AP Chemistry Notes

Stephen Akiki Colchester High School Download at http://akiscode.com/apchem Special Thanks to Stephen Bosley (Boser)

Contents
1 FOREWORD/DISCLAIMER 2 Solubility Rules 2.1 Soluble . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 2.2 Insoluble . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 2.3 Naming Rules . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 3 Periodic Table of Elements 4 Poly Atomic Naming 5 Common Units, Constants and Charges 5.1 Fundamental Constants . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 5.2 Charge . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 5.3 Radius . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 6 Atomic Theory 6.1 J.J. Thompson . . 6.2 Robert Millikan . . 6.3 Ernest Rutherford 6.4 Chadwick . . . . . 6.5 John Dalton . . . . 4 5 5 5 5 5 6 6 6 7 7 7 7 7 7 7 7 8 8 8 8 8 8 8 9 9 9 9 10 10 10 11 11 11

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7 Naming 7.1 Binary . . . . . . . . . 7.1.1 Greek Prexes 7.2 Ionic . . . . . . . . . . 7.3 Acids . . . . . . . . . 7.3.1 Polyatomic . . 7.3.2 Binary . . . . . 8 Cations

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9 Reaction Type 9.1 Combination (Synthesis) . 9.2 Decomposition . . . . . . 9.2.1 Special Binary Salt 9.3 Combustion . . . . . . . . 10 Blackbody Radiation

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11 Bohr Model 11.1 Energy Level Formula . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 11.1.1 Energy Change during Level Jumps . . . . . . . . . . . . . . . . . . . . . . . . . . . .

12 Wavelength 12.1 De Broglie Formulas . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 13 Quantum Values 13.1 Quantum Value Table . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 13.2 Special cases . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 14 Periodicity 14.1 Electron Conguration . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 14.2 Isoelectricity . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 15 Nuclear Chemistry 15.1 Isotopes . . . . . . . . . . 15.2 Radiation . . . . . . . . . 15.2.1 Alpha Radiation . 15.2.2 Beta Radiation . . 15.2.3 Gamma Radiation 15.2.4 Positron Radiation 15.2.5 Electron Capture . 15.3 Nuclear Equations . . . . 15.3.1 Radiation Table . 15.4 Nuclear Stability . . . . . 15.4.1 Forces Invloved . . 15.4.2 Belt of Stability . 15.4.3 Magic Numbers . . 15.4.4 Half-Life . . . . . .

11 11 12 12 12 13 13 13 13 13 14 14 14 14 15 15 15 15 16 16 16 16 17 17 17 17 17 17 17 18 18 18 18 18 18 18 18 19 19 19 19 19 19 20 21 21 21 22 22 22 22

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16 Ionization and Anity 16.1 Ionization Energy . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 16.2 Electron Anity . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 17 Reactions of Metals 18 Chemical Bonds 18.1 Intramolecular . . . . . . . . . . . . . . . 18.1.1 Ionic Bonding . . . . . . . . . . . . 18.1.2 Covalent Bonding . . . . . . . . . 18.1.3 Metallic Bonding . . . . . . . . . . 18.2 Intermolecular . . . . . . . . . . . . . . . 18.2.1 Ion-Dipole . . . . . . . . . . . . . . 18.2.2 Dipole-Dipole . . . . . . . . . . . . 18.2.3 Hydrogen Bond . . . . . . . . . . . 18.2.4 London Dispersion/Van der Waals 18.2.5 Intermolecular Flowchart . . . . . 18.3 Rule of Octet . . . . . . . . . . . . . . . .

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19 Lewis Structures 19.1 Structures for Atoms . . . . . . . . . . . . . . . . . . 19.2 Structures for Ions . . . . . . . . . . . . . . . . . . . 19.3 Structure for Ions of Molecules . . . . . . . . . . . . 19.4 Lewis Structures for Molecular Structures (Covalent) 19.5 Resonance Structures . . . . . . . . . . . . . . . . . . 19.5.1 Formal Charge . . . . . . . . . . . . . . . . . 20 Lattice Energies of Ionic Solids 21 Bond Lengths of Covalent Bonds

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22 Electronegativity 22.1 Dipole . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 22.1.1 Dipole Moment . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

23 Bond Enthalpy 24 VSEPR 24.1 Bond Shape Table . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 25 Organic Chemistry 25.1 Polarity . . . . . . . . . . . . . . . . . . 25.2 Alkanes . . . . . . . . . . . . . . . . . . 25.3 Alkane Branch Structure Naming . . . . 25.3.1 Branch Structure Naming Table 25.4 Alkenes . . . . . . . . . . . . . . . . . . 25.4.1 Alkene Naming . . . . . . . . . . 25.5 Alkynes . . . . . . . . . . . . . . . . . . 25.5.1 Alkyne Naming . . . . . . . . . . 26 Functional Groups 26.1 Alcohol . . . . . 26.2 Aldehyde . . . . 26.3 Carboxylic Acid . 26.4 Ester . . . . . . . 26.5 Ketone . . . . . . 26.6 Ether . . . . . . 26.7 Amine . . . . . . 26.8 Amide . . . . . . 26.9 Haloalkane . . .

23 23 23 23 23 24 24 25 26 26 26 27 27 27 27 28 28 28 28 29 29 29 29 29 30 30 30 30 30 30 30 31 31 31 31 32 32 32 33 33 33 33 33 34 34 34 34 34 34 34 35 35

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27 Complex Ions 27.1 Cations . . . . . . . . 27.2 Anions . . . . . . . . . 27.3 Coordination Number 27.4 Naming . . . . . . . . 27.4.1 Cations . . . . 27.4.2 Anions . . . . .

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28 Acidic and Basic Redox 28.1 Acidic . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 28.2 Basic . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 29 Thermodynamics 29.1 Enthalpy . . . . . . . . . . . . . . . . . . 29.1.1 Stoichiometry Problems . . . . . . 29.1.2 Calorimetry . . . . . . . . . . . . . 29.1.3 Hess Law . . . . . . . . . . . . . . 29.1.4 Standard Heat of Formation . . . . 29.2 Entropy . . . . . . . . . . . . . . . . . . . 29.2.1 State of Matter . . . . . . . . . . . 29.2.2 Number of Moles of Gasses . . . . 29.2.3 Pressure of Gas . . . . . . . . . . . 29.3 Gibbs Law of Free Energy . . . . . . . . . 29.3.1 H, S, G, Relationship Table 30 Chemical Kinetics and Rate Laws 30.1 Physical State . . . . . . . . . . . 30.2 Concentration . . . . . . . . . . . 30.3 Temperature . . . . . . . . . . . 30.4 Pressure of Gas . . . . . . . . . . 30.5 Catalysts and Inhibitors . . . . . 30.6 Rate Laws . . . . . . . . . . . . . 30.6.1 Order Table . . . . . . . .

