AspenTech Physical Prop MethodsV7 - 1-Ref

Aspen Physical
Property System
Physical Property
Methods

Version Number: V7.1
January 2009
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Contents 1
Contents
1 Overview of Aspen Physical Property Methods.....................................................5
Thermodynamic Property Methods.................................................................... 6
Equation-of-State Method...................................................................... 7
Activity Coefficient Method....................................................................12
Equation-of-State Models .....................................................................23
Activity Coefficient Models ....................................................................30
Transport Property Methods............................................................................32
Viscosity and Thermal Conductivity Methods ...........................................32
Diffusion Coefficient Methods ................................................................33
Surface Tension Methods......................................................................34
Nonconventional Component Enthalpy Calculation..............................................34
References for Overview of Aspen Physical Property Methods ..............................36
2 Property Method Descriptions ............................................................................40
Classification of Property Methods and Recommended Use ..................................40
IDEAL Property Method..................................................................................45
REFPROP (NIST Reference Fluid Thermodynamic and Transport Properties Database)47
Property Methods for Petroleum Mixtures..........................................................54
Liquid Fugacity and K-Value Model Property Methods................................55
BK10.................................................................................................55
CHAO-SEA .........................................................................................56
GRAYSON/ GRAYSON2.........................................................................57
MXBONNEL.........................................................................................58
Petroleum-Tuned Equation-of-State Property Methods ..............................59
PENG-ROB .........................................................................................59
RK-SOAVE..........................................................................................61
SRK...................................................................................................62
SRK-KD .............................................................................................63
SRK-ML .............................................................................................64
Common Models .................................................................................64
Equation-of-State Property Methods for High-Pressure Hydrocarbon Applications....65
BWR-LS.............................................................................................66
BWRS................................................................................................67
LK-PLOCK ..........................................................................................69
PR-BM...............................................................................................70
RKS-BM.............................................................................................71
Common Models .................................................................................72
Flexible and Predictive Equation-of-State Property Methods.................................72
PC-SAFT: Copolymer PC-SAFT EOS Property Method ..........................................74
Option Codes for PC-SAFT ....................................................................76
Sample Calculation Results for Copolymer PC-SAFT..................................76
PRMHV2.............................................................................................81
2 Contents
PRWS................................................................................................82
PSRK.................................................................................................83
RK-ASPEN..........................................................................................83
RKSMHV2...........................................................................................84
RKSWS..............................................................................................85
SR-POLAR..........................................................................................86
Common Models .................................................................................87
Liquid Activity Coefficient Property Methods ......................................................88
Equations of State...............................................................................89
Activity Coefficient Models ....................................................................94
Common Models ...............................................................................103
Electrolyte Property Methods ........................................................................104
AMINES ...........................................................................................105
APISOUR..........................................................................................107
ELECNRTL ........................................................................................108
ENRTL-HF ........................................................................................ 110
ENRTL-HG........................................................................................ 110
ENRTL-RK ........................................................................................111
PITZER ............................................................................................111
B-PITZER.........................................................................................113
PITZ-HG ..........................................................................................114
OLI Property Method..........................................................................115
General and Transport Property Model Parameter Requirements .............. 116
Solids Handling Property Method ................................................................... 117
Steam Tables .............................................................................................120
STEAM-TA........................................................................................121
STEAMNBS/STEAMNBS2.....................................................................121
3 Property Calculation Methods and Routes ........................................................122
Introduction ...............................................................................................122
Physical Properties in the Aspen Physical Property System................................ 123
Major Properties in the Aspen Physical Property System.......................... 124
Subordinate Properties in the Aspen Physical Property System................. 126
Intermediate Properties in the Aspen Physical Property System................ 128
Methods ....................................................................................................128
Example: Methods for calculating liquid mixture enthalpy........................ 130
Vapor Fugacity Coefficient Methods...................................................... 130
Liquid Fugacity Coefficient Methods...................................................... 131
Solid Fugacity Coefficient Methods ....................................................... 134
Vapor Enthalpy Methods.....................................................................135
Liquid Enthalpy Methods..................................................................... 136
Solid Enthalpy Methods ......................................................................140
Vapor Gibbs Energy Methods ..............................................................140
Liquid Gibbs Energy Methods ..............................................................141
Solid Gibbs Energy Methods................................................................143
Vapor Entropy Methods ......................................................................144
Liquid Entropy Methods......................................................................145
Solid Entropy Methods .......................................................................146
Molar Volume Methods.......................................................................147
Viscosity Methods..............................................................................148
Thermal Conductivity Methods ............................................................149
Diffusion Coefficient Methods ..............................................................151
Contents 3
Surface Tension Methods....................................................................151
Routes And Models......................................................................................151
Concept of Routes ............................................................................. 152
Models.............................................................................................154
Tracing a Route.................................................................................159
Modifying and Creating Property Methods .......................................................161
Modifying Existing Property Methods .................................................... 161
Creating New Property Methods...........................................................164
Modifying and Creating Routes...................................................................... 166
Example 1: Use a second data set of NRTL parameters........................... 167
Example 2: Using your own model for the liquid enthalpy........................ 167
4 Electrolyte Calculation......................................................................................169
Solution Chemistry......................................................................................169
Apparent Component and True Component Approaches .......................... 171
Aqueous Electrolyte Chemical Equilibrium.............................................175
Electrolyte Thermodynamic Models ...................................................... 177
Electrolyte Data Regression ................................................................179
5 Free-Water and Rigorous Three-Phase Calculations.........................................181
Free-Water and Dirty-Water Immiscibility Simplification.................................... 182
Specifying Free-Water or Dirty-Water Calculations ................................. 183
Rigorous Three-Phase Calculations....................................................... 185
6 Petroleum Components Characterization Methods ...........................................187
AspenTech Extensions to Characterization Methods for Petroleum Fractions......... 189
Comparison of Extended Molecular Weight Methods ............................... 191
Comparison of Extended Critical Temperature Methods........................... 191
Comparison of Extended Critical Pressure Methods................................. 192
Comparison of Extended Critical Volume Methods .................................. 193
Comparison of Extended Acentric Factor Methods...................................193
User Models for Characterization of Petroleum Fractions ................................... 194
Property Methods for Characterization of Petroleum Fractions............................ 194
Property Method ASPEN: Aspen Tech and API procedures........................ 195
Property Method API-METH: API Procedures.......................................... 196
Property Method COAL-LIQ: for Coal Liquids.......................................... 196
Property Method LK: Lee-Kesler .......................................................... 197
Property Method API-TWU: AspenTech, API, and Twu............................. 197
Property Method EXT-TWU: Twu and AspenTech Extensions .................... 198
Property Method EXT-API: API, Twu, and AspenTech Extensions .............. 198
Property Method EXT-CAV: Cavett, API, and AspenTech Extensions .......... 199
Water Solubility in Petroleum Fractions ..........................................................199
Estimation of NRTL and UNIQUAC Binary Parameters for Water and Petroleum
Fractions....................................................................................................199
Estimation of ATOMNO and NOATOM for Petroleum Fractions............................. 200
Estimation of Flash Point ..............................................................................200
Petroleum Method References.......................................................................201
7 Property Parameter Estimation........................................................................203
Parameters Estimated by the Aspen Physical Property System........................... 203
Description of Estimation Methods .......................................................205
4 Contents
Index ..................................................................................................................228

1 Overview of Aspen Physical Property Methods 5
1 Overview of Aspen Physical
Property Methods
All unit operation models need property calculations to generate results. The
most often requested properties are fugacities for thermodynamic equilibrium
(flash calculation). Enthalpy calculations are also often requested. Fugacities
and enthalpies are often sufficient information to calculate a mass and heat
balance. However, other thermodynamic properties (and, if requested,
transport properties) are calculated for all process streams.
The impact of property calculation on the calculation result is great. This is
due to the quality and the choice of the equilibrium and property calculations.
Equilibrium calculation and the bases of property calculation are explained in
this chapter. The understanding of these bases is important to choose the
appropriate property calculation. Property Method Descriptions gives more
help on this subject. The quality of the property calculation is determined by
the model equations themselves and by the usage. For optimal usage, you
may need details on property calculation. These are given in Physical
Calculation Methods and Routes and Physical Property Models.
This chapter contains three sections:
Thermodynamic property methods
Transport property methods
Nonconventional component enthalpy calculation
The thermodynamic property methods section discusses the two methods of
calculating vapor-liquid equilibrium (VLE): the equation-of-state method and
the activity coefficient method. Each method contains the following:
Fundamental concepts of phase equilibria and the equations used
Application to vapor-liquid equilibria and other types of equilibria, such as
liquid-liquid
Calculations of other thermodynamic properties
The last part of this section gives an overview of the current equation of state
and activity coefficient technology.
See the table labeled Symbol Definitions in the section Nonconventional
Component Enthalpy Calculation for definitions of the symbols used in
equations.

6 1 Overview of Aspen Physical Property Methods
Thermodynamic Property
Methods
The key thermodynamic property calculation performed in a calculation is
phase equilibrium. The basic relationship for every component i in the vapor
and liquid phases of a system at equilibrium is:
f
i
v
= f
i
l
(1)
Where:
f
i
v
= Fugacity of component i in the vapor phase
f
i
l
= Fugacity of component i in the liquid phase
Applied thermodynamics provides two methods for representing the fugacities
from the phase equilibrium relationship in terms of measurable state
variables, the equation-of-state method and the activity coefficient method.
In the equation of state method:
f
i
v
=
i
v
y
i
p (2)
f
i
l
=
i
l
x
i
p (3)
With:

(4)
Where:

= v or l
V = Total volume
n
i
= Mole number of component i
Equations 2 and 3 are identical with the only difference being the phase to
which the variables apply. The fugacity coefficient
i
is obtained from the

equation of state, represented by p in equation 4. See equation 45 for an
example of an equation of state.
In the activity coefficient method:
f
i
v
=
i
v
y
i
p (5)
f
i
l
=
x
i
i
f
i
*,l

(6)
Where
i
v
is calculated according to equation 4,
i

= Liquid activity coefficient of component i
f
i
*,l
= Liquid fugacity of pure component i at mixture
temperature
Equation 5 is identical to equation 2. Again, the fugacity coefficient is
calculated from an equation of state. Equation 6 is totally different.
Each property method in the Aspen Physical Property System is based on
either the equation-of-state method or the activity coefficient method for
phase equilibrium calculations. The phase equilibrium method determines how
other thermodynamic properties, such as enthalpies and molar volumes, are
calculated.
With an equation-of-state method, all properties can be derived from the
equation of state, for both phases. Using an activity coefficient method, the
vapor phase properties are derived from an equation of state, exactly as in
the equation-of- state method. However the liquid properties are determined
from summation of the pure component properties to which a mixing term or
an excess term is added.

Equation-of-State Method
The partial pressure of a component i in a gas mixture is:
p
i
= y
i
p (7)
The fugacity of a component in an ideal gas mixture is equal to its partial
pressure. The fugacity in a real mixture is the effective partial pressure:
f
i
v
=
i
v
y
i
p
(8)
The correction factor
i
v
is the fugacity coefficient. For a vapor at moderate
pressures,
i
v
is close to unity. The same equation can be applied to a liquid:
f
i
l
=
i
l
y
i
p
(9)
A liquid differs from an ideal gas much more than a real gas differs from an
ideal gas. Thus fugacity coefficients for a liquid are very different from unity.
For example, the fugacity coefficient of liquid water at atmospheric pressure
and room temperature is about 0.03 (Haar et al., 1984).
An equation of state describes the pressure, volume and temperature (p,V,T)
behavior of pure components and mixtures. Usually it is explicit in pressure.
Most equations of state have different terms to represent attractive and
repulsive forces between molecules. Any thermodynamic property, such as
fugacity coefficients and enthalpies, can be calculated from the equation of
state. Equation-of-state properties are calculated relative to the ideal gas
properties of the same mixture at the same conditions. See Calculation of
Properties Using an Equation-of-State Property Method.

Vapor-Liquid Equilibria
The relationship for vapor-liquid equilibrium is obtained by substituting
equations 8 and 9 in equation 1 and dividing by p:
i
v
y
i
=
i
l
x
i

(10)
Fugacity coefficients are obtained from the equation of state (see equation 4
and Calculation of Properties Using an Equation-of-State Property Method).
The calculation is the same for supercritical and subcritical components (see
Activity Coefficient Method).
Pressure-Temperature Diagram
Fluid phase equilibria depend not only on temperature but also on pressure.
At constant temperature (and below the mixture critical temperature), a
multicomponent mixture will be in the vapor state at very low pressure and
in the liquid state at very high pressure. There is an intermediate pressure
range for which vapor and liquid phases co-exist. Coming from low pressures,
first a dew point is found. Then more and more liquid will form until the vapor
disappears at the bubble point pressure. This is illustrated in the figure
labeled Phase Envelope of a Methane-Rich Hydrocarbon Mixture. Curves of
constant vapor fraction (0.0, 0.2, 0.4, 0.6, 0.8 and 1.0) are plotted as a
function of temperature. A vapor fraction of unity corresponds to a dew-point;
a vapor fraction of zero corresponds to a bubble point. The area confined
between dew-point and bubble-point curves is the two-phase region. The
dew-point and bubble-point curves meet at high temperatures and pressures
at the critical point. The other lines of constant vapor fractions meet at the
same point. In Phase Envelope of a Methane-Rich Hydrocarbon Mixture, the
critical point is found at the pressure maximum of the phase envelope
(cricondenbar). This is not a general rule.
At the critical point the differences between vapor and liquid vanish; the mole
fractions and properties of the two phases become identical. Equation 10 can
handle this phenomenon because the same equation of state is used to
evaluate
i
v
and
i
l
. Engineering type equations of state can model the
pressure dependence of vapor-liquid equilibria very well. However, they
cannot yet model critical phenomena accurately (see Equation-of-State
Models).

Phase Envelope of a Methane-Rich Hydrocarbon Mixture
Retrograde Condensation
Compressing the methane-rich mixture shown in the figure labeled Phase
Envelope of a Methane-Rich Hydrocarbon Mixture at 270 K (above the mixture
critical temperature) will show a dew-point. Then liquid will be formed up to a
vapor fraction of about 0.75 (110 bar). Upon further compression the vapor
fraction will decrease again until a second dew-point is reached. If the process
is carried out with decreasing pressure, liquid is formed when expanding. This
is the opposite of the more usual condensation upon compression. It is called
retrograde condensation and it happens often in natural gas mixtures.

Liquid-Liquid and Liquid-Liquid-Vapor Equilibria
Liquid-liquid equilibria are less pressure dependent than vapor-liquid
equilibria, but certainly not pressure independent. The activity coefficient
method can model liquid-liquid and liquid-liquid-vapor equilibria at low
pressure as a function of temperature. However, with varying pressure the
equation of state method is needed (compare Activity Coefficient Method,
Liquid-Liquid and Liquid-Liquid-Vapor Equilibria). The equation-of-state
method (equation 10) can be applied to liquid-liquid equilibria:
i
l1
x
i
l1
=
i
l2
x
i
l2

(11)
and also to liquid-liquid-vapor equilibria:
i
v
y
i
=
i
l1
x
i
l1
=
i
l2
x
i
l2

(12)
Fugacity coefficients in all the phases are calculated using the same equation
of state. Fugacity coefficients from equations of state are a function of
composition, temperature, and pressure. Therefore, the pressure dependency
of liquid-liquid equilibria can be described.
Liquid Phase Nonideality
Liquid-liquid separation occurs in systems with very dissimilar molecules.
Either the size or the intermolecular interactions between components may be
dissimilar. Systems that demix at low pressures, have usually strongly
dissimilar intermolecular interactions, as for example in mixtures of polar and
non-polar molecules. In this case, the miscibility gap is likely to exist at high
pressures as well. An examples is the system dimethyl-ether and water (Pozo
and Street, 1984). This behavior also occurs in systems of a fully- or near
fully-fluorinated aliphatic or alicyclic fluorocarbon with the corresponding
hydrocarbon (Rowlinson and Swinton, 1982), for example cyclohexane and
perfluorocyclohexane (Dyke et al., 1959; Hicks and Young, 1971).
Systems which have similar interactions, but which are very different in size,
do demix at higher pressures. For binary systems, this happens often in the
vicinity of the critical point of the light component (Rowlinson and Swinton,
1982).
Examples are:
Methane with hexane or heptane (van der Kooi, 1981; Davenport and
Rowlinson, 1963; Kohn, 1961)
Ethane with n-alkanes with carbon numbers from 18 to 26 (Peters et al.,
1986)
Carbon dioxide with n-alkanes with carbon numbers from 7 to 20 (Fall et
al., 1985)
The more the demixing compounds differ in molecular size, the more likely it
is that the liquid-liquid and liquid-liquid-vapor equilibria will interfere with
solidification of the heavy component. For example, ethane and pentacosane
or hexacosane show this. Increasing the difference in carbon number further
causes the liquid-liquid separation to disappear. For example in mixtures of
ethane with n-alkanes with carbon numbers higher than 26, the liquid-liquid
separation becomes metastable with respect to the solid-fluid (gas or liquid)
equilibria (Peters et al., 1986). The solid cannot be handled by an equation-
of-state method.

Critical Solution Temperature
In liquid-liquid equilibria, mutual solubilities depend on temperature and
pressure. Solubilities can increase or decrease with increasing or decreasing
temperature or pressure. The trend depends on thermodynamic mixture
properties but cannot be predicted a priori. Immiscible phases can become
miscible with increasing or decreasing temperature or pressure. In that case a
liquid-liquid critical point occurs. Equations 11 and 12 can handle this
behavior, but engineering type equations of state cannot model these
phenomena accurately.

Calculation of Properties Using an Equation-of-
State Property Method
The equation of state can be related to other properties through fundamental
thermodynamic equations :
Fugacity coefficient:

(13)
Enthalpy departure:

(14)
Entropy departure:

(15)
Gibbs energy departure:

(16)
Molar volume:
Solve p(T,V
m
) for V
m
.
From a given equation of state, fugacities are calculated according to equation
13. The other thermodynamic properties of a mixture can be computed from
the departure functions:
Vapor enthalpy:

(17)
Liquid enthalpy:

(18)
The molar ideal gas enthalpy, H
m
ig
is computed by the expression:

(19)
Where:
C
p,i
ig
= Ideal gas heat capacity
f
H
i
ig

= Standard enthalpy of formation for ideal gas
at 298.15 K and 1 atm
T
ref
= Reference temperature = 298.15 K
Entropy and Gibbs energy can be computed in a similar manner:

(20)

(21)

(22)

(23)
Vapor and liquid volume is computed by solving p(T,V
m
) for V
m
or computed
by an empirical correlation.

Advantages and Disadvantages of the Equation-
of-State Method
You can use equations of state over wide ranges of temperature and
pressure, including subcritical and supercritical regions. For ideal or slightly
non-ideal systems, thermodynamic properties for both the vapor and liquid
phases can be computed with a minimum amount of component data.
Equations of state are suitable for modeling hydrocarbon systems with light
gases such as CO
2
, N
2
, and H
2
S.
For the best representation of non-ideal systems, you must obtain binary
interaction parameters from regression of experimental vapor-liquid
equilibrium (VLE) data. Equation of state binary parameters for many
component pairs are available in the Aspen Physical Property System.
The assumptions in the simpler equations of state (Redlich-Kwong-Soave,
Peng-Robinson, Lee-Kesler-Plcker) are not capable of representing highly
non-ideal chemical systems, such as alcohol-water systems. Use the activity-
coefficient options sets for these systems at low pressures. At high pressures,
use the flexible and predictive equations of state.
Equations of state generally do a poor job at predicting liquid density. To
compensate for this, PENG-ROB, LK-PLOCK, RK-SOAVE, and the methods
based on these calculate liquid density using the API correlation for
pseudocomponents and the Rackett model for real components, rather than
using the liquid density predicted by the equation of state. This is more
accurate, but using causes a minor inconsistency which is mainly apparent for
supercritical fluids, where the vapor and liquid properties should be the same,
but the density will not be. All other equation-of-state methods use the
equation of state to calculate liquid density, except that SRK and some of the
methods based on it correct this density with a volume translation term based
on the Peneloux-Rauzy method.

Activity Coefficient Method
In an ideal liquid solution, the liquid fugacity of each component in the
mixture is directly proportional to the mole fraction of the component.
f
i
l
= x
i
f
i
*,l
(24)
The ideal solution assumes that all molecules in the liquid solution are
identical in size and are randomly distributed. This assumption is valid for
mixtures containing molecules of similar size and character. An example is a
mixture of pentane (n-pentane) and 2,2-dimethylpropane (neopentane)
(Gmehling et al., 1980, pp. 95-99). For this mixture, the molecules are of
similar size and the intermolecular interactions between different component
molecules are small (as for all nonpolar systems). Ideality can also exist
between polar molecules, if the interactions cancel out. An example is the
system water and 1,2-ethanediol (ethylene glycol) at 363 K (Gmehling et al.,
1988, p. 124).
In general, you can expect non-ideality in mixtures of unlike molecules. Either
the size and shape or the intermolecular interactions between components
may be dissimilar. For short these are called size and energy asymmetry.
Energy asymmetry occurs between polar and non-polar molecules and also
between different polar molecules. An example is a mixture of alcohol and
water.
The activity coefficient
i
represents the deviation of the mixture from ideality
(as defined by the ideal solution):
f
i
l
= x
i
i
f
i
*,l

(25)
The greater
i
deviates from unity, the more non-ideal the mixture. For a pure
component x
i
= 1 and
i
= 1, so by this definition a pure component is ideal. A
mixture that behaves as the sum of its pure components is also defined as
ideal (compare equation 24). This definition of ideality, relative to the pure
liquid, is totally different from the definition of the ideality of an ideal gas,
which has an absolute meaning (see Equation-of-State Method). These forms
of ideality can be used next to each other.
In the majority of mixtures,
i
is greater than unity. The result is a higher
fugacity than ideal (compare equation 25 to equation 24). The fugacity can be
interpreted as the tendency to vaporize. If compounds vaporize more than in
an ideal solution, then they increase their average distance. So activity
coefficients greater than unity indicate repulsion between unlike molecules. If
the repulsion is strong, liquid-liquid separation occurs. This is another
mechanism that decreases close contact between unlike molecules.
It is less common that
i
is smaller than unity. Using the same reasoning, this
can be interpreted as strong attraction between unlike molecules. In this
case, liquid-liquid separation does not occur. Instead formation of complexes
is possible.

Vapor-Liquid Equilibria
In the activity coefficient approach, the basic vapor-liquid equilibrium
relationship is represented by:
i
v
y
i
p = x
i
i
f
i
*,l

(26)
The vapor phase fugacity coefficient
i
v
is computed from an equation of state
(see Equation-of-State Method). The liquid activity coefficient
i
is computed
from an activity coefficient model.
For an ideal gas,
i
v
= 1. For an ideal liquid,
i
= 1. Combining this with
equation 26 gives Raoult's law:
y
i
p = x
i
p
i
*,l
(27)
At low to moderate pressures, the main difference between equations 26 and
27 is due to the activity coefficient. If the activity coefficient is larger than
unity, the system is said to show positive deviations from Raoults law.
Negative deviations from Raoult's law occur when the activity coefficient is
smaller than unity.
Liquid Phase Reference Fugacity
The liquid phase reference fugacity f
i
*,l
from equation 26 can be computed in
three ways:
For solvents: The reference state for a solvent is defined as pure component
in the liquid state, at the temperature and pressure of the system. By this
definition
i
approaches unity as x
i
approaches unity.
i
*,l
is computed as:
f
i
*,l
=
i
*,v
(T, p
i
*,l
) p
i
*,l
i
*,l

(28)
Where:
i
*,v

= Fugacity coefficient of pure component i at the
system temperature and vapor pressures, as
calculated from the vapor phase equation of
state
p
i
*,l
= Liquid vapor pressures of component i at the
system temperature
i
*,l

= Poynting correction for pressure
=

At low pressures, the Poynting correction is near unity, and can be ignored.
For dissolved gases: Light gases (such as O
2
and N
2
) are usually
supercritical at the temperature and pressure of the solution. In that case
pure component vapor pressure is meaningless and therefore it cannot serve
as the reference fugacity. The reference state for a dissolved gas is redefined
to be at infinite dilution and at the temperature and pressure of the mixtures.
i
*,l
becomes H
i
(the Henry's constant for
component i in the mixture).
The activity coefficient
i
is converted to the infinite dilution reference state
through the relationship:

(29)
Where:

= The infinite dilution activity coefficient of
component i in the mixture
By this definition
*
approaches unity as x
i
approaches zero. The phase
equilibrium relationship for dissolved gases becomes:
i
v
y
i
p = x
i
i
*H
i

(30)
To compute H
i
, you must supply the Henry's constant for the dissolved-gas
component i in each subcritical solvent component.
Using an Empirical Correlation: The reference state fugacity is calculated
using an empirical correlation. Examples are the Chao-Seader or the Grayson-
Streed model.
Electrolyte and Multicomponent VLE
The vapor-liquid equilibrium equations 26 and 30, only apply for components
which occur in both phases. Ions are components which do not participate
directly in vapor-liquid equilibrium. This is true as well for solids which do not
dissolve or vaporize. However, ions influence activity coefficients of the other
species by interactions. As a result they participate indirectly in the vapor-
liquid equilibria. An example is the lowering of the vapor pressure of a
solution upon addition of an electrolyte. For more on electrolyte activity
coefficient models, see Activity Coefficient Models.
Multicomponent vapor-liquid equilibria are calculated from binary parameters.
These parameters are usually fitted to binary phase equilibrium data (and not
multicomponent data) and represent therefore binary information. The
prediction of multicomponent phase behavior from binary information is
generally good.

Liquid-Liquid and Liquid-Liquid-Vapor Equilibria
The basic liquid-liquid-vapor equilibrium relationship is:

(31)
Equation 31 can be derived from the liquid-vapor equilibrium relationship by
analogy. For liquid-liquid equilibria, the vapor phase term can be omitted, and
the pure component liquid fugacity cancels out:

(32)
The activity coefficients depend on temperature, and so do liquid-liquid
equilibria. However, equation 32 is independent of pressure. The activity
coefficient method is very well suited for liquid-liquid equilibria at low to
moderate pressures. Mutual solubilities do not change with pressure in this
case. For high-pressure liquid-liquid equilibria, mutual solubilities become a
function of pressure. In that case, use an equation-of-state method.
For the computation of the different terms in equations 31 and 32, see Vapor-
Liquid Equilibria.
Multi-component liquid-liquid equilibria cannot be reliably predicted from
binary interaction parameters fitted to binary data only. In general,
regression of binary parameters from multi-component data will be
necessary. See the User Guide for details.
The ability of activity coefficient models in describing experimental liquid-
liquid equilibria differs. The Wilson model cannot describe liquid-liquid
separation at all; UNIQUAC, UNIFAC and NRTL are suitable. For details, see
Activity Coefficient Models. Activity coefficient models sometimes show
anomalous behavior in the metastable and unstable composition region.
Phase equilibrium calculation using the equality of fugacities of all
components in all phases (as in equations 31 and 32), can lead to unstable
solutions. Instead, phase equilibrium calculation using the minimization of
Gibbs energy always yields stable solutions.
The figure labeled (T,x,x,y)Diagram of Water and Butanol-1 at 1.01325 bar,
a graphical Gibbs energy minimization of the system n-butanol + water,
shows this.

(T,x,x,y)Diagram of Water and Butanol-1 at 1.01325 bar
The phase diagram of n-butanol + water at 1 bar is shown in this figure.
There is liquid-liquid separation below 367 K and there are vapor-liquid
equilibria above this temperature. The diagram is calculated using the UNIFAC
activity coefficient model with the liquid-liquid data set.
The Gibbs energies of vapor and liquid phases at 1 bar and 365 K are given
in the figure labeled Molar Gibbs Energy of Butanol-1 and Water at 365 K and
1 atm. This corresponds to a section of the phase diagram at 365 K. The
Gibbs energy of the vapor phase is higher than that of the liquid phase at any
mole fraction. This means that the vapor is unstable with respect to the liquid
at these conditions. The minimum Gibbs energy of the system as a function of
the mole fraction can be found graphically by stretching an imaginary string
from below around the Gibbs curves. For the case of the figure labeled Molar
Gibbs Energy of Butanol-1 and Water at 365 K and 1 atm, the string never
touches the vapor Gibbs energy curve. For the liquid the situation is more
subtle: the string touches the curve at the extremities but not at mole
fractions between 0.56 and 0.97. In that range the string forms a double
tangent to the curve. A hypothetical liquid mixture with mole fraction of 0.8
has a higher Gibbs energy and is unstable with respect to two liquid phases
with mole fractions corresponding to the points where the tangent and the
curve touch. The overall Gibbs energy of these two phases is a linear
combination of their individual Gibbs energies and is found on the tangent (on
the string). The mole fractions of the two liquid phases found by graphical
Gibbs energy minimization are also indicated in the figure labeled (T,x,x,y)
Diagram of Water and Butanol-1 at 1.01325 bar.

The Gibbs energy has been transformed by a contribution linear in the mole fraction, such that
the Gibbs energy of pure liquid water (thermodynamic potential of water) has been shifted to the
value of pure liquid n-butanol. This is done to make the Gibbs energy minimization visible on the
scale of the graph. This transformation has no influence on the result of Gibbs energy
minimization (Oonk, 1981).
Molar Gibbs Energy of Butanol-1 and Water at 365 K and 1 atm
At a temperature of 370 K, the vapor has become stable in the mole fraction
range of 0.67 to 0.90 (see the figure labeled Molar Gibbs Energy of Butanol-1
and Water at 370 K and 1 atm). Graphical Gibbs energy minimization results
in two vapor-liquid equilibria, indicated in the figure labeled Molar Gibbs
Energy of Butanol-1 and Water at 370 K and 1 atm. Ignoring the Gibbs
energy of the vapor and using a double tangent to the liquid Gibbs energy
curve a liquid-liquid equilibrium is found. This is unstable with respect to the
vapor-liquid equilibria. This unstable equilibrium will not be found with Gibbs
minimization (unless the vapor is ignored) but can easily be found with the
method of equality of fugacities.

Molar Gibbs Energy of Butanol-1 and Water at 370 K and 1 atm
The technique of Gibbs energy minimization can be used for any number of
phases and components, and gives accurate results when handled by a
computer algorithm. This technique is always used in the equilibrium reactor
unit operation model RGibbs, and can be used optionally for liquid phase
separation in the distillation model RadFrac.

Phase Equilibria Involving Solids
In most instances, solids are treated as inert with respect to phase
equilibrium (CISOLID). This is useful if the components do not dissolve or
vaporize. An example is sand in a water stream. CISOLID components are
stored in separate substreams.
There are two areas of application where phase equilibrium involving solids
may occur:
Salt precipitation in electrolyte solutions
Pyrometallurgical applications
Salt Precipitation
Electrolytes in solution often have a solid solubility limit. Solid solubilities can
be calculated if the activity coefficients of the species and the solubility
product are known (for details see Electrolyte Calculation). The activity of the
ionic species can be computed from an electrolyte activity coefficient model
(see Activity Coefficient Models). The solubility product can be computed from
the Gibbs energies of formation of the species participating in the
precipitation reaction or can be entered as the temperature function (K-SALT)
on the Reactions Chemistry Equilibrium Constants sheet.
Salt precipitation is only calculated when the component is declared as a Salt
on the Reactions Chemistry Stoichiometry sheet. The salt components are
part of the MIXED substream, because they participate in phase equilibrium.
The types of equilibria are liquid-solid or vapor-liquid-solid. Each precipitating
salt is treated as a separate, pure component, solid phase.
Solid compounds, which are composed of stoichiometric amounts of other
components, are treated as pure components. Examples are salts with crystal
water, like CaSO
4
, H
2
O.
Phase Equilibria Involving Solids for Metallurgical
Applications
Mineral and metallic solids can undergo phase equilibria in a similar way as
organic liquids. Typical pyrometallurgical applications have specific
characteristics:
Simultaneous occurrence of multiple solid and liquid phases
Occurrence of simultaneous phase and chemical equilibria
Occurrence of mixed crystals or solid solutions
These specific characteristics are incompatible with the chemical and phase
equilibrium calculations by flash algorithms as used for chemical and
petrochemical applications. Instead, these equilibria can be calculated by
using Gibbs energy minimization techniques. In Aspen Plus, the unit operation
model RGibbs is specially designed for this purpose.
Gibbs energy minimization techniques are equivalent to phase equilibrium
computations based on equality of fugacities. If the distribution of the
components of a system is found, such that the Gibbs energy is minimal,
equilibrium is obtained. (Compare the discussion of phase equilibrium
calculation using Gibbs energy minimization in Liquid-Liquid and Liquid-
Liquid-Vapor Equilibria)
As a result, the analog of equation 31 holds:

(33)
This equation can be simplified for pure component solids and liquids, or be
extended for any number of phases.
For example, the pure component vapor pressure (or sublimation) curve can
be calculated from the pure component Gibbs energies of vapor and liquid (or
solid). The figure labeled Thermodynamic Potential of Mercury at 1, 5, 10, and
20 bar shows the pure component molar Gibbs energy or thermodynamic
potential of liquid and vapor mercury as a function of temperature and at four
different pressures: 1,5,10 and 20 bar. The thermodynamic potential of the
liquid is not dependent on temperature and independent of pressure: the four
curves coincide. The vapor thermodynamic potential is clearly different at
each pressure. The intersection point of the liquid and vapor thermodynamic
potentials at 1 bar is at about 630 K. At this point the thermodynamic
potentials of the two phases are equal, so there is equilibrium. A point of the
vapor pressure curve is found. Below this temperature the liquid has the
lower thermodynamic potential and is the stable phase; above this
temperature the vapor has the lower thermodynamic potential. Repeating the
procedure for all four pressures gives the four points indicated on the vapor
pressure curve (see the figure labeled Vapor Pressure Curve of Liquid
Mercury). This is a similar result as a direct calculation with the Antoine
equation. The procedure can be repeated for a large number of pressures to
construct the curve with sufficient accuracy. The sublimation curve can also
be calculated using an Antoine type model, similar to the vapor pressure
curve of a liquid.

Thermodynamic Potential of Mercury at 1, 5, 10, and 20
bar
The pure component molar Gibbs energy is equal to the pure component
thermodynamic potential. The ISO and IUPAC recommendation to use the
thermodynamic potential is followed.

Vapor Pressure Curve of Liquid Mercury
The majority of solid databank components occur in the INORGANIC
databank. In that case, pure component Gibbs energy, enthalpy and entropy
of solid, liquid or vapor are calculated by polynomials (see Physical Property
Models).
The pure component solid properties (Gibbs energy and enthalpy) together
with the liquid and vapor mixture properties are sufficient input to calculate
chemical and phase equilibria involving pure solid phases. In some cases
mixed crystals or solid solutions can occur. These are separate phases. The
concept of ideality and nonideality of solid solutions are similar to those of
liquid phases (see Vapor-Liquid Equilibria). The activity coefficient models
used to describe nonideality of the solid phase are different than those
generally used for liquid phases. However some of the models (Margules,
Redlich-Kister) can be used for liquids as well. If multiple liquid and solid
mixture phases occur simultaneously, the activity coefficient models used can
differ from phase to phase.
To be able to distinguish pure component solids from solid solutions in the
stream summary, the pure component solids are placed in the CISOLID
substream and the solid solutions in the MIXED substream.

Calculation of Other Properties Using Activity
Coefficients
Properties can be calculated for vapor, liquid or solid phases:
Vapor phase: Vapor enthalpy, entropy, Gibbs energy and density are
computed from an equation of state (see Calculation of Properties Using an
Equation-of-State Property Method).
Liquid phase: Liquid mixture enthalpy is computed as:

(34)
Where:
H
i
*,v
= Pure component vapor enthalpy at T and
vapor pressure
vap
H
i
*
= Component vaporization enthalpy
H
m
E,l
= Excess liquid enthalpy
Excess liquid enthalpy H
m
E,l
is related to the activity coefficient through the
expression:

(35)
Liquid mixture Gibbs free energy and entropy are computed as:

(36)

(37)
Where:

(38)
Liquid density is computed using an empirical correlation.
Solid phase: Solid mixture enthalpy is computed as:

(39)
Where:
H
i
*,s
= Pure component solid enthalpy at T
H
m
E,s
= The excess solid enthalpy
Excess solid enthalpy H
m
E,s
is related to the activity coefficient through the
expression:

(40)
Solid mixture Gibbs energy is computed as:

(41)
Where:

(42)
The solid mixture entropy follows from the Gibbs energy and enthalpy:

(43)

Advantages and Disadvantages of the Activity
Coefficient Method
The activity coefficient method is the best way to represent highly non-ideal
liquid mixtures at low pressures. You must estimate or obtain binary
parameters from experimental data, such as phase equilibrium data. Binary
parameters for the Wilson, NRTL, and UNIQUAC models are available in the
Aspen Physical Property System for a large number of component pairs.
These binary parameters are used automatically. See Physical Property Data,
Chapter 1, for details.
Binary parameters are valid only over the temperature and pressure ranges of
the data. Binary parameters outside the valid range should be used with
caution, especially in liquid-liquid equilibrium applications. If no parameters
are available, the predictive UNIFAC models can be used.
The activity coefficient approach should be used only at low pressures (below
10 atm). For systems containing dissolved gases at low pressures and at
small concentrations, use Henry's law. For highly non-ideal chemical systems
at high pressures, use the flexible and predictive equations of state.

Equation-of-State Models
The simplest equation of state is the ideal gas law:
p = RT / V
m
(44)
The ideal gas law assumes that molecules have no size and that there are no
intermolecular interactions. This can be called absolute ideality, in contrast to
ideality defined relative to pure component behavior, as used in the activity
coefficient approach (see Activity Coefficient Method).
There are two main types of engineering equations of state: cubic equations
of state and the virial equations of state. Steam tables are an example of
another type of equation of state.

Cubic Equations of State
In an ideal gas, molecules have no size and therefore no repulsion. To correct
the ideal gas law for repulsion, the total volume must be corrected for the
volume of the molecule(s), or covolume b. (Compare the first term of
equation 45 to equation 44. The covolume can be interpreted as the molar
volume at closest packing.
The attraction must decrease the total pressure compared to an ideal gas, so
a negative term is added, proportional to an attraction parameter a. This term
is divided by an expression with dimension m
3
, because attractive forces are
proportional to r
-6
, with r being the distance between molecules.
An example of this class of equations is the Soave-Redlich-Kwong equation of
state (Soave, 1972):

(45)
Equation 45 can be written as a cubic polynomial in V
m
. With the two terms of
equation 45 and using simple mixing rules (see Mixtures, below). the Soave-
Redlich-Kwong equation of state can represent non-ideality due to
compressibility effects. The Peng-Robinson equation of state (Peng and
Robinson, 1976) is similar to the Soave-Redlich-Kwong equation of state.
Since the publication of these equations, many improvements and
modifications have been suggested. A selection of important modifications is
available in the Aspen Physical Property System. The original Redlich-Kwong-
Soave and Peng-Robinson equations will be called standard cubic equations of
state. Cubic equations of state in the Aspen Physical Property System are
based on the Redlich-Kwong-Soave and Peng-Robinson equations of state.
Equations are listed in the following table.
Cubic Equations of State in the Aspen Physical Property
System
Redlich-Kwong(-Soave) based Peng-Robinson based
Redlich-Kwong Standard Peng-Robinson
Standard Redlich-Kwong-Soave Peng-Robinson
Redlich-Kwong-Soave Peng-Robinson-MHV2
Redlich-Kwong-ASPEN Peng-Robinson-WS
Schwartzentruber-Renon
Redlich-Kwong-Soave-MHV2
Predictive SRK
Redlich-Kwong-Soave-WS
Pure Components
In a standard cubic equation of state, the pure component parameters are
calculated from correlations based on critical temperature, critical pressure,
and acentric factor. These correlations are not accurate for polar compounds
or long chain hydrocarbons. Introducing a more flexible temperature
dependency of the attraction parameter (the alpha-function), the quality of
vapor pressure representation improves. Up to three different alpha functions
are built-in to the following cubic equation-of-state models in the Aspen
Physical Property System: Redlich-Kwong-Aspen, Schwartzenruber-Renon,
Peng-Robinson-MHV2, Peng-Robinson-WS, Predictive RKS, Redlich-Kwong-
Soave-MHV2, and Redlich-Kwong-Soave-WS.
Cubic equations of state do not represent liquid molar volume accurately. To
correct this you can use volume translation, which is independent of VLE
computation. The Schwartzenruber-Renon equation of state model has
volume translation.
Mixtures
The cubic equation of state calculates the properties of a fluid as if it
consisted of one (imaginary) component. If the fluid is a mixture, the
parameters a and b of the imaginary component must be calculated from the
pure component parameters of the real components, using mixing rules. The
classical mixing rules, with one binary interaction parameter for the attraction
parameter, are not sufficiently flexible to describe mixtures with strong shape
and size asymmetry:

(46)

(47)
A second interaction coefficient is added for the b parameter in the Redlich-
Kwong-Aspen (Mathias, 1983) and Schwartzentruber-Renon
(Schwartzentruber and Renon, 1989) equations of state:

(48)
This is effective to fit vapor-liquid equilibrium data for systems with strong
size and shape asymmetry but it has the disadvantage that k
b,ij
is strongly
correlated with k
a,ij
and that k
b,ij
affects the excess molar volume (Lermite and
Vidal, 1988).
For strong energy asymmetry, in mixtures of polar and non-polar compounds,
the interaction parameters should depend on composition to achieve the
desired accuracy of representing VLE data. Huron-Vidal mixing rules use
activity coefficient models as mole fraction functions (Huron and Vidal, 1979).
These mixing rules are extremely successful in fitting because they combine
the advantages of flexibility with a minimum of drawbacks (Lermite and Vidal,
1988). However, with the original Huron-Vidal approach it is not possible to
use activity coefficient parameters, determined at low pressures, to predict
the high pressure equation-of-state interactions.
Several modifications of Huron-Vidal mixing rules exist which use activity
coefficient parameters obtained at low pressure directly in the mixing rules
(see the table labeled Cubic Equations of State in the Aspen Physical Property
System). They accurately predict binary interactions at high pressure. In
practice this means that the large database of activity coefficient data at low
pressures (DECHEMA Chemistry Data Series, Dortmund DataBank) is now
extended to high pressures.
The MHV2 mixing rules (Dahl and Michelsen, 1990), use the Lyngby modified
UNIFAC activity coefficient model (See Activity Coefficient Models). The
quality of the VLE predictions is good.
The Predictive SRK method (Holderbaum and Gmehling, 1991; Fischer, 1993)
uses the original UNIFAC model. The prediction of VLE is good. The mixing
rules can be used with any equation of state, but it has been integrated with
the Redlich-Kwong-Soave equation of state in the following way: new UNIFAC
groups have been defined for gaseous components, such as hydrogen.
Interaction parameters for the new groups have been regressed and added to
the existing parameter matrix. This extends the existing low pressure activity
coefficient data to high pressures, and adds prediction of gas solubilities at
high pressures.
The Wong-Sandler mixing rules (Wong and Sandler, 1992; Orbey et al.,
1993) predict VLE at high pressure equally well as the MHV2 mixing rules.
Special attention has been paid to the theoretical correctness of the mixing
rules at pressures approaching zero.

Virial Equations of State
Virial equations of state in the Aspen Physical Property System are:
Hayden-O'Connell
BWR-Lee-Starling
Lee-Kesler-Plcker
This type of equation of state is based on a selection of powers of the
expansion:

(49)
Truncation of equation 49 after the second term and the use of the second
virial coefficient B can describe the behavior of gases up to several bar. The
Hayden-O'Connell equation of state uses a complex computation of B to
account for the association and chemical bonding in the vapor phase (see
Vapor Phase Association).
Like cubic equations of state, some of these terms must be related to either
repulsion or attraction. To describe liquid and vapor properties, higher order
terms are needed. The order of the equations in V is usually higher than
cubic. The Benedict-Webb-Rubin equation of state is a good example of this
approach. It had many parameters generalized in terms of critical properties
and acentric factor by Lee and Starling (Brul et al., 1982). The Lee-Kesler-
Plcker equation of state is another example of this approach.
Virial equations of state for liquid and vapor are more flexible in describing a
(p,V) isotherm because of the higher degree of the equation in the volume.
They are more accurate than cubic equations of state. Generalizations have
been focused mainly on hydrocarbons, therefore these compounds obtain
excellent results. They are not recommended for polar compounds.
The standard mixing rules give good results for mixtures of hydrocarbons and
light gases.

