Monel Alloy K-500
Monel Alloy K-500
Monel Alloy K-500
com
C
-200
-157
-130
-70
21
100
200
300
400
500
600
700
800
900
-6
6.2
6.5
6.8
7.2
7.6
8.1
8.3
8.5
8.7
9.1
9.3
9.6
m/mC
11.2
11.7
12.2
13.0
13.7
14.6
14.9
15.3
15.7
16.4
16.7
17.3
Thermal Conductivity
2
Btu-in/h/ft /F
W/mC
86
92
103
121
136
156
178
198
220
240
262
282
e
302
Specific Heat
Btu/lb/F
Electrical Resistivity
J/kgC
ohm-circ mil/ft
d
12.3
13.1
14.7
17.2
19.4
22.2
25.4
28.2
31.4
34.2
37.3
40.2
0.071
0.077
0.087
0.100
0.107
0.114
0.117
0.120
0.125
0.132
0.141
0.157
297.3
322.4
364.3
418.7
448.0
477.3
489.9
502.4
523.4
552.7
590.3
657.3
330.8
370
372
378
385
390
393
396
400
408
0.550
0.615
0.618
0.628
0.640
0.648
0.653
0.658
0.665
0.678
43.1
0.186
778.7
418
0.695
a
Between 70F (21C) and temperature shown. Age-hardened material.
b
Material was in the annealed condition prior to test.
c
Electrical resistivity is markedly influenced by thermal history because of the age-hardening characteristics of the alloy. The data shown represent values
measured on decreasing temperature on material in an equivalent to annealed condition with a small amount of age hardening.
d
Resistivity of sample from this test tested at room temperature: 355.5 ohm/circ mil/ft.
e
Extrapolated.
26
Tensile
Strength,
ksi
Permea-
Annealed,
Quenched
92.5
Annealed,
Age-Hardened
Condition
25
24
1.02
1.05
1.1
1.0011
-210
-210
151.0
1.0018
-153
-178
Cold-Drawn
20%
137.0
1.0011
-210
Cold-Drawn
20% and AgeHardened
186.5
1.0019
-130
-150
Cold-Drawn
50%
151.3
1.0010
-210
Cold-Drawn
50% and AgeHardened
198.0
1.0019
-130
-150
200
400
600
Temperature, F
800
1000
Curie Temperature, F
for Permeability of
1.01
23
bility
-202 -210
-182 -210
-182 -210
0.6
As-received
0.2
0.8
Polished
0
-400
400
800
1200
As-received
0.8
0.2
0.6
0.4
Clean and smooth
0.4
0.6
Polished
0.2
0.4
0.6
0.4
0.2
0.8
1.0
1.0
0.8
1.0
2000
1600
1.0
2000
Temperature, F
400
800
1200
1600
Cold-Drawn
b
Cold-Drawn, Aged
Aged at 70F
Cycled
Aged at 160F
1 Month
3 Months
12 Months
1 Month
3 Months
0
-5
-5
-5
-5
-5
MECHANICAL PROPERTIES
Tensile Properties and Hardness
The nominal range of room-temperature tensile properties and hardness are shown in Table 6. Approximate relationships
between tensile properties and hardness for rods and forgings appear in Figures 4 and 5, and similar relationships for sheet
and strip are shown in Figure 6. Notch properties are compared with those of smooth specimens in Table 7.
Short-time, high-temperature tensile properties of alloy K-500 rod in various conditions are shown in Figures 7-9. Testing
speeds for hot-rolled bar were 0.016 inch per minute through the yield strength and 0.026 inch per minute from there to
fracture. The cold-drawn specimens were tested at 0.00075 inch per minute through the yield strength, then 0.075 inch per
minute.
Effect of temperature on hardness of hot-finished and hot-finished, aged material is shown in Table 8.
180
140
160
120
140
Tensile Strength
80
Reduction of Area
60
60
40
40
Elongation
20
20
120
Yield Strength
100
80
60
60
Reduction of Area
40
40
0
0
70
80
Rockwell B
100
90
Elongation
110
20
20
10
15
20
25
30 35
Hardness
Rockwell C
Figure 4 - Approximate relationships between tensile properties
and hardness of MONEL alloy K-500 hot-finished rods and
forgings and cold-drawn rods.
