Saponification Kato

Saponification of Ethyl
acetate by Sodium
hydroxide in a Plug Flow
Lindsey Kato
Reactor
Shawna
Togioka
Luke Sugie
February 2, 2005
Overview
Project Objectives
Project Planning and Execution
Background and Experimental Methods
Results and Conclusions
Recommendations and Future Work
Project Objectives
1.
2.
3.
Develop reaction kinetic data for the

saponification of ethyl acetate by sodium
hydroxide.
Develop calibration curves for electric
conductivity cell, using known concentrations
of reactants and products
Calibration of pump settings on Plug Flow
Reactor (PFR).
Ran Batch Reactor and PFR and gathered
kinetic rate data
Project Planning
Roles & Responsibilities
Team Leader Lindsey Kato

Planning agenda, Assigning tasks and goals, presentation
Operations Coordinator Shawna Togioka

Knowledge of equipment, data collections and laboratory
documentation
Safety Coordinator Luke Sugie

Hazards of the Lab, chemical safety, MSDS
Group: Background data collection and analysis
Key Planning Elements

1.
2.
3.
4.
5.
6.
7.
8.
Project Plan / Time Table

Learn about the lab, equipment, safety, hazards
Calibration Tests
Batch Reactor Tests
PFR Tests
Analysis
Oral Presentation
Written Reports
Lessons Learned
Some activities take longer than expected
Experiments dont always run smoothly.
Must rethink the experimental design.

Overall Lab time was utilized and
original project plan didnt need to be

altered.
Background Information
Reaction:
Ethyl acetate+Sodium Hydroxide Sodium acetate+Ethanol
C2H5O2CCH3 + Na-OH CH3CO2Na + H3C-CH2-OH
Theory:
-rOH = -dCOH/dt = -dCEt-O-Ac/dt = k*COH*CEt-O-Ac
A second order bimolecular reaction.
Literature Value1,2:
kOH = 0.111 L/mole-sec at 25C
Irreversible reaction
Equipment
Conductivity Meter
Uses: measured
the conductivity
in the batch reactions
and PFR experiments
Preparation: calibrated at
beginning of every lab
period.
Calibration curves were constructed
with different concentrations of
reactants and products.
Equipment
Constant Water Bath
-Batch Reaction
experiments done
at 25C
-Reactants were
submerged in the
bath to reach temp.
and then put together
for the experiment.
Equipment
Plug Flow Reactor
-Packed with small
spherical balls
-Bed Void Fraction3, , of
~0.41
-Equimolar concentrations of
NaOH and Ethyl Acetate
were pumped into PFR
-Conductivity meter used to
determine the composition
of the product stream.
-Experiment finished once
reaction reached equilibrium.
Experiments
1.
2.
3.
4.
Testing was done on the PFR pumps to

determine the resonance time for each pump
at different settings.
Calibration curves were generated for the
conductivity meter for known concentrations of
reactants and products.
Batch reactions were done using equimolar
concentrations of reactants.
PFR experiments were done using equimolar
concentrations and approx. equal molar flows.
Batch Reactor Experiments

Bath was set to 25C
Reactants were measured and put in bath
separately to heat.
Combined reactants and conductivity
measurements taken at 5 and 10 second
intervals.
Batches were constantly stirred for the
duration of the experiment.
PFR Experiments
Large quantities of equimolar mixture of Ethyl

acetate and NaOH were prepared and placed at
the inlet for each pump.
The pumps were set so that the flow rates of
each of the reactants would be equal.
Conductivity Meter was connected to the PFR at
the outlet and readings were taken during the
experiment.
Experiment was finished once the conductivity
reached a steady state.
Key Equations
Batch Reactor
COH=CEt-O-Ac
Relationship:
1 = k*t + 1
COH
COHo
PFR
COH=CEt-O-Ac
Relationship:
1 * XOH = k*
COH 1- XOH
= V/vo (Space-time)
Results Conductivity Calibration

Measurements were taken with pure NaOH, 50-50%
concentration NaOH and Sodium acetate, and pure
sodium acetate.
Results Batch Reactor

The kinetic rate constant is the initial slope at
the start of the experiment.
Results Batch Reactor
Results - PFR
The flow rate of the pumps was varied to five
different settings for data collection.
Results Batch and Plug Flow Reactor
Batch Reactor showed a kinetic rate

constant of ~0.19 L/mole-sec
Tests showed the rate constant to be 2 times

higher than literary value, but was consistent
for all trials.
Plug Flow Reactor showed the kinetic rate

constant to be ~0.24L/mole-sec
The experimental value was 2.5 times higher

than the literary value.
Major Conclusions
1.
2.
3.
4.
5.
The kinetic rate constant for batch is 0.19 L/molesec

The kinetic rate constant for a PFR is 0.24 L/molesec.
The literary value was 0.111 L/mole-sec
Discrepancies in the experiment and literature could
be caused from slightly unequal concentrations,
incorrect molar flow rates, or conductivity
calibration problems.
Reaction data showed characteristics of being
second order as theory predicted.
Lessons Learned
Some activities take longer than expected
Experiments dont always run smoothly.
Must rethink the experimental design.

Overall Lab time was utilized and
original project plan didnt need to be

altered.
Future Recommendations
More careful research done early on, so
work in the lab could go more smoothly.
Run more trials on the PFR and batch to
confirm data.
Plan out your lab times carefully and set

reasonable goals and be safe.
References
1.
2.
3.
Bamford, C.H. and C.F.H. Tipper. 1970.

Comprehensive Chemical Kinetics v.10. Elsevier
Publishing Company. New York. p.169.
Batch Reactor Kinetic Analysis. Jan 15, 2005.
www.csupomona.edu/~tknguyen/che435/Notes/P5-k
inetic.pdf
Levenspiel, Octave. 1998. Engineering Flow and Heat
Exchange. Plenum Press. New York. p.128.
Questions?

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Saponification of Ethyl

Develop reaction kinetic data for the

Roles & Responsibilities

Team Leader Lindsey Kato

Operations Coordinator Shawna Togioka

Safety Coordinator Luke Sugie

Group: Background data collection and analysis

Key Planning Elements

Project Plan / Time Table

Must rethink the experimental design.

original project plan didnt need to be

Testing was done on the PFR pumps to

Batch Reactor Experiments

Large quantities of equimolar mixture of Ethyl

Results Conductivity Calibration

Results Batch Reactor

Results Batch Reactor

Results Batch and Plug Flow Reactor

Batch Reactor showed a kinetic rate

Tests showed the rate constant to be 2 times

Plug Flow Reactor showed the kinetic rate

The experimental value was 2.5 times higher

The kinetic rate constant for batch is 0.19 L/molesec

Must rethink the experimental design.

original project plan didnt need to be

Plan out your lab times carefully and set

Bamford, C.H. and C.F.H. Tipper. 1970.

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