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Groundwater quality in Coachella Valley, California

2012, Fact Sheet

Groundwater provides more than 40 percent of California's drinking water. To protect this vital resource, the State of California created the Groundwater Ambient Monitoring and Assessment (GAMA) Program. The Priority Basin Project of the GAMA Program provides a comprehensive assessment of the State's groundwater quality and increases public access to groundwater-quality information. Coachella Valley is one of the study areas being evaluated. GAMA's Priority Basin Project evaluates the quality of untreated groundwater. However, for context, benchmarks established for drinking-water quality are used for comparison. Benchmarks and definitions of high, moderate, and low concentrations are discussed in the inset box on page 3. The USGS sampled 19 wells for this assessment; data from the California Department of Public Health database were used to supplement USGS data. Many inorganic constituents occur naturally in groundwater. The concentrations of the inorganic constituents can be affected by natural processes as well as by human activities. In the Coachella study area, one or more inorganic constituents were present at high concentrations in 42% of the primary aquifers and at moderate concentrations in 26%. Organic constituents are found in products used in the home, business, industry, and agriculture. Organic constituents can enter the groundwater system through normal usage, spills, or improper disposal. In the Coachella study area, organic constituents were present at moderate concentrations in 1% of the primary aquifers. The Coachella study area is approximately 820 square miles (2,124 square kilometers) and includes the Coachella Valley groundwater basin (California Department of Water Resources, 2003). Coachella Valley has an arid climate, with average annual rainfall of about 6 inches (15 centimeters). The runoff from the surrounding mountains drains to rivers that flow east and south out of the study area to the Salton Sea. Land use in the study area is approximately 67 percent (%) natural, 21% agricultural, and 12% urban. The primary natural land cover is shrubland. The largest urban areas are the cities of Indio and Palm Springs (2010 populations of 76,000 and 44,000, respectively). Groundwater in this basin is used for public and domestic water supply and for irrigation. The main water-bearing units are gravel, sand, silt, and clay derived from surrounding mountains. The primary aquifers in Coachella Valley are defined as those parts of the aquifers corresponding to the perforated intervals of wells listed in the California Department of Public Health database. Public-supply wells in Coachella Valley are completed to depths between 490 and 900 feet (149 to 274 meters), consist of solid casing from the land surface to a depth of 260 to 510 feet (79 to 155 meters), and are screened or perforated below the solid casing. Recharge to the groundwater system is primarily runoff from the surrounding mountains, and by direct infiltration of irrigation. The primary sources of discharge are pumping wells, evapotranspiration, and underflow to the Salton Sea and Imperial Valley areas. The Coachella Study Area Overview of Water Quality High Moderate CONSTITUENT CONCENTRATIONS Low or not detected Pie charts illustrate the percentages of the primary aquifers, on an areal basis, with concentrations in the three specified categories.

U.S. Geological Survey and the California State Water Resources Control Board Groundwater Quality in Coachella Valley, California Groundwater provides more than 40 percent of California’s drinking water. To protect this vital resource, the State of California created the Groundwater Ambient Monitoring and Assessment (GAMA) Program. The Priority Basin Project of the GAMA Program provides a comprehensive assessment of the State’s groundwater quality and increases public access to groundwater-quality information. Coachella Valley is one of the study areas being evaluated. The Coachella Study Area Overview of Water Quality 116°30’ 116°45’ 116°15’ 116° EXPLANATION SAN BERNARDINO COUNTY C ol 34° or a Co do ac Riv he ll a Lake Va que ll e du yG 33°45’ Alluvium ct r ou Study area boundary nd wa t er Ba s in 0 5 10 20 KILOMETERS SAN DIEGO COUNTY IMPERIAL COUNTY The Coachella study area is approximately 820 square miles (2,124 square kilometers) and includes the Coachella Valley groundwater basin (California Department of Water Resources, 2003). Coachella Valley has an arid climate, with average annual rainfall of about 6 inches (15 centimeters). The runoff from the surrounding mountains drains to rivers that flow east and south out of the study area to the Salton Sea. Land use in the study area is approximately 67 percent (%) natural, 21% agricultural, and 12% urban. The primary natural land cover is shrubland. The largest urban areas are the cities of Indio and Palm Springs (2010 populations of 76,000 and 44,000, respectively). Groundwater in this basin is used for public and domestic water supply and for irrigation. The main water-bearing units are gravel, sand, silt, and clay derived from surrounding mountains. The primary aquifers in Coachella Valley are defined as those parts of the aquifers corresponding to the perforated intervals of wells listed in the California Department of Public Health database. Public-supply wells in Coachella Valley are completed to depths between 490 and 900 feet (149 to 274 meters), consist of solid casing from the land surface to a depth of 260 to 510 feet (79 to 155 meters), and are screened or perforated below the solid casing. Recharge to the groundwater system is primarily runoff from the surrounding mountains, and by