BIS 455 - Portland Slag Cement Specification
BIS 455 - Portland Slag Cement Specification
BIS 455 - Portland Slag Cement Specification
Indian Standard
( Reaffiid
1995 1
PORTLAND
SLAG CEMENT-SPECIFICATION
( Fourth Revision )
@ BIS 1990
BUREAU
MANAK
OF
BHAVAN, 9
INDIAN
BAHADUR NEW DELHI
STANDARDS
SHAH 110002 e-4 ZAFAR MARG
May 1990
FOREWORD This Indian Standard ( Fourth Revision ) was adopted by the Bureau of Indian Standards on 30 October 1989, after the draft finalized by the Cement .and Concrete Sectional Committee had been approved by the Civil Engineering Division Council. Portland slag cement is obtained by mixing, Portland cement clinker, gypsum and granulated slag in suitable proportions and grinding the mixture to get a thorough and intimate mix between the constituents. It may also be manufactured by separately grinding Portland cement clinker, gypsum and granulated slag and then mixing them intimately.. The resultant product is a cement which has physical properties similar to those of ordinary Portland cement. In addition, it has low heat of hydration and is relatively better resistant to soils and water containing excessive amounts of sulphater of alkali metals. alumina and iron, as well- as to acidic waters, and can, therefore, be used for marine works with advantage. The manufacture of Portland slag cement has been developed primarily to utilize blastfumace slag, a waste product from blastfurnaces. The development of manufacture of this type of cement will considerably increase the total output of cement production in the country and will, in addition, provide a profitable use for an otherwise waste product. The slags obtained from other types of furnaces, but having identical properties as those of granulated blastfumace slag conforming to this standard, may also be used for manufacture of Portland slag cement. This standard was first published in lb53 and subsequently revised in 1962,1967 and 1976. This fourth revision incorporates the modifications required as a result of experience gained with the use of this specification and to bring the standard in line with tlse present practices followed in the production and testing of cement. Since publication of the third revision of this standard, large number of amendments have been issued from time to time in order to modify various requirements based on the experience gained with the use of the standard and the requirements of the users and also keeping in view the raw materials and fuel available in the country for manufacture of cement. The important amendments include incorporating a value of 28 day compressive strength, increasing the requirement regarding loss on ignition from 40 to 50, increasing the insoluble residue content from 25 to 4 percent, making aumdave soundness test compulsory, incorpoiating a provision for retest in respect of autoclave soundness test after aeration of the cement, incorporating a clause on false set of cement and permitting packaging of cement in 25 kg bags. In view of these large number of amendments, the Sectiolral Committee decided to bring out the fourth revision of the standard incorporating all these amendments so as to make it more convenient for the users. The desirable requirements of granulated slag suitable for the manufacture of Portland slag cement have been deleted from this revision and reference has been made to IS 12089 : 1987 Specification for granulated slag for the manufacture of Portland slag cement. This standard contains clauses 5.1 and 11.4.1 which permit the purchaser to use his option and clauses 6.5,9.2.1 and 9.3 which call for agreement between the purchaser and the manufacturer. In the formulation of this standard considerable assistance has been rendered by National Corncil for Cement and Building Materials, New Delhi as many of these modifications are based on studies carried out by them. The composition of the committee responsible for the formulation of this standard is given in Annex C.
Mass of cement packed in bags and the tolerance requirements shall be in accordance with the relevant provisions of the Standards of Weights and Measures ( Packaged Commodities ) Rules, 1977 and,B-1.2 ( see Annex B for information ). Any modification in these rules in respect of tolerance on mass of cement would apply automatically to this standard. For the purpose of deciding whether a particular requirement of this standard is complied with, the final value, observed or calculated, expressing the result of a test or analysis, shall be rounded off in accordance with IS 2 : 1960 Rules for rounding off numerical values ( r&vised ). The number of significant places retained in the rounded off value should be the same as that of the specified value in this standard.
