sf6 Leakage 1998 560 0008 1
sf6 Leakage 1998 560 0008 1
sf6 Leakage 1998 560 0008 1
Ref : 1998-560-0008
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UNIPEDE
GUIDE TO THE SAFE USE OF SF6
IN GAS INSULATED ELECTRICAL EQUIPMENT
FOREWORD
The UNIPEDE Standardisation Specific Committee formed a group of experts (230.9
NORM SF6) in order to follow up standardisation issues with regard to SF6. One of
the objectives of the group was to prepare a guide to the safe use of SF6 in gas
insulated electrical equipment.
This UNIPEDE Guide sets down an assessment of potential hazards and recommends
appropriate safeguards and methods of work to ensure the safety of employees, public
and the environment.
REVISION
Any comments on this UNIPEDE Guide should be forwarded to the UNIPEDE
secretariat
0.
INTRODUCTION ................................................................................................... 1
1.
SCOPE .................................................................................................................... 1
2.
DEFINITIONS ........................................................................................................ 2
3.
4.
5.
6.
7.
8.
9.
10.
11.
INTRODUCTION
Sulphur Hexafluoride (SF6) is a gas that has been used in electrical switchgear and
controlgear for more than 30 years. Its application is mainly in equipment for rated
voltages exceeding 1 kV up to the highest rated voltages for which switchgear and
controlgear are manufactured. It is estimated that several millions of the different types
of SF6 -filled units are currently in service.
The main features of SF6 which determine its suitability for use in electrical equipment
are :
-
The long experience with SF6 in electrical switchgear and controlgear has
demonstrated that there are no major problems concerning its use, provided that
certain elementary precautions and procedures are established and observed.
A number of international and national standards and codes of practice exist, covering
various aspects of SF6 gas. Additionally, many articles and technical papers on SF6 and
its use have been written. Very few injuries with any permanent consequences have
been reported.
SF6 is used in closed or sealed pressure systems. The small quantity of SF6 which may
leak into the atmosphere does not deplete the ozone layer and currently has a
negligible influence on global warming. However, in order to ensure that its
contribution remains negligible, it is recommended to avoid any unnecessary release of
SF6 into the atmosphere, since this gas is man-made and has a long lifetime.
The by-products of SF6 created in switchgear and controlgear by thermal effects
(heating, arcing, spark, discharge, etc.) may have toxic properties. However, the real
toxicity depends on the concentration in the switchgear and controlgear room and the
exposure time. Taking these factors into consideration it is shown that the presence of
SF6 does not impose a greater risk to the operator under normal (operating) or
abnormal (internal fault, fire) conditions than the other materials used in any other type
of switchgear and controlgear (metals, plastics, etc.), provided the procedures in this
document are followed.
1
SCOPE
This Guide is applicable to fully enclosed medium and high voltage electrical
equipment which is designed to be filled with SF6 : i.e. SF6-filled electrical equipment.
This Guide specifies the precautions to be observed to avoid pollution of the
environment by correct maintenance and operation of SF6-filled electrical equipment
and give guidance on safety precautions to be taken when handling SF6 or disposing of
SF6 by-product contaminated waste.
DEFINITIONS
There are many different types of switchgear and controlgear which use SF6 gas as a
dielectric and/or arc-quenching medium. For the purpose of this Guide, the following
definitions apply :
2.1
Sealed pressure system
For a sealed pressure system, the SF6 gas is in "sealed-for-life" enclosures, which are
never opened during the service life of the equipment.
2.2
Closed pressure system
A closed pressure system, is one in which replenishment of losses due to leakage may
be necessary and periodic maintenance involving removal and replacement of the gas is
possible.
2.3
New SF6
SF6 which complies with the requirements for purity stated in IEC 60376 [3].
2.4
Used SF6
SF6 which may have been contaminated by impurities or which has been subjected to
operating conditions after energisation of the switchgear and controlgear.
Used SF6 may contain small quantities of decomposition products, but some of them
may have toxic effects. Certain precautions are therefore required when handling used
SF6.