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31 Reaction Mechanisms 31.1 Elementary Steps . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 32 Equilibrium 32.1 Types of Equilibrium . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 32.2 Equilibrium Constant Expressions . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 32.2.1 Converting Constants . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 33 Gas 33.1 33.2 33.3 33.4 33.5 33.6 Laws Gas Units and Conversions . . . . . Ideal Gas Law . . . . . . . . . . . . . Real Gas Law . . . . . . . . . . . . . Combined Gas Law . . . . . . . . . . Daltons Law of Partial Pressures . . Gas Collection over a Water Solution

36 37 37 37 37 37 37 37 37 38 38 38 39 39 39 39 40 40 40 40 40 40 41 41 41 41 42 42 42 43 43 43 43 43 43 43 43 44 44 44 44 45

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34 ICE ICE (Baby) 35 Acids and Bases 35.1 Denitions of Acids and Bases . 35.2 pH and pOH . . . . . . . . . . . 35.2.1 Changing Concentrations 35.3 Strong Acids and Bases . . . . . 35.3.1 Strong Acids . . . . . . . 35.3.2 Strong Bases . . . . . . . 35.4 Weak Acids and Bases . . . . . . 35.4.1 Ka Constant . . . . . . . 35.4.2 Kb Constant . . . . . . . 35.5 Common Ion Eect . . . . . . . . 35.6 Buer . . . . . . . . . . . . . . .

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36 Equilibrium of Saturated, Soluable Salts 37 Kinetic Molecular Theory 37.1 Postulates: . . . . . . . . . 37.2 Root Mean Square Velocity 37.3 Eusion and Diusion . . . 37.3.1 Eusion . . . . . . . 37.3.2 Diusion . . . . . . 37.3.3 Finding the rate . .

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38 Electro Chemistry 38.1 Identifying Oxidation Numbers . . . . 38.2 Galvanic/Voltaic Cells . . . . . . . . . 38.3 Calculating Cell Potential . . . . . . . 38.3.1 Nernst Equation to Find E cell

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39 Balancing Redox Reactions 39.1 Acidic . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 39.2 Basic . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

FOREWORD/DISCLAIMER

First and formost, I am going to say what everone has on their minds. No you really should not just forget about taking notes anymore in AP Chemistry class because of this packet. This packet is meant to be a review and should be used as such. However that does not mean you can use this packet as your main notes and write notes in the margins to supplement your learning. Please take into account that this entire thing was written over the course of 4 days. As such it is inevitable that I made mistakes in spelling and/or formulas. If you have any questions/comments/xes to the text you can email me at [email protected] Good Luck 4

2
2.1

Solubility Rules
Soluble
1 Nitrates N O3 - All nitrates are soluble 1 Chlorates ClO3 - All chlorates are soluble +1 Alkali metal Cations and Ammonium cation compounds N H4 are all soluble

Chlorides, Bromides, and Iodides are all soluble EXCEPT Ag +1 , P b+2 , and Hg +2 Acetates - All are soluble except Ag + Sulfates - All are soluble except Ba+2 , P b+2 , Hg +2 , Ca+2 , Ag +1 , and Sr+2

2.2

Insoluble

2 Carbonates CO3 - all carbonates are insoluble except alkali metals and ammonium compounds 2 Chromates CrO4 - all chromates are insoluble except alkali metals, ammonium, Ca+ 2, and Sr+ 2

Hydroxides OH 1 - all hydroxides are insoluble except alkali metals, ammonium, Ba+2 , Sr+2 , and Ca+2 although the last two (Sr+2 and Ca+2 ) are only slightly soluble so a precipitate can form.
3 Phosphates P O4 all are insoluble except alkali metals and ammonium 2 Sultes SO3 all are insoluble except alkali metals and ammonium

Suldes S 2 all are insoluble except Alkali metals, alkali earth metals and ammonium

2.3

Naming Rules

All strong acids and bases are soluble and should be written as the ions when completing net ionic reactions
1 Sulfuric acid (H2 SO4 ) should be written as H + + HSO4

The strong acids are: HCL, HBR, HI, HN O3 , HClO4 , and H2 SO4 Strong bases are any alkali metal hydroxides (LiOH, N aOH, etc) and Ca(OH)2 , Sr(OH)2 , Ba(OH)2 All acids and bases should be left in their molecular form: Acetic acid HC2 H3 O2

Periodic Table of Elements

Poly Atomic Naming

Zinc Zn+2 Silver Ag +1
+1 Ammonium N H4

Hydroxide OH 1 Cyanide CN 1
1 Nitrate N O3 1 Acetate C2 H3 O2 1 Chlorate ClO3 1 Bromate BrO3 1 Iodate IO3 1 Manganate M nO3 2 Sulfate SO4 1 Bisulfate (Hydrogen Sulfate) HSO4 2 Carbonate CO3 1 Bicarbonate (Hydrogen Carbonate) HCO3 2 Selenate SeO4 1 Biselenate (Hydrogen Selenate)HSeO4 2 Oxalate C2 O4 3 Phosphate P O4 2 Hydrogen Phosphate HP O4 1 Dihydrogen Phosphate H2 P O4 2 Chromate CrO4

Per Ate Per Ic +1 Oxygen

Ate Ic Most Common Ion

Ite Ous -1 Oxygen

Hypo Ite Hypo Ous -2 Oxygen

5
5.1

Common Units, Constants and Charges

Fundamental Constants
6.02214199 1023 mol1 Plancks Constant (h) 6.62606876 1034 J s Speed of Light (c) 2.99792458 108 m/s Avogadros Number (N )

5.2

Charge

e charge = 1.602 1019 coulombs p+ charge = 1.602 1019 coulombs Atomic Mass Unit (amu) = 1.66054 1024 p+ = 1.0073 amu n = 1.0087 amu e = 5.486 104 amu

5.3

Radius

Angstroms (A) = 1010 meters

6
6.1

Atomic Theory
J.J. Thompson
charge mass

Discovered e and

ratio

Charge to Mass ratio: 1.76 108 Coulombs/Gram (Charge of e /mass) Plum Pudding Model of atom

6.2

Robert Millikan

Found charge and mass of e Millikan Oil Drop: Charge oil drops in a eld and adjust eld until drops levitate

6.3

Ernest Rutherford
Alpha particles: He2+ size, very damaging, stoppable - Beta particles - e size, damaging, hard to stop - Gamma particles - tiny, not so damaging, unstoppable -

Discovered 3 types of radiation (Decay Particles)

Also discovered proton and new dense nucleus model Rutherford worked with particles most and discredited Thompsons model of the nucleus

6.4

Chadwick

Discovers neutron by shooting radiation at light elements and it watching it kick out a neutral particle

6.5

John Dalton
Everything made of atoms Atoms of one element dier from those of a dierent element Atoms will combine in whole number ratios Atoms can not be created or destroyed

Four Postulates

Law of Constant Composition In a compound, atom ratios are constant

7
7.1

Naming
Binary
Smallest atomic number comes rst Second element ends with -ide

7.1.1

Greek Prexes

1-Mono 2-Di 3-Tri 4-Tetra 5-Penta 6-Hexa 7-Hepta 8-Octa 9-Nona 10-Deca Example Cl2 O Dichlorine Monoxide