Vapor Phase Association
Nonpolar substances in the vapor phase at low pressures behave almost
ideally. Polar substances can exhibit nonideal behavior or even association in
the vapor phase. Association can be expected in systems with hydrogen
bonding such as alcohols, aldehydes and carboxylic acids. Most hydrogen
bonding leads to dimers. HF is an exception; it forms mainly hexamers. This
section uses dimerization as an example to discuss the chemical theory used
to describe strong association. Chemical theory can be used for any type of
reaction.
If association occurs, chemical reactions take place. Therefore, a model based
on physical forces is not sufficient. Some reasons are:
Two monomer molecules form one dimer molecule, so the total number of
species decreases. As a result the mole fractions change. This has
influence on VLE and molar volume (density).
The heat of reaction affects thermal properties like enthalpy, C
p
.
The equilibrium constant of a dimerization reaction,

(50)
in the vapor phase is defined in terms of fugacities:

(51)
With:
f
i
v
=
i
v
y
i
p
(52)
and realizing that
i
v
is approximately unity at low pressures:

(53)
Equations 51-53 are expressed in terms of true species properties. This may
seem natural, but unless measurements are done, the true compositions are
not known. On the contrary, the composition is usually given in terms of
unreacted or apparent species (Abbott and van Ness, 1992), which represents
the imaginary state of the system if no reaction takes place. Superscripts t
and a are used to distinguish clearly between true and apparent species. (For
more on the use of apparent and true species approach, see Apparent
Component and True Component Approaches in the Electrolyte Calculation
chapter).
K in equation 53 is only a function of temperature. If the pressure approaches
zero at constant temperature, ,which is a measure of the degree of
association, must decrease. It must go to zero for zero pressure where the
ideal gas behavior is recovered. The degree of association can be considerable
at atmospheric pressure: for example acetic acid at 293 K and 1 bar is
dimerized at about 95% (Prausnitz et al., 1986).
The equilibrium constant is related to the thermodynamic properties of
reaction:

(54)
The Gibbs energy, the enthalpy, and the entropy of reaction can be
approximated as independent of temperature. Then from equation 54 it
follows that ln K plotted against 1/T is approximately a straight line with a
positive slope (since the reaction is exothermic) with increasing 1/T. This
represents a decrease of ln K with increasing temperature. From this it follows
(using equation 53) that the degree of association decreases with increasing
temperature.
It is convenient to calculate equilibria and to report mole fractions in terms of
apparent components. The concentrations of the true species have to be
calculated, but are not reported. Vapor-liquid equilibria in terms of apparent
components require apparent fugacity coefficients.
The fugacity coefficients of the true species are expected to be close to unity
(ideal) at atmospheric pressure. However the apparent fugacity coefficient
needs to reflect the decrease in apparent partial pressure caused by the
decrease in number of species.
The apparent partial pressure is represented by the term y
i
a
p in the vapor
fugacity equation applied to apparent components:
f
i
a,v
=
i
a,v
y
i
a
p
(55)
In fact the apparent and true fugacity coefficients are directly related to each
other by the change in number of components (Nothnagel et al., 1973;
Abbott and van Ness, 1992):

(56)

Apparent Fugacity of Vapor Benzene and Propionic Acid
This is why apparent fugacity coefficients of associating species are well below
unity. This is illustrated in the figure labeled Apparent Fugacity of Vapor
Benzene and Propionic Acid for the system benzene + propionic acid at 415 K
and 101.325 kPa (1 atm) (Nothnagel et al., 1973). The effect of dimerization
clearly decreases below apparent propionic acid mole fractions of about 0.2
(partial pressures of 20 kPa). The effect vanishes at partial pressures of zero,
as expected from the pressure dependence of equation 53. The apparent
fugacity coefficient of benzene increases with increasing propionic acid mole
fraction. This is because the true mole fraction of propionic acid is higher than
its apparent mole fraction (see equation 56).
The vapor enthalpy departure needs to be corrected for the heat of
association. The true heat of association can be obtained from the equilibrium
constant:

(57)
The value obtained from equation 57 must be corrected for the ratio of true to
apparent number of species to be consistent with the apparent vapor
enthalpy departure. With the enthalpy and Gibbs energy of association
(equations 57 and 54), the entropy of association can be calculated.
The apparent heat of vaporization of associating components as a function of
temperature can show a maximum. The increase of the heat of vaporization
with temperature is probably related to the decrease of the degree of
association with increasing temperature. However, the heat of vaporization
must decrease to zero when the temperature approaches the critical
temperature. The figure labeled Liquid and Vapor Enthalpy of Acetic Acid
illustrates the enthalpic behavior of acetic acid. Note that the enthalpy effect
due to association is very large.

Liquid and Vapor Enthalpy of Acetic Acid
The true molar volume of an associating component is close to the true molar
volume of a non-associating component. At low pressures, where the ideal
gas law is valid, the true molar volume is constant and equal to p/RT,
independent of association. This means that associated molecules have a
higher molecular mass than their monomers, but they behave as an ideal gas,
just as their monomers. This also implies that the mass density of an
associated gas is higher than that of a gas consisting of the monomers. The
apparent molar volume is defined as the true total volume per apparent
number of species. Since the number of apparent species is higher than the
true number of species the apparent molar volume is clearly smaller than the
true molar volume.
The chemical theory can be used with any equation of state to compute true
fugacity coefficients. At low pressures, the ideal gas law can be used.
For dimerization, two approaches are commonly used: the Nothagel and the
Hayden-O'Connel equations of state. For HF hexamerization a dedicated
equation of state is available in the Aspen Physical Property System.
Nothnagel et al. (1973) used a truncated van der Waals equation of state.
They correlated the equilibrium constants with the covolume b, a polarity
parameter p and the parameter d. b can be determined from group
contribution methods (Bondi, 1968) (or a correlation of the critical
temperature and pressure (as in the Aspen Physical Property System). d and
p are adjustable parameters. Many values for d and p are available in the
Nothnagel equation of state in the Aspen Physical Property System. Also
correction terms for the heats of association of unlike molecules are built-in.
The equilibrium constant, K, has been correlated to T
b
, T
c
, b, d, and p.
Hayden and O'Connell (1975) used the virial equation of state (equation 49),
truncated after the second term. They developed a correlation for the second
virial coefficient of polar, nonpolar and associating species based on the
critical temperature and pressure, the dipole moment and the mean radius of
gyration. Association of like and unlike molecules is described with the
adjustable parameter . Pure component and binary values for are
available in the Aspen Physical Property System.
The HF equation of state (de Leeuw and Watanasiri, 1993) assumes the
formation of hexamers only. The fugacities of the true species are assumed to
be ideal, and is therefore suited for low pressures. Special attention has been
paid to the robustness of the algorithm, and the consistency of the results
with theory. The equation of state has been integrated with the electrolyte
NRTL activity coefficient model to allow the rigorous representation of
absorption and stripping of HF with water. It can be used with other activity
coefficient models for hydrocarbon + HF mixtures.

Activity Coefficient Models
This section discusses the characteristics of activity coefficient models. The
description is divided into the following categories:
Molecular models (correlative models for non-electrolyte solutions)
Group contribution models (predictive models for non-electrolyte
solutions)
Electrolyte activity coefficient models

Molecular Models
The early activity coefficient models such as van Laar and Scatchard-
Hildebrand, are based on the same assumptions and principles of regular
solutions. Excess entropy and excess molar volume are assumed to be zero,
and for unlike interactions, London's geometric mean rule is used. Binary
parameters were estimated from pure component properties. The van Laar
model is only useful as correlative model. The Scatchard-Hildebrand can
predict interactions from solubility parameters for non-polar mixtures. Both
models predict only positive deviations from Raoult's law (see Activity
Coefficient Method).
The three-suffix Margules and the Redlich-Kister activity coefficient models
are flexible arithmetic expressions.
Local composition models are very flexible, and the parameters have much
more physical significance. These models assume ordering of the liquid
solution, according to the interaction energies between different molecules.
The Wilson model is suited for many types of non-ideality but cannot model
liquid-liquid separation. The NRTL and UNIQUAC models can be used to
describe VLE, LLE and enthalpic behavior of highly non-ideal systems. The
WILSON, NRTL and UNIQUAC models are well accepted and are used on a
regular basis to model highly non-ideal systems at low pressures.
A detailed discussion of molecular activity coefficient models and underlying
theories can be found in Prausnitz et al. (1986).

Group Contribution Models
The UNIFAC activity coefficient model is an extension of the UNIQUAC model.
It applies the same theory to functional groups that UNIQUAC uses for
molecules. A limited number of functional groups is sufficient to form an
infinite number of different molecules. The number of possible interactions
between groups is very small compared to the number of possible interactions
between components from a pure component database (500 to 2000
components). Group-group interactions determined from a limited, well
chosen set of experimental data are sufficient to predict activity coefficients
between almost any pair of components.
UNIFAC (Fredenslund et al., 1975; 1977) can be used to predict activity
coefficients for VLE. For LLE a different dataset must be used. Mixture
enthalpies, derived from the activity coefficients (see Activity Coefficient
Method) are not accurate.
UNIFAC has been modified at the Technical University of Lyngby (Denmark).
The modification includes an improved combinatorial term for entropy and the
group-group interaction has been made temperature dependent. The three
UNIFAC models are available in the Aspen Physical Property System. For
detailed information on each model, see Physical Property Models, UNIFAC,
UNIFAC (Dortmund Modified), UNIFAC (Lyngby Modified).
This model can be applied to VLE, LLE and enthalpies (Larsen et al., 1987).
Another UNIFAC modification comes from the University of Dortmund
(Germany). This modification is similar to Lyngby modified UNIFAC, but it can
also predict activity coefficients at infinite dilution (Weidlich and Gmehling,
1987).

Electrolyte Models
In electrolyte solutions a larger variety of interactions and phenomena exist
than in non-electrolyte solutions. Besides physical and chemical molecule-
molecule interactions, ionic reactions and interactions occur (molecule-ion and
ion-ion). Electrolyte activity coefficient models (Electrolyte NRTL, Pitzer) are
therefore more complicated than non-electrolyte activity coefficient models.
Electrolytes dissociate so a few components can form many species in a
solution. This causes a multitude of interactions, some of which are strong.
This section gives a summary of the capabilities of the electrolyte activity
coefficient models in the Aspen Physical Property System. For details, see
Electrolyte NRTL Activity Coefficient Model, Bromley-Pitzer Activity Coefficient
Model, and Pitzer Activity Coefficient Model in Physical Property Models.
The Pitzer electrolyte activity coefficient model can be used for the
representation of aqueous electrolyte solutions up to 6 molal strength
(literature references: Chen et al., 1979; Frst and Renon, 1982;
Guggenheim, 1935; Guggenheim and Turgeon, 1955; Renon, 1981; see also
Parameter Sources). The model handles gas solubilities. Excellent results can
be obtained, but many parameters are needed.
The Electrolyte NRTL model is an extension of the molecular NRTL model
(literature references: Chen et al., 1982; Chen and Evans, 1986; CRC
Handbook, 1975; Mock et al., 1984, 1986; Renon and Prausnitz, 1968). It can
handle electrolyte solutions of any strength, and is suited for solutions with
multiple solvents, and dissolved gases. The flexibility of this model makes it
very suitable for any low-to-moderate pressure application.
Electrolyte parameter databanks and data packages for industrially important
applications have been developed for both models (see Physical Property
Data, Chapter 1). If parameters are not available, use data regression, or the
Bromley-Pitzer activity coefficient model.
The Bromley-Pitzer activity coefficient model is a simplification of the Pitzer
model (literature references: Bromley, 1973; Frst and Renon, 1982). A
correlation is used to calculate the interaction parameters. The model is
limited in accuracy, but predictive.

Transport Property Methods
The Aspen Physical Property System property methods can compute the
following transport properties:
Viscosity
Thermal conductivity
Diffusion coefficient
Surface tension
Each pure component property is calculated either from an empirical equation
or from a semi-empirical (theoretical) correlation. The coefficients for the
empirical equation are determined from experimental data and are stored in
the Aspen Physical Property System databank. The mixture properties are
calculated using appropriate mixing rules. This section discusses the methods
for transport property calculation. The properties that have the most in
common in their behavior are viscosity and thermal conductivity. This is
reflected in similar methods that exist for these properties and therefore they
are discussed together.

Viscosity and Thermal Conductivity
Methods
When the pressure approaches zero, viscosity and thermal conductivity are
linear functions of temperature with a positive slope. At a given temperature,
viscosity and thermal conductivity increase with increasing density (density
increases for any fluid with increasing pressure).
Detailed molecular theories exist for gas phase viscosity and thermal
conductivity at low pressures. Some of these can account for polarity. These
low pressure properties are not exactly ideal gas properties because non-
ideality is taken into account. Examples are the Chapman-Enskog-Brokaw and
the Chung-Lee-Starling low pressure vapor viscosity models and the Stiel-
Thodos low pressure vapor thermal conductivity model.
Residual property models are available to account for pressure or density
effects. These models calculate the difference of a certain property with
respect to the low pressure value. The method used is:
x(p) = x(p = 0) + (x(p) - x(p = 0)) (58)
Where:
x = Viscosity or thermal conductivity
Most of the low pressure models require mixing rules for calculating mixture
properties.
Another class of models calculate the high pressure property directly from
molecular parameters and state variables. For example the TRAPP models for
hydrocarbons use critical parameters and acentric factor as molecular
parameters. The models use temperature and pressure as state variables.
The Chung-Lee-Starling models use critical parameters, acentric factor, and
dipole moment as molecular parameters. The models use temperature and
density as state variables. These models generally use mixing rules for
molecular parameters, rather than mixing rules for pure component
properties.
Vapor viscosity, thermal conductivity, and vapor diffusivity are interrelated by
molecular theories. Many thermal conductivity methods therefore require low
pressure vapor viscosity either in calculating thermal conductivity or in the
mixing rules.
Liquid properties are often described by empirical, correlative models:
Andrade/DIPPR for liquid viscosity and Sato-Riedel for thermal conductivity.
These are accurate in the temperature and pressure ranges of the
experimental data used in the fit. Mixing rules for these properties do not
provide a good description for the excess properties.
Corresponding-states models such as Chung-Lee-Starling and TRAPP can
describe both liquid and vapor properties. These models are more predictive
and less accurate than a correlative model, but extrapolate well with
temperature and pressure. Chung-Lee-Starling allows the use of binary
interaction parameters and an association parameter, which can be adjusted
to experimental data.

Diffusion Coefficient Methods
It is evident that diffusion is related to viscosity, so several diffusion
coefficient methods, require viscosity, for both liquid and for vapor diffusion
coefficients. (Chapman-Enskog-Wilke-Lee and Wilke-Chang models).
Vapor diffusion coefficients can be calculated from molecular theories similar
to those discussed for low pressure vapor viscosity and thermal conductivity.
Similarly, pressure correction methods exist. The Dawson-Khoury-Kobayashi
model calculates a pressure correction factor which requires the density as
input.
Liquid diffusion coefficients depend on activity and liquid viscosity.
Binary diffusion coefficients are required in processes where mass transfer is
limited. Binary diffusion coefficients describe the diffusion of one component
at infinite dilution in another component. In multicomponent systems this
corresponds to a matrix of values.
The average diffusion coefficient of a component in a mixture does not have
any quantitative applications; it is an informative property. It is computed
using a mixing rule for vapor diffusion coefficients and using mixture input
parameters for the Wilke-Chang model.

Surface Tension Methods
Surface tension is calculated by empirical, correlative models such as Hakim-
Steinberg-Stiel/DIPPR. An empirical linear mixing rule is used to compute
mixture surface tension.

Nonconventional Component
Enthalpy Calculation
Nonconventional components generally do not participate in phase equilibrium
calculations, but are included in enthalpy balances. For a process unit in
which no chemical change occurs, only sensible heat effects of
nonconventional components are significant. In this case, the enthalpy
reference state may be taken as the component at any arbitrary reference
temperatures (for example, 298.15 K). If a nonconventional component is
involved in a chemical reaction, an enthalpy balance is meaningful only if the
enthalpy reference state is consistent with that adopted for conventional
components: the constituents elements must be in their standard states at 1
atm and 298.15 K. The enthalpy is calculated as:

(59)
Frequently the heat of formation
f
h
s
is unknown and cannot be obtained
directly because the molecular structure of the component is unknown. In
many cases, it is possible to calculate the heat of formation from the heat of
combustion
c
h
s
, because the combustion products and elemental
composition of the components are known:
f
h
s
=
c
h
s
+
f
h
cp
s

(60)
f
h
cp
s
is the sum of the heats of formation of the combustion products
multiplied by the mass fractions of the respective elements in the
nonconventional component. This is the approach used in the coal enthalpy
model HCOALGEN (see Physical Property Models). This approach is
recommended for computing DHFGEN for the ENTHGEN model.
Symbol Definitions
Roman Letters Definitions
a Equation of state energy parameter
b Equation of state co-volume
B Second virial coefficient
C
p
Heat capacity at constant pressure
C Third virial coefficient
f Fugacity
G Gibbs energy
H Henry's constant
H Enthalpy
k Equation of state binary parameter
K Chemical equilibrium constant
n Mole number
p Pressure
R Universal gas constant
S Entropy
T Temperature
V Volume
x,y Molefraction
Z Compressibility factor

Greek Letters Definitions

Activity coefficient

Poynting correction

Fugacity coefficient

Thermodynamic potential

Superscripts Definitions
c Combustion property
i Component index
f Formation property
m Molar property
vap Vaporization property
r Reaction property
ref Reference state property
* Pure component property, asymmetric convention
Superscripts Definitions

At infinite dilution
a Apparent property
E Excess property
ig Ideal gas property
l Liquid property
l2 Second liquid property
l1 First liquid property
s Solid property
t True property
v Vapor property

References for Overview of
Aspen Physical Property
Methods
Abbott, M. M. and M. C. Van Ness, "Thermodynamics of Solutions Containing
Reactive Species: A Guide to Fundamentals and Applications," Fluid Phase
Equilibria, Vol 77, (1992), pp. 53-119.
Bondi, A., "Physical Properties of Molecular Liquids, Crystals, and Glasses,"
Wiley, New York, 1968.
Bromley, L.A., "Thermodynamic Properties of Strong Electrolytes in Aqueous
Solution, " AIChE J., Vol. 19, No. 2, (1973), pp. 313 320.
Brul, M.R., C.T. Lin, L.L. Lee, and K.E. Starling, "Multiparameter
Corresponding States Correlation of Coal-Fluid Thermodynamic Properties,"
AIChE J., Vol. 28, No. 4, (1982), pp. 616 637.
Chen, C.-C., H.I. Britt, J.F. Boston and L.B. Evans, "Extension and Application
of the Pitzer Equation for Vapor-Liquid Equilibrium of Aqueous Electrolyte
Systems with Molecular Solutes," AIChE.J., Vol. 25, (1979), pp. 820-831.
Chen, C.-C., H.I. Britt, J.F. Boston, and L.B. Evans, "Local Compositions
Model for Excess Gibbs Energy of Electrolyte Systems: Part I: Single Solvent,
Single Completely Dissociated Electrolyte Systems:, AIChE J., Vol. 28, No. 4,
(1982), p. 588-596.
Chen, C.-C., and L.B. Evans, "A Local Composition Model for the Excess Gibbs
Energy of Aqueous Electrolyte Systems," AIChE J., Vol. 32, No. 3, (1986), p.
444-459.
Davenport, A.J. and J.S. Rowlinson, Trans. Faraday Soc., Vol. 59 (1963), p.
78.
De Leeuw, V. V. and S. Watanasiri, "Modelling Phase Equilibria and Enthalpies
of the System Water and Hydroflouric Acid Using an HF Equation-of-state in
Conjunction with the Electrolyte NRTL Activity Coefficient Model," Paper
presented at the 13th European Seminar on Applied Thermodynamics, June 9
12, Carry-le-Rouet, France, 1993.
Dyke, D.E.L., J.S. Rowlinson and R. Thacker, Trans. Faraday Soc., Vol. 55,
(1959), p. 903.
Fall, D.J., J.L. Fall, and K.D. Luks, "Liquid-liquid-vapor immiscibility Limits in
Carbon Dioxide + n-Paraffin Mixtures," J. Chem. Eng. Data , Vol. 30, No. 1,
(1985), pp. 82-88.
Fischer, K., Die PSRK-Methode: Eine Zustandsgleichung unter Verwendung
des UNIFAC-Gruppenbeitragsmodells, VDI Fortschrittberichte, Reihe 3:
Verfahrenstechnik, Nr. 324 (Dsseldorf: VDI Verlag GmbH, 1993).
Fredenslund, Aa., R.L. Jones, and J.M. Prausnitz, "Group-Contribution
Estimation of Activity Coefficients in Nonideal Liquid Mixtures," AIChE J., Vol.
21, (1975), pp. 1086-1099.
Fredenslund, Aa., J. Gmehling, and P. Rasmussen, Vapor-Liquid Equilibria
Using UNIFAC, (Amsterdam: Elsevier, 1977).
Frst, W. and H. Renon, "Effects of the Various Parameters in the Application
of Pitzer's Model to Solid-Liquid Equilibrium. Preliminary Study for Strong 1-1
Electrolytes," Ind. Eng. Chem. Process Des. Dev., Vol. 21, No. 3, (1982),
pp. 396-400.
Gmehling, J., U. Onken and W. Arlt, "Vapor-Liquid Equilibrium Data
Collection, Aliphatic Hydrocarbons, C4 - C6," Chemistry Data Series Vol 1,
Part 6a, D. Bierens and R. Eckerman, eds., (Frankfurt/Main: Dechema, 1980).
Gmehling, J., U. Onken and W. Arlt, "Vapor-Liquid Equilibrium Data
Collection, Aqueous-Organic Systems, Supplement 2," Chemistry Data Series
Vol 1, Part 1b , D. Bierens and R. Eckerman, eds., (Frankfurt/Main: Dechema,
1988).
Guggenheim, E.A., Phil. Mag., Vol. 7, No. 19, (1935), p. 588.
Guggenheim, E.A. and J.C. Turgeon, Trans. Faraday Soc., Vol. 51, (1955), p.
747.
Haar, L., J.S. Gallagher, and J.H. Kell, NBS/NRC Steam Tables (Washington:
Hemisphere Publishing Corporation, 1984).
Handbook of Chemistry and Physics, 56th Edition, CRC Press, 1975, p. E-1.
Hayden, J.G. and J.P. O'Connell, " A Generalized Method for Predicting Second
Virial Coefficients, " Ind. Eng. Chem. Process Des. Dev., Vol. 14, No. 3,
(1975), pp. 209-216.
Hicks, C.P. and C.L. Young, Trans. Faraday Soc., Vol. 67, (1971), p.1605.
Holderbaum, T. and J. Gmehling, "PSRK: A Group Contribution Equation of
State based on UNIFAC", Fluid Phase Eq., Vol. 70, (1991), pp. 251-265.
Huron, M.-J. and J. Vidal, "New Mixing Rules in Simple Equations of state for
representing Vapour-Liquid Equilibria of Strongly Non-ideal Mixtures," Fluid
Phase Eq., Vol. 3, (1979), pp. 255-271.
Kohn, J.P., AIChE J. , Vol 7, (1961), p. 514.
Larsen, B.L., P. Rasmussen, and Aa. Fredenslund, "A Modified UNIFAC Group-
Contribution Model for the Prediction of Phase Equilibria and Heats of Mixing,"
Ind. Eng. Chem. Res., Vol. 26, (1987), pp. 2274-2286.
Lermite, Ch. and J. Vidal, "Les rgles de mlange appliques aux quations
d'tat." Revue de l'Institut Franais du Ptrole, Vol. 43, No. 1, (1988), pp. 73-
94.
Mathias, P.M., "A Versatile Phase Equilibrium Equation of State," Ind. Eng.
Chem. Process Des. Dev. Vol. 22, (1983), pp. 385-391.
Mock, B., L.B. Evans, and C.-C. Chen, "Phase Equilibria in Multiple-Solvent
Electrolyte Systems: A New Thermodynamic Model," Proceedings of the 1984
Summer Computer Simulation Conference, p. 558.
Mock, B., L.B. Evans, and C.-C. Chen, "Thermodynamic Representation of
Phase Equilibria of Mixed-Solvent Electrolyte Systems," AIChE J., Vol. 32, No.
10, (1986), p. 1655-1664.
Nothnagel, K.-H., D.S. Abrams, and J.M. Prausnitz, "Generalized Correlation
for Fugacity Coefficients in Mixtures at Moderate Pressures. Applications of
Chemical Theory of Vapor Imperfections," Ind. Eng. Chem. Process Des. Dev.,
Vol. 12, No. 1, (1973), pp. 25-35.
Orbey, H., S.I. Sandler, and D.S. Wong, "Accurate equation of state
predictions at high temperatures and pressures using the existing UNIFAC
model," Fluid Phase Eq., Vol. 85, (1993), pp. 41-54.
Peng, D.-Y. and D.B. Robinson, "A New Two-Constant Equation of state," Ind.
Eng. Chem. Fundam., Vol. 15, (1976), pp. 59-64.
Peters, C.J., R.N. Lichtenthaler, and J. de Swaan Arons, "Three Phase
Equilibria In Binary Mixtures Of Ethane And Higher N-Alkanes," Fluid Phase
Eq., Vol. 29, (1986), pp. 495-504.
Pozo, M.E. and W.B. Street, "Fluid Phase Equilibria for the System Dimethyl
Ether/Water from 50 to 200 C and Pressures to 50.9 MPa," J. Chem. Eng.
Data, Vol. 29, No. 3, (1984), pp. 324-329.
Prausnitz, J.M., R.N. Lichtenthaler, and E. Gomes de Azevedo, Molecular
Thermodynamics of Fluid-Phase Equilibria, 2nd ed., (Englewood Cliffs:
Prentice-Hall Inc., 1986), pp. 137-151.
Renon, H. and J.M. Prausnitz, "Local Compositions in Thermodynamic Excess
Functions for Liquid Mixtures", AIChE J., Vol. 14, No. 1, (1968), pp. 135-144.
Renon, H., "Deviation from Ideality in Electrolyte Solutions," Foundation of
Computer-Aided Chemical Process Design, Vol. II, Engineering Foundations,
(1981), New York.
Rowlinson, J.S. and F.L. Swinton, Liquids and Liquid Mixtures, 3rd ed.
(London, etc.:Butterworths, 1982), ch. 6.
Dahl, S. and M.L. Michelsen, "High-Pressure Vapor-Liquid Equilibrium with a
UNIFAC-based Equation of State", AIChE J., Vol. 36, No. 12 (1990), pp. 1829-
1836.
Schwartzentruber, J. and H. Renon, "Extension of UNIFAC to High Pressures
and Temperatures by the Use of a Cubic Equation of State," Ind. Eng. Chem.
Res., Vol. 28, (1989), pp. 1049-1955.
Soave, G., "Equilibrium Constants for a Modified Redlich-Kwong Equation of
State," Chem. Eng. Sci., Vol. 27, (1972), pp. 1196-1203.
van der Kooi, H.J., Metingen en berekeningen aan het systeem methaan-n-
eiscosaan, Ph.D. thesis, Delft University of Technology (Delft: Delftse
Universitaire Pers, 1981) (In Dutch).
Weidlich, U. and J. Gmehling, "A Modified UNIFAC Model. 1. Prediction of VLE,
h
E
, ," Ind. Eng. Chem. Res., Vol. 26, (1987), pp. 1372-1381.
Wong, D.S. and S.I. Sandler, "A Theoretically Correct New Mixing Rule for
Cubic Equations of State for Both Highly and Slightly Non-ideal Mixtures,"
AIChE J., Vol. 38, (1992), pp. 671-680.

40 2 Property Method Descriptions
2 Property Method
Descriptions
This chapter describes the Aspen Physical Property System property methods.
Topics include:
Classification of property methods
Recommended use
Property method descriptions, organized by application
Since Aspen Physical Property System property methods are tailored to
classes of compounds and operating conditions, they fit most engineering
needs. Customization of property methods is explained in the Property
Method Calculations and Routes chapter. Specific models are discussed in
Physical Property Models.

Classification of Property
Methods and Recommended
Use
A property method is a collection of property calculation routes. (For more on
routes, see Routes and Models). The properties involved are needed by unit
operation models.
Thermodynamic properties:
Fugacity coefficient (or equivalent: chemical potential, K-value)
Enthalpy
Entropy
Gibbs energy
Volume
Transport properties:
Viscosity
2 Property Method Descriptions 41
Surface tension
Property methods allow you to specify a collection of property calculation
procedures as one entity, for example, you might use them in a unit
operation, or in a flowsheet (see Aspen Plus User Guide, Chapter 7).
It is important to choose the right property method for an application to
ensure the success of your calculation. To help you choose a property
method, frequently encountered applications are listed with recommended
property methods. (Multiple property methods often apply. A class of property
methods is recommended, as opposed to an individual property method.)
The classes of property methods available are:
IDEAL
Liquid fugacity and K-value correlations
Petroleum tuned equations of state
Equations of state for high pressure hydrocarbon applications
Flexible and predictive equations of state
Liquid activity coefficients
Electrolyte activity coefficients and correlations
Solids processing
Steam tables
After you have decided which property method class your application needs,
refer to the corresponding section for more detailed recommendations. See
Physical Property Models for detailed information on models and their
parameter requirements. General usage issues, such as using Henry's law and
the free-water approximation, are discussed in Aspen Plus User Guide,
Chapter 7.
Recommended Classes of Property Methods for Different
Applications
Oil and Gas Production
Application Recommended Property Method
Reservoir systems Equations of state for high pressure
hydrocarbon applications
Platform separation Equations of state for high pressure
Transportation of oil and gas by
pipeline
Equations of state for high pressure
Refinery
Low pressure applications(up to
several atm)
Vacuum tower
Atmospheric crude tower
Petroleum fugacity and K-value
correlations (and assay data analysis)
Medium pressure applications (up
to several tens of atm)
Coker main fractionator
FCC main fractionator
Petroleum fugacity and K-value
correlations
Petroleum-tuned equations of state (and
assay data analysis)
Hydrogen-rich applications
Reformer
Hydrofiner
Selected petroleum fugacity correlations
Lube oil unit
De-asphalting unit
Gas Processing
Hydrocarbon separations
Demethanizer
C3-splitter
hydrocarbon applications (with k
ij
)
Cryogenic gas processing
Air separation
Gas dehydration with glycols Flexible and predictive equations of state
Acid gas absorption with
Methanol (rectisol)
NMP (purisol)
Acid gas absorption with
Water
Ammonia
Amines
Amines + methanol (amisol)
Caustic
Lime
Hot carbonate
Electrolyte activity coefficients
Claus process Flexible and predictive equations of state
Petrochemicals
Ethylene plant
Primary fractionator

Light hydrocarbons separation
train

Quench tower
Petroleum fugacity correlations
(and assay data analysis)


Aromatics
BTX extraction
Liquid activity coefficients (very sensitive
to parameters)
Substituted hydrocarbons
VCM plant
Acrylonitrile plant
Ether production
MTBE, ETBE, TAME
Ethylbenzene and styrene plants Equations of state for high pressure
hydrocarbon applications and Ideal (with
Watsol) or liquid activity coefficient
Terephthalic acid Liquid activity coefficients(with
dimerization in acetic acid section)
Chemicals
Azeotropic separations
Alcohol separation
Carboxylic acids
Acetic acid plant
Phenol plant Liquid activity coefficients
Liquid phase reactions
Estrification
Ammonia plant Equations of state for high pressure
hydrocarbon applications (with k
ij
)
Fluorochemicals Liquid activity coefficients (and HF
equation of state)
Inorganic Chemicals
Caustic
Acids
Phosphoric acid
Sulphuric acid
Nitric acid
Hydrochloric acid
Hydrofluoric acid

Electrolyte activity coefficient (and HF
equation of state)
Coal Processing
Size reduction
crushing, grinding
Solids processing (with coal analysis and
particle size distribution)
Separation and cleaning
sieving, cyclones,
preciptition, washing
Solids processing (with coal analysis and
and particle size distribution)
Combustion Equations of state for high pressure
hydrocarbon applications (with
combustion databank)
Acid gas absorption See Gas Processing earlier in this
discussion.
Coal gasification and liquefaction See Synthetic Fuel later in this discussion.
Power Generation
Combustion

Coal
Oil
hydrocarbon applications (with
combustion databank)
(and assay analysis with coal correlations)
(and assay analysis)
Steam cycles
Compressors
Turbines
Steam tables
Acid gas absorption See Gas Processing earlier in this
discussion.
Synthetic Fuel
Synthesis gas Equations of state for high pressure
Coal gasification Equations of state for high pressure
Coal liquefaction Equations of state for high pressure
hydrocarbon applications with k
ij
and
assay analysis with coal correlations)
Environmental
Solvent recovery Liquid activity coefficients
(Substituted) hydrocarbon
stripping
Acid gas stripping from
Methanol (rectisol)
NMP (purisol)
Acid gas stripping from
Water
Ammonia
Amines
Amines + methanol (amisol)
Caustic
Lime
Hot carbonate
Claus process Flexible and predictive equations of state
Acids
Stripping
Neutralization
Water and Steam
Steam systems Steam tables
Coolant Steam tables
Mineral and Metallurgical Processes
Mechanical processing
crushing, grinding,
sieving, washing
Solids Processing (with inorganic
databank)
Hydrometallurgy
Mineral leaching
Pyrometallurgy
Smelter
Converter
Solids Processing (with inorganic
databank)

IDEAL Property Method
The IDEAL property method accommodates both Raoult's law and Henry's
law. This method uses the:
Ideal activity coefficient model for the liquid phase ( = 1)
Ideal gas equation of state Pv = RT for the vapor phase
Rackett model for liquid molar volume
The IDEAL property method is recommended for systems in which ideal
behavior can be assumed, such as:
Systems at vacuum pressures
Isomeric systems at low pressures
In the vapor phase, small deviations from the ideal gas law are allowed.
These deviations occur at:
Low pressures (either below atmospheric pressure, or at pressures not
exceeding 2 bar)
Very high temperatures
Ideal behavior in the liquid phase is exhibited by molecules with either:
Very small interactions (for example, paraffin of similar carbon number)
Interactions that cancel each other out (for example, water and acetone)
The IDEAL property method:
Can be used for systems with and without noncondensable components.
Permanent gases can be dissolved in the liquid. You can use Henry's law,
which is valid at low concentrations, to model this behavior.
Does not include the Poynting correction
Returns heat of mixing of zero
Is used to initialize FLASH algorithm
The transport property models for the vapor phase are all well suited for ideal
gases. The transport property models for the liquid phase are empirical
equations for fitting experimental data.
The IDEAL property method is sometimes used for solids processing where
VLE is unimportant (for example, in coal processing). For these, however, the
SOLIDS property method is recommended. See Solids Handling Property
Method for documentation on solid phase properties.
Mixture Types
Ideal mixtures with and without noncondensable components. You should not
use IDEAL for nonideal mixtures.
Range
IDEAL is appropriate only at low pressure and low liquid mole fractions of the
noncondensable components (if present).
Use of Henry's Law
To use Henry's law for noncondensable components, you must designate
these components as Henry's components on the Components Henry-Comps
form. Henry's constant model parameters (HENRY) must be available for the
solute with at least one solvent. Use the Properties Parameters Binary
Interaction form (HENRY-1) to enter Henry's constants or to review built-in
parameters. Aspen Physical Property System contains an extensive collection
of Henry's constants for many solutes in solvents. Solvents are water and
other organic components. Aspen Physical Property System uses these
parameters automatically when you specify the IDEAL property method.
The following table lists thermodynamic and transport property models used
in IDEAL, and their minimum parameter requirements.
Parameters Required for the IDEAL Property Method
General
Property/Purpose Parameter Requirements
Mass balance,
Conversion Mass-basisMole-basis MW
Conversion Stdvol-basisMole-
basis
VLSTD
Using Free-water option: solubility
of water in organic phase
WATSOL
Enthalpy of reaction DHFORM
Gibbs energy of reaction DGFORM
Thermodynamic Properties
Properties Models Parameter Requirements
Vapor mixture

Enthalpy, entropy,
Gibbs energy

Density

Ideal gas law

Ideal gas heat capacity

Ideal gas law

CPIG or CPIGDP
Liquid mixture
Ideal liquid activity coefficient

Extended Antoine vapor
pressure

Henry's constant

Brelvi-O'Connell

PLXANT

Solvent: VC, Solute-solvent:
HENRY

Solvent: TC, PC, (ZC or
RKTZRA), Solute: (VC or
VLBROC)
Enthalpy, entropy Watson/DIPPR TC, (DHVLWT or DHVLDP)
Density Rackett TC, PC, (VC or VCRKT), (ZC or
RKTZRA)
Transport Properties
Vapor mixture
Viscosity


Diffusivity

Chapman-Enskog-Brokaw/
DIPPR

Stiel-Thodos low pres./
DIPPR

Chapman-Enskog-Wilke-Lee

MW; (MUP and (STKPAR or
LJPAR)) or MUVDIP

MW or
KVDIP

MW; MUP and (STKPAR or
LJPAR)
Surface tension Hakim-Steinberg-Stiel/
DIPPR
(TC, PC, OMEGA) or
SIGDIP
Liquid mixture
Viscosity
Thermal Conductivity
Diffusivity

Andrade/DIPPR
Sato-Riedel/DIPPR
Wilke-Chang

MULAND or MULDIP
(MW, TC, TB) or KLDIP
MW, VB

REFPROP (NIST Reference Fluid
Thermodynamic and Transport
Properties Database)
Overview
REFPROP is an acronym for REFerence fluid PROPerties. This model,
developed by the National Institute of Standards and Technology (NIST),
provides thermodynamic and transport properties of industrially important
fluids and their mixtures with an emphasis on refrigerants and hydrocarbons,
especially natural gas systems.
REFPROP is based on the most accurate pure fluid and mixture models
currently available. It implements three models for the thermodynamic
properties of pure fluids: equations of state explicit in Helmholtz energy, the
modified Benedict-Webb-Rubin equation of state, and an extended
corresponding states (ECS) model. Mixture calculations employ a model that
applies mixing rules to the Helmholtz energy of the mixture components; it
uses a departure function to account for the departure from ideal mixing.
Viscosity and thermal conductivity are modeled with either fluid-specific
correlations, an ECS method, or in some cases the friction theory method.
REFPROP in the Aspen Physical Property System is provided under an
agreement with the National Institute of Standards and Technology's (NIST)
Standard Reference Data Program (SRDP).
Fluids, models, and available properties
REFPROP in the Aspen Physical Property System includes 84 pure fluids:
The typical natural gas constituents methane, ethane, propane, butane,
isobutane, pentane, isopentane, hexane, isohexane, heptane, octane,
nonane, decane, dodecane, carbon dioxide, carbon monoxide, hydrogen,
nitrogen, and water
The hydrocarbons acetone, benzene, butene, cis-butene, cyclohexane,
cyclopropane, ethylene, isobutene, neopentane, propyne, trans-butene,
and toluene
The HFCs R23, R32, R41, R125, R134a, R143a, R152a, R227ea, R236ea,
R236fa, R245ca, R245fa, and R365mfc
The HCFCs R21, R22, R123, R124, R141b, and R142b
The traditional CFCs R11, R12, R13, R113, R114, and R115
The fluorocarbons R14, R116, R218, C4F10, C5F12, and RC318
The "natural" refrigerants ammonia, carbon dioxide, propane, isobutane,
and propylene
The main air constituents nitrogen, oxygen, and argon
The noble elements helium, argon, neon, krypton, and xenon
The cryogens argon, carbon monoxide, deuterium, krypton, neon,
nitrogen trifluoride, nitrogen, fluorine, helium, methane, oxygen, normal
hydrogen, and parahydrogen
Water (as a pure fluid)
Miscellaneous substances including carbonyl sulfide, dimethyl ether,
ethanol, heavy water, hydrogen sulfide, methanol, nitrous oxide, sulfur
hexafluoride, sulfur dioxide, and trifluoroiodomethane
The REFPROP model uses the most accurate equations of state and models
currently available:
High accuracy Helmholtz energy equations of state, including international
standard equations for water[1], R134a[2], R32[3], and R143a[4] and
equations from the literature for ethane[5], propane[6], R125[7],
ammonia[8], carbon dioxide[9], and others
High accuracy MBWR equations of state, including the international
standard EOS for R123[10]
The Bender equation of state for several of the "older" refrigerants,
including R14[11], R114[11], and RC318[11]
An extended corresponding states model for fluids with limited data
An excess Helmholtz energy model for mixture properties
Experimentally based values of the mixture parameters are available for
hundreds of mixtures
Viscosity and thermal conductivity are based on fluid-specific correlations
(where available), a modification of the extended corresponding states
model, or the friction theory model
Available properties:
Thermodynamic properties: Density (molar volume), fugacity, Enthalpy,
Entropy, Gibbs free energy
Transport properties: Thermal conductivity, Viscosity, Surface Tension
Important: For components that are not included in the valid REFPROP
component list, the Aspen Physical Property System will ignore these
components and calculate the physical properties for the remaining
components that are on the list. Pure component properties of the non-
REFPROP components will be missing. For mixture properties, the mole
fractions used in the calculations will be re-normalized.
Cautions
Enthalpy, entropy and Gibbs free energy values obtained from Aspen Plus
using REFPROP model are different from those calculated using the
standalone REFPROP program distributed by NIST. This is because of the
difference in the reference states used in the two programs. In Aspen Plus,
the reference state is ideal gas at 298.15 K and 1 atm, while in the
standalone REFPROP program [12], [13], the reference states are set up
differently. Please see the information on reference state given below.
However, the calculation of the departure function of these properties is the
same.
The REFPROP model is designed to provide the most accurate thermophysical
properties currently available for pure fluids and their mixtures. The present
version is limited to vapor-liquid equilibrium (VLE) only and does not address
liquid-liquid equilibrium (LLE), vapor-liquid-liquid equilibrium (VLLE) or other
complex forms of phase equilibrium. The model does not know the location of
the freezing line for mixtures. Certain mixtures can potentially enter into
these areas without giving warnings to the user.
Some mixtures have components with a wide range of volatilities, as
indicated by a critical temperature ratio greater than 2. Certain calculations,
especially saturation calculations, may fail without generating warnings.
Two equations of state are available for hydrogen to account for the different
quantum states of the molecule. These are implemented as two different
components:
Normal hydrogen should be used in applications where it was created and
stored at 250 K or above, or when it was cooled to below 250 K and
stored without a catalyst for less than a day.
Para hydrogen should be used where hydrogen was catalyzed or stored for
several days at the normal boiling point (NBP) and used at any
temperature within 1 day of storage at the NBP.
Since the rate of conversion between quantum states is dependent on
temperature, pressure, and the storage container, these values are only
estimates. For more information, see the Jacobsen et al. [14] literature
reference for hydrogen.
Viscosity and thermal conductivity models are not available for some fluids.
Therefore, REFPROP will not be able to return meaningful values for pure or
mixture properties of systems that contain one or more of these fluids. These
fluids are: SO2 (sulfur dioxide), SF6 (sulfur hexafluoride), Propyne, NF3
(nitrogen trifluoride), Fluorine, Deuterium, cyclopropane, carbonyl sulfide,
C5F12 (dodecafluoropentane), C4F10 (decafluorobutane), benzene, toluene,
acetone, R21 (dichlorofluoromethane), R236ea (1,1,1,2,3,3-
hexafluoropropane).
Reference state
The absolute values of enthalpy, entropy, and Gibbs free energy at a single
state point are meaningless. It is only the difference between two different
state points that matter. Thus, the value for a single state point can be set to
any arbitrary value. Many handbooks set the arbitrary state point so that the
values of these properties are positive for most liquid or gas states.
In the Aspen Physical Property System, the reference state on which the
values of the enthalpy and Gibbs free energy are based is:
Setting enthalpy to the ideal gas enthalpy of formation of the component
at 298.15 K and 1 atm (101325 Pa).
Setting Gibbs free energy to the ideal gas Gibbs free energy of formation
of the component at 298.15 K and 1 atm (101325 Pa).
In the REFPROP standalone program, there are three choices for the reference
state on which the values of enthalpy and entropy are based:
Setting enthalpy and entropy to zero for the saturated liquid at the normal
boiling point (designated as NBP).
Setting enthalpy and entropy to zero for the saturated liquid at -40 C
(designated as ASHRAE).
Setting enthalpy to 200 kJ/kg and entropy to 1.0 kJ/(kg-K) for the
saturated liquid at 0 C (designated as IIR).
For detailed information on the reference states in Aspen Plus and REFPROP
standalone program, please see help topics for the respective software.
Components in REFPROP and the valid temperature and pressure
ranges
Component name CAS number Full Chemical Name EOS Temperature and
Pressure Limits
ACETONE 67-64-1 propanone 178.5-550 K, 700 Mpa
AMMONIA 7664-41-7 ammonia 195.495-700 K, 1000
MPa
ARGON 7440-37-1 argon 83.8058-2000 K,1000
MPa
BENZENE 71-43-2 benzene 278.7-635 K, 78 MPa
N-BUTANE 106-97-8 n-butane 134.895-575 K, 69 MPa
1-BUTENE 106-98-9 1-butene 87.8-525 K, 70 MPa
CARBON-DIOXIDE 124-38-9 carbon dioxide 216.592-2000 K, 800
MPa
CARBON-MONOXIDE 630-08-0 carbon monoxide 68.16-500 K, 100 MPa
CARBONYL-SULFIDE 463-58-1 carbon oxide sulfide 134.3-650 K, 50 MPa
CIS-2-BUTENE 590-18-1 cis-2-butene 134.3-525 K, 50 MPa
CYCLOHEXANE 110-82-7 cyclohexane 279.47-700 K, 80 MPa
CYCLOPROPANE 75-19-4 cyclopropane 273-473 K, 28 MPa
N-DECANE 124-18-5 decane 243.5-675 K, 800 MPa
DEUTERIUM 7782-39-0 deuterium 18.71-423 K, 320 Mpa
DIMETHYL-ETHER 115-10-6 ethylene oxide 131.65-525 K, 40 MPa
N-DODECANE 112-40-3 dodecane 263.6-700 K, 700 MPa
Pressure Limits
ETHANE 74-84-0 ethane 90.368-675 K, 900 MPa
ETHANOL 64-17-5 ethyl alcohol 250-650 K, 280 MPa
ETHYLENE 74-85-1 ethene 103.986-450 K, 300 MPa
FLUORINE 7782-41-4 fluorine 53.4811-300 K, 20 MPa
DEUTERIUM-OXIDE 7789-20-0 deuterium oxide 276.97-800 K, 100 MPa
HELIUM-4 7440-59-7 helium-4 2.1768-1500 K, 100 MPa
N-HEPTANE 142-82-5 heptane 182.55-600 K, 100 MPa
N-HEXANE 110-54-3 hexane 177.83-600 K, 100 MPa
HYDROGEN 1333-74-0 hydrogen (normal) 13.957-1000 K, 2000
MPa
HYDROGEN-SULFIDE 7783-06-4 hydrogen sulfide 187.7-760 K, 170 MPa
ISOBUTANE 75-28-5 2-methylpropane 113.73-575 K, 35 MPa
ISOBUTYLENE 115-11-7 2-methyl-1-propene 132.4-550 K, 50 MPa
2-METHYL-PENTANE 107-83-5 2-methylpentane 119.6-550 K, 1000 MPa
2-METHYL-BUTANE 78-78-4 2-methylbutane 112.65-500 K, 1000 MPa
KRYPTON 7439-90-9 krypton 115.775-750 K, 200 MPa
METHANE 74-82-8 methane 90.6941-625 K, 1000
MPa
METHANOL 67-56-1 methanol 175.61-620 K, 800 MPa
NEON 7440-01-9 neon 24.556-700 K, 700 MPa
2,2-DIMETHYL-PROPANE 463-82-1 2,2-dimethylpropane 256.6-550 K, 200 MPa
NITROGEN 7727-37-9 nitrogen 63.151-2000 K, 2200
MPa
NITROGEN-TRIFLUORIDE 7783-54-2 nitrogen trifluoride 85-500 K, 50 MPa
NITROUS-OXIDE 10024-97-2 dinitrogen monoxide 182.33-525 K, 50 MPa
N-NONANE 111-84-2 nonane 219.7-600 K, 800 MPa
N-OCTANE 111-65-9 octane 216.37-600 K, 100 MPa
OXYGEN 7782-44-7 oxygen 54.361-2000 K, 82 MPa
*HYDROGEN-PARA 1333-74-0p parahydrogen 13.803-1000 K, 2000
MPa
N-PENTANE 109-66-0 pentane 143.47-600 K, 100 MPa
DECAFLUOROBUTANE 355-25-9 decafluorobutane 189-500 K, 30 MPa
PERFLUORO-N-PENTANE 678-26-2 dodecafluoropentane 200-500 K, 30 MPa
PROPANE 74-98-6 propane 85.53-625 K, 1000 MPa
PROPYLENE 115-07-1 propene 87.953-575 K, 1000 MPa
METHYL-ACETYLENE 74-99-7 propyne 273-474 K, 32 MPa
SULFUR-DIOXIDE 7446-09-5 sulfur dioxide 197.7-525 K, 35 MPa
SULFUR-HEXAFLUORIDE 2551-62-4 sulfur hexafluoride 223.555-625 K, 150 MPa
TOLUENE 108-88-3 methylbenzene 178-700 K, 500 MPa
TRANS-2-BUTENE 624-64-6 trans-2-butene 167.6-525 K, 50 MPa
TRIFLUOROIODOMETHANE 2314-97-8 trifluoroiodomethane 120-420 K, 20 MPa
WATER 7732-18-5 water 273.16-2000 K, 1000
MPa
Pressure Limits
XENON 7440-63-3 xenon 161.405-750 K, 700 MPa
TRICHLOROFLUOROMETHANE 75-69-4 trichlorofluoromethane 162.68-625 K, 30 MPa
DICHLORODIFLUOROMETHANE 75-71-8 dichlorodifluoromethane 116.099-525 K, 200 MPa
CHLOROTRIFLUOROMETHANE 75-72-9 chlorotrifluoromethane 92-403 K, 35 MPa
CARBON-TETRAFLUORIDE 75-73-0 tetrafluoromethane 120-623 K, 51 MPa
DICHLOROMONOFLUOROMETHA
NE
75-43-4 dichlorofluoromethane 200-473 K, 138 MPa
CHLORODIFLUOROMETHANE 75-45-6 chlorodifluoromethane 115.73-550 K, 60 MPa
TRIFLUOROMETHANE 75-46-7 trifluoromethane 118.02-475 K, 120 MPa
DIFLUOROMETHANE 75-10-5 difluoromethane 136.34-435 K, 70 MPa
METHYL-FLUORIDE 593-53-3 fluoromethane 129.82-425 K, 70 MPa
1,2,2-TRICHLORO-1,1,2-
TRIFLUOROE
76-13-1 1,1,2-trichloro-1,2,2-
trifluoroethane
236.93-525 K, 200 MPa
1,2-DICHLORO-1,1,2,2-
TETRAFLUORO
76-14-2 1,2-dichloro-1,1,2,2-
tetrafluoroethane
273.15-507 K, 21 MPa
CHLOROPENTAFLUOROETHANE 76-15-3 chloropentafluoroethane 173.75-550 K, 60 MPa
PERFLUOROETHANE 76-16-4 hexafluoroethane 173.1-425 K, 50 MPa
1,1-DICHLORO-2,2,2-
TRIFLUOROETHA
306-83-2 2,2-dichloro-1,1,1-
trifluoroethane
166-600 K, 40 MPa
2-CHLORO-1,1,1,2-
TETRAFLUOROETHA
2837-89-0 1-chloro-1,2,2,2-
tetrafluoroethane
120-470 K, 40 MPa
PENTAFLUOROETHANE 354-33-6 pentafluoroethane 172.52-500 K, 60 MPa
1,1,1,2-TETRAFLUOROETHANE 811-97-2 1,1,1,2-tetrafluoroethane 169.85-455 K, 70 MPa
1,1-DICHLORO-1-
FLUOROETHANE
1717-00-6 1,1-dichloro-1-fluoroethane 169.68-500 K, 400 MPa
1-CHLORO-1,1-
DIFLUOROETHANE
75-68-3 1-chloro-1,1-difluoroethane 142.72-470 K, 60 MPa
1,1,1-TRIFLUOROETHANE 420-46-2 1,1,1-trifluoroethane 161.34-650 K, 100 MPa
1,1-DIFLUOROETHANE 75-37-6 1,1-difluoroethane 154.56-500 K, 60 MPa
OCTAFLUOROPROPANE 76-19-7 octafluoropropane 125.45-440 K, 20 MPa
1,1,1,2,3,3,3-
HEPTAFLUOROPROPANE
431-89-0 1,1,1,2,3,3,3-
heptafluoropropane
146.35-475 K, 60 MPa
1,1,1,2,3,3-
HEXAFLUOROPROPANE
431-63-0 1,1,1,2,3,3-
hexafluoropropane
242-500 K, 60 MPa
*HFC-236FA 690-39-1 1,1,1,3,3,3-
hexafluoropropane
179.52-500 K, 40 MPa
1,1,2,2,3-
PENTAFLUOROPROPANE
679-86-7 1,1,2,2,3-
pentafluoropropane
200-500 K, 60 MPa
1,1,1,3,3-
PENTAFLUOROPROPANE
460-73-1 1,1,1,3,3-
pentafluoropropane
171.05-440 K, 200 MPa
*1,1,1,3,3-
PENTAFLUOROBUTANE
406-58-6 1,1,1,3,3-pentafluorobutane 239-500 K, 35 MPa
OCTAFLUOROCYCLOBUTANE 115-25-3 octafluorocyclobutane 233.35-623 K, 60 MPa
*Only in NIST database.
References
[1] Wagner W., Pruss A., "The IAPWS Formulation 1995 for the
Thermodynamic Properties of Ordinary Water Substance for General and
Scientific Use" J. Phys. Chem. Ref. Data, 2002, Vol. 31, No. 2, 387-535
[2] Tillner-Roth, R. and Baehr, H.D., "An international standard formulation of
the thermodynamic properties of 1,1,1,2-tetrafluoroethane (HFC-134a) for
temperatures from 170 K to 455 K at pressures up to 70 MPa," J. Phys.
Chem. Ref. Data, 1994, Vol. 23, 657-729
[3] Tillner-Roth, R. and Yokozeki, A.,"An international standard equation of
state for difluoromethane (R-32) for temperatures from the triple point at
136.34 K to 435 K and pressures up to 70 MPa," J. Phys. Chem. Ref. Data,
1997, Vol. 25, No. 6, 1273-1328
[4] Lemmon, E.W. and Jacobsen, R.T,"An International Standard Formulation
for the Thermodynamic Properties of 1,1,1-Trifluoroethane (HFC-143a) for
Temperatures from 161 to 450 K and Pressures to 50 MPa," J. Phys. Chem.
Ref. Data, 2000, Vol. 29, No. 4, 521-552
[5] Buecker, D. and Wagner, W. "A Reference Equation of State for the
Thermodynamic Properties of Ethane for Temperatures from the Melting Line
to 675 K and Pressures up to 900 MPa," J. Phys. Chem. Ref. Data, 2006, Vol.
35, No. 1, 205-266
[6] Lemmon, E.W., McLinden, M.O., Wagner, W. to be submitted to J. Phys.
Chem. Ref. Data, 2007.
[7] Lemmon, E.W. and Jacobsen, R.T, "A New Functional Form and New
Fitting Techniques for Equations of State with Application to
Pentafluoroethane (HFC-125)," J. Phys. Chem. Ref. Data, 2005, Vol. 34, No.
1, 69-108
[8] Tillner-Roth, R., Harms-Watzenberg, F., and Baehr, H.D., "Eine neue
Fundamentalgleichung fuer Ammoniak," DKV-Tagungsbericht, 1993, Vol. 20,
167-181
[9] Span, R. and Wagner, W., "A New Equation of State for Carbon Dioxide
Covering the Fluid Region from the Triple-Point Temperature to 1100 K at
Pressures up to 800 MPa," J. Phys. Chem. Ref. Data, 1996, Vol. 25, No. 6,
1509-1596
[10] Younglove, B.A. and McLinden, M.O., "An International Standard
Equation of State for the Thermodynamic Properties of Refrigerant 123 (2,2-
Dichloro-1,1,1-trifluoroethane)," J. Phys. Chem. Ref. Data, 1994, Vol. 23,
731-779
[11] Platzer, B., Polt, A., and Maurer, G., "Thermophysical properties of
refrigerants," Berlin: Springer-Verlag, 1990.
[12] Lemmon E.W., Huber M.L., McLinden M.O. NIST Standard Reference
Database 23: Reference Fluid Thermodynamic and Transport Properties-
REFPROP, Version 8.0, National Institute of Standards and Technology,
Standard Reference Data Program, Gaithersburg, 2007.
[13] NIST REFPROP website: http://www.nist.gov/srd/nist23.htm
[14] Jacobsen R.T., Leachman J.W., Penoncello S.G., Lemmon E.W. "Current
Status of Thermodynamic Properties of Hydrogen," International Journal of
Thermophysics, 2007, Vol. 28, No. 3, 758-772

