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    Lembar Perhitungan Ester

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    panjigomis
    1. The document contains calculations for a chemical reaction experiment involving sodium hydroxide, methanol, acetic acid, and sulfuric acid as a catalyst. 2. The calculations determine the volumes of methanol, acetic acid, and sulfuric acid catalyst needed at two different catalyst concentrations. 3. Kinetic experiments are performed and the rate constants for the reaction are calculated from the data obtained.

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    Lembar Perhitungan Ester

    Uploaded by

    panjigomis
    23 views7 pages
    1. The document contains calculations for a chemical reaction experiment involving sodium hydroxide, methanol, acetic acid, and sulfuric acid as a catalyst. 2. The calculations determine the volumes of methanol, acetic acid, and sulfuric acid catalyst needed at two different catalyst concentrations. 3. Kinetic experiments are performed and the rate constants for the reaction are calculated from the data obtained.

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    1. The document contains calculations for a chemical reaction experiment involving sodium hydroxide, methanol, acetic acid, and sulfuric acid as a catalyst. 2. The calculations determine the volumes of methanol, acetic acid, and sulfuric acid catalyst needed at two different catalyst concentrations. 3. Kinetic experiments are performed and the rate constants for the reaction are calculated from the data obtained.

    Copyright:

    © All Rights Reserved
    Download as DOCX, PDF, TXT or read online from Scribd
    Download as docx, pdf, or txt
    23 views7 pages

    Lembar Perhitungan Ester

    Uploaded by

    panjigomis
    1. The document contains calculations for a chemical reaction experiment involving sodium hydroxide, methanol, acetic acid, and sulfuric acid as a catalyst. 2. The calculations determine the volumes of methanol, acetic acid, and sulfuric acid catalyst needed at two different catalyst concentrations. 3. Kinetic experiments are performed and the rate constants for the reaction are calculated from the data obtained.

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    © All Rights Reserved
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    LEMBAR PERHITUNGAN

    1. Perhitungan Reagen
    NaOH 0.25N 500 ml
    N =

    x valensi
    gr NaOH = 5 gram

    asam asetat =
    1.022 gr/ml

    metanol =
    0,776 gr/ml
    H2SO4
    =
    1.7492 gr/ml
    2. Kebutuhan katalis H
    2
    SO
    4
    Variabel katalis I (H
    2
    SO
    4
    0.4 N)
    N =



    Volume total I = VH
    2
    SO
    4
    + Vmetanol+ Vasam asetat
    275 = 3,1443 + V metanol+ V asam asetat
    Vol. metanol+Vol. asam asetat = 271,8557 ml
    Perbandingan vol. metanol : Asam asetat = 2 : 1
    Misal Vol. asam asetat = X
    Vol. metanol = 271,8557 X

    Mol Metanol = 2 Mol Asam asetat
    (

    ) = 2(

    )
    (
    ()

    ) = 2(

    )
    6.3288 0.023X = 0.0327X
    90,618 mL = X
    Dimana X adalah volume asam asetat = 90.618 ml
    Vol. metanol = 299.16 90,618 ml
    = 181,237 ml
    Variabel katalis II (H
    2
    SO
    4
    0.8 N)
    N =



    Volume total II = Vol. H
    2
    SO
    4
    + Vol. metanol+ Vol. asam asetat
    275 = 5.775 + Vol. metanol+ Vol. asam asetat
    Vol. metanol+Vol. asam asetat = 269.225 ml
    Perbandingan vol metanol : Asam asetat = 2 : 1
    Misal Vol. asam asetat = X
    Vol. metanol = 269.225 X
    Mol Metanol = 2 mol Asam asetat

    = 2(

    )
    (
    ()

    ) = 2(

    )
    6.267-0.0233X = 0.059X
    89,7416 mL = X
    Dimana X adalah volume asam asetat = 89.7416 ml
    Vol. metanol = 269.225 89.7416 ml
    = 179.483 ml

    CH
    3
    COOH + C
    4
    H
    9
    OH C
    4
    H
    9
    COOCH
    3
    + H
    2
    O
    A B C D

    Variabel 1(Konsentrasi katalis H
    2
    SO
    4
    0.4N)
    Gram asam asetat = v kadar = 1.022

    90.618 ml 0.98 = 90.759 gram


    C
    AO
    =

    ()
    =

    = 5.5 mol/L
    Gram metanol = v kadar = 0.776

    181.237 ml 0.98 = 137.827 gram


    C
    BO
    =

    ()
    =

    = 15.66 mol/L
    C
    A
    =
    ( )( )

    =
    ( ) ( )