7.2

Ionic
+1 N a? Cl2 3 a N ad Clb c (ab) c

Finding Charge:

=d

7.3
7.3.1

Acids
Polyatomic HN O4 pernitric acid

Per...ate Per...ic acid

-ate

ic acid

H + N O3 HN O3 (Nitric Acid) -ite ous acid HN O2 nitrous acid Hypo...ite hypo...ous acid HN O hyponitrous acid 7.3.2 Binary H + Br Hydrobromic acid H + N Hydronitric acid Hydrocarbonic acid HC Carbonic Acid HCO3 8

Hydro + (stem)ic

Cations
Which cation forms a white precipate with HCL? Ag + (reversed proves Cl ). What color is a typical Manganese solution? Pink/light purple. The precipate is dark black. How would you test for Al+ and what would it look like? Add Aluminom, it will make a precipate red and leave the solution clear. Which cation forms a gel like precipate? Aluminum. Which cation turns deep red with KSCN ? Iron. How do you conrm the presence of zinc and what color is it? Add acid, then ammonia, which results in a white/bluish precipate. What cation turns a deep blue with ammonia? Copper.

9
9.1

Reaction Type
Combination (Synthesis)

When two or more chemicals react to form one product Example 2M g + O2 2M gO 2N a + S N a2 S Metal + Non-Metal Metal Nonmetal (Binary Salt) Metal Oxide + Water Metal Hydroxide CaO + H2 O Ca(OH)2 K2 O + H2 O 2KOH Metal Oxide + CO2 Metal Carbonate N a2 O + CO2 N a2 CO3 Nonmetallic Oxides + water Acids (nonmetal oxides retains its oxide number) N a2 O + SO3 N a2 SO4

9.2

Decomposition
Example 2Ag2 O 4Ag + O2 = Heat

When one chemical decomposes into 2 or more

Metal Carbonate Metal Oxide + CO2 CaCO3 CaO + CO2 Metal Hydroxide Metal Oxide + H2 O M g(OH)2 M gO + H2 O

 Metal Nonmetal Metal + Nonmetal (diatomic in nature) 2N aCl 2N a + Cl2 Metal Chlorates Metal Chlorides + O2 F e(ClO3 )2 F eCl3 + O2 9.2.1 Special Binary Salt Splits

These binary salts split into dierent elements (N H4 )2 CO3 N H3 + H2 O + CO2 H2 SO3 H2 O + SO2 H2 CO3 H2 O + CO2 N H4 OH N H3 + H2 O H2 O2 H2 O + O2

9.3

Combustion

Hydrocarbon + O2 CO2 + H2 O ........ Cx Hy double x (multiply by 2) then add 2 C1 : meth C2 : eth C3 : pro C4 : bu C5 : pent C6 : hex C7 : hept C8 : oct C9 : non C10 : dec

10

Blackbody Radiation
E = h

When an object is heated it will emmit radiant energy

E = Energy h = Max Plancks constant (6.626 1034 J s) = frequency Photoelectric eect: Metal will give o e s if light shines on it. Light shining on a clean sheet of metals will release e s if is strong enough.

10

11

Bohr Model

Neils Bohr: 1. Only orbits of certain radii, corresponding to certain denate energies are permitted for the electron in a hydrogen atom. 2. An electron in a permitted orbit has a specic energy and is in an allowed energy state. An electron in an allowed state will not radiate energy and therefore will not spiral into the nucleus. 3. Energy is emmitted or absorbed by the e only as the e changes from one allowed energy state to another. 4. Flawed theory because it only works for hydrogen

11.1

Energy Level Formula

1 En = (2.18 1018 J)( n2 )

E1 : 2.18 1018 J E2 : 5.45 1019 J E3 : 2.42 1019 J E4 : 1.36 1019 J E5 : 8.72 1020 J E6 : 6.056 1020 J E : 0 11.1.1 Energy Change during Level Jumps E = EF E0 n = 3 2 | 3.03 1019 J n = 4 2 | 4.09 1019 J n = 5 2 | 4.578 1019 J n = 6 2 | 4.844 1019 J

12
12.1

Wavelength
De Broglie Formulas
=
h mv

or = = Wavelength h = Plancks Constant (6.626 1034 J s) m = Mass of particle in Kg v = Velocity of particle ( meters ) second p = Momentum Example m = 9.11 1028 g v = 5.97 106 m/s 6.6261034 Js = (9.111031 Kg)(5.97106 m/s) = 1.22 1010 m 11
h p

13

Quantum Values
n = 1 (lowest) n = (at 8 or 9)
1 Follows Bohrs En = (2.18 1018 J)( n2 )

1. Principle Quantum number - (n)

2. Azimuthal Quantum number - (l ) l =n-1 if... l = 0 S shape l = 1 P shape l = 2 D shape l = 3 F shape Example n=3 l =2 3d 3. Magnetic Quantum number (orbital) - (ml ) -l and l including zero m0 = 0 m1 = 1, 0, 1 m2 = 2, 1, 0, 1, 2 4. Spin magnetic quantum number - (ms)
1 + 1 or - 2 2

13.1
n 1 2 3

Quantum Value Table

Possible l values 0 0 1 0 1 2 0 1 2 3 Subshell 1s 2s 2p 3s 3p 3d 4s 4p 4d 4f ml values 0 0 -1,0,1 0 -1,0,1 -2,-1,0,1,2 0 -1,0,1 -2,-1,0,1,2 -3,-2,-1,0,1,2,3 # of orbitals in subshell 1 1 3 1 3 5 1 3 5 7 total # of orbitals in shell 1 4 9 16 e in shell 2 8 18 32 -

13.2

Special cases

Chromium has 6 half-lled orbitals Copper has one half-lled orbital and 5 lled orbitals

12

14
14.1

Periodicity
Electron Conguration

14.2

Isoelectricity

Two atoms are considered isoelectric when they gain or lose electrons to become ions and have the same electron conguration as each other. Example N a+1 : 1S2 , 2S2 , 2P6 N e: 1S2 , 2S2 , 2P6

15

Nuclear Chemistry

Nuclear Chemistry involves changes in the nucleus of an atom. Normal Reactions involve electron transfer Reaction aected by factors such as pH, temp, pressure, [], etc. Reactions involve relatively small energy: 400 kJ-1500kJ Nuclear Reactions involve decay of nucleus i.e. transforming one element into another Aected by the type of decay and the halife of what is decaying Reactions deal with huge amounts of energy

15.1

Isotopes
X A
A ZX A

Isotopes: Atoms of the same element that have a dierent number of neutrons

X = Element Symbol A = Atomic Mass Z = Atomic Number 13

15.2
15.2.1

Radiation
Alpha Radiation

When a big nucleus ejects a He+2 size chunk of itself.

15.2.2

Beta Radiation

When a neutrally charged particle (equal amount of p+ s and e s) ejects its e s leaving only the p+ s.

