- Is the face of Calvin Klein.
- Is a supermodel.
- Was ranked #16 in Channel 5's "World's greatest supermodel".
- The print ad that launched her career was when she became the face of "Gucci Envy" (Eau de Parfum) fragrance.
- Founder of Naked Heart Foundation.
- Has five children: son Lucas Alexander Portman (b. December 22, 2001), daughter Neva Portman (b. March 24, 2006), and son Viktor Portman (b. September 13, 2007) with ex-husband Justin Portman; two sons, Maxim Arnault (b. May 2, 2014) and Roman Arnault (b. June 4, 2016), with fiance Antoine Arnault (they are dating since 2011 and got engaged in the spring 2019).
- Her ex-husband Justin Portman is a real estate heir. He is also a professional artist and often travels with Natalia and their children.
- Ex-husband's family estate is in Herefordshire, England.
- Vodianova's ex-husband is The Honourable Justin Portman, who is a professional artist. Portman is the son of a Viscount and scion of one of Britain's wealthiest real estate families which owns huge swathes of London. He chooses not to use his title.
- Returned to work 2 weeks after giving birth to her son Lucas.
- Model Agencies: NY-DNA, Paris-Viva, London-ICM, Milan-Why Not
- She got photographed naked, nursing her infant son in the hope of helping people view motherhood positively.
- Her first major modeling assignment (at age 18 and 8 months pregnant) came with a photo shoot by Juergen Teller for a Marc Jacobs fashion campaign.
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