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    Termodinamica Problem

    Uploaded by

    Juandearco Juanarco
    The document describes a cyclic process involving an ideal monoatomic gas. It provides data for 3 steps: 1) Isobaric expansion where the gas doubles in volume and temperature increases from 600K to 1200K. Work done is 4988.4J and heat is 12471J. 2) Isometric cooling where temperature decreases from 1200K to 600K. Heat absorbed is -7482.6J. 3) Isothermal compression where volume reduces by half and work done is -3457.7J with heat of -3457.7J. For the full cycle, heat is 1530.7J which equals the net work of 1530.7J while internal energy and enthalpy change are zero

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    Termodinamica Problem

    Uploaded by

    Juandearco Juanarco
    12 views6 pages
    The document describes a cyclic process involving an ideal monoatomic gas. It provides data for 3 steps: 1) Isobaric expansion where the gas doubles in volume and temperature increases from 600K to 1200K. Work done is 4988.4J and heat is 12471J. 2) Isometric cooling where temperature decreases from 1200K to 600K. Heat absorbed is -7482.6J. 3) Isothermal compression where volume reduces by half and work done is -3457.7J with heat of -3457.7J. For the full cycle, heat is 1530.7J which equals the net work of 1530.7J while internal energy and enthalpy change are zero

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    ejercicios

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    The document describes a cyclic process involving an ideal monoatomic gas. It provides data for 3 steps: 1) Isobaric expansion where the gas doubles in volume and temperature increases from 600K to 1200K. Work done is 4988.4J and heat is 12471J. 2) Isometric cooling where temperature decreases from 1200K to 600K. Heat absorbed is -7482.6J. 3) Isothermal compression where volume reduces by half and work done is -3457.7J with heat of -3457.7J. For the full cycle, heat is 1530.7J which equals the net work of 1530.7J while internal energy and enthalpy change are zero

    Copyright:

    © All Rights Reserved
    Download as DOCX, PDF, TXT or read online from Scribd
    Download as docx, pdf, or txt
    12 views6 pages

    Termodinamica Problem

    Uploaded by

    Juandearco Juanarco
    The document describes a cyclic process involving an ideal monoatomic gas. It provides data for 3 steps: 1) Isobaric expansion where the gas doubles in volume and temperature increases from 600K to 1200K. Work done is 4988.4J and heat is 12471J. 2) Isometric cooling where temperature decreases from 1200K to 600K. Heat absorbed is -7482.6J. 3) Isothermal compression where volume reduces by half and work done is -3457.7J with heat of -3457.7J. For the full cycle, heat is 1530.7J which equals the net work of 1530.7J while internal energy and enthalpy change are zero

    Copyright:

    © All Rights Reserved
    Download as DOCX, PDF, TXT or read online from Scribd
    Download as docx, pdf, or txt
    of 6

    PROBLEMAS

    PROBLEMA 1
    El siguiente grfico indica el comportamiento de un mol de gas ideal monoatmico;
    determinar L, Q, U,H para cada etapa y para todo el sistema.
    P
    A

    C
    V
    DATOS
    A (P1; V1; T1); T1=600K
    B (P2; V2; T2); V2=2V1
    C (P3; V3; T3); P3= P2/2; T3< T2
    3
    ~
    CV = R
    2
    L, Q, U,H = ?
    SOLUCION
    ETAPA
    A-B
    B-C
    C-A
    Etapa A-B
    V1 V2
    = ; P=cte
    T 1 T2

    T2=

    V 2T 1
    V1

    Como V 2=2 V 1

    PROCESO
    Expansion isobrica
    Enfriamiento isomtrico
    Compresin isotrmica

    T 2=

    2 V 1T 1
    V1

    T 2 =2T 1
    T 2 =2600 K=1200 K

    Trabajo
    V2

    Lrev=P d (V )=P1 (V 2 V 1)
    V1

    Lrev=P 1V 2P1V 1=( nRT 2 )( nRT 1 )


    Lrev=nR (T 2T 1 )

    Lrev=1mol8.314

    J
    (1200600) K
    Kmol

    Lrev=4988 . 4 J

    U
    ~
    ~
    U =nCV T =nC V(T 2T 1 )

    U =1

    mol3
    J
    8.314
    ( 1200600 ) K
    2
    Kmol

    U =7482. 6 J

    Q
    U =QL
    Q=U + L

    Q=7482.6 J + 4988.4 J
    Q=12471 J

    H
    ~
    H=nC P T

    H=1

    mol5
    J
    8.314
    ( 1200600 ) K
    2
    Kmol
    H=12471 J

    Etapa B-C
    T T
    V =cte; 2 = 3
    P2 P3

    T3=

    T 2P3
    P2

    Como P3=P2 /2

    T 3=

    T 2P2 /2
    P2

    T 3 =T 2 /2
    T3=

    1200 K
    =600 K
    2

    Trabajo
    V3

    Lrev=P d (V )
    V2

    V =cte d ( V )=0
    Lrev=0 J

    ~
    ~
    U =nCV T =nC V(T 3 T 2 )

    U =1

    mol3
    J
    8.314
    ( 6001200 ) K
    2
    Kmol

    U =7482 . 6 J

    Q
    U =QL
    L=O J

    Q= U
    Q=7482. 6 J

    H
    ~
    ~
    H=nC P T =nC P(T 3T 2)

    H=1

    mol5
    J
    8.314
    ( 6001200 ) K
    2
    Kmol
    H=12471 J

    Etapa C-A
    V 3=V 2=2V 1

    Trabajo
    V3

    Lrev= Pd (V )
    V2

    T 1 =T 3=T =cte P=

    nRT
    V

    V1

    Lrev=
    V3

    nRT
    d ( V )
    V
    V1

    Lrev=nRT
    V3

    d (V )
    V

    Lrev=nRT 1ln

    ||

    Lrev=1mol8.314

    V1
    V3

    Lrev=3457 . 7 J

    U
    ~
    ~
    U =n CV T =nC V(T 3 T 1 )
    T =cte T =0

    U =0 J

    Q
    U =QL
    U =O J

    Q=L
    Q=3457 . 7 J

    H
    ~
    ~
    H=nC P T =nC P(T 3T 2)
    T =cte T =0
    H=0 J

    | |

    V1
    J
    600 Kln
    Kmol
    2V 1

    RESULTADOS
    ETAPA
    A-B
    B-C
    C-A

    PROCESO
    Expansin isobrica
    Enfriamiento isomtrico
    Compresin isotrmica
    CICLO

    Q (J)
    12471
    - 7482.6
    - 3457.7
    1530.7

    L(J)
    4988.4
    0
    -3457.7
    1530.7

    U(J)
    7482.6
    -7482.6
    0
    0

    H(J)
    12471
    - 12471
    0
    0

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