Hydrogen (

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: Chemistry_of_Petrochemical_Processes_2E.pdf : : : : Referex
of Propane, 172, Dehydrogenation of Propane 172, Nitration of Propane 173 n-Butane Chemicals
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developed for the dehydrogenation of propane to propylene for petrochemical use. Propylene has always
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for olefin production. Dehydrogenation of n-butane to butenes and to butadiene is an (Chapter 3). Dehydrogenation of isobutane produces isobutene, which is a reactant for the
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production except the dehydrogenation of propane. Catalyst CH3CH2CH3 r CH3CH=CH2+H2Table
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for ethylene production. Dehydrogenation of butanes is a second source of butenes. However, this
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are the catalytic dehydrogenation of butanes and butenes, and dehydration of 1,4butanediol. Butadiene isoprene is the dehydrogenation of C5 olefins (tertiary amylenes) obtained by the extraction
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such as the dehydrogenation of naphthenes and the dehydrocyclization of paraffins to aromatics. Catalytic
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catalytic sites, hydrogenation-dehydrogenation sites and acid sites. The former sites are provided by best known hydrogenation-dehydrogenation catalyst and the latter (acid sites) promote carbonium ion
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aromatics are the dehydrogenation of naphthenes and the dehydrocyclization of paraffins. The first reaction represented by the dehydrogenation of cyclohexane to benzene. This reaction is fast; it reaches lower than the dehydrogenation of cyclohexanes. Table 3-6 shows the effect of temperature
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to aromatics (dehydrogenation of naphthenes and dehydrocyclization of paraffins) produce hydrogen and are
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important because the dehydrogenation of naphthenes to aromatics can reach equilibrium faster than the paraffins. Because the dehydrogenation of naphthenes and the dehydrocyclization of paraffins are highly endothermic,
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sites and hydrogenation-dehydrogenation sites. Amorphous silica-alumina, zeolites, or a mixture of them 30 The hydrogenation-dehydrogenation activity, on the other hand, is provided by catalysts such
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catalyst with hydrogenation-dehydrogenation activity, the olefins are hydrogenated to paraffinic compounds. This reaction
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formation and hydrogenation-dehydrogenation reactions. The reaction may start by forming a carbocation via
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a free radical dehydrogenation reaction, where hydrogen is a coproduct: CH3CH3 r CH2=CH2
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tube alloys catalyze dehydrogenation and formation of coke. Coke formation reduces product yields, increases
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by the catalytic dehydrogenation of butanes or a butane/butene mixture. CH3CH2CH2CH3 r CH2= first step involves dehydrogenation of the butanes to a mixture of butenes which are Lummus fixed-bed dehydrogenation of C4 mixture to butadiene.52 The process may also used for the dehydrogenation of mixed amylenes to isoprene. In the process, the hot
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uses an oxidative-dehydrogenation catalyst in the presence of air and steam. The C4 Hydrogen released from dehydrogenation reacts with oxygen, thus removing it from the equilibrium mixture of the oxidative dehydrogenation process was made by Welch et al. They concluded that
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comes from the dehydrogenation of C5 olefin fractions from cracking processes, several schemes are for isoprene production. Dehydrogenation of Tertiary Amylenes (Shell Process) t-Amylenes (2aqueous sulfuric acid. Dehydrogenation of t-amylenes over a dehydrogenation catalyst produces isoprene. The amylenes over a dehydrogenation catalyst produces isoprene. The overall conversion and recovery of t-
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olefin by a dehydrogenation step: The carbide mechanism, however, does not explain the formation
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as a fumigant. DEHYDROGENATION OF PROPANE (Propene Production) The catalytic dehydrogenation of propane Production) The catalytic dehydrogenation of propane is a selective reaction that produces mainly propene: Lummus-Crest Catofin dehydrogenation process.3 For a given dehydrogenation system, i.e., operating For a given dehydrogenation system, i.e., operating temperature and pressure, thermodynamic theory provides
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Lummus Crest Catofin dehydrogenation process:3 (1) reactor, (2) compressor, (3) temperature on the dehydrogenation of different light paraffins.4 NITRATION OF PROPANE (Production
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temperature on the dehydrogenation of light paraffins at one atmosphere.4 Nitropropane reacts with
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to be the dehydrogenation of propane and butane to the corresponding olefins followed by the predominance of dehydrogenation and cracking. Methane and ethane are by-products from the
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hydrogen (from dehydrogenation of propane) through the reverse water gas shift reaction. CO2
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isomerization followed by dehydrogenation to isobutene. The Catofin process is currently used to dehydrogenate
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activated copper-catalyzed dehydrogenation of ethanol. Currently, acetaldehyde is obtained from ethylene by using oxidation or the dehydrogenation of ethanol (approximately 500C for the oxidation and C for the dehydrogenation). Ethylene oxidation is carried out through oxidation-reduction (redox).
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are produced by dehydrogenation of nparaffins, dehydrochlorination of monochloroparaffins, or by oligomerization of ethylene complexes catalyze the dehydrogenation of n-paraffins to -olefins. The reaction uses a
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isopropanol by a dehydrogenation, oxidation, or a combined oxidation dehydrogenation route. The dehydrogenation reaction a combined oxidation dehydrogenation route. The dehydrogenation reaction is carried out using either copper dehydrogenation route. The dehydrogenation reaction is carried out using either copper or zinc oxide
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used for the dehydrogenation reaction. Acetone can also be coproduced with allyl alcohol in produced from the dehydrogenation of isopropanol and adsorbed on the catalyst surface selectively hydrogenates
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by the catalyzed dehydrogenation of sec-butanol over zinc oxide or brass at about
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produce MEK by dehydrogenation, as mentioned earlier. 2-Butanol is also used as a
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remainder comes from dehydrogenation of n-butane or n-butene streams (Chapter 3).
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11 billion pounds. Dehydrogenation of ethylbenzene to styrene occurs over a wide variety of used for the dehydrogenation reaction. Typical reaction
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followed by catalytic dehydrogenation to styrene:8 Figure 10-3. Schematic diagram of the
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-methylstyrene by dehydrogenation. -Methylstyrene is used as a monomer for polymer manufacture
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corresponding n-paraffins. Dehydrogenation of nparaffins to monoolefins using a newly developed dehydrogenation catalyst a newly developed dehydrogenation catalyst by UOP has been reviewed by Vora et al. monoolefins. Because the dehydrogenation product contains a higher concentration of olefins for a given 9) combines the dehydrogenation of n-paraffins and the alkylation of benzene.17 Monoolefins Monoolefins from the dehydrogenation section are introduced to a fixed-bed alkylation reactor over
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(1) pacol dehydrogenation reactor, (2) gas-liquid separation, (3) reactor for
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to benzene. The dehydrogenation of cyclohexane Figure 10-12. Effect of hydrogen purity and
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over a hydrogenation-dehydrogenation catalyst such as nickel. The hydrodealkylation is essentially a hydrocracking
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from, 259 from dehydrogenation of C4, 103104 polymerization with Li compounds, 308 polymers 6265 Catofin dehydrogenation process, 173 Cellulose, 301 Chain addition polymerization, 304308 Charactenzation
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from, 315 Cycloparaffins dehydrogenation of, 63 in crude oils, 13 DDT, 278 DEA ( to butadiene, 104 Dehydrogenation of ter-amylenes, 105 butanes and butenes, 103 cycloparaffins, 63
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process for C4 dehydrogenation, 103 Malathion, 243 Maleic anhydride 1,4-butanediol from, 242243
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scheme, 297 Lummus dehydrogenation process for butadiene, 103 Physical absorption, 3 Physical adsorption, 3,
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173 cracking, 97 dehydrogenation, 172 Lummus-Crest process, 173 temperature effect on, 172 heating

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: Adhesion_Science_and_Engineering_VOLUME2.pdf : Surfaces, Chemistry & Applications : : M. Chaudhury and A.V. Pocius : Referex
through hydrogenation and dehydrogenation reactions. Hydrogenation of the first conjugated carbon-carbon double bond
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catalyst, followed by dehydrogenation; a-methylstyrene is obtained as a byproduct in the production toluene followed by dehydrogenation.

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: Coulson_Richardsons_Chemical_Engineering_Volume_2.pdf : : : : Referex
formed by the dehydrogenation of ethyl benzene are shown. It may be seen that,

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: Fluid_Catalytic_Cracking_Handbook_2E.pdf : 92155.pdf : : :
reactions, such as dehydrogenation and condensation. Dehydrogenation means the removal of hydrogen; and condensation dehydrogenation and condensation. Dehydrogenation means the removal of hydrogen; and condensation means polymerization,
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matrix. Nickel promotes dehydrogenation reactions, removing hydrogen from stable compounds and making unstable olefins,
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activity to promote dehydrogenation reactions, A small amount of nickel in the FCC feed to increase the dehydrogenation reactions. Chlorides in the feed reactivate aged nickel, resulting in an indicator of dehydrogenation reactions. However, the ratio is sensitive to the reactor temperature
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Vanadium also promotes dehydrogenation reactions, but less than nickel. Vanadium"s contribution to hydrogen yield
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indicative of the dehydrogenation activity of the metals on the catalyst. The addition of
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catalyst. They cause dehydrogenation reactions, which increase hydrogen production and decrease gasoline yields. Vanadium
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with nickel, the dehydrogenation reactions that are
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7. 8. Naphthenes Dehydrogenation Dealkylation Condensation C7H14 - n-C8H18 lso-C3H Ar-C3H
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prominent reactions are dehydrogenation and coking. Dehydrogenation. Under ideal conditions (i.e., a dehydrogenation and coking. Dehydrogenation. Under ideal conditions (i.e., a "clean" feedstock molecular hydrogen. Therefore, dehydrogenation reactions will proceed only if the catalyst is contaminated with
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Transalkylation Cyclization Dealkylation Dehydrogenation Polymerization Alkylation Specific Reaction n-C10H22 -> n-C7H16 +
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catalyst, promoting undesirable dehydrogenation and condensation reactions. These nonselective reactions increase gas and coke
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Nickel, 63, 108 dehydrogenation, 135 and hydrogen, 64 passivation, 122 Nitrogen basic, 54 effects,
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37 dehydrogenation, 135 hydrogen transfer, 134 isomerization, 133 thermal cracking, 126, 283

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: Organic_Chemistry.pdf : : : :
the product of dehydrogenation of the natural product guaiol with elemental sulfur. From the
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RNH2 PThis dehydrogenation is the reverse of palladium-catalysed hydrogenation. NH2 HN R
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of FAD involve dehydrogenationsas in double bond formation from single bonds. Of course,
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a sulfur-promoted dehydrogenation has been suggested for the removal of the hydrogen atoms.