0
20
25
30
35
40
Yield Strength
80
100
Tensile Strength
Hardness, Rockwell C
Figure 5 - Approximate relationships between tensile strength and
hardness of MONEL alloy K-500 age-hardened rods and forgings.
ksi
Rod and Bar
Hot-Finished
Hot-Finished, Agedb
Hot-Finished, Annealed
Hot-Finished, Annealed and Agedb
Cold-Drawn, As-Drawn
Cold-Drawn, Agedb
Cold-Drawn, Annealed
Cold-Drawn, Annealed and Agedb
Sheet, Cold-Rolled, Annealed
Strip, Cold-Rolled
Annealed
Annealed and Agedb
Spring Temper
Spring Temper, Agedb
Tube and Pipe, Seamless
Cold-Drawn, Annealed
Cold-Drawn, Annealed and Agedb
Cold-Drawn, As-Drawn
Cold-Drawn, As-Drawn, Agedb
Plate
Hot-Finished
Hot-Finished, Agedb
Wire, Cold Drawnc
Annealed
Annealed and Agedb
Spring Temper
Spring Temper, Agedb
90-155
140-190
90-110
130-165
100-140
135-185
90-110
130-190
90-105
MPa
621-1069
965-1310
621-758
896-1138
690-965
931-1276
621-758
896-1310
621-724
Yield Strength
(0.2% Offset)
ksi
40-110
100-150
40-60
85-120
70-125
95-160
40-60
85-120
40-65
MPa
Elongation,
%
276-758
690-1034
276-414
586-827
483-862
655-1103
276-414
586-827
276-448
45-20
30-20
45-25
35-20
35-13
30-15
50-25
30-20
45-25
Hardness
Brinell
(3000-kg)
140-315
265-346
140-185
250-315
175-260
255-370
140-185
250-315
-
Rockwell
75B-35C
27-38C
75-90B
24-35C
88B-26C
25-41C
75-90B
24-35C
85B max.
90-105
621-724
40-65
276-448
45-25
85B max.
130-170
145-165
170-220
896-1172
1000-1138
1172-1517
90-120
130-160
130-195
621-827
896-1103
896-1345
25-15
8-3
10-5
24C min.
25C min.
34C min.
90-110
130-180
110-160
140-220
621-758
896-1241
758-1103
965-1517
40-65
85-120
85-140
100-200
276-448
586-827
586-965
690-1379
45-25
30-15
15-2
25-3
90B max.
24-36C
95B-32C
27-40C
90-135
140-180
621-931
965-1241
40-110
100-135
276-758
690-981
45-20
30-20
140-260
265-337
75B-26C
27-37C
80-110
120-150
145-190
160-200
552-758
827-1034
1000-1310
1103-1379
35-65
90-110
130-180
140-190
241-448
621-758
896-1241
965-1310
40-20
30-15
5-2
8-3
The ranges shown are composites for various product sizes and therefore are not suitable for specification purposes.
Nominal properties for material age-hardened to produce maximum properties.
c
Properties shown are for sizes 0.0625 - 0.250-in. diameter. Properties for other sizes may vary from these.
b
Table 7 - Room-Temperature Smooth and Notch Tensile Properties of MONEL alloy K-500
Sample
Temper
Cold-drawn,
Annealed & Aged
Rod (3 5/8-in. Dia.) Hot-Rolled & Aged
Rod (3-in. Dia.)
Cold-Drawn & Aged
Threaded cap screw Cold-Drawn & Aged
Threaded Stud
Cold-Drawn & Aged
Yield
Strength
(0.2%
Offset), ksi
Notched
Tensile
Strength, ksi
Tensile
Strength,
ksi
NT/TSa
97.5
185.5
152.5
1.22
25
43.0
28
119.0
122.0
125.5
128.0
129.5
212.0
215.0
205.0
232.0
237.5
165.0
161.0
169.0
165.0
165.5
1.28
1.34
1.21
1.41
1.43
22
22
18
20
20
45.2
43.2
28.5
42.0
41.5
32
29
31
33
32
Elongation, Reduction
%
of Area, %
Hardness,
Rc
220
160
200
140
Annealed and
Heat-Treated
140
100
60
100
All Tempers,
No Heat Treatment
80
200
20, 40 or 50%
Reduction,
Heat-Treated
180
160
70
120
20, 40 or 50%
Reduction,
Heat-Treated
120
Tensile Strength
Yield Strength
(0.2% Offset)
50
80
40
30
60
Elongation
140
40
20
20
10
All Tempers,
No Heat Treatment
120
100
10% Reduction,
Heat-Treated
80
Annealed and
Heat-Treated
60
40
10
15
20
25
30
Hardness, Rockwell C
35
40
0
0
200
400
600
800
Temperature, F
1000
1200
110
50
100
90
Tensile Strength
Stress, ksi
70
Elongation
60
50
40
20
Yield Strength
(0.2% Offset)
30
30
Elongation, %
40
80
10
20
10
0
0
0
200
400
600
800
1000
1200 1400
Temperature, F
Figure 7 - High-temperature tensile properties of MONEL alloy K500 rod (hot-rolled, as-rolled).
The low-temperature properties of MONEL alloy K500 are outstanding. Tensile and yield strengths increase
with decrease in temperature while ductility and toughness
are
virtually
unimpaired.
No
ductile-to-brittle
transformation occurs even at temperatures as low as that of
liquid hydrogen. Thus the alloy is suitable for many
cryogenic applications.