Property Methods for
Petroleum Mixtures
The property methods in the following table are designed for mixtures of
hydrocarbons and light gases. K-value models and liquid fugacity correlations
are used at low and medium pressures. Petroleum-tuned equations of state
are used at high pressures. The hydrocarbons can be from natural gas or
crude oil: that is, complex mixtures that are treated using
pseudocomponents. These property methods are often used for refinery
applications. Density and transport properties are calculated by API
procedures when possible.
The following table lists the common and the distinctive models of the
property methods. The parameter requirements of the distinctive models are
given in the tables labeled Parameters Required for the CHAO-SEA Property
Method (see CHAO-SEA), Parameters Required for the GRAYSON Property
Method (see GRAYSON), Parameters Required for the PENG-ROB Property
Method (see PENG-ROB), and Parameters Required for the RK-SOAVE
Property Method (see RK-SOAVE).
Parameter requirements for the common models are in the table labeled
Parameters Required for Common Models. For details on these models, see
Property Methods for Petroleum Mixtures
Liquid Fugacity and K-Value Models
Property Method Name Models
BK10 Braun K10 K-value model
CHAO-SEA Chao-Seader liquid fugacity, Scatchard-Hildebrand
activity coefficient
GRAYSON/GRAYSON2 Grayson-Streed liquid fugacity, Scatchard-
Hildebrand activity coefficient
MXBONNEL Maxwell-Bonnell liquid fugacity
Petroleum-Tuned Equations of State
PENG-ROB Peng-Robinson
RK-SOAVE Redlich-Kwong-Soave
SRK Soave-Redlich-Kwong
SRK-KD SRK-Kabadi-Danner
SRK-ML SRK-ML
Common Models for Property Methods for Petroleum
Mixtures
Property Model
Liquid enthalpy Lee-Kesler
Liquid molar volume API
Vapor viscosity Chapman-Enskog-Brokaw
Vapor thermal conductivity Stiel-Thodos/DIPPR
Vapor diffusivity Dawson-Khoury-Kobayashi
Surface tension API surface tension
Liquid viscosity API
Liquid thermal conductivity Sato-Riedel/DIPPR
Liquid diffusivity Wilke-Chang

Liquid Fugacity and K-Value Model Property
Methods
The BK10 property method is generally used for vacuum and low pressure
applications (up to several atm). The CHAO-SEA property method and the
GRAYSON property method can be used at higher pressures. GRAYSON has
the widest ranges of applicability (up to several tens of atm). For hydrogen-
rich systems, GRAYSON is recommended.
These property methods are less suited for high-pressure applications in
refinery (above about 50 atm). Petroleum-tuned equation of state property
methods are preferred for high pressures.
These property methods are not suited for conditions close to criticality, as
occur in light oil reservoirs, transportation of gas by pipelines, and in some
gas processing applications. Standard equations of state for non-polar
components are preferred. If polar compounds are present, such as in gas
treatment, use flexible and predictive equations of state for polar compounds.

BK10
The BK10 property method uses the Braun K-10 K-value correlations. The
correlations were developed from the K10 charts for both real components
and oil fractions. The real components include 70 hydrocarbons and light
gases. The oil fractions cover boiling ranges 450 700 K (350 800F).
Proprietary methods were developed to cover heavier oil fractions.
Mixture Types
Best results are obtained with purely aliphatic or purely aromatic mixtures
with normal boiling points ranging from 450 to 700 K. For mixtures of
aliphatic and aromatic components, or naphtenic mixtures, the accuracy
decreases. For mixtures with light gases, and medium pressures, CHAO-SEA
or GRAYSON are recommended.
Range
The BK10 property method is suited for vacuum and low pressure applications
(up to several atm). For high pressures, petroleum-tuned equations of state
are best suited.
The applicable temperature range of the K10 chart is 133 800 K (-220
980F). It can be used up to 1100 K (1520F).
The parameters for the Braun K-10 are all built-in. You do not need to supply
them. See Parameters Required for Common Models for parameter
requirements of models common to petroleum property methods.

CHAO-SEA
The CHAO-SEA property method uses the:
Chao-Seader correlation for reference state fugacity coefficient
Scatchard-Hildebrand model for activity coefficient
Redlich-Kwong equation of state for vapor phase properties
Lee-Kesler equation of state for liquid and vapor enthalpy
API method for liquid molar volume, viscosity and surface tension
Models listed in the tables labeled Parameters Required for the CHAO-SEA
Property Method (see below), and Parameters Required for Common
Models
The tables labeled Parameters Required for the CHAO-SEA Property Method
and Parameters Required for Common Models provide thermodynamic and
transport property models, and their parameter requirements.
The CHAO-SEA property method is predictive. It can be used for crude
towers, vacuum towers, and some parts of the ethylene process. It is not
recommended for systems containing hydrogen.
Mixture Types
The CHAO-SEA property method was developed for systems containing
hydrocarbons and light gases, such as carbon dioxide and hydrogen sulfide,
but with the exception of hydrogen. If the system contains hydrogen, use the
GRAYSON property method.
Range
Use the CHAO-SEA property method for systems with temperature and
pressure limits of:
200 < T < 533 K
0.5 < T
ri
< 1.3
T
rm
< 0.93
P < 140 atm
Where:
T
ri
= Reduced temperature of a component
T
rm
= Reduced temperature of the mixture
Do not use this property method at very high pressures, especially near the
mixture critical point, because of anomalous behavior in these regions.
Parameters Required for the CHAO-SEA Property Method
Thermodynamic
Properties
Models Parameter Requirements
Vapor mixture
Fugacity coefficient,
Density

Enthalpy, entropy,
Gibbs free energy

Redlich-Kwong

Ideal gas heat capacity,
Redlich-Kwong

TC, PC

CPIG or CPIGDP
TC, PC
Liquid mixture
Gibbs free energy

Scatchard-Hildebrand activity
coefficient

Chao-Seader pure component
fugacity coefficient

TC, DELTA, VLCVT1; GMSHVL

TC, PC, OMEGA

GRAYSON/ GRAYSON2
The GRAYSON property method uses the:
Grayson-Streed correlation for reference state fugacity coefficients
Scatchard-Hildebrand model for activity coefficients
Redlich-Kwong equation of state for vapor phase properties
Lee-Kesler equation of state for liquid and vapor enthalpy
API method for liquid molar volume, viscosity and surface tension
The GRAYSON2 property method uses the:
Grayson-Streed correlation with Chao-Seader acentric factors for liquid
fugacities
Scatchard-Hildebrand model for activity coefficients with special handling
for water
Redlich-Kwong equation of state for vapor phase fugacity coefficients
Redlich-Kwong equation of state for liquid and vapor phase properties
(enthalpies and volumes). Water enthalpy calculated from NBS steam
tables
TRAPP model for transport properties
The GRAYSON2 method is provided for compatibility with RT-Opt version 10
simulations. Users building new simulations should use GRAYSON.
Refer to the tables labeled Parameters Required for the GRAYSON Property
Method (below) and Parameters Required for Common Models for
thermodynamic and transport property models, and their parameter
requirements.
The GRAYSON/GRAYSON2 property methods are predictive. They can be used
for crude towers, vacuum towers, and some parts of the ethylene process.
They are recommended for systems containing hydrogen.
Mixture Types
The GRAYSON/GRAYSON2 property methods were developed for systems
containing hydrocarbons and light gases, such as carbon dioxide and
hydrogen sulfide. They are recommended over the CHAO-SEA property
method when the system contains hydrogen.
Range
The GRAYSON/GRAYSON2 property methods should give reasonable results
for temperatures from 60 F to 800 F for pressures up to 3000 psia. They
should be used with caution at pressures above 600 psia and temperatures
below 60 F. These methods are not recommended for modeling separations
of close-boiling components (e.g. isomers). Do not use these property
methods at very high pressures, especially near the mixture critical point,
because of anomalous behavior in these regions.
Parameters Required for the GRAYSON Property Method
Thermodynamic
Properties
Vapor mixture
Density

Enthalpy, entropy,
Gibbs free energy

Redlich-Kwong

Redlich-Kwong

TC, PC

CPIG or CPIGDP
TC, PC
Liquid mixture
Gibbs free energy

coefficient

Grayson-Streed pure
component fugacity coefficient

TC, DELTA, VLCVT1;GMSHVL

TC, PC, OMEGA

MXBONNEL
The MXBONNEL property method uses the:
Ideal gas for vapor fugacity coefficients
Maxwell-Bonnell model for vapor pressure to compute liquid fugacity
coefficient (K-Values)
Soave-Redlich-Kwong equation of state for liquid and vapor phase
properties. Water enthalpy calculated from NBS steam tables.
TRAPP model for transport properties
This method is similar to the BK10 method, except that Maxwell-Bonnell
vapor pressure method is used for all hydrocarbon pseudo-components. For
pure components their standard vapor pressure correlation is used. This
method should only be used in low pressure (below a few atmospheres)
applications.
Mixture Types
MXBONNEL property method can be used for crude towers, vacuum towers,
and some parts of the ethylene process. Best results are obtained for mixture
of hydrocarbons. For mixtures with light gases and medium pressures, CHAO-
SEA or GRAYSON is recommended.
Range
The MXBONNEL property method is suited for vacuum and low pressure
applications (up to several atmospheres). Do not use this property method at
very high pressures, especially near the mixture critical point, because of
anomalous behavior in these regions.

Petroleum-Tuned Equation-of-State
Property Methods
Petroleum-tuned equation-of-state property methods are based on equations
of state for nonpolar compounds with built-in binary parameters. These
property methods use the API/Rackett model for liquid density to overcome
the drawback of poor liquid density calculated by cubic equations of state.
Liquid viscosity and surface tensions are calculated by API models.
Equations of state are comparable in performance when comparing VLE.
BWR-LS is recommended for hydrogen-rich systems.
Property methods based on liquid fugacity correlations or K-value models are
generally preferred for low pressure refinery applications. Petroleum-tuned
equation-of-state models can handle critical points, but some other models of
the property methods (such as liquid density and liquid viscosity) are not
suited for conditions close to criticality, as occur in light oil reservoirs,
transportation of gas by pipe lines, and in some gas processing applications.
For these cases, equation-of-state property methods for high pressure
hydrocarbon applications are preferred. If polar compounds are present, such
as in gas treatment, use flexible and predictive equations of state for polar
compounds.

PENG-ROB
The PENG-ROB property method uses the:
Standard Peng-Robinson cubic equation of state for all thermodynamic
properties except liquid molar volume
API method for liquid molar volume of pseudocomponents and the Rackett
model for real components
Refer to the tables labeled Parameters Required for the PENG-ROB Property
thermodynamic and transport property models, and their required
parameters.
This property method is comparable to the RK-SOAVE property method. It is
recommended for gas-processing, refinery, and petrochemical applications.
Sample applications include gas plants, crude towers, and ethylene plants.
For accurate results in your VLE or LLE calculations, you must use binary
parameters, such as the Aspen Physical Property System built-in binary
parameters. Use the Properties Parameters Binary Interaction PRKBV form to
review available built-in binary parameters. You can also use the Data
Regression System (DRS) to determine the binary parameters from
experimental phase equilibrium data (usually binary VLE data).
By default, this property method uses the literature version of the alpha
function and mixing rules (D.-Y. Peng and D. B. Robinson, "A New Two-
Constant Equation-of-state," Ind. Eng. Chem. Fundam., Vol. 15, (1976), pp.
5964). However, the Peng-Robinson model has been extended to handle
polar components and non-ideal chemical systems as described in the
property model description.
Mixture Types
Use the PENG-ROB property method for nonpolar or mildly polar mixtures.
Examples are hydrocarbons and light gases, such as carbon dioxide, hydrogen
sulfide, and hydrogen. For systems with polar components, use the SR-
POLAR, PRWS, RKSWS, PRMHV2, RKSMHV2, PSRK, WILSON, NRTL, VANLAAR,
or UNIQUAC property methods.
This property method is particularly suitable in the high temperature and high
pressure regions, such as in hydrocarbon processing applications or
supercritical extractions.
This property method can be used for polar, non-ideal chemical mixtures, if
appropriate alpha functions and mixing rules are used. Please refer to the
description of the Peng-Robinson model in the property model description.
Range
You can expect reasonable results at all temperatures and pressures. The
PENG-ROB property method is consistent in the critical region. Therefore, it
does not exhibit anomalous behavior, unlike the activity coefficient property
methods. Results are least accurate in the region near the mixture critical
point.
Parameters Required for the PENG-ROB Property Method
Thermodynamic
Properties
Vapor mixture
Density

Enthalpy, entropy,
Gibbs free energy

Peng-Robinson

Peng-Robinson

TCPR or TC; PCPR or PC;
OMGPR or OMEGA

OMGPR or OMEGA
CPIG or CPIGDP
Thermodynamic
Properties
Liquid mixture

Enthalpy, entropy,
Gibbs free energy

Peng-Robinson

Peng-Robinson

OMGPR or OMEGA CPIG or
CPIGDP

OMGPR or OMEGA CPIG or
CPIGDP

RK-SOAVE
The RK-SOAVE property method uses the:
Redlich-Kwong-Soave (RKS) cubic equation of state for all thermodynamic
properties except liquid molar volume
model for real components
Refer to the tables labeled Parameters Required for the RK-SOAVE Property
thermodynamic and transport property models, and required parameters for
this property method.
This property method is comparable to the PENG-ROB property method. It is
Example applications include gas plants, crude towers, and ethylene plants.
The RK-SOAVE property method has built-in binary parameters, RKSKBV, that
are used automatically in the Aspen Physical Property System.
For accurate results in your VLE and LLE calculations, you must use binary
parameters. You can use the Aspen Physical Property System built-in
parameters. Use the Properties Parameters Binary Interaction RKSKBV-1 form
to review available built-in binary parameters. You can also use the Data
Regression System (DRS) to determine the binary parameters from
experimental phase equilibrium data (usually binary VLE data).
Mixture Types
Use the RK-SOAVE property method for nonpolar or mildly polar mixtures.
sulfide, and hydrogen. For systems with polar components, such as alcohols,
use the SR-POLAR, WILSON, NRTL, VANLAAR, or UNIQUAC property methods.
This property method is particularly suitable in the high temperature and high
pressure regions, such as in hydrocarbon processing applications or
supercritical extractions.
Range
You can expect reasonable results at all temperatures and pressures. The RK-
SOAVE property method is consistent in the critical region. Therefore, unlike
the activity coefficient property methods, it does not exhibit anomalous
behavior. Results are least accurate in the region near the mixture critical
point.
Parameters Required for the RK-SOAVE Property Method
Thermodynamic
Properties
Vapor mixture
Density

Enthalpy, entropy
Gibbs free energy

Redlich-Kwong-Soave

Redlich-Kwong-Soave

TC, PC, OMEGA

CPIG or CPIGDP,
TC, PC, OMEGA
Liquid mixture

Enthalpy, entropy,
Gibbs free energy

Redlich-Kwong-Soave

Redlich-Kwong-Soave

TC, PC, OMEGA

CPIG or CPIGDP
TC, PC, OMEGA

SRK
The SRK property method uses the Soave-Redlich-Kwong (SRK) cubic
equation of state for all thermodynamic properties with option to improve
liquid molar volume using volume correction.
This method has the following options:
Peneloux-Rauzy method for liquid molar volume correction which results
in more accurate liquid molar volume
NBS Steam Table for calculating properties of water for better accuracy
Kabadi-Danner mixing rules when dealing with water-hydrocarbon
systems (See SRK-KD)
Composition-independent fugacity coefficient for faster convergence in
equation-based modeling
Modified l
ij
parameters in the SRK-ML model.
When using the SRK method, please select STEAMNBS as the free-water
method. The NBS steam table provides greater accuracy and SRK is designed
to work with it. The enthalpy, entropy, Gibbs energy, and molar volume of
water are calculated from the steam tables. The total properties are mole-
fraction averages of these values with the properties calculated by the
equation of state for other components. Fugacity coefficient is not affected.
Refer to the tables labeled Parameters Required for the SRK Property Method
below and Parameters Required for Common Models for thermodynamic and
transport property models, and required parameters for this property method.
This property method is comparable to other property methods based on
cubic equations of state. It is recommended for gas-processing, refinery, and
petrochemical applications. Example applications include gas plants, crude
towers, and ethylene plants.
The SRK property method has built-in pure component and binary parameters
for use in modeling the ethylene process. The built-in parameters are stored
in the Ethylene databank. For other systems, you must supply pure
component and binary parameters. You can use the Data Regression System
(DRS) to determine the binary parameters from experimental phase
equilibrium data (binary VLE and LLE data).
Mixture Types
Use the SRK property method for nonpolar or mildly polar mixtures. Examples
are hydrocarbons and light gases, such as carbon dioxide, hydrogen sulfide,
and hydrogen. For systems with polar components, such as alcohols, use the
SR-POLAR, WILSON, NRTL, VANLAAR, or UNIQUAC property methods, or
specify values for the l
ij
parameters. This property method is particularly
suitable in the high temperature and high pressure regions, such as in
hydrocarbon processing applications or supercritical extractions.
With the Kabadi-Danner mixing rules, this property method can be used to
model water-hydrocarbon immiscibility.
Range
You can expect reasonable results at all temperatures and pressures. The SRK
property method is consistent in the critical region. Therefore, unlike the
activity coefficient property methods, it does not exhibit anomalous behavior.
Results are least accurate in the region near the mixture critical point.
Parameters Required for the SRK Property Method
Thermodynamic
Properties
Vapor mixture
Density

Enthalpy, entropy
Gibbs free energy

Soave-Redlich-Kwong

Soave-Redlich-Kwong

SRKTC, SRKPC, SRKOMG

(CPIG or CPIGDP) and
Liquid mixture
Density

Enthalpy, entropy,
Gibbs free energy

Soave-Redlich-Kwong

Soave-Redlich-Kwong



SRK-KD
The SRK-KD property method uses the SRK-Kabadi-Danner property model.
This is equivalent to the SRK property method with the Kabadi-Danner mixing
rules included.
The Kabadi-Danner mixing rules allow this property method to model water-
hydrocarbon immiscibility. These special mixing rules handle the interaction
between water and hydrocarbon components. The interaction is accounted for
by the use of a binary interaction parameter which can be estimated from
group contribution.
Do not use the SRK l
ij
parameters with the Kabadi-Danner mixing rules. Both
these methods model the asymmetric behavior of polar-hydrocarbon
interactions, but they are not designed to be used simultaneously.

SRK-ML
The SRK-ML property method uses the SRK-ML property model. This is
equivalent to the SRK property method with an alternate set of k
ij

parameters, and l
ij
based on the k
ij
.

Common Models
The following table lists the models used in all petroleum property methods
and their parameter requirements.
Parameters Required for Common Models
General
Property/Purpose Parameter
Requirements
Mass balance, Conversion Mass-basisMole-
basis
MW
Conversion Stdvol-basisMole-basis VLSTD
Initialization of Flash calculations PLXANT
Using Free-water option: solubility of water in
organic phase
WATSOL
Enthalpy, enthalpy of reaction DHFORM
Property Models Parameter Requirements
Liquid mixture
Enthalpy,
Entropy

Density

Ideal heat capacity,
Lee-Kesler

Real components:
Rackett

Pseudo components: API

(CPIG or CPIGDP)
TC, PC, OMEGA

TC, PC, (VC or VCRKT),
(ZC or RKTZRA)
TB, API
Property Models Paremeter Requirements
Vapor mixture
Viscosity

Thermal
Conductivity

Diffusivity

Chapman-Enskog-Brokaw/
DIPPR

Stiel-Thodos/
DIPPR

Dawson Khoury-Kobayashi

MW, (MUP and (STKPAR or
LJPAR)) or MUVDIP

MW or KVDIP (and vapor
viscosity parameters)

MW, MUP, (STKPAR or LJPAR),
VC
Liquid mixture
Viscosity

Thermal
Conductivity

Diffusivity

API

Sato-Riedel/
DIPPR

Wilke-Chang

TB, API

(MW, TB, TC) or
KLDIP

MW, VB
Surface tension API TB, TC, SG

Equation-of-State Property
Methods for High-Pressure
Hydrocarbon Applications
The following table, Equation of State Property Methods for Hydrocarbons at
High Pressure, lists property methods for mixtures of hydrocarbons and light
gases. The property methods can deal with high pressures and temperatures,
and mixtures close to their critical point (for example, pipeline transportation
of gas or supercritical extraction). All thermodynamic properties of vapor and
liquid phases are calculated from the equations of state. (See Equation of
State Method in Overview of Aspen Physical Property Methods). The TRAPP
models for viscosity and thermal conductivity can describe the continuity of
gas and liquid beyond the critical point, comparable to an equation of state.
The hydrocarbons can be from complex crude or gas mixtures treated using
pseudocomponents. But the property methods for petroleum mixtures are
better tuned for these applications at low to medium pressures. Unless you
use fitted binary interaction parameters, no great accuracy should be
expected close to the critical point. Liquid densities are not accurately
predicted for the cubic equations of state.
In the presence of polar components (for example, in gas treatment), flexible
and predictive equations of state should be used. For mixtures of polar and
nonpolar compounds at low pressures, use an activity-coefficient-based
property method.
The following table lists the common and distinctive models of the property
methods BWR-LS, LK-PLOCK, PR-BM, and RKS-BM. The parameter
requirements of the common models are given in the table labeled
Parameters Required for Common Models. The parameter requirements for
the distinctive models are in the tables labeled Parameters Required for the
BWR-LS Property Method (see BWR-LS) , Parameters Required for the BWRS
Property Method (see BWRS) , Parameters Required for the LK-PLOCK
Property Method (see LK-PLOCK) , Parameters Required for the PR-BM
Property Method (see PR-BM) , and Parameters Required for the RKS-BM
Property Method (see RKS-BM) .
Equation-of-State Property Methods for Hydrocarbons at
High Pressure
BWR-LS BWR-Lee-Starling
BWRS Benedict-Webb-Rubin-Starling
LK-PLOCK Lee-Kesler-Plcker
PR-BM Peng-Robinson-Boston-Mathias
RKS-BM Redlich-Kwong-Soave-Boston-Mathias

Property Common Models
Vapor viscosity TRAPP
Vapor thermal conductivity TRAPP
Surface tension API surface tension
Liquid viscosity TRAPP
Liquid thermal conductivity TRAPP

BWR-LS
The BWR-LS property method is based on the BWR-Lee-Starling equation of
state. It is the generalization (in terms of pure component critical properties)
of the Benedict-Webb-Rubin virial equation of state. The property method
uses the equation of state for all thermodynamic properties. Refer to the table
Parameters Required for the BWR-LS Property Method (below) and
Parameters Required for Common Models for thermodynamic and transport
property models and their parameter requirements.
The BWR-LS property method is comparable to PENG-ROB, RK-SOAVE, and
LK-PLOCK for phase equilibrium calculations, but is more accurate than PENG-
ROB and RK-SOAVE for liquid molar volume and enthalpy. You can use it for
gas processing and refinery applications. It is suited for hydrogen-containing
systems, and has shown good results in coal liquefaction applications.
For accurate results, use the binary interaction parameters. Built-in binary
parameters BWRKV and BWRKT are available for a large number of
component pairs. The Aspen Physical Property System uses these binary
parameters automatically. Use the Properties | Parameters | Binary
Interaction | BWRKV-1 and BWRKT-1 forms to review available built-in
binary parameters. You can also use the Data Regression System (DRS) to
determine the binary parameters from experimental phase equilibrium data
(usually binary VLE data).
Mixture Types
Use the BWR-LS property method for nonpolar or slightly polar mixtures, and
light gases. Asymmetric interactions between long and short molecules are
well predicted.
Range
You can expect reasonable results up to medium pressures. At very high
pressures, unrealistic liquid-liquid demixing may be predicted. High pressure
liquid-liquid demixing occurs between short and long chain hydrocarbons and
also, for example, between carbon dioxide and longer hydrocarbon chains at
high pressures.
Parameters Required for the BWR-LS Property Method
Thermodynamic
Properties
Vapor mixture
Density

Enthalpy,
Entropy,
Gibbs energy

BWR-Lee-Starling

BWR-Lee-Starling

TC, VC, OMEGA

TC, VC, OMEGA
Liquid mixture
Density

Enthalpy,
Entropy,
Gibbs energy

BWR-Lee-Starling

BWR-Lee-Starling

TC, VC, OMEGA

TC, VC, OMEGA

BWRS
The BWRS property method is based on the Benedict-Webb-Rubin-Starling
equation of state with optional pure-component and binary interaction
parameters. This equation has eleven pure-component parameters along with
binary interaction parameters. These parameters are obtained from
multiproperty (vapor-liquid-equilibrium, enthalpy, PVT, etc.) data regressions.
Parameters for chemicals common to natural gas mixtures are available from
Starling (1973). If pure-component parameters are not supplied, they are
estimated with correlations proposed by Starling. The property method uses
the equation of state for all thermodynamic properties. Refer to the table
labeled Parameters Required for the BWRS Property Method (below) and
Parameters Required for Common Models for thermodynamic and transport
property models and their parameter requirements.
The BWRS property method is comparable to PENG-ROB, RK-SOAVE, BWR-LS
and LK-PLOCK for phase equilibrium calculations, but is more accurate than
PENG-ROB and RK-SOAVE for liquid molar volume and enthalpy. You can use
it for gas processing and refinery applications. It is suited for reduced
temperatures as low as T
r
= 0.3 and reduced densities as great as
r
= 3.0. It
can be used for light hydrocarbons in the cryogenic liquid region in addition to
higher temperature regions.
For accurate results, use the binary interaction parameters. The Aspen
Physical Property System does not have built-in binary parameters. You can
use the Data Regression System (DRS) to determine the binary parameters
from experimental phase equilibrium data (usually binary VLE data).
The BWRS method is suitable when you need very high accuracy in pure
component properties. When good parameter values are given, this method
can calculate very accurate properties (vapor pressure, molar volume, and
enthalpy) for pure components. The model is also very good for light
hydrocarbon systems and light gases such as N2, CO2, and H2S when the
binary parameters are given.
When water is present, by default BWRS uses the steam table to calculate the
enthalpy, entropy, Gibbs energy, and molar volume of water. The total
properties are mole-fraction averages of these values with the properties
calculated by the equation of state for other components. Fugacity coefficient
is not affected. An option code can disable this use of the steam table.
Mixture Types
Use the BWRS property method for non-polar or slightly polar mixtures, and
light gases. Examples are hydrocarbons and light gases, such as carbon
dioxide, hydrogen sulfide, and nitrogen.
Range
BWRS property method is consistent in the critical region. It does not exhibit
anomalous behavior, unlike the activity coefficient property methods. Results
are least accurate in the region near the mixture critical point.
Parameters Required for the BWRS Property Method
Thermodynamic
Properties
Vapor mixture
Density

Enthalpy,
Entropy,
Gibbs energy

Benedict-Webb-Rubin-Starling


BWRSTC, BWRSVC, BWRSOM

Liquid mixture
Density

Enthalpy,
Entropy,
Gibbs energy




Reference: K. E. Starling, "Fluid Themodynamic Properties for Light Petroleum
Systems", Gulf Publishing Co., Houston, Texas (1973).

LK-PLOCK
The LK-PLOCK property method is based on the Lee-Kesler-Plcker equation
of state, which is a virial-type equation. LK-PLOCK uses the:
EOS to calculate all thermodynamic properties except liquid molar volume
of mixtures
model for real components, in mixtures
You can use LK-PLOCK for gas-processing and refinery applications, but the
RK-SOAVE or the PENG-ROB property methods are preferred.
Refer to the tables labeled Parameters Required for the LK-PLOCK Property
thermodynamic and transport property models, and their parameter
requirements.
For accurate results in VLE calculations, use binary parameters. Built-in binary
parameters LKPKIJ are available for a large number of component pairs. The
Aspen Physical Property System uses these binary parameters automatically.
Use the Properties Parameters Binary Interaction LKPKIJ-1 form to review
available built-in binary parameters. You can also use the Data Regression
System (DRS) to determine the binary parameters from experimental phase
equilibrium data (usually binary VLE data).
This property method also has built-in correlations for estimating binary
parameters among the components CO, CO
2
, N
2
, H
2
, CH
4
, alcohols, and
hydrocarbons. Components not belonging to the classes listed above are
assumed to be hydrocarbons.
Mixture Types
Use the LK-PLOCK property method for nonpolar or mildly polar mixtures.
sulfide, and hydrogen.
Range
You can expect reasonable results at all temperatures and pressures. The LK-
PLOCK property method is consistent in the critical region. It does not exhibit
anomalous behavior, unlike the activity coefficient property methods. Results
are least accurate in the region near the mixture critical point.
Parameters Required for the LK-PLOCK Property Method
Thermodynamic
Properties
Vapor mixture
Density

Enthalpy, entropy
Gibbs free energy

Lee-Kesler-Plcker

Lee-Kesler-Plcker

TC, PC, VC, OMEGA

(CPIG or CPIGDP)
and TC, PC, VC, OMEGA
Liquid mixture

Density

Enthalpy, entropy
Gibbs free energy

Lee-Kesler-Plcker

Rackett/API

Lee-Kesler-Plcker

TC, PC, VC, OMEGA

TB, API, TC, PC, RKTZRA

(CPIG or CPIGDP)
and TC, PC, VC, OMEGA

PR-BM
The PR-BM property method uses the Peng Robinson cubic equation of state
with the Boston-Mathias alpha function for all thermodynamic properties.
Refer to the tables labeled Parameters Required for the PR-BM Property
parameters.
This property method is comparable to the RKS-BM property method. It is
Sample applications include gas plants, crude towers, and ethylene plants.
For accurate results in your VLE calculations, you must use binary
parameters. The Aspen Physical Property System does not have built-in
binary parameters for this property method.
Mixture Types
Use the PR-BM property method for nonpolar or mildly polar mixtures.
Range
You can expect reasonable results at all temperatures and pressures. The PR-
BM property method is consistent in the critical region. Results are least
accurate in the region near the mixture critical point.
Parameters Required for the PR-BM Property Method
Thermodynamic
Properties
Vapor or liquid
mixture
Density

Enthalpy, entropy,
Gibbs free energy

Peng-Robinson

Peng-Robinson

TCPR, PCPR, OMEGA

CPIG or CPIGDP,
TCPR, PCPR, OMEGA

RKS-BM
The RKS-BM property method uses the Redlich-Kwong-Soave (RKS) cubic
equation of state with Boston-Mathias alpha function for all thermodynamic
properties.
This property method is comparable to the PR-BM property method. It is
Example applications include gas plants, crude towers, and ethylene plants.
For accurate results in your VLE calculations, you must use binary
parameters. The Aspen Physical Property System does not have built-in
binary parameters for this property method.
Mixture Types
Use the RKS-BM property method for nonpolar or mildly polar mixtures.
Range
RKS-BM property method is consistent in the critical region. Results are least
accurate in the region near the mixture critical point.
Refer to the tables labeled Parameters Required for the RKS-BM Property
parameters.
Parameters Required for the RKS-BM Property Method
Thermodynamic
Properties
Vapor or liquid
mixture
Density

Enthalpy, entropy,
Gibbs free energy

Redlich-Kwong-Soave

Redlich-Kwong-Soave

TCRKS, PCRKS, OMGRKS

CPIG or CPIGDP,
TCRKS, PCRKS, OMGRKS

Common Models
The following table lists the models common to equation-of-state property
methods for highpressure hydrocarbon applications and their parameter
requirements.
Parameters Required for Common Models
General
Mass balance,
Conversion Mass-basisMole-basis
MW
basis
VLSTD
Using Free-water option: solubility
of water in organic phase
WATSOL
Transport
Property Models Parameter
Requirements
Vapor Mixture
Viscosity


Diffusivity

TRAPP

TRAPP

Dawson-Khoury-
Kobayashi

TC, PC, OMEGA

TC, PC, OMEGA

MW, MUP, (STKPAR or
LJPAR), VC
Surface tension API TB, TC, SG
Liquid mixture
Viscosity
Diffusivity

TRAPP
TRAPP
Wilke-Chang

TC, PC, OMEGA
TC, PC, OMEGA
MW, VB

Flexible and Predictive
Equation-of-State Property
Methods
The table labeled Flexible and Predictive Equation-of-State Property Methods
(below) lists property methods for mixtures of polar and non-polar
components and light gases. The property methods can deal with high
pressures and temperatures, mixtures close to their critical point, and liquid-
liquid separation at high pressure. Examples of applications are gas drying
with glycols, gas sweetening with methanol, and supercritical extraction.
Pure component thermodynamic behavior is modeled using the Peng-
Robinson or Redlich-Kwong-Soave equations of state. They are extended with
flexible alpha-functions with up to three parameters, for very accurate fitting
of vapor pressures. This is important in separations of very closely boiling
systems and for polar compounds. In some cases they are extended with a
volume translation term for accurate fitting of liquid densities (see the table
labeled Flexible and Predictive Equation-of-State Property Methods below).
Parameters for the Schwartzentruber-Renon and Mathias-Copeman alpha
functions are available for many components in the PURECOMP databank.
Mixing rules for these models vary. Extended classical mixing rules are used
for fitting hydrogen-rich systems or systems with strong size and shape
asymmetry (Redlich-Kwong-Aspen). Composition and temperature-dependent
mixing rules fit strongly non-ideal high pressure systems (SR-POLAR).
Modified Huron-Vidal mixing rules can predict non-ideality at high pressure
from low-pressure (group-contribution) activity coeffient models (Wong-
Sandler, MHV2, PSRK). The predictive capabilities of modified Huron-Vidal
mixing rules are superior to the predictive capabilities of SR-POLAR. The
differences among capabilities of the modified Huron-Vidal mixing rules are
small (see Physical Property Models).
The Wong-Sandler, MHV2, and Holderbaum-Gmehling mixing rules use
activity coefficient models to calculate excess Gibbs or Helmholtz energy for
the mixing rules. The property methods with these mixing rules use the
UNIFAC or Lyngby modified UNIFAC group contribution models. Therefore,
they are predictive. You can use any Aspen Physical Property System activity
coefficient models with these mixing rules, including user models. Use the
Properties Methods Models sheet to modify the property method. See
Modifying and Creating Property Methods for details on how to modify a
property method.
The Chung-Lee-Starling models for viscosity and thermal conductivity can
describe the continuity of gas and liquid beyond the critical point. This is
comparable to an equation of state. These models can fit the behavior of
polar and associating components. Details about the pure component models
and mixing rules are found in Physical Property Models.
For mixtures of polar and non-polar compounds at low pressures, activity
coefficient models are preferred. For non-polar mixtures of petroleum fluids
and light gases at low to medium pressures, the property methods for
petroleum mixtures are recommended. The flexible and predictive equations
of state are not suited for electrolyte solutions.
The following table, Flexible and Predictive Equation-of-State Property
Methods, lists flexible and predictive equation-of-state property methods, the
distinctive equation-of-state models on which they are based, and some of
their characteristics. The table also gives the models that the property
methods have in common. Parameter requirements of the common models
are given in the table labeled Parameters Required for Common Flexible and
Predictive Models. Parameter requirements for the distinctive models are in
the tables labeled Parameters Required for the PRMHV2 Property Method (see
PRMHV2), Parameters Required for the PRWS Property Method (see PRWS),
Parameters Required for the PSRK Property Method (see PSRK), Parameters
Required for the RK-ASPEN Property Method (RK-ASPEN), Parameters
Required for the RKSMHV2 Property Method (see RKSMHV2), Parameters
Required for the RKSWS Property Method (see RKSWS), and Parameters
Required for the SR-POLAR Property Method (see SR-POLAR).
Flexible and Predictive Equation-of-State Property
Methods
Property Method
Name
Equation of State Volume
Shift
Mixing Rule Predictive
PC-SAFT Copolymer PC-SAFT
PRMHV2 Peng-Robinson MHV2 X
PRWS Peng-Robinson Wong-Sandler X
PSRK Redlich-Kwong-
Soave
Holderbaum-Gmehling X
RK-ASPEN Redlich-Kwong-
Soave
Mathias
RKSMHV2 Redlich-Kwong-
Soave
MHV2 X
RKSWS Redlich-Kwong-
Soave
Wong-Sandler X
SR-POLAR Redlich-Kwong-
Soave
X Schwarzentruber-
Renon

An X in the Volume Shift column indicates volume shift is included in the
property method.
An X in the Predictive column indicates that the property method is predictive.
Vapor viscosity Chung-Lee-Starling
Vapor thermal conductivity Chung-Lee-Starling
Surface tension Hakim-Steinberg-Stiel/DIPPR
Liquid viscosity Chung-Lee-Starling
Thermal conductivity Chung-Lee-Starling
Liquid diffusivity Wilke-Chang liquid

PC-SAFT: Copolymer PC-SAFT
EOS Property Method
The PC-SAFT method represents the copolymer PC-SAFT EOS model
developed by Sadowski and co-workers (Gross and Sadowski, 2001, 2002a,
2002b; Gross et al., 2003; Becker et al., 2004; Kleiner et al., 2006). Unlike
the POLYPCSF method, the copolymer PC-SAFT includes the association and
polar terms and does not apply mixing rules to calculate the copolymer
parameters from its segments. Its applicability covers fluid systems from
small to large molecules, including normal fluids, water, alcohols, and
ketones, polymers and copolymers and their mixtures.
The following table lists the physical property route structure for the PC-SAFT
property method:
Vapor
Property
Name
Route ID Model Name Description
PHIVMX PHIVMXPA ESPSAFT Copolymer PCSAFT
HVMX HVMXPA ESPSAFT Copolymer PCSAFT
GVMX GVMXPA ESPSAFT Copolymer PCSAFT
SVMX SVMXPA ESPSAFT Copolymer PCSAFT
VVMX VVMXPA ESPSAFT Copolymer PCSAFT
MUVMX MUVMX02 MUV2DNST Dean-Stiel
KVMX KVMX02 KV2STLTH Stiel-Thodos
DVMX DVMX02 DV1DKK Dawson-Khoury-Kobayashi
PHIV PHIVPA ESPSAFT0 Copolymer PCSAFT
HV HVPA ESPSAFT0 Copolymer PCSAFT
GV GVPA ESPSAFT0 Copolymer PCSAFT
SV SVPA ESPSAFT0 Copolymer PCSAFT
VV VVPA ESPSAFT0 Copolymer PCSAFT
DV DV01 DV0CEWL Chapman-Enskog-Wilke-Lee
MUV MUV01 MUV0BROK Chapman-Enskog-Brokaw
KV KV01 KV0STLTH Stiel-Thodos

Liquid
Property
Name
PHILMX PHILMXPA ESPSAFT Copolymer PCSAFT
HLMX HLMXPA ESPSAFT Copolymer PCSAFT
GLMX GLMXPA ESPSAFT Copolymer PCSAFT
SLMX SLMXPA ESPSAFT Copolymer PCSAFT
VLMX VLMXPA ESPSAFT Copolymer PCSAFT
MULMX MULMX13 MUPOLY, MULMH Aspen, Modified Mark-
Houwink/van Krevelen, Andrade
KLMX KLMXVKTR KLMXVKTR Vredeveld mixing, Modified van
Krevelen, TRAPP
DLMX DLMX02 DL1WCA Wilke-Chang-Andrade
SIGLMX SIGLMX01 SIG2HSS Hakim-Steinberg-Stiel, Power Law
Mixing
PHIL PHILPA ESPSAFT0 Copolymer PCSAFT
HL HLPA ESPSAFT0 Copolymer PCSAFT
GL GLPA ESPSAFT0 Copolymer PCSAFT
SL SLPA ESPSAFT0 Copolymer PCSAFT
VL VLPA ESPSAFT0 Copolymer PCSAFT
Liquid
Property
Name
DL DL01 DL0WCA Wilke-Chang-Andrade
MUL MULMH MUL0MH Modified Mark-Houwink/van
Krevelen, Andrade
KL KL0VKTR KL0VKTR Modified van Krevelen, TRAPP

Solid
Property
Name
HSMX HSMXDVK HS0DVK Ideal mixing, van Krevelen
GSMX GSMXDVK GS0DVK Ideal mixing, van Krevelen
SSMX SSMXDVK HS0DVK,
GS0DVK
Ideal mixing, van Krevelen
VSMX VSMXDVK VS0DVK,
VS0POLY
van Krevelen, Polynomial
HS HSDVK HS0DVK van Krevelen
GS GSDVK GS0DVK van Krevelen
SS SSDVK HS0DVK,
GS0DVK
van Krevelen
VS VSDVK VS0DVK,
VS0POLY
van Krevelen, Polynomial

Option Codes for PC-SAFT
The copolymer PC-SAFT has three option codes.
Option code 1. The user can use this option code to specify the copolymer
type. The default type is the random copolymer (0). Other types are the
alternative copolymer (1) and the block copolymer (2). All other values are
assigned to the random copolymer.
Option code 2. This option code is restricted to the Sadowskis copolymer
model in which a copolymer must be built only by two different types of
segments (Gross and Sadowski, 2003; Becker et al., 2004). In order to use
the Sadowskis copolymer model, this option code must be set to one.
Option code 3. The user can use this option code to turn off the association
term from the copolymer PC-SAFT model by setting a non-zero value.