Is 395 : 1999
Indian Standard
5.1 Portland cement clinker used in the manufacture of Portland slag cement shall comply in all respects with the chemical requirements specified for the 33 grade ordinary Portland cement in IS 269 : 1989, and the purchaser shall have the right, if he so desires, to obtain samples of the clinker used in the manufacture of Portland slag cement. 5.2 The Portland slag cement shall comply with the following chemical requirements when tested in accordance with the methods given ip IS 4032 : 1985: Percent, Max Magnesium oxide ( MgO ) Sulphur trioxide ( SO, ) Sulphide sulphur ( S ) Loss on ignition Insoluble residue
NOTES 1 Total chloride content in cement rball not exceed 0.05 percent by mass for cement used in prestressed concrete structures and long rpan reinforced concrete structures. ( Method of test for determination of chloride content in cement is given in IS 12423 : 1988. ) 2 The limit of total chloride content in cement for use in plain and other reinforced concrete structures is being reviewed. Till that time, the limit may be mutually agreed to between the purchaser and the manufacturer. 3 Granulated slag conforming to IS I2i)89 : 1987 bar been found suitable for the manufacture of Portland slag cement.
80 3-o 15 50 4d
When tested for fineness in terms of specific surface by Blaines Air permeability method described in IS 4031 ( Part 2 ) : 1988, the specific surface of slslg cement shall be not less than 225 m/kg.
6.2 Soundness
Standard sand shall conform to IS 650 : 1966. of water required to produce a patteof standard consistency (see 11.3).
2 P ijFthe percentage
6.2.1 When tested by Le-Chatelier method and autoclave test described in IS 4031 ( Part 3 ) : 1988, unaerated Portland slag cement shall not have an expansion of more than 10 mm and 08 Percent respectively. 6.2.1.1 In the event of cements failing to comply with any one or both the requirements specified in 63.1, further tests in respect of each fail&e shall be made as described in IS 4031 ( Part 3 ) : 1988 from another portion of the same sample after aeration. The aeration shall be done by spreading out the sample to a depth of 75 mm at a relative humidity of 50 to 80 percent fo,r a total period of 7 days. The expansion of cements so aerated shall be not more than 5 mm and 06 percent when tested by Le-Chatelier method and autoclave test respectively. 6.3 Setting Time The setting time of slag cement, when tested by the Vicat apparatus method described in 1S 4031 ( Part 5 ) : 1988, shall be as follows: Not less than a) Initial setting time 30 minutes Not more than b) Final setting time 600 minutes 6.3.1 If cement exhibits false set, the ratio of final Penetration measured after 5 minutes of completion of mixing period to the initial penetration measured exactly after 20 seconds of completion of mixing period, expressed as percent, shall be not less than 50. In the event of cemerit exhibiting false set, the initial and final setting time of cement when tested by the method described in 1s 4031 ( Part 5 ) : 1988 after breaking the false set, shall conform to 6.3. 6.4 Compressive Strength The average compressive strength of at least !hree mortar cubes ( area of face 50 cm* ) composed of one part of cement, three parts of standard sand ( see Note 1 ) by mass and ( P/4+3*0 ) percent( of combined mass of cement plus sand ) water, and prepared, stored and tested in the manner described in IS 4031 ( Part 6 ) : 1988, shall be as follows: a) 72&l h b) 168 f2 h c) 672 f4 h Not less than 16 MPa Not less than 22 MPa Not less than 33 MPa 2
6.5 By agreement between the purchaser and ihe manufacturer, transverse strength test of plastic mortar in accordance with the method described in IS 4031 ( Part 8 ) : 1988 may be specified in addition to the test specified in 6.4. The permissible values of the transverse strength by this method shall be as agreed to between the purchaser and the manufacturer at the time. of placing the order. 6.6 Notwithstanding the strength requirements in 6.4 and 6.5. the Portland slag cement shall show a progressive increase in strength from the strength at 72 hours. 7 STORAGE 7.1 The cement shall be stored in such a manner as to permit easy access for proper inspection and identification and in a suitable weather-tight building to protect the cement from dampness and to minimize warehouse deterioration. 8 MANUFACTURERS CERTIFICATION
8.1 The manufacturer shall satisfy him+f that the cemeni conforms to the requirements of this standard, and if requested, shall furnish a certificate to this effect to the purchaser or his representative, within ten days of despatch of cement.