direct infiltration of irrigation. The primary sources of discharge are pumping wells, evapotranspiration, and underflow to the Salton Sea and Imperial Valley areas. U.S. Department of the Interior U.S. Geological Survey 1 32 42 26 99 CONSTITUENT CONCENTRATIONS Moderate Low or not detected Pie charts illustrate the percentages of the primary aquifers, on an areal basis, with concentrations in the three specified categories. Salton Sea 33°30’ 20 MILES Number analyzed: 79 High RIVERSIDE COUNTY 10 Number analyzed: 27 Hard rock Indio 5 Organic constituents Urban area er A Palm Springs 0 Inorganic constituents Printed on recycled paper GAMA’s Priority Basin Project evaluates the quality of untreated groundwater. However, for context, benchmarks established for drinking-water quality are used for comparison. Benchmarks and definitions of high, moderate, and low concentrations are discussed in the inset box on page 3. The USGS sampled 19 wells for this assessment; data from the California Department of Public Health database were used to supplement USGS data. Many inorganic constituents occur naturally in groundwater. The concentrations of the inorganic constituents can be affected by natural processes as well as by human activities. In the Coachella study area, one or more inorganic constituents were present at high concentrations in 42% of the primary aquifers and at moderate concentrations in 26%. Organic constituents are found in products used in the home, business, industry, and agriculture. Organic constituents can enter the groundwater system through normal usage, spills, or improper disposal. In the Coachella study area, organic constituents were present at moderate concentrations in 1% of the primary aquifers. Fact Sheet 2012–3098 January 2013 RESULTS: Groundwater Quality in the Coachella Study Area INORGANIC CONSTITUENTS 37 42 Trace elements 21 10 4 Radioactive constituents 86 5 2 Nutrients 93 Inorganic Constituents with Human-Health Benchmarks Trace elements are naturally present in the minerals in rocks and soil, and in the water that comes into contact with those materials. In the Coachella study area, trace elements with human-health benchmarks were present at high concentrations in 37% of the primary aquifers. Trace elements were present at moderate concentrations in 21% of the primary aquifers. Of the 17 trace elements with humanhealth benchmarks analyzed in this study, 5 were detected at high concentrations: arsenic, boron, fluoride, molybdenum, and strontium. Vanadium was present at moderate concentrations. Radioactivity is the release of energy or energetic particles during structural changes in the nucleus of an atom. Most of the radioactivity in groundwater comes from decay of naturally occurring isotopes of uranium and thorium that are present in minerals in the aquifer. In the Coachella study area, radioactive constituents were detected at concentrations above benchmarks in 4% of the primary aquifers, and at moderate concentrations in 10%. Six radioactive constituents were analyzed; of these, uranium and gross alpha radioactivity were detected at concentrations above benchmarks. Nutrients, such as nitrate and nitrite, are naturally present at low concentrations in groundwater. High and moderate concentrations generally occur as a result of human activities, such as fertilizer application, livestock waste, or septic-system seepage. Of the three nutrients with health-based benchmarks analyzed, one, nitrate, was detected at concentrations above benchmarks in the Coachella primary aquifers. Inorganic Constituents with Non-Health Benchmarks 16 21 63 Other inorganic constituents 10 Special Interest: Perchlorate 16 74 (Not included in water-quality overview charts shown on the front page) Other inorganic constituents, such as total dissolved solids and manganese, affect the aesthetic properties of water, such as taste, color, or odor. In the Coachella study area, these constituents were present at high concentrations in 16% of the primary aquifers, and at moderate concentrations in 21%. Of the seven constituents with non-health-based benchmarks analyzed, four were detected at concentrations above benchmarks: chloride, manganese, total dissolved solids, and sulfate. Perchlorate Perchlorate is an inorganic constituent that has been regulated in California drinking water since 2007. It is an ingredient in rocket fuel, fireworks, safety flares, may be present in some fertilizers, and also occurs naturally at low concentrations in groundwater. In the Coachella study area, perchlorate was found at high concentrations in 10% and at moderate concentrations in 16% of the primary aquifers. RESULTS: Groundwater Quality in the Coachella Study Area ORGANIC CONSTITUENTS Organic Constituents with Human-Health Benchmarks The Priority Basin Project uses laboratory methods that can detect the presence of volatile organic compounds (VOCs) and pesticides at very low concentrations, far below human-health benchmarks. VOCs and pesticides detected at these very low concentrations can be used to help trace water from the land surface into the aquifer system. Volatile Organic Compounds 1 99 Volatile organic compounds VOCs are present in many household, commercial, industrial, and agricultural products, and are characterized by their tendency to volatilize into the air. Of 56 VOCs with health-based benchmarks analyzed in the Coachella study area, none were detected above benchmarks. The VOCs trichloromethane and tetrachloroethene were detected at moderate concentrations in 1% of the Coachella primary aquifers. Pesticides 100 Pesticides Pesticides are used on lawns, in gardens, around buildings, along roads, and in agriculture to help control unwanted vegetation (weeds), insects, fungi, and other pests. In the