Sample Calculation Results for Copolymer
PC-SAFT
In Figure 1, Aspen Plus applies the PC-SAFT EOS model to calculate both
vapor-liquid and liquid-liquid equilibria for methanol-cyclohexane mixtures at
p = 1.013 bar. This mixture exhibits an azeotropic vapor-liquid equilibrium at
higher temperatures and shows a liquid-liquid equilibrium at lower
temperatures. Both pure and binary parameters used are taken directly from
the paper by Gross and Sadowski (2002b). The results show that the PC-SAFT
model with the association term included can correlate phase equilibrium data
well for associating mixtures.

Figure 1. Isobaric vapor-liquid and liquid-liquid equilibria of methanol-
cyclohexane at = 1.013 bar. Experimental data are taken from Jones and
Amstell (1930) and Marinichev and Susarev (1965).
Figure 2 shows a model calculation for HDPE-Hexane mixtures. This system
exhibits both lower critical solution temperature (LCST) and upper critical
solution temperature (UCST) at p = 50 bar. The pure parameters are taken
directly from papers Gross and Sadowski (2001; 2002a). The binary
parameter between hexane and ethylene segment is set to 0.012. The phase
equilibrium calculations are carried by Flash3 block with Gibbs flash algorithm
in Aspen Plus.

Figure 2. Liquid-liquid equilibria of HDPE-Hexane mixtures in a weight
fraction-pressure plot by PC-SAFT EOS model. It shows both lower critical
solution temperature (LCST) and upper critical solution temperature (UCST).
Figure 3 shows the vapor-liquid equilibrium of the mixture water-acetone at p
= 1.703 bar. The dashed line represents PC-SAFT calculations where water is
treated as an associating component and acetone as a polar component; the
cross association in the mixture is not considered (
ij
= -0.15). The solid line
represents PC-SAFT calculations where the cross association between water
and acetone is accounted for (
ij
= -0.055) using a simple approach by
Sadowski & Chapman et al. (2006). In this approach, the association energy
and effective volume parameters of the non-associating component (acetone)
are set to zero and to the value of the associating component (water),
respectively. Further, the polar component is represented by the three pure-
component parameters without using the dipolar model.

Figure 3. Vapor-liquid equilibrium of the mixture water-acetone at p = 1.703
bar. Experimental data are taken from Othmer and Morley (1946).
Figure 4 shows the liquid-liquid equilibria of polypropylene (PP)-n-pentane at
three temperatures in a pressure-weight fraction plot. The weight average
molecular weight of PP is M
w
= 50.4 kg/mol, M
w
/M
n
= 2.2. Both pure and
binary parameters used are taken directly from the paper by Gross and
Sadowski (2002a).

Figure 4. Liquid-liquid equilibria of PP-n-Pentane at three different
temperatures. Comparison of experimental cloud points (Martin et al., 1999)
to PC-SAFT calculations (
ij
= 0.0137). The polymer was assumed to be
monodisperse at M
w
= 50.4 kg/mol.
References
Gross, J., & Sadowski, G. (2001). Perturbed-Chain SAFT: An Equation of State
Based on a Perturbation Theory for Chain Molecules. Ind. Eng. Chem. Res.,
40, 1244-1260.
Gross, J., & Sadowski, G. (2002a). Modeling Polymer Systems Using the
Perturbed-Chain Statistical Associating Fluid Theory Equation of State. Ind.
Eng. Chem. Res., 41, 1084-1093.
Gross, J., & Sadowski, G. (2002b). Application of the Perturbed-Chain SAFT
Equation of State to Associating Systems. Ind. Eng. Chem. Res., 41, 5510-
5515.
Kleiner, M., Tumakaka, F., Sadowski, G., Dominik, A., Jain, S., Bymaster, A.,
& Chapman, W. G. (2006). Thermodynamic Modeling of Complex Fluids using
PC-SAFT. Final Report for Consortium of Complex Fluids. Universitt
Dortmund & Rice University.
Martin, T. M., Lateef, A. A., & Roberts, C. B. (1999). Measurements and
modeling of cloud point behavior for polypropylene/n-pentane and
polypropylene/n-pentane/carbon dioxide mixtures at high pressures. Fluid
Phase Equilibria, 154, 241.
Othmer, D. F., & Morley, F. R. (1946). Composition of Vapors from Boiling
Binary Solutions Apparatus for Determinations under Pressure. Ind. Eng.
Chem., 38, 751-757.

PRMHV2
The PRMHV2 property method is based on the Peng-Robinson-MHV2
equation-of-state model, which is an extension of the Peng-Robinson equation
of state. The UNIFAC model is used by default to calculate excess Gibbs
energy in the MHV2 mixing rules. Other modified UNIFAC models and activity
coefficient models can be used for excess Gibbs energy.
Besides the acentric factor, up to three polar parameters can be used to fit
more accurately the vapor pressure of polar compounds.
The MHV2 mixing rules predict the binary interactions at any pressure. Using
the UNIFAC model the MHV2 mixing rules are predictive for any interaction
that can be predicted by the UNIFAC model at low pressure.
The minimum parameter requirements of the PRMHV2 property method are
given in the tables labeled Parameters Required for the PRMHV2 Property
Method (below) and Parameters Required for Common Flexible and Predictive
Models. For details about optional parameters, and calculation of pure
component and mixture properties, see Physical Property Models.
Mixture Types
You can use the PRMHV2 property method for mixtures of non-polar and polar
compounds. For light gases UNIFAC does not provide any interaction.
Range
You can use the PRMHV2 property method up to high temperatures and
pressures. You can expect accurate predictions (4% in pressure and 2% in
mole fraction at given temperature) up to about 150 bar. You can expect
reasonable results at any condition, provided the UNIFAC interaction
parameters are available. Results are least accurate close to the critical point.
Parameters Required for the PRMHV2 Property Method
Thermodynamic
Properties
Vapor and liquid
mixture

Density
Peng-Robinson-MHV2,
UNIFAC
TC, PC, OMEGA,
UFGRP, GMUFQ, GMUFR
Thermodynamic
Properties
Enthalpy,
Entropy,
Gibbs energy
Peng-Robinson-MHV2,
UNIFAC
(CPIG or CPIGDP),
TC, PC, OMEGA,
UFGRP, GMUFQ, GMUFR

PRWS
The PRWS property method is based on the Peng-Robinson-Wong-Sandler
equation-of-state model, which is based on an extension of the Peng-
Robinson equation of state. The UNIFAC model is used to calculate excess
Helmholtz energy for the mixing rules.
Besides the acentric factor, you can use up to three polar parameters to fit
more accurately the vapor pressure of polar compounds. The Wong-Sandler
mixing rules predict the binary interactions at any pressure. Using the UNIFAC
model the PRWS property method is predictive for any interaction that can be
predicted by UNIFAC at low pressure.
The minimum parameter requirements of the property method are given in
the tables labeled Parameters Required for the PRWS Property Method
(below) and Parameters Required for Common Flexible and Predictive Models.
For details about the optional parameters, and about calculation of pure
Mixture Types
You can use the PRWS property method for mixtures of non-polar and polar
compounds, in combination with light gases.
Range
You can use the PRWS property method up to high temperatures and
mole fraction at a given temperature) up to about 150 bar. You can expect
reasonable results at any condition, provided UNIFAC interaction parameters
are available. Results are least accurate close to the critical point.
Parameters Required for the PRWS Property Method
Thermodynamic
Properties
Vapor and liquid
mixture

Density
Peng-Robinson-WS,
UNIFAC
TC, PC, OMEGA, UFGRP,
GMUFR, GMUFQ
Enthalpy,
Entropy,
Gibbs energy
PengRobinson-WS,
UNIFAC
(CPIG or CPIGDP),TC, PC,
OMEGA, UFGRP, GMUFR,
GMUFQ

PSRK
The PSRK property method is based on the Predictive Soave-Redlich-Kwong
equation-of-state model, which is an extension of the Redlich-Kwong-Soave
equation of state.
more accurately the vapor pressure of polar compounds. The Holderbaum-
Gmehling mixing rules or PSRK method predict the binary interactions at any
pressure. Using UNIFAC the PSRK method is predictive for any interaction
that can be predicted by UNIFAC at low pressure. The UNIFAC interaction
parameter table has been extended for gases, for the PSRK method.
The minimum parameter requirements of the PSRK property method are
given in the tables labeled Parameters Required for the PSRK Property Method
(see below) and Parameters Required for Flexible and Predictive Models. For
details about the optional parameters, and about calculation of pure
Mixture Types
You can use the PSRK property method for mixtures of non-polar and polar
Range
You can use the PSRK property method up to high temperatures and
pressures. You can expect accurate predictions at any conditions provided
UNIFAC interaction parameters are available. Results are least accurate close
to the critical point.
Parameters Required for the PSRK Property Method
Thermodynamic
Properties
Vapor and liquid
mixture

Density
PSRK,
UNIFAC
GMUFR, GMUFQ
Enthalpy,
Entropy,
Gibbs energy
Ideal heat capacity, PSRK,
UNIFAC
GMUFQ

RK-ASPEN
The RK-ASPEN property method is based on the Redlich-Kwong-Aspen
equation-of-state model, which is an extension of Redlich-Kwong-Soave.
This property method is similar to RKS-BM, but it also applies to polar
components such as alcohols and water. RKS-BM requires polar parameters
that must be determined from regression of experimental vapor pressure data
using DRS. Use the binary parameters to obtain best possible results for
phase equilibria. RK-ASPEN allows temperature-dependent binary
parameters. If the polar parameters are zero for all components and the
binary parameters are constant, RK-ASPEN is identical to RKS-BM.
The minimum parameter requirements of the RK-ASPEN property method are
given in the tables labeled Parameters Required for the RK-ASPEN Property
Method (see below) and Parameters Required for Common Flexible and
Predictive Models. For details about the optional parameters for this model,
see Physical Property Models.
Mixture Types
You can use the RK-ASPEN property method for mixtures of non-polar and
slightly polar compounds, in combination with light gases. It is especially
suited for combinations of small and large molecules, such as nitrogen with n-
Decane, or hydrogen-rich systems.
Range
You can use the RK-ASPEN property method up to high temperatures and
pressures. You can expect reasonable results at any condition, but results are
least accurate close to the critical point.
Parameters Required for the RK-ASPEN Property Method
Thermodynamic
Properties
Vapor and liquid
mixture

Density
Redlich-Kwong-Aspen TCRKA, PCRKA, OMEGARKA
UFGRP, GMUFR, GMUFQ
Enthalpy,
Entropy,
Gibbs energy
Redlich-Kwong-Aspen
(CPIG or CPIGDP) and TCRKA,
PCRKA, OMEGARKA

RKSMHV2
The RKSMHV2 property method is based on the Redlich-Kwong-Soave MHV2
equation-of-state model, which is an extension of the Redlich-Kwong-Soave
equation of state. The Lyngby modified UNIFAC model is used to calculate
excess Gibbs energy for the MHV2 mixing rules.
more accurately the vapor pressure of polar compounds. The MHV2 mixing
rules predict the binary interactions at any pressure. Using the Lyngby
modified UNIFAC model, the Redlich-Kwong-Soave MHV2 model is predictive
for any interaction that can be predicted by Lyngby modified UNIFAC at low
pressure. The Lyngby modified UNIFAC interaction parameter table has been
extended for gases for the MHV2 method.
The minimum parameter requirements of the RKSMHV2 property method are
given in the tables labeled Parameters Required for the RKSMHV2 Property
Predictive Models. For details about optional parameters and calculation of
pure component and mixture properties, see Physical Property Models.
Mixture Types
You can use the RKSMHV2 property method for mixtures of non-polar and
polar compounds, in combination with light gases.
Range
You can use the RKSMHV2 property method up to high temperatures and
mole fraction at given temperature) up to about 150 bar. You can expect
reasonable results at any condition, provided Lyngby modified UNIFAC
interactions are available. Results are least accurate close to the critical point.
Parameters Required for the RKSMHV2 Property Method
Thermodynamic
Properties
Vapor and liquid
mixture

Density
Redlich-Kwong-Soave-MHV2,
Lyngby modified UNIFAC
TC, PC, OMEGA, UFGRPL,
GMUFLR, GMUFLQ
Enthalpy,
Entropy,
Gibbs energy
Redlich-Kwong-Soave-MHV2,
Lyngby modified UNIFAC
OMEGA, UFGRPL, GMUFLR,
GMUFLQ

RKSWS
The RKSWS property method is based on the Redlich-Kwong-Soave-Wong-
Sandler equation-of-state model, which is an extension of the Redlich-Kwong-
Soave equation of state. The UNIFAC model is used to calculate excess
Helmholtz energy for the mixing rules.
Besides the acentric factor,you can use up to three polar parameters to fit
more accurately the vapor pressure of polar compounds. The Wong-Sandler
mixing rules predict the binary interactions at any pressure. Using the UNIFAC
model it is predictive for any interaction that can be predicted by UNIFAC at
low pressure.
The minimum parameter requirements of the RKSWS property method are
given in the tables labeled Parameters Required for the RKSWS Property
Predictive Models. For details about optional parameters and calculation of
pure component and mixture properties, see Physical Property Models.
Mixture Types
You can use the RKSWS property method for mixtures of non-polar and polar
Range
You can use the RKSWS property method up to high temperatures and
mole fraction at a given temperature) up to about 150 bar. You can expect
are available. But results are least accurate close to the critical point.
Parameters Required for the RKSWS Property Method
Thermodynamic
Properties
Vapor and liquid
mixture

Density
Redlich-Kwong-Soave-WS,
UNIFAC
GMUFR, GMUFQ
Enthalpy,
Entropy,
Gibbs energy
Redlich-Kwong-Soave-WS,
UNIFAC
GMUFQ

SR-POLAR
The SR-POLAR property method is based on an equation-of-state model by
Schwarzentruber and Renon, which is an extension of the Redlich-Kwong-
Soave equation of state. You can apply the SR-POLAR method to both non-
polar and highly polar components, and to highly nonideal mixtures. This
method is recommended for high temperature and pressure applications
SR-POLAR requires:
Polar parameters for polar components. These parameters are determined
automatically using vapor pressure data generated from the extended
Antoine model.
Binary parameters to accurately represent phase equilibria. The binary
parameters are temperature-dependent.
If you do not enter binary parameters, the Aspen Physical Property System
estimates them automatically using VLE data generated from the UNIFAC
group contribution method. Therefore, the SR-POLAR property method is
predictive for any interaction that UNIFAC can predict at low pressures. The
accuracy of the prediction decreases with increasing pressure. You cannot use
UNIFAC to predict interactions with light gases.
SR-POLAR is an alternative property method that you can use for nonideal
systems, instead of using an activity coefficient property method, such as
WILSON.
Parameter requirements for the SR-POLAR property method are in the tables
labeled Parameters Required for the SR-POLAR Property Method (see below)
and Parameters Required for Common Flexible and Predictive Models. For
details about optional parameters, and calculation of pure component and
mixture properties, see Physical Property Models.
Mixture Types
You can use the SR-POLAR property method for mixtures of non-polar and
polar compounds, in combination with light gases.
Range
You can use the SR-POLAR property method up to high temperatures and
pressures. You can expect fair predictions up to about 50 bar. You can expect
are available. But results are least accurate close to the critical point.
Parameters Required for the SR-POLAR Property Method
Thermodynamic
Properties
Vapor and liquid
mixture

Density
Schwartzentruber-Renon TC, PC, OMEGA, Optional:
RKUPPn, RKUCn,
RKUKAn, RKULAn, RKUKBn
n = 0, 1, 2
Enthalpy,
Entropy,
Gibbs energy
Ideal gas heat capacity/DIPPR
Schwartzentruber-Renon
(CPIG or CPIGDP)
Optional:
RKUPPn, RKUCn,
RKUKAn, RKULAn, RKUKBn
n = 0, 1, 2

Common Models
The following table describes the models common to flexible and predictive
property methods and their parameter requirements.
Parameters Required for Common Flexible and Predictive
Models
General
Mass balance,
MW
Using Free-water option: solubility of
water in organic phase
WATSOL
Vapor mixture
Viscosity


Diffusivity

Chung-Lee-Starling

Chung-Lee-Starling

Dawson-Khoury-Kobayashi

TC, PC, OMEGA

TC, PC, OMEGA

MW, MUP, (STKPAR or LJPAR),
VC
Surface tension Hakim-Steinberg-Stiel/ DIPPR (TC, PC, OMEGA) or SIGDIP
Liquid mixture
Viscosity


Diffusivity

Chung-Lee-Starling

Chung-Lee-Starling

Wilke-Chang

TC, PC, OMEGA

TC, PC, OMEGA

MW, VB

Liquid Activity Coefficient
Property Methods
The table labeled Liquid Activity Coefficient Property Methods (see Equations
of State) lists property methods for nonideal and strongly nonideal mixtures
at low pressures (maximum 10 atm). You can model permanent gases in
liquid solution using Henry's law. Binary parameters for many component
pairs are available in the Aspen Physical Property System databanks. The
UNIFAC based property methods are predictive.
These property methods are not suited for electrolytes. In that case use an
electrolyte activity coefficient property method. Model polar mixtures at high
pressures with flexible and predictive equations of state. Non-polar mixtures
are more conveniently modeled with equations-of-state. Petroleum mixtures
are more accurately modeled with liquid fugacity correlations and equations of
state.
In labeled Liquid Activity Coefficient Property Methods (see Equations of
State) there are five different activity coefficient models and six different
equation-of-state models. Each activity coefficient model is paired with a
number of equation-of-state models to form 26 property methods. The
description of the property methods are therefore divided into two parts:
Equation of state
Activity coefficient model
Each part discusses the characteristics of the specific model and its parameter
requirements. Parameters of the models occurring in all property methods are
given in the table labeled Parameters Required for Common Models.

Equations of State
This section discusses the characteristics and parameter requirements of the
following equations of state:
Ideal gas law
Redlich-Kwong
Nothnagel
Hayden-O'Connell
HF equation of state
VPA/IK-CAPE Equation of State
Liquid Activity Coefficient Property Methods
Property Method Gamma Model Name Vapor Phase EOS
Name
NRTL NRTL Ideal gas law
NRTL-2 NRTL Ideal gas law
NRTL-RK NRTL Redlich-Kwong
NRTL-HOC NRTL Hayden-O'Connell
NRTL-NTH NRTL Nothnagel
UNIFAC UNIFAC Redlich-Kwong
UNIF-LL UNIFAC Redlich-Kwong
UNIF-HOC UNIFAC Hayden-O'Connell
UNIF-DMD Dortmund modified
UNIFAC
Redlich-Kwong-Soave
UNIF-LBY Lyngby modified
UNIFAC
Ideal Gas law
UNIQUAC UNIQUAC Ideal gas law
UNIQ-2 UNIQUAC Ideal gas law
UNIQ-RK UNIQUAC Redlich-Kwong
UNIQ-HOC UNIQUAC Hayden-O'Connell
UNIQ-NTH UNIQUAC Nothnagel
VANLAAR Van Laar Ideal gas law
VANL-2 Van Laar Ideal gas law
VANL-RK Van Laar Redlich-Kwong
VANL-HOC Van Laar Hayden-O'Connell
VANL-NTH Van Laar Nothnagel
WILSON Wilson Ideal gas law
WILS-2 Wilson Ideal gas law
WILS-GLR Wilson Ideal gas law
WILS-LR Wilson Ideal gas law
WILS-RK Wilson Redlich-Kwong
WILS-HOC Wilson Hayden-O'Connell
WILS-NTH Wilson Nothnagel
WILS-HF Wilson HF equation of state

Vapor pressure Extended Antoine
Liquid molar volume Rackett
Heat of vaporization Watson
Surface tension Hakim-Steinberg-Stiel/DIPPR
Liquid viscosity Andrade/DIPPR
Liquid thermal conductivity Sato-Riedel/DIPPR

Ideal Gas Law
The property methods that use the ideal gas law as the vapor phase model
are:
NRTL
NRTL-2
UNIF-LBY
UNIQUAC
UNIQ-2
VANLAAR
VANL-2
WILSON
WILS-2
WILS-GLR
WILS-LR
The ideal gas law is the simplest equation of state. It is also known as the
combined laws of Boyle and Gay-Lussac.
Mixture Types
The ideal gas law cannot model association behavior in the vapor phase, as
occurs with carboxylic acids. Choose Hayden-O'Connell or Nothnagel to model
this behavior.
Range
The ideal gas law is valid for low pressures. It is not suited for modeling
pressures exceeding several atm. For medium pressures, choose a Redlich-
Kwong-based property method.
There are no component-specific parameters associated with the ideal gas
law.

Redlich-Kwong
The property methods that use the Redlich-Kwong equation of state as the
vapor phase model are:
NRTL-RK
UNIFAC
UNIF-LL
UNIQ-RK
VANL-RK
WILS-RK
The Redlich-Kwong equation of state is a simple cubic equation of state.
Mixture Types
The Redlich-Kwong equation of state cannot model association behavior in the
vapor phase, as occurs with carboxylic acids.
Range
The Redlich-Kwong equation of state describes vapor phase properties
accurately up to medium pressures.
The parameter requirements for the Redlich-Kwong equation of state are
given in the following table. For details about the model, see Physical Property
Models.
Parameters Required for Redlich-Kwong Property Methods
Thermodynamic
Properties
Vapor mixture
Density
Redlich-Kwong TC, PC
Enthalpy,
Entropy,
Gibbs energy
Redlich-Kwong
(CPIG or CPIGDP), TC, PC

Nothnagel
The property methods that use the Nothnagel equation of state as vapor
phase model are:
NRTL-NTH
UNIQ-NTH
VANL-NTH
WILS-NTH
The Nothnagel equation of state accounts for dimerization in the vapor phase
at low pressure. Dimerization affects VLE; vapor phase properties, such as
enthalpy and density; and liquid phase properties, such as enthalpy.
Mixture Types
The Nothnagel equation of state can model dimerization in the vapor phase,
as occurs with mixtures containing carboxylic acids.
Range
Do not use the Nothnagel based property methods at pressures exceeding
several atm. For vapor phase association up to medium pressure choose the
Hayden-O'Connell equation.
Parameter requirements for the Nothnagel equation of state are given in the
following table. Enter equilibrium constants of association directly (NTHK). Or
calculate them from the pure component parameters NTHA, elements 1 to 3
(b
i
, p
i
and d
i
). If parameters are not available, the Aspen Physical Property
System uses default values. For prediction, the Hayden-O'Connell correlation
is more accurate. For details about the models, see Physical Property Models.
Parameters Required for Nothnagel Property Methods
Thermodynamic
Properties
Vapor mixture
Density
Nothnagel TB, TC, PC and (NTHA or
NTHK)
Enthalpy,
Entropy,
Gibbs energy
Nothnagel
(CPIG or CPIGDP), TB, TC, PC
and (NTHA or NTHK)

Hayden-O'Connell
The property methods that use the Hayden-O'Connell equation of state as
vapor phase model are:
NRTL-HOC
UNIF-HOC
UNIQ-HOC
VANL-HOC
WILS-HOC
The Hayden-O'Connell equation of state predicts solvation and dimerization in
the vapor phase, up to medium pressure. Dimerization affects VLE; vapor
phase properties, such as enthalpy and density; and liquid phase properties,
such as enthalpy.
Mixture Types
The Hayden-O'Connell equation reliably predicts solvation of polar compounds
and dimerization in the vapor phase, as occurs with mixtures containing
carboxylic acids.
Range
Do not use the Hayden-O'Connell-based property methods at pressures
exceeding 10 to 15 atm.
Parameter requirements for the Hayden-O'Connell equation of state are given
in the following table. For details about the model, see Physical Property
Models.
Parameters Required for Hayden-O'Connell Property
Methods
Thermodynamic
Properties
Vapor mixture
Density
Hayden-O'Connell TC, PC, RGYR, MUP, HOCETA
Enthalpy,
Entropy,
Gibbs energy
Hayden-O'Connell
(CPIG or CPIGDP), TC, PC,
RGYR, MUP, HOCETA

HF Equation of State
The only property methods that use the HF equation of state as the vapor
phase model are WILS-HF and ENRTL-HF.
For HF-hydrocarbon mixtures, the Wilson activity coefficient model is usually
best suited for preventing nonrealistic liquid phase splitting.
The HF equation of state predicts the strong association of HF the vapor
phase at low pressures. Association (mainly hexamerization) affects VLE,
vapor phase properties, such as enthalpy and density, and liquid phase
properties, such as enthalpy.
Mixture Types
The HF equation of state reliably predicts the strong association effects of HF
in a mixture.
Range
Do not use the WILS-HF property method at pressures exceeding 3 atm.
Parameters for the HF equation of state are built-in for temperatures up to
373 K. You can enter parameters and regress them using the Aspen Physical
Property System Data Regression System (DRS), if necessary. For details
about the model, see Physical Property Models.

VPA/IK-CAPE Equation of State
The VPA/IK-CAPE equation of state is similar to the HF equation of state but
allows dimerization and tetramerization. No property method uses this
equation of state by default. It is recommended that this equation of state is
used in place of the HF equation of state with the WILS-HF and ENRTL-HF
property methods, when dimerization and tetramerization is expected.
The main assumption of the model is that only molecular association causes
the gas phase nonideality. Attractive forces between the molecules and the
complexes are neglected.
There are three kinds of associations which can be modeled:
Dimerization (examples: formic acid, acetic acid)
Tetramerization (example: acetic acid)
Hexamerization (example: hydrogen fluoride)
Mixture Types
The VPA/IK-CAPE equation of state can be used to model strong association
effects such as the presence of dimers, tetramers and hexamers. Use the VPA
model for associating compounds like acids and hydrogen fluoride.
Range
Do not use the VPA/IK-CAPE equation of state at pressures exceeding 3
atmospheres. Parameters (equilibrium constants) for the formation of dimers,
tetramers and hexamers are not built in to the Aspen Physical Property
System. You can enter parameters and regress them using the Aspen Physical
Property Data Regression System (DRS)

Activity Coefficient Models
This section discusses the characteristics and parameter requirements of the
following activity coefficient models:
NRTL
UNIFAC
UNIQUAC
Van Laar
Wilson

NRTL
The property methods that use the NRTL activity coefficient model are listed
in the following table:
NRTL Property Methods
Binary Parameters
Property
Method Name
Dataset
Number
VLE
Lit Reg
LLE
Lit Reg
Henry
Lit Reg
Vapor Phase
EOS Name
Poynting
Correction
NRTL 1 X X X X X Ideal Gas law
NRTL-2 2 X X X X X Ideal Gas law
NRTL-RK 1 X X X Redlich-Kwong X
Binary Parameters
Property
Method Name
Dataset
Number
VLE
Lit Reg
LLE
Lit Reg
Henry
Lit Reg
Vapor Phase
EOS Name
Poynting
Correction
NRTL-HOC 1 X X X Hayden-O'Connell X
NRTL-NTH 1 X X Nothnagel X
An X in the Lit columns indicates the parameters were obtained from the
literature. An X in the Reg columns indicates the parameters were regressed
by AspenTech from experimental data in the Dortmund Databank (DDB).
The NRTL model can describe VLE and LLE of strongly nonideal solutions. The
model requires binary parameters. Many binary parameters for VLE and LLE,
from literature and from regression of experimental data, are included in the
Aspen Physical Property System databanks. For details, see Physical Property
Data, Chapter 1.
You can model the solubility of supercritical gases using Henry's law. Henry
coefficients are available in the Aspen Physical Property System databanks for
many solutes with water and other solvents (see Physical Property Data,
Chapter 1).
The property methods with a vapor phase model that can be used up to
moderate pressures, have the Poynting correction included in the liquid
fugacity coefficient calculation. See the table labeled NRTL Property Methods
(above) .
Heat of mixing is calculated using the NRTL model.
You can use separate data sets for the NRTL binary parameters to model
properties or equilibria at different conditions. It is also possible to use one
data set for VLE and a second data set for LLE (use NRTL and NRTL-2)
property methods are identical except for the data set number they use. For
example, you can use these property methods in different flowsheet sections
or column sections.
Mixture Types
The NRTL model can handle any combination of polar and non-polar
compounds, up to very strong nonideality.
Range
Parameters should be fitted in the temperature, pressure, and composition
range of operation. No component should be close to its critical temperature.
Parameter requirements for the NRTL activity coefficient model are given in
the following table. For details about the model, see Physical Property Models.
Parameters Required for NRTL Property Methods
Thermodynamic
Properties
Liquid mixture
Gibbs energy
NRTL liquid activity coefficient NRTL
Thermodynamic
Properties

pressure
PLXANT
Henry's constant Solvent: VC,
Solute-solvent: HENRY
Brelvi-O'Connell Solvent: TC, PC, (ZC or
VLBROC)
Enthalpy,
Entropy
Ideal gas heat capacity CPIG or CPIGDP

Watson/DIPPR heat of
vaporization
NRTL liquid activity coefficient NRTL
Density Rackett TC, PC, (VC or VCRKT),
(ZC or RKTZRA)

UNIFAC
UNIFAC is an activity coefficient model, like NRTL or UNIQUAC. But it is based
on group contributions, rather than molecular contributions. With a limited
number of group parameters and group-group interaction parameters,
UNIFAC can predict activity coefficients. The following table lists the property
methods based on UNIFAC.
UNIFAC Property Methods
Property
Method
Name
Model
Name
Parameters
Rev. Yr
Tmin
/K
Tmax
/K
Henry
Lit Reg
Vapor Phase
EOS Name
Poynting
Correction
UNIFAC UNIFAC 5, 1991 290 420 X X Redlich-Kwong X
UNIF-LL UNIFAC , 1991 280 310 X X Redlich-Kwong X
UNIF-HOC UNIFAC 5, 1991 290 420 X X Hayden-
O'Connell
X
UNIF-DMD DMD-
UNIF
1, 1993 290 420 X X Redlich-
Kwong-
Soave
X
UNIF-LBY LBY-UNIF , 1987 290 420 X X Ideal Gas law
The original version of UNIFAC can predict VLE and LLE, using two sets of
parameters. So there are two property methods based on the original UNIFAC
model, one using the VLE data set (UNIFAC), the other using the LLE data set
(UNIF-LL).
There are two modifications to the UNIFAC model. They are named after the
location of the universities where they were developed: Lyngby in Denmark,
and Dortmund in Germany. The corresponding property methods are UNIF-
LBY and UNIF-DMD. Both modifications:
Include more temperature-dependent terms of the group-group
interaction parameters
Predict VLE and LLE with a single set of parameters
Predict heats of mixing better
In the Dortmund modification, the prediction for activity coefficients at infinite
dilution is improved.
coefficients are available in the Aspen Physical Property System databanks for
many solutes with water and other solvents (see Physical Property Data,
Chapter 1).
The option sets with a vapor phase model that can be used up to moderate
pressures, have the Poynting correction included in the liquid fugacity
coefficient calculation (see the table labeled UNIFAC Property Methods
above).
Heats of mixing are calculated using the UNIFAC or modified UNIFAC models.
Mixture Types
The UNIFAC and modified UNIFAC models can handle any combination of
polar and nonpolar compounds. Dissolved gas in solutions can be handled
with Henry's Law. However, gas-solvent interactions are not predicted by
UNIFAC.
Range
No component should be close to its critical temperature. Approximate
temperature ranges are indicated in the table labeled UNIFAC Property
Methods (above).
The parameter sets for all UNIFAC models are regularly revised and extended.
The table labeled UNIFAC Property Methods (above) gives the revision
number currently used in the Aspen Physical Property System. For details on
the parameters used, see Physical Property Data, Chapter 3.
The minimum parameter requirements for the UNIFAC and modified UNIFAC
models are given in the following table. For details about the models, see
Parameters Required for the UNIFAC Property Methods
Thermodynamic
Properties
Liquid mixture
Fugacity coefficient, UNIFAC UFGRP
Gibbs energy or:
Dortmund modified UNIFAC UFGRPD
or:
Lyngby modified UNIFAC UFGRPL
pressure
PLXANT
Thermodynamic
Properties
RKTZRA),
Solute: (VC or VLBROC)
Enthalpy, Entropy Ideal gas heat capacity CPIG or CPIGDP
vaporization
TC, (DHVLWT or DHVLDP)
UNIFAC UFGRP
or:
Dortmund modified UNIFAC UFGRPD
or:
Lyngby modified UNIFAC UFGRPL
RKTZRA)

UNIQUAC
The property methods that use the UNIQUAC activity coefficient model are
listed in the following table.
UNIQUAC Property Methods

Binary Parameters
Property
Method
Name
Dataset
Number
VLE
Lit Reg
LLE
Lit Reg
Henry
Lit Reg
Vapor Phase
EOS Name
Poynting
Correction
UNIQUAC 1 X X X X X X Ideal Gas law
UNIQ-2 2 X X X X X X Ideal Gas law
UNIQ-RK 1 X X X Redlich-Kwong X
UNIQ-HOC 1 X X X Hayden-O'Connell X
UNIQ-NTH 1 X X Nothnagel X
The UNIQUAC model can describe strongly nonideal liquid solutions and
liquid-liquid equilibria. The model requires binary parameters. Many binary
parameters for VLE and LLE, from literature and from regression of
experimental data, are included in the Aspen Physical Property System
databanks (for details, see Physical Property Data, Chapter 1).
coefficients are available from the databank (see Physical Property Data,
Chapter 1).
fugacity coefficient calculation (see the table labeled UNIQUAC Property
Methods above).
Heats of mixing are calculated using the UNIQUAC model.
You can use separate data sets for the UNIQUAC binary parameters to model
properties or equilibria at different conditions. It is also possible to use one
data set for VLE and a second data set for LLE (use UNIQUAC and UNIQ-2).
The property methods are identical except for the data set number they use.
For example, you can use these options sets in different flowsheet sections or
column sections.
Mixture Types
The UNIQUAC model can handle any combination of polar and non-polar
Range
Parameter requirements for the UNIQUAC activity coefficient model are given
Models.
Parameters Required for UNIQUAC Property Methods
Thermodynamic
Properties
Liquid mixture
Gibbs energy UNIQUAC liquid activity
coefficient
GMUQR, GMUQQ, UNIQ
pressure
PLXANT
RKTZRA),

Enthalpy,
Entropy


CPIG or CPIGDP
vaporization
UNIQUAC liquid activity
coefficient
GMUQR, GMUQQ, UNIQ
RKTZRA)

Van Laar
The property methods that use the Van Laar activity coefficient model are
listed in the following table.
Van Laar Property Methods

Binary Parameters
Property
Method
Name
Dataset
number
VLE
Lit Reg
LLE
Lit Reg
Henry
Lit Reg
Vapor Phase EOS
Name
Poynting
Correction
VANLAAR 1 X X Ideal Gas law
VANL-2 2 X X Ideal Gas law
VANL-RK 1 X X Redlich-Kwong X
VANL-HOC 1 X X Hayden-O'Connell X
VANL-NTH 1 X X Nothnagel X
The Van Laar model can describe nonideal liquid solutions with positive
deviations from Raoult's law (see Activity Coefficient Method in Overview of
Aspen Physical Property Methods). The model requires binary parameters.
coefficients are available from the Aspen Physical Property System databank
(see Physical Property Data, Chapter 1).
fugacity coefficient calculation (see the table labeled Van Laar Property
Methods above).
Heats of mixing are calculated using the Van Laar model.
You can use separate data sets to model properties or equilibria at different
conditions (use VANLAAR and VANL-2). The property methods are identical
except for the data set number they use. For example, you can use these
property methods in different flowsheet or column sections.
Mixture Types
The Van Laar model can handle any combination of polar and non-polar
compounds with positive deviations from Raoult's law.
Range
Parameters should be fitted in the temperature range of operation. No
component should be close to its critical temperature.
Parameter requirements for the Van Laar activity coefficient model are given
Models.
Parameters Required for Van Laar Property Methods
Thermodynamic
Properties
Liquid mixture
Gibbs energy Van Laar liquid activity
coefficient
VANL
pressure
PLXANT
Brelvi-O'Connell Solvent: TC, PC, ( ZC or
RKTZRA),

Enthalpy,
Entropy


CPIG or CPIGDP
vaporization
Van Laar liquid activity
coefficient
VANL
RKTZRA)

Wilson
The property methods that use the Wilson activity coefficient model or the
Wilson Model with Liquid Molar Volume are listed in the following table. Only
WILS-VOL uses the latter model.
Wilson Property Methods

Binary Parameters
Property
Method
Name
Dataset
number
VLE
Lit Reg
LLE
Lit Reg
Henry
Lit Reg
Vapor Phase
EOS Name
Poynting
Correction
WILSON 1 X X X X Ideal Gas law
WILS-2 2 X X X X Ideal Gas law
WILS-GLR 1 X X X X Ideal Gas law
WILS-LR 1 X X X X Ideal Gas law
WILS-RK 1 X X X Redlich-Kwong X
WILS-HOC 1 X X X Hayden-O'Connell X
WILS-NTH 1 X X Nothnagel X
WILS-HF 1 X X HF X
WILS-VOL 1 X X Redlich-Kwong X
The Wilson model can describe strongly nonideal liquid solutions. The model
cannot handle two liquid phases. In that case use NRTL or UNIQUAC. The
model requires binary parameters. Many binary parameters for VLE, from
literature and from regression of experimental data, are included in the Aspen
Physical Property System databanks (for details, see Physical Property Data,
Chapter 1).
The solubility of supercritical gases can be modeled using Henry's law. Henry
coefficients are available from the databank for many solutes with water and
other solvents (see Physical Property Data, Chapter 1).
fugacity coefficient calculation (see the table labeled Wilson Property Methods
above).
Heats of mixing are calculated using the Wilson model.
You can use separate data sets for the Wilson binary parameters to model
properties or equilibria at different conditions (use WILSON and WILS-2). The
property methods are identical except for the data set number they use. For
example, you can use these property methods in different flowsheet or
column sections.
Mixture Types
The Wilson model can handle any combination of polar and non-polar
Range
Parameter requirements for the Wilson activity coefficient model are given in
the table below. For details about the model, see Physical Property Models.
Parameters Required for the Wilson Property Methods
Thermodynamic
Properties
Liquid mixture
Gibbs energy Wilson liquid activity coefficient WILSON
pressure
PLXANT
Henry's constant Solvent: VC, Solute-solvent:
HENRY
VLBROC)
Enthalpy,
Entropy
Ideal gas heat capacity CPIG or CPIGDP
vaporization
Thermodynamic
Properties
Wilson liquid activity coefficient WILSON
RKTZRA)

Common Models
The following table describes the models common to activity coefficient
property methods and their parameter requirements.
Parameters Required For Common Models
General
Mass balance,
Conversion Mass-basisMole-
basis
MW
basis
VLSTD
Using Free-water option:
solubility of water in organic
phase
WATSOL
Vapor mixture
Viscosity Chapman-Enskog-Brokaw/
DIPPR
LJPAR)) or MUVDIP
Thermal
conductivity
Stiel-Thodos low pres./ DIPPR MW or KVDIP
Diffusivity Chapman-Enskog-Wilke-Lee MW; MUP and (STKPAR or
LJPAR)
Liquid mixture
Viscosity Andrade/DIPPR MULAND or MULDIP
Thermal
Conductivity
Sato-Riedel/DIPPR (MW, TC, TB) or KLDIP
Diffusivity Wilke-Chang MW, VB

Electrolyte Property Methods
The following table lists property methods for electrolyte solutions. Electrolyte
solutions are extremely nonideal because of the presence of charged species.
Property methods based on correlations can handle specific components
under well-described conditions; rigorous models are generally applicable.
The ELECNRTL property method can handle mixed solvent systems at any
concentration. The PITZER property method is accurate for aqueous solutions
up to 6M. Binary parameters for many component pairs are available in the
databanks. B-PITZER is predictive but less accurate. You can use these
property methods at low pressures (maximum 10 atm). ENRTL-HF is similar
to ELECNRTL, but with a vapor phase model for the strong HF association.
This property method should be used at low pressures (maximum 3 atm).
Permanent gases in liquid solution can be modeled by using Henry's law.
Transport properties are calculated by standard correlations with corrections
for the presence of electrolytes.
Electrolyte Property Methods
Correlation-Based Property Methods
Property Method Correlation System
AMINES Kent-Eisenberg MEA, DEA, DIPA, DGA
APISOUR API Sour water
correlation
H2O, NH3, CO2, H2S
Activity Coefficient Model-Based Property Methods
Property Method Gamma Model Name Vapor Phase EOS Name
ELECNRTL Electrolyte NRTL Redlich-Kwong
ENRTL-HF Electrolyte NRTL HF equation of state
ENRTL-HG Electrolyte NRTL Redlich-Kwong
PITZER Pitzer Redlich-Kwong-Soave
PITZ-HG Pitzer Redlich-Kwong-Soave
B-PITZER Bromley-Pitzer Redlich-Kwong-Soave
Other Property Methods
Property Method
OLI
Common Models For Rigorous Property Methods
Property Model
Vapor pressure Extended Antoine
Liquid molar volume Rackett/Clarke
Heat of vaporization Watson/DIPPR
Infinite dilution heat capacity Criss-Cobble
Property Model
Surface tension Hakim-Steinberg-Stiel/DIPPR -
Onsager-Samara
Liquid viscosity Andrade/DIPPR - Jones-Dole
Liquid thermal conductivity Sato-Riedel/DIPPR - Riedel
Liquid diffusivity Wilke-Chang - Nernst-Hartley
Do not use the electrolyte property methods for nonelectrolyte systems. See
Classification of Property Methods and Recommended Use for more help.
For general thermodynamic principles, see Electrolyte Models in Overview of
Aspen Physical Property Methods. The Electrolyte Calculation chapter contains
specifics on electrolyte calculation. For details on methods, see Property
Calculation Methods and Routes. The property method descriptions give the
minimum parameter requirements for the thermodynamic property models
used, also of the common thermodynamic property models. The general and
transport property parameter requirements for coefficient-based property
methods are in the table labeled Parameters Required for General and
Transport Models. For details on models, see Physical Property Models.