2.5
Enclosed equipment
Equipment using mainly air as the primary insulating medium. The SF6 is contained in
switching enclosures made from metal or cast resin. SF6-filled medium-voltage circuitbreaker and load-break switch equipment is frequently of this type of construction.
2.6
Gas-Insulated Switchgear (GIS)
High voltage equipment using mainly SF6 as the primary insulating medium.
Compartments within a gas-insulated assembly, containing various functional modules
(circuit-breakers, switches, busbars), may be physically isolated from each other, such
that each can be regarded as a separate gas enclosure.
2.7
SF6-lnsulated cubicles
Medium-voltage Ring Main Units (RMU) where busbars and switching devices are
contained into the same SF6 insulating enclosure.
2.8
Handling
Any process which might involve contact of workers with new or used SF6.
This includes removing the gas from an item of switchgear or controlgear either
completely or as a sample to be tested, opening a gas-filled enclosure, cleaning out an
open enclosure and working inside large enclosures.
2.9
Leakage
Leakage from equipment in service is the unplanned, usually continuous, emission of
gas from a sealed or closed system. Leakage occurs at seals and joints and by
molecular diffusion through certain enclosure materials. Leakage does not include
2
releases of gas due to intervention with the systems intended to contain it.
2.10 Rated voltage
Medium voltage : Rated voltages from 1 kV up to and including 52 kV.
High voltage : Rated voltages above 52 kV.
This distinction is made because there are often significant differences in design,
construction and size between the two categories.
2.11 Global Warming
The average global temperature of the earth results from a balance between the heating
effects of solar radiation and the cooling associated with infra-red radiation from the
earth. Some of the infra-red radiation is reflected back to the surface of the earth and
therefore does not escape from the atmosphere which induces a relative increasing of
the earth's temperature.
2.12 Radiative forcing
Radiative forcing quantifies the net change in the infra-red heat flux and the associated
global warming. SF6 absorbs infra-red radiation. Therefore SF6 contributes to radiative
forcing but its concentration in the atmosphere compared with CO2 is
negligible.[8][11]
The first point of identification of SF6 should be the manufacturers name-plate. When
equipment containing a large amount of SF6 is installed, such as G.I.S., in a building,
suitable information should be displayed inside the building near to the access point.
Reference [11] gives guidance on a suitable notice. IEC 60480 [4] gives guidance to
identify SF6 and its by-products.
Clean, new SF6 gas has no colour, smell or taste. It is non-combustible, non toxic and
is chemically inert at room temperatures.
Precautions for working safely with SF6 are required for the following reasons:
a) SF6 gas is about five times heavier than air and will, if released into the
atmosphere in a sufficient quantity, tend to accumulate initially in low-lying
areas where there is no natural ventilation and may cause asphyxiation.
b) SF6 decomposes at high temperatures. Decomposition may occur if the gas
is heated, for example, by fire external to the equipment and will occur if
there is an electric arc, spark or other electrical discharge within it. Some
of the decomposition products may have toxic effects, but under normal
service conditions in switchgear and controlgear these are contained within
a well-controlled and enclosed environment.
c) SF6 gas, when released into the atmosphere, has a relatively long life [11]
3
5.1
Design
SF6 insulated electrical power equipment is designed for low leakage losses in
accordance with the relevant equipment standards [1], [2], [5], [7]. Leakage is
essentially due to enclosure porosity, sealing and through associated gas pipework.
At present, a loss rate of 1% per year is specified for SF6 insulated electrical power
equipment. Preliminary data from utilities indicate that actual leakage rates in operating
equipment are often substantially lower. Apart from some early poorly designed
equipment, leakage rates below 1% are found for first generation equipment (before
about 1985). Second generation equipment leakage rates are usually below 0.5% per
year. For distribution applications, sealed-for-life equipment is being produced for
which leakage rates below 0.1 % per year are obtained. If the equipment is not sealed
for life, built in and portable monitoring devices are available to detect gas leakage.
