- He resides in Berlin with actress Alexandra Maria Lara. They meet on the set of Control (2007).
- Son, Ben, was born in January 2014. Mother is Alexandra Maria Lara.
- Lead singer of the band 10,000 Things, signed to Domino Records between 2003-2006. His brother George Riley played Bass.
- He proposed to his girlfriend Alexandra Maria Lara on December 24, 2008.
- Once worked in a clothing factory in Leeds after his band was dropped by their record label.
- Was named one of the "Ten Actors to Watch" by Variety magazine (2007).
- Former member of the National Youth Theatre.
- Went to Uppingham School in Rutland, England.
- His sister is actress Annabel Riley.
- He appeared in the music video "Shadowplay" by the rock band The Killers, from the soundtrack of Control (2007).
- He was only four months old when Ian Curtis died, of whom he plays in his breakthrough film Control (2007).
- Born on the same date as Rachel Nichols.
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