15.2.3

Gamma Radiation

When a particle experiences some type of radiation (called * here) that causes the remaining nucleus to collapse. This causes gamma () rays to be emitted. Gamma radiation is also caused when a positron and an electron smash into each other.

14

15.2.4

Positron Radiation

When a positively charged nucleus emits its p+ leaving only the n .

15.2.5

Electron Capture

When an electron in orbit falls into the nucleus (positively charged) and makes it neutrally charged.

15.3
15.3.1

Nuclear Equations
Radiation Table Neutron: Proton: Electron: Positron: Alpha Particle: Beta Particle:
1 0n 1 + 1p 0 1 e 0 1e 4 2 He 0 1 e

or 4 2 0 or 1

Example Alpha 238 U 234 T h +4 He 92 90 2 Beta 131 131 0 53 I 54 Xe+1 e

0 1 p+1 e 1 Positron 11 C 11 B+0 e 6 5 1 1 0n

1 n+0 e 0 1 Electron Capture 81 0 81 37 Rb+1 e 36 Kr

1 1p

1 n 0 Positron-Electron Collision (Gamma) 0 0 0 1 e+1 e 0 15

1 0 1 p+1 e

15.4

Nuclear Stability

Understanding why are some nuclides are radioactive while others are not. 15.4.1 Forces Invloved Try to rip apart the nucleus because of like charges Strong Nuclear Try to pull together the nucleus because subatomic particles naturally stick together The Glue Neutrons act as the glue and more of it is required when the electrostatic force gets really strong 15.4.2 Belt of Stability More neutrons than protons - Beta decay creates protons Area B Less neutrons than protons - Positron emission (Smaller B) or Electron Capture (Larger B) Area C Every element above 83 p+ is radioactive and no glue can hold it together - Alpha decay

Electrostatic

Area A

15.4.3

Magic Numbers

The Magic Numbers tend to be stable if you have either a proton or neutron in those numbers. If you have both, they are very stable. (p+ ) (n ) 2 2 8 8 20 20 28 28 50 50 82 82 126

If (p+ ) and (n ) even likely stable If either is odd could go either way If (p+ ) and (n ) odd likely unstable 16

15.4.4

Half-Life
1 2

The time it takes

the amount of a substance to decay. Example 5g of nuclide life of 15 years

1 2

How much of the original nuclide remains after 45 years? 5 (15 years) 2.5 (30 years) 1.25 (45 years) 0.625g

16
16.1

Ionization and Anity

Ionization Energy

The energy needed to remove an e (how easy it is to lose an e ). Needs energy (+).

16.2

Electron Anity

How much a gaseous atom will be attracted to a free e (how easy it is to gain an e ). Releases energy (-).

17

Reactions of Metals

Metal Oxides = Basic Metal + Water Metal Hydroxide + H2 Metal + O2 (Li or any non-Alkali metal) Metal Oxide
1 K + O2 (Any other Alkali metal) Metal Peroxide (O2 )

K + O2 KO2 Metal Oxide + H2 O Metal Hydroxide N a2 O + H2 O N aOH Metal Oxide + Acid Salt + H2 O N a2 O + HCL N aCl + H2 O Nonmetal Oxides = Acidic Nonmetal Oxide + H2 O Acid CO2 + H2 O H2 CO3 SO2 + H2 O H2 SO3 P4 O10 + H2 O H3 P O4 Nonmetal Oxide + Base Salt + H2 O CO2 + N aOH N a2 CO3 + H2 O

18

Chemical Bonds

When 2 or more atoms are strongly attached (attracted) to each other.

18.1

Intramolecular

These forces act inside an atom or molecule: 17

18.1.1

Ionic Bonding

Gain/lose e s (strong metal + strong nonmetal) 18.1.2 Covalent Bonding

Share e s (weak metal or nonmetal + nonmetal) 18.1.3 Metallic Bonding

There are two models that explain metallic bonding: Electron Sea Model
1

Metal atoms are oating in a sea of e s. No one e belongs to any particular atom. Orbital Bonding Model The valence e s are overlapped and shared so much you have bonds of delocalized e s that are free to move but are still holding the atoms together. Properties that result from metallic bonding include: Conductivity of electricity and heat Malibility and ductility Ability to form alloys

18.2

Intermolecular

These forces act between molecules: 18.2.1 Ion-Dipole

Ions bonding to molecules with a dipole (polver solvent). The strongest intermolecular force. 18.2.2 Dipole-Dipole

Polar near another polar. Weaker than Ion-Dipole but still strong, based on how strong the polarity is. 18.2.3 Hydrogen Bond

Either (H N ), (H O), or (H F ). No shielding e s on Hydrogen so central atoms e pair gets full pull of Hydrogen nucleus. 18.2.4 London Dispersion/Van der Waals

An induced dipole between 2 polar molecules. An increase in pressure or decrease in temperature will cause one side to have a more positive force as the majority of e s move to other side.
1 Of

the two theories, this is generally the more accepted one

18

18.2.5

Intermolecular Flowchart

18.3

Rule of Octet

Atoms tend to bond in such a way as to gain, lose, or share e s in order to gain a complete valence (outer s and p).

19
19.1

Lewis Structures
Structures for Atoms

19.2

Structures for Ions

19.3

Structure for Ions of Molecules

19

19.4

Lewis Structures for Molecular Structures (Covalent)

1. Add valence e s from all the atoms. 2. Write the symbols for the atoms. If there are more than 2 atoms, identify the central atom. Connect them with a single line which represents 2 shared e s. Subtract the number of e s from total found in step 1. Central atom will be closest to Si, P or Metaloid staircase. 3. Complete octets around the atoms bonded to the central atom (Hydrogen does not get more than 2). 4. Place the remaining pairs around the central atom even if doing so gives more than an octet to the central atom. 5. If there are not enough pairs to complete an octet in the central atom, then you ned to try using double or triple bonds. CH4

CH2 Cl2

HN O3

CO2

HCN

20

19.5

Resonance Structures
Benzene

19.5.1

Formal Charge Valence e s of an atom - (total unbonded e s +

1 2

total bonded e s)

Molecular structures that tend to be the common one have a formal charge is closest to zero and any negative charge is on the most electronegative element.

20

Lattice Energies of Ionic Solids

Coulombs Law KQ1 Q2 d

E= Q1 /Q2 = ion charges

d = Distance between ions of the nal crystalized lattice form. The greater the charge, the higher the energy. The closer the ions, the higher the energy. Example Which has a greater lattice energy?
+1 1 +2 1 +2 1

N aCl vs M g Cl2 M g Cl2 has greater charges thus a higher lattice energy.
+1 1 +1 1 +1 +1 +1 1 +1 1 +1

LiCl vs N aCl Li is smaller than N a so Li wil be closer to Cl than N a will so LiCl will have a higher lattice energy.