5.2
Typical quantities of SF 6
SF6 gas in electrical equipment is normally at a pressure of 0.1MPa to 0.9MPa
absolute. The quantity varies approximately between 0.1 kilogram in one pole of a
medium voltage switching device and several hundreds of kilograms in the largest
compartment of a large high voltage GIS substation.
6.1
Effect on atmospheric environment
SF6 has been identified as a greenhouse gas having a long atmospheric lifetime. The
Kyoto Summit on Climate Change held in December 1997 included SF6 in the basket
of greenhouse gases. The present atmospheric concentration of SF6 is negligible[11].
Therefore, the release of SF6 should be minimised, especially by recycling and
avoidance of deliberate release.
6.2
Recycling
The cost of SF6 and its effect on the atmospheric environment mean that SF6 should,
wherever possible, be recycled and reused during equipment development, product
testing, commissioning, maintenance and repair and decommissioning. It should also be
recycled from equipment being phased out, into new equipment.
Successful recycling requires :
-
HANDLING OF SF6
filing of switchgear ;
maintenance operations ;
recycling of used gas ;
decommissioning of SF6-filled equipment.
SF6 could present a danger of asphyxiation due to oxygen deficiency if personnel are
working, for example, below ground in ducts or trenches. Therefore there is a need to
check for SF6 concentration before entry.
When maintenance is required, or if gas is inadvertently released into the atmosphere,
precautions are needed to ensure the safety of personnel.
The SF6 reclaiming ability of any user, will in general, be limited to detecting and treating
normal case scenarios. The technology to handle special contamination of SF6 is relatively
expensive and requires experience. The user of SF6 may find it too expensive to provide
such facilities by himself but, if so, service providers capable of processing such material
should be used.
8.1
Storage
New gas is supplied in cylinders. The new gas cylinders should not be used for storage of
used SF6 at any time. However appropriately labelled cylinders can be used for storage of
SF6. Cylinders should be specially marked to avoid the mix of used gas with new gas.
Used SF6 gas can be stored at a safe ratio of 1 kg of SF6 per 1 litre volume by the use of
suitably designed simple storage vessels.
8.2
Transportation
For transport of new SF6, local transport regulations will apply. Some countries have
introduced transport regulations for used SF6. None of the regulations currently in
existence explicitly mentions contaminated SF6, a multilateral agreement has been formed
with regard to all non-mentioned gases and gas mixtures.
The main criteria for the transport of used contaminated SF6 are the corrosive and toxic
characteristics of the contaminants and their concentrations. Proposed storage and
5
Personnel who are in the vicinity of, or approaching SF6 filled equipment or
undertaking routine maintenance including the testing of SF6 gas which generally does
not require internal access to the SF6 compartments, do not need any protective
clothing or equipment.
When routine or emergency work involves gaining acces to SF6 compartments, unless
there is an indication that SF6 decomposition products are present inside an SF6
compartment, work may proceed without the need for protective clothing and
equipment.
When routine or emergency work involves contact with SF6 decomposition products
protective clothing and equipment is necessary (see appendix A).
Maintenance involving internal access to SF6 compartments is likely to be infrequent
and some MV equipment may be removed from site for this purpose. On high voltage
equipment it is generally not practical to remove equipment from site.
9.1
Protective clothing and equip ment
Approved types of protective clothing and equipment, as detailed in Appendix A
should be available in quantities sufficient for operational and maintenance
requirements. It is not intended that every site with SF6 would be equipped but
provision should be made at selected sites, central stores or in mobile units. Operators
should be made aware of the nearest source.
After removal of SF6 gas and any decomposition products from the work area,
protective clothing and equipment should be cleaned off using disposable materials
and/or an approved vacuum cleaner. It will then be in order to remove protective
6
clothing and equipment and this may be carried out within the work area, if practicable.
The treatment of disposable items should be carried out as indicated in Section 11.
Personnel should wash all exposed parts of the body as soon as possible after leaving
the operational area.
