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    Electrochemistry

    Uploaded by

    aashish
    This document contains questions about various topics in electrochemistry. It asks the student to calculate standard cell potentials, Gibbs free energy and equilibrium constants for galvanic cells. It also asks about defining and explaining how conductivity and molar conductivity vary with concentration for electrolyte solutions. Several questions involve calculating conductivity, molar conductivity, mass deposited, charge required and electricity needed for various electrolysis and electrochemical reactions. The last few questions are about explaining how rusting acts as an electrochemical cell, describing the recharging of a lead-acid battery, calculating resistivity from resistance measurements, determining the potential of a hydrogen electrode based on pH, and explaining the construction and working of a hydrogen electrode.

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    Electrochemistry

    Uploaded by

    aashish
    33 views2 pages
    This document contains questions about various topics in electrochemistry. It asks the student to calculate standard cell potentials, Gibbs free energy and equilibrium constants for galvanic cells. It also asks about defining and explaining how conductivity and molar conductivity vary with concentration for electrolyte solutions. Several questions involve calculating conductivity, molar conductivity, mass deposited, charge required and electricity needed for various electrolysis and electrochemical reactions. The last few questions are about explaining how rusting acts as an electrochemical cell, describing the recharging of a lead-acid battery, calculating resistivity from resistance measurements, determining the potential of a hydrogen electrode based on pH, and explaining the construction and working of a hydrogen electrode.

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    cbse chemistry test papers

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    This document contains questions about various topics in electrochemistry. It asks the student to calculate standard cell potentials, Gibbs free energy and equilibrium constants for galvanic cells. It also asks about defining and explaining how conductivity and molar conductivity vary with concentration for electrolyte solutions. Several questions involve calculating conductivity, molar conductivity, mass deposited, charge required and electricity needed for various electrolysis and electrochemical reactions. The last few questions are about explaining how rusting acts as an electrochemical cell, describing the recharging of a lead-acid battery, calculating resistivity from resistance measurements, determining the potential of a hydrogen electrode based on pH, and explaining the construction and working of a hydrogen electrode.

    Copyright:

    © All Rights Reserved
    Download as DOCX, PDF, TXT or read online from Scribd
    Download as docx, pdf, or txt
    33 views2 pages

    Electrochemistry

    Uploaded by

    aashish
    This document contains questions about various topics in electrochemistry. It asks the student to calculate standard cell potentials, Gibbs free energy and equilibrium constants for galvanic cells. It also asks about defining and explaining how conductivity and molar conductivity vary with concentration for electrolyte solutions. Several questions involve calculating conductivity, molar conductivity, mass deposited, charge required and electricity needed for various electrolysis and electrochemical reactions. The last few questions are about explaining how rusting acts as an electrochemical cell, describing the recharging of a lead-acid battery, calculating resistivity from resistance measurements, determining the potential of a hydrogen electrode based on pH, and explaining the construction and working of a hydrogen electrode.

    Copyright:

    © All Rights Reserved
    Download as DOCX, PDF, TXT or read online from Scribd
    Download as docx, pdf, or txt
    of 2

    ELECTROCHEMISTRY(MM=30, 1hr)

    1) Calculate the standard cell potentials of galvanic cell in which the following
    reactions take place:
    (i) 2Cr(s) + 3Cd2+(aq) 2Cr3+(aq) + 3Cd
    (ii) Fe2+(aq) + Ag+(aq) Fe3+(aq) + Ag(s)
    Calculate the Gr and equilibrium constant of the reactions.
    (2)
    2) Define conductivity and molar conductivity for the solution of an electrolyte.
    Discuss their variation with concentration.
    (2)
    3) The conductivity of 0.20 M solution of KCl at 298 K is 0.0248 S cm1. Calculate
    its molar conductivity. (1)
    4) The resistance of a conductivity cell containing 0.001M KCl solution at 298 K is
    1500. What is the cell constant if conductivity of 0.001M KCl solution at 298K is
    0.146 103 S cm1.
    (2)
    5) How much charge is required for the following reductions:
    (i) 1 mol of Al3+ to Al.
    (ii) 1 mol of Cu2+ to Cu.
    (iii) 1 mol of MnO4 to Mn2+.
    (2)
    6) How much electricity in terms of Faraday is required to produce
    (i) 20.0 g of Ca from molten CaCl2.
    (ii) 40.0 g of Al from molten Al2O3.
    (2)
    7) How much electricity is required in coulomb for the oxidation of
    (i) 1 mol of H2O to O2.
    (ii) 1 mol of FeO to Fe2O3.
    (2)
    8) A solution of Ni(NO3)2 is electrolysed between platinum electrodes using a current
    of 5 amperes for 20 minutes. What mass of Ni is deposited at the cathode?
    (2)
    9) Three electrolytic cells A,B,C containing solutions of ZnSO4, AgNO3 and CuSO4,
    respectively are connected in series. A steady current of 1.5 amperes was passed

    through them until 1.45 g of silver deposited at the cathode of cell B. How long
    did the current flow? What mass of copper and zinc were deposited?
    (2)
    10) Predict the products of electrolysis in each of the following:
    (i) An aqueous solution of AgNO3 with silver electrodes.
    (ii) An aqueous solution of AgNO3with platinum electrodes.
    (iii) A dilute solution of H2SO4with platinum electrodes.
    (iv) An aqueous solution of CuCl2 with platinum electrodes

    (2)

    11) Explain how rusting of iron is envisaged as setting up of an electrochemical cell ?


    (2)
    12) Write the chemistry of recharging the lead storage battery, highlighting all the
    materials that are involved during recharging.
    (2)
    13) The electrical resistance of a column of 0.05 mol L1 NaOH solution
    of diameter 1 cm and length 50 cm is 5.55 103 ohm. Calculate its resistivity,
    conductivity and molar conductivity. (2)
    14) Calculate the potential of hydrogen electrode in contact with a solution whose
    pH is 10.
    (1)
    15) Can you store copper sulphate solutions in a zinc pot?

    (1)

    16) Explain the construction and working of hydrogen electrode? (3)

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