21

21

Bond Lengths of Covalent Bonds

Single - Longest Double - Medium Triple - Shortest Length Single Double Triple
4 CO4

1.42 A 1.24 A 1.13 A

CO2 CO

22

Electronegativity

Dierence in electronegativity determines the character of the bond. Large dierence Ionic Bond Biggest dierence is 3.3 Medium dierence Polar Covalent HF - 1.8 Small/No dierence Non-Polar Covalent H2 - 0

22.1

Dipole
H F Arrow points towards more electronegative atom.

22.1.1

Dipole Moment

Numeric value that represents how strong the dipole is Example Which has the greater dipole moment? OR Which has greater electronegative dierence? HI or HF Answer: HF

22

23

Bond Enthalpy

H: Energy given o or taken in during a reaction. H = Exothermic H = + Endothermic Breaking bonds requires energy Forming bonds releases energy Example CH4 + 2O2 CO2 + 2H2 OO Breaking Forming 4 (C H) = (4 413) 2 (C=O) = (2 799) 2 (O2 ) =(2*495) 4 (H O) =(4*463) 2642 3450 H = Broken - Formed H = 2642 - 3450 = -808 KJ

24

VSEPR

VSEPR stands for Valence Shell Electron Pair Repulsion. Make sure when counting bonds to treat double and triple bonds like a single bond. Also keep in mind that bonded pairs and lone pairs repel.

24.1

Bond Shape Table

Example BeH2 BCl3 1 N O2 CH4 N H3 H2 O P Cl5 SF4 BrF3 ICl2 SF6 BrF5 ICl4 Total e 2 3 3 4 4 4 5 5 5 5 6 6 6 Bonded Pairs 2 3 2 4 3 2 5 4 3 2 6 5 4 Lone e Pairs 0 0 1 0 1 2 0 1 2 3 0 1 2 Hybrid Orbital sp sp2 sp2 sp3 sp3 sp3 sp3 d sp3 d sp3 d sp3 d sp3 d2 sp3 d2 sp3 d2

Shape Linear Trigonal Planar Bent Tetrahedral Trigonal Pyramidal Bent Trigonal Bipyramidal See-Saw T-Shape Linear Octahedral Square Pyramidal Square Planer

25
25.1

Organic Chemistry
Polarity

Polarity in regards to organic chemistry relies on an element disrupting the symmetry of a molecule. For example the double bonded oxygen in Acetone allows it to be more polar than Propane. Acetone Propane

23

25.2

Alkanes
Spotted by seeing a single bond

CH4 Methane C2 H6 Ethane C3 H8 Propane C4 H10 Butane C5 H12 Pentane C6 H14 Hexane C7 H16 Heptane C8 H18 Octane C9 H20 Nonane C10 H22 Decane Pentane CH3 (CH2 )3 CH3

25.3

Alkane Branch Structure Naming

To name all single-bonded Carbon chains, see subsection on Alkanes above. To name a branch structure rst look for the longest unbroken Carbon chain, this is the root name. Then take the root prex of the alkyl (the branch of the root chain) and add -yl (for instance Methane becomes methyl). Number the Carbon chain giving the side with an alkyl the lowest number. The end result should be something such as 2 Methyl Butane. 2 Methyl Butane

24

25.3.1

Branch Structure Naming Table

25

25.4

Alkenes
Spotted by seeing a double bond

CH2 Methene C2 H4 Ethene C3 H6 Propene C4 H8 Butene C5 H10 Pentene C6 H12 Hexene C7 H14 Heptene C8 H16 Octene C9 H18 Nonene C10 H20 Decene 25.4.1 Alkene Naming

Naming Alkenes is similar to naming Alkanes save for the naming of the root chain. To name the root chain you must give side where the double bond is the lowest number and name all branches after using this number scheme. You should end up with something like 2 Pentene 2 Pentene

25.5

Alkynes
Spotted by seeing a triple bond

CH Methyne C2 H2 Ethyne C3 H4 Propyne C4 H6 Butyne C5 H8 Pentyne C6 H10 Hexyne C7 H12 Heptyne C8 H14 Octyne C9 H16 Nonyne C10 H18 Decyne

26

25.5.1

Alkyne Naming

Naming Alkynes is similar to naming Alkenes. Identify the root chain as you would using Alkenes except now you identify the triple bond instead of the double bond. 2 Hexyne

26

Functional Groups
When discussing functional groups, the letter R is used to signify any hydrocarbon or hydrocarbon chain.

26.1

Alcohol

Root Name: -ol Identication: R-OH Ethanol

26.2

Aldehyde

Root Name: -al Identication: R-CHO Ethanal

27

26.3

Carboxylic Acid

Root Name: -oic Identication: R-COOH Propanoic Acid

26.4

Ester

Root Name: A-yl B-oate Identication: R-COO-R Ethyl Propanoate

B A

CH3 CH2 CO OCH2 CH3

26.5

Ketone

Root Name: -one Identication: R-CO-R Acetone

26.6

Ether

Root Name: A-yl B-yl Ether Identication: R-O-R Propyl Methyl Ether
A B

CH3 CH2 CH2 O CH3

28

26.7

Amine

Root name: -amine Identication: R-NH2 Methylamine

26.8

Amide

Root Name: -amide Identication: R-CONH2 Ethanamide

26.9

Haloalkane

Root Name: None, use standard naming of root chain Identication: Some Hydrogens in a a hydrocarbon are replaced with a halogen (F, Cl, Br, I) 2 Chloro Butane

27

Complex Ions

Complex Ions are usually metal ions with attached ligands (Lewis Bases).

27.1

Cations
[Cr(H2 O)6 ]+3 The charge of a cation is the charge of the transition metal (Cr in this case).

29

27.2

Anions
[Al(OH)4 ]1 The charge of a anion is determined by the individual charges of the elements. Al+3 + 4(OH)1 3-4 -1

27.3

Coordination Number

Generally (especially with cations) the coordination number is twice the charge of the transition metal. Example [Cr(H2 O)6 ]+3 Cr+3 3 2 = 6

27.4
27.4.1

Naming
Cations

Give the prex associated with the coordination number Give appropriate name for ligand Name the transition metal Give roman numeral of transition metal Example
Chromium Hexa

Cr

(H2 O)
Aqua

]+3

Hexa Aqua Chromium (III) 27.4.2 Anions

Give prex associated with the coordination number Give appropriate Ligand name Name transition metal with -ate ending Give roman numeral Example [Al(OH)4 ]1 Tetra Hydroxo Aluminate No roman numeral because Al is always +3

28
28.1

Acidic and Basic Redox

Acidic
1 2

Find oxidation number Write reaction with e s

Add H2 O, then H + and balance accordingly Balance for e s and everything else Add together both balanced
1 2

reactions and cancel out where possibly to simplify

30

28.2

Basic
1 2

Find oxidation number Write reaction with e s

Add H2 O, then H + and balance accordingly Add OH amounts to both sides equal to the number of H + Cancel out the H + with the OH to form H2 O Move all H2 O to one side Balance for e s and everything else Add together both balanced
1 2

reactions and cancel out where possibly to simplify Example

+3 2 2 +1 C2 O4 M n

2 2 M n O4 + O2 + C O3 (4OH + C2 O4 2CO3 + 2e + 2H2 O) 3

+7

+4

(2H2 O + M nO4 + 3e M nO2 + 4OH) 2 12OH + 3C2 O4 6CO3 + 6e + 6H2 O 4H2 O + 2M nO4 + 6e 2M nO2 + 8OH 2 4OH + 3C2 O4 + 2M nO4 2M nO2 + 6CO3