Properties of alloy K-500 base metal and welded sheet
at temperatures down to -423F, as reported by the National
Aeronautics and Space Administration, are shown in Figures
10-12. Welds can be produced with the strength of agehardened base metal with no serious loss in ductility if aging
treatments are performed after welding annealed material.
Welding of age-hardened material should be avoided
because of greatly reduced ductility.
Tensile tests on sheet and autogenous welds by Watson
et al are shown in Table 9.
Elongation, %
160
Stress, ksi
180
80
10% Reduction,
Heat-Treated
70F (21C)
700F (371C)
241
331
223
311
Hot-Finished
Hot-Finished, Aged
Hardness, Brinell
800F (427C)
900F (482C)
207
302
80
160
1000F (538C)
201
293
1100F (593C)
170
255
179
229
200
Annealed
Aged
180
Tensile Strength
70
140
Tensile Strength
160
Tensile Strength
140
120
60
Yield Strength
(0.2% Offset)
50
40
Stress, ksi
80
100
Elongation, %
Stress, ksi
100
Yield Strength
50
Elongation
80
Yield Strength
60
40
Elongation, %
120
30
Elongation
40
20
20
10
30
60
Elongation
40
20
0
-500
0
-400
-300
-200
-100
100
Temperature, F
10
20
0
0
200
400
600
800
Temperature, F
Figure 9. High-temperature tensile properties of annealed and agehardened MONEL alloy K-500.
Table 9 - Tensile Properties of MONEL Alloy K-500 Sheet and Butt Weldsa
Test
Temperature,
F
78
-100
-320
-423
Sheet
Tensile
Strength,
ksi
Yield
Strength,
ksi
154
166
183
200
97.3
107
120
136
Weld
Tensile
Strength,
ksi
NT/
TSb
Elongation,
%
22
24
30
28
0.93
0.93
0.95
0.99
141
154
170
190
Joint
Efficiency,
%
Elongation,
%
92
93
93
95
11
14
15
14
0.020-in. sheet age-hardened 1080F/16 hr. Heliarc welds heat-treated after welding. Longitudinal tests.
Ratio of notch tensile strength to smooth tensile strength, Kt=6.3.
200
200
180
180
Tensile Strength
160
160
140
140
Tensile Strength
Yield Strength
40
Elongation
60
30
Yield Strength
40
20
20
10
Elongation, %
80
0
-500
Stress, ksi
Stress, ksi
50
100
0
-400
-300
-200
-100
Temperature, F
100
Figure 11 - Low-temperature tensile properties of MONEL alloy K500 welded and annealed (gas tungsten arc welds in 0.063-in.
sheet with MONEL Filler Metal 64).
100
50
80
40
60
30
Elongation
40
20
20
10
0
-500
Elongation, %
120
120
0
-400
-300
-200
-100
Temperature, F
100
Figure 12 - Low-temperature tensile properties of MONEL alloy K500 welded and age-hardened (gas tungsten arc welds in 0.063-in.
sheet using MONEL Filler Metal 64).
Condition
Hot-Rolled
Hot-Rolled, Aged
Cold-Drawn
Cold-Drawn, Aged
a
27
57
48
62
Angle of
Twist,
deg/in.
29
67
55
71
620
104
360
76
Table 11 - Comparison of Tensile and Torsional Properties of MONEL Alloy K-500 Rod and Wire
Breaking
Strength,
ksi
Proportional
Limit,
ksi
Torsional
Breaking
Strength/
Tensile
Strength
Torsional
Torsional
Proportional Proportional
Limit/
Limit/Torsion
Tensile
-al Breaking
Strength
Strength
107
68
0.657
0.417
0.635
Cold-Drawn 50%
Cold-Drawn 50%,
Age-Hardened
163
Yield
Strength
(0.2%
Offset), ksi
-
197
137
75
0.696
0.380
0.547
Hot-Rolled
Hot-Rolled, AgeHardened
Cold-Drawn 20%
Cold-Drawn 20%,
Age-Hardened
98
45
69
18
0.704
0.184
0.261
134
103
80
62
45
0.597
0.336
0.562
155
125
102
50
0.658
0.373
0.490
Condition
Form
Ratios
Torsional
Tensile
Tensile
Strength,
ksi
Shear Properties
Shear strength of alloy K-500 is shown in Table 12. Tests
were made in double shear on duplicate 0.050 x 0.250-in.
specimens with the cutters set to 0.005-in. clearance. This
type of test simulates the service requirements of pins used
in shackles or clevises.
Table 13 lists the shear strength of rivet wire. Properties
were determined from the load required to produce double
shearing of a 0.118 x 1.00-in. wide wire specimen in a
tongue and groove jig with 0.002-in. clearance. These data
show that rivets can be made to develop exceptionally high
strength by partial or full heat treatment prior to driving. The
ratio of shear strength to ultimate tensile strength decreases
very slightly with increasing hardness, indicating that the
longer aging periods increase tensile strength more rapidly
than shear strength. Based on these tests, aging for 4 hr at
1080 to 1100F followed by air cooling is recommended
for cold-headed rivets; this treatment is adequate to develop
a shear strength of about 85 ksi in the shank.