Personnel who may be required to make use of the protective clothing and equipment,
should be familiar with its method of use as indicated in Appendices B and C of this
document and the relevant manufacturer's instructions.
Once cleaning up has taken place, then a respirator may be changed for a face mask for
practical reasons.
9.2
Hygiene
When there is any work on equipment which involves contact with SF6 or its
decomposition products, the following conditions must be observed :
-
9.3
Procedure for opening SF6 filled equipment
Prior to opening any equipment containing SF6, the gas should be removed or
evacuated as necessary. Detailed instructions for carrying out the removal of SF6 gas
and subsequent opening and ventilation should be prepared as part of an individual
equipment maintenance procedure incorporating the recommendations in accordance
with this document.
This procedure will normally include the following [12] :
identification of any decomposition products ;
removal of the majority of SF6 using gas handling plant and storage system ;
removal of remaining SF6 ;
refilling of compartment with air at atmospheric pressure ;
opening of compartment and removal of adsorbing materials.
9.3.1 Equipment designed for arc interruption
Authorised personnel, or personnel working under the supervision of a suitably
authorised person and wearing protective clothing, including overalls, full face mask
canister respirator, boots and gloves, may then open the equipment. The approved
vacuum cleaner should be used where applicable to remove any decomposition
products in the equipment.
9.3.2 Equipment not designed for arc interruption
Unless there is an indication that SF6 decomposition products are present inside an SF6
compartment, work may proceed without the need for protective clothing and
equipment.
10
Although very unlikely, abnormal releases of SF6 can occur for following reasons:
abnormal leakage ;
internal fault leading to pressure relief or burn-through of enclosure ;
external fire causing damage to enclosure.
If polluted parts of equipment are not treated on site, they should then be wrapped and
sealed in polythene, labelled and transported to a suitable location for removal of gas
and any decomposition products.
10.3 External fire
SF6 gas can be released through :
-
As SF6 is non-flammable it cannot feed the fire and indeed could have an extinguishing
effect. After release, SF6 would be rapidly dissipated by convection and should
therefore not be exposed to direct heat for long enough for further significant
8
11
Before disposal of disposable overalls, cleaning materials, filters and filter materials,
they should be treated in the following manner :
(a). Dissolve 0.5 kg of ordinary washing soda in 45 litres of water in a suitable
container such as a dustbin, ensuring that all crystals are completely
dissolved.
(b). Place the materials into the solution.
(c). Stir thoroughly and leave for 24 hours.
(d). Pour the bulk of the liquid down the drain and allow running water to flow
over the materials in the container for two hours, stirring occasionally.
(e). After emptying out the water the solid material can be safely disposed of in
the normal manner.
Under no circumstances should untreated filter or cleaning material be heated or burnt.
The waste water may be run into the foul drain or cesspool in the normal manner,
provided it is washed down with at least an equal quantity of water.
Other methods may be also used (cf IEC 61234 [8]).
A2
Overalls
Disposable pocketless hooded non-permeable coveralls having elastic wrist grips.
A3
Gloves
Lightweight neoprene gauntlet type.
A4
Rubber Boots
Boots as normal issue to staff.
A5
Head Protection
Safety helmets as normal issue to staff.
A6
Eyewash Bottles
Portable unit containing saline solution.
A7
A8
Cleaning Materials
Disposable wiping cloths.
A9
SF6 Gas handling plant
Includes a portable vacuum pump with a disposable filter.
A10 Vacuum Cleaner
Vacuum cleaner with high efficiency exhaust filter and disposable bag, complying with
IEC 61634 [8].
A11 Oxygen Detector
Portable unit with visual and audible warning.
10
APPENDIX B :
B1
Respirator
Guidance regarding the assembly and fitting of the respirator should be obtained from
the manufacturer's instructions supplied with the equipment. It is important to realise
that the respirator mask must achieve a good face seal to be effective and this may be
prevented by the presence of a beard or facial hair.