29

Thermodynamics

The study of energy and its transformations Units of Energy: Joules and Calories 1 cal = 4.184 J The two main driving forces of thermodynamics is Enthalpy and Entropy:

29.1

Enthalpy

Enthalpy stands for the Heat of the reaction and is denoted by H. If: H<0 Reaction is exothermic H>0 Reaction is endothermic There are 4 ways to nd H. 29.1.1 Stoichiometry Problems Example How much heat is released when 3.2 grams of Hydrogen is reacted with excess Oxygen? 2H2 + O2 2H2 O H = 572 KJ 3.2 g H2 1 mole H2 2.02 g H2 2572 KJ2 = 453.069 KJ 1 mole H Energy Released Ratio = Coef f icient of Hydrogen in f ormula

31

29.1.2

Calorimetry

Find the H by running a reaction and heating or cooling a substance. q = m c T q = Heat released or absorbed m = Mass of what is being heated (grams)
J c = Specic heat. Unique to every substance ( gC )

Specic heat of water is 4.184 T = Change in temperature Example Burn 0.1 grams of CH4 and it heats 100 grams H2 O from 20 C to 33.29 C. q = 100 4.184 13.29 = 5560 J = 5.560 KJ 0.1 grams CH4 mole CH 1 16 g CH4 4 = 0.00625 moles CH4 1 KJ 5.560 0.00625 = 889.6 M ole 29.1.3 Hess Law

Multiple reactions can be added together then Hs can be added together. Example KJ Si + 2H2 SiH4 H = +34 M ole Si + O2 SiO2
KJ H = 911 M ole KJ H2 + 1 O2 H2 O H = 242 M ole 2 Find H for: SiH4 + 2O2 SiO2 + 2H2 O KJ SiH4 Si+2H2 H = 34 M ole

Si+O2 SiO2

KJ H = 911 M ole

KJ 2H2 + 2O2 H2 O H = 484 M ole KJ SiH4 + 2O2 SiO2 + 2H2 O H = 1429 M ole

29.1.4

Standard Heat of Formation

Standard heat (enthalpy) of formation (Hf )2 is the energy involved in forming one mole of a chemical from its elements under standard conditions.

Elemental substances (O2 , H2 , etc.) always have a H of zero. Example Find the H for: 2H2 O2 2H2 O + O2 Hf H2 O2 = 187 Hf H2 O = 285
2(187) 2(285)

2H2 O2 2H2 O + O2
374 570

H = product reactant KJ H = 570 (374) = 196 M ole

2 This

symbol may be shortened to H or Hf in this subsection.

32

29.2

Entropy

Entropy stands for the Disorder of the reaction and is denoted by S. If: S<0 Order is increasing S>0 Disorder is increasing 29.2.1 If: Solid Liquid S = + Gas Solid S = Solid Lowest S 29.2.2 Number of Moles of Gasses Liquid Gas Highest S State of Matter

Solids and liquids do not apply Example N2(g) + 3H2(g) 2N H3(g) 4 moles gas 2 moles gas | S = 2 moles gas 4 moles gas | S = + 29.2.3 Pressure of Gas

When pressure increases, disorder decreases. When pressure decreases, disorder increases. Example What has more disorder? N2 at 1 atm N2 at 0.001 atm Answer: N2 at 0.001 atm

29.3

Gibbs Law of Free Energy

Gibbs Law determines G which signies whether a reaction is spontaneous or not. G = H (T S) G = Free Energy in a system H = Enthalpy (KJ) S = Entropy ( KJ ) K S MUST be converted from T = Temperature in Kelvin To convert C K add 273
J K

to

KJ K .

33

If: G<0 Spontaneous G>0 Not spontaneous 29.3.1 H, S, G, Relationship Table S = + S = S = + S = G = G = G = + G = + Always spontaneous Spontaneous at low temperatures Spontaneous at high temperatures Never spontaneous Example P OCL3 2P Cl3 + O2 H = 542 KJ J S = 179 K What temperature is it spontaneous at? 0 = 542 KJ (T 0.179 KJ ) K 542 = 0.179T T = 3027.93 K

H = H = H = + H = +

30

Chemical Kinetics and Rate Laws

Factors that aect reaction rates

30.1

Physical State
An increase in surface area means in an increase in the rate.

Solid

Gas - Gas Liquid - Gas Liquid - Liquid

30.2
3

Concentration
moles liter

Molarity =

[HCL] = 3M An increase in concentration is generally an increase in rate.

30.3

Temperature

An increase in temperature is an increase in rate.

30.4

Pressure of Gas

An increase in pressure is an bincrease in rate.

30.5

Catalysts and Inhibitors

is signied by []s

A catalyst lowers the activation energy while an inhibitor increases the activation energy.
3 Molarity

34

30.6

Rate Laws
A+B C +D rate = k[A]m [B]n

k = Constant m = Order of A n = Order of B Order of 0 No eect Order of 1 Linear - Double the concentration and you double the rate Order of 2 Squared - Double the concentration and you quadruple the rate Trial 1 2 3 Example: [A] [B] Rate 0.1 M 0.1 M 0.04 M/s 0.2 M 0.1 M 0.08 M/s 0.1 M 0.2 M 0.04 M/s Solve for m:

trial 2 [] rate 0.2 m 0.08 = ( )m = =( ) = trial 1 [] rate 0.1 0.04 2m = 2 m=1 Solve for n: ( 0.2 n 0.04 ) = 0.1 0.04 1n = 1 n=0 rate = k[A]1 [B]0 Solve for k: 0.04 = k[0.1]1 [0.1]0 k = 0.4 30.6.1 Order Table Comments Rate Law Integrated Rate law Graph K = Slope Half-Life (t 1 ) 2 Zero Order rate = k [A] [A]0 = kt [A] = kt + [A]0 [A] vs Time Slope = k t 1 = [A]0 2k 2 First Order rate = k[A]1 ln[A] ln[A]0 = kt ln[A] = kt + ln[A]0 ln[A] vs time Slope = k t 1 = 0.693 k 2 Second Order rate = k[A]2 1 1 [A] [A]0 = kt 1 1 [A] = kt + [A]0 1 [A] vs time Slope = k 1 t 1 = k[A]0 2

35

Example: 2N2 O5 4N O2 + O2 [N2 O5 ] 0.1 0.0707 0.05 0.025 0.0125 0.00625 1. What is the order of the reaction? [A] = straight
1 [A]

Time (s) 0 50 100 200 300 400

= straight

ln[A] = straight Order of 1 2. What is the k constant value?

ln(0.0707)ln(0.1) 500 0.347 50

= 0.00693

k = 0.00693 3. What is the concentration of N2 O5 at t = 150? ln[A] = (0.00693)(150) + ln(0.1) ln[A] = 3.34 [A] = 0.0354 M 4. What is the rate at 150 seconds? rate = k[A] rate = 0.00693 [0.0354] rate = 2.45 104 M/s 5. What is the half life? t 1 = 0.693 k 2 0.693 1 t 2 = 0.00693 t 1 = 100 s 2

31

Reaction Mechanisms

Many/most reactions do not take place in one step. If a reaction were to react in one step, then you could use the balanced reaction to determine the rate law. For example, assume the following occured in one step. M gCl2 + 2Hbr 2HCl + M gBr2 rate = k[M gCl2 ]1 [HBr]2 In reality though, things are not always as easy. Through experimentation we gure out that the rate law for: N O2 + CO N O + CO2 is rate = k[N O2 ]2 Because the rate law does not link up with the equation, it is not a single step reaction.