Bearing strength data are given in Table 14. These were
determined with 0.062 x 1.25 x 2.5-in. material having a
3/16-in. hole drilled 3/8-in. from the edge. The pin fitted
closely into the hole. The maximum load for tearing out of
the hole and the load required for a permanent enlargement
of the hole diameter by 2% were determined and calculated
as ultimate and yield strengths, respectively, in bearing.
Tensile
Hardness,
Maximum Deflection
Elongation
Rockwell
Strength, at Maximum Strength,
%
Strength, ksi
ksi
C
ksi
65.3
96.5
71.0
98.8
89.5
98.5
0.08
0.06
0.04
0.05
0.04
0.04
97.5
147.2
122.0
155.6
151.5
168.5
49.0
29.0
12.5
24.0
16.5
12.5
84B
29
25
31
33
37
As
Received
Aged
2 Hoursa
69.3
107.3
0.64
13
83.2
133.0
0.63
24
34
23
40
30
Hardness, Rc
Head
Shank
a
Aged
8 Hoursc
Aged
4 Hoursb
Rivet Wire
85.3
137.6
0.62
26
Rivetse
85.0
26
40
32
40
30
Aged
16 Hoursd
89.2
147.0
0.61
32
40
34
Tensile Properties
Condition
Tensile
Strength, ksi
Annealed
Annealed, Aged
Hard
Hard, Aged
92.2
145.5
145.9
195.5
Yield Strength
(0.2% offset),
ksi
Elongation.
%
Ultimate
Strength,a
ksi
Yield
Strength,b
49.0
31.0
5.0
10.0
178.0
295.0
294.0
358.0
68.8
162.0
190.0
262.0
38.5
98.5
139.0
177.0
ksi
Ultimate
Strength
Yield
Strength
1.93
2.03
1.72
1.83
1.79
1.65
1.37
1.48
Tearing out.
2% enlargement of hole dia. in sheet.
Compressive Properties
The results of compressive tests on alloy K-500, made on
triplicate samples from the same melt, are given in Table 15.
Impact Strength
Impact strength at room temperature is shown in Table 16
for typical specimens of various tempers. Charpy V-notch
impact strength of annealed and aged hot-rolled and colddrawn rod is in Tables 17 and 18.
The effect of low temperature on bending impact and
tension impact strength, as determined by the Naval
Engineering Experiment Station is shown in Table 19; all
samples showed ductile fracture. Charpy impact test results
down to -320F may be found in Table 20.
10
AsRolled
Cold-Drawn
Aged
AsDrawn
Aged
165
5
300
33
205
23
330
35
167
316
210
336
100.0
151.0
106.0
158.0
47.0
42.5
111.0
30.0
85.0
26.5
120.0
22.0
40.0
121.0
76.0
121.0
34.0
96.0
55.0
102.0
Charpy Keyhole
Impact
Strength, ft-lb
Hot-Finished
Longitudinal
Transverse
74
51
Hot-Finished, Annealeda
Longitudinal
Transverse
Longitudinal
Transverse
Longitudinal
Transverse
Longitudinal
Transverse
Longitudinal
Longitudinal
Longitudinal
Longitudinal
Longitudinal
75
48
39*
23*
25*
20*
38*
22*
40
90
26*
20*
46*
Condition
Hot-Finished, Agedb
Hot-Finished, Agedc
Hot-Finished, Annealed & Agedd
Cold-Drawn
Cold-Drawn,
Cold-Drawn,
Cold-Drawn,
Cold-Drawn,
Annealeda
Agedb
Agedc
Annealed & Agedd
c
Diameter,
in.
Yield Strength
(0.2% offset), ksi
Charpy V-Notch
Impact Strength, ft-lb
92.5
103.0
110.6
76.25
43.75
39.5
1.250
0.812
0.687
a
Condition
Notched Specimena
Hot-Finished, Aged
Cold-Drawn, Aged
158
127
Hot-Finished, Aged
Cold-Drawn, Aged
Tension Test
145
141
37
108
117
34
Bending test
42
185
30
37
28
35
29
50
30
55
32
1.250
1.250
0.875
1.00
a
Yield Strength
(0.2% offset), ksi
Charpy V-Notch
Impact Strength, ft-lb
97.3
92.5
109.3
111.0
54
72
45
38
Table 20 - Charpy V-Notch Impact Strength of MONEL alloy K500a at Low Temperatures
Temperature, F
Room
-110
-320
a
37.0
34.0
31.0
Fatigue Strength
Fatigue strength (108 cycles) at room temperature of various tempers of alloy K-500 are given in Table 21. The data on rod
were developed on high-speed (10,000-rpm) rotating-beam machines using polished specimens and represent average values
of a number of tests. Data on strip were reported by Greenall and Gohn. Specimens were subjected to alternate back-and-forth
bending as a flat spring; specimens were cut with the longitudinal direction parallel to the direction of rolling.