    = 0.05v 0.4
    Xa = 1-



    T (menit) Volume NaOH C
    A
    = 0.05v 0.4 Xa
    0 70
    3.1 0.4364
    13 35
    1.35 0.7545
    26 34.5 1.325
    0.7590
    39 33 1.25
    0.7727
    52 32.5 1.225
    0.7773
    65 32 1.2
    0.7818


    C
    A
    = C
    AO
    (1-X
    A
    ) = C
    AO
    C
    AO
    .XA = 5.5 (1-X
    A
    )
    C
    B
    = C
    BO
    C
    AO
    .X
    A
    = 15.66 5.5 X
    A

    C
    C
    = C
    AO
    .X
    A
    = 5.5 X
    A
    C
    D
    = C
    AO
    .X
    A
    = 5.5 X
    A

    M =

    =


    = 2.847
    -

    = k
    1
    (

    = k
    1
    (

    = k
    1
    (

    ) (

    )
    (

    )(

    = k
    1
    (

    ) (

    = k
    1

    ((

    ) (

    = k
    1

    ((

    ) (

    = k
    1

    ((

    ) (

    )
    Pada saat kesetimbangan
    k =

    =
    (

    )(

    )(

    )

    Konstanta Kesetimbangan
    K =
    (

    )(

    )
    =
    ()

    ()( )
    = 1.356

    = k
    1

    ((

    ) (

    = k
    1

    ((

    ) (

    )
    Mencari nilai

    *(

    )(

    =

    *(

    )(

    =

    [

    =

    [

    =

    [



    Rumus ABC
    (

    ) = (X
    A
    13.845)(X
    A
    -0.782)
    0.048

    )(

    = 0.048

    =
    (

    )(

    )
    (

    )(

    )


    A + B = 0
    -0. 782A-13.845 B = 1
    A = 0.07655
    B = -0.07655
    Sehingga persamaan menjadi
    0.048*

    ()

    + = k
    1
    . t
    0.048xln *
    ()()
    ()()
    + = k
    1
    . t y = mx
    t (x) X
    A
    Y XY X
    2
    0
    0.4364
    0.0377 0 0
    13
    0.7545
    0.158 2.054 169
    26
    0.7590
    0.16656 4.33 676
    39
    0.7727
    0.21 8.19 1521
    52
    0.7773
    0.243 12.636 2704
    65
    0.7818
    0.394 25.6 4225

    9295

    k
    1
    = m =

    ()
    =
    ()()
    ()()
    = 4.5677 . 10
    -3
    mol/men
    K =

    k
    2
    =

    = 3.3685 . 10
    -3
    mol/men

    Variabel 2 (Konsentrasi katalis H
    2
    SO
    4
    0.8N)
    Gram asam asetat = v kadar = 1.022

    89.7416 ml 0.98 = 89.88 gram


    C
    AO
    =

    ()
    =

    = 5.447 mol/L
    Gram metanol = v kadar = 0.776

    179.483 ml 0.98 = 136.49 gram


    C
    BO
    =

    ()
    =

    = 15.51 mol/L
    C
    A
    =
    ( )( )

    =
    ( ) ( )

    = 0.05v 0.8
    Xa = 1-



    t (menit) Volume NaOH C
    A
    = 0.05v 0.8 X
    A
    = 1


    0 50
    1.7
    0.6879
    13 44.5
    1.425 0.7384
    26 43
    1.35 0.7521
    39 41
    1.25 0.7705
    52 40
    1.2 0.7797
    65 39.5
    1.175 0.7843

    Pada saat kesetimbangan
    k =

    =
    (

    )(

    )(

    )

    Konstanta Kesetimbangan
    K =
    (

    )(

    )
    =
    ()

    ()( )
    = 1.3825
    Mencari nilai

    *(

    )(

    =

    *(

    )(

    =

    [

    =

    [

    =

    [


    Rumus ABC
    (

    ) = (X
    A
    13.1)(X
    A
    - 0.784)
    0.05

    )(

    = 0.05

    =
    (

    )(

    )
    (

    )(

    )

    A + B = 0
    -0.784A-13.1 B = 1
    A = 0.0812
    B = -0.0812
    Sehingga persamaan menjadi
    0.05*

    ()

    + = k
    1
    . t
    0.05xln *
    ()()
    ()()
    + = k
    1
    . t y = mx
    t (X) X
    A
    Y XY X
    2
    0 0.6879 0.102 0 0
    13 0.7384 0.1393 1.8109 169
    26 0.7521 0.1571 4.0846 676
    39 0.7705 0.2 7.8 1521
    52 0.7797 0.2572 13.3744 2704
    65 0.7834 0.3557 23.12 4225



    50.189

    9295

    k
    1
    = m =

    ()
    =
    ()()
    ()()
    = 3.659 . 10
    -3
    mol/men
    K =

    k
    2
    =

    = 2.6467 . 10
    -3
    mol/men

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