8.2 The manufacturer shall furnish a certificate, within ten days of despatch of the cement, indicating the total chloride content in Percent by mass of cement. 9 DELIVERY 9.1 The cement shall be packed in bags [jute sacking bag conforming to IS 2580 : 1982, double hessian bituminized ( CR1 type ), multi-wall paper conforming to IS 11761 : 1986, polyethylene lined ( CR1 type ) jute, light weight0 jute conforming to 1s 12154 : 1987, woven HDPE conforming to 1s 11652 : 1986, woven polypropylene conforming to IS 11653 : 1986, jute synthetic union conforming to IS 12174 : 1987 or any other approved composite bags ] bearing the manufacturers name or his registered trade-mark, if any. The words Portland Slag Cement or a suitable mark to distinguish Portland slag cement froqr other Portland cements shall be clearly and indelibly marked on each bag. The number of bags ( net mass ) to the tonne or the average net mass of the cement shall be legibly and indelibly marked on each bag. The bags shall be in good condition at the time of inspection.
Is 455 : 1989 9.1.1 Similar information shall be provided in the delivery advices accompanying the shipment of packed or bulk cement ( see 9.3 ). 9.2 The average net mass of cement per bag shall be 50 kg ( see Annex B ).
9.2.1 The average net mass of cement per bag may 11 TESTS 11.1 The sample or samples of cement for tests shall be taken as described in IS 3535 : 1986 and s!~$ll be tested in the manner prescri&d in the relevant clauses.
11.2 Temperature for Testing The temperature at which the physical tests may be carried out shall, as far as possible, be 27 %!C. The actual temperature during the testing shall be recorded.
11.3 Consistency of Standard Cement Paste
also be 25 kg subject to tolerances as given in 9.2.1.1 and packed in suitable bags as agreed to between the purchaser and the manufacturer. 9.2.1.1 The number of bags in a sample taken for weighment showing a minus error greater than 2 percent of the specified net mass shall be not more than 5 percent of the bags in the sample. Also the minus error in none of such bags in the sample shall exceed 4 percent of the specified net mass of cement in the bag. However, the average net mass of cement in a sample shall be equal to or more than 25 kg. 9.3 Supplies of cement in bulk may be made by agreement between the purchaserand the supplier ( manufacturer or stockist ).
single bag or container containing 1 000 kg or more net mass of cement shall be consiSupplies of cement dered as bulk supply of cement. may also be made in intermediate containers, for example drurrs of 200 kg, by agreement between the purchaser and the manufacturer.
The quantity of water required to produce a paste of standard tionsistency, to be used for the determination of the water content of mortar for the compressive strength test and for the determination of soundness and setting time. shall be obtained by the method descrilbed in IS 4031 (Part4): 1988.
11.4 Independent Testing 11.4.1 If the purchaser or his representative requires independent test, the samples shall be taken before or immediately after delivery at the option of the purchaser or his representative, and the tests shall be carried out in accordance with this standard on the written instructions of the purchaser or his representative. 1 t .4.2 Cost of Testing
NOTE -A
10 SAMPLING
10.1 Samples for Testing A sample or samples for testing may be !aken by
the purchaser or his representative, or by any person appointed to superintend the work for the purpose of which the cement is required, or by the latters representative.
10.1.1 The samples shall be taken within three weeks of the delivery and ail the tests shall be commenced within one week of sampnng.
The manufacturer shall supply, free of charge, the cement required for testing. Unless otherwise specified in the enquiry and order, the cost of tests shall be borne as follows: a) By the manufacturer if the results show that the cement does not comply with this standard; and b) By the purchaser if the results show that the cement complies with this standard,
11.4.3 After a representative sample has been drawn and hermetically sealed. tests on the sample shall be carried out as expeditiously as possible.
10.1.2 When it is not possible to test the samples within one week, the samples shall be packed. and stored in air-tight containers till such time that they are tested. 10.2 In addition to the requirements of 10.1, the methods and procedure of sampling shall be in accordance with IS 3535 : 1986, 10.3 Facilities for Sampling and Identifying The manufacturer or tipplier shall afford every facility, and shall provide all labour and materials for taking and packing the samples for testing the cement and for subsequent identification of the cement sampled. 3
12 REJECTION 12.1 Cement may be rejected if it does not comply with any of the requirements specified in this specification. 12.2 Cement remaining in bulk storage at the mill, prior to shipment, for more than six months, or cement in bags in local storages in the hands of a vendor for more than three months after compia tion of tests, may be retested before use and may be rejected if it fails to conform to any of the requirements in this specification.