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: Renewable_Energy_3E_.pdf : : : :
second stage involves dehydrogenation (removing hydrogen atoms from the biomass material), such as
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4.152) followed by dehydrogenation: 2C2H5OH + CO2 2CH3COOH + CH4 (4.153) The
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of hydrogenation and dehydrogenation multistage adia5.2 ENERGY STORAGE 553
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nitrogen in the dehydrogenation and hydrogen in the hydrogenation units. A number of ammoniated

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: BRETHERICK_Handbook_Reactive_Chemical_Hazards_6E_VOLUME1.pdf : : : : Referex
1978, 88, 120946 Dehydrogenation of the Hantzsch ester in a melt with the

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operation feasible; butane dehydrogenation, for example, is done this way. Because of their long

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: 84607_01.pdf : c01 1..44 : : :
intermediate reduction step. Dehydrogenation of the alcohol to the aldehyde is followed by aldol

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: 84607_16.pdf : c01 1..60 : : :
procedure, desaturation or dehydrogenation, offers more attractive prospects. Flavor deterioration in fat-rich milk

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: 84607_32.pdf : c03 49..66 : : :
be explained by dehydrogenation and rearrangement of a- and g-terpinene, and hydrogenation and

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: 84607_41.pdf : c12 319..360 : : :
lycopene by hydrogenation, dehydrogenation, cyclization, and oxidation, or a combination of these processes (

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: 84607_80.pdf : c08 279..306 : : :
begins with the dehydrogenation of unsaturated fatty acids, such as linolenic acid, by means

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: 84607_81.pdf : c09 307..352 : : :
to be the dehydrogenation from the a-methylene group to form a radical. Since

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: Instrumentation_Reference_Book_3E.pdf : Instrumentation Reference Book Third Edition : : Walt Boyes : Referex
co-doping and dehydrogenation of the fiber to increase its photosensitivity. Gratings have also

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: Rules_of_Thumb_for_Chemical_Engineers_3E.pdf : RULES OF THUMB FOR CHEMICAL ENGINEERS : : CARL BRANAN : Referex
proposed ethyl-benzene dehydrogenation process. Ethylbenzene and steam were fed to the reactor. and
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development of butane dehydrogenation, coal conversion, and gas cracking processes in the 194Os, additional hydrocarbon processing. Butane dehydrogenation plant personnel noted how iron oxide and coke radiated outward

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: M26.pdf : Section 26 Members : : :
Quorum & Associates DEHYDROGENATION SYSTEMS Aker Kvaerner, Inc. CB&I Howe-Baker Process &

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: J.G.Speight - Chemical and process design handbook.pdf : : : :
Dehydration / 1.13 Dehydrogenation / 1.14 Esterfication / 1.16 Ethynylation / 1.17 Fermentation /
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DEHYDROGENATION Dehydrogenation is a reaction that results in the removal of as in the dehydrogenation of ethane to ethylene: CH3CH3 CH that causes some dehydrogenation, indicated by the presence of unsaturated compounds and free hydrogen. very large-scale dehydrogenation processes. Styrene is produced from ethylbenzene by dehydrogenation (Fig. from ethylbenzene by dehydrogenation (Fig. 1). Many lower molecular weight aliphatic ketones are
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distillation follows. The dehydrogenation of n-paraffins yields detergent alkylates and nolefins. The rhenium for selective dehydrogenation has increased in recent years since dehydrogenation is one of recent years since dehydrogenation is one of the most commonly practiced of the chemical processes. See Hydrogenation. DEHYDROGENATION 1.15
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higher temperatures favor dehydrogenation, but the catalysts used are the same as for hydrogenation.
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desired temperature. See Dehydrogenation.
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alcohol by either dehydrogenation (preferred) or air oxidation. These are catalytic processes at
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by either partial dehydrogenation to olefins and addition to benzene with hydrogen fluoride (
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and by the dehydrogenation of butane or the butenes using an iron oxide (
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to tetrahydrofuran. With dehydrogenation catalysts, such as copper chromite, butanediol forms butyrolactone. With certain both dehydration and dehydrogenation occur, giving 2,3-dihydrofuran. Heating butanediol or tetrahydrofuran with ammonia pyrrolidines. With a dehydrogenation catalyst, amino groups replace one or both of the hydroxyl
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butane. One is dehydrogenation to isobutylene followed by conversion of the isobutylene to the
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this material is dehydrogenation of butanediol. The manufacture of butyrolactone by hydrogenation of maleic
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through a catalytic dehydrogenation reactor where part of the ethyl alcohol is dehydrogenated to 2 Distillation Distillation Dehydrogenation reactorSelective hydrogenation reactor Hydrogen Ethyl acetate Ethyl alcohol Recycle
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oxidation or simple dehydrogenation. 2CH3OH + O2 2HCH=O + to cause the dehydrogenation to take place. In the process (Figs. 1 and
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is formed by dehydrogenation of pyridine and quaternization with ethylene dibromide. 2.257
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hydrogenation, oxidation, and dehydrogenation. The 1-naphthol is made from naphthalene, which is obtained
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produced by the dehydrogenation of iso-pentane in the same plant used for the
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by cracking and dehydrogenation of n-paraffins, as practiced in the petrochemical section of
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nonbiodegradability. Cracking and dehydrogenation of n-paraffins is now the preferred method, giving very
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such as alkylation, dehydrogenation, hydrogenation, and isomerization, are essentially identical to those operations used
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from ethylbenzene by dehydrogenation at high temperature (630oC) with various metal oxides as H2 Most dehydrogenations do not occur readily even at high temperatures. The driving
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are prepared by dehydrogenation of paraffins, by polymerization of ethylene to a-olefins using
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oxide and nonylphenol. Dehydrogenation of n-alkanes from petroleum (C9H20
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yield aromatics are dehydrogenation or aromatization of cyclohexanes, dehydroisomerization of substituted cyclopentanes, and the cyclopentanes, and the cyclodehydrogenation of paraffins. One toluene production process commences with mixed hydrocarbon
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of alcohol, 1.13 Dehydrogenation, 1.14 catalysts for, 1.1.3 Detergents, 2.190 Dextrose, 1.18 Diallyl phthalate,
File Title
: Applied_Process_Design_VOLUME1_3E.pdf : APPLIED PROCESS DESIGN FOR CHEMICAL AND PETROCHEMICAL PLANTS, Volume 1, 3rd Edition Subject : Author : Ernest E. Ludwig Keywords : Referex
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: F585A1265F4FE23F5629236910CA9E78.pdf : : : :
which decreases the dehydrogenation poisoning activity of Ni and V. The catalytic cracker is reforming reaction is dehydrogenation of naphthenes, or removal of hydrogen from the molecule. Important

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: Renewable_Energy_3E_.pdf : : : :
second stage involves dehydrogenation (removing hydrogen atoms from the biomass material), such as
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4.152) followed by dehydrogenation: 2C2H5OH + CO2 2CH3COOH + CH4 (4.153) The
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of hydrogenation and dehydrogenation multistage adia5.2 ENERGY STORAGE 553
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nitrogen in the dehydrogenation and hydrogen in the hydrogenation units. A number of ammoniated

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: 677rev.pdf : Microsoft Word - 677rev.doc : : Administrator :
a set of dehydrogenation and cyclization reactions finally yielding a graphitic coke layer. Several

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: Borsa_20PhD_20Thesis_20Defense.PDF : Defense : : Tom McKinnon :
subsequent impingement and dehydrogenation on the reactor surface. Iron plays a role in

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: ccl4 effect on pyrolysis reaction.pdf : No Job Name : : :
for EDC pyrolysis. Dehydrogenation of C2H4 is also known to be one of the

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: coking.pdf : Defense : : Tom McKinnon :
subsequent impingement and dehydrogenation on the reactor surface. Iron plays a role in

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: Experiments in Catalytic Reaction Engineering (J. M. Berty).pdf : Experiments in Catalytic Reaction Engineering : : J. M. Berty : Referex
such as butane dehydrogenation. For exothermic reactions, very small diameter tubes with a single
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presented for the dehydrogenation of butane.
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for an endothermic dehydrogenation in the synthetic rubber program during World War 11 were
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vehicle fLels. Ethylbenzene dehydrogenation to styrene is another example. On Figure 8.:2.2 the

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: Fluid catalytic cracking Handbook.pdf : 92155.pdf : : :
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: BRANAN, C. R. (2002). Rules of Thumb for Chemical Engineers (3rd ed.).pdf Title : RULES OF THUMB FOR CHEMICAL ENGINEERS Subject : Author : CARL BRANAN Keywords : Referex
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: Chemical Reaction Engineering & kinetics.pdf : : : :
independent equations. The dehydrogenation of ethane (C,H,) is used to produce ethylene
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1) Dehydration and dehydrogenation of C$H,OH VV QH,OH + GH, +
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metal catalyst favors dehydrogenation of an alcohol to an aldehyde, but an oxide catalyst
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In the dehydrogenation of &He to produce CzH4, CH4 is a minor
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in the ethane dehydrogenation mechanism of Section 6.1.2: Ho + C,H; + C,
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rate of ethane dehydrogenation. These and similar reactions have a substantial influence in reactions
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process like ethane dehydrogenation, where detailed molecular models of the free-radical chemistry are
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kinetics of ethane dehydrogenation to produce ethylene, the relatively simple mechanism given in Section
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6.1.2 for the dehydrogenation of CzH6, obtain the rate law for CzH6 + Cz&
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11 on the dehydrogenation of ethane to produce ethylene. It can be treated as
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good hydrogenation and dehydrogenation catalysts. (7) Although it may be correct to say
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and subsequently catalyze dehydrogenation reactions. In this case, the yield of gasoline is reduced,
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kinetics of ethanol dehydrogenation over Cu in the presence of water vapor, acetone, or
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S) by a dehydrogenation reaction catalyzed by yeast alcohol dehydrogenase (YADH). Nikolova et
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Examples are the dehydrogenation of C,H6 to produce C,H, (noncatalytic, low
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such as the dehydrogenation of ethane for production of ethylene, take place in such example, in the dehydrogenation of ethylbenzene for the production of styrene monomer, or in
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as in the dehydrogenation of ethane to ethylene. We consider next the three types
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Nonisobaric Operation The dehydrogenation of ethane (A) to ethene (B) is conducted
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which may undergo dehydrogenation to form benzene and isomerization to form methylcyclopentane, as follows:
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styrene monomer by dehydrogenation of ethylbenzene: CsH,, * CsH, + H, (W This
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we use the dehydrogenation of ethylbenzene, reaction (D) in Section 21.1. This is example. For the dehydrogenation of ethylbenzene at equilibrium, CsH,, (EB) + CsH, (
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such as the dehydrogenation of ethylbenzene), as also shown in Section 5.3 and illustrated
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ethylbenzene (EB) dehydrogenation reactor in Sarnia, Ontario, as it existed at that time.
involving only the dehydrogenation reaction ((D) in Section 21.1), and use the kinetics
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stages, for the dehydrogenation of ethylbenzene (A) to styrene (S) (monomer), a) For the dehydrogenation of ethylbenzene (A), reaction (D) in Section 21.1,
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flow, for the dehydrogenation of ethylbenzene (A) to styrene (S) (monomer). flow, for the dehydrogenation of ethylbenzene (A) to styrene (S) (monomer). flow, for the dehydrogenation of ethylbenzene (A) to styrene (S) (monomer).
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517,574,575 Ethane, CzH,+ dehydrogenation, 35-36,154,286,366, 376-377,379-380 mechanism, 116,124-125,137,138-139,158 165,172,173314,445 Ethylbenzene, CsHrs: dehydrogenation to styrene, 176,366,513,522 equilibrium considerations, 520-521,522, 547 reactor calculations,
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273,275 for ethane dehydrogenation, 116,124-125, 137,138-139,158,165,172,173-175 for formation of HBr, 160-