AMINES
The AMINES property method uses the Kent-Eisenberg method for K-values
and enthalpy. It is designed for systems containing water, one of four
ethanolamines, hydrogen sulfide, carbon dioxide, and other components
typically present in gas-sweetening processes. It can be used for the following
four amines:
Monoethanolamine (MEA)
Diethanolamine (DEA)
Diisopropanolamine (DIPA)
Diglycolamine (DGA)
Range
Use the AMINES property method for amine systems with ranges of:
MEA DEA DIPA DGA
Temperature (F) 90 280 90 275 90 260 90 280
Maximum H2S or CO2 Loading
(moles gas/mole amine)
0.5 0.8 0.75 0.5
Amine Concentration in
Solution(mass percent)
5 40 10 50 10 50 30 75
If the amine concentration is outside the recommended range, the Chao-
Seader method is used for K-values (only for that particular property
evaluation).
Refer to the following table for parameter requirements for this property
method.
Parameters Required for the AMINES Property Method
General
Property/Purpose Parameter
Requirements
Mass balance, Conversion Mass-basisMole-
basis
MW
Using free-water option: solubility of water in
organic phase
WATSOL
Vapor mixture
Density
Redlich-Kwong TC; PC
Enthalpy, entropy Ideal gas heat capacity/DIPPR CPIG or CPIGDP
Liquid mixture
Gibbs energy
coefficient
TC; DELTA; VLCVT1; GMSHVL
Chao-Seader pure component
fugacity coefficient
TC; PC; OMEGA
pressure (amines and water
only)
PLXANT
Kent-Eisenberg (H2S and CO2
only)

Enthalpy, entropy Watson heat of vaporization
and DIPPR model
TC; PC;DHVLWT or DHVLDP
Density Rackett molar volume TC; PC: VC or VCRKT; ZC or
RKTZRA
Vapor mixture
Viscosity Dean-Stiel MW; (MUP and (STKPAR or
LJPAR)) or MUVDIP; TC, PC, VC
Thermal
conductivity
Stiel-Thodos MW, TC, PC, VC, ZC
Diffusivity Dawson-Khoury-Kobayaski MW; MUP and (STKPAR or
LJPAR); VC
Liquid mixture
Thermal
Conductivity

APISOUR
The APISOUR property method:
Uses the API procedure for K-values and enthalpy of sour water systems.
Is designed for sour water systems containing primarily water, ammonia,
hydrogen sulfide and carbon dioxide.
Is applicable in the temperature range of 20 140C.
Has an overall average error between measured and predicted partial
pressures of about 30% for ammonia, carbon dioxide, and hydrogen
sulfide.
Does not require any user-supplied parameters.
Is recommended for fast calculation of sour water systems at limited
concentration. For more accurate results, use the ELECNRTL property
method.
Note: APISOUR uses an activity coefficient method such as NRTL or Wilson to
calculate fugacity coefficients for components other than water, ammonia,
hydrogen sulfide, or carbon dioxide. To specify this method, on the
Properties | Property Methods | APISOUR | Models sheet, select a
model for calculating gamma. The default is GMRENON which uses NRTL.
Parameter requirements for the APISOUR property method are listed in the
following table.
Parameters Required for the APISOUR Property Method
General
Mass balance, Conversion Mass-
basisMole-basis
MW
Using Free-water option: solubility of
water in organic phase
WATSOL
Vapor mixture
DIPPR
LJPAR)) or MUVDIP
Thermal
conductivity
LJPAR)
Liquid mixture
Thermal
Conductivity

ELECNRTL
The ELECNRTL property method is the most versatile electrolyte property
method. It can handle very low and very high concentrations. It can handle
aqueous and mixed solvent systems.
The ELECNRTL is fully consistent with the NRTL-RK property method: the
molecular interactions are calculated exactly the same way, therefore
ELECNRTL can use the databank for binary molecular interaction parameters
for the NRTL-RK property method.
Many binary and pair parameters and chemical equilibrium constants from
regression of experimental data are included in Aspen Physical Property
System databanks. See Physical Property Data, Chapter 2, for details on the
systems included, the sources of the data, and the ranges of application.
The solubility of supercritical gases can be modeled using Henry's law. Henry
coefficients are available from the databank (see Activity Coefficient Method
in Overview of Aspen Physical Property Methods).
Heats of mixing are calculated using the electrolyte NRTL model.
The Redlich-Kwong equation of state is used for all vapor phase properties,
which cannot model association behavior in the vapor phase as occurs with
carboxylic acids or HF. For carboxylic acids, choose Hayden-O'Connell or
Nothnagel; for HF choose ENRTL-HF.
Mixture Types
Any liquid electrolyte solution unless there is association in the vapor phase.
Range
Vapor phase properties are described accurately up to medium pressures.
Interaction parameters should be fitted in the range of operation.
The parameter requirements for the ELECNRTL property method are given in
the following table, and in Parameters Required for General and Transport
Property Models. For details about the model see Physical Property Models.
Parameters Required for the ELECNRTL Property Method
Thermodynamic
Properties
Vapor mixture
Density
Redlich-Kwong TC, PC
Enthalpy,
Entropy,
Gibbs energy
Ideal gas heat capacity / DIPPR
/ Barin correlation

Redlich-Kwong
CPIG or CPIGDP or
CPIXP1, CPIXP2, CPIXP3

TC, PC
Liquid mixture
Gibbs energy
Electrolyte NRTL Mol.: CPDIEC
Ion: RADIUS
Mol.-Mol.: NRTL
Mol.-Ion, Ion-Ion: GMELCC,
GMELCD
GMELCE, GMELCN
pressure
PLXANT
Henry's constant Solvent: VC, Mol. solute-
solvent: HENRY
RKTZRA), Mol. solute: (VC or
VLBROC)
Enthalpy,
Entropy
Ideal gas heat capacity/ DIPPR
and
vaporization

Infinite dilution heat capacity /
Criss-Cobble

Electrolyte NRTL
CPIG or CPIGDP

Solvent: TC, (DHVLWT or
DHVLDP)

Ions: CPAQ0 or
Ions: IONTYP, S025C

Mol.: CPDIEC
Ion: RADIUS
Mol.-Mol.: NRTL
Mol.-Ion, Ion-Ion: GMELCC,
GMELCD
GMELCE, GMELCN
Density Rackett / Clarke Mol.: TC, PC, (VC or VCRKT),
(ZC or RKTZRA) Ion-ion: VLCLK
Solid pure (and
mixture)

Enthalpy,
Entropy
Solids heat capacity
polynomial/ Barin correlation
CPSP01 or CPSXP1 to CPSXP7
Density Solids molar volume polynomial VSPOLY

ENRTL-HF
The ENRTL-HF property method is similar to the ELECNRTL property method
except that it uses the HF equation of state as vapor phase model.
The HF equation of state predicts the strong association of HF in the vapor
phase at low pressures. Association (mainly hexamerization) affects both
vapor phase properties (for example, enthalpy and density) and liquid phase
properties (for example, enthalpy).
A data package is available to accurately model vapor and liquid phases of HF
and water mixtures in any proportion.
Mixture Types
The HF equation of state reliably predicts the strong association effects of HF
in the vapor phase. The liquid can be any liquid electrolyte solution.
Range
Usage should not exceed pressures of 3 atm.
Parameters for the HF equation of state are built-in for temperatures up to
373 K. Parameters can be entered and regressed using the Aspen Physical
Property Data Regression System (DRS) if needed. For details about the
model, see Electrolyte NRTL Activity Coefficient Model in Physical Property
Models. For the parameter requirements for the electrolyte NRTL model, see
the table labeled Parameters Required for the ELECNRTL Property Method
(see ELECNRTL). For general and transport property parameter requirements,
see the table Parameters Required for General and Transport Property
Models.

ENRTL-HG
The ENRTL-HG property method is similar to the ELECNRTL property method,
except it uses the Helgeson model for standard properties calculations. The
Helgeson model is a very accurate and flexible equation of state that
calculates standard enthalpy, entropy, Gibbs free energy and volume for
components in aqueous solutions. The Helgeson model should provide more
accurate enthalpy and Gibbs free energy of process streams up to high
temperatures and pressures. The model is also used to calculate Gibbs free
energy for use in estimating chemical equilibrium constants (for both
equilibrium and salt precipitation reactions) when they are missing.
Equilibrium constants calculated using the Helgeson model have been found
to be reasonably accurate and extrapolate well with respect to temperature.
Mixture Types
Any liquid electrolyte solution is acceptable, unless there is association in the
vapor phase.
Range
Vapor phase properties are described accurately up to medium pressures.
For parameter requirements for the electrolyte NRTL model, see the table
labeled Parameters Required for the ELECNRTL Property Method (see
ELECNRTL). For general and transport property parameter requirements, see
the table labeled Parameters Required for General and Transport Property
Models.

ENRTL-RK
ELECNRTL with Redlich-Kwong vapor phase properties, similar to NRTL-RK.

PITZER
The PITZER property method is based on an aqueous electrolyte activity
coefficient model. It has no overlap with other activity coefficient models. It
can accurately calculate the behavior of aqueous electrolyte solutions with or
without molecular solutes up to 6 molal ionic strength.
Many interaction parameters from regression of experimental data are
included in databanks and data packages (for details, see Overview of Aspen
Physical Property Methods).
coefficients are available from the Aspen Physical Property System databanks
(see Overview of Aspen Physical Property Methods).
Heats of mixing are calculated using the Pitzer model.
The Redlich-Kwong-Soave equation of state is used for the vapor phase
fugacity coefficient. All other vapor phase properties are assumed ideal.
Redlich-Kwong-Soave cannot model association behavior in the vapor phase
(for example, carboxylic acids or HF). For carboxylic acids, choose a non-
electrolyte activity coefficient model with Hayden-O'Connell or Nothnagel; for
HF choose ENRTL-HF or WILS-HF.
Mixture Types
You can use the Pitzer model for any aqueous electrolyte solution up to 6M
ionic strength, not showing association in the vapor phase.
Range
Vapor phase fugacities are described accurately up to medium pressures.
The parameter requirements for the PITZER property method are given in the
following table, and the table labeled Parameters Required for General and
Transport Property Models. For details about the model, see Physical Property
Models.
Parameters Required for the PITZER Property Method
Thermodynamic
Properties
Vapor mixture
Density
Redlich-Kwong-Soave TC, PC, OMEGA
Enthalpy,
Entropy,
Gibbs energy
/ Barin correlation

Redlich-Kwong
CPIG orCPIGDP or
CPIXP1, CPIXP2, CPIXP3

TC, PC, OMEGA
Liquid mixture
Gibbs energy
Pitzer Cation-anion: GMPTB0,
GMPTB1, GMPTB2, GMPTB3,
GMPTC
Cation-cation: GMPTTH
Anion-anion: GMPTTH
Cation1-cation2-common
anion: GMPTPS
Anion1-anion2-common cation:
GMPTPS
Molecule-ion, Mol. Mol.:
GMPTB0, GMPTB1, GMPTC
pressure
PLXANT
solvent: HENRY
VLBROC)
Enthalpy,
Entropy
and
vaporization
CPIG or CPIGDP

DHVLDP)
Criss-Cobble
Ions: CPAQ0 or
Ions: IONTYP, S025C
Pitzer Cation-anion: GMPTB0,
GMPTB1, GMPTB2, GMPTB3,
GMPTC
Anion-anion: GMPTTH
Cation1-cation2-common
anion: GMPTPS
Anion1-anion2-common cation:
GMPTPS
Molecule-ion, Mol. Mol.:
GMPTB0,GMPTB1,GMPTC
Solid pure (and
mixture)

Enthalpy,
Entropy
CPSP01 or
CPSXP1 to CPSXP7

B-PITZER
The B-PITZER property method is based on the simplified Pitzer aqueous
electrolyte activity coefficient model, which neglects third order interactions.
It can predict the behavior of aqueous electrolyte solutions up to 6 molal ionic
strength. It is not as accurate as ELECNRTL or PITZER with fitted parameters.
But, it is better than using these property methods without interaction
parameters.
coefficients are available from the Aspen Physical Property System databanks
(see Overview of Aspen Physical Property Methods).
Heats of mixing are calculated using the Bromley-Pitzer model.
The Redlich-Kwong-Soave equation of state is used for the vapor phase
fugacity coefficient. All other vapor phase properties are assumed ideal.
Redlich-Kwong-Soave cannot model association behavior in the vapor phase
(for example with carboxylic acids or HF). For carboxylic acids, choose a non-
electrolyte activity coefficient model with Hayden-O'Connell or Nothnagel; for
HF choose ENRTL-HF or WILS-HF.
Mixture Types
You can use the B-PITZER model for any aqueous electrolyte solution up to
6M ionic strength, not showing association in the vapor phase.
Range
The parameter requirements for the B-PITZER property method are given in
the following table, and the table labeled Parameters Required for General
and Transport Property Models. For details about the model, see Pitzer
Activity Coefficient Model in Physical Property Models.
Parameters Required for the B-PITZER Property Method
Thermodynamic
Properties
Vapor mixture
Density Redlich-Kwong-Soave TC, PC, OMEGA
Enthalpy,
Entropy,
Gibbs energy
/ Barin correlation
and
Redlich-Kwong
CPIG or CPIGDP or CPIXP1,
CPIXP2, CPIXP3

TC, PC, OMEGA
Liquid mixture
Thermodynamic
Properties
Gibbs energy
Bromley-Pitzer Ionic: GMBPB, GMBPD
Optional:
Cation-anion: GMPTB0,
GMPTB1, GMPTB2, GMPTB3
Anion-anion: GMPTTH
Molecule-ion, Mol.-Mol.:
GMPTB0, GMPTB1
pressure
PLXANT
solvent: HENRY
VLBROC)
Enthalpy,
Entropy
and
vaporization

Criss-Cobble
CPIG or CPIGDP

DHVLDP)

Ions: CPAQ0 or
Ions: IONTYP, S025C
Bromley-Pitzer Ionic: GMBPB, GMBPD
Optional:
Cation-anion: GMPTB0,
GMPTB1, GMPTB2, GMPTB3
Cation-cation:GMPTTH
Anion-anion: GMPTTH
Molecule-ion, Mol.-Mol.:
GMPTB0, GMPTB1
Solid pure (and
mixture)

Enthalpy,
Entropy
CPSP01 or CPSXP1 to CPSXP7

PITZ-HG
The PITZ-HG property method is similar to the PITZER property method,
except it uses the Helgeson model for standard properties calculations. The
Helgeson model is a very accurate and flexible equation of state that
calculates standard enthalpy, entropy, Gibbs free energy and volume for
components in aqueous solutions. The Helgeson model should provide more
accurate enthalpy and Gibbs free energy of process streams up to high
temperatures and pressures. The Helgeson model is also used to calculate
Gibbs free energy for use in estimating chemical equilibrium constants (for
both equilibrium and salt precipitation reactions) when they are missing.
Equilibrium constants calculated using the Helgeson model have been found
to be reasonably accurate and extrapolate well with respect to temperature.
Mixture Types
You can use this property method for any aqueous electrolyte solution up to
6M ionic strength, not showing association in the vapor phase.
Range
The parameter requirements for the PITZ-HG property method are given in
the table labeled Parameters Required for the PITZER Property Method (see
PITZER), and the table labeled Parameters Required for General and
Transport Property Models. For details about the model, see Physical Property
Models.

OLI Property Method
The OLI property method provides accurate results for the thermodynamic
and transport properties of aqueous mixtures and associated immiscible
organic mixtures, using Aspen OLI.
Aspen OLI is a software solution that enables process engineers to quickly
and reliably perform process modeling and analysis of aqueous electrolyte
systems. Together with Aspen Physical Property System-based solids and
electrolytes modeling technology, Aspen OLI Interface provides the chemical
process industries with comprehensive capability to model aqueous electrolyte
systems over the complete concentration range, including most of the
elements in the Periodic Table.
Licensing Structure
Aspen OLI consists of two parts:
Aspen OLI Interface provided by AspenTech. The interface is included with
Aspen Plus and Aspen Properties and is provided without additional
license.
OLI Alliance Suite for Aspen OLI licensed by OLI Systems.
Existing customers of Aspen OLI are entitled to the OLI license automatically.
However, new customers of Aspen OLI will need to sign a contract with OLI
Systems. OLI Systems will provide the necessary software license manager,
Hardlock security key and serial number required to access the OLI Alliance
Suite for Aspen OLI.
To obtain a license, please contact OLI Systems:
OLI Systems, Inc.
American Enterprise Park
108 American Road
Morris Plains, NJ 07950
USA
Phone (973) 539-4996
Fax (973) 539-5922
http://www.olisystems.com
Software Installation
Installation of Aspen OLI requires these steps:
1. Contact OLI Systems to obtain the OLI Hardlock security key, serial
number, and password for installing the OLI Alliance Suite as part of the
continued licensing of Aspen OLI.
2. Install the Aspen OLI Interface, a sub-feature of the AES Installation.
When this installation is complete, you will have installed all of the
components required within the Aspen framework to support the OLI
Engine.
3. Install the OLI Alliance Suite for Aspen OLI <version> in order to
complete the installation of Aspen OLI. OLI Alliance Suite for Aspen OLI
<extended version number>.exe will be delivered when the Aspen OLI
Interface is installed (e.g., to C:\Program Files\AspenTech\Aspen OLI
Interface <version>). This is a self-extracting script that installs the
components supplied by OLI in a directory of your choosing (or the default
location C:\Program Files\OLI Systems\Alliance Suites\Aspen OLI
<version>). During the installation, you will be asked to supply the serial
number obtained in step 1.
4. Finally, you will need to use the OLI Hardlock security key and serial
number obtained in step 1 to enable OLIs license manager.

General and Transport Property Model
Parameter Requirements
The following table describes the general and transport property models used
and their parameter requirements for activity coefficient-based electrolyte
property methods.
Parameters Required for General and Transport Property
Models
General
Mass balance,
Conversion Mass-
basisMole-basis
MW
Enthalpy of reaction Solvents, Mol. solutes: DHFORM
Solids,Salts: (DHSFRM or CPSXP1 to CPSXP7)
Ions: DHAQFM
Gibbs energy of
reaction
Solvents, Mol. solutes: DGFORM
Solids,Salts: (DGSFRM or CPSXP1 to CPSXP7)
Ions: DGAQFM
Vapor mixture
DIPPR
LJPAR)) or MUVDIP
Thermal
conductivity
LJPAR)
Surface tension Hakim-Steinberg-Stiel/ DIPPR
Onsager-Samaras
Solv., Mol.sol.: (TC, PC,
OMEGA) or SIGDIP
Ion: CHARGE
Liquid mixture
Viscosity Andrade/DIPPR
Jones-Dole
Solv., Mol.sol.: MULAND or
MULDIP
Ion: IONMUB, IONMOB
Thermal
Conductivity
Sato-Riedel/ DIPPR
Riedel
Solv., Mol.sol.: (MW, TC, TB) or
KLDIP
Ion: IONRDL
Diffusivity Wilke-Chang
Nernst-Hartley
Solv., Mol.sol.: MW, VB
Ion: CHARGE, IONMOB
Note: For surface tension and liquid mixture properties, the second method is
used only for rigorous electrolyte properties.

Solids Handling Property
Method
The SOLIDS property method is designed for many kinds of solids processing:
Coal processing
Pyrometallurgical processes
Miscellaneous other solids processing (such as starch and polymers)
The properties of solids and fluid phases cannot be calculated with the same
type of models. Therefore the components are distributed over the
substreams of types MIXED, CISOLID and NC and their properties are
calculated with appropriate models (for details on the use of substreams, see
Aspen Plus User Guide, Chapter 9).
During the mechanical processing of raw materials (ore, coal, wood), physical
properties can often be handled as nonconventional components with an
overall density and an overall heat capacity. The characterization of
nonconventional components and the specification of property models is
discussed in the Aspen Plus User Guide, Chapter 7. Details on
nonconventional property methods are given in Nonconventional Component
Enthalpy Calculation in Overview of Aspen Physical Property Methods. Details
on nonconventional property models are given in Physical Property Models.
When the solids are decomposed into individual components (for example, to
selectively undergo chemical reactions), they occur in the CISOLID
substream. The property models for these components are pure component
property models of the polynomial type. The components are not in phase
equilibrium with the fluid components. Some examples are coal dust in air,
burning carbon, and sand in water.
In pyrometallurgical applications, a CISOLID component can be in
simultaneous phase and chemical equilibrium. This can happen only in the
RGIBBS model, an equilibrium reactor based on Gibbs energy minimization.
Under other conditions, the CISOLID component can undergo reactions but
not phase equilibrium. As another exception, homogeneous solid mixture
phases can occur in the same reactor. The nonideality of solid mixtures can
be handled using activity coefficient models. To distinguish a solid mixture
from single CISOLID components, they are placed in the MIXED substream.
In pyrometallurgical applications, many phases can occur simultaneously.
These phases may need to be treated with different activity coefficient models
(use the SOLIDS property method). For details, see Getting Started Modeling
Processes with Solids.
Fluid components always occur in the MIXED substream. They are treated
with the same fluid phase models as discussed in IDEAL. If non-ideality in the
liquid phase occurs, the ideal activity coefficient model can be replaced.
Permanent gases may be dissolved in the liquid. You can model them using
Henry's law, which is valid at low concentrations.
Hydrometallurgical applications cannot be handled by the SOLIDS property
method. Use an electrolyte property method.
The transport property models for the vapor phase are all well suited for ideal
gases. The transport property models for the liquid phase are empirical
equations for fitting of experimental data.
The following table lists the models used in the SOLIDS property method and
their parameter requirements. For details on these models, see Physical
Property Models.
Parameters Required for the SOLIDS Property Method
General
Mass balance,
MW
Free-water option: solubility of water
in organic phase
WATSOL
Enthalpy of reaction DHFORM, (DHSFRM or CPSXP1 to
CPSXP7)
Gibbs energy of reaction DGFORM, (DGSFRM or CPSXP1 to
CPSXP7)
Vapor pure and
mixture

Fugacity
Coefficient
Ideal gas law
Enthalpy,
Entropy,
Gibbs energy
/ Barin correlation
CPIG or CPIGDP or CPIXP1,
CPIXP2, CPIXP3
Density Ideal gas law
Liquid pure and
mixture

Fugacity
Coefficient,
Gibbs energy
pressure /
Barin correlation
PLXANT or
CPIXP1, CPIXP2
Henry's constant Solvent: VC, Solute-solvent:
HENRY
RKTZRA),
Enthalpy,
Entropy
Ideal gas heat capacity/
DIPPR
and
vaporization
CPIG or
CPIGDP

TC, (DHVLWT or DHVLDP)]
DIPPR heat capacity
correlation/
Barin correlation
(CPLDIP or
CPLXP1, CPLXP2
Density Constant Volume,
Ideal mixing
VLCONS
Solid pure (and
mixture)

Fugacity
Coefficient,
Gibbs energy
Solid Antoine vapor pressure /
Barin correlation
PSANT
CPSXP1 to CPSXP7
Enthalpy,
Entropy
polynomial/
Barin correlation
CPSP01 or
CPSXP1 to CPSXP7
Vapor pure and
mixture

DIPPR
LJPAR))
or MUVDIP
Thermal
conductivity
LJPAR)
Surface tension Hakim-Steinberg-Stiel/
DIPPR
(TC, PC, OMEGA) or
SIGDIP
Liquid pure and
mixture

Thermal
Conductivity
Solids pure
Thermal
Conductivity
Solids, polynomial KSPOLY

Steam Tables
The following table lists the names of the two steam table property methods
available in Aspen Physical Property System.
Steam tables can calculate all thermodynamic properties for systems
containing pure water or steam. For mixtures of water and other components,
refer to the beginning of this chapter for more help.
For process calculations, the accuracy of all three models is adequate. The
STEAM-TA method is made up of different correlations covering different
regions of the P-T space. These correlations do not provide continuity at the
boundaries, which can lead to convergence problems and predict wrong
trends. STMNBS2 can also have this problem. STEAMNBS does not have this
problem and it extrapolates better, so it may be a better choice when there
are not other considerations. For similar reasons, it may be better to use
STEAMNBS with property methods such as SRK that calculate water
properties from the free-water property method.
The transport property models for both property methods are from the
International Association for Properties of Steam (IAPS).
All models have built-in parameters. For details, see ASME Steam Tables and
NBS/NRC Steam Tables in Physical Property Models.
Steam Tables Property Methods
Property Method
Name
Models (Steam Tables)
STEAM-TA ASME 1967
STEAMNBS/STMNBS2 NBS/NRC 1984
Common models
IAPS surface tension
IAPS viscosity for water and steam
IAPS thermal conductivity for water and steam

STEAM-TA
The STEAM-TA property method uses the:
1967 ASME steam table correlations for thermodynamic properties
International Association for Properties of Steam (IAPS) correlations for
transport properties
Use this property method for pure water and steam. The Aspen Physical
Property System uses STEAM-TA as the default property method for the free-
water phase, when free-water calculations are performed.
For process calculations, the accuracy of the models is adequate. The STEAM-
TA method is made up of different correlations covering different regions of
the P-T space. These correlations do not provide continuity at the boundaries,
which can lead to convergence problems and predict wrong trends. For some
applications STEAMNBS may be a better choice.
Range
Use the STEAM-TA property method for pure water and steam with
temperature ranges of 273.15 K to 1073 K. The maximum pressure is 1000
bar.

STEAMNBS/STEAMNBS2
The STEAMNBS/STMNBS2 property methods use:
1984 NBS/NRC steam table correlations for thermodynamic properties
International Association for Properties of Steam (IAPS) correlations for
transport properties
The STMNBS2 uses the same equations as STEAMNBS but with a different
root search method.
Use these property methods for pure water and steam, and in particular for
the free-water phase.
Range
Use the STEAMNBS/STMNBS2 property methods for pure water and steam
with temperature ranges of 273.15 K to 2000 K. The maximum pressure is
over 10000 bar. The STEAMNBS method is recommended for use with the
SRK, BWRS, MXBONNEL and GRAYSON2 property methods.

122 3 Property Calculation Methods and Routes
3 Property Calculation
Methods and Routes
In the Aspen Physical Property System the methods and models used to
calculate thermodynamic and transport properties are packaged in property
methods. Each property method contains all the methods and models needed
for a calculation. A unique combination of methods and models for calculating
a property is called a route.
The Aspen Plus User Guide, Chapter 7, describes the property methods
available in the Aspen Physical Property System, provides guidelines for
choosing an appropriate property method for your calculation, and describes
how to modify property methods to suit your calculation needs by replacing
property models.
This chapter discusses:
Major, subordinate, and intermediate properties in the Aspen Physical
Property System
Calculation methods available
Routing concepts
Property models available
Tracing routes
Modifying and creating property methods
Modifying and creating routes

Introduction
Most properties are calculated in several steps. An example is the calculation
of the fugacity coefficient of a component in a liquid mixture:
i
l
=
i
i
*,l

(1)
Where:
i
*,l

=
i
*,v
p
i
*,l
/ p
(2)
3 Property Calculation Methods and Routes 123
Equations 1 and 2 are both derived from thermodynamics. The equations
relate the properties of interest (
i
l
,
i
*,l
)to other properties (
i
,
i
*,v
, p
i
*,l
) and
state variables (x
i
, p). In general, this type of equation is derived from
universal scientific principles. These equations are called methods.
In the computation of the liquid mixture fugacity, you need to calculate:
Activity coefficient (
i
)
Vapor pressure (p
i
*,l
)
Pure component vapor fugacity coefficient
This type of property is usually calculated using equations that depend on
universal parameters like T
c
and p
c
; state variables, such as T and p; and
correlation parameters. The use of correlation parameters makes these
equations much less universal and more subjective than methods. For
distinction, we call them models. Often several models exist to calculate one
property. For example, to calculate
i
you can use the NRTL, UNIQUAC, or
UNIFAC model.
The reason for treating models and methods separately is to allow for
maximum flexibility in property calculations. Therefore the descriptions
provided should help show the flexibility of the Aspen Physical Property
System, rather than constitute definitions. For detailed descriptions and lists
of available methods and models, see Methods and Routes and Models.
A complete calculation route consists of a combination of methods and
models. A number of frequently used routes have been defined in the Aspen
Physical Property System. Routes that belong logically together have been
grouped to form property methods. For more about property methods, see
Property Method Descriptions. Routes are discussed in detail in Routes and
Models.
To choose a different calculation route for a given property route than what is
defined in a property method, you can exchange routes or models in property
methods (See Modifying and Creating Property Methods).
For a specific property, there are many choices of models and methods used
to build a route. Therefore the Aspen Physical Property System does not
contain all possible routes as predefined routes. However you can freely
construct calculation routes according to your needs. This is a unique feature
of the Aspen Physical Property System. Modifying and creating new routes
from existing methods, routes and models, and using them in modified or
new property methods is explained in Modifying and Creating Routes.

Physical Properties in the
System
The following properties may be required by Aspen Physical Property System
calculations:
Fugacity coefficients (for K values)
Enthalpy
Entropy
Gibbs energy
Molar volume
Viscosity
Surface tension
The properties required by unit operation models in the Aspen Physical
Property System are called major properties and are listed in the table labeled
Major Properties in the Aspen Physical Property System. A major property
may depend on other major properties. In addition, a major property may
depend on other properties that are not major properties. These other
properties can be divided into two categories: subordinate properties and
intermediate properties.
Subordinate properties may depend on other major, subordinate or
intermediate properties, but are not directly required for unit operation model
calculations. Examples of subordinate properties are enthalpy departure and
excess enthalpy. The table labeled Subordinate Properties in the Aspen
Physical Property System lists the subordinate properties.
Intermediate properties are calculated directly by property models, rather
than as fundamental combinations of other properties. Common examples of
intermediate properties are vapor pressure and activity coefficients. The table
labeled Intermediate Properties in the Aspen Physical Property System lists
the intermediate properties.
Major and subordinate properties are obtained by a method evaluation.
Intermediate properties are obtained by a model evaluation.

Major Properties in the Aspen Physical
Property System
Property
Name
Symbol Description
PHIV
i
*,v

Vapor pure component fugacity coefficient
PHIL
i
*,l

Liquid pure component fugacity coefficient
PHIS
i
*,s

Solid pure component fugacity coefficient
PHIVMX
i
v

Vapor fugacity coefficient of a component in
a mixture
PHILMX
i
l

Liquid fugacity coefficient of a component in
a mixture
PHISMX
i
s

Solid fugacity coefficient of a component in a
mixture
Property
Name
Symbol Description
HV H
i
*,v
Vapor pure component molar enthalpy
HL H
i
*,l
Liquid pure component molar enthalpy
HS H
i
*,s
Solid pure component molar enthalpy
HVMX H
m
v
Vapor mixture molar enthalpy
HLMX H
m
l
Liquid mixture molar enthalpy
HSMX H
m
s
Solid mixture molar enthalpy
GV
i
*,v

Vapor pure component molar Gibbs free
energy
GL
i
*,l

Liquid pure component molar Gibbs free
energy
GS
i
*,s

Solid pure component molar Gibbs free
energy
GVMX G
m
v
Vapor mixture molar Gibbs free energy
GLMX G
m
l
Liquid mixture molar Gibbs free energy
GSMX G
m
s
Solid mixture molar Gibbs free energy
SV S
i
*,v
Vapor pure component molar entropy
SL S
i
*,l
Liquid pure component molar entropy
SS S
i
*,s
Solid pure component molar entropy
SVMX S
m
v
Vapor mixture molar entropy
SLMX S
m
l
Liquid mixture molar entropy
SSMX S
m
s
Solid mixture molar entropy
VV V
i
*,v
Vapor pure component molar volume
VL V
i
*,l
Liquid pure component molar volume
VS V
i
*,s
Solid pure component molar volume
VVMX V
m
v
Vapor mixture molar volume
VLMX V
m
l
Liquid mixture molar volume
VSMX V
m
s
Solid mixture molar volume
MUV
i
*,v

Vapor pure component viscosity
MUL
i
*,l

Liquid pure component viscosity
MUVMX
v

Vapor mixture viscosity
MULMX
l

Liquid mixture viscosity
KV
i
*,v

Vapor pure component thermal conductivity
KL
i
*,l

Liquid pure component thermal conductivity
KS
i
*,s

Solid pure component thermal conductivity
KVMX
v

Vapor mixture thermal conductivity
KLMX
l

Liquid mixture thermal conductivity
KSMX
s

Solid mixture thermal conductivity
DV D
ij
v
Vapor binary diffusion coefficient
DL D
ij
l
Liquid binary diffusion coefficient
Property
Name
Symbol Description
DVMX D
i
v
Vapor diffusion coefficient of a component in
a mixture
DLMX D
i
l
Liquid diffusion coefficient of a component in
a mixture
SIGL
i
*,l

Pure component surface tension
SIGLMX

l

Mixture surface tension

Subordinate Properties in the Aspen
Physical Property System
Property
Name
Symbol Description
DHV H
i
*,v
- H
i
*,ig
Vapor pure component molar enthalpy
departure
DHL H
i
*,l
- H
i
*,ig
Liquid pure component molar enthalpy
departure
DHS H
i
*,s
- H
i
*,ig
Solid pure component molar enthalpy
departure
DHVMX H
m
v
- H
m
ig
Vapor mixture molar enthalpy departure
DHLMX H
m
l
- H
m
ig
Liquid mixture molar enthalpy departure
DHSMX H
m
s
- H
m
ig
Solid mixture molar enthalpy departure
DHVPC H
i
*,v
(p) - H
i
*,v
(p
i
*
) Vapor pure component molar enthalpy
departure pressure correction
DHLPC H
i
*,l
(p) - H
i
*,s
(p
i
*
) Liquid pure component molar enthalpy
DHSPC H
i
*,l
(p) - H
i
*,s
(p
i
*
) Solid pure component molar enthalpy
DGV
i
*,v
-
i
*,ig

Vapor pure component molar Gibbs energy
departure
DGL
i
*,l
-
i
*,ig

Liquid pure component molar Gibbs energy
departure
DGS
i
*,s
-
i
*,ig

Solid pure component molar Gibbs energy
departure
DGVMX G
m
v
- G
m
ig
Vapor mixture molar Gibbs energy departure
DGLMX G
m
l
- G
m
ig
Liquid mixture molar Gibbs energy departure
DGSMX G
m
s
- G
m
ig
Solid mixture molar Gibbs energy departure
DGVPC
i
*,v
(p) -
i
*,v
(p
i
*
)
Vapor pure component molar Gibbs energy
DGLPC
i
*,l
(p) -
i
*,l
(p
i
*
)
Liquid pure component molar Gibbs energy
DGSPC
i
*,s
(p) -
i
*,s
(p
i
*
)
Solid pure component molar Gibbs energy
DSV S
i
*,v
- S
i
*,ig
Vapor pure component molar entropy
departure
Property
Name
Symbol Description
DSL S
i
*,l
- S
i
*,ig
Liquid pure component molar entropy
departure
DSS S
i
*,s
- S
i
*,ig
Solid pure component molar entropy
departure
DSVMX S
m
v
- S
m
ig
Vapor mixture molar entropy departure
DSLMX S
m
l
- S
m
ig
Liquid mixture molar entropy departure
DSSMX S
m
s
- S
m
ig
Solid mixture molar entropy departure
HNRY H
iA
Henry's constant of supercritical component i
in subcritical component A
HLXS H
m
E,l
Liquid mixture molar excess enthalpy
HSXS H
m
E,s
Solid mixture molar excess enthalpy
GLXS G
m
E,l
Liquid mixture molar excess Gibbs energy
GSXS G
m
E,s
Solid mixture molar excess Gibbs energy
PHILPC
*,l

Pure component liquid fugacity coefficient
pressure correction
PHISPC
*,s

Pure component solid fugacity coefficient
pressure correction
GAMPC

E

Liquid activity coefficient pressure correction,
symmetric convention
GAMPC1
*E

Liquid activity coefficient pressure correction,
asymmetric convention
HNRYPC

Henry's constant pressure correction for
supercritical component i in subcritical
component A
XTRUE x
t
True composition
MUVLP
i
*,v
(p=0)
Pure component low pressure vapor viscosity
MUVPC
i
*,v
(p) -
i
*,v
(p=0)
Pure component vapor viscosity pressure
correction
MUVMXLP
v
(p=0)
Low pressure vapor mixture viscosity
MUVMXPC
v
(p) -
v
(p=0)
Vapor mixture viscosity pressure correction
KVLP
i
*,v
(p=0)
Pure component low pressure vapor thermal
conductivity
KVLP
i
*,v
(p) -
i
*,v
(p=0)
Pure component vapor thermal conductivity
pressure correction
KVMXLP
v
(p=0)
Low pressure, vapor mixture thermal
conductivity
KVMXPC
v
(p) -
v
(p=0)
Vapor mixture thermal conductivity pressure
correction

Intermediate Properties in the Aspen
Physical Property System
Property
Name
Symbol Description
GAMMA

Liquid phase activity coefficient
GAMUS
*

Liquid phase activity coefficient,
unsymmetric convention
GAMMAS

s

Solid phase activity coefficient
WHNRY w Henry's constant mixing rule weighting
factor
PL p
i
*,l
Liquid pure component vapor pressure
PS p
i
*,s
Solid pure component vapor pressure
DHVL
vap
H
i
*

Pure component enthalpy of vaporization
DHLS
fus
H
i
*

Pure component enthalpy of fusion
DHVS
sub
H
i
*

Pure component enthalpy of sublimation
VLPM V
i
l
Partial molar liquid volume

Methods
This section describes the methods available for calculating the major and
subordinate properties in the Aspen Physical Property System.
A method is an equation used to calculate physical properties based on
universal scientific principles only, such as thermodynamics. This equation
may contain assumptions, such as the vapor can be treated as ideal gas or
the pressure is low enough to neglect the pressure correction. The equation
may need properties and state variables but not correlation parameters to
calculate a specific property.
Applied thermodynamics indicate that there usually is more than one method
for calculating a particular property. For example, the enthalpy departure of a
component in the liquid phase, H
i
*,l
- H
i
*,ig
can be calculated from its fugacity
coefficient in the liquid phase:

This method is often used for supercritical solutes in liquid solution.
Alternatively, the liquid departure function can be calculated from the vapor
enthalpy departure and the heat of vaporization:

Both methods are equally valid. There is another possibility, which is to
calculate the departure function directly by an equation of state. Equations of
state use correlation parameters and are therefore classified as models, so:

This is not a method but rather a valid alternative to calculate the enthalpy
departure. To make the model available to the list of methods, a simple
method is used that refers to a model:

In general, a list of methods available for a property will be similar to the list
presented here for the enthalpy departure. Compare these tables:
Vapor Fugacity Coefficient
Methods
Vapor Entropy Methods
Liquid Fugacity Coefficient
Methods
Liquid Entropy Methods
Solid Fugacity Coefficient
Methods
Solid Entropy Methods
Vapor Enthalpy Methods Molar Volume Methods
Liquid Enthalpy Methods Viscosity Methods
Solid Enthalpy Methods Thermal Conductivity Methods
Vapor Gibbs Energy Methods Diffusion Coefficient Methods
Liquid Gibbs Energy Methods Surface Tension Methods
Solid Gibbs Energy Methods
In a method you can have any number of major properties, subordinate
properties, or models. Usually there is a method that can be used with an
equation of state approach and an alternative that is used with the activity
coefficient approach (see Thermodynamic Property Methods in Overview of
Aspen Physical Property Methods). There is always a method that refers to a
model. Although there are a limited number of thermodynamic methods, in
general, all the existing thermodynamic methods for each property are
present.
Transport property methods are not as universal as thermodynamic methods.
Therefore the transport property methods offered in the Aspen Physical
Property System might not be exhaustive, but multiple methods for one
property also exist.
All physical property methods available for calculating major and subordinate
properties in the Aspen Physical Property System are provided in the physical
property methods tables listed above. For each major or subordinate
property, these tables list:
Property symbol and name
Property type: major or subordinate
Methods available for calculating the property
For each method the fundamental equation is given. The table also lists which
information is needed to specify each step in the method (see Routes and
Models).

Example: Methods for calculating liquid
mixture enthalpy
From the table labeled Liquid Enthalpy Methods, there are four methods for
calculating HLMX:
Method 1 HLMX is calculated directly by an empirical model. The model may
depend on temperature T, pressure p, liquid composition, and certain model
specific parameters.

Method 2 HLMX is calculated from the ideal liquid mixture enthalpy and
excess enthalpy.

The major property HLMX depends on the liquid pure component enthalpy,
HL, and the liquid mixture excess enthalpy, HLXS. HL is also a major
property, while HLXS is a subordinate property.
Method 3 HLMX is calculated from the ideal gas mixture enthalpy, HIGMX, and
the liquid mixture enthalpy departure, DHLMX.

(HLMX = HIGMX + DHLMX)
The subordinate property DHLMX can be calculated by one of the methods
listed in the table labeled Liquid Enthalpy Methods. In all the equation of state
property methods, DHLMX is calculated directly by an equation of state (that
is, method 1 is used for DHLMX).
Method 4 HLMX is calculated directly by the Electrolyte model.

Where:
x
t
= The component true mole fractions
(x
t
is also the symbol for the subordinate property XTRUE:
HLMX = f (XTRUE)).

Vapor Fugacity Coefficient Methods
Property
Symbol
and Name

Property
Type

Method
Code

Method

Route Structure
Information Required
i
*,v

PHIV
Major 1 Specified
model
i
*,v
Model name
i
v

PHIVMX
Major 1 Specified
model
i
v
Model name (Default:
i
v
=1)
2
i
v
=f(y
i
,
i
*,v
)
i
*,v
Route ID
i
v
Model name
3
i
v
=f(
i
)
i
Model name
i
v
Model name

Liquid Fugacity Coefficient Methods
Property
Symbol
and Name
Property
Type
Method
Code

Method
Route Structure
Information
Required
i
*,l

PHIL
Major 1 Specified model
i
*,l
Model name
2

p
*,l
Model name
i
*,v
Model name
(Default:
i
*,v
= 1)

*,l
Route ID
(Default:
*,l
= 1)
3 Specified model for supercritical
components

For subcritical components:

i
*,l
Model name
p
*,l
Model name
i
*,l
Model name
V
i
*,l
Model Name
4 Steam table for water, otherwise from

p
*,l
Model name
i
*,v
Model name
(Default:
i
*,v
= 1)

*,l
Route ID
(Default:
*,l
= 1)
i
*,l

PHILPC
Subord. 1

p
*,l
Model name
V
i
*,l
Model Name
Integration option
code
(Default:1 point)
2 Specified model
i
*,l
Model name
i
l

PHILMX
i
l
Model name
2
i
*,l
i
E

i
Model name
(Default:
i
= 1)
i
*,l
Route ID
i
E
Route ID
(Default:
i
E
= 1)
Property
Symbol
and Name
Property
Type
Method
Code

Method
Route Structure
Information
Required
3 Unsymmetric Convention
For subcritical components (A or B):
A
*,l
Route ID

A
l
=
A
A
*,l

A
Model name
(Default:
A
= 1)
For supercritical components (i or j)

Where:

H
jA
Route ID

w
B
Model name

w
B
Model option code
(see Model Option
Code Help)

Method Option code
0: Do not calculate H
i

1: Calculate H
i

(Default = 0 )
4

i
Model name
(Default:
i
= 1)
i
*,l
Route ID
i
E
Route ID
(Default:
i
E
= 1)
Where:

i
= f(x
t
) (Default:
i
E
= 1)
x
t
Route ID
5 Unsymmetric Convention
For subcritical components (A or B):
i
*,l
Route ID

A
Model name
(Default:
A
= 1)
Where:

x
t
Route ID
For supercritical components (i or j)

Where:
Property
Symbol
and Name
Property
Type
Method
Code

Method
Route Structure
Information
Required
H
jA
Route ID

w
B
Model name

w
B
Model option code
(see Model Option
Code Help)

Method Option code
0: Do not calculate H
i

1: Calculate H
i

(Default = 0 )
6
i
l
= f(
i
)
i
Model name
i
l
Model name
7 Similar to method 3, but the fugacity coefficients of some
components can be overridden by a special PHILMX model.
Currently, this method is used to override the fugacity
coefficients of CO2, H2S, NH3, and H2O calculated by an activity
coefficient property method by the API sour water model.
x
t

XTRUE
Subord. 1

i
Model name
i
E

GAMPC
Subord. 1

V
i
l
Model name
V
i
*,l
Model name
Integration option
code
(Default: 1 point)
2 Specified model
i
E
Model name
i
*,E

GAMPC1
Subord. 1

V
i
l
Model name
Integration option
code
(Default: 1 point)
2 Specified model
i
*,E
Model name
H
iA

HNRY
Subord. 1 Specified model H
iA
Model name
2

H
iA
Model name
Route ID
(Default: = 1)
p
ref
defined by the
p
ref
option code of
HNRYPC
Property
Symbol
and Name
Property
Type
Method
Code

Method
Route Structure
Information
Required

HNRYPC
Subord. 1

p
A
*,l
Model name (if
needed for p
ref

prefOption code
1: pref= 0
2: pref= 1 atm
3: pref= p
A
*,l
(T)
(Default = 2)

Model name
Integration code
(Default: 1 point)
2 Specified model
Model name
For calculating fugacity coefficients, H
i
is not needed explicitly; the quantity
needed is . Methods which can calculate this quantity directly have an
option code to force the calculation of H
i
. This can be set to 1 when H
i
is
needed for prop-set property reporting. Certain property methods need H
i
for
other reasons and these methods set this option code to 1.