Is 455 : 198)
ANNEX
( Clullse 2.1 )
LIST OF REFERRED INDIAN STANDARDS
IS No. Title IS No. Title
269 : 1989
Specification for 33 grade ordinary Portland cement (fourth revision ) Specification for standard sand for testing of cement (first revision )
11652 ! 1986
Specification for high density polyethylene ( HDPE ) woven sacks fdr packing cement Specification for polypropylene I PP ) woven sacks fey packing cement Specification for multi-wall paper sacks for cement valved-sewn gussetted type Specification for granulated slag for the manufacture of Portland slag cement Specification for light weight jute bags for packing cement Specification for jute -synthetic union bag for packing cement Met hod for cblorimetric of hydraulic cement analysis
650 : 1966
11653 : 1986
2580 : 1982
11761 : 1986
3535 : 1986 4031 ( Part 1 toPart 13) 4032 : 1985 4845 : 1968 4905 : 1968
Methods of sampling hydraulic cements (first revision ) Methods of physical test for hydraulic cement (first revision ) Method of chemical analysis of hydraulic Cement (firsf revision ) Definitions and terminology ting to hydraulic cement rela-
12089 : 1987
ANNEX
( Clause 9.2 )
TOLERANCE REQUIREMENTS B-1 The average bags at the plant more than 50 kg. shall be as given FOR THE MASS OF CEMENT PACKED IN BAGS net mass ( 50 kg ) shall be not more than 5 percent of the bags in the sample. Also the minus error in none of such bags in the sample shall exceed 4 percent of the specified net mas of cement in the bag.
matter given in B-l and B-l.1 are NOTE -The extracts based on the Srandurds of We&&s qnd Measures ( Pcckaged Commodities ) Rules, 1977 to Any which reference shall be made for full details. modification made in these Rules and other related Acts and Rules would apply automatically.
net mass of cement packed in in a sample shall be equal to or The number of bags in a sample below:
Sample Size
B-l.2 In case of a wagon/truck load of 20 to 25 tonnes, the overall tolerance on net mass of cement shall be 0 to -t 0.5 percent.
mass of a jute sacking bag conforNOTE -The ming to IS 2580 : 1982 to hold 50 kg of cement in 531 g, the mass of a double hessian bituminized ( CRI type ) bag to hold 50 kg of cement is 630 g. the mass of a 6-ply paper bag to hold 50 kg of cement is approximately 400 g and the mass of a polyethylene lined ( CR1 type ) jute bag to hold 50 kg of cement is approximately 480 g.
B-l.1 The number of bags in a sample showing a minus error greater than 2 percent of the specified
4
Is 455 : 1989
ANNEX C ( Fofeword )
COMPOSITION
Chairman .Dn H. C. ~ISYESVARAY.4 Members
SHRI K. P. BANERIRE SHRI HARISfl N. MALANI ( A/t~~re SHRI S. K. BANRRJEE CHIEFENCIINE~R BD ) ( SHRI J. C. BASUR ( Akrnatc ) ) Larsen and Toubro National Bhakra Central Test House, Limited, Calcutta Board, Nangal Township New Delhi Bombay
CED 2
CHIEP ENGINEER( DF~IONS ) SUPERIN~NDINQ ENQINEER( S & S ) ( Alternate ) CHIEF ENGINEER( RESEARCH-CUMD~RECXOR) RESEARCH OFFICER ( CONCRETE TECHNOLOGY ) ( Alternote ) DIRECTOR JOINT DIRXTOR ( Alternafe )
Department,
Irrigation
Department,
Government
of Punjab
A. P. Engineering Central
Research
Laboratories,
Hyderabad
DIRECTOR CHEEPRESEARCH GFFXER ( Alternate DIRECTOR (C & MDD-II ) DEPUTY DIRECTOR ( C 8c MDD-II )
Research
Station,
New Delhi
( Alternafe
SHRI V. K. GHANEKAR SHRI S. GOPINATH SHRI A. K. GUPTA SHRI J. S~?NGUPTA SHRI P. J. JANUS DR A. K. CHATTERJFE( Alternate