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: Chemical Reactor Design Optimization & Scaleup - Nauman.pdf : 3799-nauman-pre 1..14 : : :
for the catalytic dehydrogenation of ethylbenzene to form styrene: C8H10 !C8H8
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favorable equilibrium. Ethylbenzene dehydrogenation fits this situation. Repeat Problem 3.7 but substitute an annular
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HR for the dehydrogenation of ethylbenzene to styrene at 298.15K and 1 bar. Solution:
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for the ethylbenzene dehydrogenation reaction at 973K and 0.5 atm. Solution: From Example 7.8,
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R for the dehydrogenation of ethylbenzene to styrene at 298.15 K. Solution: Table 7.2
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of the ethylbenzene dehydrogenation reaction at 298.15K and 0.5 atm. Consider two cases: 1.
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from the ethylbenzene dehydrogenation reaction at 973K and 0.5 atm. The starting composition is amount of a dehydrogenation catalyst. The reaction rate has the form kf A
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trajectory for ethylbenzene dehydrogenation.
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process for the dehydrogenation of ethylbenzene uses 3-mm spherical catalyst particles. The rate
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10.5. The ethylbenzene dehydrogenation catalyst of Example 3.1has a firstorder rate
constant of 3.752
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C., Catalytic dehydrogenation of ethylbenzene, Chem. Eng. Prog., 44, 275286 (1948).

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: Chemical.Process.and.Design.Handbook.pdf : : : :
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File
: Cheremisinoff - Pressure Safety Design Practices for Refinery and Chemical Operations.pdf Title : Subject : Author : Keywords :
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cracking, isomerization, alkylation, dehydrogenation, etc., taking place in a cat reactor, they are complicated,
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as feedstock for dehydrogenation to butadiene. The rich acid extract is flashed to about
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1-butenes for dehydrogenation feed, the isobutylene dimer being added to the motor gasoline
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isobutylene extraction, butene dehydrogenation, or used in further refinery processing. Isoprene The demand for
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from Ethylbenzene by Dehydrogenation Ethylbenzene is dehydrogenated to styrene over a fixed bed of
File
: Ed Peters and Timmerhaus - Plant Design and Economics for Chemical Engineer - 4th Edition.pdf Title : Subject : Author : Keywords :
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by catalytic t dehydrogenation of
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produced by the dehydrogenation of isopropanol according to the following reaction: CH3\ /H
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production by catalytic dehydrogenation are to be analyzed with respect to three variables. These
File
: Ludwig Applied_Process_Design_For_Chemical_And_Petrochemical_Plants__Volume_1 3rd Ed 1999.pdf Title : APPLIED PROCESS DESIGN FOR CHEMICAL AND PETROCHEMICAL PLANTS, Volume 1, 3rd Edition Subject : Author : Ernest E. Ludwig Keywords : Referex
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: Ray & Johnston - Chemical Engg Design Project A Case Study Approach.pdf Title : Subject : Author : Keywords :
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of acetone. Catalytic dehydrogenation of ethyl benzene. Hydrochlorination of methanol. Catalytic dehydrogenation of nof methanol. Catalytic dehydrogenation of n-butenes; feedstock of liquid mixed hydrocarbon stream containing

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: Soares - Process Engineering Equipment Handbook - 2002.pdf : : : :
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of naphthenes through dehydrogenation and of paraffins through isomerization and dehydrocyclization. The reformer catalyst, reformers do. The dehydrogenation and dehydrocyclization reactions produce large amounts of hydrogen as a

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: Speight - Chemical Process & Design Handbook - 2002.pdf : Microsoft Word - Doc1.doc : :a :
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: Walas - Chemical Process Equipment - Selection and Design - 1990.pdf : : : :
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for hydrodealkylation and dehydrogenation reactions Palladium-on-alumina catalyst, for selective hydrogenation of acetylene
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from ethanol 18. Dehydrogenation of isopropanol 19. Isomerization of n-butane 20. Postchlorination

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: 30A9B8D1823ABBC9E2E9FCF73FB8C717.pdf : Speight_Part II_K and L : : Systems Administrator :

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: 3D1619E86AD17469AECBA817225B76E.pdf : Speight_Part II_A : : Systems Administrator :
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: 4DFCD212563EFB48B5E607A6D5F081.pdf : Speight_Part II_H : : Systems Administrator :

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: 5F8EDEADEA27CB27003EB3C034E9FD.pdf : Speight_Part II_O&P : : Systems Administrator :

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: 6DEE225BB9712C11AFAF9D52EC496.pdf : Speight_Part 1_H : : Systems Administrator :
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: 83D76FDA28112EDD8B955961C1A2CA7.pdf : Speight_Part II_S : : Systems Administrator :
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: 9E26C05E48104BE4A1DD16A082955D17.pdf : Speight_Part II_I : : Systems Administrator :
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: A6914BED4D79868813A211C6C43902D.pdf : Speight_Part II_N : : Systems Administrator :

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: AFCDFD46BB6145807DC55AAE2917254D.pdf : Speight_Part II_E : : Systems Administrator :

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: C31E3FD43EAEC5E661CCCB0809A1FB.pdf : Speight_Part II_B : : Systems Administrator :
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: CC92C94D0E857FDED2FD8AE1840BC97.pdf : Speight_Part 1_C&D : : Systems Administrator :
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: D6AC68B3AB4D17F98E72EAD2C62EF0B3.pdf : Index_Speight_HB1 6x9 : : Systems Administrator :

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: DE56D48D9A3EB57B869C5B68EF163ACC.pdf : Speight_Part II_T : : Systems Administrator :

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: F64F21FD3359EE5DD459D678E8FE1218.pdf : Speight_Part II_F : : Systems Administrator :

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: FA94FBA92701ACCC2B7612576CCA134.pdf : FM_Speight_HB1 : : Systems Administrator :

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: PEP Yearbook process list.pdf : PEP Yearbook process list.xls : : Russell Heinen :
BY VAPOR PHASE DEHYDROGENATION ACETONITRILE ACETONITRILE RECOVERY IN ACRYLONITRILE MANUFACTURE ACETYLENE ACETYLENE FROM CALCIUM
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BUTENES BY OXIDATIVE DEHYDROGENATION BUTADIENE RECOVERY BY DIMETHYLFORMAMIDE EXTRACTIVE DISTILLATION BUTADIENE RECOVERY BY N-
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FROM ETHANE BY OXYDEHYDROGENATION ETHYLENE FROM ETHANE BY CONVENTIONAL CRACKING WITH FRONT-END DEETHANIZATION
Page: 8
BY THE OLEFLEX DEHYDROGENATION PROCESS ISOBUTYLENE FROM ISOBUTANE BY THE SNAMPROGETTI/YARSINTEZ PROCESS ISODECYL
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BY VAPOR PHASE DEHYDROGENATION OF METHANOL METHYL ISOBUTYL CARBINOL METHYL ISOBUTYL CARBINOL FROM METHYL
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PROPANE BY CATALYTIC DEHYDROGENATION PROPYLENE, POLYMER GRADE, FROM REFINERY GRADE PROPYLENE (66 WT
File
: Dipo Baskoro - Prarancangan Pabrik Metil Tersier Butil Eter dari Isobutylene dan Metanol.pdf Title : Microsoft Word - Dipo Baskoro - Prarancangan Pabrik Metil Tersier Butil Eter dari Isobutylene dan Metanol.doc Subject : Author : Dipo Keywords :
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Could not extract contextual text. The document has restricted security permissions and content copying is not allowed.

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: Levenspiel O. Chemical reaction engineering (3ed., Wiley, 19.pdf : : : :
21.12. In catalytic dehydrogenation of hydrocarbons the catalyst activity decays with use because of

Page: 557
: Marks.Standard.Handbook.for.Mechanical.Engineers.10th.Editio.pdf : : : :
Provide oxygenates Isobutane dehydrogenation Feedstock for oxygenate synthesis Catalytic cracker naphtha fractionation Increase alkylate

Page: 160
: McGraw-Hill"s Engineering Companion.pdf : : : :
balances. The ethanol dehydrogenation reaction is carried out with the feed entering at 300 chart of ethanol dehydrogenation process.

Page: 20
: Plant Design and Economics for Chemical Engineers (M. S. Pet.pdf : : : :
by catalytic t dehydrogenation of
Page: 855
produced by the dehydrogenation of isopropanol according to the following reaction: CH3\ /H
Page: 880
production by catalytic dehydrogenation are to be analyzed with respect to three variables. These

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: Rules_of_Thumb_for_Chemical_Engineers.pdf : RULES OF THUMB FOR CHEMICAL ENGINEERS : : CARL BRANAN : Referex
Page: 271

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: 10376_05.pdf : : : :
of LAS. The dehydrogenation of paraffins, followed by alkylation of benzene with a mixed

Page: 20
: 10376_13.pdf : : : :
hydrogen over hydrogenation-dehydrogenation catalysts, which may be supported on alumina or silica-alumina.
Page: 21
a suitable feed. Dehydrogenation is a main chemical reaction in catalytic reforming, and hydrogen is to promote dehydrogenation and hydrogenation reactions, that is, the production of aromatics,

Page: 24
: 75551_04.pdf : : : :
Condensation Dehydrogenation Esterification Halogenation and manufacture of halogens Hydrogenation

Page: 38
: 4CA091E7C4F3F03356F860E0AE64D16A.pdf : : : :
cracking, oxidation, alkylation, dehydrogenation, hydration, and chlorination. Most processes use proprietary catalysts to increase

Page: 10
: 7766X_01a.pdf : : : :
fractionation section. The dehydrogenation of isobutane to isobutene is represented by iCH,CH(CH,), The gas phase dehydrogenation of isobutane to isobutene iC,Hlo 3 iC,H, +
Page: 11
process flowsheet for dehydrogenation of isobutane Mixing Point 4 unknowns (itAl, itBl, it4,
Page: 12
of gas phase dehydrogenation of isobutane before convergence.
Page: 13
of gas phase dehydrogenation of isobutane after convergence. The enthalpy of formation of iC, Formulas for the Dehydrogenation of lsobutene D3 = 0.35 (given fractional conversion of

