Solutions Code 0 JEEAdvanced2013 VMC Solved
Solutions Code 0 JEEAdvanced2013 VMC Solved
Solutions Code 0 JEEAdvanced2013 VMC Solved
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Part1:PHYSICS
1.
32
(x
+ y2
32
appropriate dimensions), when the particle is taken from the point (a, 0) to the point (0, a) along a circular path of radius a about the origin in the x-y plane is : (A) Ans.(D) W =
2K a r r uu F .dr = K a K 2a
(B)
(C)
(D)
( Fx dx + Fy dy )
W =K
xdx
(x
+ y2
3/ 2
ydy
(x
+ y2
3/ 2
1 1 = =0 d = K x2 + y 2 x2 + y 2 ( a, 0 ) a, 0
( 0, a )
0 ,a
2.
Two rectangular blocks, having identical dimensions, can be arranged either in configuration I or in configuration II as shown in the figure. One of the blocks has thermal conductivity and the other 2 . The temperature difference between the ends along the x-axis is the same in both the configurations. It takes 9s to transport a certain amount of heat from the hot end to the cold end in the configuration I. The time to transport the same amount of heat in the configuration II is :
(A) Ans.(A) H =
2.0s
(B)
3.0s
(C)
4.5s
(D)
6.0s
dQ
Q=
T R
(i)
2 KA 3l R1 = 2 KA 1 2 KA KA 3KA = + = l l l R2
(configuration 1)
(configuration 2)
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R2 =
l
3KA
t2 = 2 sec
3.
Two non-reactive monoatomic ideal gases have their atomic masses in the ratio 2 : 3. The ratio of their partial pressures, when enclosed in a vessel kept at a constant temperature, is 4 : 3. The ratio of their densities is :
(A)
1:4 = = 2 3 4 3
(B)
1:2
(C)
6:9
(D)
8:9
Ans.(D)
M1 M2 P 1 P2
Using PM = RT
P 1M 1 1 = P2 M 2 2 1 2 = P 1M1 P2 M 2 =
4 3
2 3
8 9
4.
A particle of mass m is projected from the ground with an initial speed u0 at an angle with the horizontal. At the highest point of its trajectory, it makes a completely inelastic collision with another identical particle, which was thrown vertically upward from the ground with the same initial speed u0. The angle that the composite system makes with the horizontal immediately after the collision is :
(A)
(B)
(C)
(D)
Ans.(A) From energy conservation both will have equal speeds at the point of collision. V = u0 cos
For perfectly inelastic collision, to conserve linear momentum Final velocity of combined mass will be along the Resultant
= 45o
5.
A pulse of light of duration 100 ns is absorbed completely by a small object initially at rest. Power of the pulse is 30 mW and the speed of light is 3 108 ms 1 . The final momentum of the object is :
(A) (C)
0.3 1017 kg ms 1 3.0 1017 kg ms 1
(B) (D)
Ans.(B) P =
E C
power t C
30 103 3 10
8
100 109
= 1017 kgm / s
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6.
In the Young's double slit experiment using a monochromatic light of wavelength , the path difference (in terms of an integer n) corresponding to any point having half the peak intensity is :
(A)
( 2n + 1)
2
(B)
( 2n + 1)
(C)
( 2n + 1)
(D)
( 2n + 1)
16
Ans.(B) I = 4 I 0 cos 2
2 I 0 = 4 I 0 cos 2
cos 2 2 = 1 2
2 1 2
2
= ( 2n + 1)
p.d . = ( 2n + 1)
p.d = ( 2n + 1)
7.
The image of an object, formed by a plano-convex lens at a distance of 8 m behind the lens, is real and is onethird the size of the object. The wavelength of light inside the lens is radius of the curved surface of the lens is :
(A)
2 3
1m
(B)
2m
(C)
3m
(D)
6m
Ans.(C)
V u
1 3
8 u
1 3
u = 24
1 1 1 = v u f =
1
2 3
1 f 0 =
1 8
1 24
f =6
= 3/ 2
f
1 6
= =
1 1 1 1 R
3/ 2 1 1 1 R
R= 3
8.
One end of a horizontal thick copper wire of length 2L and radius 2R is welded to an end of another horizontal thin copper wire of length L and radius R. When the arrangement is stretched by applying forces at two ends, the ratio of the elongation in the thin wire to that in the thick wire is :
(A)
0.25
x = Fl Fl = Ay r 2 y
(B)
0.50
(C)
2.00
(D)
4.00
2 2 l r x1 l1 r2 1 2L R = = 1 . 2 = = 2 x2 r1 l 2 l 2 r1 2 L 2R
x2 =2 x1
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9.