The respirator and canister will filter out toxic gas and dust but it is not suitable when
the atmosphere is deficient in oxygen. If there is any doubt, then an oxygen deficiency
meter must be used to establish if a hazard exists.
The respirator must be worn in addition to the protective clothing when equipment is
being opened for maintenance or following an emergency when personnel may come
into contact with the gas or associated decomposition products. This also applies to
the changing of gas filters on circuit breakers or gas servicing equipment generally.
The respirator canister should be changed after a period of 30 minutes use when the
wearer is exposed to SF6 gas decomposition products, and whenever the respirator is
worn by another person. Cleaning of the face mask and breathing tube should be
carried out using soap and water, and they may be wiped with a mild solution of
disinfectant if required. After use, the canister should be removed and disposed of, but
a new one should not be fitted until required, taking care that the shelf life has not
expired.
When carrying out maintenance which involves opening the SF6 filled equipment, all
preliminary work which does not require the use of the respirator including removal of
the gas and preparation for opening should be completed before the respirator is worn.
This will enable the best use to be made of the canister exposure duration, which is 30
minutes.
B2
Protective clothing
The approved disposable overalls have elasticated wrists and ankle fastenings and are
fitted with hoods. The overalls are one size and can be worn over the normal overalls.
The disposable overalls, due to the restricted breathing of the material, retain body heat
and this should be borne in mind when dressing.
Normal clothing removed should be stored away from contamination in the washing
and changing area designated for use during SF6 working.
The disposable overalls should be worn with the elasticated wrists and ankles over the
gloves and boots to prevent any dust entering at these points. The hood should be
fitted after the respirator has been donned. A safety helmet can be worn over the hood
where necessary.
On completion of work involving use of the protective clothing, including the full face
11
mask respirator, personnel should clean themselves with disposable cleaning materials
before removing the respirator. The overalls should be removed before the boots and
gloves and dealt with according to Section 11 of this document, followed by the boots
and gloves.
Personnel should wash their hands and face thoroughly before dressing in their normal
clothes.
12
Situations
Normal service
(without handling
gas)
Filling up unused
gas
Maintenance
operations
(with handling used
gas)
Risks
NIL
Precautions
NIL
Body protections
NIL
leakage of unused
gas
leakage of used gas
Measure A
NIL
Measure B
Internal fault
External fire
heavy leakage of
polluted gas
Measure C
- Respirator
- Overall
- Gloves
- Boots
- Head protection
- Respirator
- Overall
- Gloves
- Boots
- Head protection
Measure A :
efficiently ventilate the room,
do not operate alone.
Measure B :
do not operate alone,
ensure availability of protective clothing and equipment in the vicinity.
If acid odour occurs:
- warn the control engineer,
- ventilate the room,
- and if it is required to enter the room, wear protective clothing and
equipment.
Measure C :
warn firemen of the presence of SF6 ,
warn the control engineer,
ventilate the room,
and if it is required to enter the room, wear protective clothing and equipment.
13
[2] :
IEC 60298: 1990, A.C. metal-enclosed switchgear and controlgear for rated
voltages above 1 kV and up to and including 52 kV
[3] :
[4] :
IEC 60480: 1974, Guide to the checking of sulphur Hexafluoride (SF6) taken
from electrical equipment
[5] :
[6] :
IEC 60694 : 1980, Common clauses for high voltage switchgear and
controlgear standards.
[7] :
[8] :
IEC 61634 : 1995, Technical Report-High voltage switchgear and controlgearUse and handling of sulphur Hexafluoride(SF6) in high voltage switchgear and
controlgear.
[9] :
Electra n136 June 1991 : Handling of SF6 and its decomposition products in a
gas insulated switchgear, part 1.
[10] : Electra n137 August 1991 : Handling of SF6 and its decomposition products
in a gas insulated switchgear, part 2.
[11] : Electra n164 February 1996 : SF6 and the global atmosphere.
[12] : Electra n173 August 1997 : SF6 recycling guide : Re-use of SF6 in electrical
power equipment and final disposal.
14