Solid Fugacity Coefficient Methods
Property
Symbol and
Name
Property
Type
Method
Code

Method
Route Structure
Information
Required
i
*,s

PHIS
Major 1 Specified Model
i
*,s
Model name
2

p
i
*,s
Model name
i
*,v
Model name
(Default:
i
*,v
= 1)
i
*,s
Route ID
(Default:
i
*,s
= 1)
3
i
*,s
i
*,l

i
*,s
Model name
i
*,l
Route ID
i
*,s

PHISPC
Subord. 1

p
i
*,s
Model name
V
i
*,s
Model name
Integration option code
(Default: 1 point)
2 Specified model
i
*,s
Model name
i
s

PHISMX
i
s
Model name
2
i
s
= f(x
i
s
,
i
*,s
)
i
*,s
Route ID
i
s
Model name
Property
Symbol and
Name
Property
Type
Method
Code

Method
Route Structure
Information
Required
3
i
s
i
*,s

i
s
Model name
i
*,s
Route ID

Vapor Enthalpy Methods
Property
Symbol and
Name
Property
Type
Method
Code

Method
Route Structure
H
i
*,v

HV
Major 1 Specified model H
i
*,v
Model name
2

(H
i
*,v
- H
i
*,ig
) Route ID
(Default: H
i
*,v
- H
i
*,ig
=0)
3
H
i
*,l
+
vap
H
i
*

H
i
*,l
Route ID
vap
H
i
*
Model name
H
i
*,v
- H
i
*,ig

DHV
Subord. 1 Specified model (H
i
*,v
- H
i
*,ig
) Model
name
2

i
*,v
Model name
H
m
v

HVMX
m
v
Model name
2

H
i
*,v
Route ID
3 H
m
ig
+ (H
m
v
- H
m
ig
) (H
m
v
- H
m
ig
) Route ID
(Default: H
m
v
- H
m
ig
=0)
4 Specified model H
i
*,v
H
i
*,v
Route ID
H
m
v
Model name used
to provide mixing rules
for the pure component
property H
i
*,v

H
m
v
- H
m
ig
DHVMX
m
v
- H
m
ig
) Model name
2

i
v
Model name
3
H
m
v
- H
m
ig
= f(
i
)
i
Model name
Equation of state model
name

Liquid Enthalpy Methods
Property
Symbol
and
Name
Property
Type
Method
Code

Method
Route Structure
Information
Required
H
i
*,l

HL
i
*,l
Model name
2 H
i
*,ig
+ (H
i
*,l
- H
i
*,ig
) (H
i
*,l
- H
i
*,ig
) Route ID
H
i
*,l
-
H
i
*,ig

DHL
i
*,l
- H
i
*,ig
) Model
name
2

i
*,l
Model name
3 (H
i
*,v
(T, p
i
*,l
) - H
i
*,ig
(T))
-
vap
H
i
*
(T)
+ (H
i
*,l
(T, p) - H
i
*,l
(T, p
i
*,l
))
p
i
l
Model name
(H
i
*,v
- H
i
*,ig
) Route ID
(Default: H
i
*,v
- H
i
*,ig

= 0)
vap
H
i
l
Model name
(H
i
*,l
(T, p) - H
i
*,l
(T,
p
i
*,l
)) Route ID
(Default: (H
i
*,l
(T, p) -
H
i
*,l
(T, p
i
*,l
)) = 0)
4 (H
i
*,v
(T, p
i
*,l
) - H
i
*,ig
(T))
-
vap
H
i
*
(T)
+ (H
i
*,l
(T, p) - H
i
*,l
(T, p
i
*,l
))
for polymer property method
p
i
l
Model name
(H
i
*,v
- H
i
*,ig
) Route ID
(Default: H
i
*,v
- H
i
*,ig

= 0)
vap
H
i
l
Model name
(H
i
*,l
(T, p) - H
i
*,l
(T,
p
i
*,l
)) Route ID
(Default: (H
i
*,l
(T, p) -
H
i
*,l
(T, p
i
*,l
)) = 0)
5 (H
i
*,v
(T, p
i
*,l
) - H
i
*,ig
(T))
-
vap
H
i
*
(T)
+ (H
i
*,l
(T, p) - H
i
*,l
(T, p
i
*,l
))
for electrolyte activity coefficient
property method
p
i
l
Model name
(H
i
*,v
- H
i
*,ig
) Route ID
(Default: H
i
*,v
- H
i
*,ig

= 0)
vap
H
i
l
Model name
(H
i
*,l
(T, p) - H
i
*,l
(T,
p
i
*,l
)) Route ID
(Default: (H
i
*,l
(T, p) -
H
i
*,l
(T, p
i
*,l
)) = 0)
(H
i
*,l
(T,
p) -
H
i
*,l
(T,
p
i
*,l
))
DHLPC
Subord. 1 (H
i
*,l
(T, p) - H
i
*,ig
(T)) -
(H
i
*,l
(T, p
i
*,l
) - H
i
*,ig
(T))
p
i
*,l
Model name
(H
i
*,l
- H
i
*,ig
) Route ID
2

p
i
*,l
Model name
Property
Symbol
and
Name
Property
Type
Method
Code

Method
Route Structure
Information
Required
V
i
*,l
Model name
Integration option
code
(Default: 1 point )
3 Specified model
Model name
H
m
l

HLMX
m
l
Model name
2

H
i
*,l
Route ID
H
i
E,l
Route ID
(Default: =0)
3 H
m
ig
+ (H
m
l
- H
m
ig
) (H
m
l
- H
m
ig
) Route ID
4 Electrolyte model (x
t
) H
m
l
Model name
x
t
Route ID
5 Specified model H
i
*,l
H
i
*,l
Route ID
H
m
l
Model name used
to provide mixing
rules for the pure
component property
H
i
*,l

6 H
m
ig
+ (H
m
l
- H
m
ig
) for electrolyte
system
(H
m
l
- H
m
ig
) Route ID
H
m
l
- H
m
ig

DHLMX
m
l
- H
m
ig
) Model
name
2

(H
i
*,l
- H
i
*,ig
) Route ID
H
m
E,l
Route ID
(Default: H
m
E,l
= 0)
Property
Symbol
and
Name
Property
Type
Method
Code

Method
Route Structure
Information
Required
3 Unsymmetric convention
For subcritical components A or B:

For supercritical component i or j:

where:

(H
A
*,l
- H
A
*,ig
) Route
ID
where:
B
Model name

H
iB
Route ID

w
B
Model name
w
B
Model option code
(see Model Option
Code Help)
4 Special mixing rule for Aspen
Polymers

M
i
Reference mole
weight (from
parameter MW)
M
i
t
True number-
average mole weight
i
Model name
Equation of state
model name
Property
Symbol
and
Name
Property
Type
Method
Code

Method
Route Structure
Information
Required
5 Unsymmetric convention for Aspen
Polymers
For subcritical components A or B:

For supercritical component i or j:

where:

(H
A
*,l
- H
A
*,ig
) Route
ID
where:
B
Model name
M
i
Reference mole
weight (from
parameter MW)
M
i
t
True number-
average mole weight

H
iB
Route ID

w
B
Model name
w
B
Model option code
(see Model Option
Code Help)
6 Unsymmetric convention, as in
method 3 but for electrolyte activity
coefficient property method
(H
A
*,l
- H
A
*,ig
) Route
ID
B
Model name
H
iB
Route ID
w
B
Model name
w
B
Model option code
H
m
E,l

HLXS
m
E,l
Model name
2

i
Model name
3 Method for Aspen Polymers only:

i
Model name
M
i
Reference mole
weight (from
parameter MW)
M
i
t
True number-
average mole weight

Solid Enthalpy Methods
Property
Symbol
and Name
Property
Type
Method
Code

Method
Route Structure
H
i
*,s

HS
i
*,s
Model name
2 H
i
*,ig
+ (H
i
*,s
- H
i
*,ig
) (H
i
*,s
- H
i
*,ig
) Route ID
H
i
*,s
- H
i
*,ig

DHS
i
*,s
- H
i
*,ig
) Model name
2 (H
i
*,v
(T,p
i
*,s
) - H
i
*,ig
(T))
-
sub
H
i
*
(T)
+ (H
i
*,s
(T,p) - H
i
*,s
(T,p
i
*,s
))
p
i
*,s
Model name
(H
i
*,v
- H
i
*,ig
) Route ID
(Default: H
i
*,v
- H
i
*,ig
= 0 )
sub
H
i
*
(T) Model name
(H
i
*,s
(T,p) - H
i
*,s
(T,p
i
*,s
))
Route ID (Default:
H
i
*,s
(T,p) - H
i
*,s
(T,p
i
*,s
) =
0)
H
i
*,s
(T,p) -
H
i
*,s
(T,p
i
*,s
)
DHSPC
Subord. 1

p
i
*,s
Model name
V
i
*,s
Model name
(Default: 1 point)
H
m
s

HSMX
m
s
Model name
2

H
i
*,s
Route ID
H
m
E,s
Route ID
(Default: H
m
E,s
= 0 )
3 H
m
ig
+ (H
m
s
- H
m
ig
) (H
m
s
- H
m
ig
) Route ID
4 Specified model H
i
*,s
H
i
*,s
Route ID
H
m
s
Model name used to
provide mixing rules for
the pure component
property H
i
*,s

H
m
s
- H
m
ig

DHSMX
m
s
- H
m
ig
) Model name
2

(H
i
s
- H
i
ig
) Route ID
H
m
E,s
Route ID
(Default: H
m
E,s
= 0 )
H
m
E,s

HSXS
m
E,s
Model name
2

i
Model name

Vapor Gibbs Energy Methods
Property
Symbol
and Name
Property
Type
Method
Code

Method
Route Structure
i
*,v

GV
i
*,v
Model name
Property
Symbol
and Name
Property
Type
Method
Code

Method
Route Structure
2
i
*,ig
+ (
i
*,v
-
i
*,ig
) (
i
*,v
-
i
*,ig
) Route ID
(Default:
i
*,v
-
i
*,ig
= 0
)
i
*,v
-
i
*,ig

DGV
Subord. 1 Specified model
(
i
*,v
-
i
*,ig
) Model
name
2

i
*,v
Route ID
G
m
v

GVMX
Major 1 Specified model G
m
v
Model name
2

i
*,v
Route ID
3 G
m
ig
+ (G
m
v
- G
m
ig
) (G
m
v
- G
m
ig
) Route ID
(Default: G
m
v
- G
m
ig
= 0 )
4
Specified model
i
*,v

i
*,v
Route ID
G
m
v
Model name used to
provide mixing rules for
the pure component
property
i
*,v

G
m
v
- G
m
ig

DGVMX
Subord. 1 Specified model (G
m
v
- G
m
ig
) Model name
2

i
v
Route ID
(Default:
i
v
= 1 )
3
G
m
v
- G
m
ig
= f(
i
)
i
Model name
name

Liquid Gibbs Energy Methods
Property
Symbol and
Name
Property
Type
Method
Code

Method
Route Structure
i
*,l

GL
i
*,l
Model name
2
i
*,ig
+ (
i
*,l
-
i
*,ig
) (
i
*,l
-
i
*,ig
) Route ID
i
*,l
-
i
*,ig

DGL
(
i
*,l
-
i
*,ig
) Model name
2

i
*,l
Route ID
Property
Symbol and
Name
Property
Type
Method
Code

Method
Route Structure
3
(
i
*,l
(T,p
i
*,l
) -
i
*,ig
(T))
+ (
i
*,l
(T,p) -
i
*,l
(T,p
i
*,l
))

p
i
*,l
Model name
(
i
*,l
-
i
*,ig
) Route ID
(Default:
i
*,l
-
i
*,ig
= 0)
(
i
*,l
(T,p) -
i
*,l
(T,p
i
*,l
)) Route
ID (Default:
i
*,l
(T,p) -
i
*,l
(T,p
i
*,l
) = 0 )
i
*,l
(T,p) -
i
*,l
(T,p
i
*,l
)
DGLPC
Subord. 1
(
i
*,l
(T,p) -
i
*,ig
(T))
- (
i
*,l
(T,p
i
*,l
) -
i
*,ig
(T))
p
i
*,l
Model name
(
i
*,l
-
i
*,ig
) Route ID
2

p
i
*,l
Model name
V
i
*,l
Model Name
(Default: 1 point)
G
m
l

GLMX
m
l
Model name
2

i
*,l
Route ID
G
m
E,l
Route ID
(Default: G
m
E,l
= 0)
3 G
m
ig
+ (G
m
l
- G
m
ig
)
4 (x
t
) Model name
x
t
Route ID
5

Where TMW is the true
molecular weight for
polymers.
i
*,l
Route ID
G
m
E,l
Route ID
(Default: G
m
E,l
= 0 )
6
Specified model
i
*,l

i
*,l
Route ID
G
m
l
Model name used to
provide mixing rules for the
pure component property
i
*,l

7 G
m
ig
+ (G
m
l
- G
m
ig
)
for electrolyte system

G
m
l
- G
m
ig

DGLMX
m
l
- G
m
ig
) Model name
Property
Symbol and
Name
Property
Type
Method
Code

Method
Route Structure
2

(
i
*,l
-
i
*,ig
) Route ID
G
m
E,l
Route ID
(Default: = 0 )
3

i
l
Route ID
4
G
m
l
- G
m
ig
= f(
i
)
i
Model name
Equation of state model name
5

using electrolyte activity
coefficient model
i
l
Route ID
G
m
E,l

GLXS
Subord. 1 Specified model G
m
E,l
Model name
2

i
Model name
3

Where TMW is the true
molecular weight for
polymers.
i
Model name

Solid Gibbs Energy Methods
Property
Symbol
and Name
Property
Type
Method
Code

Method
Route Structure
i
*,s

GS
i
*,s
Model name
2
i
*,ig
+ (
i
*,s
-
i
*,ig
) (
i
*,s
-
i
*,ig
) Route ID
i
*,s
-
i
*,ig

DGS
(
i
*,s
-
i
*,ig
) Model name
2

i
*,s
Route ID
Property
Symbol
and Name
Property
Type
Method
Code

Method
Route Structure
3
(
i
*,s
(T,p
i
*,s
) -
i
*,ig
(T))
+ (
i
*,s
(T,p) -
i
*,s
(T,p
i
*,s
))

p
i
*,s
Model name
(
i
*,s
(T,p
i
*,s
) -
i
*,ig
(T))Route
ID (Default: (
i
*,s
(T,p
i
*,s
) -
i
*,ig
(T)) = 0)
(
i
*,s
(T,p) -
i
*,s
(T,p
i
*,s
))
Route ID (Default:
(
i
*,s
(T,p) -
i
*,s
(T,p
i
*,s
)) = 0
)
i
*,s
(T,p) -
i
*,s
(T,p
i
*,s
)
DGSPC
Subord. 1

p
i
*,l
Model name
V
i
*,l
Model Name
(Default: 1 point)
G
m
s

GSMX
m
s
Model name
2

i
*,s
Route ID
G
m
E,s
Route ID
(Default: G
m
E,s
= 0 )
3 G
m
ig
+ (G
m
s
- G
m
ig
)
4
Specified model
i
*,s
Route ID
G
m
s
Model name used to
provide mixing rules for the
pure component property
i
*,s

G
m
s
- G
m
ig

DGSMX
m
s
- G
m
ig
) Model name
2

(
i
*,s
-
i
*,ig
) Route ID
G
m
E,s
Route ID
(Default: G
m
E,s
= 0 )
G
m
E,s

GSXS
Subord. 1 Specified model G
m
E,s
Model name
2

i
Model name

Vapor Entropy Methods
Property
Symbol
and Name
Property
Type
Method
Code
Method Route Structure
S
i
*,v

SV
Major 1

H
i
*,v
Route ID
Property
Symbol
and Name
Property
Type
Method
Code
Method Route Structure
2 S
i
*,ig
+ (S
i
*,v
- S
i
*,ig
) (S
i
*,v
- S
i
*,ig
) Route ID
(Default: S
i
*,v
- S
i
*,ig
= 0 )
3 Specified model S
i
*,v
Model name
S
i
*,v
- S
i
*,ig

DSV
Subord. 1

(H
i
*,v
- H
i
*,ig
) Route ID
(Default: H
i
*,v
- H
i
*,ig
= 0 )
(
i
*,v
-
i
*,ig
) Route ID
(Default:
i
*,v
-
i
*,ig
= 0)
2

(
i
*,v
-
i
*,ig
) Model name
Specified model S
i
*,v
- S
i
*,ig
Model name
S
m
v

SVMX
Major 1

H
m
v
Route ID
G
m
v
Route ID
2 S
m
ig
+ (S
m
v
- S
m
ig
) (S
m
v
- S
m
ig
) Route ID
(Default: S
m
v
- S
m
ig
= 0 )
3 Specified model S
m
v
Model name
S
m
v
- S
m
ig

DSVMX
Subord. 1 Specified model (S
m
v
- S
m
ig
) Model name
2

(H
m
v
- H
m
ig
) Route ID
(Default: H
m
v
- H
m
ig
= 0 )
(G
m
v
- G
m
ig
)Route ID
(Default G
m
v
- G
m
ig
= 0)
3

(G
m
v
- G
m
ig
) Model name
4
S
m
v
- S
m
ig
= f(
i
)
i
Model name
name

Liquid Entropy Methods
Property
Symbol
and
Name
Property
Type
Method
Code

Method
Route Structure
Information
Required
S
i
*,l

SL
Major 1

H
i
*,l
Route ID
i
*,l
Route ID
2 S
i
*,ig
+ (S
i
*,l
- S
i
*,ig
) (S
i
*,l
- S
i
*,ig
) Route ID
3 Specified model S
i
*,l
Model name
S
i
*,l
- S
i
*,ig

DSL
Subord. 1 (H
i
*,l
- H
i
*,ig
) Route ID
Property
Symbol
and
Name
Property
Type
Method
Code

Method
Route Structure
Information
Required
2

(
i
*,l
-
i
*,ig
) Route ID
(
i
*,l
-
i
*,ig
) Model
name
3 Specified Model (S
i
*,l
- S
i
*,ig
) Model
name
S
m
l

SLMX
Major 1

H
m
l
Route ID
G
m
l
Route ID
2 S
m
ig
+ (S
m
l
- S
m
ig
) (S
m
l
- S
m
ig
) Route ID
3 Specified model S
m
l
Model name
4 S
m
l
= f(H
m
l
, G
m
l
, x
t
) H
m
l
model
G
m
l
model
x
t
Route ID
5

for electrolyte system
H
m
l
Route ID
G
m
l
Route ID
S
m
l
- S
m
ig

DSLMX
m
l
- S
m
ig
) Model name
2

(H
m
l
- H
m
ig
) Route ID
(G
m
l
- G
m
ig
) Route ID
3

(G
m
l
- G
m
ig
) Model
name
4
S
m
l
- S
m
ig
= f(
i
)
i
Model name
name

Solid Entropy Methods
Property
Symbol
and
Name
Property
Type
Method
Code

Method
Route Structure
Information
Required
S
i
*,s

SS
Major 1 Specified model S
i
*,s
Model name
2

H
i
*,s
Route ID
i
*,s
Route ID
S
i
*,s
- S
i
*,ig

DSS
Subord. 1

(H
i
*,s
- H
i
*,ig
) Route ID
(
i
*,s
-
i
*,ig
) Route ID
2 Specified model (S
i
*,s
- S
i
*,ig
) Model
name
Property
Symbol
and
Name
Property
Type
Method
Code

Method
Route Structure
Information
Required
S
m
s

SSMX
Major 1

H
m
s
Route ID
Route ID
2 S
m
ig
+ (S
m
s
- S
m
ig
) (S
m
s
- S
m
ig
) Route ID
S
m
s
- S
m
ig

DSSMX
m
s
- S
m
ig
) Model
name
2

(H
m
s
- H
m
ig
) Route ID
(G
m
s
- G
m
ig
) Route ID
3

(G
m
s
- G
m
ig
) Model
name

Molar Volume Methods
Property
Symbol
and Name
Property
Type
Method
Code

Method
Route Structure
V
i
*,v

VV
Major 1 Specified model V
i
*,v
Model name
V
m
v

VVMX
m
v
Model name
2
V
m
v
= f(y
i
, V
i
*,v
)
V
i
*,v
Route ID
V
m
v
Model name
3
V
m
v
= f(
i
)
i
Model name
i
Model name (eos only)
V
i
*,l

VL
i
*,l
Model name
V
m
l

VLMX
m
l
Model name
2
V
m
l
= f(x
i
, V
i
*,l
)
V
i
*,l
Route ID
V
m
l
Model name
t
) V
i
*,l
Model name
x
t
Route ID
4
V
m
l
= f(
i
)
i
Model name
V
m
l
Model name (eos
only)
V
i
*,s

VS
i
*,s
Model name
V
m
s

VSMX
m
s
Model name
2
V
m
s
= f(x
i
s
, V
i
*,s
)
V
i
*,s
Route ID
V
m
s
Model name

Viscosity Methods
Property
Symbol
and Name
Property
Type
Method
Code

Method
Route Structure
i
*,v

MUV
i
*,v
Model name
2
i
*,v
=
i
*,v
(p=0) (
i
*,v
(p=0)) Route ID
3
i
*,v
= f(V
i
*,v
)
V
i
*,v
Route ID
i
*,v
Model name
4
i
*,v
=
i
*,v
(p=0)
+ (
i
*,v
(p) -
i
*,v
(p=0))
(
i
*,v
(p=0)) Route ID
(
i
*,v
(p) -
i
*,v
(p=0))
Route ID
i
*,v
(p=0)
MUVLP
(
i
*,v
(p=0)) Model name
i
*,v
(p) -
i
*,v
(p=0)
MUVPC
(
i
*,v
(p) -
i
*,v
(p=0))
Model name
2
(
i
*,v
(p) -
i
*,v
(p=0)) = f(V
i
*,v
)
V
i
*,v
Route ID
Model name
v

MUVMX
v
Model name
2
v
= f(y
i
,
i
*,v
)
i
*,v
Route ID
v
Model name
3
v
=
v
(p=0) (
v
(p=0)) Route ID
4
v
= f(V
m
v
)
V
m
v
Route ID
5
i
v
=
i
v
(p=0)
+ (
i
v
(p) -
i
v
(p=0))
v
Model name
(
v
(p=0)) Route ID
(
i
v
(p) -
i
v
(p=0)) Route
ID
v
(p=0)
MUVMXLP
(
v
(p=0)) Model name
2
(
v
(p=0)) = f(y
i
,
i
*,v
(p=0)) (
i
*,v
(p=0)) Route ID
(
v
(p=0)) Model name
v
(p) -
v
(p=0)
MUVMXPC
(
v
(p) -
v
(p=0)) Model
name
2
(
v
(p) -
v
(p=0)) = f(V
m
v
)
V
m
v
Route ID
(
v
(p) -
v
(p=0)) Model
name
i
*,l

MUL
i
*,l
Model name
2
i
*,l
= f(V
i
*,l
)
V
i
*,l
Route ID
i
*,l
Model Name
Property
Symbol
and Name
Property
Type
Method
Code

Method
Route Structure
l

MULMX
l
Model name
2
l
= f(x
i
,
i
*,l
)
i
*,l
Route ID
l
Model name
3
l
= f(V
m
l
)
V
m
l
Route ID
l
Model name
t
)
l
Model name
x
t
Route ID

Thermal Conductivity Methods
Property
Symbol
and Name
Property
Type
Method
Code

Method
Route Structure
i
*,v

KV
i
*,v
Model name
2
i
*,v
= (
i
*,v
(p=0)) (
i
*,v
(p=0)) Route ID
3
i
*,v
= (
i
*,v
(p=0))
+ (
i
*,v
(p) -
i
*,v
(p=0))
(
i
*,v
(p=0)) Route ID
(
i
*,v
(p) -
i
*,v
(p=0)) Route
ID
4
i
*,v
= f(V
i
*,v
,
i
*,v
(p=0))
V
i
*,v
Route ID
(
i
*,v
(p=0)) Model name
i
*,v
Model Name
i
*,v
(p=0)
KVLP
(
i
*,v
(p=0)) Model name
2
i
*,v
(p=0) = f(
i
*,v
(p=0)) (
i
*,v
(p=0)) Route ID
i
*,v
Model name
i
*,v
(p) -
i
*,v
(p=0)
KVPC
(
i
*,v
(p) -
i
*,v
(p=0)) Model
name
2
(
i
*,v
(p) -
i
*,v
(p=0)) =
f(V
i
*,v
)
V
i
*,v
Route ID
(
i
*,v
(p) -
i
*,v
(p=0)) Model
name
v

KVMX
v
Model name
2
v
= f(y
i
,
i
*,v
)
i
*,v
Route ID
v
Model name
3
v
= (
v
(p=0)) (
v
(p=0)) Route ID
4
v
= (
v
(p=0))
+ (
v
(p) -
v
(p=0))
(
v
(p=0)) Route ID
(
v
(p) -
v
(p=0)) Route ID
Property
Symbol
and Name
Property
Type
Method
Code

Method
Route Structure
5
v
= f(V
m
v
,
v
(p=0))
V
m
v
Route ID
(
v
(p=0)) Route ID
v
Model name
v
(p=0)
KVMXLP
(
v
(p=0)) Model name
2
v
(p=0) =
f(y
i
,
i
*,v
(p=0),
i
*,v
(p=0))
i
*,v
Route ID
(
i
*,v
(p=0)) Route ID
(
v
(p=0)) Model name
v
(p) -
v
(p=0)
KVMXPC
(
v
(p) -
v
(p=0)) Model
name
2
(
v
(p) -
v
(p=0)) = f(V
m
v
)
V
m
v
Route ID
(
v
(p) -
v
(p=0)) Model
name
i
*,l

KL
i
*,l
Model name
2
i
*,l
= f(V
i
*,l
,
i
*,v
(p=0))
V
i
*,l
Route ID
(
i
*,v
(p=0)) Route ID
i
*,l
Model name
l

KLMX
l
Model name
2
l
= f(x
i
,
i
*,l
)
i
*,l
Route ID
l
Model name
3
l
= f(V
m
l
,
v
(p=0))
V
m
l
Route ID
(
v
(p=0)) Route ID
l
Model name
t
)
l
Model name
x
t
Route ID
i
*,s

KS
i
*,s
Model name
s

KSMX
s
Model name
2
s
= f(x
i
s
,
i
*,s
)
i
*,s
Route ID
s
Model name

Diffusion Coefficient Methods
Property
Symbol
and Name

Property
Type

Method
Code

Method

Route Structure
D
ij
v

DV
Major 1 Specified model D
ij
v
Model name
D
i
v

DVMX
Major 1 Specified model D
i
v
Model name
2 D
i
v
= f(y
i
, D
ij
v
) D
ij
v
Route ID
y
i
Model name
D
ij
l

DL
Major 1 Specified model Model name
2
Specified model
l

l
Route ID
D
ij
l
Model name
D
i
l

DLMX
2 D
i
l
= f(x
i
, D
ij
l
) D
ij
l
Route ID
D
i
l
Model name
3
D
i
l
= f(x
i
,
l
)
l
Route ID
D
i
l
Model name
t
) D
i
l
Model name
x
t
Route ID

Surface Tension Methods
Property
Symbol
and Name

Property
Type

Method
Code

Method

Route Structure
i
*,l

SIGL

l

SIGLMX
2

l
= f(x
i
,
i
*,l
)
i
*,l
Route ID

l
Model name
t
)

l
Model name
x
t
Route ID

Routes And Models
This section explains the structure of physical property calculations by
showing the relationship between models and routes, and between routes on
different levels. It also explains how to trace a calculation route.

Concept of Routes
Each property value needed for a method evaluation is obtained from either
another method evaluation or a model evaluation. Properties obtained by
method evaluation are major or subordinate properties. Properties obtained
by a model evaluation are intermediate properties. The calculation of the top
level property is dictated by:
Property name
Method
Sub level route for each major or subordinate property
Model name for each intermediate property (sometimes with a model
option code)
This information is called a route. There is not necessarily a major or
subordinate property in each method, but if one occurs in the method of the
property of interest, then the route depends on sub level routes. There can be
any number of levels in a route. Each level needs the information listed
previously to be completely specified. This way a tree of information is
formed. Since a model does not depend on lower level information, you can
think of it as an end point of a tree branch. Model option codes are discussed
in Models. (Example 1 discusses a route that does not depend on other
routes.)
Each built in route in the Aspen Physical Property System has a unique route
ID, which is composed of the property name (see the tables labeled Major
Properties in the Aspen Physical Property System, Subordinate Properties in
the Aspen Physical Property System, and Intermediate Properties in the
Aspen Physical Property System) and a number, for example HLMX10.
Therefore the route ID can be used to represent the route information. (See
example 2 for a route which depends on a secondary route.)
Route IDs associated with the route information represent a unique
combination of sub-level routes and models. Therefore, a top-level route ID
specifies the full calculation tree. Because of the uniqueness of route IDs, you
can use them for documenting your calculation.
A property method can calculate a fixed list of properties (see Physical
Properties in the Aspen Physical Property System). The calculation procedure
of each property constitutes a route and has a route ID. Therefore, a property
method consists of a collection of the route IDs of the properties it can
calculate. The Property Methods Routes sheet shows the routes used in a
property method. If you want to see all of the built-in routes used for
calculating the property specified in the Property field, use the list box in a
Route ID field (see the figure labeled Properties Property Methods Routes
Sheet.

Properties Property Methods Routes Sheet
Example 1 shows route information for PHILMX, method 1. Example 2 shows
Route information for HLMX, method 3.

Example 1: Route information for PHILMX,
method 1
The first method from the table labeled Liquid Fugacity Coefficient Methods for
the calculation of the fugacity coefficient of component in a liquid mixture is
specified model. The model can be an equation of state model, that calculates
the fugacity coefficient as a function of state variables and correlation
parameters:
i
l
= f(p, T, x
i
, correlation parameters)
There are many models that can be used to calculate
i
l
, such as the Redlich
Kwong Soave model, the Peng Robinson model, or the Hayden O'Connell
model. It is sufficient to select a model name in order to completely specify a
route according to this method.

Example 2: Route information for HLMX, method
3
The third method for calculating the liquid mixture enthalpy H
m
l
(see the table
labeled Liquid Enthalpy Methods) is:
H
m
l
= H
m
ig
+ (H
m
l
- H
m
ig
)
In this method, H
m
l
depends on the ideal gas enthalpy and the enthalpy
departure H
m
l
- H
m
ig
, a subordinate property. The table labeled Liquid
Enthalpy Methods indicates in the rightmost column that the required
information is the route ID for the subordinate property. The top-level route
now refers to a sub-level route ID. For all methods that use both an ideal gas
contribution and a departure function, the Aspen Physical Property System
automatically fills in the ideal gas calculation. You need to specify only the
departure function. To specify the sub-level route for the enthalpy departure,
you must choose a method. For example, method 1: specified model (see the
table labeled Liquid Enthalpy Methods). For this method, the required
information is the model name, such as the Redlich Kwong Soave equation-
of-state model.

Models
A model consists of one or more equations to evaluate a property, and has
state variables, universal parameters, and correlation parameters as input
variables. Properties obtained by model evaluation are called intermediate
properties. They never depend on major or subordinate properties, which
need a method evaluation. In contrast to methods which are based on
universal scientific principles only, models are much more arbitrary in nature,
and have constants which need to be determined by data fitting. An example
of a model is the Extended Antoine vapor pressure equation (see Physical
Property Models). Equations of state have built in correlation parameters and
are also models.
Models are sometimes used in multiple routes of a property method. For
example, an equation of state model can be used to calculate all vapor and
liquid departure functions of an equation of state based property method. The
Rackett model can be used to calculate the pure component and mixture
liquid molar volumes, (V
i
*,l
and V
m
l
), and it can also be used in the calculation
of the Poynting correction factor, as part of the calculation of the pure
component liquid fugacity coefficient.
The Properties Property Methods Models sheet displays the models that are
globally used in the routes of the current property method (see the figure
labeled Properties Property Methods Models Sheet). In specific routes,
exceptions to the global usage may occur. Modifying and Creating Routes
discusses how to identify these exceptions. For a given model, click on the
Affected Properties button to display a list of properties which are affected by
the model calculations. Use the list box on the Model Name field to display a
list of all available models for a specific property. You can also use the tables
labeled Thermodynamic Physical Property Models , Transport Physical
Property Models , and Nonconventional Solid Property Models on page . If you
need to use a proprietary model or a new model from the literature, you can
interface these to the Aspen Physical Property System (See Aspen Plus User
Models.)

Properties Property Methods Models Sheet
Some models have model option codes to specify different possible calculation
options. For example, the model WHNRY has three options to calculate the
weighting factor from the critical molar volume. The calculation option is
identified by the model option code. On the Property Methods Models sheet,
first select the model, then click the Option Codes button to display a list of
option code values for the model. Use Help for descriptions of the option
codes.

Thermodynamic Physical Property Models
Model
Model Name Phase Properties
Extended Antoine/Wagner PL0XANT L L1 L2 PL
API liquid volume VL2API L VLMX
API Sour SWEQ L PHILMX
Aqueous Electrolyte NRTL Enthalpy HAQELC L HLMX
Aqueous Electrolyte NRTL Gibbs
Energy
GAQELC L GLMX
ASME Steam Tables ESH2O0,ESH2O V L
Benedict-Webb-Rubin-Starling ESBWRS, ESBWRS0 V L ,
Braun K-10 NK10 L PHILMX
Brelvi-O'Connell VL1BROC L VLPM
Bromley-Pitzer GMPT2 L GAMMA
Bromley-Pitzer Enthalpy HAQPT2 L HLMX
Bromley-Pitzer Gibbs Energy GAQPT2 L GLMX
Model
BWR-Lee-Starling ESBWR0, ESCSTBWR V L ,
Cavett Liquid Enthalpy Departure DHL0CVT, DHL2CVT L DHL,DHLMX
Chao-Seader PHL0CS L PHIL
Chien-Null GMCHNULL L GAMMA
Clarke Aqueous Electrolyte Volume VAQCLK L VLMX
Constant Activity Coefficient GMCONS S GAMMA
COSTALD Liquid Volume VL0CTD,VL2CTD L VL,VLMX
COSMO-SAC COSMOSAC L GAMMA
Debye-Hckel Volume VAQDH L VLMX
DIPPR / PPDS / IK-CAPE Liquid
Heat Capacity
HL0DIP, DHL0DIP L HL, DHL
Electrolyte NRTL GMENRTL, GMELC,
GMENRHG
L L1 L2 GAMMA
Electrolyte NRTL Enthalpy HMXENRTL, HAQELC,
HMXELC, HMXENRHG
L HLMX
Electrolyte NRTL Gibbs Energy GMXENRTL, GAQELC,
GMXELC, GMXENRHG
L GLMX
Enthalpies Based on Different
Refrence States
DHL0HREF L V DHL
ENRTL-SAC (patent pending) ENRTLSAC L GAMMA
Grayson-Streed PHL0GS L PHIL
Hansen HANSEN L GAMMA
Hayden-O'Connell ESHOC0, ESHOC V ,
Henry's constant HENRY1 L HNRY,WHNRY
HF equation of state ESHF0, ESHF V ,
Ideal Gas ESIG0, ESIG V ,
Ideal Liquid GMIDL L GAMMA
Kent-Eisenberg ESAMINE L PHILMX,
GLMX, HLMX,
SLMX
Lee-Kesler ESLK V L
Lee-Kesler-Plcker ESLKP0, ESLKP V L ,
Liquid Constant Molar Volume VL0CONS L VL
Liquid Volume Quadratic Mixing
Rule
VL2QUAD L VLMX
Maxwell-Bonnell PL0MXBN L L1 L2 PL
Modified Rackett VL2MRK L VL, VLMX
NBS/NRC Steam Tables ESSTEAM0, ESSTEAM V L ,
Nothnagel ESNTH0, ESNTH V ,
NRTL (Non-Random-Two-Liquid) GMRENON L L1 L2 GAMMA
NRTL-SAC (patent pending) NRTLSAC L GAMMA
Peng-Robinson ESPR0, ESPR V L ,
Pitzer GMPT1 L GAMMA
Pitzer Enthalpy HAQPT1 L HLMX
Model
Pitzer Gibbs Energy GAQPT1 L GLMX
Polynomial Activity Coefficient GMPOLY L S GAMMA
Peng-Robinson-Wong-Sandler ESPRWS0, ESPRWS V L
Peng-Robinson-MHV2 ESPRV20, ESPRV2 V L
Predictive SRK ESRKSV10, ESRKSV1 V L
Rackett / Campbell-Thodos Mixture
Liquid Volume
VL2RKT L VLMX
Rackett / DIPPR / PPDS / IK-CAPE
Liquid Volume
VL0RKT L VL
Redlich-Kister GMREDKIS L S GAMMA
Redlich-Kwong ESRK0, ESRK V ,
Redlich-Kwong-Aspen ESRKA0, ESRKA V L ,
Redlich-Kwong-Soave ESRKSTD0, ESRKSTD V L ,
Redlich-Kwong-Soave-Boston-
Mathias
ESRKS0, ESRKS V L ESVPA0,
ESVPA
Redlich-Kwong-Soave-MHV2 ESRKSV20, ESRKSV2 V L
Redlich-Kwong-Soave-Wong-
Sandler
ESRKSWS0, ESRKSWS V L
Schwartzentruber-Renon ESRKU0, ESRKU V L ,
Scatchard-Hildebrand GMXSH L GAMMA
Soave-Redlich-Kwong ESSRK0, ESSRK V L ,
Solid Antoine PS0ANT S PS
Aspen / DIPPR / Barin / PPDS / IK-
CAPE Solids Heat Capacity
HS0POLY S HS
Aspen / DIPPR / IK-CAPE Solid
Molar Volume
VS0POLY S VS
SRK-Kabadi-Danner ESSRK0, ESSRK V L ,
SRK-ML ESRKSML0, ESRKSML V L ,
Standard Peng-Robinson ESPRSTD0, ESPRSTD V L ,
Three-Suffix Margules GMMARGUL L S GAMMA
UNIFAC GMUFAC L L1 L2 GAMMA
UNIFAC (Lyngby Modified) GMUFLBY L L1 L2 GAMMA
UNIFAC (Dortmund Modified) GMUFDMD L L1 L2 GAMMA
UNIQUAC GMUQUAC L L1 L2 GAMMA
van Laar GMVLAAR L GAMMA
VPA/IK-CAPE equation of state ESVPA0, ESVPA V ,
Wagner interaction parameter GMWIP S GAMMA
Watson / DIPPR / PPDS / IK-CAPE /
Clausius-Clapeyron equation
DHVLWTSN L DHVL
Wilson GMWILSON L GAMMA
Wilson model with liquid molar
volume
GMWSNVOL L GAMMA
A pure component equation of state model calculates:
PHIL,PHIV,DHL,DHV,DGL,DGV,DSL,DSV,VL,VV
A mixture equation of state model calculates:
PHILMX,PHIVMX,DHLMX,DHVMX,DGLMX,DGVMX,DSLMX,DSVMX,VLMX,VVMX
DHLMX,DHVMX,DGLMX,DGVMX,DSLMX,DSVMX,VLMX,VVMX

Transport Property Models
Model
Andrade / DIPPR / PPDS / IK-CAPE,
Andrade Liquid Mixture Viscosity
MUL0ANDR,
MUL2ANDR
L MUL, MULMX
API liquid viscosity MUL2API L MULMX
API 1997 liquid viscosity MULAPI97 L MULMX
API surface tension SIG2API L SIGLMX
Aspen liquid mixture viscosity MUASPEN L MULMX
ASTM liquid mixture viscosity MUL2ASTM L MULMX
Chapman-Enskog-Brokaw / DIPPR /
PPDS / IK-CAPE
MUV0CEB V MUVLP
Chapman-Enskog-Brokaw-Wilke
mixing rule
MUV2WILK V MUVMXLP
Chapman-Enskog-Wilke-Lee Binary DV0CEWL V DV
Chapman-Enskog-Wilke-Lee
Mixture
DV1CEWL V DVMX
Chung-Lee-Starling low pressure
Viscosity
MUL0CLSL, MUL2CLSL V MUVLP,
MUVMXLP
Chung-Lee-Starling Viscosity MUV0CLS2, MUV2CLS2,
MUL0CLS2, MUL2CLS2
V L MUV, MUVMX
Chung-Lee-Starling thermal
conductivity
KV0CLS2, KV2CLS2
KL0CLS2, KL2CLS2
V
L
KV, KVMX
KL, KLMX
Dawson-Khoury-Kobayashi Binary DV1DKK V DV
Dawson-Khoury-Kobayashi Mixture DV1DKK V DVMX
Dean-Stiel pressure correction MUV0DSPC, MUV2DSPC V MUVPC,
MUVMXPC
Hakim-Steinberg-Stiel / DIPPR /
IK-CAPE
SIG0HSS, SIG2HSS L SIGL, SIGLMX
IAPS surface tension SIG0H2O L SIGL
IAPS thermal conductivity for water KV0H2O
KL0H2O
V
L
KV
KL
IAPS viscosity MUV0H2O
MUL0H2O
V
L
MUV
MUL
Jones-Dole electrolyte correction MUL2JONS L MULMX
Letsou-Stiel MUL0LEST, MUL2LEST L MUL, MULMX
Li mixing rule KL2LI L KL, KLMX
Liquid mixture surface tension SIG2IDL L SIGLMX
Lucas MUV0LUC, MUV2LUC V MUV, MUVMX
Modified MacLeod-Sugden SIG2MS L SIGLMX
Nernst-Hartley DL0NST, DL1NST L DL, DLMX
Model
Onsager-Samaras electrolyte
correction
SIG2ONSG L SIGLMX
Riedel electrolyte correction KL2RDL L KLMX
Sato-Riedel / DIPPR / PPDS / IK-
CAPE
KL0SR, KL2SRVR L KL, KLMX
Stiel-Thodos / DIPPR / PPDS / IK-
CAPE
KV0STLP V KVLP
Stiel-Thodos pressure correction KV0STPC, KV2STPC V KVPC
TRAPP viscosity MUV0TRAP, MUV2TRAP
MUL0TRAP, MUL2TRAP
V
L
MUV, MUVMX,
MUL, MULMX
TRAPP thermal conductivity KV0TRAP, KV2TRAP
KL0TRAP, KL2TRAP
V
L
KV, KVMX
KL, KLMX
Twu liquid viscosity MUL2TWU L MULMX
Viscosity quadratic mixing rule MUL2QUAD L MULMX
Vredeveld mixing rule KL2SRVR L KLMX
Wassiljewa Mason Saxena mixing
rule
KV2WMSM V KVMXLP
Wilke-Chang binary DL0WC2 L DL
Wilke-Chang mixture DL1WC L DLMX

Nonconventional Solid Property Models
Model
Model Name Phase
General Coal Enthalpy Model HCOALGEN S
General Density Polynomial DNSTYGEN S
General Heat Capacity Polynomial ENTHGEN S
IGT Coal Density Model DCOALIGT S
IGT Char Density Model DCHARIGT S

Tracing a Route
The structure of a full calculation route is generally shaped as a tree control.
Each point in the tree where a branch splits off (a node) represents a method.
The branches themselves are the routes. The ends of the branches are
models. The starting point for tracing a route is usually finding a route ID on
the Property Methods Routes sheet, for which you want to know the
calculation procedure. Example 1 describes how you can trace a known route
ID.

Example 1: Tracing the route HLMX08
The route ID is on the Properties Property Methods Routes sheet for the
Wilson property method. It appears in the second column, next to the
property HLMX: HLMX08 (a similar sheet is shown in the figure labeled
Properties Property Methods Routes Sheet).
Click on the property HLMX or the route ID HLMX08, then click the View
button. The View Route dialog box appears.

If you click on a route or model on the tree, a short descriptions of the route
or model appears in the Prompt area. At the first node, the route HLMX08
appears, which uses method 3. In this method, the liquid mixture enthalpy is
calculated from the ideal gas enthalpy and the enthalpy departure. the Aspen
Physical Property System automatically fills in the ideal gas calculations. Only
the departure function route ID must be specified. Therefore, there is only
one branch attached to the node for route HLMX08.
There are two ways to look up the equation corresponding to the method
number of a route.
The first method, if you are in the Aspen Physical Property System is to:
1. Close the View Route dialog box.
2. Go to the Property field corresponding to the route.
3. Use Help to get online help on methods corresponding to this property.
4. Locate the formula corresponding to the method number.
The second method is to look up the method in the table labeled Vapor
Fugacity Coefficient Methods in the section corresponding to the property for
which you trace the route (HLMX). The formula is listed next to the method
number.
The next step in the route HLMX08 is the calculation of the liquid mixture
enthalpy departure with route ID: DHLMX08. This calculation is based on
method 2, which calculates DHLMX as the mole fraction average of pure
component enthalpy departure (DHL) and the excess enthalpy (HLXS).
Therefore, two branches split from this route and the complete route can be
traced this way.
These two steps in tracing the route HLMX08 show that a route ID is
characteristic for the methods, routes and models specified on its own level.
However, by specifying DHLMX08 on the top level, the top level route is also
characteristic for the level below because DHLMX08 stands for a full
specification on its secondary level. If we continue this reasoning down the
tree to the models, then it becomes clear that HLMX08 represents the full
specification of the full tree. And DHLMX08 represents the full specification of
the full tree, minus the top level. Therefore every built in route has a unique
ID. This feature will be used in Modifying and Creating Routes.

Modifying and Creating
Property Methods
The built in property methods in the Aspen Physical Property System contain
choices of major property routes that fit most engineering needs. The
combinations of the routes for different properties are chosen in a logical way,
as explained in Classifications of Property methods and Recommended Use in
Property Method Descriptions. You may sometimes need to customize
property methods. For example, to change models or routes on a main or a
sub level. This section explains how to do this and gives examples of how to
implement the most frequently used modifications.

Modifying Existing Property Methods
The following subsections explain the different types of modifications that can
be made to property methods.
Replacing Routes
Replacing Models and Using Multiple Data Sets
Conflicting Route and Model Specifications

Replacing Routes
The Property Methods Routes sheet allows you to see which routes are used
in a certain property method and to trace a route (see Routes and Models).
This form also allows you to replace routes. A route replacement influences
the calculations of one property at a time.
To replace routes:
1. From the Data menu, select Properties, then Property Method.
The Property Methods Object Manager appears.
2. Select the property method and click on Edit.
The Property Methods form appears.
3. Go to the Routes sheet.
4. In the Route ID field of the property of interest, use List to list all available
routes for this property.
As you scroll through the list, the prompt displays a short description of
the route. When you gain experience, the description from the prompt
should be sufficient. If you require more information,
o Select the route, the click on the View button to get the tree diagram
for this route (see Routes and Models). You can now trace the route in
detail.
o Close the View Route dialog box to return to the Routes sheet.
5. Select a route that fits your needs.
The newly selected route changes color, so that you are able to locate
your property method modifications immediately on this sheet.
The technique is identical for subordinate properties.

Example 1: Using COSTALD liquid molar volume in
PENG-ROB
In the PENG ROB property method, the Rackett equation is used for the liquid
molar volume (route VLMX01, property VLMX). For high pressure calculations,
use the COSTALD model which is suited for compressed liquids. The route
selected is VLMX22. For consistency with pure component results, replace the
VL calculation with VL06.

Example 2: Using Lee-Kesler liquid volume in RK-
Soave
For a high pressure hydrocarbon application, use the Lee Kesler liquid molar
volume calculation rather than the atmospheric API density calculation. Select
VLMX13 for VLMX. No corresponding pure component routes are available,
since these calculations are for complex petroleum mixtures, of which the
pure components are only partially known.

Example 3: Using ideal mixing for the liquid molar
volume in WILSON
You want to compare the Rackett mixture equation with ideal mixing. The
pure component liquid molar volume should remain as it is (Model: VL0RKT,
Route ID: VL01). Select the route VLMX23 to use the ideal mixing rule (mole
fraction average of pure component liquid molar volumes).

Example 4: Removing Poynting correction of an
activity coefficient
The Poynting correction is the pressure correction to the pure component
liquid fugacity coefficient. For validation purposes, you need to compare your
calculation with previous results that have been obtained without the Poynting
correction.
In all activity coefficient based property methods with the Redlich Kwong
equation of state as the vapor phase model, the route PHIL04 is used for the
pure component liquid fugacity coefficient. Tracing PHIL04 (using the View
button) shows that the pressure correction is calculated by the subordinate
property PHILPC with route ID PHILPC01.
On the Property Methods Routes sheet, select Subordinate property in the
Property route field. Locate the property PHILPC in the Property field, then
replace PHILPC01 with PHILPC00 (no correction) in the Route ID field. If you
trace PHIL04 again (using the View button), you will notice that the tree is
dynamic; it reflects the changes you made in a sub level route, in this case
for PHILPC.
In the activity coefficient based property methods with the ideal gas law as
the vapor phase model, the route PHIL00 is used. Tracing PHIL00 shows that
PHILPC00 is used by default. No changes are needed.

Replacing Models and Using Multiple Data Sets
The Property Methods Models sheet allows you to see which models are used
in a certain property method (see Routes and Models). This sheet also allows
you to replace models. Route replacements influence only one property at a
time. In contrast, a model replacement influences all the properties that use
the same model. You can trace the routes of these properties to determine
where exactly the model is used in the calculation. If you want to limit the
effect of a model replacement to a single route, you can modify an existing
route or create a new route (see Modifying and Creating Routes). Click the
Affected properties button to see a list of properties affected by the model.
If you need to change both routes and models, you must change the routes
first using the Routes sheet, then change the models. If you use the Models
sheet before using the Routes sheet, the changes you made on the Models
sheet will be lost.
To replace models:
1. From the Data menu, select Properties, then Property Methods.
3. Go to the Models sheet.
4. On the Model name field of the property of interest, use List for all
available models for this property. (You can also use the table labeled
Liquid Fugacity Coefficient Methods.)
As you scroll through the list, the prompt displays a short description of
the model.
5. Select a model.
The newly selected model changes color, so that you are able to locate
your property method modifications immediately on this form. All
properties using the same model will also be changed.
If you draw a tree diagram of a property in which the new model is used, the
modification is also shown (see Tracing a Route).