1 2
(i +
1 2
(i
(B)
45
(C)
60
(D)
75
Ans.(A) Cos =
= 120
i= 180 = 30 2
10.
The diameter of a cylinder is measured using a Vernier callipers with no zero errors. It is found that the zero of the Vernier scale lies between 5.10 cm and 5.15 cm of the main scale. The Vernier scale has 50 divisions equivalent to 2.45cm. The 24th division of the Vernier scale exactly coincides with one of the main scale divisions. The diameter of the cylinder is :
(A)
5.112 cm
(B)
5.124 cm
2.45 cm 50
(D)
5.136 cm
(D)
5.148 cm
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In the circuit shown in the figure, there are two parallel plate capacitors each of capacitance C. The switch S1 is The switch S2 is then pressed to charge pressed first to fully charge the capacitor C1 and then released. After some time, S2 is released and then S3 is pressed. After some time, the capacitor C2. (A) the charge on the upper plate of C1 is 2CV0 (B) the charge on the upper plate of C1 is CV0
(C)
(D)
Ans.(BD)
12.
r A particle of mass M and positive charge Q, moving with a constant velocity u1 = 4 i ms 1 , enters a region of
uniform static magnetic field normal to the x y plane. The region of the magnetic field extends from x = 0 to
x = L for all values of y. After passing through this region, the particle emerges on the other side after 10 r i + j ms 1 . The correct statement(s) is (are) milliseconds with a velocity u2 = 2 3
The direction of the magnetic field is -z direction. The direction of the magnetic field is +z direction The magnitude of the magnetic field
50 M units. 3Q 100 M units. 3Q
r u1 = 4 i Ans.(AC) r u2 = 2( 3 i+ j) Tan = 2 2 3 = 30
M
QB
10 103 =
B=
.M 6
QB
50 M units 3Q
M
6Q
100 =
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13.
A horizontal stretched string, fixed at two ends, is vibrating in its fifth harmonic according to the equation,
y ( x,t ) = (0.01 m) sin [(62.8 m 1 ) x] cos[628 s 1 )t ]. Assuming = 3.14, the correct statements(s) is (are)
The number of nodes is 5. The length of the string is 0.25 m. The maximum displacement of the midpoint of the string, from its equilibrium position is 0.01 m. The fundamental frequency is 100 Hz.
1 1 y = ( 0.01 m ) sin ( 62.8 m ) x cos ( 628 s ) t
=l 2 62.8 = 2 = 2 m 62.8
k=
14.
arrangement is placed in a liquid of density 2 and is allowed to reach equilibrium. The correct statement(s) is
4 R3 g 3k 8 R3 g 3k
the net elongation of the spring is the net elongation of the spring is
the light sphere is partially submerged. the light sphere is completely submerged. In equilibrium let elongation of spring is x
Then kx =
vg
x=
vg
k
4 R 3 g 3k
In equilibrium net force of weight and spring force on light sphere in downward direction is
kx + vg = 2 vg = FB
So it is fully submerged.
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15. Two non-conducting solid spheres of radii R and 2R, having uniform volume charge densities 1 and 2
respectively, touch each other, The net electric field at a distance 2R from the centre of the smaller sphere, along 1 the line joining the centres of the spheres, is zero. The ratio can be. 2
(A)
Ans.(BD)
(B)
32 25
(C)
32 25
(D)
For EP = 0
Q1 4 0 ( 2 R )
2
2 R
3 0
1 R3
4 0 ( 2 R ) 3
( )
2
2 R
3 0
2 Also for EQ = 0
Q1 4 0 ( 2 R )
2
=4
Q2 4 0 ( 5 R )
2
=0
Q1 Q2
4 25
1 2
32 25
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A bob of mass m, suspended by a string of length l1, is given a minimum velocity required to complete a full circle in the vertical plane. At the highest point, it collides elastically with another bob of mass m suspended by a string of length l2, which is initially at rest. Both the strings are mass-less and inextensible. If the second bob, after collision acquires the minimum speed required to complete a full circle in the vertical plane, the ratio
l1 is l2
Ans.(5) u1 = 5 gl1
At highest point v1 =
u2 = v1 = gl1
To complete vertical circle
gl1 = 5 gl2
l1 =5 l2
17.