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: F585A1265F4FE23F5629236910CA9E78.pdf : : : :
which decreases the dehydrogenation poisoning activity of Ni and V. The catalytic cracker is reforming reaction is dehydrogenation of naphthenes, or removal of hydrogen from the molecule. Important

Page: 11
: Chap23.pdf : : : :
benzene to cyclohexane Dehydrogenation of ethylbenzene to styrene Tarhan (Catalytic Reactor Design, McGraw-
Page: 14
reaction in the dehydrogenation of ethylbenzene is to styrene and hydrogen, C6H5C2H5 C6H5C2H3 +
Page: 25
is a suitable dehydrogenation accelerator but possibly with a different most-favorable temperature. Catalytic
Page: 28
They catalyze hydrogenation/dehydrogenation as well as many of the reactions catalyzed by acids, 4. Dehydration and dehydrogenation combined utilizes dehydration agents together with mild dehydrogenation agents. Included together with mild dehydrogenation agents. Included in this class are phosphoric acid, silicamagnesia, 13. Hydrogenation and dehydrogenation employ catalysts that form unstable surface hydrides. Raney nickel or
Page: 29
are the hydrogenation/ dehydrogenation component of the catalyst and alumina is the acid component
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and polyphosphazene membranes. Dehydrogenation processes in particular have been studied, with conversions in most

Page: 35
: Chap30.pdf : : : :
studies of the dehydrogenation of heptane to toluene. Incomplete reaction, deterioration of catalyst performance,

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: Index.pdf : perryfinal1.PDF : : shalko :
37 2-68 dehydrogenation 23-14 ethyl benzoate 2-37 2-52 2-68

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: 9614x_18.pdf : : : :

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: Process Engg Equipment Handbook_Soares.pdf : : : :

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: 37A9DAABCD3E2A486DE7436661FE95D5.pdf : : : :

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: Air_Pollution_Prevention_Control_Handbook.pdf : Handbook of Air Pollution Prevention and Control : : Nicholas P. Cheremisinoff : Referex
processes: (1) dehydrogenation of naphthenes to aromatics; (2) dehydrocyclization of paraffins to 4) hydrocracking. The dehydrogenation reactions are very endothermic, requiring that the hydrocarbon stream be
Page: 116
and propylene, catalytic dehydrogenation of isobutane, and conversion of tertiary butyl alcohol recovered as
Page: 571
85, 88 catalytic dehydrogenation of isobutane, 99 catalytic hydrocracking, 85, 90 catalytic reforming, 85,
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of paraffins, 93 dehydrogenation reactions, 93 dehydrogenation of naphthenes, 93 density, 160 deoxyribonucleic acid dehydrogenation reactions, 93 dehydrogenation of naphthenes, 93 density, 160 deoxyribonucleic acid (DNA), 13

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: Chemical_Engineering_Coulson_Richardson.pdf : : : : Referex

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: Fanchi - Energy Technology and Directions for The Future.pdf : : Referex 2005 : ELOX"s Community :
removed in a dehydrogenation process that requires acidophilic (acid-forming) bacteria. The net

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: Finlayson B.A. - Introduction to Chemical Engineering Computing.pdf : Introduction to chemical engineering computing : : Bruce A. Finlayson. :
make acetaldehyde by dehydrogenation of ethanol over a silver catalyst (Aguilo and Acetaldehyde production by dehydrogenation of ethanol.

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: Harriot - Chemical Reactor Design.pdf : CHEMICAL REACTOR DESIGN : FM: Chemical Reactor Design : Peter Harriott :
the literature. The dehydrogenation of sec-butyl alcohol to methyl ethyl ketone on brass
Page: 71
Reaction rate for dehydrogenation of sec-butyl alcohol. (From Ref. 10.) Copyright
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a chromia-alumina dehydrogenation catalyst, the catalyst activity and coke formation rate were measured
Page: 130
H2S-promoted oxidative dehydrogenation of butene was studied by Vodekar and Pasternak [12].
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by the catalytic dehydrogenation of ethyl benzene (EB) in a two-stage fixed-
Page: 228
temperatures. 5.9 The dehydrogenation of ethyl benzene (EB) to styrene (S) is

Page: 28
: Hill - An Introduction to Chemical Engineering Kinetics.pdf : : : :
will involve the dehydrogenation of ethane over a suitable catalyst (yet to be
Page: 31
produced by the dehydrogenation of butene over an appropriate catalyst. C4H8 H2 C4H6 In
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a gas phase dehydrogenation reaction that occurs at a constant temperature of 1000
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the catalytic oxidative dehydrogenation of various butene isomers to form 1,3-butadiene. Over a
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6. Polymerization 7. Dehydrogenation Reactants N2 + H2 NH3 + O2 SO2 + O2
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then act as dehydrogenation catalysts. The product distribution is markedly affected with lower yields
Page: 236
reduction, polymerization, dehydration, dehydrogenation, etc. Their versatility is a reflection of the range and
Page: 536
studied the catalytic dehydrogenation of cyclohexane to benzene over a platinum-onalumina catalyst.
Page: 537
have studied the dehydrogenation of cyclohexane to benzene over a platinum on alumina pelleted
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judgment. 17. Oxidative Dehydrogenation of Butene to Butadiene UW Chemical Corporation Madison, Wisconsin To:
for the butene dehydrogenation reaction is effectively removed since hydrogen is converted to water for the endothermic dehydrogenation reaction. For preliminary discussions of the proposed expansion program, it to other oxidative dehydrogenation catalysts. Select a promising catalyst material and prepare a reactor
Page: 594
158-160 Butene, dehydrogenation, 22, 538-539 isomerization, 20 d-s-Butyl a-chloroacrylate
Page: 595
164-165 Cyclohexane, dehydrogenation, 527-529 Cyclohexanol, reaction with acetic acid, 69 Cyclohexene, from of tetrachloroethane, 307 Dehydrogenation, butene, 22, 162 cyclohexane, 527-529 ethane, 19-21 ethylbenzene,
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equation, 493 Ethane, dehydrogenation, 19, 21 Ethanol, via hydration of ethylene, 12-14 reaction
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536-537 Oxidative dehydrogenation of butene, 538-539 Ozone decomposition, 97-98, 123124

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: Licker M.D. - McGraw Hill Dictionary of Chemistry 2E.pdf : McGraw-Hill Dictionary of Chemistry : : :
formed by spontaneous dehydrogenation of tetrahydrocannabinol from cannabis. { kan
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n } dehydrogenation [CHEM] Removal of hydrogen from a compound. { de

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: Licker M.D. - McGraw Hill Dictionary of Engineering 2E.pdf : : : :
hard, smooth butane dehydrogenation [CHEM ENG] A procrounded edge or surface; used for
Page: 162
} involving both dehydrogenation and cyclization, degradation [THERMO] The conversion of en- as
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a Houdry butane dehydrogenation [CHEM ENG] refractory slurry. { ha t

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: Nauman E.B. - Chemical reactor design, optimization, and scaleup.pdf : : : :
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10.5. The ethylbenzene dehydrogenation catalyst of Example 3.1 has a firstorder rate
constant of
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: Nunes - Membrane Technology.pdf : : : :
5.3.2 Large-scale dehydrogenations with inorganic membranes 210 5.3.3 OTM syngas process 212 5.3.4
Page: 14
debottlenecking 284, 285 dehydrogenation 201, 210212 dense membrane 6 Desal-5 15, 16,
Page: 208
methane, several oxidative dehydrogenations have been investigated, including the conversion of ethane to ethene
Page: 209
up is the dehydrogenation of methanol and butane using A microporous g-alumina and
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relatively simple alkane dehydrogenations. For the dehydrogenation of ethane catalytically active tubular membranes have dehydrogenations. For the dehydrogenation of ethane catalytically active tubular membranes have been used [ 72], whereas cyclohexane dehydrogenation was performed in packed-bed membrane reactors [73, 74]. e.g. the dehydrogenation of propane [7982], isobuta-
Page: 215
industrial application of dehydrogenation membrane reactors. These are: defects in metallic membranes at elevated of commercially available dehydrogenation catalysts. Anew development in this field is the use of
Page: 217
assisted esterifications and dehydrogenations will be discussed as well as the OTM process for
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5.3.2 Large-scale dehydrogenations with inorganic membranes Over the years, several processes for the for the catalytic dehydrogenation of propane to propylene have been developed, which can be process. As the dehydrogenation of propane to propylene comprises an equilibrium reaction (11), membranes in different dehydrogenation processes. As the Oleflex process uses four reactor beds in
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feasibility, the propane dehydrogenation process requires membranes with a selectivity much higher than Knudsenviable membrane-assisted dehydrogenation process of propane. The potential application of ceramic membranes for membranes for the dehydrogenation of ethylbenzene to styrene (12) has also been evaluated 12) For the dehydrogenation of ethylbenzene in a packed bed ceramic membrane reactor, three mixture. By oxidative dehydrogenation, the oxygen burns the hydrogen which is formed (C).
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configurations for the dehydrogenation of ethylbenzene [126].According to the study by van process for the dehydrogenation of ethylbenzene. The profit from the higher styrene yield by Aviable membrane-assisted dehydrogenation of ethylbenzene asks for cheaper membranes, being highly selective with

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: Odian G. - Principles of Polymerization. 4th edition.pdf : Principles of Polymerization : Team DDU : George Odian :
oxidative coupling (dehydrogenation) of p-xylene: nCH3 CH3 H CH2 CH2 H +

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: Schmidt - The Engineering of Chemical Reactions.pdf : : : :
is obtained by dehydrogenation of ethane. (a) Write out these reactions. (b)
Page: 69
much heat, while dehydrogenation reactions are fairly endothermic and oxidation reactions are fairly exothermic.
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branched alkanes and dehydrogenation of cyclics to aromatics would enhance the octane enormously. In
Page: 85
These alkanes undergo dehydrogenation and cracking reactions. A higher-molecular-weight fraction of alkanes,
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reaction is simple dehydrogenation, Cd6 -+ C2H4 + Hz In modern steam cracking processes
Page: 97
reactor stages, ethane dehydrogenation, ethylene oxidation, and ethylene oxide hydration. (a) What are (b) Both dehydrogenation and hydration have nearly 100% selectivity (with recycle of
Page: 99
all cracking and dehydrogenation reactions are strongly endothermic, while in the regenerator, strongly exothermic
Page: 101
is made by dehydrogenation of ethane. HCN is made by reacting CH4, NHs, and
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l l C, dehydrogenation maleic anhydride l l FCC 400 - CH,OH l
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by the oxidative dehydrogenation of ethane. Over a suitable catalyst the reactions and rates
Page: 220
The gas-phase dehydrogenation of ethane to ethylene C2H6 + CzH4 + H2 proceeds
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causes the oxidative dehydrogenation of ethane to ethylene CzH6 + $2 -+ C2H4 causes the oxidative dehydrogenation of ethane to ethylene C2& + $2 -+ C2H4
Page: 281
causes the oxidative dehydrogenation of ethane to ethylene C2H6 + $2 + C2H4 causes the oxidative dehydrogenation of ethane to ethylene C2H6 + 502 + C2H4 +
Page: 501
concentrations. Hydrogenation and dehydrogenation reactor Another example of a gasphase membrane reactor is
: Soares - Process Engineering Equipment Handbook.pdf : : : :
Page: 1220