Fatigue strength of wire is shown in Figure 13.
Table 22 shows fatigue of aged MONEL alloy K-500 at 1000F. At low temperatures, fatigue strength increases (see Table
23). The material used in these tests was 0.051-in. sheet, cold-rolled half-hard and aged, with a tensile strength of 182.0 ksi.
Tests were in flexure (R = -1) at 1800 cpm except those at -423F, which were at 3450 cpm.
The effect of surface finish on fatigue strength has been studied. Table 24 shows the detrimental effect of an oxidized
surface. These tests indicate that it is advisable to use polished surfaces for parts subject to cyclical stresses. The oxide surface
was produced by age hardening in air.
11
Strip,
Tensile Strength,
ksi
Ratio,
Fatigue Strength/Tensile Strength
38
43
51
45
47
27
37
88
99
155
120
170
88
153
0.43
0.43
0.33
0.37
0.28
0.31
0.24
Annealed
Hot-Rolled
Hot-Rolled, Aged
Cold-Drawn
Cold-Drawn, Aged
Annealed
Spring-Temper, Aged
Stress, ksi
80
Condition
Age-Hardened
Fatigue Strength,
(108 cycles), ksi
80
1000
80
1000
46.0
43.0
52.0
48.0
Hot-Finished, Aged
Stress-Equalized
60
Temperature, F
Cold-Drawn, Aged
40
105
106
107
108
Cycles to Failure
Figure 13 - Fatigue strength of commercially produced MONEL
alloy K-500 wire (0.0375-in. diameter, cold-drawn 75% after final
anneal). Tested in processed condition. Data determined with a
rotating-wire (5000 rpm) arc-fatigue machine.
105 cycles
106 cycles
107 cycles
70
-110
-320
-423
90
99
105
143
55
67
69
101
37
Surface Finish
Tensile Strength,
ksi
Fatigue Strength
(108 cycles), ksi
Ratio, Fatigue
Strength/Tensile Strength
Polished
Oxidized
Polished
Oxidized
171.0
172.5
174.5
167.5
50.0
39.5
57.0
39.5
0.29
0.23
0.33
0.24
Low-Cycle Fatigue
Cyclic strain fatigue of alloy K-500 is shown in Figure 14. The curve represents a best fit for data on material in different
initial conditions but having received the same age-hardening treatment (1080-1100F/16 hr, F.C. 15-25F/hr to 900F).
Also, since data from both axial and completely reversed bending were used to derive the curve, it would be conservative when
pure bending is being considered. In Figure 14, Sa, stress amplitude, was calculated from
Sa = _____ x E
2
where = total strain range applied to the specimen after shakedown, and E = Youngs modulus of the specimen.
12
10
104
10
10
10
10
10
106
60 ksi
Reloaded to original length
at 8-day intervals
35 ksi
30 ksi
25 ksi
20 ksi
2
15 ksi
Cycles to Failure ( Nf )
0
0
16
24
32
40
48
56
64
Time, days
Figure 15 - Relaxation at 500F of MONEL alloy K-500 springs,
age-hardened at 1000F/6 hr. All stresses are shearing stresses
corrected for curvature; modulus corrected for temperature.
Spring Properties
MONEL alloy K-500 is useful for corrosion-resistant springs at temperature up to 500F. Typical usage stresses are shown in
Table 25.
The recommended aging treatment after cold coiling is 1000F/10 hr; or 980 to 1000F/6 hr followed by cooling to 900F
at a rate of 15 to 25F/hr. Some effects of heat treatment on properties of springs are shown in Table 26. The springs were
coiled on standard automatic equipment, cold-pressed to solid height several times, and heat-treated.
Relaxation of alloy K-500 springs at 500F is shown in Figure 15. Using a criterion of 5 to 6% relaxation in 7 days, these
data indicate a maximum useful temperature of 500F.
Method of
Coiling
Aging Treatment
After Coiling
Cold
Hot
400 to 450F
450 to 500F
65
65
65
65
50
55
All values include the Wahl Curvature Correction Factor and are based on 5% relaxation maximum at stress and temperature after 7 days. Stresses at
temperature are adjusted for modulus (G) at temperature.
Selection of break in size for hot or cold winding will be governed largely by the spring index and processing.