A particle of mass 0.2 kg is moving in one dimension under a force that delivers a constant power 0.5 W to the particle. If the initial speed (in ms 1 ) of the particle is zero, the speed (in ms 1 ) after 5 s is
Ans.(5)
P = 0.5W
W = Pdt = Pt = 0.5 5 = 2.5 J
K = W 1 2 1 0.2 v 2 = 2.5 mv = W 2 2 v 2 = 25 v = 5 m / s
18.
The work functions of Silver and Sodium are 4.6 and 2.3 eV, respectively. The ratio of the slope of the stopping potential versus frequency plot for Silver to that of Sodium is
Ans.(1) h = w0 + eVC
w h VC = 0 e e
Slope of VC versus is Hence ratio = 1
h = Constant e
19.
A freshly prepared sample of a radioisotope of half-life 1386 s has activity 103 disintegrations per second. Given that ln 2 = 0.693, the fraction of the initial number of nuclei (expressed in nearest integer percentage) that will decay in the first 80 s after preparation of the sample is
Ans.(4)
T1/ 2 =
0.693
= 1386 =
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N = N 0e
t t
N N N 0 (1 e ) t = = 1 e f = 0 N0 N0 1 1 t = 80 = = 0.04 2000 25
f = (1 e
0.04
) = 1 0.96 = 0.04
Percentage fraction = 4
20.
A uniform circular disc of mass 50 kg and radius 0.4 m is rotating with an angular velocity of 10 rad s 1 about its own axis, which is vertical. Two uniform circular rings, each of mass 6.25 kg and radius 0.2 m, are gently placed symmetrically on the disc in such a manner that they are touching each other along the axis of the disc and are horizontal. Assume that the friction is large enough such that the rings are at rest relative to the disc and the system rotates about the original axis. The new angular velocity (in rad s 1 ) of the system is
I = ( I + 2 I 1 )1
2 2 MR 2 R 2 MR R = + 2 m + m 1 2 2 2 2 2 MR 2 MR 2 = + mR 2 1 2
50 50 10 = + 6.25 1 2 2
1 = 8 rad/s
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Part2:CHEMISTRY
P = [ FeF6 ]
2+
2+
4s0 3d5
n =5
Q = [V(H 2 O)6 ]2 + V2 +
4s0 3d3
n =3
R = [Fe(H 2 O)6 ]2 + Fe 2+
4s0 3d 6
n=4
22.
The arrangement of X ions around A+ ion in solid AX is given in the figure (not drawn to scale). If the radius of
X is 250 pm, the radius of A+ is.
104 pm (B) 125 pm (A) Ans. (A)Using radius ratio for octahedral void (FCC)
r+ r
= 0.414
(C)
183 pm
(D)
57 pm
23.
Sulfide ores are common for the metals (A) Ag, Cu and Pb (C) Ag, Mg and Pb
Silver glance Copper glance & Copper pyrite Galena Cu2S, CuFeS2 PbS
(B) (D)
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24.
The
standard
enthalpies
of
formation
of
CO2(g),
H2O(l)
and
glucose
(s)
at
25o C
are
400 kJ / mol, 300 kJ / mol and 1300 kJ / mol , respectively. The standard enthalpy of combustion per gram
+ 2900 kJ
(B)
2900 kJ
(C)
16.11 kJ
(D)
+ 16.11 kJ
As we know
H = H f (Product) H f (Reactants)
2900 180
= 16.11 kJ .
25.
Upon treatment with ammoniacal H2S, the metal ion that precipitates as a sulfide is. (A) Fe (III) (B) Al (III) (C) Mg (II) (D)
Zn (II)
Methylene blue, from its aqueous solution, is absorbed on activated charcoal at 25o C . For this process, the correct statement is.
(A) The adsorption requires activation at 25o C (B) The adsorption is accompanied by a decrease in enthalpy (C) The adsorption increases with increase of temperature (D) The adsorption is irreversible Ans. (B) Methylene blue on activated charcoal is an example of physiosorption. Since entropy decreases adsorption
KI in acetone, undergoes SN2 reaction with each of P, Q, R and S. The rates of the reaction vary as.
(A) (C)
P>Q>R>S P>R>Q>S
(B) (D)
S>P>R>Q R>P>S>Q
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28.