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: Vannice - Kinetics of Catalytic Reactions.pdf : Kinetics of Catalytic Reactions : : :
is isopropyl alcohol dehydrogenation to produce acetone, and this is discussed in Illustration 7.2.
Page: 167
7.2 Isopropanol Dehydrogenation on Cu: A L-H Reaction Model Isopropyl alcohol dehydrogenation Model Isopropyl alcohol dehydrogenation over copper catalysts has been studied by Rioux and Vannice
Page: 169
for Isopropyl Alcohol Dehydrogenation over 0.98% Cu/Activated Carbona (Reprinted from ref.
Page: 175
to hydrogenation or dehydrogenation reactions, such as those involving hydrocarbons and organic molecules, because
Page: 186
obtained if concurrent dehydrogenation reactions occur to create carbonaceous species on the surface which
Page: 191
Illustration 7.5 Dehydrogenation of Methylcyclohexane on Pt: no RDS One of the easiest reactions the dehydrogenation of methylcyclohexane (MCH) to toluene (TOL): C6H11CH3 used for a dehydrogenation reaction? Answer: To minimize deactivation by inhibiting the build-up
Page: 251
of freedom, 110 Dehydrogenation, 151, 175, 203 Density of sites (see Site density)
Page: 252
9, 175 Isopropanol dehydrogenation, 151 Isotherm Freundlich (see Freundlich isotherm) Langmuir (see
Page: 253
85, 205 Methylcyclohexane dehydrogenation, 175 Michaelis constant, 224 Michaelis-Menten enzyme kinetics, 224 Micropores,
Page: 255
(see Methylcyclohexane dehydrogenation) Tortuosity, 69 Total surface area (see Specific surface area)

Page: 153
: Vogel - Fermentation and Biochemical Engineering Handbook.pdf : : : :
NAD in biochemical dehydrogenation. Microorganisms share similar chemical compositions and universal pathways. They all
Page: 809
Biocatalysts 3 Biochemical dehydrogenation 128 Bioenergetics 128 Biomedical device 677 Bioprocess Expert 702 Bioprocess

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: An introduction to chemical engineering kinetics.pdf : : : :
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: ChemicalProcessDesignHandbook_muyac.pdf : : : :
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: Coulson & Richardson"s Chemical Engineering. Vol. 6, Chemical Engineering Design, 4th Ed.pdf Title : Subject : Author : Keywords :
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it undergoes catalytic dehydrogenation to acetone. The reactor exit gases (acetone, water, hydrogen
Page: 209
manufactured by the dehydrogenation of 2-butanol. A simplified description of the processes listing
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manufactured by the dehydrogenation of 2-butanol using a shell and tube type reactor.

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: 1699_03.pdf : Heat Transfer in Industrial Combustion : Chapter 3: Heat Transfer Modes : Charles E. Baukal, Jr. :
hypothesized that the dehydrogenation and polymerization of hydrocarbon fuels occurs in the liquid phase, particles agglomerate after dehydrogenation and polymerization are completed. Gray et al. (1976) noted

Page: 4
: Chemistry of Petrochemical Processes 2E.pdf : : : : Referex
of Propane, 172, Dehydrogenation of Propane 172, Nitration of Propane 173 n-Butane Chemicals
Page: 44
developed for the dehydrogenation of propane to propylene for petrochemical use. Propylene has always
Page: 45
for olefin production. Dehydrogenation of n-butane to butenes and to butadiene is an (Chapter 3). Dehydrogenation of isobutane produces isobutene, which is a reactant for the
Page: 46
production except the dehydrogenation of propane. Catalyst CH3CH2CH3 r CH3CH=CH2+H2Table
Page: 47
for ethylene production. Dehydrogenation of butanes is a second source of butenes. However, this
Page: 50
are the catalytic dehydrogenation of butanes and butenes, and dehydration of 1,4butanediol. Butadiene isoprene is the dehydrogenation of C5 olefins (tertiary amylenes) obtained by the extraction
Page: 74
such as the dehydrogenation of naphthenes and the dehydrocyclization of paraffins to aromatics. Catalytic
Page: 75
catalytic sites, hydrogenation-dehydrogenation sites and acid sites. The former sites are provided by best known hydrogenation-dehydrogenation catalyst and the latter (acid sites) promote carbonium ion
Page: 76
aromatics are the dehydrogenation of naphthenes and the dehydrocyclization of paraffins. The first reaction represented by the dehydrogenation of cyclohexane to benzene. This reaction is fast; it reaches lower than the dehydrogenation of cyclohexanes. Table 3-6 shows the effect of temperature
Page: 78
to aromatics (dehydrogenation of naphthenes and dehydrocyclization of paraffins) produce hydrogen and are
Page: 81
important because the dehydrogenation of naphthenes to aromatics can reach equilibrium faster than the paraffins. Because the dehydrogenation of naphthenes and the dehydrocyclization of paraffins are highly endothermic,
Page: 92
sites and hydrogenation-dehydrogenation sites. Amorphous silica-alumina, zeolites, or a mixture of them 30 The hydrogenation-dehydrogenation activity, on the other hand, is provided by catalysts such
Page: 93
catalyst with hydrogenation-dehydrogenation activity, the olefins are hydrogenated to paraffinic compounds. This reaction
Page: 101
formation and hydrogenation-dehydrogenation reactions. The reaction may start by forming a carbocation via
Page: 104
a free radical dehydrogenation reaction, where hydrogen is a coproduct: CH3CH3 r CH2=CH2
Page: 105
tube alloys catalyze dehydrogenation and formation of coke. Coke formation reduces product yields, increases
Page: 116
by the catalytic dehydrogenation of butanes or a butane/butene mixture. CH3CH2CH2CH3 r CH2= first step involves dehydrogenation of the butanes to a mixture of butenes which are Lummus fixed-bed dehydrogenation of C4 mixture to butadiene.52 The process may also used for the dehydrogenation of mixed amylenes to isoprene. In the process, the hot
Page: 117
uses an oxidative-dehydrogenation catalyst in the presence of air and steam. The C4 Hydrogen released from dehydrogenation reacts with oxygen, thus removing it from the equilibrium mixture of the oxidative dehydrogenation process was made by Welch et al. They concluded that
Page: 118
comes from the dehydrogenation of C5 olefin fractions from cracking processes, several schemes are for isoprene production. Dehydrogenation of Tertiary Amylenes (Shell Process) t-Amylenes (2aqueous sulfuric acid. Dehydrogenation of t-amylenes over a dehydrogenation catalyst produces isoprene. The amylenes over a dehydrogenation catalyst produces isoprene. The overall conversion and recovery of t-
Page: 142
olefin by a dehydrogenation step: The carbide mechanism, however, does not explain the formation
Page: 185
as a fumigant. DEHYDROGENATION OF PROPANE (Propene Production) The catalytic dehydrogenation of propane Production) The catalytic dehydrogenation of propane is a selective reaction that produces mainly propene: Lummus-Crest Catofin dehydrogenation process.3 For a given dehydrogenation system, i.e., operating For a given dehydrogenation system, i.e., operating temperature and pressure, thermodynamic theory provides
Page: 186
Lummus Crest Catofin dehydrogenation process:3 (1) reactor, (2) compressor, (3) temperature on the dehydrogenation of different light paraffins.4 NITRATION OF PROPANE (Production
Page: 187
temperature on the dehydrogenation of light paraffins at one atmosphere.4 Nitropropane reacts with
Page: 191
to be the dehydrogenation of propane and butane to the corresponding olefins followed by the predominance of dehydrogenation and cracking. Methane and ethane are by-products from the
Page: 193
hydrogen (from dehydrogenation of propane) through the reverse water gas shift reaction. CO2
Page: 194
isomerization followed by dehydrogenation to isobutene. The Catofin process is currently used to dehydrogenate
Page: 211
activated copper-catalyzed dehydrogenation of ethanol. Currently, acetaldehyde is obtained from ethylene by using oxidation or the dehydrogenation of ethanol (approximately 500C for the oxidation and C for the dehydrogenation). Ethylene oxidation is carried out through oxidation-reduction (redox).
Page: 219
are produced by dehydrogenation of nparaffins, dehydrochlorination of monochloroparaffins, or by oligomerization of ethylene complexes catalyze the dehydrogenation of n-paraffins to -olefins. The reaction uses a
Page: 242
isopropanol by a dehydrogenation, oxidation, or a combined oxidation dehydrogenation route. The dehydrogenation reaction a combined oxidation dehydrogenation route. The dehydrogenation reaction is carried out using either copper dehydrogenation route. The dehydrogenation reaction is carried out using either copper or zinc oxide
Page: 243
used for the dehydrogenation reaction. Acetone can also be coproduced with allyl alcohol in produced from the dehydrogenation of isopropanol and adsorbed on the catalyst surface selectively hydrogenates
Page: 255
by the catalyzed dehydrogenation of sec-butanol over zinc oxide or brass at about
Page: 258
produce MEK by dehydrogenation, as mentioned earlier. 2-Butanol is also used as a
Page: 269
remainder comes from dehydrogenation of n-butane or n-butene streams (Chapter 3).
Page: 279
11 billion pounds. Dehydrogenation of ethylbenzene to styrene occurs over a wide variety of used for the dehydrogenation reaction. Typical reaction
Page: 280
followed by catalytic dehydrogenation to styrene:8 Figure 10-3. Schematic diagram of the
Page: 283
-methylstyrene by dehydrogenation. -Methylstyrene is used as a monomer for polymer manufacture
Page: 288
corresponding n-paraffins. Dehydrogenation of nparaffins to monoolefins using a newly developed dehydrogenation catalyst a newly developed dehydrogenation catalyst by UOP has been reviewed by Vora et al. monoolefins. Because the dehydrogenation product contains a higher concentration of olefins for a given 9) combines the dehydrogenation of n-paraffins and the alkylation of benzene.17 Monoolefins Monoolefins from the dehydrogenation section are introduced to a fixed-bed alkylation reactor over
Page: 289
(1) pacol dehydrogenation reactor, (2) gas-liquid separation, (3) reactor for
Page: 295
to benzene. The dehydrogenation of cyclohexane Figure 10-12. Effect of hydrogen purity and
Page: 297
over a hydrogenation-dehydrogenation catalyst such as nickel. The hydrodealkylation is essentially a hydrocracking
Page: 393
from, 259 from dehydrogenation of C4, 103104 polymerization with Li compounds, 308 polymers 6265 Catofin dehydrogenation process, 173 Cellulose, 301 Chain addition polymerization, 304308 Charactenzation
Page: 394
from, 315 Cycloparaffins dehydrogenation of, 63 in crude oils, 13 DDT, 278 DEA ( to butadiene, 104 Dehydrogenation of ter-amylenes, 105 butanes and butenes, 103 cycloparaffins, 63
Page: 398
process for C4 dehydrogenation, 103 Malathion, 243 Maleic anhydride 1,4-butanediol from, 242243
Page: 400
scheme, 297 Lummus dehydrogenation process for butadiene, 103 Physical absorption, 3 Physical adsorption, 3,
Page: 401
173 cracking, 97 dehydrogenation, 172 Lummus-Crest process, 173 temperature effect on, 172 heating