( CSIR ), Ghaziabad
The Associated
Cement
)
Research, Designs and Railways ), Lucknow Organization
JOINT DIRIXTOR STANDARDS ( B & S )/CB-I JOINT DIRECTOR STANDARDS ( B & S )/ CB-II ( Alternate ) SHRI N. G. J&HI SHRI R. L. KAP~OR SHRI R. K. SAXENA ( AIternore DR A. K. MULLlCK &RI G. K. MAJUMDAR )
Bombay
), Department
of
Surface
National Council for Cement and Building Materials, New Delhi Hospital Services Consultancy Corporation ( India ) Ltd, New Delhi Geological Survey of India, Calcutta
)
for Cement
Industry
( Ministry
of
Private
Limited,
Calcutta
SHRI R. C. PARATE
Engineer-in-Chiefs
)
Army Headquarters
DR MOHAN RAI
Hindustan Prefab Limited, New Delhi Indian Roads Congress, New Delhi; and Central Road Research Institute.( CSIK ). New Delhi Central Road Research Institute ( CSIR ), New Delhi Central Building Research Institute ( CSIR ). Roorkee Dalmia
)
DR S. S. REHSI ( Alternote
SHRI A. V. RAMANA DR K. C. NARANO ( Alternate .SHRI G. RAMDAS SHRI T. N. SUBBA RAO SHrtt S. A. REDDI ( Alternate
Membera
Du M. RAMAIAA DR A. 0. MAIX~AVA RAO ( Alternate SHRI A. U. RIJHSWOHANI SiiIl C. S. SHAiUtA ( AIternate
SEcw!YhRY Smr K. R. SAXEIM ( Alternote )
Representing Structural
)
Research of India,
Ccntre New
( CSIR ), Madras
Cement Central
)
SUPEERINTENDINO ENC~NEER DESIGNS ) ( EXECUTIVEENQINEER SMD DWIS~ON ) ( ( Alfemute ) SHRI L. SWAROOP SHRI H. BHA~ACHARYA ( Alterrare )
Public
Works
of Tamil Nadu
Orissa Cement
New Delhi
Gannon
Dunkerly
of Engineers
BIS ( Ex-oficlo
Secretary
: 1
DR H. C. VI~VESVARAYA Members
DR A. K. MULLICK DR (-Svr ) S. LAXMI
for Cement
and Bqilding
Materials,
( Alternates 3
to Dr H. C. Visvesvaraya
New Delhi
Ctscesce~p
( RESEARCH-CUM)
SHRIJ. K. PAPAL ( Alternate ) DIRgCToa -ARCH OFFICIZR Alternote ) ( m(C&MDDII) Darun DIRFXTOR( C A MDD II ) ( Afternore ) Spur i. K. GATTANI SHRI R. K. VAHHNAM ( AIternatc ) SWRIJ. SEN GIJPTA &IN P. J. JAOLJS DR A. K. CHATTERJEB Alternate ) ( Jomy D~recrou, STANDARDS ( B & S )/CB-I &XNT DIRECTOR. STANDARDS ( B & S )/CB-11 ( Ahmate ) SRI: R. L KA~OOR
SHRI
Gujarat
Engineering
Research
Institute,
Vadodara Nasik
Maharashtra Central
Engineering
Research
Institute,
Water Commission,
New Delhi
Shree Digvijay
Cement
Co Ltd, Bombay
National Buildings Organization, New Delhi The Associated Cement Companies Ltd, Bombay Research, Designs and Standards Organization, Lucknow
R. K. DANA ( Alternate
) ( Department
of Surface
!&RI W. N. KARODE
Construction Co Ltd, Bombay Corporation Ltd. Poliyur, Tamil Nadu Hospital Services Consultancy Corporation ( India ) -New Delhi
Chettinad Cement
Ltd,
Is 455 : 1989
MembcrJ ,SHRI K. P. kIiIDEEN SHRIN~RHALSINQH SHRI S. S. MI~LANI ( Alrcrno~c ) SHRt Y. R. PHULL SHRI S. S. SEEHRA( Alternafe) SHRI A. V. RAMANA DR K. C. NARAN~ ( Aflernale ) COL V. K. Rao
SHRI N. S. GALANDE ( Altemufe SHRI S. A. REDDI
Represenfing Central Warehousiog Corporation, New Delhi Development Commissioner for Cement Industry ( Ministry Industry ) Ceotral Road Research Institute ( CSlR ). New Delhi of
DR S.S. REHSI DR IRSHAD MASOOD ( Rlfemate ) SHRI A. U. RIJHSINQHANI SHRI M. P. SINGH SUPERINTENDING ENGINEER (D) SENIORDEPUTY CHIRPEN~INEZR ( GENERAL ( Alternate ) ) SHRI L. SWAROOP Srrru H. BHAT~ACHARYA AIrernole ) ( SHR~ V. M. WAD
( CSIR ), Roorkee
Cement Corporation of India Ltd, New Delhi Federation of Mini Cement Plants, New Delhi Public Works Department, Government of Tamil Nadu