In the reaction,
P + Q R + S
the time taken for 75% reaction of P is twice the time taken for 50% reaction of P. The concentration of Q varies with reaction time as shown in the figure. The overall order of the reaction is.
(A) (C)
2 0
(B) (D)
3 1
Ans. (D)Since time taken for 75% reaction of P is twice the time taken for 50% reaction of P. Hence reaction is first order
w.r.t. P. Analysis of graph of Q w.r.t. time shows, reaction of Q is of zero order. Hence overall order of the reaction is one.
Concentrated nitric acid, upon long standing, turns yellow-brown due to the formation of (A) NO (B) NO2 (C) N2O (D) N2O4 1 2 NO 2 + O 2 + H 2 O Ans. (B) HNO3 on standing decomposes as 2 HNO3 2
29.
30.
The compound that does NOT liberate CO2, on treatment with aqueous sodium bicarbonate solution, is. (A) Benzoic acid (B) Benzenesulphonic acid (C) Salicylic acid (D) Carbolic acid (Phenol) Ans. (D)Phenol is too weak to liberate CO2 with NaHCO3.
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31.
The initial rate ofr hydrolysis of methyl acetate (1M) by a weak acid (HA, 1M) is 1/100th of that of a strong acid (HX, 1M), at 25o C. The Ka of HA is (A)
1 104 1106
(B) 1 10 (D)
1103
[Since (RCOOR) is common]
(Given)
K = Ae Ea / Rt
Kw Ks
Aw As
100
. . . .(i)
HA + H 2 O
H3O + + A
C C
In equation (i)
C 1
1 100
= 0.01 (Q C = 1M)
and
Ka =
C 2 1
= 104
32.
The hyperconjugative stabilities of tert-butyl cation and 2-butene, respectively, are due to (A) p (empty ) and * electron deloaclisations. (B) * and electron deloaclisations.
(C) p ( filled ) and electron deloaclisations. (D) p ( filled ) * and * electron deloaclisations. Ans. (A)Hyperconjugation in tert-butyl carbocation refers to delocalisation of -electrons over the empty p-orbitals of C+. In 2-butene, it refers to delocalisation of -electrons over the * orbitals of C = C.
33.
The pair(s) of coordination complexes/ions exhibiting the same kind of isomerism is(are) (A) [Cr ( NH 3 )5 Cl ] Cl2 and [Cr ( NH 3 ) 4 Cl2 ] Cl (B) (C) (D)
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34.
(A) (C)
P R
(B) Q (D) S
Ans. (ABCD)
(A)
(B)
(C)
110 115C
(D)
35.
Benzene and naphthalene form an ideal solution at room temperature. For this process, the true statement(s) is (are) (a) G is positive (b) S system is positive (c) S surroundings = 0
(d) H = 0 Ans. (BCD) Benzene and Naphthalene form an ideal solution at room temperature. H = 0 For mixing of liquids, Ssystem is positive. (Entropy increase for mixing).
qsys SSurr = T =0
( Since
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The atomic masses of He and Ne are 4 and 20 a.m.u., respectively. The value of the de Broglie wavelength of He gas at -73 0C is M times that of the de Broglie wavelength of Ne at 727 0C. M is
h 2m( KE )
37.
EDTA
is ethylenediaminetetraacetate ion. The total number of N-Co-O bond angles in Co( EDTA)
complex ion is
Ans. (8)
38.
Ans. (2)
39.
A tetrapeptide has COOH group on alanine. This produces glycine (Gly), valine (Val), phenyl alanine (Phe) and alanine (Ala), on complete hydrolysis. For this tetrapeptide, the number of possible sequences (primary structures) with NH 2 group attached to a chiral centre is
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O || Ans. (4) (gly/valine/Ph-al) NH C C OH | CH3
Primary structure If glycine is at left corner, then NH2 will be at if valine at corner
O || gly NH 2 C H C NH alanine | Phenyl alanine i pr
2 arrangements
2 arrangements
4 possible structures.
40.
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Part3:MATHS
For a > b > c > 0 , the distance between (1, 1) and the point of intersection of the lines ax + by + c = 0 is less than 2 2 . Then
(A) (C)
(B) (D)
Ans.
42.
The area enclosed by the curves y = sin x + cos x and y =| cos x sin x | over the interval 0 , is 2
4( 2 1)
(B) (D)
2 2 ( 2 1)
2( 2 + 1)
2 2( 2 + 1)
43.
6 2
(B) (D)
4 0
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Ans.
44.