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: Chemical Process- Design and Integration.pdf : : 0470011912.pdf : :
produced by the dehydrogenation of an aqueous solution of isopropanol according to the reaction:
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produced by the dehydrogenation of 2- propanol. In this process, the product from the
File
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: Biochemistry The Chemical Reactions of Living Cells 2e Vols .pdf : : : :
Oxidoreductases. Enzymes catalyzing dehydrogenation or other oxidation and reduction reactions. E. Classification of Enzymes
Page: 514
there are two dehydrogenation steps. The first (step b) removes hydrogen atoms from than does the dehydrogenation of an alcohol, for which NAD+ is adequate. Addition of
Page: 515
acids, like the dehydrogenation of pyruvate to acetyl-CoA, takes place within the inner
Page: 519
in the four dehydrogenation steps are indicated. Their reduced forms are reoxidized by the
Page: 708
concerted decarboxylation and dehydrogenation may sometimes occur,241242 the enzymes of this group
Page: 767
15-2 Some Dehydrogenation Reactions Catalyzed by Flavoproteins Table 15-3 SingleCarbon Compounds keto reductases 3. Dehydrogenation of Amino Acids and Amines 4. Glyceraldehyde-3Phosphate Dehydrogenase Potentials 2. Typical Dehydrogenation Reactions Catalyzed by Flavoproteins 3. More Flavoproteins 4. Modified Flavin
Page: 768
Reactions 15 The dehydrogenation of an alcohol to a ketone or aldehyde (Eq. becomes reduced by dehydrogenation of an alcohol, one of the hydrogen atoms removed from that these biological dehydrogenations may be viewed as removal of a hydride ion (
Page: 769
oxidant) BC Dehydrogenation of an alcohol Alcohol dehydrogenase (NAD+) HC OH H
C O H+ Dehydrogenation of an amine Amino acid dehydrogenases, amine oxidases (NAD+ NH4C O Dehydrogenation of adduct of thiol and aldehyde Glyceraldehyde 3-phosphate dehydrogenase + H D Dehydrogenation of acyl-CoA, acyl-ACP, or carboxylic acid Reduction of
Page: 778
775 3. Dehydrogenation of Amino Acids and Amines The dehydrogenation of an amine and Amines The dehydrogenation of an amine or the reverse reaction, the reduction of 8, step a). Dehydrogenation of such a hydrate yields an acid (Eq. 15cleavage to the dehydrogenation, it drives the [NADPH] / [NADP+] ratio to
Page: 780
carry out the dehydrogenation of an acyl-CoA (reaction type D of Table
Page: 781
oxo group by dehydrogenation is essential. Bound NAD+ is also present in Sadenosylhomocysteine
Page: 784
variety of other dehydrogenations. (2) Flavins can be reduced either by one- or
Page: 785
acceptor. 2. Typical Dehydrogenation Reactions Catalyzed by Flavoproteins The functions of flavoprotein enzymes are
Page: 786
sequence to link dehydrogenation of glucose to the iron-containing catalyst that interacted with
Page: 787
15-2, the dehydrogenation of an acyl-coenzyme A (CoA), could not be reduced pyridine nucleotide.) Dehydrogenation reactions of this type are important in the energy metabolism the , dehydrogenation of fatty acyl-CoA derivatives. The pro-R hydrogen atoms 15-2 Some Dehydrogenation Reactions Catalyzed by Flavoproteinsa AB B. 2[H]
Page: 788
acid cycle is dehydrogenation of succinate to fumarate by succinate dehydrogenase (Eq. 1521).177a The dehydrogenation also involves trans removal of one of the two hydrogens,
Page: 793
for this reason dehydrogenation may often take place by proton transfer mechanisms.
Experimental support
Page: 794
mechanism of flavin dehydrogenation consists of consecutive transfer of a hydrogen atom and of
Page: 802
by a simple dehydrogenation. However, the pyruvate dissociates slowly and in the presence of
Page: 847
by decarboxylation and dehydrogenation of two of the carboxyethyl side chains of uroporphyrin III
Page: 888
chemical reactions of dehydrogenation, hydroxylation, or oxygenation. Galactose oxidase (Fig. 16-29), from
Page: 889
hydroxylation followed by dehydrogenation (Eq. 16-57). First identified in mushrooms, the enzyme
Page: 896
passes electrons from dehydrogenation of formate to FAD and then to the deazaflavin coenzyme
Page: 908
288 Acyl-ACP, dehydrogenation of 766 Acyl adenylate 507 Acyl carrier protein (ACP)
Page: 909
to carbonyl 677 dehydrogenation of 765 767 Alcohol dehydrogenase(s) 766 isoenzymes 774 covalent hydrates 775 dehydrogenation of 766 oxidation of 775 Aldehyde dehydrogenases 776 Aldehyde oxidases to carbonyl 677 dehydrogenation of 766 Amine oxidases 766, 782 Amino acid(s) 51 57 configurations 42 dehydrogenation of 775 as dipolar ions 42, 51 essential 52, 53
Page: 913
activation of 507 dehydrogenation of 766 Carboxylic acid reductase 893 Carboxyltransferase 724 of propionic
Page: 916
768 775 Dehydrogenation of alcohols 765 767 of amines 775 of amino
Page: 919
s) 513, 788 dehydrogenation reactions 782 787 table 784 reduction potentials of 782
Page: 922
equation 308 for dehydrogenation reactions 771 for multisubstituted compounds 309 table of constants 308
Page: 938
group 677 adduct, dehydrogenation of 766 binding of mercury ions 125 Thiol disulfide
Page: 942
CoA molecule is dehydrogenation. Removal of the hydrogen as a proton is made
Page: 944
that catalyze the dehydrogenation of acyl-CoA molecules to unsaturated enoyl-CoAs (step is a normal dehydrogenation to a 2-trans-5-cis-dienoyl-CoA. In pathway
Page: 945
rapidly, perhaps by dehydrogenation to the oxo acids (Eq. 17-3, step b)
Page: 946
new type of dehydrogenation with concurrent decarboxylation. Alpha oxidation also occurs to some extent
Page: 953
that gained from dehydrogenation and use of an electron transport chain.78 The solution
Page: 965
understood chemically. The dehydrogenation of glyceraldehyde 3-P and the accompanying ATP formation (
Page: 966
(i) a dehydrogenationdecarboxylation system, (ii) an isomerizing system, and (iii) rearrangement system. The dehydrogenationdecarboxylation system cleaves glucose 6-P to CO2 and the opening. A second dehydrogenation is catalyzed by 6-phosphogluconate dehydrogenase (Eq. 17-12,
Page: 967
product. Since the dehydrogenation system works only on glucose 6-P, a part of
Page: 983
liver cells, the dehydrogenations catalyzed by lactate dehydrogenase, sn-glycerol 3phosphate dehydrogenase, and
that several other dehydrogenation reactions are nearly at equilibrium. This conclusion has been confirmed
Page: 988
51).198 Further dehydrogenation to formate and of formate to CO2 via formate dehydrogenase
Page: 994
cycle), (3) dehydrogenation, and (4) decarboxylation. In many cases steps 3
Page: 1014
a thioester by dehydrogenation b. Substrate-level phosphorylation c. Thiamin-dependent condensation d.
Page: 1025
are oxidized by dehydrogenation is usually attributed to H. Wieland. During the years 1912
Page: 1052
glycolysis and other dehydrogenations in the cytoplasm quickly reduce available NAD+ to NADH. For
Page: 1060
the idea of dehydrogenation dominated thinking about biological oxidation. Many scientists assumed that the bond followed by dehydrogenation of the resulting alcohol. Nevertheless, it was observed that small
Page: 1062
usually followed by dehydrogenation or oxidative decarboxylation by NAD+ to give a catechol, whose
Page: 1068
aromatic amines and dehydrogenation of the resulting catechols or o-aminophenols (Eq. 16-
Page: 1089
by O2. c) Dehydrogenation of ascorbate by O2. How would the ratio of ATP
Page: 1137
step process involving dehydrogenation and enolization (steps c and d), is converted to 24 However, the dehydrogenation step is lacking in human beings and other primates, in
Page: 1141
carbonyl group by dehydrogenation with tightly bound NAD+ (Eq. 20-10, step a)
Page: 1198
apparently occurs by dehydrogenation of CH = CH . Examples of naturally occurring
Page: 1248
enzyme catalyzes the dehydrogenation of the 3-OH group to a ketone allowing for
Page: 1255
a. Hydroxylation b. Dehydrogenation c. Isomerization f. Hydroxylation g. Hydroxylation and oxidation to acyl-
Page: 1256
O2-dependent steps. Dehydrogenation of the 3-OH group of pregnenolone to C =
Page: 1320
The four-electron dehydrogenation of two water Figure 23-35 Proposed sequence of Sstates
Page: 1327
P2NADP+ 2NADPH Dehydrogenation decarboxylationsteps of oxidative pentose phosphate pathway (Eq. 17-12)
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to -guanidinobutyraldehyde. Dehydrogenation and hydrolysis lead, again, to aminobutyrate.189 Specific arginine
Page: 1394
most organisms is dehydrogenation (Eq. 24-37, step c)336 to form 2-
Page: 1396
by NAD+-dependent dehydrogenation,357 to the corresponding 2-oxoacid and oxidative decarboxylation of
Page: 1398
after the initial dehydrogenation in the -oxidation sequence, carbon dioxide is added using
Page: 1400
20) that involves dehydrogenation, transamination, and hydrolysis by a phosphatase. It can also be
Page: 1404
IX Decarboxylation and dehydrogenation H H NH3 e f g d h + Porphobilinogen
Page: 1440
Fig. 13-5) dehydrogenation, and side-chain cleavage as shown in Eq. 25-8
Page: 1452
Ring to histidinol. Dehydrogenation of this alcohol Regulation of histidine synthesis. In all, ten
Page: 1921
1655s Acyl-ACP, dehydrogenation of 766 Acyl adenylate 507 of tRNA 1672, 1695, 1696
Page: 1922
to carbonyl 677 dehydrogenation of 765 774 Alcohol dehydrogenase(s) 479, 766 covalent hydrates 775 dehydrogenation of 766 oxidation of 775 Aldehyde dehydrogenases 776 Aldehyde oxidases to carbonyl 677 dehydrogenation of 766 Amine oxidases 766, 782 Amino acid(s) 51 C-terminal 57 dehydrogenation of 775 as dipolar ions 42, 51 essential 52, 53,
Page: 1928
activation of 507 dehydrogenation of 766 Carboxylic acid reductase 893 Carboxyltransferase 724, 971 of
Page: 1933
1026 1028 Dehydrogenation 1022 of alcohols 765 767 of amines 775 of of, table 766 Dehydrogenation- decarboxylation system of pentose phosphate pathway 963 3-Dehydroquinate 1423s,
Page: 1939
s) 513, 788 dehydrogenation reactions 782 787 table 784 reduction potentials of 782
Page: 1943
equation 308 for dehydrogenation reactions 771 for multisubstituted compounds 309 table of constants 308
Page: 1971
group 677 adduct, dehydrogenation of 766 binding of mercury ions 125 Thioldisulfide equilibria