36

31.1

Elementary Steps

Unimolecular - 1 reactant Bimolecular - 2 reactants Terrmolecular - 3 reactants

32

Equilibrium

The state where the concentration or partial pressures (if it is a gas) of all the reactants and products remain constant with time. For equilibrium to occur, the forward reaction rate must equal the reverse rate. In other words, the amounts do not have to be equal, but the rates must be.

32.1

Types of Equilibrium

Static No movement Dynamic Movement such as a sealed container of water

32.2

Equilibrium Constant Expressions

aA + bB Kc = Kp = cC + dD [C]c [D]d [A]a [B]b

(P C c )(P Dd ) (P Aa )(P B b )

Kc = Concentration constant Kp = Partial Pressure constant 32.2.1 Converting Constants

To convert between the two constants Kc and Kp use the formula: Kp = Kc (RT )n n = P roduct Coef f icients Reactant Coef f icients

33
33.1

Gas Laws
Gas Units and Conversions
1 Atm = 760 Torr (mmHg) = 101.3 kPa = 14.7 PSI

33.2

Ideal Gas Law

P v = nRT

P = Pressure (Atm) v = Volume (L) n = Number of moles R = 0.0821 (constant) T = Temperature (Kelvin) Example 3 grams of HCl at 26 C in a 3 Liter container. What is the pressure?
P (3) 3

3 ( 36.5grams )(0.081)(26+273) g/mole 3

P = 0.0664 Atm

37

33.3

Real Gas Law

For use when the ideal gas law fails. The ideal gas law fails when these two postulates fail: Molecules do have volume Molecules are attracted This law is also used when there are conditions with high pressure and low temperature. P v = nRT (P + n a ) (v nb) = nRT v2
2

a = constant that xes the intermolecular force issue b = constant that xes the volume issue a and b are unique to each type of gas All other variables are the same as the ideal gas law

33.4

Combined Gas Law

P1 V1 P2 V2 = T1 T2

33.5

Daltons Law of Partial Pressures

For a mixture of gases in a container, the total pressure (Ptot ) is equal to the sum of the pressures each gas exerts as if it were alone. Ptot = P1 + P2 + P3 + + Pn Example: A mixture of 1g H and 1g He in a 1 L container is at 27 C. Calculate the mole fraction of each gas, partial pressures of each and total pressure. H2 1 g 1 = 0.5 moles 2 x= (H mole) 0.5 = = 0.667 (H + He moles) 0.75 He 1 g 1 = 0.25 moles 4 x= 0.25 = 0.333 0.75 He P v = nRT P (1) = (0.25)(0.0821)(300) P = 6.15 Atm

H2 P v = nRT P (1) = (0.5)(0.0821)(300) P = 12.3 Atm

Ptot = 12.3 + 6.15 = 18.45 Atm

38

33.6

Gas Collection over a Water Solution

Example: A 0.986 g sample has Zinc and some impurities. Excess HCl is added and reacts with thte Zinc but not the impurities. Find the percent Zinc in the sample if 240 mL of H2 are collected over H2 O at 30 C and 1.032 Atm (HINT: This is the Ptot ). Ptot = P1 + PH2 O 1.032 = P1 + 0.042 P1 = 0.99 Atm H2 P v = nRT (0.99)(0.240) = n(0.0821)(303) n = 0.0096 mole H2 0.0096 mole H2 = 0.0096 mole Zn 0.0096 mole Zn 65.4 g Zn = 0.628 g Zn 1 M ole 0.628 g Zn 100 = 63.7%Zn 0.986 g total

34

ICE ICE (Baby)

Given initial values for a system at equilibrium and one of the equilibrium values, you should nd: a - The other equilibrium values b - The equilibrium constant Example: A closed system initially containing 1 103 M H2 and 2 103 M I2 at 448 C is allowed to reach equilibrium. Analysis of the equilibrium mixture shows the [HI] = 1.7 103 M . Find the equilibrium concentration for H2 and I2 as well as the Kc value. H2 + I2 Initial Change Equilibrium 1 10 M 0.935 103 0.065 103
3

2HI 2 103 M 0.935 103 1.065 103 0M 1.87 103 1.87 103

[H2 ] = 0.065 M [I2 ] = 1.065 103 M Kc = [1.87 103 ]2 [1.065 103 ][0.065 103 ]

35
35.1

Acids and Bases

Denitions of Acids and Bases
An acid dissociates in water to form H + ions and a base dissociates to form OH ions.

1. Arrhenius 2. Bronsted-Lowry Acids are proton donors (H + ) and a base is a proton acceptor. Conjugate acid base pair
HN O3 + H2 O H3 O+ + N O3 Acid 1 Base 2 Acid 2 Base 1

3. Lewis Acid Acid is an e pair acceptor while a base is an e pair donor. 39

35.2

pH and pOH

pH and pOH are measures of the amount of ions in a solution that either cause the solution to be acidic or basic. pH Scale Basic 0 14 Acidic Important Formulas pH = log[H + ] pOH = log[OH ] pH + pOH = 14 [H + ] = 1 10pH [OH ] = 1 10pOH Example What is the concentration of HCl with a pH of 3? [HCl] = 0.001 M 35.2.1 Changing Concentrations M1 V 1 = M2 V 2 (0.25 M )(5 mL) = M2 (50 mL) M2 = 0.025 M

35.3

Strong Acids and Bases

Strong acids and bases completely dissociate in water. 35.3.1 Strong Acids

HCl H2 SO4 HBr HI HN O3 HClO4 35.3.2 Strong Bases

Group 1 - Hydroxides N aOH KOH Group 2 - Heavier Hydroxides Ca(OH)2 Sr(OH)2 Ra(OH)2

35.4

Weak Acids and Bases

Weak acids and bases do not completely dissociate in water.