23 25
23 24
(B) (D)
25 23
24 23
45.
y y A curve passes through the point 1, . Let the slope of the curve at each point x, y be + sec ,x > 0 . x 6 x
(B) (D)
y cos ec = log x + 2 x
2y sec = log x + 2 x
1 2y cos = log x + 2 x
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46.
1 Let f : ,1 2
(the set of all real numbers) be a positive, non-constant and differentiable function such
1/ 2
(B) (D)
(e 1, 2e 1)
e 1 0, 2
47.
r r and SQ = determine diagonals of a parallelogram PQRS and i+ j 2k i 3 j 4k Let PR = 3 r r another vector. Then the volume of the parallelepiped determined by the vectors PT ,PQ and
r be PT = i + 2 j + 3k r PS is
5 10
(B) (D)
20 30
48.
Perpendiculars are drawn from points on the line perpendicular lie on the line.
(A) (C)
x y 1 z 2 = = 13 5 8 x y 1 z 2 = = 7 4 3
(B) (D)
Ans.
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49.
Four persons independently solve a certain problem correctly with probabilities that the problem is solved correctly by at least one of them is
(A) (C)
235 256
(B) (D)
21 256
3 256
253 256
Ans.
50.
(B)
1 2
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(C) Ans.
1 7
(D)
1 3
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, + ( 1 + 2t ) l1 : ( 3 + t ) i j + ( 4 + 2t ) k , + ( 3 + 2s ) l : (3 + 2s ) i j + (2 + s) k
2
Then, the coordinate(s) of the point(s) on l2 at a distance of 17 from the point of intersection of l and l1 is (are) (A) 7 , 7 , 5 (B) ( 1, 1, 0 ) 3 3 3 7 7 8 (D) (C) (1, 1, 1) , , 9 9 9
Ans.
52.
Let f ( x) = x sin x, x > 0 . Then for all natural numbers n, f(x) vanishes at (A) a unique point in the interval n, n + 1 2 (B) a unique point in the interval n + 1 , n + 1 (C) a unique point in the interval ( n, n + 1) (D) two points in the interval ( n, n + 1)
2
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Ans.
53.
Let S n = ( 1)
k =1
4n
k ( k +1) 2
(A) (C)
Ans.
1056 1120
54.
For 3x3 matrices M and N, which of the following statement(s) is(are) NOT correct? (A) NT M N is symmetric or skew symmetric, according as M is symmetric or skew symmetric (B) M N N M is skew symmetric for all symmetric matrices M and N (C) M N is symmetric for all symmetric matrices M and N (D) (adj M) (adj N) = adj (M N) for all invertible matrices M and N
Ans.
55.
A rectangular sheet of fixed perimeter with sides having their lengths in the ratio 8:15 is converted into an open rectangular box by folding after removing squares of equal area from all four corners. If the total area of removed squares is 100, the resulting box has maximum volume. Then the lengths of the sides of the rectangular sheet are (A) 24 (B) 32 (C) 45 (D) 60
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Ans.
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56.
ways. Then p is
Ans.
57.
Of the independent events E1, E2 and E3 the probability that only E1 occurs is , only E2 occurs is and only E3 occurs is Let the probability p that none of events E1, E2 or E3 occurs satisfy the equations
( 2 ) p = and ( 3 ) p = 2 .
All the given probabilities are assumed to lie in the interval (0,1). Probability of occurrence of E1 Then = Probability of occurrence of E 3
Ans.
58.
n +5
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Ans.
59.
A pack contain n cards numbered from 1 to n. Two consecutive numbered cards are removed from the pack and the sum of the numbers on the remaining cards is 1224. If the smaller of the numbers on the removed cards is k, then k-20 =
Ans.
60.
x y + = 1 at the points P and Q. Let the 4 3 tangents to the ellipse at P and Q meet at the point R. If ( h ) =area of the triangle PQR, 1 = max ( h) and
A vertical line passing through the point (h, 0) intersects the ellipse
1/ 2 h 1
8 1 8 2 = 5
Ans.
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JEEAdvanced2013 AnswerKey
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PHYSICS
1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 D A D A B B C C A B B,D A,C B,C A,D B,D 5 5 1 4 8 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40
CHEMISTRY
B A A C D B B D B D A A B,D A,B,C,D B,C,D 5 8 2 4 6
MATHS
41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 59 60 A B C B A D C D A C B,D B,C A,D C,D A,C 5 6 6 5 9
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