Coachella study area, pesticides were not detected or only detected at low concentrations. Of the 20 pesticides with health-based benchmarks that were analyzed in the Coachella primary aquifers, none were detected at high or moderate concentrations in the primary aquifers. BENCHMARKS FOR EVALUATING GROUNDWATER QUALITY CONSTITUENT CONCENTRATIONS EXAMPLE GAMA’s Priority Basin Project uses benchmarks established for drinking water to provide context for evaluating the quality of untreated groundwater. After withdrawal, groundwater may be disinfected, filtered, mixed, or exposed to the atmosphere before being delivered to consumers. Federal and California regulatory benchmarks for protecting human health (Maximum Contaminant Level, MCL) are used when available. Otherwise, nonregulatory benchmarks for protecting human health (Notification Level, NL, and Lifetime Health Advisory, HAL) and nonregulatory benchmarks for protecting aesthetic properties such as taste and odor (Secondary Maximum Contaminant Level, SMCL) are used. High Moderate Low or not detected Values are a percentage of the area of the primary aquifers with concentrations in the three specified categories. High, moderate, and low concentrations are defined relative to benchmarks Concentrations are considered high if they are greater than a benchmark. For inorganic constituents, concentrations are moderate if they are greater than one-half of a benchmark. For organic and special-interest constituents, concentrations are considered moderate if they are greater than one-tenth of a benchmark; this lower threshold was used because organic constituents are generally less prevalent and have smaller concentrations relative to benchmarks than inorganic constituents. Low concentrations include nondetections and values less than moderate concentrations. Methods for evaluating water quality are discussed by Milby Dawson and Belitz (2012). Trace Element Concentrations Throughout the California Desert Region Priority Basin Assessments Trace elements were present at high concentrations in all of the Desert Region primary aquifers. In the Coachella study area, they were high in 37% of the primary aquifers, on an areal basis; the range of high trace element percentages in the Desert Region primary aquifers was 15 to 54% (Milby Dawson and Belitz, 2012). The trace elements with the highest percentages in Coachella were arsenic (high in 21% of the primary aquifers) and fluoride (21%). Arsenic was found at high concentrations in all of the primary aquifers in the Desert region. Fluoride was found at high concentrations in five of the six Desert Region study areas and in the highest proportion in Coachella. Indian Wells Antelope ARIZONA Mojave Colorado River Coachella CALIFORNIA MEXICO 60% 40% 20% 0% 100% Arsenic 80% 60% 40% 20% 0% 100% Fluoride 80% 60% 40% 20% 0% Mojave NEVADA Trace Elements 80% Antelope Owens Valley 100 KILOMETERS 100% Colorado River 0 25 50 100 MILES Coachella 50 Indian Wells 25 Owens 0 Percentage of area of primary aquifers with concentrations in the specified categories Desert Region Study Areas EXPLANATION High aquifer proportion Moderate aquifer proportion By Barbara J. Milby Dawson and Kenneth Belitz SELECTED REFERENCES California Department of Water Resources, 2003, California’s groundwater: California Department of Water Resources Bulletin 118, 246 p., available at http://www.water.ca.gov/groundwater/bulletin118/update2003.cfm Goldrath, D.A., Wright, M.T., and Belitz, K., 2009, Ground-water quality data in the Coachella Valley study unit, 2007—Results from the California GAMA Program: U.S. Geological Survey Data Series 373, 70 p., available at http://pubs.usgs.gov/ds/373 Milby Dawson, B.J., and Belitz, K., 2012, Status of groundwater quality in the California Desert Region, 2006–2008—California GAMA Program Priority Basin Project: U.S. Geological Survey Scientific Investigations Report 2012-5040, 100 p. GAMA’s Priority Basin Project (PBP) assesses water quality in that part of the aquifer system used for drinking water, primarily public supply. Water quality in shallower and deeper parts may differ from water quality in the primary aquifers. GAMA’s Domestic Well Project assesses water quality in the shallower parts of the aquifer system. Ongoing assessments are being conducted in more than 120 basins throughout California. The PBP assessments are based on a comparison of constituent concentrations in untreated groundwater with benchmarks established for the protection of human health and for aesthetic concerns. The PBP does not evaluate the quality of drinking water delivered to consumers. The PBP uses two approaches for assessing groundwater quality. The first approach uses a network of wells to provide a statistically based assessment of the status of groundwater quality. The second approach uses additional wells to help assess the factors that affect water quality. Both approaches use data routinely collected for regulatory compliance, as well as data collected by the PBP. The PBP includes chemical analyses not generally available as part of regulatory compliance monitoring, including measurements at concentrations much lower than humanhealth benchmarks, and measurement of constituents that can be used to trace the sources and movement of groundwater. For more information Technical reports and hydrologic data collected for the GAMA Program may be obtained from: GAMA Program Unit U.S. Geological Survey California Water Science Center 4165 Spruance Road, Suite 200 San Diego, CA 92101 Telephone number: (619) 225-6100 WEB: http://ca.water.usgs.gov/gama GAMA Program Unit State Water Resources Control Board Division of Water Quality PO Box 2231, Sacramento, CA 95812 Telephone number: (916) 341-5779 WEB: http://www.waterboards.ca.gov/gama/