Conflicting Route and Model Specifications
If you specify a route for a certain property and you also specify a model that
calculates a property that is part of the route you specified, the information
can be conflicting. In the Aspen Physical Property System both replacements
will be executed. The result, in most cases, is that the model takes
precedence, but you can always predict the result by analyzing the route and
checking if there is an occurrence of this type of model in the tree.
Example 1 describes how to use COSTALD liquid molar volume in PENG-ROB.
Example 2 describes how to use Peng Robinson for vapor phase properties in
NRTL RK.

Example 1: Using COSTALD liquid molar volume in
PENG-ROB: Replacing Models
The reasoning is the same as in Example 1, Replacing Routes. The approach
here is to replace the Rackett models (VL0RKT, VL2RKT) by the COSTALD
models (VL0CTD, VL2CTD). The result is exactly the same as for the route
replacement.

Example 2: Using Peng-Robinson for vapor phase
properties in NRTL-RK
You want to use the Peng Robinson equation of state as the vapor phase
model of an activity coefficient based property method. Instead of replacing
every vapor phase property route, it is more efficient to replace the equation
of state model used for all vapor phase properties. In the model field, if you
select ESPR for a single vapor phase property, the Aspen Physical Property
System replaces all other vapor phase properties by the ESPR model as well.
For consistency, use ESPR0 for pure component vapor phase properties.

Creating New Property Methods
The purpose of creating new property methods is not so much to build the
collection of routes from scratch, although this is possible. It is more a matter
of methodology and documentation of your work. Suppose you make changes
to existing property methods, and you have successfully completed your
calculations. One year later you may have a similar project where you begin
with your old calculation models. You may not remember that the WILSON
property method you used is not the standard version. Therefore, it is
recommended that you:
1. Create a new property method with an ID similar to the property method
on which it is based.
2. Copy the base property method to the new property method
3. Make your changes.
There are two ways to begin the creation of a property method.
The first way to begin is:
4. On the Properties Specifications Global sheet, select the base property
method on the Base method field.
5. Check the Modify property models checkbox. The Modify Property Method
dialog box appears.
6. Enter the new property method name, then click OK.
7. Go to the Properties Property Methods Object Manager.
8. Select the new property method, then click Edit.
The second way to begin is:
10. Click on New and enter the new property method name.
Then for both methods do the following steps:
11. Select the Property Methods .Routes or the Property Methods .Models
sheet.
12. On the Base property method field, use List and select an existing
property method name.
The Aspen Physical Property System fills in all the routes and models in
both sheets.
13. Make your changes.
14. Use the newly created property method in a flowsheet, a block, a property
analysis, or a column section.

Using Multiple Data Sets in Multiple Property
Methods
To use a second data set with a model:
3. Go to the Models sheet.
The DataSet column is to the right of the Model name column. The default
for a data set number is 1.
4. Change the data set number to 2 to introduce a second set of parameters
for a model.
A second data set is frequently used for activity coefficient models. For
example, the VLE are calculated with one set of parameters, the LLE with
another set. If you introduce a second data set for an activity coefficient
model, it is effective throughout the property method. To use two data sets in
different parts of the flowsheet or a distillation column, you must use two
property methods: one property method that uses the default data set 1, and
another property method that uses the data set 2. If you create a second
data set for a model, the Aspen Physical Property System automatically
defines the second set of parameters on the Properties Parameters forms. So
you must enter the parameters values for the second data set after creating
the property method in which they are to be used.
There are a few pre-defined property methods which use data set 2: NRTL-2,
UNIQ-2, VANL-2, and WILS-2. When you add one of these property methods
to your simulation, the binary parameter form for the data set it uses is
added under Properties | Parameters.
Note: Data regression runs can only manipulate the first data set. You can
copy parameters obtained through data regression into any other data set
and then use that data set during simulation runs.

Modifying and Creating Routes
The built in routes in the Aspen Physical Property System cover most
engineering needs (see Routes and Models). However, while modifying or
creating property methods you may need a route that is not built in (see
Modifying and Creating Property Methods). You can create such a route based
on the available methods. This section explains and gives examples of
modifying and creating routes.
To decide if you want to create a new route or modify an existing route, apply
the same reasoning as for deciding whether to modify or create a new
property method (see Creating New Property Methods). We recommend you
choose a new route ID.
To modify an existing route or create a new route:
1. Follow the procedure to trace routes, and consider the available methods
for the property of interest. Decide on the route you want to modify, or
the method you want to use to create a route.
2. From the Data menu, select Properties, then Advanced, then Routes.
The Routes Object Manager appears. There are no objects listed because
there are hundreds of available routes. So you need to know from the
analysis you did on the Property Methods Routes sheet which route you
want to modify.
3. Click on New. Enter a new route ID to create a new route, or enter an
existing route ID to modify an existing route.
The Routes Specifications sheet appears. At the top are the:
o Property name
o Method code
o Route ID of the route to modify
4. When you base your new route on an existing route, enter the property
name in the Property name field and the base route ID in the Copy route
from field, and make your changes.
Or
When you create a completely new route, enter the property name and
method code. Fill the Route ID and Model name fields.
5. Use the Property Methods Routes sheet and enter the new route in a
property method.
Or
Use the Routes Specifications sheet of another route to use the newly
created route in another route.
Example 1 describes how to use a second data set of NRTL parameters for
HLXS. Example 2 describes how to use your own model for the liquid
enthalpy.

Example 1: Use a second data set of NRTL
parameters
The representation of two properties with one data set is sometimes not
satisfactory, for example with VLE and excess enthalpy data. If two data sets
can describe the properties separately, you will need to use both sets in the
calculation.
In this example, one set of binary parameters for the NRTL model is used for
VLE calculations. A second set of binary parameters is used for excess
enthalpy (HLXS).
Create a new route to calculate HLXS. The simplest way is to modify the
existing route used in the NRTL property method. The Route ID is HLXS10.
On the Properties Advanced Routes Specification sheet, change Data Set from
1 to 2.

Example 2: Using your own model for the
liquid enthalpy
Your company has developed a correlation for the enthalpy in a specific
process stream that you want to use. The necessary user model subroutines
have been written according to Aspen Plus User Models. All built in routes in
the Aspen Physical Property System for the liquid molar enthalpy are based
on methods 2, 3 or 4. However, to use the user model, method 1 (Specified
model) is needed. Because no existing route uses method 1 or needs this
type of model, there is no model for liquid enthalpy on the Property Methods
Models sheet.
Create a new route, for example HLMXAP, using method 1. On the Routes
Specifications sheet. the property name HLMX appears in the Model area. Use
List from the Model name field to select HL2USR, the liquid mixture enthalpy
user model.
Reference the route HLMXAP in the property method on the Property Methods
Routes sheet. You can check that the user enthalpy model HL2USR appears
on the Property Methods Models sheet.

4 Electrolyte Calculation 169
4 Electrolyte Calculation
Electrolyte process calculation has many applications. In the Aspen Physical
Property System, you can analyze and optimize processes involving ionic
species, complex ions, salt precipitation, with strong acids, weak acids and
bases.
Examples of applications for electrolyte process calculation with the Aspen
Physical Property System include:
Sour water stripping (petrochemical industry)
Caustic brine evaporation and crystallization (chlor-alkali industry)
Acid gas removal (chemical and gas industries)
Nitric acid separation (nuclear chemical industry)
Trona processing (mining industry)
Organic salt separation (biochemical industry)
Black liquor evaporation (pulp and paper industry)
Electrolyte systems have three important characteristics:
Solution chemistry in the liquid phase
Apparent and true component compositions are different
Non-ideal liquid phase thermodynamic behavior
This chapter describes applications of electrolyte process calculation and
reviews the following fundamental characteristics of electrolyte systems:
Solution chemistry
Apparent component and true component approaches
Electrolyte thermodynamics models
Electrolyte data regression

Solution Chemistry
The solution chemistry involves a variety of chemical reactions in the liquid
phase. Examples of such chemical reactions are:
Complete dissociation of strong electrolytes
Partial dissociation of weak electrolytes
170 4 Electrolyte Calculation
Ionic reactions among ionic species
Complex ion formation
Salt precipitation and dissolution
These chemical reactions occur rapidly in solution, so chemical equilibrium
conditions are assumed.
Solution chemistry affects electrolyte process calculation by influencing
physical properties, phase equilibrium, and other fundamental characteristics
of electrolyte systems. For most nonelectrolyte systems, chemical reactions
occur only in reactors. For electrolyte systems, chemical equilibrium
calculations are essential to all types of unit operations modeling.
Solution chemistry dictates the true components in solution and imposes
equality constraints on their composition. The chemical equilibrium
relationship for reaction j is expressed as:

(1)
Where:

= Chemical equilibrium constant

= Reaction stoichiometric coefficient of
component i

= Activity of component i
Computation of the solution chemistry is often combined with phase
equilibrium calculations. Typical electrolyte calculations involving solution
chemistry are:
Liquid (aqueous) phase equilibrium (for example, calculating the pH for
the titration of organic acid with caustic solution)
Vapor-liquid (aqueous) phase equilibrium (for example, extractive
distillation with salts as extractive agents, and sour water stripping)
Liquid (aqueous)-liquid (organic) phase equilibrium (for example,
hydrocarbon-sour water system and liquid-liquid extraction of metals)
Liquid (aqueous)-solid equilibrium of salt precipitation (for example,
crystallization of organic or inorganic salts)
To simulate an electrolyte system, you must properly identify all relevant
chemical reactions. Physical interactions in solutions are sometimes described
by postulating chemical reactions at equilibrium. The chemical theory of
solutions is used only for real chemical reactions. Incorrect assumptions about
the solution chemistry is the major cause of inaccuracies in calculations of
reactive chemical systems.
Use the Electrolyte Expert System to identify all relevant chemical reactions.
Starting from this set of reactions, you can remove and/or add reactions as
required to properly represent your process.
You can use the Reactions Chemistry form to describe the solution chemistry
and to enter the chemical equilibrium constants. However, we strongly
recommend that you use the Elec Wizard on the Components Specifications
Selection sheet and allow the Electrolyte Expert System to set up the property
specifications for you.
For a system with a solvent dielectric constant less than 10, ionic reactions do
not take place. Therefore, the Aspen Physical Property System bypasses all
solution chemistry calculations for such systems.
If you define the reactions on the Reactions Chemistry form, the Aspen
Physical Property System checks for infeasible or redundant reactions. If such
reactions exist, the Aspen Physical Property System ignores them during the
calculations.

Apparent Component and True Component
Approaches
As a result of the solution chemistry, a set of true species is present in the
liquid phase that differs from apparent molecular components. Apparent or
parent components are present in the system if no reactions occurred. For
example, the sour water stripper system has three apparent molecular
components: water, ammonia, and hydrogen sulfide. The three molecular
components dissociate in the liquid phase.
There are four ionic reactions:

(2)

(3)

(4)

(5)
Five ionic species are thereby produced from these aqueous phase ionic
reactions. All components in these reactions exist at chemical equilibrium
conditions and are the true components of the electrolyte system. The
apparent components are ,and .
These two sets of components have major effects on the treatment of
electrolyte process calculation. Apparent components are of major concern to
some electrolyte processes since process measurements are usually
expressed in terms of apparent components. To other electrolyte processes,
expression in terms of true species is the only way to characterize an
electrolyte system. The selection of apparent components or true components
therefore depends on the type of electrolyte system you simulate.
Three types of molecular components may be present in an electrolyte
system: solvents, molecular solutes, and electrolytes. As a result of
electrolyte solution chemistry, ions, salts, and nonvolatile molecular solutes
may be present as additional true species. These components are defined as:
Solvent: water is the solvent for aqueous electolyte systems. For mixed-
solvent electrolyte systems, there are other solvent components in
addition to water.
Molecular solutes are molecular species, other than solvent compounds,
that exist in the liquid phase in molecular form. All molecular solutes are
treated with Henry's law. They are often supercritical components.
Electrolytes are also molecular species. However, strong electrolytes
dissociate completely to ionic species in the liquid phase. Undissociated
weak electrolytes can be solvent components or molecular solutes.
Ions are nonvolatile ionic species that exist only in the liquid phase.
Salts are nonvolatile molecular species that exist as solids.

Choosing the True or Apparent Approach
The apparent component approach and the true component approach are
interchangeable because liquid solution chemistry based on apparent
component composition defines the true component composition of a system.
The Aspen Physical Property System calculates thermodynamic properties of
components and mixtures expressed in terms of apparent component
composition from properties expressed in terms of true component
composition. For example, the liquid fugacity coefficient of ammonia with the
apparent component approach is calculated from the liquid fugacity coefficient
of ammonia with the true component approach:

(6)
Where:

= Fugacity coefficient of apparent component i

= Fugacity coefficient of true component i

= Liquid component mole fraction of component i
(superscript a indicates apparent composition, t
indicates true composition)
Similar relationships are established for other properties (Chen et al., 1983).
However, the apparent component mole fractions are not always calculated
from the true component mole fractions because ambiguity can exist in the
stoichiometric relations.
Using the apparent component approach in vapor-liquid equilibrium implies:
The vapor-liquid equilibrium is solved in terms of apparent components
only.
The liquid solution chemistry in the liquid is solved in terms of true and
apparent components.
This approach restricts the specification of the solution chemistry, because
the reaction products (which are true components only by definition) cannot
contain volatile components. Only apparent components can take part in
vapor-liquid equilibrium. The true component approach does not have this
restriction.
Note: True and apparent component approaches only apply to the liquid
phase. The vapor phase does not contain ions, so this distinction is
meaningless there.
In process calculation, the true component approach requires that you specify
the process in terms of true components. The Aspen Physical Property System
carries true components and their compositions in each process stream and
each unit operation. Unit operation computational algorithms have been
developed to solve the chemical equilibrium relationship in addition to the
unit-operation describing equations.
The apparent component approach requires that you specify the process only
in terms of apparent components. The solution chemistry and the true
components are handled by the physical property system and are transparent
to process flowsheets and unit operations.
The apparent component approach makes it possible to use existing unit
operation computational algorithms, such as:
Flash algorithms for vapor-liquid equilibrium
Liquid phase splitting algorithms for liquid-liquid equilibrium
Distillation algorithms
Rigorous representation of the (effective) partial molar properties of apparent
components requires the solution of the chemical equilibrium and the
knowledge of the partial molar properties of the true components.
Deciding whether to use the apparent component or true component
approach can depend on:
Your personal preference
The way you specify the process (in terms of apparent components or true
components)
Convergence considerations
Generally, the apparent component approach is preferred for simple
electrolyte systems. It offers the advantage that only apparent components
need to be considered. When the system grows more complex and it becomes
difficult to select the apparent components, the true component approach is
preferred. For complex distillation columns or flowsheet specifications, the
true component approach can improve convergence.
Important: When the apparent components yield volatile reaction products,
always use the true component approach.
When you use apparent components, the Aspen Physical Property System
checks for generation of volatile species in excess of an amount determined
by a tolerance, and generates an error if such a problem is found. You can
adjust the tolerance or disable the check using the Setup | Simulation
Options | Reactions sheet in Aspen Plus or Setup | Calculation Options |
Reactions sheet in Aspen Properties, but the recommended way to resolve
this error is to use the true component approach.
If you use the apparent component approach, solution chemistry is required.
Reference
C.C. Chen, H.I. Britt, J.F. Boston, and W.M. Clarke, "Thermodynamic Property
Evaluation in Computer-Based Flowsheet Simulation for Aqueous Electrolyte
Systems," Paper presented at the Denver AIChE Meeting, August, 1983.

Reconstitution of Apparent Component Mole
Fractions
Several electrolyte property models in the Aspen Physical Property System
use the technique of constructing a set of arbitrary mole fractions of all
possible apparent components from a mixture described in terms of
compositions of true components. These models are listed in the following
table, and are discussed in detail in Physical Property Models.
Model Name Property
Clarke Aqueous Electrolyte Volume Molar volume
Jones-Dole Viscosity
Riedel Thermal conductivity
Nernst-Hartley Diffusivity
Onsager-Samaras Surface tension
The mole fractions of the apparent components are reconstituted from mole
fractions of true components, even if you use the apparent component
approach. All possible apparent components ca from cations c and anions a
are considered. For example, if you dissolve calcium sulphate and sodium
chloride in water, then the solution contains: Na
+
, Ca
2+
, SO
4
2-
, and Cl
-
. This
solution could have been made from water and an infinite number of different
combinations of amounts of the apparent components CaSO
4
, CaCl
2
, NaCl,
and Na
2
SO
4
.
From all possible solutions, the Aspen Physical Property System uses one
arbitrary solution of the amounts of apparent electrolytes:

(7)
This solution generates all possible combinations of anions and cations.
However, for the case of 2-2 electrolytes, the amount is multiplied by 2, to
avoid the creation of, for example, Ca
2
(SO
4
)
2
instead of CaSO
4
. In general,
the correction factor should be the highest common factor of the charges (z
c
)
and (z
a
), but the 3-3 or 2-4 electrolytes are not known.
From this the total amount of apparent moles and apparent mole fractions
can be calculated:

(8)
Where k can refer to any solvent B, molecular solute i, or apparent electrolyte
ca.

Aqueous Electrolyte Chemical Equilibrium
In determining the composition of an electrolyte system, it is important to
know the equilibrium constants of the reactions taking place. An equilibrium
constant is expressed as the product of the activity of each species raised to
its stoichiometric coefficients. Two different scales for equilibrium constants
are used in the Aspen Physical Property System, the molality scale and the
mole fraction scale.
The Mole Fraction Scale
The equilibrium constant is written as follows:

(1)
or

(2)
Where:

= Equilibrium constant

= Water mole fraction

= Water activity coefficient

= Mole fraction of non-water component (solute)

= Activity coefficient of non-water component (solute)

= Stoichiometric coefficient
The Molality Scale
The equilibrium constant is written as follows:

(3)
or

(4)
Where:

= Equilibrium constant on molality scale

= Molality of non-water component (solute)

= Activity coefficient of non-water component (solute)
on molality scale
The activity coefficient of non-water component (solute) on the molality scale
is defined as follows:

(5)
Where:

= Molecular weight of water
Using equation 5, we can convert the logarithm of the equilibrium constant
from the mole fraction scale to the molality scale:

(6)
This derivation is general and is not tied to a particular activity coefficient
model, even though the activity coefficients and have to be calculated
from a model or correlation.
Example
For the reaction:

(7)
The equilibrium constant is:

(8)
Where a is the activity of a species. Therefore, we have:

(9)

(10)

(11)
Equation 11 holds for all 1-1 aqueous electrolytes.
The molality scale equilibrium constant is usually expressed in the form:

(12)
Combining equations 11 and 12, we can calculate the equilibrium constant in
either scale.
If chemical equilibrium constants are not available, the Aspen Physical
Property System estimates them from the reference state free energy of the
system:

(13)
Applying equation 13 to 1-1 electrolyte systems using equation 11:

()
More generally, we can rewrite equation 14 as follows:

()
The Aspen Physical Property System offers a number of methods for
calculating , including Electrolyte NRTL.

Electrolyte Thermodynamic Models
In electrolyte process calculation, the following thermophysical properties
must be computed at a given temperature, pressure and composition:
Activity coefficient
Enthalpy
Reference state Gibbs energy
These properties are necessary to perform phase equilibrium, chemical
equilibrium, and mass and energy balance calculations. Activity coefficients
are the most critical properties for process calculation. They determine the
flow rates, compositions, and stability of phases.
Advances in electrolyte thermodynamics have produced several semi-
empirical excess Gibbs energy models that correlate and predict: activity
coefficients of individual ions, mean ionic activity coefficients, and activity
coefficients of molecular solvents and solutes. The Pitzer equation, the
Electrolyte NRTL Model, and the Zemaitis equations are the most widely
adopted equations among these models.

Pitzer Equation
The Pitzer equation is a virial expansion equation. The model requires second-
order parameters at low concentrations, and both second- and third-order
parameters at high concentrations. The equation has been applied
successfully to represent data within experimental error from dilute solutions
up to an ionic strength of six molal for both aqueous single strong electrolyte
systems and multicomponent strong electrolyte systems (Pitzer, 1973). The
Pitzer equation is also extended to model aqueous weak electrolyte systems
(Chen et al., 1982). It provides a thermodynamically consistent model that
accurately represents electrolyte nonideality for many industrial aqueous
electrolyte systems.
This model is the basis for the PITZER property method. For details on the
model, see Pitzer Activity Coefficient Model in Physical Property Models.
References
C.C. Chen, H.I. Britt, J.F Boston, and L.B. Evans, "Local Composition Model
for Excess Gibbs Energy of Electrolyte Systems," AIChE J., Vol. 28, (1982),
p. 588.
Pitzer, K.S., "Thermodynamics of Electrolytes.I. Theoretical Basis and General
Equations," J. Phys. Chem., Vol. 77, (1973), p. 268.

Electrolyte NRTL Equation
The electrolyte NRTL equation provides another thermodynamically consistent
model for aqueous electrolyte systems. This equation was developed with the
local composition concept. This concept is similar to the NRTL (Non-Random
Two Liquid) model for nonelectrolyte systems (Renon and Prausnitz, 1968).
With only binary parameters, the equation satisfactorily represents physical
interactions of true species in aqueous single electrolyte systems and
multicomponent electrolyte systems over wide ranges of concentrations and
temperatures. This model can represent infinitely dilute electrolyte systems
(where it reduces to the Debye-Hckel model), nonelectrolyte systems (where
it reduces to the NRTL model), and pure fused salts. It connects these limiting
systems. The equation has been extended to model mixed solvent electrolyte-
systems (Mock et al., 1984).
This model is the basis for the ELECNRTL property method. For details on the
model, see Electrolyte NRTL Activity Coefficient Model in Physical Property
Models.
References
B. Mock, L.B. Evans, and C.-C. Chen, "Phase Equilibria in Multiple-Solvent
Electrolyte Systems: A New Thermodynamic Model," Paper presented at the
Boston Summer Computer Simulation Conference, July 1984.
H. Renon and J.M. Prausnitz, "Local Compositions in Thermodynamic Excess
Function for Liquid Mixtures," AIChE J., Vol. 14, (1968), p. 135.

Zemaitis Equation (Bromley-Pitzer Model)
The Zemaitis equation is based on the Bronsted-Guggenheim mean ionic
activity coefficient equation with the Guggenheim term expressed in
Bromley's form as an expansion of ionic strength. The activity of solvent
water in single electrolyte systems is then computed by application of the
Gibbs-Duhem integration on the mean ionic activity coefficient equation. In
multicomponent electrolyte systems, the activity coefficient of solvent water
is computed with the Meissner approximation to avoid excessive Gibbs-
Duhem integration (Bromley, 1973). Activity coefficients of molecular solutes
are estimated with the Setschenow equation. The Zemaitis equation is not a
thermodynamically consistent model, and binary parameters are empirical
functions of ionic strength. The model offers the advantage of predicting
mean ionic activity coefficients for unmeasured electrolyte systems from
Bromley's correlation of binary parameters (Meissner and Kusik, 1973). For
details on the model, see Bromley-Pitzer Activity Coefficient Model in Physical
Property Models.
References
L.A. Bromley, "Thermodynamic Properties of Strong Electrolytes in Aqueous
Solutions," AIChE J., Vol. 18, (1973), p. 313.
H.P. Meissner and C.L. Kusik, "Aqueous Solutions of Two or More Strong
Electrolytes-Vapor Pressures and Solubilities," Ind. Eng. Chem. Process Res.
Develop., Vol. 12, (1973), p. 205.

Future Models
Active research is being conducted in the field of electrolyte thermodynamics
(Mauer, 1983). For example, models based on Mean Spherical Approximation
(Planche and Renon, 1981, Watanasiri et al., 1982) and equation of state
electrolyte models (Frst and Renon, 1993) are being developed. Generally,
the trend is toward developing thermodynamically consistent models with
fewer adjustable parameters, broader applicability, and greater predictive
capability. A broad range of electrolyte activity coefficient models will soon be
available.
References
G. Mauer, "Electrolyte Solutions," Fluid Phase Equilibria, Vol. 13, (1983),
p. 269.
H. Planche and H. Renon, "Mean Spherical Approximation Applied to a Simple
but Nonprimitive Model of Interaction for Electrolyte Solutions and Polar
Substance," J. Phys. Chem, Vol. 85, (1981), p. 3924.
S. Watanasiri, M.R. Brule, and L.L. Lee, "Prediction of Thermodynamic
Properties of Electrolytic Solutions Using the Me an Spherical Approximation,"
J. Phys. Chem., Vol. 86, (1982), p. 282.

Electrolyte Data Regression
Data regression is a critical part of electrolyte process calculation. For
example, electrolyte activity coefficient models require regression of
experimental data to determine model parameters. It may also be necessary
to determine chemical equilibrium constants by data regression.
The Aspen Physical Property System Data Regression System (DRS) can be
used for electrolytes. There are two unique considerations for electrolyte
systems:
Ions are nonvolatile, so vapor-liquid phase equilibrium constraints for ions
are not applicable.
The chemical equilibrium constraint of the solution chemistry must be
satisfied.
Experimental data for electrolyte systems can be divided into four main
categories for both single electrolyte systems and multicomponent electrolyte
systems:
Electrolyte properties, such as mean ionic coefficients
Molecular properties, such as osmotic coefficient, solvent vapor pressure,
vapor-liquid phase equilibrium data, and liquid-liquid phase equilibrium
data
Solution properties, such as liquid mixture enthalpy and density
Salt solubility
Electrolyte data regression is most often performed on electrolyte properties
and molecular properties to determine activity coefficient model parameters.
Solution enthalpy data provide valuable information on temperature
derivatives of activity coefficients and can be used with other data to
determine the temperature dependency of activity coefficient model
parameters. These data can also be used to regress chemical equilibrium
constants and activity coefficient model parameters. Salt saturation limits can
be used to obtain equilibrium constants for salt precipitation (salt solubility
product).
See the User Guide for details on data regression.

5 Free-Water and Rigorous Three-Phase Calculations 181
5 Free-Water and Rigorous
Three-Phase Calculations
This chapter describes free-water, dirty-water, and rigorous three-phase
calculations in the Aspen Physical Property System. Guidelines to help you
choose the most appropriate method are included.
The following table lists the unit operation models that allow three-phase
calculations. The table shows, for each model, whether or not free-water,
dirty-water, and/or rigorous three-phase calculations can be performed.
Unit Operation Models That Allow Three-Phase
Calculations

Name

Description

Free-Water
Calculations

Dirty-Water
Calculations
Water
Decant
Stream
Rigorous
3-Phase
Calculations
Mixer Stream mixer YES YES YES YES
FSplit Stream splitter YES YES NO YES
Sep Component separator YES YES NO YES
Sep2 Two outlet separator YES YES NO YES
DSTWU Shortcut distillation
design
YES YES YES NO
Distl Shortcut distillation
rating
YES YES YES NO
SCFrac Shortcut petroleum
distillation
YES NO YES NO
RadFrac Rigorous distillation YES YES YES YES
MultiFrac Rigorous multicolumn
distillation
YES NO YES NO
PetroFrac Rigorous petroleum
distillation
YES NO YES NO
Extract Rigorous liquid-liquid
extractor
NO NO NO
Heater Heater/cooler YES YES YES YES
Flash2 Two outlet flash YES YES YES YES
Flash3 Three outlet flash NO NO NO YES
182 5 Free-Water and Rigorous Three-Phase Calculations

Name

Description

Free-Water
Calculations

Dirty-Water
Calculations
Water
Decant
Stream
Rigorous
3-Phase
Calculations
Decanter Liquid-liquid decanter YES NO NO
Heatx Two stream heat
exchanger
YES YES YES YES
MHeatx Multistream heat
exchanger
YES YES YES YES
RStoic Stoichiometric reactor YES YES YES YES
RYield Yield reactor YES YES YES YES
RGibbs Equilibrium reactor
Gibbs energy
minimization
NO NO NO YES
Pump Pump/hydraulic turbine YES YES YES YES
Compr Compressor/turbine YES YES YES YES
MCompr Multistage
compressor/turbine
YES YES YES YES
CrystallizerCrystallizer NO NO NO NO
Pipeline Pipeline YES NO NO YES
Dupl Stream duplicator
Mult Stream multiplier
Condenser only
Rigorous liquid-liquid equilibrium calculations
RGibbs handles any number of phases rigorously.

Free-Water and Dirty-Water
Immiscibility Simplification
The unit operation models in the table labeled Unit Operation Models That
Allow Three-Phase Calculations can handle the presence and the decanting of
free water or dirty water, when performing flash calculations or liquid-liquid
equilibrium calculations on water-organic systems in which the water phase is
essentially pure or has trace amounts of organic components.
Free-water calculations involve special methods for calculating the solubility
of water in the organic phase and a test for the presence of a pure water
phase. Free-water calculations are always faster than rigorous three-phase
calculations and require minimal physical property data preparation. Just like
free-water calculations, dirty-water calculations also involve special methods
for calculating the solubility of water in the organic phase. In addition to this,
special methods are used to compute the aolubility of organic compounds in
the water phase.
For water-hydrocarbon systems, free-water calculations are normally
adequate. The hydrocarbon solubility in the water phase is generally
negligible. In applications where the hydrocarbon solubility in the water phase
is of great concern (such as in an environmental study), use dirty-water or
rigorous three-phase calculations.
For chemical systems such as water-higher alcohols, free-water or dirty-water
calculations do not apply. Solubility of the organics in the water phase is
significant. Rigorous three-phase calculations are required.

Specifying Free-Water or Dirty-Water
Calculations
The free-water or dirty-water calculations are completely rigorous, except for
the assumption that the water phase is pure or has only a trace amount of
organic components. If free water or dirty water is present and you specify a
decant stream for the block, the Aspen Physical Property System places the
water phase in the decant stream. If you do not specify a decant stream, the
Aspen Physical Property System mixes the water phase with the organic
phase.
To request free-water or dirty-water
calculations for
Use the Free-Water field to Yes or
Dirty on the
The entire flowsheet Setup Specifications Global sheet
An individual unit operation block Block Options form for the block
An individual outlet stream in some blocks Flash-Specs form for the block
For all unit operation blocks except the distillation models, you can select two
types of free-water calculations using the following flash specification:
Valid Phases=Vapor-Liquid, to consider vapor and liquid phases
Valid Phases=Liquid-Only, to consider only liquid phases
Valid Phases=Vapor-Liquid-Liquid is reserved for rigorous three-phase
calculations. If you specify Valid Phases=Vapor-Liquid-Liquid, any free-water
specification is ignored. Dirty-water calculations will override the rigorous
three-phase calculations.
For all distillation models except RadFrac, MultiFrac, and PetroFrac, free water
calculations are performed in the condenser only. For RadFrac, MultiFrac, and
PetroFrac, you can request free-water calculations for additional stages in the
column. For details, please see the Aspen Plus User Guide, Chapter 10. Dirty-
water calculations are allowed only in RadFrac and in the condenser of
DSTWU and Distl.

Free-Water Phase Properties
The free-water phase K-value, K
w
*
, is calculated as follows:
K
w
*
=
w
*,l
/
w
v

Where:
w
*,l

= The fugacity coefficient of pure liquid water, calculated using a
free-water property method (for example, the STEAM-TA property
method)
w
v

= The fugacity coefficient of water in the vapor phase mixture,
calculated using the primary property method
When a free-water phase is present, its other thermodynamic properties
(such as enthalpy) and transport properties (such as viscosity) are calculated
using the free-water property method.

Organic Phase Properties
The K-value of water in the organic phase (for both free-water and dirty-
water calculations) is:

Where:
w

= The activity coefficient of water in the organic phase
w
*,l

= The fugacity coefficient of pure liquid water, calculated using the
free-water property method
w
v

You can select the calculation methods for
w
and
w
v
using the Water
solubility field on the Properties Specifications Global sheet or the Block
Options form.
Note: These methods apply to all vapor-liquid calculations for activity and
fugacity of water, whether or not free-water is specified.
Solu-water
option
Calculate
w
from Calculate
w
v
from
0

Free-water property method
1

Primary property method
2
where
when
3 Primary property method Primary property method
4

5
where
when
Free-water property method
Solu-water option 3 is not recommended unless binary interaction parameters
regressed from liquid-liquid equilibrium data are available.
The limiting solubility of water in the organic phase (x
w
sol
) is calculated as a
mole fraction weighted average of the solubilities of water in the individual
organic species:

Where:
x
i
= Water-free mole fraction of the ith organic
species
x
wi
sol
= Mole fraction solubility of water in the ith
species
The value of x
wi
sol
is calculated as a function of temperature, using the Water
Solubility model (WATSOL).

Dirty-Water Phase Properties
The K-value of water in the dirty-water phase, , is calculated as follows:

Where:
w
*,l

= The fugacity coefficient of pure liquid water, calculated using a
free-water property method (for example, the STEAM-TA
property method)
w
v

The K-values of other components are calculated as follows:

Where:

x
i
sol
, the solubility of component i in water, is calculated using the
Hydrocarbon Solubility model (HCSOL).

Rigorous Three-Phase Calculations
The unit operation models that can perform rigorous three-phase or two-
liquid-phase calculations are indicated in the table labeled Unit Operation
Models That Allow Three-Phase Calculations. These calculations make no
assumptions about the nature of the two liquid phases. The Aspen Physical
Property System uses the primary property method to calculate the K-values
of all components in both liquid phases. The second liquid phase does not
have to be aqueous. If the second liquid phase is aqueous, the solubility of
organics in water is treated rigorously. To obtain correct three-phase results,
you must use the appropriate binary parameters for the property model used
in the property method.
Specify rigorous three-phase calculations at the individual block level, using
the flash option Valid Phases=Vapor-Liquid-Liquid, except for Flash3. Flash3
has no flash options, since it performs only rigorous three-phase flashes.
Extract always performs rigorous two-liquid-phase calculations.

6 Petroleum Components Characterization Methods 187
6 Petroleum Components
Characterization Methods
The Aspen Physical Property System provides a wide range of methods for
characterization of petroleum fractions, or pseudocomponents. These
methods are used to estimate parameters, such as critical temperature, and
properties, such as ideal gas heat capacity, vapor pressure, and liquid
viscosity. The following table lists the:
Parameters that the Aspen Physical Property System estimates for
petroleum fractions
Methods available for each parameter. The literature references for each
method are listed at the end of this chapter.
Petroleum Fractions Characterization Methods
Parameter Description Methods Available
MW Molecular weight Brule et al. (1982)
Extended API (2002)
Extended Twu (2002)
Hariu-Sage (1969)
Hariu-Sage-Aspen (1994)
Kesler-Lee (1976)
Riazi API (1986)
Riazi API (1986), heavy petro
Riazi-Daubert (1980)
Tsang-Aspen (1978)
User routine PCMWU
Winn correlation (1957)
TC Critical temperature Brule et al. (1982)
Cavett (1962)
Extended Twu 1 (2002)
Extended Twu 2 (2002)
Extended Cavett (2002)
Kesler-Lee (1976)
Riazi API (1986)
Robinson-Peng (1978)
Tsang-Aspen (1978)
Twu (1984)
User routine PCTCU
188 6 Petroleum Components Characterization Methods
PC Critical pressure Cavett (1962)
Extended Edmister
(2002)Extended Twu (2002)
Kesler-Lee (1976)
Riazi API (1986)
Tsang-Aspen (1978)
Twu (1984)
User routine PCPCU
VC Critical volume Brule et al. (1982)
Edmister (1984)
Extended Twu (2002)
Lee-Kesler (1984)
Riedel (1954)
Twu (1984)
User routine PCVCU
OMEGA Acentric factor Defining relation
Edmister (1984)
Extended Lee-Kesler (2002)
Kesler-Lee (1976)
Kesler-Lee-Aspen (1994)
User routine PCOMGU
Twu generalized correlation
(1994)
Aspen-Twu generalized
correlation
PL Vapor pressure BK-10 (AspenTech
implementation)
Kesler-Lee (1980)
Maxwell-Bonnell (1955)
Tsang-SWAP (1978)
User routine PCPLU
VL Liquid molar volume Cavett (1974)
Rackett (Spencer and Danner,
1972)
User routine PCVOLU
WATSOL Water solubility in
hydrocarbon
Aspen
API Kerosene
Hibbard-Schalla (API)
User routine PCWSLU
User routine PCWSLU2
HCSOL Hydrocarbon
solubility in water-
rich phase
Aspen
User routine PCHSLU
MUL Liquid viscosity Watson (1935)
User routine PCMULU
User routine PCMULU2
CPIG Ideal gas heat
capacity
API Hybrid
Brule et al. (1982)
Cavett (1962)
Kesler-Lee (1976)
Mathias-Monks (1982)
Simplified Lee-Kesler
Tsang-Aspen (1978)
User routine PCCPGU
DHVL Enthalpy of
vaporization
Kistiakowsky (1923)
Vetere (1973)
User routine PCDHVU
DHFORM Ideal gas heat of
formation at 298.15
K
Default to zero
Edmister (1988)
Edmister-API (1988)
Edmister-API97 (1988)
User routine PCDHFU
DGFORM Ideal gas Gibbs free
energy of formation
at 298.15 K
Default to zero
Edmister (1988)
Edmister-API97 (1988)
User routine PCDGFU
RKSKBV RKS binary
interaction
parameters
API 1978
API 1987
User routine PCRKIU
User routine PCRKIU2
BWRGMA BWR orientation
parameter
Brule et al. (1982)
User routine PCBWRU
TCBWR BWR critical
temperature
Brule et al. (1982)
User routine PCBWRU
VCBWR BWR critical volume Brule et al. (1982)
User routine PCBWRU
The RKS binary interaction parameters are estimated for each
pseudocomponent in pairs with certain light gases which are present in the
simulation. The 1978 method estimates parameters for pseudocomponents
with CO
2
, CO, H
2
S, N
2
. The 1987 method estimates parameters for
pseudocomponents with methane, CO
2
, H
2
S, N
2
, and H
2
, and sets the
parameters for pseudocomponents with CO to zero.

AspenTech Extensions to
Characterization Methods for
Petroleum Fractions
A number of the methods for characterization of petroleum fractions are
AspenTech extensions to well-known methods. These are listed below. Plots
are available showing how some of the extended methods compare for a
typical crude assay.
Property Method Description
Molecular weight Hariu and Sage-
Aspen
Hariu-Sage (1969) model with Aspen
modification for light fractions.
Extended API Riazi-Daubert (1980) model with Aspen
modification for light fractions.
Extended Twu Twu (1984) model with Aspen modification for
high-boiling fractions.
Critical
temperature
Extended Twu 1 Twu (1984) model with Aspen modification for
high-boiling fractions using linear
extrapolation.
Extended Twu 1 Twu (1984) model with Aspen modification for
high-boiling fractions using extrapolation based
on constant Watson K.
Extended Cavett Cavett (1962) model with Aspen modification
for high-boiling fractions.
Critical pressure Extended Edmister Edmister (1984) model with Aspen
modification for high-boiling fractions.
Extended Twu Twu (1984) model with Aspen modification for
Critical volume Extended Twu Twu (1984) model with Aspen modification for
Acentric factor Lee and Kesler,
Aspen
Kesler-Lee (1976) model with Aspen
modification for high-boiling fractions.
Extended Lee-
Kesler
Further modifications for high-boiling fractions.
Aspen-Twu
generalized
correlation
Twu generalized correlation (1994) with Aspen
improvement for heavy components.
Water solubility Aspen AspenTech empirical correlation
Ideal gas heat
capacity
API Hybrid Combination of API Technical databook
procedure 7D4.2 and Brule et al. (1982)
Simplified Lee-
Kesler
Kesler-Lee (1976) model with AspenTech
modification.

Comparison of Extended Molecular Weight
Methods

Comparison of Extended Critical
Temperature Methods


Comparison of Extended Critical Pressure
Methods

Comparison of Extended Critical Volume
Methods

Comparison of Extended Acentric Factor
Methods

User Models for
Characterization of Petroleum
Fractions
All characterization parameters and properties of petroleum fractions can be
estimated by user routines. See Aspen Plus User Models, Chapter 25, for
details on writing these routines.
Property Routine
Molecular weight PCMWU
Critical temperature PCTCU
Critical pressure PCPCU
Critical volume PCVCU
Acentric factor PCOMGU
Vapor pressure PCPLU
Liquid molar volume PCVOLU
Water solubility PCWSLU, PCWSLU2
Hydrocarbon solubility PCHSLU
Liquid viscosity PCMULU, PCMULU2
Ideal gas heat capacity PCCPGU
Enthalpy of vaporization PCDHVU
Standard enthalpy of formation PCDHFU
Standard Gibbs free energy of
formation
PCDGFU
RKS interaction parameters PCRKIU, PCRKIU2
BWR orientation parameter, Tc, Vc PCBWRU
Normal boiling point PCABPU
Specific gravity PCSGU

Property Methods for
Characterization of Petroleum
Fractions
Since there are several methods available for estimation of a given
parameter, it is often difficult to select the appropriate method for the
application. For your convenience, we have grouped several sets of methods
into property methods. These selections are made according to standard
industry practices, most commonly used methods, or based on AspenTech's
own extensions. The AspenTech extensions are intended to improve the
behavior of the correlations in the low and high-boiling ranges.
The following property methods are available:
The API-METH property method consists of methods based mainly on the
API procedure. This property method is appropriate for refinery
applications.
COAL-LIQ property method consists of methods developed for coal liquid
applications. The database used to develop the correlations contains a
large percentage of aromatic compounds.
ASPEN property method consists of methods developed by AspenTech for
petroleum components and methods based on the API procedure. This
method is recommended.
LK property method is based mainly on the methods of Kesler and Lee.
API-TWU property method is based on the ASPEN property method, but
uses the Twu correlations for critical properties.
EXT-TWU property method is similar to the API-TWU method, except that
AspenTech extensions to both low boiling and high boiling ranges are used
for MW, TC, PC, VC, and acentric factor.
EXT-API property method is similar to the EXT-TWU method, except that
the extended API method is used for molecular weight and the extended
Lee-Kesler method is used for acentric factor.
EXT-CAV property method is similar to the EXT-API method, except that
the extended Cavett method is used for critical temperature and the
extended Edmister method is used for critical pressure and critical volume.
There are no documented temperature limits for these methods from their
authors, but our studies show that the limits within which the methods are
reliable depend on the property. The first five methods typically behave
properly for fractions up to a normal boiling point of 800 to 1000 F. The
extended methods extend the range of applicability for MW, TC, PC, and
acentric factor to a normal boiling point of about 1500 F.
The models associated with each of the property methods available for
characterization of pseudocomponents are listed in the tables below.

Property Method ASPEN: Aspen Tech and
API procedures
Property Model
Molecular weight Hariu and Sage-Aspen
T
c
Riazi-Daubert
P
c
Riazi-Daubert
V
c
Riedel
Acentric factor Lee and Kesler, Aspen
Vapor pressure BK-10
Water solubility Aspen
Liquid viscosity Watson
Ideal gas heat capacity Kesler-Lee
Enthalpy of vaporization Vetere
Standard enthalpy of formation Edmister
Property Model
Standard Gibbs energy of
formation
Edmister
RKS binary parameters API 1978

Property Method API-METH: API
Procedures
Property Model
Molecular weight Hariu-Sage
T
c
Riazi-Daubert
P
c
Riazi-Daubert
V
c
Riedel
Acentric factor Kesler-Lee
Vapor pressure Maxwell-Bonnell
Standard enthalpy of formation Default to zero
formation
Default to zero
BWR orientation parameter, T
c
, V
c
Brule et al.

Property Method COAL-LIQ: for Coal Liquids
Property Model
Molecular weight Hariu-Sage
T
c
Tsang-Aspen
P
c
Tsang-Aspen
V
c
Riedel
Vapor pressure Tsang-SWAP
Ideal gas heat capacity Mathias-Monks
Standard enthalpy of formation Default to zero
formation
Default to zero
Property Model
BWR orientation parameter, T
c
, V
c
Brule et al.

Property Method LK: Lee-Kesler
Property Model
Molecular weight Kesler-Lee
T
c
Kesler-Lee
P
c
Kesler-Lee
V
c
Riedel
Vapor pressure Kesler-Lee
formation
Edmister

Property Method API-TWU: AspenTech,
API, and Twu
Property Model
Molecular weight Hariu and Sage-Aspen
T
c
Twu
P
c
Twu
V
c
Twu
Acentric factor Lee and Kesler, Aspen
Water solubility API kerosene-line
formation
Edmister

Property Method EXT-TWU: Twu and
AspenTech Extensions
Property Model
Molecular weight Extended Twu
T
c
Extended Twu
P
c
Extended Twu
V
c
Extended Twu
Acentric factor Extended Twu
formation
Edmister

Property Method EXT-API: API, Twu, and
Property Model
Molecular weight Extended API correlation
T
c
Extended Twu
P
c
Extended Twu
V
c
Extended Twu
Acentric factor Extended Lee-Kesler
formation
Edmister

Property Method EXT-CAV: Cavett, API, and
Property Model
Molecular weight Extended API correlation
T
c
Extended Cavett
P
c
Extended Edmister
V
c
Extended Edmister
Acentric factor Extended Lee-Kesler
formation
Edmister

Water Solubility in Petroleum
Fractions
The solubility of water in the hydrocarbon phase is calculated by the water-
solubility correlation. Coefficients for this correlation for a pseudocomponent
can be calculated using any of the following:
The Kerosene line correlation (API Technical databook procedure 9A1.4).
An AspenTech proprietary correlation which depends on TB, SG and MW.
The Hibbard & Schalla Correlation. API Technical Data Book Procedure
9A1.5

Estimation of NRTL and
UNIQUAC Binary Parameters
for Water and Petroleum
Fractions
The NRTL and UNIQUAC binary parameters for water and pseudocomponents
are intended for use in LLE calculations, as water and hydrocarbons tend to
form two liquid phases. These interaction parameters are estimated from the
mutual solubility data. The solubility of water is estimated from one of the
methods described above. The solubility of pseudocomponent in water is
estimated from the API procedure 9A2.17.
Since water and hydrocarbons are essentially immiscible, the mutual
solubilities are very low. As a result, the solubility is inversely proportional to
the infinite dilution activity coefficients. For infinitely dilute binary system,
binary interaction parameters for the NRTL and UNIQUAC models can be
computed directly from infinite-dilution activity coefficient data.