40

35.4.1

Ka Constant HA HA + H2 O Ka = H + + A H 3 O + + A [H + ][A ] [HA]

Example Benzoic acid dissociates as follows: HC7 H5 O2

H + + C7 H6 O2 x2 x x

[HC7 H5 O2 ] = 0.4 M Ka = 6.3 105 What is the pH? Ka = 6.3

[H + ][C7 H5 O2 ] [HC7 H5 O2 ] x2 105 = 0.4

35.4.2

Kb Constant

The Kb constant is used when bases are involved in a reaction (as opposed to Ka which is used in reactions with acids). To convert between Kb and Ka use the following formula: Ka Kb = Kw Kw = 1 1014 Example HF + OH F + H2 O Ka = 7.2 104 What is the Kb constant? 11014 Kb = 7.2104 = 1.39 1011 Find the pH and pOH. Kb = 1.39
[HF ][OH ] [F ] x2 11 10 = ( 0.002 ) 20+13.3 7

x = 9.13 10 pOH = 6.04 pH = 7.96

35.5

Common Ion Eect

The eect of ionization of a weak electrolyte (acid/base) is decreased by adding a strong electrolyte that has an ion in common with the weak electrolyte.

35.6

Buer

Made of 2 components: 1. Weak acid 2. The salt of that acid

41

36

Equilibrium of Saturated, Soluable Salts

Example: 2 CaCO3 (s) Ca+2 + CO3 (aq) (aq) 2 Ksp = [Ca+2 ][CO3 ]

Solubility is how well a solute dissolves in a solvent4 .

Ksp is the solubility product A large Ksp means the solution is very soluable (meaning lots of products) A small Ksp means the solution is not very soluable. 1. Given Ksp , nd the ion concentration.
2 Ksp = [Ca+2 ][CO3 ] = 4.5 109 2 [Ca+2 ] = [CO3 ] = 4.5 109 = 6.7 105 M

2. Given Ksp , nd the solubility (g/L). 6.7 105 M =

6.7105 1

100.1 1mole

= 6.37 103 g/L

3. Given solubility, nd ion concentration. Solubility of Silver Chloride at 25 C is 1.3 107 100gmL 1.3 107 100gmL
1.3106 L g L

10 10

g = 1.3 106 L

1 mole 143.35 g

= 9.11 109 m L

4. Given solubility, nd Ksp Ksp = [Ag + ][Cl ] = (9.11 109 )2 = 8.3 1017

37
37.1

Kinetic Molecular Theory

Postulates:
So volume is determined by the space between molecules

The volume of the individual particales of a gas can be assumed to be negligible.

The gas particles are in constant motion. The pressure exerted by a gas is due to collisions of the gas with the walls of the container. Gas particles are not attracted to one another. The average kinetic energy of a gas is directly proportional to the Kelvin temperature.
3 Kenergy = 2 (0.0821)T OR Kenergy = 1 (M olar M ass)(V elocity)2 2

A) CO at 760 torr and 0 C B) N2 at 760 torr and 0 C C) H2 at 760 torr and 0 C Q. Which will have the highest kinetic energy? A. All will have the same kinetic energy Q. Which will have a higher velocity? 1 A. H2 will because if all kinetic energies are constant according to the formula k = mv 2 the 2 smallest mass will yield the highest velocity to keep k constant.
4 Virtually

every salt is soluable to some degree.

42

37.2

Root Mean Square Velocity

Urms = 3RT M

J R = 8.314 KM ole

M = molar mass (Kg/mole) NOT g/mole

37.3
37.3.1

Eusion and Diusion

Eusion

When you pass a gas through a small opening into an evacuated chamber. 37.3.2 Diusion

When you mix gases 37.3.3 Finding the rate

The formula for nding the rate is as follows: Rate of Ef f usion of Gas 1 = Rate of Ef f usion of Gas 2 WHich euses faster, He or N O2 ? He - it moves faster because it is smaller For the reaction: H2 + N2 at 20 C and having a rate of eusion for H2 being 10 mL/min what is the rate for N2 ?
10 x 28 2 10 2 = 28

(M olar M ass 2) (M olar M ass1)

x=

2.67 ml/min

The rate for the gas is 24 mL/min, at the same temperature methane has a rate of 47.8 mL/min. What is the molar mass of the unknown gas?
24 47.8

16 x

x = 63.7 g/mole

38
38.1

Electro Chemistry
Identifying Oxidation Numbers
H2 O H +1 O -2 H2 SO4 H +1 S +6 O -2 Cl2 Cl 0

The chemical that has been oxidized is the reducing agent. The chemical that has been reduced is the oxidizing agent.

38.2

Galvanic/Voltaic Cells

There are two beakers with salt and e s in each solution. A salt bridge between the two solutions allows passage of ions. One side is identied as the cathode an the other the anode. The cations go to the cathode and the anions go to the anode. The e s go to the cathode.

43

38.3

Calculating Cell Potential

E cell = E reduction + E Oxidation Example Cu+2 + Zn Zn+2 + Cu Oxidation Zn Zn+2 + 2e e = 0.76 Reduction Cu+2 + 2e Cu e = 0.34 E cell = 0.34 + 0.76 = 1.1 volts

38.3.1

Nernst Equation to Find E cell

The Nernst equation to be used under standard conditions is: E cell = E E = Normal standard potential n = Number of moles of e s changing Q = Reaction Quotient =
[P roduct] [Reactant]

0.0592 log(Q) n

Example Cu(s) + Cu+2 Cu+2 +Cu(s) Q = 0.1 = 0.1 1 n = 2 (2 e being transfered) E = 0(1M 1M = N ovoltage E cell = 0 0.0592 log(0.1) 2 This Nernst equation is to be used when the temperature is not standard and the concentrations are not equal. RT E cell = E ln(Q) nF R = 9.31
volt coulomb mole Kelvin 1 M 0.1 M

F = 96,500 per mole e T = Temperature in Kelvin Example Zn + Cu+2 Cu + Zn+2 E cell = 1.1 0.0592 log( 0.5 ) 2 2 E cell = 1.1178 volts
2 M 0.5 M

39
39.1

Balancing Redox Reactions

Acidic
2 Cr2 O7 + Cl Cr+3 + Cl2 +2 2 1 +3 0

Half-Reactions [2Cl Cl2 + 2e ] 3 14H + + 6e + Cr2 O7 2Cr+3 + 7H2 O 14H + + 6Cl + Cr2 O7 2Cr+3 + 7H2 O + Cl2 44
+6

39.2

Basic
CN + M nO4 CN O + M nO2

Half-Reactions 2OH + H2 O + CN CN O + 2e + 2H + 2OH

H2 O 4OH + 4H + +3e + M nO4 M nO2 + 2H2 O + 4OH 2H2 O

(2OH + H2 O + CN CN O + 2e + 2H + 2OH ) 3
H2 O (4OH + 4H + +3e + M nO4 M nO2 + 2H2 O + 4OH) 2 2H2 O

6OH + 3CN 3CN O + 6e + 3H2 O

H2 O + 6e + 2M nO4 2M nO2 + 2OH

H2 O + 3CN

2M nO4

3CN O + 2M nO2 + 2OH

45