Bureau of Indian Standards BIS is a statutory institution established under the Bureuu of Indian Standards Act, 1986 to promote harmonious development of the activities of standardization, marking and quality certification of goods and attending to connected matters in the country. Copyright No part of these publications may be reproduced in any form BIS has the copyright of all its publications. without the prior permission in writing of BIS. This does not preclude the free use, in the course of implementing the standard, of necessary details, such as symbols and sizes, type or grade designations. Enquiries relating to copyright be addressed to the Director (Publication), BIS. Review of Indian Standards Amendments are issued to standards as the need arises on the basis of comments. Standards are also reviewed periodically; a standard along with amendments is reaffirmed when such review indicates that no changes are needed; if the review indicates that changes are needed, it is taken up for revision. Users of Indian Standards should ascertain that they are in possession of the latest amendments or edition by referring to the latest issue of BIS Handbook and Standards Monthly Additions. This Indian Standard has been developed from Dot: No. CED Amendments Amend No. Date of Issue 2 ( 4745 )
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OF INDIAN
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tinted at Dee Kay Printers, New Delhi, India
AMENDMENT
NO. 1 TO
APRIL
1991
Revision
Insert the
/
new clauses after so
11~1
following
9.2.2 When cement is intended for export and if the putch,>scr requires, packing of cement may be done in bags with an average mass per bag as agreed to by the purchaser and the manufacturer.. 9.2.2.1 For this purpose the permission of the certifying be obtained in advance for each export order. 9.2.2.2 cement The words FOR EXPORT per bag shall be clearly marked material shall be and the in indelible aa agreed authority
shall (It
the supplier
9.2.2.4 The tolerance requirements for the mass of cement packed in bags shall be as given in 9.2.1.1 except the average net mass wlricll shall be equal to or more than the quantity in 9.2.2.
(CXDZ)
AMENDMENT
FED21
AMENDMENT
[ Ptqe 3, clnrrse 9.2.1.1 ( see u/so Amendment No. 1 ) ] following for the existing clauses 9.2.2 to 9.2.2.4:
Substitute tbe
9.2.2 When cement is intended for export and if the purchaser so requires, paching of cement may be done in bags or in drums with an average net mass of cement per bag or drum as agreed to between the purchaser and the manufacturer. 9.2.2.1 For this purpose the pemlission of tbe certifying obtained in advance for each export order. authority shall be
9.2.2.2 Tbe words FOR EXPORT and the average net mass of cement per bag/drum shall be clearly marked in indelible inkon each bag/drum. 9.2.2.3 The packing material shall be as agreed to between the manufacturer and the purchaser. 9.2.2.4 The tolerance requirements for the mass of cement packed in bags/drum shall be as given in 9.2.1.1 except the average net mass which shall be equal to or more than the quantity in 9.2.2.
AMENDMENT
Substitute net mass for average net mass wherever it appears in the standard. ( Page 1, clause 4.1, lust sentence ) 65 percent. Substitute 70 percent jor
(CED2)
Reprography Unit, BIS, New Delhi, India