Estimation of ATOMNO and
NOATOM for Petroleum
Fractions
ATOMNO and NOATOM, which combine to form the chemical formula, are
estimated from the molecular weight and carbon-to-hydrogen (C/H) ratio. The
C/H ratio is estimated using the procedure in Technical Data Book - Petroleum
Refining, vol. 2, fig. 2B6.1, American Petroleum Institute, 1983. These
components are assumed to contain no atoms but carbon and hydrogen, and
the carbon and hydrogen numbers are adjusted to meet the molecular weight
and C/H ratio. As a result, H and C may be fractional.

Estimation of Flash Point
Aspen Plus provides several properties representing different methods of
calculating the flash point. The following methods are available:
FLPT-API, the API method for determining flash point
FLPT-PM, the Pennsky-Martens method (ASTM-D93)
FLPT-TAG, the Tag method (ASTM-D56)
FLPT-API uses the ASTM D86 10% temperature for the petroleum fraction or
the normal boiling point for pure components in a procedure based on the API
computerized procedure 2B7.1 (Riazi, 1985, 1986). Linear extrapolation is
also performed.
The other two methods use a modified bubble point calculation described in
Seader and Henley (1998). These methods use mole-weight-modified K-
values for a bubble point flash in which the value of the summation ,
normally 1, has been replaced with an experimentally determined parameter
a. The parameter a has different values for the two methods.

Petroleum Method References
(BK10) AspenTech implementation of the method described in B.C. Cajander
et al., Prediction of Equilibrium Ratios from Nomograms of Improved
Accuracy," J. Chem. Eng. Data, 5 (3), p. 251 (1960), and in J.M. Lenoir,
"Predict K Values at Low Temperatures," Hydro. Proc., (1969).
Brul, M.R., C.T. Lin, L.L. Lee, and K.E. Starling, AIChE J., 28, p. 616 (1982).
Cavett, R.H., "Physical Data for Distillation Calculations Vapor-Liquid
Equilibria," Presented at 27th Midyear Meeting of API Division of Refining, May
15, 1962.
Cavett, R.H., FLOWTRAN Physical Properties Reference Manual, Monsanto
Company, 1974.
Edmister, W.C. and B.I. Lee, Applied Hydrocarbon Thermodynamics, 2nd
edition, Vol. 1, Ch. 7, Gulf Publishing Co., (1988).
Edmister, W.C., Applied Hydrocarbon Thermodynamics, 2nd edition, Table
24.9 pp. 221-228, Gulf Publishing Co., (1988).
Edmister, W.C. and B.I. Lee, Applied Hydrocarbon Thermodynamics, 2nd
edition, Vol. 2, Ch. 25, Gulf Publishing Co., (1988). The Edmister-API97
methods use the API97 viscosity model instead of the older API model.
Hariu, O.H. and R.C. Sage, Hydro. Proc., (1969).
Hibbard and Schalla, Water solubility parameters from API Databook
procedure 9A1.5; Natl. Advisory Comm. Aeron. Rm. E52024 (1952).
Kerosene line from API Databook, Figure 9A1.4.
Kesler, M.G. and B.I. Lee, Hydro. Proc., 55 (3), p. 153, (1976).
Kesler, M.G. and B.I. Lee, Hydro. Proc., 59 (7), p. 163, (1980).
Kistiakowsky, W., Z. Phys. Chem., 107, 65 (1923).
Mathias, P.M., and K.G. Monks, SRC-I Quarterly Progress Report, Air Products
and Chemicals, Inc., April June 1982.
Maxwell and Bonnell, API Procedure 5A1.15 (1955).
Redlich-Kwong-Soave interaction parameters from API Databook, Table
8D1.3, 3
rd
Ed (1978).
Redlich-Kwong-Soave interaction parameters from API Databook, Table
8D1.3, 5
th
Ed (1987).
Riazi, M.R., private communication, 1985. and M.R. Riazi, API Databook, 5th
Ed., procedure 2B7.1 (1986).
Riazi, M.R., API Databook, 5th Ed., 2B2.B (1986). Model for heavy petroleum
fractions for a molecular weight range of 200-800.
Riazi, M.R., API Databook, 5th Ed., 4D3.1 (1986).
Riazi, M.R. and T.E. Daubert, Hydro. Proc., 59 (3), p. 115, (1980).
Riedel, L., API Prodedure 4A3.1 (1954).
Robinson D.B., and D.Y. Peng "The Characterization of the Heptanes and
Heavier Fractions for the GPA Peng-Robinson Programs," GPA Research
Report RR-28, March (1978).
Seader, J.D. and Ernest J. Henley, Separation Process Principles, p. 281,
Wiley and Sons, 1998.
Spencer, C.F. and R.P. Danner, J. Chem Eng. Data., 17, (1972).
Tsang, M., Computer-Aided Industrial Process Design, The ASPEN Project,
Second Annual Report, June 1, 1977 to May 30, 1978; Submitted to U.S.
D.O.E. by M.I.T. Department of Chemical Engineering and Energy Laboratory
under Contract No. E(4918) 2295, Task No. 9, June 15, 1978.
Twu, C.H., "An Internally Consistent Correlation for Predicting the Critical
Propeties and Molecular Weights of Petroleum and Coal-Tar Liquids," Fluid
Phase Equilibria, 16, p. 137 (1984).
Twu, C.H., J.E. Coon, and J.R. Cunningham, "A Generalized Vapor Pressure
Equation for Heavy Hydrocarbons", Fluid Phase Equilibria, 96, p. 19-31
(1994).
Vetere, A., "Modification of the Kistiakowsky Equation for the Calculation of
the Enthalpies of Vaporization of Pure Compounds," Laboratory Richerche
Chimica Industriale SNAM PROGETTI, San Donato, Milanese, 1973.
Watson, K. et al., API Figure 11A4.1 (1935).
Winn, F.W., The Petroleum Refiner, 36, p. 157, (1957).

7 Property Parameter Estimation 203
7 Property Parameter
Estimation
This chapter describes:
Estimation methods used by the Property Constant Estimation System
(PCES)
How to generate a report for the estimated parameters
If you request estimation, the Aspen Physical Property System, by default,
estimates all missing property parameters required by physical property
models. These parameters include any not available in the databank and not
specified on Properties Parameters forms. The following table labeled
Parameters Estimated by the Aspen Physical Property System lists all the
parameters that the Aspen Physical Property System can estimate.

Parameters Estimated by the
System
See Physical Property Models for more information on the models listed
below.
Pure Component Constants
Parameter Description Model
MW Molecular weight
TB Normal boiling point
TC Critical temperature
PC Critical pressure
VC Critical volume
ZC Critical compressibility factor
DHFORM Ideal gas heat of formation at
298.15 K

204 7 Property Parameter Estimation
DGFORM Ideal gas Gibbs free energy of
formation at 298.15 K

OMEGA Pitzer acentric factor
DHVLB Heat of vaporization at TB
Pure Component Constants
VB Liquid molar volume at TB
VLSTD Standard liquid volume
RGYR Radius of gyration
DELTA Solubility parameter at 298.15 K
GMUQR UNIQUAC R parameter UNIQUAC
GMUQQ UNIQUAC Q parameter UNIQUAC
PARC Parachor
DHSFRM Solid enthalpy of formation at 98.15
K

DGSFRM Solid Gibbs energy of formation at
298.15 K

DHAQHG Aqueous infinite dilution enthalpy of
formation
Helgeson
DGAQHG Aqueous infinite dilution Gibbs
energy of formation
Helgeson
S25HG Entropy at 298.15 K Helgeson
Parachor is needed in estimating surface tension and radius of gyration.
Temperature-Dependent Property Correlation Parameters
CPIG Ideal gas heat capacity Ideal Gas Heat
Capacity/DIPPR
CPLDIP Liquid heat capacity Liquid Heat
Capacity, DIPPR
CPSPO1 Solid heat capacity Solid Heat
Capacity
PLXANT Vapor pressure Antoine/Wagner
DHVLWT Heat of vaporization Watson/DIPPR
RKTZRA Liquid molar volume Rackett/DIPPR
OMEGHG Helgeson OMEGA heat capacity
coefficient
Helgeson
CHGPAR Helgeson C Heat Capacity Coefficient Helgeson
MUVDIP Vapor viscosity Chapman-
Enskog-
Brokaw/DIPPR
MULAND Liquid viscosity Andrade/DIPPR
KVDIP Vapor thermal conductivity Stiel-
Thodos/DIPPR
KLDIP Liquid thermal conductivity Sato-
Riedel/DIPPR
SIGDIP Surface tension Hakim-
Steinberg-
Stiel/DIPPR
Binary Parameters
WILSON/1,
WILSON/2
Wilson parameters Wilson
NRTL/1,
NRTL/2
NRTL parameters NRTL
UNIQ/1,
UNIQ/2
UNIQUAC parameters UNIQUAC
UNIFAC Group Parameters
GMUFR UNIFAC R Parameter UNIFAC
GMUFQ UNIFAC Q Parameter UNIFAC
GMUFDR R parameter for Dortmund UNIFAC Dortmund
UNIFAC
GMUFDQ Q parameter for Dortmund UNIFAC Dortmund
UNIFAC
GMUFLR R parameter for Lyngby UNIFAC Lyngby UNIFAC
GMUFLQ Q parameter for Lyngby UNIFAC Lyngby UNIFAC

Description of Estimation Methods
This section describes the:
Methods available for estimating property parameters
Application range for each method (when appropriate)
Expected error for each method (when appropriate)
The expected error information can help you to evaluate a method.

Molecular Weight (MW)
If you use the general method to enter molecular structure on the Properties
Molecular Structure General sheet, the Aspen Physical Property System
estimates molecular weight from the molecular formula. If you do not use the
general method, then either:
You must enter molecular weight using the Properties Parameters Pure
Component Scalar form
The molecular weight must be available from the Aspen Physical Property
System databank.

Normal Boiling Point (TB)
The Aspen Physical Property System uses the normal boiling point to estimate
many other parameters, such as critical temperature and critical pressure, if
they are missing. Normal boiling point is one of the most important pieces of
information required for property/parameter estimation. Therefore, if you
have an experimental normal boiling point, you should enter it using the
Properties Parameters Pure Component Scalar form.
PCES provides the following methods for estimating normal boiling point:
Method Information Required
Joback Structure
Ogata-Tsuchida Structure
Gani Structure
Mani PC, Vapor pressure data (also uses TC if available)
Joback Method
The Joback method gives only an approximate estimate of normal boiling
point. Absolute average error is 12.9 K for 408 diverse organic compounds.
The Joback method is less accurate than the Ogata-Tsuchida method, but it is
easier to use and applies to a wider range of compounds.
Table 3.5 in Physical Property Data lists the functional groups for the Joback
method.
Ogata-Tsuchida Method
The Ogata-Tsuchida method is for compounds with a single functional group
(such as -OH) and a radical type (such as methyl). This method performed
reliably for 600 compounds tested; 80% were within 2 K, 89% were within 3
K, and 98% were within 5 K. Deviations larger than 5 K were generally for
compounds containing the methyl radical.
Table 3.8 in Physical Property Data lists the functional groups for the Ogata-
Tsuchida method.
Gani Method
The Gani method uses contributions from both first-order and second-order
groups. The second order groups account for the effect of neighboring atoms.
Use of second order groups results in higher accuracy. The estimation error of
this method is about 2/5 of that of the Joback method. (AIChE J.
40,1697,1994).
Table 3.4A in Physical Property Data lists the functional groups for this
method.
Mani Method
The Mani method was developed by Juan-Carlos Mani of Aspen Technology.
This method estimates TB from the Riedel vapor pressure equation when one
or two experimental temperature-vapor pressure data pairs are available.
Such data is usually available for new specialty chemicals, especially for large
molecules. This method can also be used to estimate TC and vapor pressure.
This method provides very accurate and reliable estimates of TB, TC and
vapor pressure curve when some experimental vapor pressure data is
available. It is very useful for complex compounds that decompose at
temperatures below the normal boiling points.
The Riedel equation gives vapor pressure as a function of TB, TC and PC of
the component. If one T-P pair is available, and TC and PC are known or
estimated, the equation can be used to provide estimates of TB and vapor
pressure. When two T-P pairs are available and PC is known or estimated, the
equation can provide estimates of TB, TC, and vapor pressure.

Critical Temperature (TC)
PCES provides the following methods for estimating critical temperature :
Joback Structure, TB
Lydersen Structure, TB
Ambrose Structure, TB
Fedors Structure
Simple MW, TB
Gani Structure
Mani PC, Vapor pressure
Joback Method
The Joback method is based on the Lydersen method, except it uses a larger
database and has fewer functional groups. Joback tested approximately 400
organic compounds. The average relative error is 0.8%. The average error is
4.8K.
method.
Lydersen Method
The Lydersen method is one of the first successful methods for estimating
critical parameters. The functional groups listed in Table 3.7, Physical
Property Data, are almost identical to those for the Joback method. The
estimated error for TC is usually less than 2%. For high molecular weight
nonpolar compounds (MW >> 100), the errors are 5% or higher.
Ambrose Method
The Ambrose method yields smaller errors than the Joback and Lydersen
methods, but is more difficult to use. Table 3.1 in Physical Property Data lists
the functional groups for this method. The errors for approximately 400
organic compounds are: average relative error = 0.7%; average error=4.3K.
Fedors Method
The Fedors method is not as accurate as the Joback, Lydersen, and Ambrose
methods. For some compounds, the errors can be very large. Klincewicz and
Reid (AIChE J. 30, 137, 1984) reported an average error of 4% for 199
compounds. Use this method only when TB is unknown. Table 3.4 in Physical
Property Data lists the functional groups for this method.
Simple Method
The Simple method does not depend on molecular structure, but requires MW
and TB as input. This method was developed by Klincewicz and Reid. The
average error for about 200 diverse organic compounds tested is 2.3%.
Gani Method
Use of second order groups results in higher accuracy (AIChE J. 40,1697,1994).
Estimation accuracy is generally superior to other methods For 400
compounds tested, the average relative error is 0.85%. The average error is
4.85K. Table 3.4A in Physical Property Data lists the functional groups for this
method.
Mani Method
This method estimates TC from the Riedel equation when two experimental
temperature-vapor pressure data pairs are available. Such data is usually
available for new specialty chemicals, especially for large molecules. This
method can also be used to estimate TB and vapor pressure.
This method provides very accurate and reliable estimate of TB, TC and vapor
pressure curve when some experimental vapor pressure data is available. It is
very useful for complex compounds that decompose at temperatures below
the normal boiling points.

Critical Pressure (PC)
PCES provides the following methods for estimating critical pressure:
Joback Structure
Lydersen Structure, MW
Ambrose Structure, MW
Gani Structure
Joback Method
database and has fewer functional groups. For 390 organic compounds
tested, the average relative error is 5.2%; the average error is 2.1bar.
method.
Lydersen Method
critical parameters. The functional groups listed in Table 3.7, Physical
Property Data, are almost identical to those for the Joback method. The
estimated error is approximately 4%.
Ambrose Method
the functional groups for this method. For 390 organic compounds tested, the
average relative error is 4.6 %; the average error is 1.8 bar.
Gani Method
Estimation accuracy is generally superior to other methods. For 390 organic
compounds tested, the average relative error is 2.89 %; the average error is
1.13 bar. Table 3.4A in Physical Property Data lists the functional groups for
this method.

Critical Volume (VC)
PCES provides the following methods for estimating critical volume:
Joback Structure
Lydersen Structure
Ambrose Structure
Riedel TB, TC, PC
Fedors Structure
Gani Structure
Joback Method
database and has fewer functional groups. For 310 organic compounds
tested, the average relative error is 2.3%; the average error is 7.5 cc/mole.
method.
Lydersen Method
critical parameters. The functional groups listed in Table 3.7 Physical Property
Data are almost identical to those for the Joback method. The estimated error
is approximately 4%.
Ambrose Method
the functional groups for this method. For 310 organic compounds tested, the
average relative error is 2.8%; the average error is 8.5 cc/mole.
Riedel Method
This method is recommended for hydrocarbons only.
Fedors Method
The Fedors method is not as accurate as the Joback, Lydersen, and Ambrose
methods. For some compounds, the errors can be very large. Klincewicz and
Reid (AIChE J. 30, 137, 1984) reported an average error of 4% for 199
compounds. Use this method only when TB is unknown. Table 3.4 in Physical
Property Data lists the functional groups for this method.
Gani Method
Estimation accuracy is generally superior to other methods. For 310 organic
compounds tested, the average relative error is 1.79%; the average error is
6.0 cc/mole. Table 3.4A in Physical Property Data lists the functional groups
for this method.

Critical Compressibility Factor (ZC)
The Aspen Physical Property System calculates the critical compressibility
factor (ZC) by:

Where:
R = Universal gas constant
P
c
= Critical pressure
V
c
= Critical volume
T
c
= Critical temperature

Acentric Factor (OMEGA)
PCES provides two methods for estimating acentric factor:
Definition method
Lee-Kesler method
Definition Method
When you use the definition method, the acentric factor is calculated from its
definition:

Where P
i
*
is vapor pressure calculated at reduced temperature, (T/T
c
) of 0.7.
When you use the definition method, the vapor pressure correlation
parameters PLXANT, TC, and PC must be available from the databank or
estimated.
Lee-Kesler Method
The Lee-Kesler method depends on TB, TC, and PC. This method is
recommended for hydrocarbons. Lee and Kesler reported that this method
yields values of acentric factors close to those selected by Passut and Danner
(Ind. Eng. Chem. Process Des. Dev. 12, 365, 1973).

Ideal Gas Heat of Formation (DHFORM)
PCES provides the following methods for estimating the ideal gas heat of
formation at 298.15 K:
Benson Structure
Joback Structure
BensonR8 Structure
Gani Structure
All methods are group contribution methods that apply to a wide range of
compounds. The Benson Method is recommended.
The heat of formation of the ideal gas is calculated relative to the zero
enthalpy of the constituent elements at 25C and 1 atm in their natural
phases (for instance, solid graphite for carbon, liquid for mercury, and H
2
gas
for hydrogen).
Benson Method
The Benson method is a second-order group contribution method. This
method:
Accounts for the effect of neighboring atoms
Is more complex to use than the Joback method
Reports more accurate results than Joback (average error is 3.7 kJ/mol)
Table 3.2 in Physical Property Data lists the functional groups for the Benson
method.
Joback Method
The Joback method is a first-order group contribution method. It is simpler to
use than the other available methods, but is less accurate. Reported average
error is 8.9 kJ/mol.
method.
BensonR8 Method
This is the Benson method provided with Release 8 of Aspen Plus. It is
retained for upward compatibility. The Benson method is preferred.
Gani Method
Use of second order groups results in higher accuracy than the Joback
method (average error is 3.71 kJ/mol) (AIChE J. 40,1697,1994).
method.

Ideal Gas Gibbs Free Energy of Formation
(DGFORM)
PCES provides the following methods for estimating ideal gas Gibbs free
energy of formation at 298.15 K:
Joback Structure
Benson Structure
Gani Structure
The Gibbs energy of formation of the ideal gas is calculated relative to the
zero Gibbs energy of the constituent elements at 25C and 1 atm in their
natural phases (for instance, solid graphite for carbon, liquid for mercury, and
H
2
gas for hydrogen).
Benson Method
The Benson method is a second-order group contribution method. For this
property, the Benson method requires you to enter the symmetry number
and the number of possible optical isomers, if applicable. The Aspen Physical
Property System does not generate this information automatically from the
general molecular structure.
method.
Joback Method
use than the other available methods, but is less accurate. Reported errors
are in the range of 5 to 10 kJ/mol. The errors are larger for complex
materials.
method.
Gani Method
The Gani method:
Is more complex to use than the Joback method
Reports more accurate results than Joback (average error is 3.24 kJ/mol)
method

Heat of Vaporization at TB (DHVLB)
PCES estimates heat of vaporization at the normal boiling point by applying
the heat of vaporization correlation (DHVLWT) at TB.

Liquid Molar Volume at TB (VB)
PCES estimates liquid molar volume at the normal boiling point by applying
the Rackett equation (RKTZRA) at TB.

Standard Liquid Volume (VLSTD)
PCES estimates standard liquid volume by applying the Rackett liquid molar
volume correlation (RKTZRA) at 60 F.

Radius of Gyration (RGYR)
PCES estimates radius of gyration from parachor (PARC).

Solubility Parameter (DELTA)
The solubility parameter is calculated from the definition.

UNIQUAC R and Q Parameters (GMUQR, GMUQQ)
PCES provides the Bondi method for estimating the UNIQUAC R and Q
parameters. This method requires only molecular structure as input. Table 3.3
in Physical Property Data lists the functional groups.

Parachor (PARC)
PCES provides one method for estimating Parachor. The Parachor method is a
group-contribution method. The functional groups for this method are listed in
Table 3.10 in Physical Property Data.

Ideal Gas Heat Capacity (CPIG)
PCES provides three methods for estimating ideal gas heat capacity:
Data Ideal gas heat capacity data
Benson Structure
Joback Structure
PCES uses the Ideal-Gas-Heat-Capacity-Polynomial model for this property.
Both the Benson and Joback methods are group-contribution methods that
apply to a wide range of compounds.
Do not use the Benson or Joback methods outside the temperature range of
280 to 1100 K. Errors are generally less than 1 to 2%.
Benson Method
Benson is the recommended method. It accounts for the effect of neighboring
atoms. In comparison with the Joback method, Benson:
Is more complex to use
Reports more accurate results (average error 1.1% for 27 diverse
compounds)
method.
Joback Method
use than the Benson method, but is less accurate. Reported average error is
1.4% for 28 diverse components.
method.
Data Method
The Data method determines parameters for the ideal gas heat capacity
polynomial. Experimental ideal gas heat capacity data are fitted. You enter
this data on the Properties Data Pure Component form.

Vapor Pressure (PLXANT)
PCES provides the following methods for estimating vapor pressure:
Data Vapor pressure data
Riedel TB, TC, PC, (vapor pressure data)
Li-Ma Structure, TB, (vapor pressure data)
Mani PC, (vapor pressure data) (also uses TC if available)
The Extended Antoine model is used for this property.
Data Method
The Data method determines parameters for the Extended Antoine equation
by fitting experimental vapor pressure data that you enter on the Properties
Data Pure Component form.
Riedel Method
The Riedel method estimates parameters for the Extended Antoine vapor
pressure equation by applying the Riedel parameter and the Plank-Riedel
constraint at the critical point. It also makes use of the condition that at the
normal boiling point, the vapor pressure is 1 atm. The parameters are valid
from TB to TC. This method is accurate for nonpolar compounds, but not for
polar compounds.
Li-Ma Method
The Li-Ma method is a group contribution method for estimating parameters
for the Extended Antoine vapor pressure equation. The parameters are valid
from TB to TC. This method is accurate for polar and nonpolar compounds.
For 28 diverse compounds, the reported average error was 0.61% (Fluid
Phase Equilibria, 101, 101, 1994).
method.
Mani Method
This method estimates parameters for the Extended Antoine vapor pressure
equation using the Riedel equation when one or two experimental
temperature-vapor pressure data pairs are available. Such data is usually
available for new specialty chemicals, especially for large molecules. This
method can also be used to estimate TB and TC.
This method provides very accurate and reliable estimates of TB, TC and
vapor pressure curve when some experimental vapor pressure data values
are available. It is very useful for complex compounds that decompose at
temperatures below the normal boiling points. The vapor pressure equation is
applicable from the lowest temperature data point to the critical temperature.

Heat of Vaporization (DHVLWT)
PCES provides the following methods for estimating heat of vaporization:
Data Heat of vaporization data
Definition TC, PC, PL, (Heat of vaporization data)
Vetere MW, TB, (Heat of vaporization data)
Gani Structure, (Heat of vaporization data)
Ducros Structure, (Heat of vaporization data)
Li-Ma Structure, TB, (Heat of vaporization data)
The Watson model is used for this property.
Data Method
The Data method determines the Watson parameters by fitting experimental
heat of vaporization data that you enter on the Properties Data Pure
Component form.
Definition Method
The Definition method calculates heat of vaporization from the Clausius-
Clapeyron equation. It requires vapor pressure, TC, and PC as input. The
calculated heat of vaporization values are used to determine the parameters
for the Watson equation. When the Riedel method was used to estimate vapor
pressure, reported average error for the heat of vaporization was 1.8% for 94
compounds.
Vetere Method
The Vetere method estimates heat of vaporization at TB, then uses the
Watson equation to extrapolate heat of vaporization to TC. Reported average
error is 1.6%.
Gani Method
The Gani method is a group contribution method for estimating heat of
vaporization at 298K. It uses the Watson equation to extrapolate heat of
vaporization to TC. This method requires only molecular structure as input.
method.
Ducros Method
The Ducros method is a group contribution method for estimating heat of
vaporization at 298K. It uses the Watson equation to extrapolate heat of
vaporization to TC (Thermochimica Acta, 36, 39, 1980; 44, 131, 1981; 54, 153,
1982; 75, 329, 1984). This method:
Uses more complex structure correction
Can be applied to organo-metallic compounds
method.
Li-Ma Method
The Li-Ma method is a group contribution method for estimating heat of
vaporization at different temperatures. This method requires molecular
structure and TB as input. Reported average error for 400 diverse compounds
was 1.05% (Fluid Phase Equilibria, 1997).
method.

Liquid Molar Volume (RKTZRA)
PCES provides three methods for estimating liquid molar volume:
Data Liquid molar volume data
Gunn-Yamada TC, PC.OMEGA
Le Bas Structure
The Rackett model is used for this property.
Gunn-Yamada Method
The Gunn-Yamada method estimates saturated liquid molar volume, when the
reduced temperature is less than 0.99. The calculated values are used to
determine the Rackett parameter. This method:
Applies to nonpolar and slightly polar compounds
Is more accurate than the Le Bas method
Le Bas Method
The Le Bas method estimates liquid molar volume at TB. The result is used to
determine the Rackett parameter. For 29 diverse compounds, an average
error of 3.9% is reported. This method requires only molecular structure as
input. Table 3.6 in Physical Property Data lists the functional groups.
Data Method
The Data method determines the Rackett parameter by fitting the
experimental liquid molar volume data that you enter on the Properties Data
Pure Component form.

Liquid Viscosity (MULAND)
PCES provides the following methods for estimating liquid viscosity:
Data Liquid viscosity data
Orrick-Erbar Structure, MW, VL, ZC, TC, PC
Letsou-Stiel MW, TC, PC, OMEGA
The Andrade model is used for this property.
Orrick-Erbar Method
Orrick-Erbar is a group-contribution method that depends on liquid molar
volume. It is limited to low temperatures, ranging from above the freezing
point to the reduced temperature of 0.75. This method:
Is not reliable for highly branched structures
Does not apply to inorganic liquids or sulfur compounds
Reports an average error of 15% for 188 organic liquids
Table 3.9 in Physical Property Data lists the functional groups for this method.
Letsou-Stiel Method
The Letsou-Stiel method is appropriate for high temperatures and for reduced
temperatures of 0.76 to 0.92. The average error is 3% for 14 liquids.
Data Method
The Data method determines the Andrade parameters by fitting experimental
liquid viscosity data that you enter on the Properties Data Pure Component
form.

Vapor Viscosity (MUVDIP)
PCES provides the following methods for estimating vapor viscosity:
Data Vapor viscosity data
Reichenberg Structure, MW,TC, PC
The DIPPR vapor viscosity correlation is used for this property.
Reichenberg Method
Reichenberg is a group-contribution method. For nonpolar compounds, the
expected error is between 1 and 3%. For polar compounds, the errors are
higher, but usually less than 4%. Table 3.11 in Physical Property Data lists
the functional groups for this method.
Data Method
The Data method determines the DIPPR vapor viscosity correlation
parameters by fitting experimental vapor viscosity data you enter on the
Properties Data Pure Component form.

Liquid Thermal Conductivity (KLDIP)
PCES provides the following methods for estimating liquid thermal
conductivity:
Data Liquid thermal conductivity data
Sato-Riedel MW, TB, TC
The DIPPR liquid thermal conductivity correlation is used for this property.
Sato-Riedel Method
When you use the Sato-Riedel method, accuracy varies widely from 1 to 20%
for the compounds tested. The accuracy is poor for light and branched
hydrocarbons.
Data Method
The Data method determines the DIPPR liquid thermal conductivity correlation
parameters. This method fits experimental liquid thermal conductivity data.
Enter this data on the Properties Data Pure Component form.

Vapor Thermal Conductivity (KVDIP)
No estimation method is available for estimating vapor thermal conductivity.
You can use the Data method to fit experimental data directly to the DIPPR
vapor thermal conductivity correlation. Use the Properties Data Pure
Component form to enter experimental vapor thermal conductivity data.

Surface Tension (SIGDIP)
PCES provides the following methods for estimating surface tension:
Data Surface tension data
Brock-Bird TB, TC, PC
Macleod-Sugden TB, TC, PC, VL, PARC
Li-Ma Structure, TB
The DIPPR surface tension correlation is used for this property.
Data Method
The Data method determines the DIPPR surface tension correlation
parameters by fitting experimental surface tension data. Enter this data on
the Properties Data Pure Component form.
Brock-Bird Method
The Brock-Bird method applies to non-hydrogen-bonded liquids. The expected
error is less than 5%.
Macleod-Sugden Method
The Macleod-Sugden method applies to nonpolar, polar, and hydrogen-
bonded liquids. For hydrogen-bonded liquids, errors are normally less than 5
to 10%.
Li-Ma Method
The Li-Ma method is a group contribution method for estimating surface
tension at different temperature. This method requires only molecular
structure and TB as input. Reported average error for 427 diverse compounds
was 1.09% (Fluid Phase Equilibria, 118, 13, 1996).
method.

Liquid Heat Capacity (CPLDIP)
PCES provides the following methods for estimating liquid heat capacity:
Data Liquid heat capacity data
Ruzicka Structure
The DIPPR liquid heat capacity correlation is used for this property.
Data Method
The Data method determines the DIPPR liquid heat capacity correlation
parameters by fitting experimental liquid heat capacity data. Enter this data
on the Properties Data Pure Component form.
Ruzicka Method
The Ruzicka method is a group contribution method for estimating
parameters for the DIPPR liquid heat capacity correlation. The parameters are
valid from the melting point to the normal boiling point. This method requires
only molecular structure as input. For 9772 diverse compounds, reported
average errors were 1.9% and 2.9% for nonpolar and polar compounds,
respectively (J. Phys. Chem. Ref. Data, 22, 597, 1993; 22, 619, 1993).
method.

Solid Heat Capacity (CPSPO1)
PCES provides the following methods for estimating solid heat capacity:
Data Solid heat capacity data
Mostafa Structure
The solid heat capacity correlation is used for this property.
Data Method
The Data method determines the solid heat capacity correlation parameters
by fitting experimental liquid heat capacity data. You enter this data on the
Properties Data Pure Component form.
Mostafa Method
The Mostafa method is a group contribution method for estimating
parameters for the solid heat capacity correlation. This method is applied to
solid inorganic salts which are divided to cations, anions and ligands.
Reported average errors for 664 diverse solid inorganic salts, was 3.18%
(Ind. Eng. Chem. RES., 35, 343, 1996).
method.

Solid Standard Enthalpy of Formation (DHSFRM)
Only the Mostafa method is available for estimating solid standard enthalpy of
formation.
The heat of formation of the solid is calculated relative to the zero enthalpy of
the constituent elements at 25C and 1 atm in their natural phases (for
instance, solid graphite for carbon, liquid for mercury, and H
2
gas for
hydrogen).
Mostafa Method
The Mostafa method is a group contribution method. This method applies to
solid inorganic salts which can be divided to cations, anions and ligands.
Reported average errors for 938 diverse solid inorganic salts was 2.57% (Ind.
Eng. Chem. RES., 34, 4577, 1995).
method.

Solid Standard Gibbs Free Energy of Formation
(DGSFRM)
Only the Mostafa method is available for estimating solid standard Gibbs free
energy of formation.
The Gibbs energy of formation of the solid is calculated relative to the zero
Gibbs energy of the constituent elements at 25C and 1 atm in their natural
2
gas
for hydrogen).
Mostafa Method
The Mostafa method is a group contribution method. This method applies to
solid inorganic salts which can be divided to cations, anions and ligands.
Reported average errors for 687 diverse solid inorganic salts was 2.06% (Ind.
Eng. Chem. RES., 34, 4577, 1995).
method.

Standard Enthalpy of Formation of Aqueous
Species (DHAQHG)
PCES provides the following methods for estimating standard enthalpy of
formation of aqueous species for the Helgeson electrolyte model:
AQU-DATA DHAQFM
THERMO DGAQFM, S025C
AQU-EST1 DGAQFM
AQU-EST2 S025C
The heat of formation of the aqueous components is calculated relative to the
zero enthalpy of the constituent elements at 25C and 1 atm in their natural
2
gas
for hydrogen).
AQU-DATA Method
The AQU-DATA method uses directly experimental standard enthalpy of
formation at infinite dilution (DHAQFM) if it exists in the databank.
THERMO Method
The THERMO method estimates standard enthalpy of formation according to
thermodynamic relationship if DGAQFM and S025C exist in the databank, as
follows:

where S025E is the sum of absolute entropy of the constituent elements of a
compound at 25C.
AQU-EST1 Method
If DGAQFM is in the databank, the AQU-EST1 method estimates standard
enthalpy of formation using an empirical relation developed by Aspen
Technology, as follows:

AQU-EST2 Method
If S025C is in the databank, the AQU-EST2 method estimates standard
enthalpy of formation using an empirical relation developed by Aspen

compound at 25C.

Standard Gibbs Free Energy of Formation of
Aqueous Species (DGAQHG)
PCES provides the following methods for estimating standard Gibbs free
energy of formation of aqueous species for the Helgeson electrolyte model:
AQU-DATA DGAQFM
THERMO DHAQFM, S025C
AQU-EST1 DHAQFM
AQU-EST2 S025C
The Gibbs energy of formation of the aqueous components is calculated
relative to the zero Gibbs energy of the constituent elements at 25C and 1
atm in their natural phases (for instance, solid graphite for carbon, liquid for
mercury, and H
2
gas for hydrogen).
AQU-DATA Method
The AQU-DATA method uses directly experimental standard Gibbs free energy
of formation at infinite dilution (DGAQFM) if it exists in the databank.
THERMO Method
If DHAQFM and S025C are in the databank, the THERMO method estimates
standard Gibbs free energy of formation according to thermodynamic
relationship, as follows:

compound at 25C.
AQU-EST1 Method
If DHAQFM is in the databank, the AQU-EST1 method estimates standard
Gibbs free energy of formation using an empirical relation developed by
Aspen Technology, as follows:

AQU-EST2 Method
If S025C is in the databank, the AQU-EST2 method estimates standard Gibbs
free energy of formation using an empirical relation developed by Aspen

compound at 25C.

Absolute Entropy of Aqueous Species (S25HG)
PCES provides the following methods for estimating absolute entropy of
aqueous species for the Helgeson electrolyte model:
AQU-DATA S025C
THERMO DGAQFM, DHAQFM
AQU-EST1 DGAQFM
AQU-EST2 DHAQFM
AQU-DATA Method
The AQU-DATA method uses directly the experimental absolute entropy
(S025C) if it exists in the databank.
THERMO Method
If DGAQFM and DHAQFM are in the databank, the THERMO method estimates
absolute entropy according to thermodynamic relationship, as follows:

compound at 25C.
AQU-EST1 Method
If DGAQFM is in the databank, the AQU-EST1 method estimates absolute
entropy using an empirical relation developed by Aspen Technology, as
follows:

compound at 25C.
AQU-EST2 Method
If DHAQFM is in the databank, the AQU-EST2 method estimates absolute
entropy using an empirical relation developed by Aspen Technology, as
follows:

Born Coefficient (OMEGHG)
Only the Helgeson method is available for estimating the Born coefficient of
aqueous species for the Helgeson electrolyte model. This method requires
S25HG and CHARGE as input.

Helgeson Capacity Parameters (CHGPAR)
PCES provides the following methods for estimating the Helgeson capacity
parameters of aqueous species for the Helgeson electrolyte model:
HG-AUQ OMEGHG, CPAQ0
HG-CRIS OMEGHG, S25HG, CHARGE, IONTYP
HG-EST OMEGHG, S25HG
HG-AQU Method
The HG-AQU method estimates the Helgeson capacity parameters from the
infinite dilution heat capacity CPAQ0.
HG-CRIS Method
The HG-CRIS method estimates the Helgeson capacity parameters according
to the Criss-Cobble method.
HG-EST Method
The HG-EST method estimates the Helgeson capacity parameters using an
empirical relation developed by Aspen Technology.

Binary Parameters (WILSON, NRTL, UNIQ)
PCES estimates binary parameters for the WILSON, NRTL, and UNIQUAC
models, using infinite-dilution activity coefficients. Infinite-dilution activity
coefficients can be supplied by:
Laboratory data entered on the Properties Data Mixture form, with data
type=GAMINF
Estimation, using the UNIFAC, UNIF-LL, UNIF-DMD or UNIF-LBY method
For best results, use experimental infinite-dilution activity coefficient data. Of
the four UNIFAC methods, the Dortmund method (UNIF-DMD) gives the most
accurate estimate of infinite-dilution activity coefficients. This method is
recommended. See UNIFAC, UNIFAC (Dortmund modified), and UNIFAC
(Lyngby modified) for detailed descriptions of these methods.
If the data is at a single temperature, PCES estimates only the second
element of the parameter, such as WILSON/2. If the data cover a
temperature range, PCES estimates both elements of the parameter, such as
WILSON/1 and WILSON/2.
For NRTL, the alpha parameter (c
ij
) is by default set to 0.3, but the value can
be changed, and in some cases such change may be necessary. The
procedure estimates NRTL coefficients from limiting activity coefficients, and
does not necessarily represent the concentration range (such as non-zero
molefractions) on which the alpha parameter has a marked influence,
especially in two-liquid systems. You can set c
ij
for the binary system to the
appropriate value before running the estimation.
Value Systems for which this value is recommended
0.30 Nonpolar substances, nonpolar with polar non-associated liquids, small
deviations from ideality
0.20 Saturated hydrocarbons with polar non-associated liquids and systems
that exhibit liquid-liquid immiscibility
0.47 Strongly self-associated substances with nonpolar substances

UNIFAC R and Q Parameters (GMUFR, GMUFQ,
GMUFDR, GMUFDQ, GMUFLR, GMUFLQ)
PCES provides the Bondi method for estimating the R and Q parameters for
UNIFAC functional groups. the Aspen Physical Property System uses these
parameters in the UNIFAC, Dortmund UNIFAC, and Lyngby UNIFAC models.
The Bondi method requires only molecular structure as input. Table 3.3 in
Physical Property Data lists the functional groups for the Bondi method.


228 Index
Index
A
Acentric factor estimation methods
211
Activity coefficient method 6, 12
for calculating phase equilibrium
6
list 12
Activity coefficient models 30, 94,
103
characteristics of 30
common models for 103
list of property methods 94
AMINES property method 105
API-METH property method 194
APISOUR property method 107
API-TWU pseudocomponent
property method 194
Apparent component 171, 174
approach 171
mole fractions 174
Applications 18, 22
chemical 18
liquid-liquid equilibrium 22
metallurgical 18
petrochemical 18
ASPEN pseudocomponent property
method 194
B
Binary parameters estimation
methods 225
BK10 property method 55
B-PITZER property method 113
BWR-LS property method 66
C
CHAO-SEA property method 55, 56
Chemical reactions for electrolytes
169
Chemistry 169
Classes of property methods 40
COAL-LIQ property method 194
Critical compressibility factor
estimation methods 210
Critical pressure estimation
methods 208
Critical temperature estimation
methods 207
Critical volume estimation methods
209
Cubic equations of state 23
D
Data regression 179
and electrolytes 179
Diffusion coefficient property
methods 33, 151
E
ELECNRTL property method 108
Electrolyte activity coefficient
models 31
Electrolyte calculation 169
overview 169
Electrolyte data regression
overview 179
Electrolyte NRTL 178
equation 178
Electrolyte property methods 104,
108, 110, 116
ELECNRTL 108
ENRTL-HF 110
Electrolyte thermodynamic models
overview 177
ENRTL-HF property method 110
ENRTL-HG property method 110
Enthalpy balances 34
nonconventional components 34
Enthalpy of formation estimation
methods 211, 221
solid 221
standard ideal gas 211
Index 229
Equation-of-state 6, 7, 23, 65, 72
common models for property
methods 72
method for phase equilibrium 6,
7
property methods
for high-pressure hydrocarbon
applications 65
property models 23
equilibrium constants 175
molality versus mole fraction
scale 175
F
Flexible and predictive property
methods 72
equation-of-state 72
Free-water calculations 181
G
Gibbs energy of formation
estimation methods 212, 222
aqueous species 222
solid 222
GRAYSON property method 55, 57
Group contribution activity
coefficient models 31, 96
Dortmund-modified UNIFAC 96
Lyngby-modified UNIFAC 96
UNIFAC 96
H
Hayden-O'Connell 92
property methods 92
Heat of formation estimation
methods 211
Heat of vaporization 213, 216
estimation method at TB 213
Helgeson property model 110, 114
ENRTL-HG property method 110
PITZ-HG property method 114
Henry's Law 45
noncondensable components 45
HF equation of state 93, 110
ENRTL-HF property method 110
property methods using 93
I
Ideal gas heat capacity estimation
methods 214
Ideal gas law 23, 90
property methods using 90
IDEAL property method 45
Intermediate properties 123
L
Liquid activity coefficient property
methods 88
list 88
Liquid enthalpy 136
methods 136
Liquid entropy methods 145
Liquid fugacity coefficient methods
131
Liquid Gibbs energy methods 141
Liquid heat capacity estimation
methods 220
Liquid molar volume 213, 217
estimation methods (at TB) 213
Liquid thermal conductivity
Liquid viscosity estimation methods
218
Liquid-liquid equilibria 9, 15
activity coefficient method 15
equation-of-state method 9
Liquid-liquid-vapor equilibria 15
LK property method 194
LK-PLOCK property method 69
M
Major properties 123
Metallurgical applications 18, 117
phase equilibria 18, 117
Models (physical properties) 154,
163
definition 154
replacing 163
molality scale 175
Molar volume methods 147
mole fraction scale 175
Molecular weight estimation
method 205
230 Index
N
NIST 47
REFPROP 47
Nonconventional components 34
enthalpy calculations 34
Nonconventional solid property
models 159
Normal boiling point estimation
methods 206
Nothnagel 91
property methods 91
NRTL activity coefficient model 94
P
Parachor estimation method 214
PCES 203
PENG-ROB property method 59
Peng-Robinson 59
property method 59
Petroleum components
characterization methods 187
Petroleum mixtures 54, 64
property methods for 54, 64
petroleum property methods 196
API-METH 196
API-TWU 197
ASPEN 195
COAL-LIQ 196
EXTAPI 198
EXTCAV 199
EXTTWU 198
LK 197
Petroleum-tuned equation-of-state
property methods 59
Phase equilibria and solids 18
Phase equilibrium calculation 6
Physical properties 123, 128, 152,
154
calculation methods 128
major and subordinate properties
123
models 154
overview 123
routes 152
Pitzer activity coefficient model 177
PITZER property method 111
PITZ-HG property method 114
PR-BM property method 70
Predictive property methods 72, 87
equation-of-state 72
PRMHV2 property method 81
Property Constant Estimation
System 203
Property methods 5, 6, 32, 33, 34,
40, 54, 55, 59, 64, 65, 72, 87,
88, 103, 104, 116, 122, 161,
164, 194
activity coefficient common
models 103
classes of 40
common models for equation-of-
state 72
common models for petroleum
mixtures 64
creating 161, 164
definition 40, 122
disffusion coefficient 33
equation-of-state 59, 65
flexible and predictive equation-
of-state 72
flexible and predictive models 87
for characterizing petroleum
components 194
for electrolyte solutions 104, 116
for K-value models 55
for liquid fugacity 55
for petroleum mixtures 54
liquid activity coefficient 88
list 5
modifying 161
petroleum-tuned equation-of-
state 59
surface tension 34
thermal conductivity 32
thermodynamic 6
transport 32
viscosity 32
Property parameters 203
estimating 203
PRWS property method 82
PSRK 83
property method 83
R
Radius of gyration estimation
method 213
Redlich-Kwong 61, 71, 72, 91,
108, 111
Index 231
equation-of-state 61, 71, 72, 91,
108, 111
REFPROP 47
Rigorous three-phase calculations
181
list of unit operation models 181
RK-ASPEN property method 83
RKS-BM property method 71
RKSMHV2 property method 84
RK-SOAVE property method 61
RKSWS property method 85
Routes 122, 152, 159, 161, 164,
166
conflicting 164
creating 166
definition 122, 152
modifying 166
replacing 161
tracing 159
S
Solid enthalpy methods 140
Solid enthalpy of formation of
aqueous species estimation
methods 222
Solid entropy methods 146
Solid fugacity coefficient methods
134
Solid Gibbs energy methods 143
Solid heat capacity estimation
methods 221
Solid standard enthalpy of
formation estimation methods
221
Solid standard Gibbs free energy of
formation estimation methods
222
Solids activity coefficient method
18
SOLIDS property method 117
Solubility parameter estimation
method 214
Solution chemistry 169
SRK property method 62
SRK-KD property method 63
SRK-ML property method 64
SR-POLAR property method 86
Standard enthalpy of formation
211, 222
aqueous species 222
Standard Gibbs free energy of
formation 212, 223
aqueous species 223
Standard heat of formation 211
Standard liquid volume estimation
method 213
Steam tables 120
ASME 120
list 120
property methods 120
STEAMNBS property method 121
STEAM-TA property method 121
STMNBS2 property method 121
Subordinate properties 123
Surface tension 34, 219
property methods 34
Surface tension methods 151
T
Thermal conductivity 32
property method 32
Thermal conductivity methods 149
Thermodynamic property 6
methods 6
Thermodynamic property models
155
Tracing routes 159
Transport property 32
methods 32
Transport property models 158
True component approach 171
U
UNIFAC 96, 226
activity coefficient model 96
R and Q parameters estimation
method 226
UNIQUAC 98, 214
activity coefficient model 98
R and Q parameters estimation
method 214
Unit operation models 181
rigorous three-phase calculations
181
V
Van Laar activity coefficient model
100
232 Index
Vapor enthalpy methods 135
Vapor entropy methods 144
Vapor fugacity coefficient methods
130
Vapor Gibbs energy methods 140
Vapor phase association 26
Vapor pressure estimation methods
215
Vapor thermal conductivity
Vapor viscosity estimation methods
218
Vapor-liquid equilibria activity
coefficient method 13
Vapor-liquid equlibria equation-of-
state method 7
Virial equations of state 25
Viscosity 32
property method 32
Viscosity methods 148
VPA/IK-CAPE equation of state 93
W
Wilson activity coefficient model
101
Z
Zemaitis equation 178

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