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: Chemical_Engineering.pdf : EOPSAT-ChEng : : :
include isomerization, hydrogenation, dehydrogenation, and dehydrocyclization. Fundamental catalysis Work that develops the basic principles
Page: 94
KCl/Al2O3 Paraffin dehydrogenation Pt/Al2O3 (S-poisoned) Phthalic anhydride V2O5 Steam reforming
Page: 96
Butadiene by Humble dehydrogenation 1964 Molex paraffin UOP separation 1970 Methanol low ICI pressure
Page: 97
it has a hydrogenationdehydrogenation component to promote arene and cyclization reactions. 3. Alkylation. Reactions
Page: 101
synthesis, hydrogenation, and dehydrogenation. A. Scale-Up and Development Catalyst scale-up is a
Page: 104
catalyst. Oxidation, hydrogenation dehydrogenation, isomerization, alkylation, and hydrotreating are carried out in such reactors.
Page: 362
e.g., propane dehydrogenation, natural gas steam reforming, these membrane reactors show good transport
Page: 395
Limitations Membrane concept Dehydrogenation Ethyl benzene to styrene 500600C; FeCr-
Page: 409
(1968). Dehydrogenation of cyclohexane on a hydrogenporous membrane, J. Catal. 11(1),
Page: 496
produced by catalytic dehydrogenation of butylene and the liquid butadiene is then extracted with

Page: 811
: Organic Chemistry.pdf : : : :
the product of dehydrogenation of the natural product guaiol with elemental sulfur. From the
Page: 1095
RNH2 PThis dehydrogenation is the reverse of palladium-catalysed hydrogenation. NH2 HN R
Page: 1289
of FAD involve dehydrogenationsas in double bond formation from single bonds. Of course,
Page: 1312
a sulfur-promoted dehydrogenation has been suggested for the removal of the hydrogen atoms.
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shikimate pathway 1402 dehydrogenation of guaiol with sulfur 830 of heterocycles 1175, 1212 with
Page: 1381
NMR 830 guaiol, dehydrogenation of 830 guanidine, basicity of 202, 587 guanidine, reaction with
Page: 1386
as catalyst for dehydrogenation 1175 as catalyst for hydrogenation 6237, 1164, 1198 tetrakistriphenylphosphine
Page: 1390
of) 1251 in dehydrogenation of guaiol by 830 oxidation states of 12489 stabilisation

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: Textbook of modern toxicology 3ed.pdf : A Textbook of Modern Toxicology : Team DDU : Ernest Hodgson :
Prostaglandin synthetase cooxidation Dehydrogenation Acetaminophen, benzidine, epinephrine N-Dealkylation Benzphetamine, dimethylaniline Epoxidation/hydroxylation Benzo(
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Dehalogenation, 112, 465 Dehydrogenation, 112 Delaney Amendmentsee Food, Drug and Cosmetics Act Demeton,

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: 1699_03.pdf : Heat Transfer in Industrial Combustion : Chapter 3: Heat Transfer Modes : Charles E. Baukal, Jr. :
hypothesized that the dehydrogenation and polymerization of hydrocarbon fuels occurs in the liquid phase, particles agglomerate after dehydrogenation and polymerization are completed. Gray et al. (1976) noted

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: An introduction to chemical engineering kinetics.pdf : : : :
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: 93851_17a.pdf : : : :
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for hydrodealkylation and dehydrogenation reactions Palladium-on-alumina catalyst, for selective hydrogenation of acetylene

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: 93851_17b.pdf : : : :
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: Chemical Process Equipment Selection and Design by Walas.pdf : : : :
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used. Hydrogenation and dehydrogenation employ catalysts that form unstable surface hydrides. Transition-group and are the hydrogenation-dehydrogenation component of the catalyst and alumina is the acid component
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for hydrodealkylation and dehydrogenation reactions G-58 Palladium-on-alumina catalyst, for selective hydrogenation
Page: 591
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from ethanol 18. Dehydrogenation of isopropanol 19. lsomerization of n-butane 20. Postchlorination

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: Coulson and Richardson"s - Chemical Engineering (Vol. 2) 3E.pdf : : : : Referex

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: Coulson and Richardson"s - Chemical Engineering (Vol. 5) 2E.pdf : : : :
by the catalytic dehydrogenation of ethylbenzene according to the reaction: C6H5 CH2

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: Coulson and Richardson"s - Chemical Engineering (Vol. 6) 3E.pdf : : : :
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: CRC Handbook of Chemistry and Physics 85th ed.pdf : CRC Handbook of Chemistry and Physics : : LRN EBOOKS :
for hydrogenation and dehydrogenation reactions. It is alloyed and used in jewelry trades. White
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the dehydration and dehydrogenation of ethyl alcohol. It is used in infrared absorbing glass

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: Gilbert & Kenneth - Chemical Reactor Analysis and Design.pdf : : : :
I-Bu~ene Dehydrogenation into Butudiene, 571 11.10 Two-Dimensional Heterogeneous &lodeis 12
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calcium-nickel phosphate dehydrogenation synthesis) Hydrogenation of aromatics and aromatization Platinum-acid alumina and
Page: 118
with hydrogenations and dehydrogenations. (Note that, except for noble metals, they would not
Page: 119
+ H2 (dehydrogenation) catalyst With hydrocarbons, the two types of catalysts cause cracking versus hydrogenation or dehydrogenations. An interesting and very practical example of these phenomena concerns
Page: 120
the metal site dehydrogenation step could not readily move to the acid sites for
Page: 133
reaction rate form. Dehydrogenation reactions are of the form and a specific example will
Page: 141
sequence consisting of dehydrogenation, isomerization, and hydrogenation. The dehydrogenation and hydrogenation steps occur on and hydrogenation. The dehydrogenation and hydrogenation steps occur on platinum sites, represented by I; the overall reaction: Dehydrogenation A + [ - A1 K I = CA JP, steps of the dehydrogenation or hydrogenation reactions is considered to be rate determining, the
Page: 142
the treatment of dehydrogenation reactions given above. Since these pressure dependent
rate equations are K,is theequilibriumconstant fordehydrogenation,and K, = K,K9KroK,, is the equilibrium constant for
Page: 147
They studied the dehydrogenation of ethanol into acetaldehyde in an integral type flow reactor
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b-2 Ethanol dehydrogenation. Conversion versus space time at various temperatures. (W/F,,)(
Page: 150
b-3 Ethanol dehydrogenation. Initial rate versus total pressure at various temperatures. PA, ( b-4 Ethanol dehydrogenation. Rearranged initial rate data.
Page: 152
b-6 Ethanol dehydrogenation. Arrhenius plot for rate coeficient and adsorption constants. From the
Page: 158
discrimination in the dehydrogenation of I-butene into butadiene Dumez and Froment studied the Froment studied the dehydrogenation of 1-butene into butadiene on a chromium-aluminium oxide (a) Atomic Dehydrogenation ; Sugace Recombination of Hydrogen where B = n-butene; (b) Atomic Dehydrogenation; Gas Phase Hydrogen Recombination KINETICS OF HETEROGENEOUS CATALYTIC REACTIONS
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(c) Molecular Dehydrogenation (d) Atomic Dehydrogenation; Intermediate Complex with Short Lqetime; Surface (d) Atomic Dehydrogenation; Intermediate Complex with Short Lqetime; Surface Recombination of Hydrogen (
Page: 160
discrimination in butene dehydrogenation. Operability region, equi/ibrium surface, location of preliminary and designed
Page: 161
Table 1 Dehydrogenation of I-butene. Evolution of sequential model discrimination Number of
Page: 162
l-2 Ethanol Dehydrogenation. Sequential Discrimination Using the Integral Method of Kinetic Analysis The Froment on ethanol dehydrogenation 1401 three rate equations were retained. They were already referred
Page: 163
qure I Ethanol dehydrogenation. Operability region, location of preliminary and ojdesigned experimentsfor optimal discrimination.
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discrimination in the dehydrogenation of ethanol into acetaldehyde, using integral reactor duta as such
Page: 170
study of the dehydrogenation over a brass catalyst of sec-butyl alcohol to methyl
Page: 171
l for the dehydrogenation of methylcyclohexane to toluene. In addition, they found that the
Page: 172
step of the dehydrogenation reaction were rate controlling. Contrast this with the corre rate
Page: 173
steps. 2.12 The dehydrogenation of ethanol was carried out in an integral reactor at
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Gradients in Ethanol Dehydrogenation Experiments The dehydrogenation of ethanol into acetaldehyde C,H,OH Dehydrogenation Experiments The dehydrogenation of ethanol into acetaldehyde C,H,OH = CH,CHO
Page: 254
Selectivity in Butene Dehydrogenation An experimental investigation of this industrially significant process was reported
Page: 321
of naphtha, and dehydrogenation of ethyl- 284 CHEMICAL ENGINEERING KINETICS
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19] in butene dehydrogenation. If the coke precursor would be formed from a reaction
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Coking in the Dehydrogenation of I-Butene into Butadiene on a Chromia-Alumina Catalyst
In the catalytic dehydrogenation of 1-butene into butadiene, which will be described in
Page: 332
Figure I Butene dehydrogenation. Partial pressure and coke profiles inside a cata[yst particle.
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study of butene dehydrogenation Dumez and Froment [19] were able to take samples 30] in the dehydrogenation of isobutene for which they derived a hyperbolic deactivation function
Page: 334
53.e-I Dehydrogenation of I-Bufene into Butadiene Dumez and Froment [I93 I93 studied the dehydrogenation of 1-butene into butadiene in the temperature range 480 derived from various dehydrogenation schemes and ratedetermining steps. The discrimination between these models was corresponding to molecular dehydrogenation and surface reaction on dual sites as a ratedetermining step,
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Figure I Butene dehydrogenation. Coke content of catalyst as a function of time.in
Page: 337
function for the dehydrogenation was also determined by means of the microbalance, by measuring
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Figure 2 Butene dehydrogenation. Deactication fwrction for the main reaction, mH. versus rime. Problems
Page: 502
or with ethylbenzene dehydrogenation into styrene. Strongly exothermic reactions lead to a temperature rise
Page: 557
study of the dehydrogenation of butene into butadiene, Dumez Bnd Froment [I411 observed
Page: 558
1393. In butene dehydrogenation into butadiene on a chromium-aluminium-oxide catalyst at 59S
Page: 608
for I-Butene Dehydrogenation into Butadiene This is an example, taken from Dumez and
The 1-butene dehydrogenation process considered here is carried out at temperatures of about
Page: 610
owing to the dehydrogenation and to a certain extent to the coking. The right-
Page: 612
the 1-butene dehydrogenation reactor. The molecular diffusivities were calculated from a weighted average
Page: 613
in I-butene dehydrogenation reactor. 576 CHEMICAL REACTOR DESIGN
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but as the dehydrogenation rate is lowered the bed temperature slowly rises, thus favoring
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produced by catalytic dehydrogenation of ethylbenzene. The reaction is endothermic and reversible and takes
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of, 37 Butene dehydrogenation, coking in, 294, 297 effect of particle size in, 217
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of polymerization, 40 Dehydrogenation, of 1-butene, see Butene dehydrogenation of ethanol, see Ethanol butene, see Butene dehydrogenation of ethanol, see Ethanol dehydrogenation Design, see Reactor design Differential ethanol, see Ethanol dehydrogenation Design, see Reactor design Differential method of kinetic analysis, with
Page: 797
simulation, 410 Ethanol dehydrogenation, calculations for, 151 model discrimination for, 125 Ethylene oxidation, catalytic,