Table 26 - Properties of MONEL alloy K-500 Helical Springs (0.148-in. dia. Spring-Temper Wire, 65% Reduction)
Properties of Wires
Thermal Treatment after
Cold Coiling
As-Drawn
Stress-Equalized 525F/3 hr
Aged 980F/6 hr, plus 900F/6 hr
Tensile
Strength, ksi
Torsional
Breaking
Strength, ksi
Torsional
Proportional
Limit, ksi
162.5
171.8
197.0
106.3
107.2
137.2
67.5
67.5
74.6
55.0
59.5
107 Cycles
Initial Stress - 10.0 ksi
44.0
Initial Stress - 20.0 ksi
51.0
108 Cycles
39.5
47.0
13
MICROSTRUCTURE
100
80
750F
800F
60
900F
Stress, ksi
40
30
20
1000F
10
0.01
0.1
Creep Rate, %/1000 hr
Stress, ksi
60
900F
40
1000F
30
1100F
20
10
100
1,000
10,000
Rupture Life, hr
Figure 17 - Rupture life of hot-finished aged MONEL alloy K-500.
Bolting Applications
MONEL alloy K-500 is approved by the ASME Boiler and
Pressure Vessel Code as an acceptable material for use as
bolting. Allowable stresses for Section VIII, Division 1
usage up to 500F are presented in ASME Code Case 1192,
latest revision.
14
Figure 18 - Microstructure of hot-rolled, as-rolled MONEL alloy K500. Etchant: Carapellas and glyceregia. 100X.
CORROSION RESISTANCE
The corrosion resistance of MONEL alloy K-500 is
substantially equivalent to that of alloy 400 except that,
when in the age-hardened condition, alloy K-500 has a
greater tendency toward stress-corrosion cracking in some
environments.
MONEL alloy K-500 has been found to be resistant to a
sour-gas environment. After 6 days of continuous immersion
in saturated (3500 ppm) hydrogen sulfide solutions at acidic
and basic pHs (ranging from 1.0 to 11.0), U-bend specimens
of age-hardened sheet showed no cracking. Hardness of the
specimens ranged from 28 to 40 Rc.
The combination of very low corrosion rates in highvelocity sea water and high strength make alloy K-500
particularly suitable for shafts of centrifugal pumps in
marine service. In stagnant or slow-moving sea water,
fouling may occur followed by pitting, but this pitting slows
down after a fairly rapid initial attack.
For more information on the resistance of alloy K-500
and other alloys to attack by various corrosive media, the
reader is directed to the Special Metals publication High
Performance Alloys for Resistance to Aqueous Corrosion
on the website www.specialmetals.com.
WORKING INSTRUCTIONS
Heating and Pickling
The Federal Standard for alloy K-500, QQ-N-286,
addresses only solution annealing. In-process annealing is
left to the discretion of the heat treater. The stated solution
annealing temperature range in Revision F is 1600 to
1900F. Thus, if an alloy K-500 component must be solution
annealed at 2050F because of the presence of titanium
carbide, it must subsequently be reduced in section thickness
before final heat treatment (solution annealing + age
hardening) to comply with the requirements of the
specification. Revision G has amended the solution
annealing requirement to a minimum annealing temperature
of 1600F. Thus, material solution-annealed at 2050F can
be aged without further reduction in section thickness and is
acceptable if it meets the other requirements of the
specification (mechanical properties, etc.)
For optimum aging response and maximum softness, it
is important to obtain an effective water quench from the
heating temperature without delay. A delay in quenching or
a slow quench can result in partial precipitation of the agehardening phase and subsequent impairment of the aging
response. Addition of about 2% by volume of alcohol to the
water will minimize oxidation and facilitate pickling.
The effect of water quenching from various
temperatures is shown in Figure 19.
300
Thermal Treatments
General procedures and precautions for heating and pickling
of MONEL alloys may be found in the Special Metals
Corporation publication Fabricating on the website,
www.specialmetals.com.
Two types of annealing procedures are performed on
MONEL alloy K-500: solution annealing and process
annealing. The treatments are different in both their purpose
and procedure.
Solution Annealing - MONEL alloy K-500 is hardened
by the formation of submicroscopic particles of a secondary
phase, Ni3(Ti,Al). Formation of the particles takes place as a
solid state reaction during an age-hardening (or
precipitation-hardening) heat treatment. Prior to the aging
treatment, the alloy component should be solution-annealed
to dissolve any phases that may have formed in the alloy
during previous processing. Solution annealing is normally
performed by heating hot-finished products to 1800F and
cold-worked products to 1900F. To avoid excessive grain
growth, time at temperature should be kept to a minimum
(normally, less than 30 minutes). Heating (ramp) and
cooling times must be kept to a minimum to avoid
precipitation of detrimental phases. Cooling after solution
annealing is normally accomplished by quenching in water.
Process Annealing - During mechanical processing in
production and subsequent forming of alloy K-500 products,
intermediate process annealing may be required to soften the
product. Such anneals recrystallize the structure and are
typically conducted at temperatures between 1400-1600 F.
While higher temperatures will anneal the product,
intermediate process annealing temperatures are limited to
avoid excessive grain growth. Time at temperature must be
limited to avoid the formation of secondary phases which
can compromise the hardness of the aged alloy K-500
product.
Holding for one hour after the part has reached the set
temperature and equalized is normally sufficient to soften
the alloy product during processing. The user is cautioned
that exposure at temperature for times greater than 1.5 hours
is not recommended. Excessive exposure can result in the
formation of titanium carbide (TiC). This compound is
stable at the aging temperatures used to harden alloy K-500
such that the titanium cannot participate in the hardening
reaction, the formation of Ni3(Ti,Al). Thus, the strength and
hardness can be compromised.
Obviously, it is best to avoid the formation of the
titanium carbide phase. If, however, the phase is formed as a
result of improper processing, solution annealing at 2050F
for 30 minutes is required to dissolve the particles. It should
be noted that this heat treatment will result in a large grain
size which can somewhat compromise formability.
However, the high-temperature solution treatment is
necessary if the component is to develop full hardness and
strength during the aging treatment.
250
200
150
400
800
1200
1600
2000
Temperature, F
Figure 19 - Effect of water quenching from various annealing
temperatures on hardness of MONEL alloy K-500.
15
The following age-hardening procedures are recommended for achievement of maximum properties.
1. Soft material (140-180 Brinell, 75-90 Rockwell B).
Hold for 16 hr at 1100 to 1125F followed by furnace cooling at a rate of 15 to 25F per hr to 900F. Cooling from
900F to room temperature may be carried out by furnace or air cooling, or by quenching, without regard for cooling rate.
This procedure is suitable for as-forged and quenched or annealed forgings, for annealed or hot-rolled rods and large colddrawn rods (over 1 in. diameter) and for soft-temper wire and strip.
2. Moderately cold-worked material (175-250 Brinell, 8-25 Rockwell C).
Hold for 8 hr or longer at 1100 to 1125F, followed by cooling to 900F at a rate not to exceed 15 to 25F per hr. Higher
hardnesses can be obtained by holding for as long as 16 hr at temperature, particularly if the material has been coldworked only slightly. As a general rule, material with an initial hardness of 175-200 Brinell should be held the full 16 hr.
Material close to the top figure of 250 Brinell (25 Rockwell C) should attain full hardness in 8 hr.
These procedures are applicable to cold-drawn rods, half-hard strip, cold-upset pieces and intermediate-temper wire.
3. Fully cold-worked material (260-325 Brinell, 25-35 Rockwell C).
Hold for 6 hr or longer at 980 to 1000F followed by cooling to 900F at a rate not exceeding 15 to 25F per hr. In some
instances slightly higher hardnesses may be obtained (particularly with material near the lower end of the hardness range)
by holding 8 to 10 hr at temperature.
This procedure is suitable for spring-temper strip, spring wire or heavily cold-worked pieces such as small, cold-formed
balls.
NOTE: Cooling may be done in steps of 100F, holding the furnace 4 to 6 hr at each step. For example, procedure 1 could be
16 hr at 1100F + 4 to 6 hr at 1000F + 4 to 6 hr at 900F. Procedures described under 1, 2, and 3, however, will usually give
higher properties. Effects of furnace cooling and step cooling on yield strength of cold-drawn rod are compared in Table 27.
In some instances it may be desired to decrease heat-treating time, either for cost saving or for obtaining intermediate
properties. It is difficult to make specific recommendations which would cover the full range of possibilities. The best
procedure is to make pilot tests on specimens which duplicate the cross section of the material to be hardened.
Table 28, showing the effect of short-time aging at 1100 and 1000F, can be used as a guide. More information is given
later under Cold Forming.
Material which has been heated for any appreciable length of time in the temperature range 1100 to 1400F will be
overaged to an extent dependent on time and temperature of exposure. Overaged material will have lower mechanical
properties than properly aged metal, and the properties cannot be raised by subsequent aging treatments. In order to strengthen
overaged material, it must be solution-annealed (1800-1900F) to redissolve the age-hardening constituents, and then reaged.
All benefits of cold work are lost in annealing. The highest strength obtainable is that corresponding to the annealed and aged
condition.
Material that has been age-hardened to produce maximum hardness will not show an appreciable change in properties if
again heated to or held at any temperature up to that at which the original heat treatment was carried out. There may be a small
increase in properties if the rate of cooling in the original heat treatment was too rapid between 1050 and 800F. If the
hardened material is subsequently heated above 1100F and then cooled, there will be a decrease in properties.
Hardened MONEL alloy K-500 has been subjected to long continued heating at 800F. A further slow aging occurred
during the first month of exposure, but continued heating caused no further significant change in properties. Average data for
three typical heats are shown in Table 29.
Pickling
Pickling is a standard method for producing a clean surface on alloy K-500. Procedures and precautions are described in the
Special Metals publication Fabricating on the website www.specialmetals.com.