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: O.Levenspiel - Chemical reaction engineering. 3rd edition.pdf : : : :

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10.5. The ethylbenzene dehydrogenation catalyst of Example 3.1 has a firstorder rate
constant of
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10.5. The ethylbenzene dehydrogenation catalyst of Example 3.1 has a firstorder rate constant of
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: Silla,H. - Chemical Process Engineering Design and Economics - Copy.pdf : CHEMICAL PROCESS ENGINEERING Design and Economics : FM: CHEMICAL PROCESS ENGINEERING Design and Economics : Harry Silla :
is produced by dehydrogenation of ethylbenzene in an adiabatic, fixedbed reactor. Although Sheel and
: Soares - Process Engineering Equipment Handbook.pdf : : : :
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: Couper - Chemical Process Equipment.pdf : Chemical Process Equipment : : James R. Couper :
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They catalyze hydrogenation dehydrogenation as well as many of the reactions catalyzed by acids 4. Dehydration and dehydrogenation combined utilizes dehydration agents combined with mild dehydrogenation agents. Included combined with mild dehydrogenation agents. Included in this class of catalysts are phosphoric acid, 13. Hydrogenation and dehydrogenation employ catalysts that form unstable surface hydrides. Transition-group and
Page: 617
are the hydrogenationdehydrogenation component of the catalyst and alumina is the acid component
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for hydrodealkylation and dehydrogenation reactions G-58 Palladium-on-alumina catalyst, for selective hydrogenation
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: fundamentals_of_organic_chemistry.pdf : : : :
aldehyde stage. 1) Dehydrogenation of an organic compound corresponds to oxidation, whereas hydrogenation corresponds
File
: Ludwig - Applied Process Design for Chemical and Petrochemical Plants Vol 1.pdf Title : APPLIED PROCESS DESIGN FOR CHEMICAL AND PETROCHEMICAL PLANTS, Volume 1, 3rd Edition Subject : Author : Ernest E. Ludwig Keywords : Referex
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: Rules of thumb for chemical engineers 3e.pdf : RULES OF THUMB FOR CHEMICAL ENGINEERS : : CARL BRANAN : Referex
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: Schmidt - The Engineering of Chemical Reactions.pdf : : : :
is obtained by dehydrogenation of ethane. (a) Write out these reactions. (b)
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much heat, while dehydrogenation reactions are fairly endothermic and oxidation reactions are fairly exothermic.
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branched alkanes and dehydrogenation of cyclics to aromatics would enhance the octane enormously. In
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These alkanes undergo dehydrogenation and cracking reactions. A higher-molecular-weight fraction of alkanes,
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reaction is simple dehydrogenation, Cd6 -+ C2H4 + Hz In modern steam cracking processes
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reactor stages, ethane dehydrogenation, ethylene oxidation, and ethylene oxide hydration. (a) What are (b) Both dehydrogenation and hydration have nearly 100% selectivity (with recycle of
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all cracking and dehydrogenation reactions are strongly endothermic, while in the regenerator, strongly exothermic
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is made by dehydrogenation of ethane. HCN is made by reacting CH4, NHs, and
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l l C, dehydrogenation maleic anhydride l l FCC 400 - CH,OH l
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by the oxidative dehydrogenation of ethane. Over a suitable catalyst the reactions and rates
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The gas-phase dehydrogenation of ethane to ethylene C2H6 + CzH4 + H2 proceeds
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causes the oxidative dehydrogenation of ethane to ethylene CzH6 + $2 -+ C2H4 causes the oxidative dehydrogenation of ethane to ethylene C2& + $2 -+ C2H4
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causes the oxidative dehydrogenation of ethane to ethylene C2H6 + $2 + C2H4 causes the oxidative dehydrogenation of ethane to ethylene C2H6 + 502 + C2H4 +
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concentrations. Hydrogenation and dehydrogenation reactor Another example of a gasphase membrane reactor is

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: Walas - Chemical Process Equipment.pdf : Chemical Process Equipment Selection and Design : : Stanley M. Walas : Referex
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: Wilson I.D, et al. (eds.) Encyclopedia of separation science (AP, 2000)(T)(4927s).pdf Title : Subject : Author : Keywords :
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equilibrium of the dehydrogenation reaction cyclohexane to cyclohexene. Conclusions The mechanism of water dissociation demonstrated that the dehydrogenation of cyclohexane to cyclohexene could be increased if the hydrogen to catalyse the dehydrogenation reaction. A membrane reactor of this type is illustrated in a myriad of dehydrogenation reactions. In the dehydrogenation reactions, hydrogen leaves the reactor by reactions. In the dehydrogenation reactions, hydrogen leaves the reactor by permeating through the semipermeable reactions (often dehydrogenations). The thermodynamic equilibrium of the reactants and products at the given reaction. For dehydrogenation reactions, increasing temperature and decreasing pressure promote an enhanced reaction.
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equilibrium of the dehydrogenation reaction cyclohexane to cyclohexene. Conclusions The mechanism of water dissociation demonstrated that the dehydrogenation of cyclohexane to cyclohexene could be increased if the hydrogen to catalyse the dehydrogenation reaction. A membrane reactor of this type is illustrated in a myriad of dehydrogenation reactions. In the dehydrogenation reactions, hydrogen leaves the reactor by reactions. In the dehydrogenation reactions, hydrogen leaves the reactor by permeating through the semipermeable reactions (often dehydrogenations). The thermodynamic equilibrium of the reactants and products at the given reaction. For dehydrogenation reactions, increasing temperature and decreasing pressure promote an enhanced reaction.
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addition of hydrogen Dehydrogenation CyclohexanePbenzene#3H2 Remove hydrogen to shift equilibrium limitation Partial oxidation highly active butane dehydrogenation catalyst operating at 1 atm total pressure (pure
normal removal on the dehydrogenation of butane. Based on pure butane feed with 1.1 atm illustrative purposes, the dehydrogenation of a compound to form hydrogen will be considered. The
Page: 1681
especially hydrogenation and dehydrogenation reactions. Thus, using this material to achieve both functions was gas in catalytic dehydrogenation membrane systems has been reported. At dehydrogenation temperatures (300} been reported. At dehydrogenation temperatures (300}6003C), oxygen can react with hydrogen to In contrast, the dehydrogenation reaction is endothermic. Thus, thermal matching of the heat released consumed by the dehydrogenation reaction would allow for an isothermal system. Because the hydrogenation
Page: 1684
membrane reactors, including dehydrogenation of hydrocarbons, hydrogenations and partial oxidation reactions are high temperature reactor for the dehydrogenation of butane, the system performance increased markedly. With no membrane,
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selectivity on a dehydrogenation reaction in a membrane-enclosed catalytic reactor. Journal of Membrane
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selectivity on a dehydrogenation reaction in a membrane-enclosed catalytic reactor. Journal of Membrane
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10.) on enzymatic dehydrogenation of D--hydroxybutyrate into acetoacetate and subsequent decarboxylation
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position, by enzymatic dehydrogenation and via formation of nicotinamide adenine dinucleotide (NADH), spectrometric
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cyclization, oxidation or dehydrogenation. The oxygenated derivatives are known as xanthophylls and bare either
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alkanes and the dehydrogenation of cyclohexanes to aromatics; and (2) steam reforming of
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achieve virtually complete dehydrogenation of cylcohexane to benzene at temperatures where the equilibrium constant

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: McGraw.Hill.Dictionary.Of.Engineering.eBook-LiB.pdf : : : :
hard, smooth butane dehydrogenation [CHEM ENG] A procrounded edge or surface; used for
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} involving both dehydrogenation and cyclization, degradation [THERMO] The conversion of en- as
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a Houdry butane dehydrogenation [CHEM ENG] refractory slurry. { ha t
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: Nauman E.B. Chemical reactor design, optimization, and scaleup (MGH, 2002)(T)(618s).pdf Title : Subject : Author : Keywords :
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10.5. The ethylbenzene dehydrogenation catalyst of Example 3.1 has a firstorder rate constant of
Page: 410

Page: 100
: Wypych G. (ed.) Handbook of solvents (ChemTec Pub., 2001)(1694s).pdf : : : :
major reactions occur: dehydrogenation of naphthenes to aromatics, dehydrocyclization of paraffins to aromatics, isomerization,
Page: 101
hydration, dehydration, hydrogenation, dehydrogenation, dimerization and esterification. For example methyl ethyl ketone is manufactured butanol then a dehydrogenation step converts it to methyl ethyl ketone. The production of

Page: 11
: M26.pdf : Section 26 Members : : :
Quorum & Associates DEHYDROGENATION SYSTEMS Aker Kvaerner, Inc. CB&I Howe-Baker Process &

Page: 513
: O.Levenspiel - Chemical reaction engineering. 3rd edition.pdf : : : :

Page: 315
: biodiversity in prod.pdf : DK3816_C000.fm : : Scott A. Suckling :
C4, followed by dehydrogenation and aromatization of the ring to yield p-hydroxybenzoate, which

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homogeneous, vapor-phase dehydrogenation of benzene in a tubular-flow reactor considered two reactions:

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be explained by dehydrogenation and rearrangement of a- and g-terpinene, and hydrogenation and

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lycopene by hydrogenation, dehydrogenation, cyclization, and oxidation, or a combination of these processes (

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to be the dehydrogenation from the a-methylene group to form a radical. Since

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