16
Tensile
Strength, ksi
Yield Strength
(0.2% offset), ksi
Elongation,
%
Reduction
of Area, %
Hardness,
Rc
Yield Strength
(0.2% offset),b ksi
156.5
154.0
152.0
149.0
156.0
160.5
152.0
153.0
150.0
153.0
155.5
156.5
156.0
155.0
98.0
95.0
96.5
91.5
99.0
102.0
100.5
100.5
96.5
100.0
99.5
101.5
100.5
99.5
26
24
26
26
25
26
26
26
26
26
26
25
27
27
42
39
46
45
45
42
49
47
51
49
45
45
46
47
29
29
28
27
29-30
29
29
28
27
28
29
29
28
26
94.5
94.0
95.5
90.0
98.0
98.5
98.5
97.5
96.0
100.0
99.0
101.5
97.5
97.0
3 1/4
3
3
2 3/4
2 5/8
1 1/2
1 1/2
1 3/8
1 1/4
1 1/4
1
1
5/8
5/8
a
Aged by step procedure: 1100F/16 hr, +1000F/6 hr, +900F/6 hr, A.C.
Rod,
Hot-Rolled
Strip,
Annealed
Yield
Tensile Strength ElonStrength,
(0.2% gation,
ksi
offset),
%
ksi
Hardness,
Rockwell C
1100
0
2
4
8
93
132
136
142
45
82
86
90
44
36
34
33
82B
17
20
22
1100
0
2
4
8
100
142
141
140
50
90
96
98
39
31
27
27
85B
24
25
26
0
2
4
8
2
4
8
111
155
155
156
141
144
149
90
122
122
123
124
123
129
27
23
21
21
24
23
22
19
31
31
31
31
31
32
Condition
Temperature,
F
1100
1000
1100
1000
Time,
hr
Thermal
Treatment
Tensile Properties
These data are offered as a guide to short-time aging treatments and are
not suitable for specification purposes.
1100
1000
1100
1000
Time,
hr
Tensile Properties
Yield
Tensile Strength ElonStrength,
(0.2% gation,
ksi
offset),
%
ksi
Hardness,
Rockwell C
0
2
4
8
2
4
8
125
163
163
163
169
170
174
115
140
142
141
143
143
148
14
18
18
18
17
18
18
23
34
33
33
34
34
35
0
2
4
8
2
4
8
143
175
176
174
182
183
184
136
159
159
156
165
164
167
5
14
14
14
11
14
13
27
37
36
36
37
37
38
0
2
4
8
2
4
8
148
179
181
177
187
189
189
141
166
165
161
173
174
174
4
12
12
13
10
13
11
29
38
38
38
39
39
39
17
Hot-Rolled
1080F/16 hr
1080F/16 hr
1080F/16 hr
1080F/16 hr
1080F/16 hr
1080F/16 hr
+
+
+
+
+
800F/1 month
800F/2 months
800F/4 months
800F/8 months
800F/16 months
Tensile
Strength,
ksi
Yield Strength
(0.2% Offset),
ksi
Elongation,
%
Izod Impact,
ft-lb
Hardness,
Brinell,
(3000-kg)
97.5
147.0
161.5
165.0
162.3
164.3
163.5
40.5
92.0
109.0
112.0
109.2
113.2
112.0
44.0
28.0
26.0
25.0
25.5
23.1
24.5
83
48
26
23
24
27
25
169
270
310
307
310
308
305
Fabricating
MONEL alloy K-500 is readily fabricated by standard
commercial procedures. Recommendations are given in
Special Metals publication Fabricating on the website,
www.specialmetals.com.
Hot Forming. Proper temperature during deformation is the
most important factor in achievement of hot malleability.
Maximum recommended heating temperature for hotworking MONEL alloy K-500 is 2100F. Metal should be
charged into a hot furnace and withdrawn when uniformly
heated. Prolonged soaking at this temperature is harmful. If
a delay occurs, such that the material should be subjected to
prolonged soaking, the temperature should be reduced to or
held at 1900F until shortly before ready to work, then
brought to 2100F. When the piece is uniformly heated, it
should be withdrawn. In the event of long delay, the work
should be removed from the furnace and water-quenched.
The hot-working temperature range is 1600 to 2100F.
Heavy work is best done between 1900 and 2100F;
working below 1600F is not recommended. To produce
finer grain in forgings, the final reheat temperature should be
2000F and at least 30% reduction of area should be taken in
the last forging operation.
When hot working has been completed, or when it is
46
210
44
Cold Work
Plus Age Hardening
190
42
40
37
450
400
INCONEL alloy 718
350
300
250
Steel
Stainless
Type 304
600
INCONEL alloy
K-500
oy
MONEL all
00
Nickel 2
200
150
100
170
500
34
150
31
27
130
22
Cold Work Only
Hardness, Rockwell C
Thermal
Treatment
16
110
9
0
50
90
0
10 15 20 25 30 35 40 45 50 55 60 65 70
Cold Work, %
18
10
20
30
40
50
60
Cold Work, %
Figure 21 - Effect of cold work and age hardening on properties of
MONEL alloy K-500.
Joining
19
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